CN114700654A - Ceramic particle welding wire for roller surface of roller press and preparation method thereof - Google Patents
Ceramic particle welding wire for roller surface of roller press and preparation method thereof Download PDFInfo
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- CN114700654A CN114700654A CN202210420065.6A CN202210420065A CN114700654A CN 114700654 A CN114700654 A CN 114700654A CN 202210420065 A CN202210420065 A CN 202210420065A CN 114700654 A CN114700654 A CN 114700654A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 204
- 238000003466 welding Methods 0.000 title claims abstract description 167
- 239000002245 particle Substances 0.000 title claims abstract description 121
- 238000002360 preparation method Methods 0.000 title claims abstract description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 88
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 71
- 238000002844 melting Methods 0.000 claims abstract description 63
- 230000008018 melting Effects 0.000 claims abstract description 63
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims abstract description 55
- 229910000423 chromium oxide Inorganic materials 0.000 claims abstract description 55
- UNASZPQZIFZUSI-UHFFFAOYSA-N methylidyneniobium Chemical compound [Nb]#C UNASZPQZIFZUSI-UHFFFAOYSA-N 0.000 claims abstract description 55
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 55
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 55
- 238000005266 casting Methods 0.000 claims abstract description 40
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 31
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910033181 TiB2 Inorganic materials 0.000 claims abstract description 30
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 20
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 20
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000001125 extrusion Methods 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims description 70
- 239000007788 liquid Substances 0.000 claims description 52
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 44
- -1 aluminum oxide Chemical compound 0.000 claims description 43
- 238000001035 drying Methods 0.000 claims description 39
- 239000000463 material Substances 0.000 claims description 17
- 239000003973 paint Substances 0.000 claims description 17
- 238000011049 filling Methods 0.000 claims description 15
- 239000007789 gas Substances 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 13
- 239000011261 inert gas Substances 0.000 claims description 13
- 238000002156 mixing Methods 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 238000005491 wire drawing Methods 0.000 claims description 13
- 238000005260 corrosion Methods 0.000 abstract description 9
- 230000007797 corrosion Effects 0.000 abstract description 9
- 229910052751 metal Inorganic materials 0.000 abstract description 8
- 239000002184 metal Substances 0.000 abstract description 8
- 238000005096 rolling process Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000005299 abrasion Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000004901 spalling Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/3601—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with inorganic compounds as principal constituents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/362—Selection of compositions of fluxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/40—Making wire or rods for soldering or welding
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Nonmetallic Welding Materials (AREA)
- Powder Metallurgy (AREA)
Abstract
The invention discloses a ceramic particle welding wire for a roller surface of a roller press and a preparation method thereof, belonging to the technical field of welding wires. The ceramic particle welding wire comprises the following components in parts by weight: niobium carbide: 15-35 parts of ceramic component: 150-170 parts of alumina: 10-20 parts of silicon carbide: 10-20 parts of iron powder: 180-250 parts of chromium oxide: 50-80 parts; the ceramic comprises the following components in parts by weight: titanium diboride: 20-40 parts of silicon oxide: 10-20 parts of silicon dioxide: 50-80 parts; which comprises the following steps: (1) pre-treating; (2) surfacing treatment; (3) carrying out melting treatment; (4) processing a casting blank; (5) and (4) extrusion molding. The impact toughness and the corrosion resistance of the metal-based ceramic particle welding wire can be improved.
Description
Technical Field
The invention belongs to the technical field of welding wires, and particularly relates to a ceramic particle welding wire for a roller surface of a roller press and a preparation method thereof.
Background
At present, abrasion, corrosion and fracture are three modes of failure of metal materials, and the economic loss caused by abrasion is the most serious. For example, ceramic rolls, which are grinding members of vertical roller mills, have considerable wear resistance and are widely used in cement production and thermal power plants for the production of raw materials, coal, and clinker. However, some ceramic rollers fail prematurely due to the presence of irregular material or excessive wear, resulting in surface spalling and cracking, resulting in breakage of portions of critical areas before the end of life expectancy, resulting in reduced productivity and even downtime. The existing solution is to order imported new ceramic rolls for replacement, but the lead time plus installation down time takes 3-6 months. Therefore, to avoid the huge economic losses associated with downtime, it is imperative that the weld overlay repair be performed before the new roll arrives. The wear-resistant surfacing welding is an economic and rapid process method for modifying the surface of a material, can effectively change the wear resistance, corrosion resistance and other mechanical properties of the surface of the material, has obvious effects of prolonging the service life of parts, reasonably using the material, improving the product performance and reducing the cost, and is more and more widely applied to the manufacturing and repairing of mechanical parts. Especially for the work piece that high abrasion resistance, high temperature corrosion resistance nature environment required under extreme operating mode, especially important. The more commonly used flux-cored wires E501T-1(E71T-1) all belong to titanium flux-cored wires, and the powder of the flux-cored wires is mainly acidic oxides and reaches the balance of oxidation and reduction with deoxidizers in the powder in molten pool reaction. The ceramic liner is mainly composed of silicon dioxide and aluminum oxide. When the ceramic liner is used together with a flux-cored wire, electric arcs directly act on the ceramic liner during first backing welding, and silicon dioxide and aluminum oxide in the ceramic liner enter a molten pool to react, so that oxides in the molten pool are increased, the balance of redox reaction is broken, and inclusions in deposited metal are increased. The plasticity and the toughness of the welding seam are reduced, and the crack tendency is increased.
Disclosure of Invention
Problems to be solved
Aiming at the problems in the prior art, the invention provides the ceramic particle welding wire for the roller surface of the roller press and the preparation method thereof, which effectively improve the impact toughness and the corrosion resistance of the metal-based ceramic particle welding wire.
Technical scheme
In order to solve the above problems, the present invention adopts the following technical solutions.
A ceramic particle welding wire for the roller surface of a roller press,
the paint comprises the following components in parts by weight:
15 to 35 parts of niobium carbide,
150 to 170 parts of ceramic components,
10 to 20 parts of aluminum oxide,
10 to 20 parts of silicon carbide,
180 to 250 portions of iron powder,
50-80 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
20 to 40 portions of titanium diboride,
10 to 20 parts of silicon oxide, and the like,
50-80 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the paint comprises the following components in parts by weight:
20 to 30 parts of niobium carbide,
160 to 170 portions of ceramic components,
13 to 20 parts of aluminum oxide,
10 to 18 parts of silicon carbide,
190-220 parts of iron powder,
60-70 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
25 to 40 parts of titanium diboride,
10 to 20 parts of silicon oxide, and the like,
60-80 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the paint comprises the following components in parts by weight:
25 parts of niobium carbide, namely 25 parts of niobium carbide,
165 parts of a ceramic component, namely a ceramic,
17 parts of aluminum oxide, namely aluminum oxide,
14 parts of silicon carbide, namely 14 parts of silicon carbide,
200 parts of iron powder, namely 200 parts of iron powder,
65 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
32 parts of titanium diboride, namely titanium diboride,
15 parts of silicon oxide, namely silicon oxide,
and 70 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the iron powder is reduced iron powder;
the purity of the iron powder is 99%.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the average grain diameter of the chromium oxide is 200um-400 um.
A preparation method of a ceramic particle welding wire for the roller surface of a roller press comprises the following steps:
(1) pretreatment: preparing niobium carbide, ceramic components, aluminum oxide, silicon carbide, iron powder and chromium oxide, and then drying at high temperature for later use;
(2) surfacing treatment: overlaying the ceramic component and the alumina by adopting an arc welding method to obtain an overlaying object;
(3) melting treatment: carrying out electric melting on niobium carbide, silicon carbide, iron powder and chromium oxide to obtain an electric molten liquid;
(4) casting blank treatment: electromagnetically mixing the surfacing material obtained in the step (2) with the electric melting liquid obtained in the step (3), placing the mixture in a crucible for melting at 2500 ℃ to obtain a mixed liquid, transferring the mixed liquid into a mold, and cooling to obtain a casting blank;
(5) extrusion molding: and (5) transferring the casting blank obtained in the step (4) into an extruder, and performing wire drawing treatment.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature for high-temperature drying in the step (1) is 200 ℃.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
and (2) filling inert gas in the high-temperature drying environment in the step (1).
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the arc welding parameters in the step (2) are as follows: welding current 200A, arc voltage 15V and gas flow 20L/min.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature of electric melting in the step (3) is 1780 ℃.
Advantageous effects
Compared with the prior art, the invention has the beneficial effects that:
the ceramic particle welding wire prepared by the method has good comprehensive performance, and the results of examples 1 to 5 show that the impact toughness and the corrosion resistance of the metal-based ceramic particle welding wire can be effectively improved, wherein the range of the impact toughness at the temperature of 20 ℃ below zero is 162J to 175J, and the corrosion resistance index is in a higher grade. Specifically, the niobium carbide, the silicon oxide, the silicon carbide, the chromium oxide, the iron powder and the titanium diboride are creatively arranged, the filling rate of the welding wire is increased, the percentage content of ceramic particles is increased, and the problem of low abrasion resistance of deposited metal is solved.
Detailed Description
The invention is further described with reference to specific examples.
Example 1
The ceramic particle welding wire for the roll surface of the rolling machine of the embodiment,
the paint comprises the following components in parts by weight:
15 parts of niobium carbide, namely, niobium carbide,
170 parts of a ceramic component, namely ceramic,
10 parts of aluminum oxide, namely aluminum oxide,
20 parts of silicon carbide, namely 20 parts of silicon carbide,
180 parts of iron powder,
80 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
20 parts of titanium diboride, namely titanium diboride,
20 parts of silicon oxide, namely silicon oxide,
and 50 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the iron powder is reduced iron powder;
the purity of the iron powder is 99%.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the average grain diameter of the chromium oxide is 200 um.
The preparation method of the ceramic particle welding wire for the roller surface of the roller press comprises the following steps:
(1) pretreatment: preparing niobium carbide, ceramic components, aluminum oxide, silicon carbide, iron powder and chromium oxide, and then drying at high temperature for later use;
(2) surfacing treatment: overlaying the ceramic component and the alumina by adopting an arc welding method to obtain an overlaying object;
(3) melting treatment: carrying out electric melting on niobium carbide, silicon carbide, iron powder and chromium oxide to obtain an electric molten liquid;
(4) casting blank treatment: electromagnetically mixing the surfacing material obtained in the step (2) with the electric melting liquid obtained in the step (3), placing the mixture in a crucible for melting at 2500 ℃ to obtain a mixed liquid, transferring the mixed liquid into a mold, and cooling to obtain a casting blank;
(5) extrusion molding: and (5) transferring the casting blank obtained in the step (4) into an extruder, and performing wire drawing treatment.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature for high-temperature drying in the step (1) is 200 ℃.
In the above-mentioned method for manufacturing a ceramic particle welding wire for a roll surface of a roll squeezer,
and (2) filling inert gas in the high-temperature drying environment in the step (1).
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the arc welding parameters in the step (2) are as follows: welding current 200A, arc voltage 15V and gas flow 20L/min.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature of electric melting in the step (3) is 1780 ℃.
Example 2
The ceramic particle welding wire for the roller surface of the roller press of the embodiment,
the paint comprises the following components in parts by weight:
35 parts of niobium carbide, namely, niobium carbide,
150 parts of a ceramic component, namely a ceramic,
20 parts of aluminum oxide, namely aluminum oxide,
10 parts of silicon carbide, namely silicon carbide,
250 parts of iron powder, namely iron powder,
50 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
40 parts of titanium diboride, namely titanium diboride,
10 parts of silicon oxide, namely silicon oxide,
and 80 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the iron powder is reduced iron powder;
the purity of the iron powder is 99%.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the average grain diameter of the chromium oxide is 200 um.
The preparation method of the ceramic particle welding wire for the roller surface of the roller press comprises the following steps:
(1) pretreatment: preparing niobium carbide, ceramic components, aluminum oxide, silicon carbide, iron powder and chromium oxide, and then drying at high temperature for later use;
(2) surfacing treatment: overlaying the ceramic component and the alumina by adopting an arc welding method to obtain an overlaying object;
(3) melting treatment: carrying out electric melting on niobium carbide, silicon carbide, iron powder and chromium oxide to obtain an electric molten liquid;
(4) casting blank treatment: electromagnetically mixing the surfacing material obtained in the step (2) with the electric melting liquid obtained in the step (3), placing the mixture in a crucible to melt at 2500 ℃ to obtain a mixed liquid, transferring the mixed liquid into a mold, and cooling to obtain a casting blank;
(5) extrusion molding: and (5) transferring the casting blank obtained in the step (4) into an extruder, and performing wire drawing treatment.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature for high-temperature drying in the step (1) is 200 ℃.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
and (2) filling inert gas in the high-temperature drying environment in the step (1).
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the arc welding parameters in the step (2) are as follows: welding current 200A, arc voltage 15V and gas flow 20L/min.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature of electric melting in the step (3) is 1780 ℃.
Example 3
The ceramic particle welding wire for the roll surface of the rolling machine of the embodiment,
the paint comprises the following components in parts by weight:
20 parts of niobium carbide, namely 20 parts of niobium carbide,
170 parts of a ceramic component, namely ceramic,
13 parts of aluminum oxide, namely aluminum oxide,
18 parts of silicon carbide, namely 18 parts of silicon carbide,
190 parts of iron powder,
70 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
25 parts of titanium diboride,
20 parts of silicon oxide, namely silicon oxide,
and 60 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the iron powder is reduced iron powder;
the purity of the iron powder is 99%.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the average grain diameter of the chromium oxide is 400 um.
The preparation method of the ceramic particle welding wire for the roller surface of the roller press comprises the following steps:
(1) pretreatment: preparing niobium carbide, ceramic components, aluminum oxide, silicon carbide, iron powder and chromium oxide, and then drying at high temperature for later use;
(2) surfacing treatment: overlaying the ceramic component and the alumina by adopting an arc welding method to obtain an overlaying object;
(3) melting treatment: carrying out electric melting on niobium carbide, silicon carbide, iron powder and chromium oxide to obtain an electric molten liquid;
(4) casting blank treatment: electromagnetically mixing the surfacing material obtained in the step (2) with the electric melting liquid obtained in the step (3), placing the mixture in a crucible for melting at 2500 ℃ to obtain a mixed liquid, transferring the mixed liquid into a mold, and cooling to obtain a casting blank;
(5) extrusion molding: and (5) transferring the casting blank obtained in the step (4) into an extruder, and performing wire drawing treatment.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature for high-temperature drying in the step (1) is 200 ℃.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
and (2) filling inert gas in the high-temperature drying environment in the step (1).
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the arc welding parameters in the step (2) are as follows: welding current 200A, arc voltage 15V and gas flow 20L/min.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature of electric melting in the step (3) is 1780 ℃.
Example 4
The ceramic particle welding wire for the roll surface of the rolling machine of the embodiment,
the paint comprises the following components in parts by weight:
30 parts of niobium carbide, namely 30 parts of niobium carbide,
160 parts of a ceramic component, namely,
13 parts of aluminum oxide, namely aluminum oxide,
10 parts of silicon carbide, namely 10 parts of silicon carbide,
220 parts of iron powder, namely iron powder,
60 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
40 parts of titanium diboride, namely titanium diboride,
10 parts of silicon oxide, namely silicon oxide,
and 80 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the iron powder is reduced iron powder;
the purity of the iron powder is 99%.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the average grain diameter of the chromium oxide is 400 um.
The preparation method of the ceramic particle welding wire for the roller surface of the roller press comprises the following steps:
(1) pretreatment: preparing niobium carbide, ceramic components, aluminum oxide, silicon carbide, iron powder and chromium oxide, and then drying at high temperature for later use;
(2) surfacing treatment: overlaying the ceramic component and the alumina by adopting an arc welding method to obtain an overlaying object;
(3) melting treatment: carrying out electric melting on niobium carbide, silicon carbide, iron powder and chromium oxide to obtain an electric molten liquid;
(4) casting blank treatment: electromagnetically mixing the surfacing material obtained in the step (2) with the electric melting liquid obtained in the step (3), placing the mixture in a crucible for melting at 2500 ℃ to obtain a mixed liquid, transferring the mixed liquid into a mold, and cooling to obtain a casting blank;
(5) extrusion molding: and (5) transferring the casting blank obtained in the step (4) into an extruder, and performing wire drawing treatment.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature for high-temperature drying in the step (1) is 200 ℃.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
and (2) filling inert gas in the high-temperature drying environment in the step (1).
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the arc welding parameters in the step (2) are as follows: welding current 200A, arc voltage 15V and gas flow 20L/min.
In the above-mentioned method for manufacturing a ceramic particle welding wire for a roll surface of a roll squeezer,
the temperature of electric melting in the step (3) is 1780 ℃.
Example 5
The ceramic particle welding wire for the roll surface of the rolling machine of the embodiment,
the paint comprises the following components in parts by weight:
25 parts of niobium carbide, namely 25 parts of niobium carbide,
165 parts of a ceramic component, namely a ceramic,
17 parts of aluminum oxide, namely aluminum oxide,
14 parts of silicon carbide, namely 14 parts of silicon carbide,
200 parts of iron powder, namely 200 parts of iron powder,
65 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
32 parts of titanium diboride, namely titanium diboride,
15 parts of silicon oxide, namely silicon oxide,
and 70 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the iron powder is reduced iron powder;
the purity of the iron powder is 99%.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the average grain diameter of the chromium oxide is 300 um.
The preparation method of the ceramic particle welding wire for the roller surface of the roller press comprises the following steps:
(1) pretreatment: preparing niobium carbide, ceramic components, aluminum oxide, silicon carbide, iron powder and chromium oxide, and then drying at high temperature for later use;
(2) surfacing treatment: overlaying the ceramic component and the alumina by adopting an arc welding method to obtain an overlaying object;
(3) melting treatment: carrying out electric melting on niobium carbide, silicon carbide, iron powder and chromium oxide to obtain an electric molten liquid;
(4) casting blank treatment: electromagnetically mixing the surfacing material obtained in the step (2) with the electric melting liquid obtained in the step (3), placing the mixture in a crucible for melting at 2500 ℃ to obtain a mixed liquid, transferring the mixed liquid into a mold, and cooling to obtain a casting blank;
(5) extrusion molding: and (5) transferring the casting blank obtained in the step (4) into an extruder, and performing wire drawing treatment.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature for high-temperature drying in the step (1) is 200 ℃.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
and (2) filling inert gas in the high-temperature drying environment in the step (1).
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the arc welding parameters in the step (2) are as follows: welding current 200A, arc voltage 15V and gas flow 20L/min.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature of electric melting in the step (3) is 1780 ℃.
Comparative example 1
The ceramic particle welding wire for the roll surface of the rolling machine of the embodiment,
the paint comprises the following components in parts by weight:
165 parts of a ceramic component, namely a ceramic,
17 parts of aluminum oxide, namely aluminum oxide,
14 parts of silicon carbide, namely, silicon carbide,
200 parts of iron powder, namely 200 parts of iron powder,
65 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
32 parts of titanium diboride, namely titanium diboride,
15 parts of silicon oxide, namely silicon oxide,
and 70 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the iron powder is reduced iron powder;
the purity of the iron powder is 99%.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the average grain diameter of the chromium oxide is 300 um.
The preparation method of the ceramic particle welding wire for the roller surface of the roller press comprises the following steps:
(1) pretreatment: preparing ceramic components, aluminum oxide, silicon carbide, iron powder and chromium oxide, and then drying at high temperature for later use;
(2) surfacing treatment: overlaying the ceramic component and the alumina by adopting an arc welding method to obtain an overlaying object;
(3) melting treatment: carrying out electric melting on silicon carbide, iron powder and chromium oxide to obtain an electric molten liquid;
(4) casting blank treatment: electromagnetically mixing the surfacing material obtained in the step (2) with the electric melting liquid obtained in the step (3), placing the mixture in a crucible for melting at 2500 ℃ to obtain a mixed liquid, transferring the mixed liquid into a mold, and cooling to obtain a casting blank;
(5) extrusion molding: and (5) transferring the casting blank obtained in the step (4) into an extruder, and performing wire drawing treatment.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature for high-temperature drying in the step (1) is 200 ℃.
In the above-mentioned method for manufacturing a ceramic particle welding wire for a roll surface of a roll squeezer,
and (2) filling inert gas in the high-temperature drying environment in the step (1).
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the arc welding parameters in the step (2) are as follows: welding current 200A, arc voltage 15V and gas flow 20L/min.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature of electric melting in the step (3) is 1780 ℃.
Comparative example 2
The ceramic particle welding wire for the roll surface of the rolling machine of the embodiment,
the paint comprises the following components in parts by weight:
25 parts of niobium carbide, namely 25 parts of niobium carbide,
165 parts of a ceramic component, namely a ceramic,
17 parts of aluminum oxide, namely aluminum oxide,
14 parts of silicon carbide, namely 14 parts of silicon carbide,
200 parts of iron powder, namely 200 parts of iron powder,
65 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
32 parts of titanium diboride, namely titanium diboride,
70 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the iron powder is reduced iron powder;
the purity of the iron powder is 99%.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the average grain diameter of the chromium oxide is 300 um.
The preparation method of the ceramic particle welding wire for the roller surface of the roller press comprises the following steps:
(1) pretreatment: preparing niobium carbide, ceramic components, aluminum oxide, silicon carbide, iron powder and chromium oxide, and then drying at high temperature for later use;
(2) surfacing treatment: overlaying the ceramic component and the alumina by adopting an arc welding method to obtain an overlaying object;
(3) melting treatment: carrying out electric melting on niobium carbide, silicon carbide, iron powder and chromium oxide to obtain an electric molten liquid;
(4) casting blank treatment: electromagnetically mixing the surfacing material obtained in the step (2) with the electric melting liquid obtained in the step (3), placing the mixture in a crucible for melting at 2500 ℃ to obtain a mixed liquid, transferring the mixed liquid into a mold, and cooling to obtain a casting blank;
(5) extrusion molding: and (5) transferring the casting blank obtained in the step (4) into an extruder, and performing wire drawing treatment.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature for high-temperature drying in the step (1) is 200 ℃.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
and (2) filling inert gas in the high-temperature drying environment in the step (1).
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the arc welding parameters in the step (2) are as follows: welding current 200A, arc voltage 15V and gas flow 20L/min.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature of electric melting in the step (3) is 1780 ℃.
Comparative example 3
The ceramic particle welding wire for the roller surface of the roller press of the embodiment,
the paint comprises the following components in parts by weight:
25 parts of niobium carbide, namely 25 parts of niobium carbide,
165 parts of a ceramic component, namely a ceramic,
17 parts of aluminum oxide, namely aluminum oxide,
200 parts of iron powder, namely 200 parts of iron powder,
65 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
32 parts of titanium diboride, namely titanium diboride,
15 parts of silicon oxide, namely silicon oxide,
70 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the iron powder is reduced iron powder;
the purity of the iron powder is 99%.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the average grain diameter of the chromium oxide is 300 um.
The preparation method of the ceramic particle welding wire for the roller surface of the roller press comprises the following steps:
(1) pretreatment: preparing niobium carbide, ceramic components, aluminum oxide, iron powder and chromium oxide, and then drying at high temperature for later use;
(2) surfacing treatment: overlaying the ceramic component and the alumina by adopting an arc welding method to obtain an overlaying object;
(3) melting treatment: carrying out electric melting on niobium carbide, iron powder and chromium oxide to obtain an electric molten liquid;
(4) casting blank treatment: electromagnetically mixing the surfacing material obtained in the step (2) with the electric melting liquid obtained in the step (3), placing the mixture in a crucible to melt at 2500 ℃ to obtain a mixed liquid, transferring the mixed liquid into a mold, and cooling to obtain a casting blank;
(5) extrusion molding: and (5) transferring the casting blank obtained in the step (4) into an extruder, and performing wire drawing treatment.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature for high-temperature drying in the step (1) is 200 ℃.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
and (2) filling inert gas in the high-temperature drying environment in the step (1).
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the arc welding parameters in the step (2) are as follows: welding current 200A, arc voltage 15V and gas flow 20L/min.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature of electric melting in the step (3) is 1780 ℃.
Comparative example 4
The ceramic particle welding wire for the roller surface of the roller press of the embodiment,
the paint comprises the following components in parts by weight:
25 parts of niobium carbide, namely 25 parts of niobium carbide,
165 parts of a ceramic component, namely a ceramic,
17 parts of aluminum oxide, namely, aluminum oxide,
14 parts of silicon carbide, namely 14 parts of silicon carbide,
200 parts of iron powder;
the ceramic comprises the following components in parts by weight:
32 parts of titanium diboride, namely titanium diboride,
15 parts of silicon oxide, namely silicon oxide,
and 70 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the iron powder is reduced iron powder;
the purity of the iron powder is 99%.
The preparation method of the ceramic particle welding wire for the roller surface of the roller press comprises the following steps:
(1) pretreatment: preparing niobium carbide, ceramic components, aluminum oxide, silicon carbide and iron powder, and then drying at high temperature for later use;
(2) surfacing treatment: overlaying the ceramic component and the alumina by adopting an arc welding method to obtain an overlaying object;
(3) melting treatment: carrying out electric melting on niobium carbide, silicon carbide and iron powder to obtain an electric molten liquid;
(4) casting blank treatment: electromagnetically mixing the surfacing material obtained in the step (2) with the electric melting liquid obtained in the step (3), placing the mixture in a crucible to melt at 2500 ℃ to obtain a mixed liquid, transferring the mixed liquid into a mold, and cooling to obtain a casting blank;
(5) extrusion molding: and (5) transferring the casting blank obtained in the step (4) into an extruder, and performing wire drawing treatment.
In the above-mentioned method for manufacturing a ceramic particle welding wire for a roll surface of a roll squeezer,
the temperature for high-temperature drying in the step (1) is 200 ℃.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
and (2) filling inert gas in the high-temperature drying environment in the step (1).
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the arc welding parameters in the step (2) are as follows: welding current 200A, arc voltage 15V and gas flow 20L/min.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature of electric melting in the step (3) is 1780 ℃.
Comparative example 5
The ceramic particle welding wire for the roll surface of the rolling machine of the embodiment,
the paint comprises the following components in parts by weight:
25 parts of niobium carbide, namely 25 parts of niobium carbide,
165 parts of a ceramic component, namely a ceramic,
17 parts of aluminum oxide, namely aluminum oxide,
14 parts of silicon carbide, namely, silicon carbide,
65 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
32 parts of titanium diboride, namely titanium diboride,
15 parts of silicon oxide, namely silicon oxide,
and 70 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the average grain diameter of the chromium oxide is 300 um.
The preparation method of the ceramic particle welding wire for the roller surface of the roller press comprises the following steps:
(1) pretreatment: preparing niobium carbide, ceramic components, aluminum oxide, silicon carbide and chromium oxide, and then drying at high temperature for later use;
(2) surfacing treatment: overlaying the ceramic component and the alumina by adopting an arc welding method to obtain an overlaying object;
(3) melting treatment: carrying out electric melting on niobium carbide, silicon carbide and chromium oxide to obtain an electric molten liquid;
(4) casting blank treatment: electromagnetically mixing the surfacing material obtained in the step (2) with the electric melting liquid obtained in the step (3), placing the mixture in a crucible for melting at 2500 ℃ to obtain a mixed liquid, transferring the mixed liquid into a mold, and cooling to obtain a casting blank;
(5) extrusion molding: and (5) transferring the casting blank obtained in the step (4) into an extruder, and performing wire drawing treatment.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature for high-temperature drying in the step (1) is 200 ℃.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
and (2) filling inert gas in the high-temperature drying environment in the step (1).
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the arc welding parameters in the step (2) are as follows: welding current 200A, arc voltage 15V and gas flow 20L/min.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature of electric melting in the step (3) is 1780 ℃.
Comparative example 6
The ceramic particle welding wire for the roll surface of the rolling machine of the embodiment,
the paint comprises the following components in parts by weight:
25 parts of niobium carbide, namely 25 parts of niobium carbide,
165 parts of a ceramic component, namely ceramic,
17 parts of aluminum oxide, namely aluminum oxide,
14 parts of silicon carbide, namely 14 parts of silicon carbide,
200 parts of iron powder, namely 200 parts of iron powder,
65 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
15 parts of silicon oxide, namely silicon oxide,
and 70 parts of silicon dioxide.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the iron powder is reduced iron powder;
the purity of the iron powder is 99%.
In the ceramic particle welding wire for the roll surface of the roll squeezer,
the average grain diameter of the chromium oxide is 300 um.
The preparation method of the ceramic particle welding wire for the roller surface of the roller press comprises the following steps:
(1) pretreatment: preparing niobium carbide, ceramic components, aluminum oxide, silicon carbide, iron powder and chromium oxide, and then drying at high temperature for later use;
(2) surfacing treatment: overlaying the ceramic component and the alumina by adopting an arc welding method to obtain an overlaying object;
(3) melting treatment: carrying out electric melting on niobium carbide, silicon carbide, iron powder and chromium oxide to obtain an electric molten liquid;
(4) casting blank treatment: electromagnetically mixing the surfacing material obtained in the step (2) with the electric melting liquid obtained in the step (3), placing the mixture in a crucible for melting at 2500 ℃ to obtain a mixed liquid, transferring the mixed liquid into a mold, and cooling to obtain a casting blank;
(5) extrusion molding: and (5) transferring the casting blank obtained in the step (4) into an extruder, and performing wire drawing treatment.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature for high-temperature drying in the step (1) is 200 ℃.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
and (2) filling inert gas in the high-temperature drying environment in the step (1).
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the arc welding parameters in the step (2) are as follows: welding current 200A, arc voltage 15V and gas flow 20L/min.
In the above-mentioned method for preparing ceramic particle welding wire for roller surface of roller press,
the temperature of electric melting in the step (3) is 1780 ℃.
Example 6
The ceramic particle welding wires prepared in examples 1 to 5 and comparative examples 1 to 6 were subjected to the test:
reference test method- (1) chinese invention patent, application No.: CN201210479528.2, publication No.: CN102941422A, discloses a gas shielded flux-cored wire used in cooperation with a ceramic liner;
(2) chinese invention patent, application number: CN202110696194.3, publication No.: CN113319463A discloses a metal-based ceramic particle welding wire and a preparation process thereof.
The prepared welding wire is tested, and the test results are as follows:
TABLE 1
As can be seen from Table 1, the ceramic particle welding wire prepared by the method has good comprehensive properties, and the results of examples 1 to 5 show that the impact toughness and the corrosion resistance of the metal-based ceramic particle welding wire can be effectively improved, wherein the impact toughness at 20 ℃ below zero is in the range of 162J to 175J, and the corrosion resistance index is in a higher grade. Specifically, the niobium carbide, the silicon oxide, the silicon carbide, the chromium oxide, the iron powder and the titanium diboride are creatively arranged, the filling rate of the welding wire is increased, the percentage content of ceramic particles is increased, and the problem of low abrasion resistance of deposited metal is solved.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.
Claims (10)
1. A ceramic particle welding wire for the roll surface of a roll squeezer is characterized in that:
the paint comprises the following components in parts by weight:
15 to 35 parts of niobium carbide,
150 to 170 parts of ceramic components,
10 to 20 portions of alumina, and the balance,
10 to 20 parts of silicon carbide,
180 to 250 portions of iron powder,
50-80 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
20 to 40 portions of titanium diboride,
10 to 20 parts of silicon oxide, and the like,
50-80 parts of silicon dioxide.
2. The ceramic particle welding wire for roll surfaces of a roll squeezer according to claim 1, wherein:
the paint comprises the following components in parts by weight:
20 to 30 parts of niobium carbide,
160-170 parts of ceramic components,
13 to 20 parts of aluminum oxide,
10 to 18 parts of silicon carbide,
190-220 parts of iron powder,
60-70 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
25 to 40 portions of titanium diboride,
10 to 20 parts of silicon oxide, and the like,
60-80 parts of silicon dioxide.
3. The ceramic particle welding wire for roll surfaces of a roll squeezer according to claim 2, wherein:
the paint comprises the following components in parts by weight:
25 parts of niobium carbide, namely 25 parts of niobium carbide,
165 parts of a ceramic component, namely a ceramic,
17 parts of aluminum oxide, namely aluminum oxide,
14 parts of silicon oxide, namely silicon oxide,
200 parts of iron powder, namely 200 parts of iron powder,
65 parts of chromium oxide;
the ceramic comprises the following components in parts by weight:
32 parts of titanium diboride, namely titanium diboride,
15 parts of silicon carbide, namely 15 parts of silicon carbide,
and 70 parts of silicon dioxide.
4. The ceramic particle welding wire for roll surfaces of a roll squeezer according to claim 3, wherein:
the iron powder is reduced iron powder;
the purity of the iron powder is 99%.
5. The ceramic particle welding wire for roll surfaces of a roll squeezer according to claim 3, wherein:
the average grain diameter of the chromium oxide is 200um-400 um.
6. A preparation method of a ceramic particle welding wire for a roller surface of a roller press is characterized by comprising the following steps of:
the method comprises the following steps:
(1) pretreatment: preparing niobium carbide, ceramic components, aluminum oxide, silicon carbide, iron powder and chromium oxide, and then drying at high temperature for later use;
(2) surfacing treatment: overlaying the ceramic component and the alumina by adopting an arc welding method to obtain an overlaying object;
(3) melting treatment: carrying out electric melting on niobium carbide, silicon carbide, iron powder and chromium oxide to obtain an electric molten liquid;
(4) casting blank treatment: electromagnetically mixing the surfacing material obtained in the step (2) with the electric melting liquid obtained in the step (3), placing the mixture in a crucible for melting at 2500 ℃ to obtain a mixed liquid, transferring the mixed liquid into a mold, and cooling to obtain a casting blank;
(5) extrusion molding: and (5) transferring the casting blank obtained in the step (4) into an extruder, and performing wire drawing treatment.
7. The method for preparing the ceramic granular welding wire for the roll surface of the roll squeezer according to claim 6, wherein:
the temperature for high-temperature drying in the step (1) is 200 ℃.
8. The method for preparing the ceramic particle welding wire for the roll surface of the roll squeezer according to claim 6, wherein:
and (2) filling inert gas in the high-temperature drying environment in the step (1).
9. The method for preparing the ceramic particle welding wire for the roll surface of the roll squeezer according to claim 6, wherein:
the arc welding parameters in the step (2) are as follows: welding current 200A, arc voltage 15V and gas flow 20L/min.
10. The method for preparing the ceramic particle welding wire for the roll surface of the roll squeezer according to claim 6, wherein:
the temperature of electric melting in the step (3) is 1780 ℃.
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KR101466559B1 (en) * | 2013-07-08 | 2014-12-01 | 한국생산기술연구원 | Flux cored wire for overlay welding |
CN104959747A (en) * | 2015-05-22 | 2015-10-07 | 宝志坚 | Metal ceramic welding wire and preparation method thereof |
CN109623195A (en) * | 2019-01-29 | 2019-04-16 | 江苏德龙镍业有限公司 | A kind of heat-resistant and wear-resistant cermet flux-cored wire |
CN111112875A (en) * | 2019-12-31 | 2020-05-08 | 上海交通大学 | Containing TiB2Granular aluminum alloy welding wire and preparation method thereof |
CN113319463A (en) * | 2021-06-23 | 2021-08-31 | 磐固合金(常州)有限公司 | Metal-based ceramic particle welding wire and preparation process thereof |
CN113953715A (en) * | 2021-11-26 | 2022-01-21 | 潍坊昌成耐磨材料有限公司 | Ceramic particle welding wire and preparation process thereof |
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2022
- 2022-04-21 CN CN202210420065.6A patent/CN114700654A/en active Pending
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Publication number | Priority date | Publication date | Assignee | Title |
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KR101466559B1 (en) * | 2013-07-08 | 2014-12-01 | 한국생산기술연구원 | Flux cored wire for overlay welding |
CN104959747A (en) * | 2015-05-22 | 2015-10-07 | 宝志坚 | Metal ceramic welding wire and preparation method thereof |
CN109623195A (en) * | 2019-01-29 | 2019-04-16 | 江苏德龙镍业有限公司 | A kind of heat-resistant and wear-resistant cermet flux-cored wire |
CN111112875A (en) * | 2019-12-31 | 2020-05-08 | 上海交通大学 | Containing TiB2Granular aluminum alloy welding wire and preparation method thereof |
CN113319463A (en) * | 2021-06-23 | 2021-08-31 | 磐固合金(常州)有限公司 | Metal-based ceramic particle welding wire and preparation process thereof |
CN113953715A (en) * | 2021-11-26 | 2022-01-21 | 潍坊昌成耐磨材料有限公司 | Ceramic particle welding wire and preparation process thereof |
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