CN114702204A - Aquatic industrial wastewater treatment method and treatment system thereof - Google Patents

Aquatic industrial wastewater treatment method and treatment system thereof Download PDF

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CN114702204A
CN114702204A CN202210381957.XA CN202210381957A CN114702204A CN 114702204 A CN114702204 A CN 114702204A CN 202210381957 A CN202210381957 A CN 202210381957A CN 114702204 A CN114702204 A CN 114702204A
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wastewater
tank
ammonia nitrogen
nitrogen concentration
oil separation
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陈艺敏
谢建华
郑素卿
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Zhangzhou Institute of Technology
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/40Devices for separating or removing fatty or oily substances or similar floating material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2203/00Apparatus and plants for the biological treatment of water, waste water or sewage
    • C02F2203/002Apparatus and plants for the biological treatment of water, waste water or sewage comprising an initial buffer container
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/14NH3-N
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/18PO4-P
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/22O2
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/308Biological phosphorus removal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

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  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

The invention discloses a method for treating waste water in aquatic industry and a treatment system thereof, wherein the waste water is discharged into a pretreatment system consisting of an oil separation tank, an air flotation tank and a regulating tank, and steam of a cooking boiler is introduced into the oil separation tank; discharging the wastewater into an anaerobic tank-A2an/O reaction cell according to A2Adjusting the wastewater temperature in the oil separation tank by the ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tankImproving the efficiency of short-cut nitrification and denitrification, and discharging the wastewater into a vertical secondary sedimentation tank for sludge-water separation; and (3) enabling the supernatant of the vertical flow type secondary sedimentation tank to flow into an inclined tube sedimentation tank, and carrying out advanced treatment on the wastewater. The steam of the cooking boiler is introduced into the oil separation tank, and the water inlet temperature of the oil separation tank is increased and A is increased by utilizing the steam2The temperature of the feed water to the/O reaction tank and according to A2The ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank adjusts the temperature of the wastewater in the oil separation tank, the efficiency of shortcut nitrification and denitrification can be improved, ammonia nitrogen can be quickly and effectively removed, the quality of the outlet water is guaranteed to be stable and reach the standard, and the method has the advantages of low investment, stable operation and high treatment efficiency.

Description

Aquatic industrial wastewater treatment method and treatment system thereof
Technical Field
The invention relates to the technical field of wastewater treatment, in particular to an aquatic industry wastewater treatment method and a treatment system thereof.
Background
With the rapid development of fishery in China, China has become the main aquatic product producing country in the world, and the aquatic product processing industry is developed and developed. The aquatic product processing wastewater has the characteristics of more suspended matters, high organic matter content, high ammonia nitrogen total phosphorus concentration, low water temperature, low biochemical degradation speed and the like. In order to discharge the wastewater of aquatic products up to the standard, a plurality of physical and chemical methods, such as oil removal, air flotation, coagulating sedimentation and the like, are adopted by a plurality of scholars by taking biological treatment as a core, so that a better treatment effect is achieved. However, for aquatic wastewater with high ammonia nitrogen concentration, when the water temperature is low, the biological denitrification efficiency of the sewage is low.
Disclosure of Invention
The invention aims to provide an aquatic industrial wastewater treatment method and an aquatic industrial wastewater treatment system, so as to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: a method of treating aquaculture industrial wastewater, the method comprising:
discharging the wastewater into a pretreatment system consisting of an oil separation tank, an air flotation tank and an adjusting tank to remove grease and suspended matters in the wastewater, wherein steam of a cooking boiler is introduced into the oil separation tank to ensure that the wastewater in the oil separation tank keeps the temperature within a preset temperature range;
discharging the wastewater treated by the pretreatment system into an anaerobic tank-A2A biochemical treatment system consisting of an O reaction tank, organic matter removal, ammonia nitrogen removal by nitrification and biochemical phosphorus removal, wastewater discharge into a vertical flow type secondary sedimentation tank for mud-water separation, monitoring A2The ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank is according to A2Adjusting the ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank to adjust the wastewater in the oil separation tankWater temperature to improve the efficiency of short-cut nitrification and denitrification;
and (3) enabling the supernatant of the vertical flow type secondary sedimentation tank to flow into an inclined tube sedimentation tank, and carrying out advanced treatment on the wastewater by adopting a dephosphorization agent.
Further, according to A2Adjusting the wastewater temperature in the oil separation tank by the ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank: setting an initial temperature, detecting A2And (4) the initial ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank is repeatedly increased until the ammonia nitrogen concentration is continuously greater than the initial ammonia nitrogen concentration so as to obtain the wastewater temperature in the oil separation tank.
Further, according to A2Adjusting the wastewater temperature in the oil separation tank by the ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank: setting an initial temperature, detecting A2And (3) repeatedly reducing the initial ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank and detecting the ammonia nitrogen concentration in the wastewater at the water outlet end until the ammonia nitrogen concentration is continuously less than the initial ammonia nitrogen concentration so as to obtain the temperature of the wastewater in the oil separation tank.
Further, monitor A2When the ammonia nitrogen concentration in the wastewater at the water inlet end of the/O reaction tank is gradually increased, the ammonia nitrogen concentration is gradually increased for the A2And (3) carrying out ammonia nitrogen resistant culture on nitrifying bacteria in the/O reaction tank.
Further, monitor A2When the phosphate concentration in the wastewater at the water inlet end of the/O reaction tank is increased in a gradient manner, the phosphate concentration in the wastewater is adjusted to be A2And (3) carrying out salt-tolerant culture on nitrifying bacteria in the/O reaction tank.
Further, lime and/or coagulant are added to carry out advanced treatment on the wastewater.
An aquatic product industrial wastewater treatment system comprises an oil separation tank, an air flotation tank, an adjusting tank, an anaerobic tank and a tank A which are sequentially connected through pipelines2The treatment system comprises a/O reaction tank, a vertical flow type secondary sedimentation tank, an inclined tube sedimentation tank, a controller, a steam pipeline for introducing steam of a cooking boiler, and a water inlet pipe, wherein the oil separation tank is internally provided with a steam pipeline for introducing steam of the cooking boiler, and the water inlet pipe is connected with the controller2The water outlet end of the/O reaction tank is provided with an effluent ammonia nitrogen online detector for monitoring the ammonia nitrogen concentration in the wastewater at the water outlet end, and the controller and the effluent ammonia nitrogen are onlineDetector signal connection according to A2Adjusting the temperature of the wastewater in the oil separation tank by the ammonia nitrogen concentration in the wastewater at the water outlet end of the O reaction tank.
Further, said A2The water inlet end of the/O reaction tank is provided with an inlet ammonia nitrogen online detector for monitoring the ammonia nitrogen concentration in the waste water at the water inlet end, the controller is further connected with the inlet ammonia nitrogen online detector in a signal mode, and when the outlet ammonia nitrogen online detector detects that the ammonia nitrogen concentration gradually increases, the controller is used for detecting the ammonia nitrogen concentration of the waste water at the water inlet end and the outlet ammonia nitrogen online detector detects that the ammonia nitrogen concentration gradually increases to A2And (3) carrying out ammonia nitrogen resistant culture on nitrifying bacteria in the/O reaction tank.
Further, A is2The water inlet end of the/O reaction tank is provided with an online detector for monitoring the concentration of phosphate in wastewater at the water inlet end, the controller is further in signal connection with the online detector, and when the online detector detects that the concentration gradient of the phosphate is increased, the controller is used for controlling the concentration of the phosphate in the wastewater at the water inlet end to be A2And (3) carrying out salt-tolerant culture on nitrifying bacteria in the/O reaction tank.
Further, A is2the/O reaction tank is provided with an online DO instrument for controlling the aeration amount.
Compared with the prior art, the invention has the beneficial effects that: the steam of the cooking boiler is introduced into the oil separation tank, the water inlet temperature of the oil separation tank is improved by utilizing the steam, the problems of oil collection tank blockage and low separation efficiency caused by condensed oil blocks in the oil separation tank due to low external temperature are solved, and A is improved2The temperature of the feed water to the/O reaction tank and according to A2The ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank adjusts the temperature of the wastewater in the oil separation tank, the efficiency of short-cut nitrification and denitrification can be improved, ammonia nitrogen can be quickly and effectively removed, a three-section combined treatment process is adopted to ensure that the quality of the outlet water is stable and reaches the standard, and the method has the advantages of low investment, stable operation and high treatment efficiency.
Drawings
FIG. 1 is a schematic diagram of an aquaculture industrial wastewater treatment system according to the present invention;
FIG. 2 is a flow chart of the method for treating the aquatic industrial wastewater of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The main processing products of a certain aquaculture processing company are mainly shrimps and fish, and the wastewater mainly comes from the waste water of removing heads and cleaning, cooking and washing of equipment and containers of raw materials in the production process. The wastewater has high organic matter content, more suspended matters and high ammonia nitrogen content, and because the polyphosphate is used in the aquatic product production, the concentration of phosphorus in water is greatly increased. The engineering water inlet amount is designed to be 50t/d, the designed water inlet quality is shown in the table 1, and the designed water outlet quality reaches the first-level standard in GB8978-1996 Integrated wastewater discharge Standard. The quality of the inlet water and the discharge standard of the outlet water are shown in Table 1.
TABLE 1 Water quality of inlet and outlet water
Figure BDA0003592187500000031
The production and domestic sewage of the factory area of the aquatic product processing enterprise are firstly discharged into the water collecting tank, the wastewater inlet of the water collecting tank is provided with the fine grid, as shown in figure 1, the embodiment provides an aquatic product industrial wastewater treatment system, which comprises an oil separation tank 1, a collecting tank 11, an air flotation tank 2, an adjusting tank 3, an anaerobic tank 4, an A tank which are sequentially connected through a pipeline2a/O reaction tank 5, a vertical flow type secondary sedimentation tank 6, an inclined tube sedimentation tank 7, a sludge concentration tank 8, a sludge screw stacking machine 9, an aeration device and a dosing system, wherein the treatment system also comprises a controller, an oil separation tank 1, an air flotation tank 2 and an adjusting tank 3 form a primary materialization pretreatment system, and an anaerobic tank 4 and an A tank2the/O reaction tank 5 and the vertical flow type secondary sedimentation tank 6 form a secondary biochemical treatment system, the inclined tube sedimentation tank 7 is used as a tertiary chemical phosphorus removal system, the oil separation tank 1 mainly removes organic matters floating on the water surface and recovers the organic matters into the collection tank 2 for utilization, the air floatation tank 2 can remove most suspended matters, and the air floatation tank 2 has more common pollutants, so that the secondary biochemical treatment system has the advantages of high efficiency, low cost and high safetyThe dosing system comprises an alkali medicine barrel 101, a PAC barrel 102 and a PAM medicine barrel 103, when pollutants in water are more, the alkali medicine barrel 101, the PAC barrel 102 and the PAM medicine barrel 103 can be opened, the regulating reservoir 3 has the main function of regulating water quantity and water quality, a blast device is arranged in the regulating reservoir 3 and can play a role of pre-aeration, and the anaerobic reservoir 4 and the anaerobic reservoir A have the functions of pre-aeration2A second-stage biochemical treatment system consisting of an O reaction tank 5 and a vertical flow type secondary sedimentation tank 6, wherein a nitrification process is carried out in an aerobic stage to remove organic matters, and a denitrification process is carried out in an anoxic stage to remove ammonia nitrogen; the phosphorus accumulating bacteria release phosphorus in an anaerobic stage, absorb phosphorus in an aerobic stage, and discharge excess sludge to achieve the aim of biological phosphorus removal, in order to prevent the influence of low water temperature in winter on the subsequent biochemical process, a steam pipeline 12 for introducing steam of a cooking boiler is arranged in the oil separation tank 1, and A2The water outlet end of the/O reaction tank 5 is provided with an effluent ammonia nitrogen online detector 51 for monitoring the ammonia nitrogen concentration in the effluent end wastewater, and the controller is in signal connection with the effluent ammonia nitrogen online detector 51 and is used for controlling the ammonia nitrogen concentration according to A2Adjusting the temperature of the wastewater in the oil separation tank 1 by the ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank 5, wherein A is2The water inlet end of the/O reaction tank 5 is provided with an inlet ammonia nitrogen online detector 52 for monitoring the ammonia nitrogen concentration in the wastewater at the water inlet end, the controller is further in signal connection with the inlet ammonia nitrogen online detector 52, and when the outlet ammonia nitrogen online detector 52 detects that the ammonia nitrogen concentration gradually increases, the controller controls the A to perform the reaction2Nitrifying bacteria in the/O reaction tank 5 are subjected to ammonia nitrogen resistant culture, wherein A is2The water inlet end of the/O reaction tank 5 is provided with an online detector 53 for monitoring the concentration of phosphate in wastewater at the water inlet end, the controller is further in signal connection with the online detector 53, and when the online detector 53 detects that the concentration gradient of the phosphate is increased, the controller is used for controlling the concentration of the phosphate in the wastewater at the water inlet end to be A2The nitrifying bacteria in the/O reaction tank 5 are subjected to salt-tolerant culture to improve the efficiency of short-cut nitrification and denitrification, the wastewater is subjected to mud-water separation in the vertical flow type secondary sedimentation tank 6, certain excess sludge is discharged, the supernatant flows into the inclined tube sedimentation tank 7 for chemical phosphorus removal, in order to ensure that the effluent stably reaches the standard, the dosing system further comprises a lime medicine barrel 104 and a coagulant medicine barrel 105, the lime reacts with phosphate in the wastewater to generate indissolvable phosphorus-containing compounds, and the phosphorus-containing compounds become large flocculation under the action of the coagulantThe method comprises the steps of precipitating an aluminum ion from sewage to achieve the purpose of phosphorus removal, reacting the aluminum ion with a phosphate radical ion in water to generate an aluminum phosphate precipitate, hydrolyzing the aluminum salt in water to generate a hydroxyl complex and positively charge the hydroxyl complex, neutralizing negative charge substances in water to accelerate colloid destabilization, adding a polymeric flocculant in a flocculation zone to help particles to coalesce and precipitate, and further precipitating and separating fine impurity particles in water in an inclined tube precipitation zone to enable final effluent to reach the standard for discharge. The discharged excess sludge enters the sludge concentration tank 8 for sludge-water separation by means of gravity sedimentation, in order to improve the dehydration performance of the sludge, the dosing system further comprises a cationic polyacrylamide dosing barrel 106, cationic Polyacrylamide (PAM) is added to improve the dehydration performance of the sludge, the sludge is dehydrated by a screw stacking machine 9, and the dehydrated sludge cake is transported outside for disposal.
As shown in fig. 2, the present embodiment further provides a method for treating wastewater from aquaculture industry, the method comprising the following steps:
s1: discharging the wastewater into a pretreatment system consisting of an oil separation tank, an air flotation tank and an adjusting tank to remove grease and suspended matters in the wastewater, wherein steam of a cooking boiler is introduced into the oil separation tank to ensure that the wastewater in the oil separation tank keeps the temperature within a preset temperature range;
s2: discharging the wastewater treated by the pretreatment system into an anaerobic tank-A2A biochemical treatment system consisting of an O reaction tank, organic matter removal, ammonia nitrogen removal by nitrification and biochemical phosphorus removal, wastewater discharge into a vertical flow type secondary sedimentation tank for mud-water separation, monitoring A2The ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank is according to A2Adjusting the temperature of the wastewater in the oil separation tank by the ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank so as to improve the shortcut nitrification and denitrification efficiency;
s3: and (3) enabling the supernatant of the vertical flow type secondary sedimentation tank to flow into an inclined tube sedimentation tank, and carrying out advanced treatment on the wastewater by adopting a dephosphorization agent.
Specifically, production and domestic sewage of a factory area of an aquatic product processing enterprise is firstly discharged into a water collecting tank, and as more animal and vegetable oil and suspended substances exist in inlet water, in order to reduce the burden of subsequent biological treatment, a pretreatment system consisting of an oil separating tank, an air flotation tank and an adjusting tank is adopted to remove the oil and suspended substances in the wastewater, and the oil separating tank is used for removing the oil and suspended substances1 mainly get rid of the organic matter that floats on the surface of water and retrieve to collecting pit 2 and carry out the recycle, and floating pit 2 can get rid of most suspended solid, when aquatic pollutant is more, can open alkali explosive barrel 101, PAC bucket 102, PAM explosive barrel 103, and equalizing basin 3 main function is the regulation water yield quality of water, discharges the waste water after pretreatment system handles into anaerobism pond 4-A2The biochemical treatment system composed of the/O reaction tank 5 is used for removing organic matters, nitrifying to remove ammonia nitrogen and carrying out biochemical phosphorus removal, the nitrification process is carried out in the aerobic stage to remove the organic matters, and the denitrification process is carried out in the anoxic stage to remove the ammonia nitrogen; the phosphorus accumulating bacteria release phosphorus in the anaerobic stage, absorb phosphorus in the aerobic stage, and discharge excess sludge to reach the aim of biological phosphorus removal, so as to prevent the influence of low water temperature on the subsequent biochemical process in winter and improve A2The denitration efficiency of the/O reaction tank 5, the steam of a cooking boiler is introduced into the oil separation tank 1, and A is monitored2The ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank 5 is according to A2Adjusting the temperature of the wastewater in the oil separation tank 1 by the concentration of ammonia nitrogen in the wastewater at the water outlet end of the/O reaction tank 5, for example, setting the initial temperature and detecting A2The method comprises the steps of increasing the initial ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank 5, repeatedly increasing the initial temperature and detecting the ammonia nitrogen concentration in the wastewater at the water outlet end until the ammonia nitrogen concentration is continuously higher than the initial ammonia nitrogen concentration to obtain the wastewater temperature in the oil separation tank, repeatedly decreasing the initial temperature and detecting the ammonia nitrogen concentration in the wastewater at the water outlet end until the ammonia nitrogen concentration is continuously lower than the initial ammonia nitrogen concentration to obtain the wastewater temperature in the oil separation tank, specifically, setting the wastewater temperature in the oil separation tank 1 to be 20 ℃, and detecting A2The initial ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank 5 is 16mg/L, the temperature of the wastewater in the oil separation tank 1 is increased to 22 ℃, and A detection is carried out2The initial ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank 5 is 15mg/L, the temperature of the wastewater in the oil separation tank 1 is increased again to 25 ℃, the ammonia nitrogen concentration in the wastewater at the water outlet end is detected to be 13mg/L, the temperature of the wastewater in the oil separation tank 1 is increased again to 26 ℃, the ammonia nitrogen concentration in the wastewater at the water outlet end is detected to be 14mg/L, and the following results can be seen: when the temperature of the wastewater is 25 ℃, the ammonia nitrogen concentration is continuously higher than the initial ammonia nitrogen concentration, so that the temperature of 25 ℃ can be used as the setting temperature of the oil separation tank 1, the ammonia nitrogen concentration is 13mg/L, and then the temperature is reducedThe temperature of the wastewater in the oil interceptor 1 is 19 ℃, and the detection A is carried out2The initial ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank 5 is 15mg/L, the temperature of the wastewater in the oil separation tank 1 is reduced to 17 ℃ again, and A detection is carried out2The initial ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank 5 is 20mg/L, and it can be seen that: when the temperature of the wastewater is 25 ℃, the ammonia nitrogen concentration is continuously less than the initial ammonia nitrogen concentration, so that the 25 ℃ is used as the optimal set temperature of the oil separation tank 1, the effect of shortcut nitrification and denitrification is ensured, and in addition, the embodiment can also monitor A2The ammonia nitrogen concentration in the wastewater at the water inlet end of the/O reaction tank 5 is gradually increased for the ammonia nitrogen concentration A2The nitrifying bacteria in the/O reaction tank 5 are subjected to ammonia nitrogen resistant culture, for example, the first detection A2The ammonia nitrogen concentration in the wastewater at the water inlet end of the/O reaction tank 5 is 85mg/L, and when the A is detected for the second time2When the ammonia nitrogen concentration in the wastewater at the water inlet end of the/O reaction tank 5 is 87mg/L, adding a proper amount of culture solution to the A2Culturing 5 nitrifying bacteria in the/O reaction tank, and detecting A for the third time2When the ammonia nitrogen concentration in the wastewater at the water inlet end of the/O reaction tank 5 is 90mg/L, adding a proper amount of culture solution again to the A2Culturing 5 kinds of nitrifying bacteria in the/O reaction tank until A2The ammonia nitrogen concentration in the water outlet end wastewater of the/O reaction tank 5 is greater than the ammonia nitrogen concentration at the last time, so the nitrifying bacteria are subjected to ammonia nitrogen-resistant culture, the nitrifying bacteria are gradually adapted to the high ammonia nitrogen sewage environment, the nitrification efficiency is improved, the ammonia nitrogen removal rate is improved, and because polyphosphate is used in the aquatic production, the concentration of phosphorus in water is greatly increased, the A-type wastewater treatment device can also monitor the A-type wastewater treatment process2The phosphate concentration in the wastewater at the water inlet end of the/O reaction tank 5 is adjusted to A when the phosphate concentration gradient is increased2The nitrifying bacteria in the/O reaction tank 5 are subjected to salt-tolerant culture, e.g. first detection of A2The phosphate concentration in the wastewater at the water inlet end of the/O reaction tank 5 is 7mg/L, and when the A is detected for the second time2When the ammonia nitrogen concentration in the wastewater at the water inlet end of the/O reaction tank 5 is 8mg/L, adding a proper amount of culture solution to the A2Culturing 5 nitrifying bacteria in the/O reaction tank, and detecting A for the third time2When the ammonia nitrogen concentration in the wastewater at the water inlet end of the/O reaction tank 5 is 9mg/L, adding a proper amount of culture solution again to the A2Culturing 5 kinds of nitrifying bacteria in the/O reaction tank until A2The ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank 5 is higher than the ammonia nitrogen concentration at the last time, so that the nitrifying bacteria are subjected to salt-tolerant culture, the nitrifying bacteria are gradually adapted to a high-salt sewage environment, the nitrification efficiency is improved, and the ammonia nitrogen removal rate is improved; the method comprises the following steps of carrying out sludge-water separation on wastewater in a vertical flow type secondary sedimentation tank 6, discharging certain residual sludge, enabling supernatant to flow into an inclined tube sedimentation tank 7 for chemical phosphorus removal, enabling lime to react with phosphate in the wastewater to generate insoluble phosphorus-containing compounds, enabling the insoluble phosphorus-containing compounds to become large floccules to be precipitated from the wastewater under the action of a coagulant to achieve the aim of phosphorus removal, enabling aluminum ions to react with phosphate ions in the water to generate aluminum phosphate precipitates, meanwhile, hydrolyzing the aluminum salts in the water to generate hydroxyl complexes and positively charging the hydroxyl complexes, neutralizing negative charge substances in the water to accelerate colloid destabilization, adding a high polymer flocculant in a flocculation zone to help particle coalescence and precipitation, further precipitating and separating fine impurity particles in the water in the inclined tube sedimentation zone, and enabling final effluent to reach the standard for discharge. The discharged excess sludge firstly enters a sludge concentration tank 8 to carry out sludge-water separation by means of gravity sedimentation, cationic Polyacrylamide (PAM) is added to improve the dehydration performance of the sludge, then a screw folding machine 9 is used for dehydration, and the dehydrated sludge cake is transported outside for disposal.
In this example, as shown in table 2, the production and domestic wastewater in the plant area was collected by the pipe network and entered the wastewater treatment system, and the Chemical Oxygen Demand (COD) of the wastewater was measured at the water inletCr) 2375mg/L, five days Biochemical Oxygen Demand (BOD)5) 980mg/L, ammonia Nitrogen (NH)3-N) was 93.6mg/L and Total Phosphorus (TP) was 12.3 mg/L. The sewage has high organic matter concentration and high ammonia nitrogen concentration, about 50 percent of organic matter, partial ammonia nitrogen and total phosphorus can be removed after the sewage passes through a pretreatment system consisting of an oil separation tank, an air floatation tank and a regulating tank, but when the sewage enters a biochemical treatment stage, solid and colloidal protein in the sewage are hydrolyzed and ammoniated to release the ammonia nitrogen, so that the ammonia nitrogen concentration can be increased. Thus to increase A2In the denitration efficiency of the/O reaction tank 5, on one hand, the water temperature is adjusted to the optimal temperature, for example, to 25 ℃ by using boiler steam to ensure the effect of short-cut nitrification and denitrification, on the other hand, the nitrifying bacteria are subjected to ammonia nitrogen resistant and salt tolerant culture to improve the nitrification efficiency, and the biological sludge and phosphorus removal efficiency is generally not more than that of biological sludge dischargeAnd if the concentration is over 70 percent, in order to ensure that the effluent stably reaches the standard, adding lime and a coagulant into an inclined tube sedimentation tank behind a vertical flow type secondary sedimentation tank, reacting the lime with phosphate in the sewage to generate an insoluble phosphorus-containing compound, and precipitating the phosphorus-containing compound into a large flocculating constituent from the sewage under the action of the coagulant to achieve the aim of removing phosphorus. The inclined tube sedimentation tank has the characteristics of good treatment effect, short retention time and small occupied area, the addition of the polymeric flocculant in the flocculation zone is favorable for particle coalescence and sedimentation, and the inclined tube sedimentation zone can further precipitate and separate out fine impurity particles in water. Finally, chemical COD is measured at the water outletCrThe concentration is 75mg/L, BOD5The concentration is 15mg/L, NH3The concentration of N is 10mg/L, the concentration of TP is 0.43mg/L, the removal rates are 96.8 percent, 98.5 percent, 89.3 percent and 96.5 percent respectively, and the wastewater reaches the first-level discharge standard in the integrated wastewater discharge standard.
TABLE 2 debugging run results (unit: mg/L)
Figure BDA0003592187500000071
The cost of sewage treatment per ton is about 5 yuan in this embodiment, and the operating cost mainly includes charges of electricity, labour cost and medicament cost, and wherein the charges of electricity account for more than half of the operating cost, and main power consumptive equipment includes air-blower, aerator and backwash pump. Therefore, in order to reduce the cost of sewage treatment, the sewage treatment device can be arranged in a regulating tank A2An on-line DO instrument is added in the/O reaction tank 5 to strictly control the aeration quantity, so that the running electric charge is saved.
The steam of the cooking boiler is introduced into the oil separation tank, the water inlet temperature of the oil separation tank is improved by utilizing the steam, the problems of oil collection tank blockage and low separation efficiency caused by condensed oil blocks in the oil separation tank due to low external temperature are solved, and A is improved2The temperature of the feed water to the/O reaction tank and according to A2The ammonia nitrogen concentration in the wastewater at the water outlet end of the O reaction tank adjusts the temperature of the wastewater in the oil separation tank, and the ammonia nitrogen concentration can be adjustedThe efficiency of short-cut nitrification and denitrification is improved, ammonia nitrogen is quickly and effectively removed, the stable and standard effluent quality is ensured by adopting a three-section combined treatment process, and the method has the advantages of investment saving, stable operation and high treatment efficiency.
Although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that various changes in the embodiments and/or modifications of the invention can be made, and equivalents and modifications of some features of the invention can be made without departing from the spirit and scope of the invention.

Claims (10)

1. A method for treating aquaculture industrial wastewater, the method comprising:
discharging the wastewater into a pretreatment system consisting of an oil separation tank, an air flotation tank and an adjusting tank to remove grease and suspended matters in the wastewater, wherein steam of a cooking boiler is introduced into the oil separation tank to ensure that the wastewater in the oil separation tank keeps the temperature within a preset temperature range;
discharging the wastewater treated by the pretreatment system into an anaerobic tank-A2A biochemical treatment system consisting of an O reaction tank, organic matter removal, ammonia nitrogen removal by nitrification and biochemical phosphorus removal, wastewater discharge into a vertical flow type secondary sedimentation tank for mud-water separation, monitoring A2The ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank is according to A2Adjusting the temperature of the wastewater in the oil separation tank by the ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank so as to improve the efficiency of shortcut nitrification and denitrification;
and (3) enabling the supernatant of the vertical flow type secondary sedimentation tank to flow into an inclined tube sedimentation tank, and carrying out advanced treatment on the wastewater by adopting a dephosphorization agent.
2. The aquaculture industrial wastewater treatment process according to claim 1, characterized in that according to A2Adjusting the wastewater temperature in the oil separation tank by the ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank: setting an initial temperature, detecting A2Repeatedly increasing the initial temperature and detecting the ammonia nitrogen in the wastewater at the water outlet end of the/O reaction tankAnd a concentration step until the ammonia nitrogen concentration is continuously greater than the initial ammonia nitrogen concentration so as to obtain the wastewater temperature in the oil separation tank.
3. The method for treating aquaculture industrial wastewater according to claim 1 or 3, characterized in that according to A2Adjusting the temperature of the wastewater in the oil separation tank by the ammonia nitrogen concentration in the wastewater at the water outlet end of the O reaction tank: setting an initial temperature, detecting A2And (3) repeatedly reducing the initial ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank and detecting the ammonia nitrogen concentration in the wastewater at the water outlet end until the ammonia nitrogen concentration is continuously less than the initial ammonia nitrogen concentration so as to obtain the temperature of the wastewater in the oil separation tank.
4. The aquaculture industrial wastewater treatment method according to claim 1, characterized in that: monitoring A2When the ammonia nitrogen concentration in the wastewater at the water inlet end of the/O reaction tank is gradually increased, the ammonia nitrogen concentration is gradually increased for the A2And (3) carrying out ammonia nitrogen resistant culture on nitrifying bacteria in the/O reaction tank.
5. The method for treating aquatic industrial wastewater according to claim 1 or 4, wherein: monitoring A2Phosphate concentration in wastewater at the water inlet end of the/O reaction tank, when the phosphate concentration gradient is increased, for A2And (3) carrying out salt-tolerant culture on nitrifying bacteria in the/O reaction tank.
6. The aquaculture industrial wastewater treatment method according to claim 1, characterized in that: lime and/or coagulant are added to carry out advanced treatment on the wastewater.
7. An aquatic product industry effluent disposal system which characterized in that: comprises an oil separation tank, an air flotation tank, an adjusting tank, an anaerobic tank and a tank A which are connected in sequence through pipelines2The treatment system comprises a/O reaction tank, a vertical flow type secondary sedimentation tank, an inclined tube sedimentation tank, a controller, a steam pipeline for introducing steam of a cooking boiler, and a water inlet pipe, wherein the oil separation tank is internally provided with a steam pipeline for introducing steam of the cooking boiler, and the water inlet pipe is connected with the controller2The water outlet end of the/O reaction tank is provided with an effluent ammonia nitrogen online detector for monitoring the ammonia nitrogen concentration in the wastewater at the water outlet endThe controller is in signal connection with the effluent ammonia nitrogen online detector according to A2And adjusting the temperature of the wastewater in the oil separation tank by the ammonia nitrogen concentration in the wastewater at the water outlet end of the/O reaction tank.
8. The aquaculture industrial wastewater treatment system of claim 7, wherein: a is described2The water inlet end of the/O reaction tank is provided with an inlet ammonia nitrogen online detector for monitoring the ammonia nitrogen concentration in the waste water at the water inlet end, the controller is further in signal connection with the inlet ammonia nitrogen online detector, and when the outlet ammonia nitrogen online detector detects that the ammonia nitrogen concentration is gradually increased, the controller is used for controlling the ammonia nitrogen concentration in the waste water at the water inlet end to be gradually increased2And (3) carrying out ammonia nitrogen resistant culture on nitrifying bacteria in the/O reaction tank.
9. The aquaculture industrial wastewater treatment system of claim 7 or 8, wherein: a is described2The water inlet end of the/O reaction tank is provided with an online detector for monitoring the concentration of phosphate in wastewater at the water inlet end, the controller is further in signal connection with the online detector, and when the online detector detects that the concentration gradient of the phosphate is increased, the controller is used for controlling the concentration of the phosphate in the wastewater at the water inlet end to be A2And (3) carrying out salt-tolerant culture on nitrifying bacteria in the/O reaction tank.
10. The aquaculture industrial wastewater treatment system of claim 7, wherein: a is described2the/O reaction tank is provided with an online DO instrument for controlling the aeration quantity.
CN202210381957.XA 2022-04-12 2022-04-12 Aquatic industrial wastewater treatment method and treatment system thereof Pending CN114702204A (en)

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