CN109796721A - A kind of ABS alloy material easy to clean and preparation method thereof - Google Patents
A kind of ABS alloy material easy to clean and preparation method thereof Download PDFInfo
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- CN109796721A CN109796721A CN201811624991.5A CN201811624991A CN109796721A CN 109796721 A CN109796721 A CN 109796721A CN 201811624991 A CN201811624991 A CN 201811624991A CN 109796721 A CN109796721 A CN 109796721A
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- abs alloy
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Abstract
The invention discloses a kind of ABS alloy materials easy to clean and preparation method thereof, it is characterised in that: the alloy material is prepared in parts by weight by following components: 50-90 parts of ABS resin；10-60 parts of polycarbonate；1-10 parts of filler；2-10 parts of surface modifier；1-5 parts of compatilizer；0.3-1 parts of antioxidant；0.5-2.5 parts of lubricant；0.2-1 parts of organic solvent；Strong base-weak acid salt 0.2-1；ABS alloy material prepared by the present invention is not easy to accumulate dust, and easy wiped clean.
Description
Technical field
The present invention relates to technical field of polymer materials, specially a kind of ABS alloy material easy to clean and preparation method thereof.
Background technique
Currently, the development of countries in the world household electric appliances is increasingly increasingly becoming production from human nature, customer experience and safety
The core focus of product, in the living conditions, the cleaning of dust, greasy dirt remove the first major issue for having become people's headache；Dust
It is extremely harmful for each organ of human body, especially it is attached to that the pollutants such as metal ion, benzene, formaldehyde are generated in finishing
Grain object can destroy the mucous membrane tissue of human body by organs such as nasal cavity, the upper respiratory tracts, lead to headache dizziness, visual impairment, breathing
A series of diseases such as difficulty, neu obstacle, are in peril of one's life when serious.
Simultaneously in industrial aspect, dust is accumulated for a long time at the functors such as engine or wind wheel component position, influences air quantity,
The refrigeration effect of complete machine is seriously affected, in addition dust influences the dynamic balancing of flabellum rotation, seriously affects flabellum and impeller place goes out
Air quantity and electrical machinery life.
So providing a kind of ABS alloy material and its system easy to clean being able to solve convenient for ABS alloy material cleaning problems
Preparation Method, which becomes us, to be solved the problems, such as.
Summary of the invention
The purpose of the present invention is to provide a kind of ABS alloy materials easy to clean and preparation method thereof, to solve above-mentioned background
It proposes to be convenient for ABS alloy material cleaning problems in technology.
To achieve the above object, the invention provides the following technical scheme:
A kind of ABS alloy material easy to clean and preparation method thereof, it is characterised in that: the alloy material be by following components by
Parts by weight are prepared:
Preferably, the partial size of the ABS resin is 3-4 μm, mass percent 30%.
Preferably, the filler be white carbon black, poly- methyl carbamide resin, metallic soap, diatomite, in wollastonite at least
It is a kind of.
Preferably, the partial size of the filler is 100-200nm.
Preferably, the surface modifier is perfluorocarboxylic acid chromium complex, acrylic acid fluorohydrocarbon esters resin, acrylic acid fluorine
At least one of hydrocarbon sulfonamido ethyl ester, chlorotrifluoroethylene-vinylidene fluoride copolymers.
Preferably, the compatilizer is maleic anhydride grafted propylene nitrile butadiene-styrene copolymer, styrene-the third
Alkene nitrile-copolymer-maleic anhydride, Styrene-Maleic Anhydride Copolymer and acrylonitrile-styrene-methacrylic acid copolymer
At least one of；
The antioxidant is 2,2- methylene-bis- (4- methyl-6-tert butyl phenol), N, N- [3- (3,5- di-t-butyl -4-
Hydroxy phenyl) propionyl] hexamethylene diamine, 4,4'- thiobis (6- tert-butyl -3- methylphenol), bis- [1, the 1- dimethyl-of 3,9-
2- [(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionyloxy] ethyl] four oxaspiro of -2,4,8,10-, N, the bis- [3- of N ' -
At least one of (3 ', 5 '-di-t-butyls -4 '-hydroxy phenyl) propionyl hexamethylene diamine.
Preferably, the lubricant is pentaerythritol stearate, N, N- has supportted bis-stearamides, lignite wax, glycerol
At least one of monoesters acid value, amide waxe, o-phthalic acid dibutyl ester and butyl stearate；
The organic solvent is ethanol solution.
Preferably, ethyl alcohol mass percent is 80%-90% in the ethanol solution.
Preferably, the strong base-weak acid salt is at least one of hydrogen phosphite sodium, calcium bicarbonate, saleratus.
A kind of preparation method of ABS alloy material easy to clean, it is characterised in that: method includes the following steps:
(1) polycarbonate and strong base-weak acid salt are mixed to get mixture, it is 15- that mixture, which is then placed on pressure,
CF4 RF plasma processing 20-50min is used in reactor under the conditions of 120Pa.
(2) by step (1) treated polycarbonate and strong base weak acid salt mixture investment screw extruder, while one
And ABS resin, filler, surface modifier, compatilizer, antioxidant and lubricant are put into screw extruder, it is squeezed through melting
Out, pelletizing obtains primary ABS alloy material；
(3) primary ABS alloy material will be obtained in (2) and place 36-48H in organic solvent, then air-dried to obtain
ABS alloy material product.
Compared with prior art, the beneficial effects of the present invention are: ABS alloy material prepared by the present invention is not easy heap dust stratification
Dirt, and easy wiped clean, therefore in the living conditions, dust, greasy dirt are carried out to product made of ABS alloy material convenient for user
Cleaning；In industrial aspect, dust long-term accumulation in equipment is prevented, the indirect performance for improving equipment.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
In the description of the present invention, it is to be understood that, term " on ", "lower", "front", "rear", "left", "right", "top",
The orientation or positional relationship of the instructions such as "bottom", "inner", "outside" is the orientation or positional relationship based on shown in, is merely for convenience of retouching
It states the present invention and simplifies description, rather than the device or element of indication or suggestion meaning must have a particular orientation, with specific
Orientation construction and operation, therefore be not considered as limiting the invention.
Embodiment 1:
A kind of ABS alloy material easy to clean and preparation method thereof, it is characterised in that: the alloy material be by following components by
Parts by weight are prepared:
A kind of ABS alloy material easy to clean the preparation method is as follows:
(1) polycarbonate and strong base-weak acid salt are mixed to get mixture, mixture is then placed on low pressure (30Pa)
Under the conditions of reactor (reactor outer wall be stainless steel bulge, reaction chamber center install about two parallel diameters be
Disk electrode of the 25cm at a distance of 10cm, top crown and chamber wall ground connection, bottom crown connects radio-frequency power supply) in use CF4 radio frequency plasma
Body handles 20min；
(2) by step (1) treated polycarbonate and strong base weak acid salt mixture investment screw extruder, while one
And ABS resin, filler, surface modifier, compatilizer, antioxidant and lubricant are put into screw extruder, it is squeezed through melting
Out, pelletizing obtains primary ABS alloy material；
(3) primary ABS alloy material will be obtained in (2) and place 36H in organic solvent, then air-dried to obtain ABS
Alloy material product.
Embodiment 2:
A kind of ABS alloy material easy to clean the preparation method is as follows:
(1) polycarbonate and strong base-weak acid salt are mixed to get mixture, mixture is then placed on low pressure (30Pa)
Under the conditions of reactor (reactor outer wall be stainless steel bulge, reaction chamber center install about two parallel diameters be
Disk electrode of the 25cm at a distance of 10cm, top crown and chamber wall ground connection, bottom crown connects radio-frequency power supply) in use CF4 radio frequency plasma
Body handles 20min；
(2) by step (1) treated polycarbonate and strong base weak acid salt mixture investment screw extruder, while one
And ABS resin, filler, surface modifier, compatilizer, antioxidant and lubricant are put into screw extruder, it is squeezed through melting
Out, pelletizing obtains primary ABS alloy material；
(3) primary ABS alloy material will be obtained in (2) and place 36H in organic solvent, then air-dried to obtain ABS
Alloy material product.
Embodiment 3:
A kind of ABS alloy material easy to clean the preparation method is as follows:
(1) polycarbonate and strong base-weak acid salt are mixed to get mixture, mixture is then placed on low pressure (30Pa)
Under the conditions of reactor (reactor outer wall be stainless steel bulge, reaction chamber center install about two parallel diameters be
Disk electrode of the 25cm at a distance of 10cm, top crown and chamber wall ground connection, bottom crown connects radio-frequency power supply) in use CF4 radio frequency plasma
Body handles 20min；
(2) by step (1) treated polycarbonate and strong base weak acid salt mixture investment screw extruder, while one
And ABS resin, filler, surface modifier, compatilizer, antioxidant and lubricant are put into screw extruder, it is squeezed through melting
Out, pelletizing obtains primary ABS alloy material；
(3) primary ABS alloy material will be obtained in (2) and place 36H in organic solvent, then air-dried to obtain ABS
Alloy material product.
Embodiment 4:
A kind of ABS alloy material easy to clean the preparation method is as follows:
(1) polycarbonate and strong base-weak acid salt are mixed to get mixture, mixture is then placed on low pressure (30Pa)
Under the conditions of reactor (reactor outer wall be stainless steel bulge, reaction chamber center install about two parallel diameters be
At a distance of the disk electrode of 10cm, top crown and chamber wall ground connection, bottom crown connect in radio-frequency power supply) with CF4 radio frequency plasma 25cm
Body handles 20min；
(2) by step (1) treated polycarbonate and strong base weak acid salt mixture investment screw extruder, while one
And ABS resin, filler, surface modifier, compatilizer, antioxidant and lubricant are put into screw extruder, it is squeezed through melting
Out, pelletizing obtains primary ABS alloy material；
(3) primary ABS alloy material will be obtained in (2) and place 36H in organic solvent, then air-dried to obtain ABS
Alloy material product.
Embodiment 5:
A kind of ABS alloy material easy to clean the preparation method is as follows:
(1) polycarbonate and strong base-weak acid salt are mixed to get mixture, mixture is then placed on low pressure (30Pa)
Under the conditions of reactor (reactor outer wall be stainless steel bulge, reaction chamber center install about two parallel diameters be
Disk electrode of the 25cm at a distance of 10cm, top crown and chamber wall ground connection, bottom crown connects radio-frequency power supply) in use CF4 radio frequency plasma
Body handles 20min；
(2) by step (1) treated polycarbonate and strong base weak acid salt mixture investment screw extruder, while one
And ABS resin, filler, surface modifier, compatilizer, antioxidant and lubricant are put into screw extruder, it is squeezed through melting
Out, pelletizing obtains primary ABS alloy material；
(3) primary ABS alloy material will be obtained in (2) and place 36H in organic solvent, then air-dried to obtain ABS
Alloy material product
Comparative example 1:
A kind of ABS alloy material easy to clean the preparation method is as follows:
(1) polycarbonate and strong base-weak acid salt are mixed to get mixture, mixture is then placed on low pressure (30Pa)
Under the conditions of reactor (reactor outer wall be stainless steel bulge, reaction chamber center install about two parallel diameters be
Disk electrode of the 25cm at a distance of 10cm, top crown and chamber wall ground connection, bottom crown connects radio-frequency power supply) in use CF4 radio frequency plasma
Body handles 20min；
(2) by step (1) treated polycarbonate and strong base weak acid salt mixture investment screw extruder, while one
And ABS resin, filler, surface modifier, compatilizer, antioxidant and lubricant are put into screw extruder, it is squeezed through melting
Out, pelletizing obtains primary ABS alloy material；
(3) primary ABS alloy material will be obtained in (2) and place 36H in organic solvent, then air-dried to obtain ABS
Alloy material product.
Comparative example 2:
A kind of ABS alloy material easy to clean the preparation method is as follows:
(1) polycarbonate and strong base-weak acid salt are mixed to get mixture, mixture is then placed on low pressure (30Pa)
Under the conditions of reactor (reactor outer wall be stainless steel bulge, reaction chamber center install about two parallel diameters be
Disk electrode of the 25cm at a distance of 10cm, top crown and chamber wall ground connection, bottom crown connects radio-frequency power supply) in use CF4 radio frequency plasma
Body handles 20min；
(2) by step (1) treated polycarbonate and strong base weak acid salt mixture investment screw extruder, while one
And ABS resin, filler, surface modifier, compatilizer, antioxidant and lubricant are put into screw extruder, it is squeezed through melting
Out, pelletizing obtains primary ABS alloy material；
(3) primary ABS alloy material will be obtained in (2) and place 36H in organic solvent, then air-dried to obtain ABS
Alloy material product.
Comparative example 3:
A kind of ABS alloy material easy to clean the preparation method is as follows:
(1) in polycarbonate and strong base weak acid salt mixture investment screw extruder, while together in screw extruder
Investment ABS resin, filler, surface modifier, compatilizer, antioxidant and lubricant obtain primary through melting extrusion, pelletizing
ABS alloy material；
(2) primary ABS alloy material will be obtained in step (1) and places 36H in organic solvent, then air-dried to obtain
ABS alloy material product.
ABS alloy material after embodiment 1-5 and comparative example 1-3 preparation is tested for the property, and specific test result is such as
Shown in table 1:
Table 1
Remarks: floating ash state 1-10 points, 10 points of surface dirt depositions are most, and 1 point indicates entirely without any dust；Oil dripping
The complexity 1-10 of wiped clean points afterwards, 1 point of expression is easily cleaned, and 10 points indicate super difficult cleaning.
Sub-fraction dust is only had accumulated from the ABS alloy material prepared in embodiment 1-5, and in comparative example 1-2 then
More dust is had accumulated, therefore as can be seen that ABS alloy material prepared by the present invention from embodiment 1-5 and comparative example 1-2
It is not easy to accumulate dust, and easy wiped clean；Simultaneously by embodiment 1 and comparative example 3 as can be seen that being prepared in ABS alloy material
CF4 RF plasma processing is used in step process, from table 1 it follows that after using CF4 RF plasma processing
The ABS alloy material of preparation is not easy to accumulate dust, and easy wiped clean.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (10)
1. a kind of ABS alloy material easy to clean, it is characterised in that: the alloy material be prepared in parts by weight by following components and
At:
2. a kind of ABS alloy material easy to clean according to claim 1, it is characterised in that: the partial size of the ABS resin is
3-4 μm, mass percent 30%.
3. a kind of ABS alloy material easy to clean according to claim 1, it is characterised in that: the filler be white carbon black,
At least one of poly- methyl carbamide resin, metallic soap, diatomite, wollastonite.
4. a kind of ABS alloy material easy to clean according to claim 3, it is characterised in that: the partial size of the filler
100-200nm。
5. a kind of ABS alloy material easy to clean according to claim 1, it is characterised in that: the surface modifier is complete
Carboxylic acid fluoride chromium complex, acrylic acid fluorohydrocarbon esters resin, acrylic acid fluorohydrocarbon sulfonamido ethyl ester, chlorotrifluoroethylene-vinylidene
At least one of copolymer.
6. a kind of ABS alloy material easy to clean according to claim 1, it is characterised in that: the compatilizer is maleic acid
Acid anhydride grafted propylene nitrile butadiene-styrene copolymer, styrene-acrylonitrile-copolymer-maleic anhydride, phenylethylene-maleic two
At least one of acid anhydride copolymer and acrylonitrile-styrene-methacrylic acid copolymer；
The antioxidant is 2,2- methylene-bis- (4- methyl-6-tert butyl phenol), N, N- [3- (3,5- di-t-butyl -4- hydroxyl
Phenyl) propionyl] hexamethylene diamine, 4,4'- thiobis (6- tert-butyl -3- methylphenol), bis- [1, the 1- dimethyl -2- of 3,9-
[(3- tertiary butyl-4-hydroxy -5- aminomethyl phenyl) propionyloxy] ethyl] four oxaspiro of -2,4,8,10-, N, N '-it is bis- [3- (3 ',
At least one of 5 '-di-t-butyls -4 '-hydroxy phenyl) propionyl hexamethylene diamine.
7. a kind of ABS alloy material easy to clean according to claim 1, it is characterised in that: the lubricant is Ji Wusi
Alcohol stearate, N, N- have supportted bis-stearamides, lignite wax, monoglyceride acid value, amide waxe, o-phthalic acid dibutyl ester and fourth
At least one of base stearate；
The organic solvent is ethanol solution.
8. a kind of ABS alloy material easy to clean according to claim 7, it is characterised in that: ethyl alcohol in the ethanol solution
Mass percent 80%-90%.
9. a kind of ABS alloy material easy to clean according to claim 1, it is characterised in that: the strong base-weak acid salt is Asia
At least one of dibastic sodium phosphate, calcium bicarbonate, saleratus.
10. a kind of preparation method of such as described in any item ABS alloy materials easy to clean of claim 1-9, it is characterised in that: should
Method the following steps are included:
(1) polycarbonate and strong base-weak acid salt are mixed to get mixture, it is 15-120Pa that mixture, which is then placed on pressure,
Under the conditions of reactor in use CF4 RF plasma processing 20-50min；
(2) by step (1) treated polycarbonate and strong base weak acid salt mixture investment screw extruder, while existing together
ABS resin, filler, surface modifier, compatilizer, antioxidant and lubricant are put into screw extruder, through melting extrusion, are cut
Grain, obtains primary ABS alloy material；
(3) primary ABS alloy material will be obtained in (2) and place 36-48H in organic solvent, then air-dried to obtain ABS conjunction
Golden material product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811624991.5A CN109796721A (en) | 2018-12-28 | 2018-12-28 | A kind of ABS alloy material easy to clean and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811624991.5A CN109796721A (en) | 2018-12-28 | 2018-12-28 | A kind of ABS alloy material easy to clean and preparation method thereof |
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| CN109796721A true CN109796721A (en) | 2019-05-24 |
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| CN201811624991.5A Pending CN109796721A (en) | 2018-12-28 | 2018-12-28 | A kind of ABS alloy material easy to clean and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110317427A (en) * | 2019-07-03 | 2019-10-11 | 南宁珀源能源材料有限公司 | Novel special backing plate of photovoltaic buddha's warrior attendant wire-electrode cutting |
| CN112876829A (en) * | 2021-01-15 | 2021-06-01 | 万华化学(四川)有限公司 | Electroplating PC/ABS alloy material and preparation method thereof |
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