CN114605968A - Engine coolant and application thereof - Google Patents

Engine coolant and application thereof Download PDF

Info

Publication number
CN114605968A
CN114605968A CN202011407517.4A CN202011407517A CN114605968A CN 114605968 A CN114605968 A CN 114605968A CN 202011407517 A CN202011407517 A CN 202011407517A CN 114605968 A CN114605968 A CN 114605968A
Authority
CN
China
Prior art keywords
engine coolant
imidazoline
parts
peptide
corrosion inhibitor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202011407517.4A
Other languages
Chinese (zh)
Inventor
丁烨
杨兵
黄海鹏
耿立波
樊秀菊
黄红亚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Petroleum and Chemical Corp
Original Assignee
China Petroleum and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum and Chemical Corp filed Critical China Petroleum and Chemical Corp
Priority to CN202011407517.4A priority Critical patent/CN114605968A/en
Publication of CN114605968A publication Critical patent/CN114605968A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/20Antifreeze additives therefor, e.g. for radiator liquids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The invention belongs to the technical field of engine cooling liquid, and particularly relates to engine cooling liquid and application thereof, wherein the engine cooling liquid comprises the following components in percentage by weight: 30-50% of propylene glycol, 1-5% of organic carboxylic acid, 3-9% of corrosion inhibitor, 0.1-1% of defoaming agent and the balance of deionized water; wherein the corrosion inhibitor is a composition of an imidazoline corrosion inhibitor and a peptide compound. The engine cooling liquid disclosed by the invention adopts environment-friendly raw material components, has good anti-freezing, heat-dissipating and defoaming effects, and can effectively prevent a motorcycle cooling system from generating a metal corrosion phenomenon.

Description

Engine coolant and application thereof
Technical Field
The invention belongs to the technical field of engine cooling liquid, and particularly relates to engine cooling liquid and application thereof.
Background
The environment-friendly engine coolant special for the motorcycle is used for a water-cooling motorcycle engine cooling system, is used as a heat transfer medium of the motorcycle water cooling system, conducts heat of an engine, and keeps the temperature of the engine within a proper temperature range.
The water cooling motorcycle is mainly a motorcycle with the discharge capacity of more than 150CC, the components of a cooling system of the water cooling motorcycle mainly comprise a water tank, a water pump, a temperature control system, a fan and the like, the related metal materials comprise aluminum, copper, steel, soldering tin and the like, and the requirements on cooling liquid mainly comprise freezing prevention, rust prevention, heat dissipation, low toxicity and the like.
Disclosure of Invention
The invention aims to provide the engine coolant which is environment-friendly, low in toxicity and good in anti-freezing, defoaming and corrosion inhibition effects. The engine coolant adopts the propylene glycol and the low-toxicity additive, so that the environmental pollution and the damage to coolant replacement personnel can be reduced. By utilizing the synergistic effect of the corrosion inhibitor and adopting different corrosion inhibitor compounding technologies, the corrosion inhibitor has good protection effect on metals, can ensure the normal operation of a motorcycle cooling system, and prolongs the service life of the system.
Specifically, the invention provides the following technical scheme:
an engine coolant comprises the following components in percentage by weight:
Figure BDA0002817666050000011
wherein the corrosion inhibitor is a composition of an imidazoline corrosion inhibitor and a peptide compound.
The propylene glycol is an antifreezing agent, can effectively lower the freezing point, and prevents the liquid from freezing at a low temperature.
Preferably, the engine coolant comprises the following components in percentage by weight:
Figure BDA0002817666050000021
preferably, in the engine coolant, the mass ratio of the imidazoline corrosion inhibitor to the peptide compound is 2: 1-3: 1. The imidazoline corrosion inhibitor has a metal corrosion inhibition effect, can prevent metal in a water cooling system from rusting, has a good synergistic effect by being matched with a peptide compound, can strengthen the metal corrosion inhibition effect of a formula, and has an excellent corrosion inhibition effect on metal in a proper proportion.
Preferably, in the engine coolant, the imidazoline-type corrosion inhibitor is one or more selected from coco carboxymethyl sodium imidazoline acetate, imidazoline-type sodium phosphate, hydroxyethyl oleic acid imidazoline betaine, and undecyl carboxymethyl sodium imidazoline acetate, and is more preferably coco carboxymethyl sodium imidazoline acetate.
Preferably, in the engine coolant, the peptide compound is selected from one or more of pupa acylated peptide, cationic protein peptide, glutathione and casein phosphopeptide, and further preferably pupa acylated peptide and cationic protein peptide.
Preferably, in the engine coolant, the defoaming agent is a composition of a hydrophobic association water-soluble polymer AM-CO-NSAM and guar gum, and the mass ratio of the AM-CO-NSAM to the guar gum is 1: 1-1: 4; further preferably, the guar gum is hydroxypropyl guar gum JK201 or ultra-hydroxypropyl guar gum JK101, more preferably hydroxypropyl guar gum JK 201. The defoaming agent can inhibit the generation of foam in the cooling liquid and avoid the influence of the foam on the heat conduction capability of the cooling liquid.
Preferably, the engine coolant consists of the following components in parts by weight:
45 parts of propylene glycol, 4 parts of organic carboxylic acid, 4 parts of cocoyl sodium carboxymethyl imidazoline acetate, 1 part of pupa acylated peptide, 1 part of cationic protein peptide, 0.2 part of hydrophobically associating water-soluble polymer AM-CO-NSAM, 0.78 part of hydroxypropyl guar gum JK 2010.6 and 44.2 parts of deionized water.
The invention also provides application of the engine coolant in the field of motorcycle engine cooling.
The engine coolant related to the invention has the following remarkable advantages:
(1) the corrosion inhibitor has good corrosion inhibition effect on various metals, protects metal parts in a motorcycle water cooling system from being rusted, and prolongs the service life of the system.
(2) The cooling liquid defoaming agent has excellent defoaming performance, and the two defoaming agents are compounded according to a certain proportion, so that the generation of foam can be effectively inhibited, and the influence of the foam on the heat dissipation performance of the cooling liquid is avoided.
(3) The antifreeze and the additive with low toxicity and good environmental protection performance are adopted, so that the influence on the environment and the health of operators contacting the cooling liquid are reduced.
Detailed Description
The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention. Unless otherwise specified, the reagents used in the examples are all conventional commercially available reagents, and the technical means used in the examples are conventional means well known to those skilled in the art.
Example 1
45 parts of propylene glycol, 4 parts of ketoglutaric acid, 4 parts of sodium cocoyl carboxymethyl imidazoline acetate, 1 part of pupa acylated peptide, 1 part of cationic protein peptide, 0.2 part of hydrophobically associating water-soluble polymer AM-CO-NSAM, 0.78 part of hydroxypropyl guar gum JK 2010.6 and 44.2 parts of deionized water.
The preparation method comprises the following steps: and uniformly mixing propylene glycol, ketoglutaric acid, sodium cocoyl carboxymethyl imidazoline acetate, pupa acylated peptide, cationic protein peptide, hydrophobically associating water-soluble polymer AM-CO-NSAM, hydroxypropyl guar gum JK201 and deionized water at room temperature according to the using amount to obtain the special environment-friendly engine coolant for the motorcycle.
Example 2
30 parts of propylene glycol, 1 part of ketoglutaric acid, 4 parts of imidazoline type sodium phosphate, 2 parts of hydroxyethyl oleic acid imidazoline betaine, 3 parts of casein phosphopeptide, 0.5 part of hydrophobically associating water-soluble polymer AM-CO-NSAM, 0.78 part of hydroxypropyl guar gum JK 2010.5 and 59 parts of deionized water.
The preparation method comprises the following steps: uniformly mixing propylene glycol, ketoglutaric acid, imidazoline type sodium phosphate, hydroxyethyl oleic acid imidazoline betaine, casein phosphopeptide, hydrophobically associating water-soluble polymer AM-CO-NSAM, hydroxypropyl guar gum JK201 and deionized water at room temperature according to the above dosage to obtain the special environment-friendly engine coolant for the motorcycle.
Example 3
35 parts of propylene glycol, 5 parts of ketoglutaric acid, 1.5 parts of sodium cocoyl carboxymethyl sodium imidazoline acetate, 0.5 part of sodium undecyl carboxymethyl sodium imidazoline acetate, 0.5 part of cationic protein peptide, 0.5 part of glutathione, 0.1 part of hydrophobically associating water-soluble polymer AM-CO-NSAM, JK 1010.35 parts of ultra-hydroxypropyl guar gum and 56.55 parts of deionized water.
The preparation method comprises the following steps: uniformly mixing propylene glycol, ketoglutaric acid, sodium cocoyl carboxymethyl sodium imidazoline acetate, sodium undecyl carboxymethyl sodium imidazoline acetate, cationic protein peptide, glutathione, hydrophobically associating water-soluble polymer AM-CO-NSAM, ultra-hydroxypropyl guar gum JK101 and deionized water at room temperature according to the using amount to obtain the environment-friendly engine coolant special for the motorcycle.
Example 4
40 parts of propylene glycol, 3 parts of ketoglutaric acid, 0.5 part of sodium cocoyl carboxymethyl sodium imidazoline acetate, 1 part of imidazoline type sodium phosphate, 0.3 part of hydroxyethyl oleic acid imidazoline betaine, 0.7 part of undecyl carboxymethyl sodium imidazoline acetate, 0.2 part of pupa acylated peptide, 0.2 part of cationic protein peptide, 0.2 part of glutathione, 0.4 part of casein phosphopeptide, 0.2 part of hydrophobically associating water-soluble polymer AM-CO-NSAM, 1010.4 parts of ultra-hydroxypropyl guar gum JK and 52.9 parts of deionized water.
The preparation method comprises the following steps: according to the above dosage, uniformly mixing propylene glycol, ketoglutaric acid, sodium cocoyl carboxymethyl sodium imidazoline acetate, imidazoline type sodium phosphate, hydroxyethyl oleic acid imidazoline betaine, sodium undecyl carboxymethyl sodium imidazoline acetate, pupa acylated peptide, cationic protein peptide, glutathione, casein phosphopeptide, hydrophobically associating water-soluble polymer AM-CO-NSAM, super hydroxypropyl guar gum JK101 and deionized water at room temperature to obtain the special environment-friendly engine coolant for the motorcycle of the embodiment.
Example 5
45 parts of propylene glycol, 2 parts of ketoglutaric acid, 1.7 parts of sodium cocoyl carboxymethyl imidazoline acetate, 1.7 parts of imidazoline type sodium phosphate, 1.2 parts of hydroxyethyl oleic acid imidazoline betaine, 0.2 part of pupa acylated peptide, 0.5 part of cationic protein peptide, 1 part of glutathione, 0.2 part of hydrophobically associating water-soluble polymer AM-CO-NSAM, 0.78 part of hydroxypropyl guar gum JK 2010.4 and 46.1 parts of deionized water.
The preparation method comprises the following steps: uniformly mixing propylene glycol, ketoglutaric acid, sodium cocoyl carboxymethyl sodium imidazoline acetate, imidazoline type sodium phosphate, hydroxyethyl oleic acid imidazoline betaine, pupa acylated peptide, cationic protein peptide, glutathione, hydrophobically associating water-soluble polymer AM-CO-NSAM, hydroxypropyl guar gum JK201 and deionized water at room temperature according to the using amount to obtain the environment-friendly engine coolant special for the motorcycle.
Comparative example 1
Comparative example 1, which does not contain a peptide compound, is composed of the following:
45 parts of propylene glycol, 4 parts of ketoglutaric acid, 6 parts of sodium cocoyl carboxymethyl imidazoline acetate, 0.2 part of hydrophobically associating water-soluble polymer AM-CO-NSAM, JK 2010.6 parts of hydroxypropyl guar gum and 44.2 parts of deionized water.
Comparative example 2
Comparative example 2 does not contain imidazoline corrosion inhibitor, and comprises the following specific components:
45 parts of propylene glycol, 4 parts of ketoglutaric acid, 3 parts of pupa acylated peptide, 3 parts of cationic protein peptide, 0.2 part of hydrophobically associating water-soluble polymer AM-CO-NSAM, JK 2010.6 parts of hydroxypropyl guar gum and 44.2 parts of deionized water.
Experimental example:
the freezing point, glassware corrosion and foaming tendency of the environment-friendly engine coolant special for motorcycles obtained in the examples 1 to 5 are measured according to SH/T0090, SH/T0085 and SH/T0066 methods, and the detection results are shown in Table 1.
TABLE 1 detection results of cooling liquid for environment-friendly engine special for motorcycle
Figure BDA0002817666050000061
And (4) conclusion: experimental results show that the engine coolant provided by the invention has excellent antifreezing capacity, metal corrosion inhibition capacity and defoaming capacity, and can provide excellent antifreezing, anticorrosion and defoaming protection for a motorcycle cooling system.
Although the invention has been described in detail hereinabove by way of general description, specific embodiments and experiments, it will be apparent to those skilled in the art that many modifications and improvements can be made thereto based on the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.

Claims (10)

1. The engine coolant is characterized by comprising the following components in percentage by weight:
Figure FDA0002817666040000011
wherein the corrosion inhibitor is a composition of an imidazoline corrosion inhibitor and a peptide compound.
2. The engine coolant as set forth in claim 1, characterized by comprising the following components in percentage by weight:
Figure FDA0002817666040000012
3. the engine coolant as claimed in claim 1 or 2, wherein the mass ratio of the imidazoline type corrosion inhibitor to the peptide compound is 2: 1-3: 1.
4. The engine coolant of any one of claims 1 to 3, wherein the imidazoline type corrosion inhibitor is selected from one or more of coco carboxymethyl sodium imidazoline acetate, imidazoline type sodium phosphate, hydroxyethyl oleic imidazoline betaine, undecyl carboxymethyl sodium imidazoline acetate, and is preferably coco carboxymethyl sodium imidazoline acetate.
5. The engine coolant of any one of claims 1 to 4, wherein the peptide compound is selected from one or more of pupation acylated peptide, cationic protein peptide, glutathione and casein phosphopeptide.
6. The engine coolant of claim 5 wherein the peptide compounds are pupation acylated peptides and cationic protein peptides.
7. The engine coolant according to any one of claims 1 to 6, wherein the defoaming agent is a composition of a hydrophobically associating water-soluble polymer AM-CO-NSAM and guar gum, and the mass ratio of the AM-CO-NSAM to the guar gum is 1: 1-1: 4.
8. Engine coolant according to claim 6, characterized in that the guar gum is hydroxypropyl guar JK201 or ultra-hydroxypropyl guar JK101, preferably hydroxypropyl guar JK 201.
9. The engine coolant as set forth in claim 1, which is composed of the following components in parts by weight:
45 parts of propylene glycol, 4 parts of organic carboxylic acid, 4 parts of cocoyl sodium carboxymethyl imidazoline acetate, 1 part of pupa acylated peptide, 1 part of cationic protein peptide, 0.2 part of hydrophobically associating water-soluble polymer AM-CO-NSAM, 0.78 part of hydroxypropyl guar gum JK 2010.6 and 44.2 parts of deionized water.
10. Use of the engine coolant of any one of claims 1 to 9 in the field of cooling of motorcycle engines.
CN202011407517.4A 2020-12-04 2020-12-04 Engine coolant and application thereof Pending CN114605968A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011407517.4A CN114605968A (en) 2020-12-04 2020-12-04 Engine coolant and application thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011407517.4A CN114605968A (en) 2020-12-04 2020-12-04 Engine coolant and application thereof

Publications (1)

Publication Number Publication Date
CN114605968A true CN114605968A (en) 2022-06-10

Family

ID=81856947

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011407517.4A Pending CN114605968A (en) 2020-12-04 2020-12-04 Engine coolant and application thereof

Country Status (1)

Country Link
CN (1) CN114605968A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07292386A (en) * 1993-12-29 1995-11-07 Sunstar Inc Detergent composition
WO1999059958A1 (en) * 1998-05-20 1999-11-25 The Associated Octel Company Limited Biodegradable corrosion inhibitors
CN101824310A (en) * 2009-12-19 2010-09-08 乌鲁木齐现代石油化工有限公司 Compounded corrosion inhibitor and water-based propylene glycol coolant
WO2013060616A1 (en) * 2011-10-26 2013-05-02 Haertol Chemie Gmbh Alkali metal nitrate as additive to coolants in coolant systems
US20150245986A1 (en) * 2012-10-01 2015-09-03 Rhodia Operations Foam improvement of soap containing compositions
CN105199043A (en) * 2015-10-21 2015-12-30 西安长庆化工集团有限公司 Hydrophobically associating water-soluble polymer (HAWP) and preparation method thereof
US20180334750A1 (en) * 2017-05-19 2018-11-22 King Fahd University Of Petroleum And Minerals Composition and methods for inhibition of metal corrosion for use in the oil and gas industry

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07292386A (en) * 1993-12-29 1995-11-07 Sunstar Inc Detergent composition
WO1999059958A1 (en) * 1998-05-20 1999-11-25 The Associated Octel Company Limited Biodegradable corrosion inhibitors
CN101824310A (en) * 2009-12-19 2010-09-08 乌鲁木齐现代石油化工有限公司 Compounded corrosion inhibitor and water-based propylene glycol coolant
WO2013060616A1 (en) * 2011-10-26 2013-05-02 Haertol Chemie Gmbh Alkali metal nitrate as additive to coolants in coolant systems
US20150245986A1 (en) * 2012-10-01 2015-09-03 Rhodia Operations Foam improvement of soap containing compositions
CN105199043A (en) * 2015-10-21 2015-12-30 西安长庆化工集团有限公司 Hydrophobically associating water-soluble polymer (HAWP) and preparation method thereof
US20180334750A1 (en) * 2017-05-19 2018-11-22 King Fahd University Of Petroleum And Minerals Composition and methods for inhibition of metal corrosion for use in the oil and gas industry

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
干信等: "蛹酰化肽的酰化条件优化及理化性质研究", 湖北工学院学报, vol. 3, no. 4, pages 1 - 5 *
蒋海福;王国民;全嘉榕;甘冬丽;覃克;黄福川;: "基于理想点法的重负荷LNG发动机冷却液的研制", 当代化工, no. 05 *
郭海军等: "新型疏水缔合水溶性聚合物的合成及溶液性能研究", 化工进展, vol. 22, no. 12, pages 1312 - 1315 *
陈一帆;魏雅男;唐弓斌;潘发存;康克;黄福川;: "采用模糊层次法的全配方重负荷发动机冷却液研制", 润滑与密封, vol. 1, no. 08, pages 211 - 212 *

Similar Documents

Publication Publication Date Title
CN1072252C (en) Silicate-, borate- and nitrate-free antifreeze concentrates and coolant compositions comprising them
US6045719A (en) Use of quaternized imidazoles as corrosion inhibitors for non-ferrous metals, and coolant compositions and antifreeze concentrates comprising them
EP1206504B1 (en) Synergistic combinations of carboxylates for use as freezing point depressants and corrosion inhibitors in heat transfer fluids
CN1522289A (en) Monocarboxylic acid based antifreeze composition
JPH02182782A (en) Heat transfer fluid containing dicarboxylic acid mixture as corrosion inhibitor
JPH0195179A (en) Anticorrosive antifreeze liquid blend
JPH06116764A (en) Antifreeze composition
CN102786915A (en) Multifunctional car water tank antifreeze fluid
CN107987803B (en) Phosphorus-containing engine coolant and preparation method thereof
CN1351105A (en) Corrosion inhibitor for cooling liquid of IC engine
AU1453699A (en) Silicate free antifreeze composition
CN1371431A (en) Corrosion inhibiting composition for heat transfer fluids
CN111978932B (en) Organic corrosion inhibition cooling liquid and preparation method thereof
CN114605968A (en) Engine coolant and application thereof
CN107418527A (en) A kind of high-efficiency anticorrosive engine coolant
CN112501619A (en) All-organic additive formula for light-load glycol type cooling liquid
KR19980037435A (en) Cooling Antifreeze Composition
CN1346396A (en) Monocarboxylic acid based antifreeze composition for diesel engines
CN113563854B (en) Environment-friendly anhydrous cooling liquid and preparation method and application thereof
CA2336644A1 (en) Antifreeze concentrates and coolant compositions containing these concentrates for cooling circuits in internal combustion engines
CN114574173B (en) Cooling liquid and preparation method and application thereof
CN101949015A (en) Protective agent for water-cooled engine cooling system
JP2008088242A (en) Cooling liquid composition
JP2001158878A (en) Cooling liquid composition
JPS646277B2 (en)

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20220610