CN114672277A - Dust catching glue for dust-free workshop and preparation method thereof - Google Patents

Dust catching glue for dust-free workshop and preparation method thereof Download PDF

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Publication number
CN114672277A
CN114672277A CN202210494987.1A CN202210494987A CN114672277A CN 114672277 A CN114672277 A CN 114672277A CN 202210494987 A CN202210494987 A CN 202210494987A CN 114672277 A CN114672277 A CN 114672277A
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CN
China
Prior art keywords
dust
free workshop
polyamide resin
vinyl acetate
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210494987.1A
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Chinese (zh)
Inventor
徐志明
吴冬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changzhou Yalong Electronic Science & Technology Co ltd
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Changzhou Yalong Electronic Science & Technology Co ltd
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Priority to CN202210494987.1A priority Critical patent/CN114672277A/en
Publication of CN114672277A publication Critical patent/CN114672277A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J177/00Adhesives based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J177/00Adhesives based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Adhesives based on derivatives of such polymers
    • C09J177/06Polyamides derived from polyamines and polycarboxylic acids
    • C09J177/08Polyamides derived from polyamines and polycarboxylic acids from polyamines and polymerised unsaturated fatty acids

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a dust catching glue for a dust-free workshop, which comprises the following raw materials in parts by weight: 61.5-62.0 parts of polyamide resin, 26.0-26.5 parts of ethylene-vinyl acetate copolymer, 11.0-11.5 parts of water-soluble polyethylene glycol wax, 0.2-0.4 part of filler and 0.1-0.3 part of tackifying resin. The invention also discloses a preparation method of the dust catching glue for the dust-free workshop, which comprises the following steps: the polyamide resin, the ethylene-vinyl acetate copolymer, the water-soluble polyethylene glycol wax, the filler and the tackifying resin are uniformly dispersed at a high speed after being mixed, so that the dust catching glue for the dust-free workshop is obtained. The dust catching adhesive for the dust-free workshop is a liquid adhesive, can be directly coated on the top of a blank ground of the dust-free workshop, a side wall of the blank ground or a dust-free equipment shell, and can also be coated on a plastic film and then adhered to the top of the blank ground of the dust-free workshop, the side wall of the blank ground or the dust-free equipment shell to continuously catch dust, so that the dust removing effect is achieved.

Description

Dust catching glue for dust-free workshop and preparation method thereof
Technical Field
The invention relates to the technical field of adhesives, in particular to a dust catching adhesive for a dust-free workshop and a preparation method thereof.
Background
With the development of precision machining and the requirements of precision manufacturing, more and more precision manufacturing is finished and produced in clean rooms of dust-free workshops, and certain dust particles are generated in certain machining processes and need to be removed on site to prevent pollution of the dust-free workshops. The existing on-site removing mode almost adopts a filtering retention type dust removing device to adsorb dust particles, the filtering retention type dust removing needs to install the adsorption device and arrange an air circulation pipeline in a dust-free workshop, meanwhile, the positive pressure and negative pressure design of the dust-free workshop is also considered, the effect of balance between production and dust removal is difficult to achieve, and meanwhile, the installation device also brings not little cost input.
Disclosure of Invention
In view of the above, the present invention provides a dust catching glue for a dust-free workshop and a preparation method thereof to solve the above existing problems.
The technical scheme adopted by the invention for solving the technical problems is as follows:
the dust catching glue for the dust-free workshop comprises the following raw materials in parts by weight: 61-62 parts of polyamide resin, 26.0-26.5 parts of ethylene vinyl acetate copolymer, 11.0-11.5 parts of water-soluble polyethylene glycol wax, 0.2-0.4 part of filler and 0.1-0.3 part of tackifying resin.
Further, the polyamide resin includes at least one of a dimer acid polyamide resin and an amino polyamide resin.
Further, the molecular weight of the dimer acid polyamide resin is 1000-1500.
Further, the molecular weight of the amino polyamide resin is 4000-6000.
Further, the ethylene-vinyl acetate copolymer comprises at least one of vinyl acetate-acrylate, vinyl acetate-maleate and vinyl acetate methylol acrylamide.
Further, the water-soluble polyethylene glycol wax is PEG400 with the molecular weight of 300-500.
Further, the filler includes at least one of calcium silicate and calcium carbonate.
Further, the tackifying resin comprises at least one of polyamide resin, rosin resin, terpene resin and hydrogenated petroleum resin.
Further, the preparation method of the dust catching glue for the dust-free workshop comprises the following steps:
the polyamide resin, the ethylene-vinyl acetate copolymer, the water-soluble polyethylene glycol wax, the filler and the tackifying resin are mixed and then placed in a dispersing machine to be uniformly dispersed, so that the liquid dust catching glue for the dust-free workshop is obtained.
Further, the rotating speed of the dispersion machine is 1200-1800 rpm, and the dispersion time is 40-60 minutes.
The invention has the beneficial effects that:
(1) the dust catching glue for the dust-free workshop is a liquid adhesive, is free from the limitation of equipment and field during use, can be directly coated on a blank top wall and a side wall of the dust-free workshop and a machine shell of the equipment, or coated on a plastic film and fixed to the blank top wall and the side wall and the machine shell of the equipment, realizes the catching of various particle dusts, achieves the dust removal effect, has low softening point, can be used for a long time in a normal room temperature environment and cannot be solidified, and prolongs the service time of the liquid adhesive.
(2) According to the invention, a high-temperature high-pressure reaction is not required in the process of preparing the dust catching adhesive for the dust-free workshop, the preparation method is simple, the energy consumption is low, the cost is low, the effect is obvious, the liquid adhesive does not contain volatile organic solvent, is friendly to human body and environment, and can be used for effectively preventing the liquid adhesive from being solidified and becoming hard and brittle when in use due to volatilization of the organic solvent, so that the dust removing effect of the liquid adhesive is improved.
Detailed Description
The technical solution of the present invention is further illustrated by the following examples. The scope of the present invention is not limited to the specific embodiments but is defined by the scope of the claims.
The invention relates to a dust catching glue for a dust-free workshop, which comprises the following raw materials in parts by weight: 61-62 parts of polyamide resin, 26.0-26.5 parts of ethylene vinyl acetate copolymer, 11.0-11.5 parts of water-soluble polyethylene glycol wax, 0.2-0.4 part of filler and 0.1-0.3 part of tackifying resin; wherein the polyamide resin comprises at least one of dimer acid polyamide resin and amino polyamide resin, the molecular weight of the dimer acid polyamide resin is 1000-1500, and the molecular weight of the amino polyamide resin is 4000-6000; the ethylene-vinyl acetate copolymer comprises at least one of vinyl acetate-acrylic ester, vinyl acetate-maleic acid ester and vinyl acetate hydroxymethyl acrylamide; the water-soluble polyethylene glycol wax is PEG400 with the molecular weight of 300-500; the filler comprises at least one of calcium silicate and calcium carbonate; the tackifying resin comprises at least one of polyamide resin, rosin resin, terpene resin and hydrogenated petroleum resin.
The preparation method of the dust catching glue for the dust-free workshop comprises the following steps:
mixing polyamide resin, ethylene-vinyl acetate copolymer, water-soluble polyethylene glycol wax, filler and tackifying resin, and then placing the mixture into a dispersing machine to disperse for 40-60 minutes at the rotating speed of 1200-1800 rpm to obtain the dust catching glue for the dust-free workshop.
Example 1
The raw materials of the dust-free workshop dust catching glue of the embodiment comprise 61.5g of dimer acid polyamide resin, 26g of vinyl acetate-acrylate, 11g of PEG400, 0.3g of calcium silicate and 0.3g of hydrogenated petroleum resin in parts by weight.
The preparation method of the dust catching glue for the dust-free workshop comprises the following steps:
mixing dimer acid polyamide resin, vinyl acetate-acrylate, PEG400, calcium silicate and hydrogenated petroleum resin, and dispersing in a dispersing machine at 1200 rpm for 60 minutes to obtain the dust catching glue for the dust-free workshop.
Example 2
The raw materials of the dust-free workshop dust catching glue of the embodiment comprise, by weight, 62g of amino polyamide resin, 26g of vinyl acetate-acrylate, 11g of PEG400, 0.3g of calcium silicate and 0.3g of hydrogenated petroleum resin.
The preparation method of the dust catching glue for the dust-free workshop comprises the following steps:
mixing the amino polyamide resin, vinyl acetate-acrylate, PEG400, calcium silicate and hydrogenated petroleum resin, and dispersing in a dispersing machine at 1400 rpm for 50 minutes to obtain the dust catching glue for the dust-free workshop.
Example 3
The raw materials of the dust catching glue for the dust-free workshop in the embodiment comprise, by weight, 62g of dimer acid polyamide resin, 26g of vinyl acetate methylol acrylamide, 11g of PEG400, 0.3g of calcium silicate and 0.3g of rosin resin.
The preparation method of the dust catching glue for the dust-free workshop comprises the following steps:
mixing dimer acid polyamide resin, vinyl acetate hydroxymethyl acrylamide, PEG400, calcium silicate and rosin resin, and dispersing in a dispersing machine at 1600 rpm for 50 minutes to obtain the dust catching glue for the dust-free workshop.
Example 4
The raw materials of the dust-free workshop dust catching glue of the embodiment comprise 61g of amino polyamide resin, 26g of vinyl acetate hydroxymethyl acrylamide, 11g of PEG400, 0.3g of calcium silicate and 0.3g of terpene resin in parts by weight.
The preparation method of the dust catching glue for the dust-free workshop comprises the following steps:
mixing the amino polyamide resin, the vinyl acetate hydroxymethyl acrylamide, the PEG400, the calcium silicate and the terpene resin, and then placing the mixture into a dispersing machine to disperse for 40 minutes at the speed of 1800 rpm to obtain the dust catching glue for the dust-free workshop.
Experimental example:
the cleanliness of the clean room in which the dust-trapping adhesive for the clean room was not coated was measured using a Y09-3016 laser dust particle counter for 24 hours, 36 hours and 48 hours, using a clean room in which the dust-trapping adhesive for the clean room prepared in examples 1-4 was not coated, and the measurement standards were referred to "JJG 547-1988 dust particle counter examination specification" and "GB 50073-2001 clean room design Specification examination specification" of national Standard, and the specific measurement results are shown in Table 1-Table 3:
table 1: dust catching glue performance measuring result table for dust-free workshop (24h)
Cleanliness Blank example Example 1 Example 2 Example 3 Example 4
0.1um 20000 9000 10000 9500 9700
0.2um 5000 1000 900 980 900
0.3um 2400 800 850 900 790
0.5um 530 300 350 350 450
1.0um 160 70 90 80 80
5.0om 3 0 0 0 0
Table 2: dust catching glue performance measuring result table for dust-free workshop (36h)
Cleanliness Blank example Example 1 Example 2 Example 3 Example 4
0.1um 20000 8500 8000 8600 8800
0.2um 5000 930 800 870 850
0.3um 2400 400 500 450 450
0.5um 530 100 90 95 80
1.0um 160 0 0 0 0
5.0om 3 0 0 0 0
Table 3: dust catching glue performance measuring result table for dust-free workshop (48h)
Cleanliness Blank example Example 1 Example 2 Example 3 Example 4
0.1um 20000 7900 7800 7900 7900
0.2um 5000 870 800 800 800
0.3um 2400 400 450 450 400
0.5um 530 90 90 90 80
1.0um 160 0 0 0 0
5.0om 3 0 0 0 0
As can be seen from comparison between examples 1 to 4 and the blank examples in tables 1 to 3, in examples 1 to 4, the dust-free workshop dust catching adhesive prepared by the present invention is directly coated on the blank top wall and side wall of the dust-free workshop and the housing of the device, and the liquid adhesive can catch various particle dusts to achieve a dust removing effect, and meanwhile, the dust catching adhesive prepared by the present invention in examples 1 to 4 has a characteristic of low softening point, can be used in a normal room temperature environment for a long time without solidification, prolongs the service life of the liquid adhesive, and still has a good dust catching effect after 48 hours.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that a person skilled in the art may make several modifications and additions without departing from the method of the invention, and these modifications and additions should also be considered as within the scope of the invention.

Claims (10)

1. The dust catching glue for the dust-free workshop is characterized by comprising the following raw materials in parts by weight: 61-62 parts of polyamide resin, 26.0-26.5 parts of ethylene vinyl acetate copolymer, 11.0-11.5 parts of water-soluble polyethylene glycol wax, 0.2-0.4 part of filler and 0.1-0.3 part of tackifying resin.
2. The dust-catching glue for a clean room as claimed in claim 1, wherein the polyamide resin comprises at least one of dimer acid polyamide resin and amino polyamide resin.
3. The dust-free workshop dust capture adhesive as defined in claim 2, wherein the molecular weight of said dimer acid polyamide resin is 1000-1500.
4. The dust-catching glue for dust-free workshop as claimed in claim 2, wherein the molecular weight of the amino polyamide resin is 4000-6000.
5. The dust catching glue for a dust-free workshop as claimed in claim 1, wherein the ethylene-vinyl acetate copolymer comprises at least one of vinyl acetate-acrylate, vinyl acetate-maleate and vinyl acetate methylol acrylamide.
6. The dust-free workshop dust catching glue of claim 1, wherein the water-soluble polyethylene glycol wax is PEG400 with molecular weight of 300-500.
7. The dust catching glue for a clean room as claimed in claim 1, wherein the filler comprises at least one of calcium silicate and calcium carbonate.
8. The dust-free workshop dust catching glue of claim 1, wherein said tackifying resin comprises at least one of polyamide resin, rosin resin, terpene resin, and hydrogenated petroleum resin.
9. A preparation method of dust catching glue for a dust-free workshop is characterized by comprising the following steps:
the polyamide resin, the ethylene-vinyl acetate copolymer, the water-soluble polyethylene glycol wax, the filler and the tackifying resin are mixed and then placed in a dispersing machine to be uniformly dispersed, so that the liquid dust catching glue for the dust-free workshop is obtained.
10. The method as claimed in claim 9, wherein the rotation speed of the disperser is 1200-1800 rpm, and the dispersion time is 40-60 min.
CN202210494987.1A 2022-05-07 2022-05-07 Dust catching glue for dust-free workshop and preparation method thereof Pending CN114672277A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210494987.1A CN114672277A (en) 2022-05-07 2022-05-07 Dust catching glue for dust-free workshop and preparation method thereof

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Application Number Priority Date Filing Date Title
CN202210494987.1A CN114672277A (en) 2022-05-07 2022-05-07 Dust catching glue for dust-free workshop and preparation method thereof

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101914330A (en) * 2010-04-26 2010-12-15 上海立昌环境工程有限公司 High-temperature resistant dust-binding membrane
CN102337624A (en) * 2010-07-21 2012-02-01 深圳市新纶科技股份有限公司 High-density low-dust-generation wiping cloth used for dust-free room and manufacture method thereof
CN103657263A (en) * 2013-12-26 2014-03-26 彭健智 Bionic dust collection surface and bionic dust collection device
JP2015196269A (en) * 2014-03-31 2015-11-09 大日本印刷株式会社 Resin sheet and method of producing protective layer formation material using the same
CN105567134A (en) * 2016-03-16 2016-05-11 苏州华周胶带有限公司 Heat-resistant adhesive material
CN208500853U (en) * 2018-07-13 2019-02-15 浙江纳鑫胶带制品有限公司 A kind of tape roller

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101914330A (en) * 2010-04-26 2010-12-15 上海立昌环境工程有限公司 High-temperature resistant dust-binding membrane
CN102337624A (en) * 2010-07-21 2012-02-01 深圳市新纶科技股份有限公司 High-density low-dust-generation wiping cloth used for dust-free room and manufacture method thereof
CN103657263A (en) * 2013-12-26 2014-03-26 彭健智 Bionic dust collection surface and bionic dust collection device
JP2015196269A (en) * 2014-03-31 2015-11-09 大日本印刷株式会社 Resin sheet and method of producing protective layer formation material using the same
CN105567134A (en) * 2016-03-16 2016-05-11 苏州华周胶带有限公司 Heat-resistant adhesive material
CN208500853U (en) * 2018-07-13 2019-02-15 浙江纳鑫胶带制品有限公司 A kind of tape roller

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