CN114571818A - High-heat-insulation laminated tile and preparation method thereof - Google Patents

High-heat-insulation laminated tile and preparation method thereof Download PDF

Info

Publication number
CN114571818A
CN114571818A CN202110354311.8A CN202110354311A CN114571818A CN 114571818 A CN114571818 A CN 114571818A CN 202110354311 A CN202110354311 A CN 202110354311A CN 114571818 A CN114571818 A CN 114571818A
Authority
CN
China
Prior art keywords
adhesive
layer
resin adhesive
adhesive layer
laminated tile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110354311.8A
Other languages
Chinese (zh)
Inventor
姜松
赵岳响
彭青
陈凯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU PIONEER TECHNOLOGY CO LTD
Original Assignee
JIANGSU PIONEER TECHNOLOGY CO LTD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU PIONEER TECHNOLOGY CO LTD filed Critical JIANGSU PIONEER TECHNOLOGY CO LTD
Priority to CN202110354311.8A priority Critical patent/CN114571818A/en
Publication of CN114571818A publication Critical patent/CN114571818A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/043—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/09—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/18—Layered products comprising a layer of metal comprising iron or steel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207—Heat-activated adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
    • C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D13/00—Special arrangements or devices in connection with roof coverings; Protection against birds; Roof drainage; Sky-lights
    • E04D13/16—Insulating devices or arrangements in so far as the roof covering is concerned, e.g. characterised by the material or composition of the roof insulating material or its integration in the roof structure
    • E04D13/1687—Insulating devices or arrangements in so far as the roof covering is concerned, e.g. characterised by the material or composition of the roof insulating material or its integration in the roof structure the insulating material having provisions for roof drainage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B37/1207—Heat-activated adhesive
    • B32B2037/1215—Hot-melt adhesive
    • B32B2037/1223—Hot-melt adhesive film-shaped
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • B32B2037/1269—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives multi-component adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/416—Reflective
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/552—Fatigue strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B80/00—Architectural or constructional elements improving the thermal performance of buildings

Abstract

The invention belongs to the technical field of heat insulation materials, and particularly relates to a high-heat-insulation laminated tile and a preparation method thereof. The utility model provides a high heat-proof quality tectorial membrane tile, from the top down includes first composite bed, first adhesive layer, steel deck, second adhesive layer and second composite bed in proper order, first composite bed is including mirror surface aluminium foil layer. The inventor sets up mirror surface aluminium foil layer in this technical scheme, through the effectual sunshine reflection that will shine on the tectorial membrane tile of mirror surface aluminium foil, has improved the heat-proof quality of tectorial membrane tile, can keep lower temperature in the factory building summer, can keep higher temperature in the factory building winter, has saved the power consumption of heating and refrigeration, has saved the energy that the regulation temperature consumes.

Description

High-heat-insulation laminated tile and preparation method thereof
Technical Field
The invention belongs to the technical field of heat insulation materials, and particularly relates to a high-heat-insulation laminated tile and a preparation method thereof.
Background
The most mainstream factory leakage-proof roof material in the market at present is a color steel tile, which is also called a color coating plate, different paint coatings are coated on the surface of a metal substrate by various coating methods to form a paint film so as to protect the metal substrate, and the color coating plate is formed into the color steel tile by cold pressing and bending.
The high-quality color-coated sheet has better performance in all aspects under the environment of dry and non-corrosive gas or liquid, and has longer service life, but the prior color-coated sheet has poorer heat-insulating performance. And when the color-coated sheet is corroded in a long-term humid or corrosive environment, the service time is greatly shortened. This is because the coating film of the color-coated sheet has many pinholes on a microscopic level, and the average diameter of the pinholes is generally 10-1～10-3And mu m. The contact of moisture, oxygen, corrosive ions, etc. with the substrate through the pinholes leads to oxidative corrosion and electrochemical corrosion, the corrosion phenomena of which are particularly pronounced in humid and corrosive environmentsObviously, for example, in coastal environment, chemical plant, steel plant, pickling plant, casting plant, culturing farm, etc., the corrosion rate of the color-coated sheet is greatly increased, and most of the color-coated sheets basically rust and leak water in 1-2 years under the severe environment. The heat resistance and corrosion resistance of the color coated sheet of the factory building are seriously reduced in 1 to 2 years, and the color coated sheet needs to be replaced again, thereby wasting a great deal of resources, expenses, manpower and energy. The present invention is a kind of plant and house facing material with high heat insulating and corrosion resisting performance.
Disclosure of Invention
In order to solve the above technical problems, a first aspect of the present invention provides a high thermal insulation laminated tile, which sequentially comprises, from top to bottom, a first composite layer, a first adhesive layer, a steel plate layer, a second adhesive layer, and a second composite layer, wherein the first composite layer comprises a mirror aluminum foil layer.
Preferably, the first composite layer sequentially comprises a first polymer film layer, a third adhesive layer and a mirror aluminum foil layer from top to bottom, and the second composite layer comprises a second polymer film layer.
Preferably, a first hot melt adhesive film layer is arranged between the first adhesive layer and the steel plate layer, and a second hot melt adhesive film layer is arranged between the second adhesive layer and the steel plate layer.
Preferably, the first polymer film layer and the second polymer film layer are at least one selected from the group consisting of a polyester and modified polyester film, a cellulose film, a polyamide film, a polysulfone film, a polyolefin film, and a polytetrafluoroethylene film.
Preferably, the adhesives of the first adhesive layer, the second adhesive layer and the third adhesive layer are respectively selected from at least one of epoxy resin adhesive, phenolic resin adhesive, polyurethane resin adhesive, polyamide resin adhesive and alpha-cyanoacrylate adhesive.
Preferably, the adhesive of the first adhesive layer is a mixture of an epoxy resin adhesive and a polyamide resin adhesive, and the mass ratio of the epoxy resin adhesive to the polyamide resin adhesive is as follows: (3-5): 1.
preferably, the adhesive of the second adhesive layer is a polyamide resin adhesive.
Preferably, the adhesive of the third adhesive layer is a mixture of a polyurethane resin adhesive and an alpha-cyanoacrylate adhesive, and the mass ratio of the polyurethane resin adhesive to the alpha-cyanoacrylate adhesive is 1: (2-3).
Preferably, the upper side and the lower side of the steel plate layer are both provided with a zinc coating.
The second aspect of the present invention provides a method for preparing a high thermal insulation laminated tile, which at least comprises the following steps:
(1) preparing a first composite layer;
(2) preparing a second composite layer;
(3) and respectively bonding the first composite layer and the second composite layer with the steel plate layer through the first adhesive layer and the second adhesive layer, and carrying out hot pressing to form the steel plate layer so as to obtain the high-heat-insulation laminated tile.
Has the advantages that:
(1) the inventor sets up mirror surface aluminium foil layer in this technical scheme, through the effectual sunshine reflection that will shine on the tectorial membrane tile of mirror surface aluminium foil, has improved the heat-proof quality of tectorial membrane tile, can keep lower temperature in the factory building summer, can keep higher temperature in the factory building winter, has saved the power consumption of heating and refrigeration, has saved the energy that the regulation temperature consumes.
(2) According to the technical scheme, the first polymer film and the second polymer film are respectively arranged in the first composite layer and the second composite layer, so that the corrosion resistance and the weather resistance of the laminated tile are improved, and the service life of the laminated tile is further prolonged.
(3) Through set up first hot melt adhesive film layer between first adhesive layer and steel deck, set up second hot melt adhesive film layer between second adhesive layer and the steel deck, through better laminating nature between steel deck and the hot melt adhesive film layer, prevent during gaseous and liquid enters into the steel sheet, further improved the corrosion resistance of steel sheet in the tectorial membrane tile, guaranteed the long-term good performance of tectorial membrane tile.
(4) The inventor selects different adhesives in the first adhesive layer, the second adhesive layer and the third adhesive layer, so that the bonding performance between the adhesives and different bonding base materials is ensured, and the stability of the laminated tile is improved.
Drawings
Fig. 1 is a schematic view of the entire structure in embodiment 1.
1-a first modified polyester film layer, 2-a third adhesive layer, 3-a mirror aluminum foil layer, 4-a first adhesive layer, 5-a first EVA hot melt adhesive film layer, 6-a galvanized steel sheet layer, 7-a second EVA hot melt adhesive film layer, 8-a second adhesive layer and 9-a second modified polyester film layer.
Detailed Description
For purposes of the following detailed description, it is to be understood that the invention may assume various alternative variations and step sequences, except where expressly specified to the contrary. Moreover, other than in any operating examples, or where otherwise indicated, all numbers expressing, for example, quantities of ingredients used in the specification and claims are to be understood as being modified in all instances by the term "about". Accordingly, unless indicated to the contrary, the numerical parameters set forth in the following specification and attached claims are approximations that may vary depending upon the desired properties to be obtained by the present invention. At the very least, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques.
Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the invention are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the standard deviation found in their respective testing measurements.
When a range of values is disclosed herein, the range is considered to be continuous and includes both the minimum and maximum values of the range, as well as each value between such minimum and maximum values. Further, when a range refers to an integer, each integer between the minimum and maximum values of the range is included. Further, when multiple range-describing features or characteristics are provided, the ranges may be combined. In other words, unless otherwise indicated, all ranges disclosed herein are to be understood to encompass any and all subranges subsumed therein. For example, a stated range from "1 to 10" should be considered to include any and all subranges between the minimum value of 1 and the maximum value of 10. Exemplary subranges of the range 1 to 10 include, but are not limited to, 1 to 6.1, 3.5 to 7.8, 5.5 to 10, and the like.
In order to solve the above technical problems, a first aspect of the present invention provides a high thermal insulation laminated tile, which sequentially comprises, from top to bottom, a first composite layer, a first adhesive layer, a steel plate layer, a second adhesive layer, and a second composite layer, wherein the first composite layer comprises a mirror aluminum foil layer.
Mirror surface aluminium foil layer has higher reflectivity to the sunlight, and the inventor is through setting up mirror surface aluminium foil layer in first composite bed, through the effectual sunshine reflection that will shine on the tectorial membrane tile of mirror surface aluminium foil, improved the heat-proof quality of tectorial membrane tile, can keep lower temperature in the factory building summer, can keep higher temperature in the factory building winter, saved and heated and refrigerated power consumption, saved the energy that the regulating temperature consumes.
As a preferable technical solution, the first composite layer sequentially includes a first polymer film layer, a third adhesive layer and a mirror aluminum foil layer from top to bottom, and the second composite layer includes a second polymer film layer.
As a preferred technical scheme, a first hot melt adhesive film layer is arranged between the first adhesive layer and the steel plate layer, and a second hot melt adhesive film layer is arranged between the second adhesive layer and the steel plate layer.
As a preferred technical scheme, the first hot melt adhesive film layer and the second hot melt adhesive film layer are EVA hot melt adhesive films.
Only the adhesive is used for bonding with the steel plate layer, and because the adhesive can form bubbles and pores in the film forming process, gas or liquid can permeate into the steel plate layer to corrode the steel plate to a certain extent, so that the service life of the steel plate is shortened. The EVA hot-melt adhesive film layer is arranged between the adhesive layer and the steel layer, and has a closed bubble structure, does not absorb water, is moisture-proof, has good water resistance and acid and alkali corrosion resistance, has higher toughness, good shock resistance and buffering performance, and heat insulation performance. Not only can improve the corrosion resistance of the steel plate, but also can improve the weather resistance of the laminated tile, and because the EVA has better toughness and impact resistance, the dimensional stability of the laminated tile can be improved.
In a preferred embodiment, the first polymer film layer and the second polymer film layer are at least one selected from the group consisting of polyester and modified polyester films, cellulose films, polyamide films, polysulfone films, polyolefin films, and polytetrafluoroethylene films.
In a preferred embodiment, the first polymer film layer and the second polymer film layer are made of modified polyester films.
The polyester film has good air tightness, weather resistance, mechanical property, toughness, impact resistance, moisture resistance and lower moisture permeability reduction. The gas and liquid can be effectively prevented from being immersed into the steel plate layer in a humid environment, the corrosion phenomenon of the steel plate layer is effectively prevented, and the service life of the laminated tile is prolonged. The modified polyester film obtained by adding the ultraviolet resistant agent into the polyester further improves the weather resistance of the polyester film and improves the heat insulation property of the laminated tile. The inventor finds that although the alkali resistance of the modified polyester film is poor, the EVA hot melt adhesive film has good acid and alkali resistance, can make up the defects of the modified polyester film, improves the corrosion resistance of the laminated tile, and prolongs the service life of the laminated tile.
As a preferable technical solution, the adhesives of the first adhesive layer, the second adhesive layer and the third adhesive layer are respectively selected from at least one of epoxy resin adhesive, phenolic resin adhesive, polyurethane resin adhesive, polyamide resin adhesive and alpha-cyanoacrylate adhesive.
As a preferred technical solution, the adhesive of the first adhesive layer is a mixture of an epoxy resin adhesive and a polyamide resin adhesive, and the mass ratio between the epoxy resin adhesive and the polyamide resin adhesive is: (3-5): 1.
the epoxy resin adhesive contains various polar groups and epoxy groups with high activity, and can form strong bonding with mirror aluminum foil and EVA hot melt adhesive film, but the inventor finds that when only the epoxy resin adhesive is used, the impact resistance and toughness of the laminated tile are poor. The inventors have unexpectedly found that when a certain amount of a polyamide resin adhesive is mixed in an epoxy resin adhesive, not only the adhesive strength between the adhesive layer and the mirror-surface aluminum foil and EVA can be improved, but also the curing speed of the adhesive layer can be increased, and the toughness of the adhesive layer can be improved. The inventor believes that the possible reason is that the polyamide resin adhesive and the epoxy resin adhesive are crosslinked to form a better three-dimensional crosslinking structure, so that the bonding strength and the toughness of the adhesive layer are improved, and the stability of the laminated tile is further improved. When the amount of the polyamide resin adhesive is too large, the hardness of the adhesive layer is lowered, and when the amount of the polyamide resin adhesive is too small, the toughening effect cannot be obtained.
As a preferable technical solution, the adhesive of the second adhesive layer is a polyamide resin adhesive.
As a preferable technical solution, the adhesive of the third adhesive layer is a mixture of a polyurethane resin adhesive and an α -cyanoacrylate adhesive, and the mass ratio of the polyurethane resin adhesive to the α -cyanoacrylate adhesive is 1: (2-3).
The inventor uses a polyurethane resin adhesive as a main raw material of the third adhesive layer to bond the mirror surface aluminum foil layer and the modified polyester layer, and finds that the polyurethane resin adhesive has good bonding performance with the mirror surface aluminum foil layer, but has poor bonding strength with the modified polyester layer. The inventor thinks that the possible reasons are that the ester group acting force between the modified polyester and the alpha-cyanoacrylate is larger, the bonding strength between the adhesive layer and the modified polyester can be improved, and the bonding strength between the adhesive layer and the mirror aluminum foil layer can be enhanced by more polar groups in the alpha-cyanoacrylate.
As a preferred technical scheme, the upper side and the lower side of the steel plate layer are both provided with a zinc coating.
The galvanized layers are arranged on the upper side and the lower side of the steel plate layer, so that the steel plate can be well prevented from rusting, and the better mechanical property of the steel plate can be kept for a long time.
The second aspect of the present invention provides a method for preparing a high thermal insulation laminated tile, which at least comprises the following steps:
(1) preparing a first composite layer;
(2) preparing a second composite layer;
(3) and respectively bonding the first composite layer and the second composite layer with the steel plate layer through the first adhesive layer and the second adhesive layer, and carrying out hot pressing to form the steel plate layer so as to obtain the high-heat-insulation laminated tile.
In addition, the starting materials used are all commercially available, unless otherwise specified.
Example 1
As shown in fig. 1, the first aspect of the present embodiment provides a laminated tile with high thermal insulation performance, which comprises, from top to bottom, a first modified polyester film layer 1 of 36um, a third adhesive layer 2 of 40um, a mirror aluminum foil layer 3 of 15um, a first adhesive layer 4 of 40um, a first EVA hot melt adhesive film layer 5 of 50um, a galvanized steel plate layer 6 of 500um, a second EVA hot melt adhesive film layer 7 of 50um, a second adhesive layer 8 of 40um, and a second modified polyester film layer 9 of 36um, wherein the modified polyester film is purchased from dupont. The adhesive of the first adhesive layer is a mixture of an epoxy resin adhesive and a polyamide resin adhesive, and the mass ratio of the epoxy resin adhesive to the polyamide resin adhesive is as follows: 3: 1, the epoxy resin adhesive is purchased from a New Material Co., Ltd, from Dongguan city, type: XC-3030, the polyamide resin adhesive is purchased from Virginian adhesive industry, and has the following model: HR-707. The adhesive of the second adhesive layer is a polyamide resin adhesive, and the polyamide resin adhesive is purchased from the hui adhesive industry, and has the following model: HR-707. The adhesive of the third adhesive layer is a mixture of a polyurethane resin adhesive and an alpha-cyanoacrylate adhesive, and the mass ratio of the polyurethane resin adhesive to the alpha-cyanoacrylate adhesive is 1: 2, the polyurethane resin adhesive is purchased from xiao county longpu chemical industry ltd, model: 6181, the alpha-cyanoacrylate adhesive is available from Ming Yu New materials science and technology Limited, Dongguan, model: 431.
in a second aspect of this embodiment, there is provided a method for manufacturing a laminated tile with high thermal insulation, including the steps of:
(1) bonding a first modified polyester film layer 1, a third adhesive layer 2, a mirror aluminum foil layer 3, a first adhesive layer 4 and a first EVA hot melt adhesive film layer 5;
(2) bonding the second EVA hot melt adhesive film layer 7, the second adhesive layer 8 and the second modified polyester film layer 9;
(3) and (3) carrying out hot pressing on the composite layer obtained in the step (1) and the step (2) to form the composite layer, thus obtaining the high-heat-insulation laminated tile.
Example 2
The first aspect of this embodiment provides a high heat-proof quality tectorial membrane tile, from the top down includes the first modified polyester rete of 36um, 40um third adhesive layer, 15um mirror surface aluminium foil layer, the first adhesive layer of 40um, the first EVA hot melt adhesive rete of 50um, 500um galvanized steel sheet layer, 50um second EVA hot melt adhesive rete, 40um second adhesive layer, the modified polyester rete of 36um second in proper order, the modified polyester film is purchased from dupont. The adhesive of the first adhesive layer is a mixture of an epoxy resin adhesive and a polyamide resin adhesive, and the mass ratio of the epoxy resin adhesive to the polyamide resin adhesive is as follows: 5: 1, the epoxy resin adhesive is purchased from a New Material Co., Ltd, from Dongguan city, type: XC-3030, the polyamide resin adhesive is purchased from Virginian adhesive industry, and has the following model: HR-707. The adhesive of the second adhesive layer is a polyamide resin adhesive, and the polyamide resin adhesive is purchased from the hui adhesive industry, and has the following model: HR-707. The adhesive of the third adhesive layer is a mixture of a polyurethane resin adhesive and an alpha-cyanoacrylate adhesive, and the mass ratio of the polyurethane resin adhesive to the alpha-cyanoacrylate adhesive is 1: 2, the polyurethane resin adhesive is purchased from xiao county longpu chemical industry ltd, model: 6181, the alpha-cyanoacrylate adhesive is available from Ming Yu New materials science and technology Limited, Dongguan, model: 431.
a second aspect of this embodiment provides a method for manufacturing a laminated tile with high thermal insulation, comprising at least the steps of:
(1) bonding the first modified polyester film layer, the third adhesive layer, the mirror aluminum foil layer, the first adhesive layer and the first EVA hot melt adhesive film layer;
(2) bonding the second EVA hot-melt adhesive film layer, the second adhesive layer and the second modified polyester film layer;
(3) and (3) carrying out hot pressing on the composite layer obtained in the step (1) and the step (2) to form the composite layer, thus obtaining the high-heat-insulation laminated tile.
Example 3
The first aspect of this embodiment provides a high heat-proof quality tectorial membrane tile, from the top down includes the first modified polyester rete of 36um, 40um third adhesive layer, 15um mirror surface aluminium foil layer, the first adhesive layer of 40um, the first EVA hot melt adhesive rete of 50um, 500um galvanized steel sheet layer, 50um second EVA hot melt adhesive rete, 40um second adhesive layer, the modified polyester rete of 36um second in proper order, the modified polyester film is purchased from dupont. The adhesive of the first adhesive layer is a mixture of an epoxy resin adhesive and a polyamide resin adhesive, and the mass ratio of the epoxy resin adhesive to the polyamide resin adhesive is as follows: 3: 1, the epoxy resin adhesive is purchased from a New Material Co., Ltd, from Dongguan city, type: XC-3030, the polyamide resin adhesive is purchased from Virginian adhesive industry, and has the following model: HR-707. The adhesive of the second adhesive layer is a polyamide resin adhesive, and the polyamide resin adhesive is purchased from the hui adhesive industry, and has the following model: HR-707. The adhesive of the third adhesive layer is a mixture of a polyurethane resin adhesive and an alpha-cyanoacrylate adhesive, and the mass ratio of the polyurethane resin adhesive to the alpha-cyanoacrylate adhesive is 1: 3, the polyurethane resin adhesive is purchased from xiao county longpu chemical industry ltd, model: 6181, the alpha-cyanoacrylate adhesive is available from Ming Yu New materials science and technology Limited, Dongguan, model: 431.
in a second aspect of this embodiment, there is provided a method for manufacturing a laminated tile with high thermal insulation, comprising at least the steps of:
(1) bonding the first modified polyester film layer, the third adhesive layer, the mirror aluminum foil layer, the first adhesive layer and the first EVA hot melt adhesive film layer;
(2) bonding the second EVA hot-melt adhesive film layer, the second adhesive layer and the second modified polyester film layer;
(3) and (3) carrying out hot pressing on the composite layer obtained in the step (1) and the step (2) to form the composite layer, thus obtaining the high-heat-insulation laminated tile.
Example 4
The first aspect of this embodiment provides a high heat-proof quality tectorial membrane tile, from the top down includes the first modified polyester rete of 36um, 40um third adhesive layer, the first adhesive layer of 40um, the first VA hot melt adhesive rete of 50umE, 500um galvanized steel sheet layer, the first EVA hot melt adhesive rete of 50um, 40um second adhesive layer, the modified polyester rete of 36um second in proper order, the modified polyester film is purchased from dupont. The adhesive of the first adhesive layer is a mixture of an epoxy resin adhesive and a polyamide resin adhesive, and the mass ratio of the epoxy resin adhesive to the polyamide resin adhesive is as follows: 3: 1, the epoxy resin adhesive is purchased from a New Material Co., Ltd, from Dongguan city, type: XC-3030, the polyamide resin adhesive is purchased from Virginian adhesive industry, and has the following model: HR-707. The adhesive of the second adhesive layer is a polyamide resin adhesive, and the polyamide resin adhesive is purchased from the hui adhesive industry, and has the following model: HR-707. The adhesive of the third adhesive layer is a mixture of a polyurethane resin adhesive and an alpha-cyanoacrylate adhesive, and the mass ratio of the polyurethane resin adhesive to the alpha-cyanoacrylate adhesive is 1: 2, the polyurethane resin adhesive is purchased from xiao county longpu chemical industry ltd, model: 6181, the alpha-cyanoacrylate adhesive is available from Ming Yu New materials science and technology Limited, Dongguan, model: 431.
in a second aspect of this embodiment, there is provided a method for manufacturing a laminated tile with high thermal insulation, comprising at least the steps of:
(1) bonding the first modified polyester film layer, the third adhesive layer, the mirror aluminum foil layer, the first adhesive layer and the first EVA hot melt adhesive film layer;
(2) bonding the second EVA hot-melt adhesive film layer, the second adhesive layer and the second modified polyester film layer;
(3) and (3) carrying out hot pressing on the composite layer obtained in the step (1) and the step (2) to form the composite layer, thus obtaining the high-heat-insulation laminated tile.
Example 5
The first aspect of this embodiment provides a high heat-proof quality tectorial membrane tile, from the top down includes the first modified polyester rete of 36um, 40um third adhesive layer, 15um mirror surface aluminium foil layer, the first adhesive layer of 40um, the first EVA hot melt adhesive rete of 50um, 500um galvanized steel sheet layer, 50um second EVA hot melt adhesive rete, 40um second adhesive layer, the modified polyester rete of 36um second in proper order, the modified polyester film is purchased from dupont. The adhesive of the first adhesive layer is an epoxy resin adhesive, and the epoxy resin adhesive is obtained from a new material Co., Ltd, available from Xiaochuan of Dongguan city, and has the following model: XC-3030. The adhesive of the second adhesive layer is a polyamide resin adhesive, and the polyamide resin adhesive is purchased from the hui adhesive industry, and has the following model: HR-707. The adhesive of the third adhesive layer is a mixture of a polyurethane resin adhesive and an alpha-cyanoacrylate adhesive, and the mass ratio of the polyurethane resin adhesive to the alpha-cyanoacrylate adhesive is 1: 2, the polyurethane resin adhesive is purchased from xiao county longpu chemical industry ltd, model: 6181, the alpha-cyanoacrylate adhesive is available from Ming Yu New materials science and technology Limited, Dongguan, model: 431.
a second aspect of this embodiment provides a method for manufacturing a laminated tile with high thermal insulation, comprising at least the steps of:
(1) bonding the first modified polyester film layer, the third adhesive layer, the mirror aluminum foil layer, the first adhesive layer and the first EVA hot melt adhesive film layer;
(2) bonding the second EVA hot-melt adhesive film layer, the second adhesive layer and the second modified polyester film layer;
(3) and (3) carrying out hot pressing on the composite layer obtained in the step (1) and the step (2) to form the composite layer, thus obtaining the high-heat-insulation laminated tile.
Example 6
The first aspect of this embodiment provides a high heat-proof quality tectorial membrane tile, from the top down includes the first modified polyester rete of 36um, 40um third adhesive layer, 15um mirror surface aluminium foil layer, the first adhesive layer of 40um, the first EVA hot melt adhesive rete of 50um, 500um galvanized steel sheet layer, 50um second EVA hot melt adhesive rete, 40um second adhesive layer, the modified polyester rete of 36um second in proper order, the modified polyester film is purchased from dupont. The adhesive of the first adhesive layer is a mixture of an epoxy resin adhesive and a polyamide resin adhesive, and the mass ratio of the epoxy resin adhesive to the polyamide resin adhesive is as follows: 3: 1, the epoxy resin adhesive is purchased from a New Material Co., Ltd, from Dongguan city, type: XC-3030, the polyamide resin adhesive is purchased from Virginian adhesive industry, and has the following model: HR-707. The adhesive of the second adhesive layer is a polyamide resin adhesive, and the polyamide resin adhesive is purchased from the hui adhesive industry, and has the following model: HR-707. The adhesive of the third adhesive layer is a polyurethane resin adhesive, and the polyurethane resin adhesive is purchased from xiao county dragon pump chemical industry ltd, model: 6181.
in a second aspect of this embodiment, there is provided a method for manufacturing a laminated tile with high thermal insulation, comprising at least the steps of:
(1) bonding the first modified polyester film layer, the third adhesive layer, the mirror aluminum foil layer, the first adhesive layer and the first EVA hot melt adhesive film layer;
(2) bonding the second EVA hot-melt adhesive film layer, the second adhesive layer and the second modified polyester film layer;
(3) and (3) carrying out hot pressing on the composite layer obtained in the step (1) and the step (2) to form the composite layer, thus obtaining the high-heat-insulation laminated tile.
Example 7
The first aspect of this embodiment provides a high heat-proof quality tectorial membrane tile, from the top down includes the first modified polyester rete of 36um, 40um third adhesive layer, 15um mirror surface aluminium foil layer, the first adhesive layer of 40um, the first EVA hot melt adhesive rete of 50um, 500um galvanized steel sheet layer, 50um second EVA hot melt adhesive rete, 40um second adhesive layer, the modified polyester rete of 36um second in proper order, the modified polyester film is purchased from dupont. The adhesive of the first adhesive layer is a mixture of an epoxy resin adhesive and a polyamide resin adhesive, and the mass ratio of the epoxy resin adhesive to the polyamide resin adhesive is as follows: 3: 0.1, wherein the epoxy resin adhesive is purchased from a New Material Co., Ltd, from Xiaochuan of Dongguan city, and has the model number: XC-3030, the polyamide resin adhesive is purchased from Virginian adhesive industry, and has the following model: HR-707. The adhesive of the second adhesive layer is a polyamide resin adhesive, and the polyamide resin adhesive is purchased from the hui adhesive industry, and has the following model: HR-707. The adhesive of the third adhesive layer is a mixture of a polyurethane resin adhesive and an alpha-cyanoacrylate adhesive, and the mass ratio of the polyurethane resin adhesive to the alpha-cyanoacrylate adhesive is 1: 2, the polyurethane resin adhesive is purchased from xiao county longpu chemical industry ltd, model: 6181, the alpha-cyanoacrylate adhesive is available from Ming Yu New materials science and technology Limited, Dongguan, model: 431.
in a second aspect of this embodiment, there is provided a method for manufacturing a laminated tile with high thermal insulation, comprising at least the steps of:
(1) bonding the first modified polyester film layer, the third adhesive layer, the mirror aluminum foil layer, the first adhesive layer and the first EVA hot melt adhesive film layer;
(2) bonding the second EVA hot-melt adhesive film layer, the second adhesive layer and the second modified polyester film layer;
(3) and (3) carrying out hot pressing on the composite layer obtained in the step (1) and the step (2) to form the composite layer, thus obtaining the high-heat-insulation laminated tile.
Example 8
The first aspect of this embodiment provides a high heat-proof quality tectorial membrane tile, from the top down includes the first modified polyester rete of 36um, 40um third adhesive layer, 15um mirror surface aluminium foil layer, the first adhesive layer of 40um, the first EVA hot melt adhesive rete of 50um, 500um galvanized steel sheet layer, 50um second EVA hot melt adhesive rete, 40um second adhesive layer, the modified polyester rete of 36um second in proper order, the modified polyester film is purchased from dupont. The adhesive of the first adhesive layer is a mixture of an epoxy resin adhesive and a polyamide resin adhesive, and the mass ratio of the epoxy resin adhesive to the polyamide resin adhesive is as follows: 3: 1, the epoxy resin adhesive is purchased from a New Material Co., Ltd, from Dongguan city, type: XC-3030, the polyamide resin adhesive is purchased from Virginian adhesive industry, and has the following model: HR-707. The adhesive of the second adhesive layer is a polyamide resin adhesive, and the polyamide resin adhesive is purchased from the hui adhesive industry, and has the following model: HR-707. The adhesive of the third adhesive layer is a mixture of a polyurethane resin adhesive and an alpha-cyanoacrylate adhesive, and the mass ratio of the polyurethane resin adhesive to the alpha-cyanoacrylate adhesive is 1: 5, the polyurethane resin adhesive is purchased from xiao county longpu chemical industry ltd, model: 6181, the alpha-cyanoacrylate adhesive is available from Ming Yu New materials science and technology Limited, Dongguan, model: 431.
a second aspect of this embodiment provides a method for manufacturing a laminated tile with high thermal insulation, comprising at least the steps of:
(1) bonding the first modified polyester film layer, the third adhesive layer, the mirror aluminum foil layer, the first adhesive layer and the first EVA hot melt adhesive film layer;
(2) bonding the second EVA hot-melt adhesive film layer, the second adhesive layer and the second modified polyester film layer;
(3) and (3) carrying out hot pressing on the composite layer obtained in the step (1) and the step (2) to form the composite layer, thus obtaining the high-heat-insulation laminated tile.
Performance testing
Performance test-referring to the performance test standard of GB 8624-.
Performance test two the thermal conductivity of the coated tiles obtained in examples 1 to 8 was tested with reference to the performance test standard of GB/T10297-.
Performance test three the maximum force value born by the laminated tile span of 800mm obtained in examples 1-8 was tested with reference to the performance test standard of GB/T9341-.
Performance test four the coated tiles obtained in examples 1 to 8 were tested for high temperature resistance at 80 ℃ for 24h, referring to the performance test standard of GB/T22412-2008.
Performance test five the coated tiles obtained in examples 1 to 8 were tested for low temperature resistance at-40 ℃ for 24h, with reference to the performance test standard of GB/T22412-2008.
Performance test six the coated tiles obtained in examples 1 to 8 were tested for acid resistance for 24 hours under 10% acetic acid solution conditions, with reference to the performance test standard of GB/T22412-2008.
Performance test seven the membrane tiles obtained in examples 1 to 8 were tested for alkali resistance for 24 hours in the condition of 10% sodium hydroxide solution, with reference to the performance test standard of GB/T22412-2008.
Performance test eight the impact test of the coated tiles obtained in examples 1 to 8 under the condition of (23 ± 2) ° c, relative humidity (50 ± 10)%, 500g steel ball, 2m drop, was tested with reference to the performance test standard of JG 149-2003.
Performance test nine
The tiles obtained in examples 1-8 were tested for cold and flexural resistance at-10 ℃, 30mm diameter bent plate, 3s bend 90 ℃, according to the performance test criteria of JG/T2251-2014.
Figure BDA0003003199140000121
Figure BDA0003003199140000131
While the invention has been described with reference to the preferred embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention.

Claims (10)

1. The high-heat-insulation laminated tile is characterized by sequentially comprising a first composite layer, a first adhesive layer, a steel plate layer, a second adhesive layer and a second composite layer from top to bottom, wherein the first composite layer comprises a mirror aluminum foil layer.
2. The laminated tile with high thermal insulation of claim 1, wherein the first composite layer comprises a first polymer film layer, a third adhesive layer and a mirror aluminum foil layer from top to bottom, and the second composite layer comprises a second polymer film layer.
3. The high thermal insulation laminated tile according to claim 1, wherein a first hot melt adhesive film layer is arranged between the first adhesive layer and the steel plate layer, and a second hot melt adhesive film layer is arranged between the second adhesive layer and the steel plate layer.
4. The membrane tile as claimed in claim 2, wherein the first and second polymer film layers are at least one selected from polyester and modified polyester films, cellulose films, polyamide films, polysulfone films, polyolefin films and polytetrafluoroethylene films.
5. The high thermal insulation laminated tile according to claim 2, wherein the adhesives of the first adhesive layer, the second adhesive layer and the third adhesive layer are respectively selected from at least one of epoxy resin adhesive, phenolic resin adhesive, polyurethane resin adhesive, polyamide resin adhesive and alpha-cyanoacrylate adhesive.
6. The high thermal insulation laminated tile according to claim 5, wherein the adhesive of the first adhesive layer is a mixture of an epoxy resin adhesive and a polyamide resin adhesive, and the mass ratio of the epoxy resin adhesive to the polyamide resin adhesive is as follows: (3-5): 1.
7. the high insulating laminated tile according to claim 5, wherein the adhesive of the second adhesive layer is a polyamide resin adhesive.
8. The high thermal insulation laminated tile according to claim 5, wherein the adhesive of the third adhesive layer is a mixture of a polyurethane resin adhesive and an alpha-cyanoacrylate adhesive, and the mass ratio of the polyurethane resin adhesive to the alpha-cyanoacrylate adhesive is 1: (2-3).
9. The high thermal insulation laminated tile according to any one of claims 1 to 8, wherein said steel sheet layer is provided with zinc plating layers on both upper and lower sides thereof.
10. A method for manufacturing a high insulating laminated tile according to any one of claims 1 to 9, characterized in that it comprises at least the steps of:
(1) preparing a first composite layer;
(2) preparing a second composite layer;
(3) and respectively bonding the first composite layer and the second composite layer with the steel plate layer through the first adhesive layer and the second adhesive layer, and carrying out hot pressing to form the steel plate layer so as to obtain the high-heat-insulation laminated tile.
CN202110354311.8A 2021-04-01 2021-04-01 High-heat-insulation laminated tile and preparation method thereof Pending CN114571818A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110354311.8A CN114571818A (en) 2021-04-01 2021-04-01 High-heat-insulation laminated tile and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110354311.8A CN114571818A (en) 2021-04-01 2021-04-01 High-heat-insulation laminated tile and preparation method thereof

Publications (1)

Publication Number Publication Date
CN114571818A true CN114571818A (en) 2022-06-03

Family

ID=81768317

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110354311.8A Pending CN114571818A (en) 2021-04-01 2021-04-01 High-heat-insulation laminated tile and preparation method thereof

Country Status (1)

Country Link
CN (1) CN114571818A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1775889A (en) * 2005-12-23 2006-05-24 中冶集团建筑研究总院 Adhesive for slow-binding prestress reinforcement
CN102504708A (en) * 2011-11-07 2012-06-20 北京天山新材料技术股份有限公司 Toughened alpha-cyanoacrylate adhesive and preparation method thereof
CN104403619A (en) * 2014-11-13 2015-03-11 山东华亚环保科技有限公司 Epoxy polyamide adhesive and preparation method thereof
CN110126379A (en) * 2019-04-29 2019-08-16 江苏派恩新型材料有限公司 A kind of precoated metal watt of high-strength and high-weather-resistance
CN209534386U (en) * 2018-10-12 2019-10-25 明冠新材料股份有限公司 A kind of anticorrosive heat insulating film-covered metal plate

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1775889A (en) * 2005-12-23 2006-05-24 中冶集团建筑研究总院 Adhesive for slow-binding prestress reinforcement
CN102504708A (en) * 2011-11-07 2012-06-20 北京天山新材料技术股份有限公司 Toughened alpha-cyanoacrylate adhesive and preparation method thereof
CN104403619A (en) * 2014-11-13 2015-03-11 山东华亚环保科技有限公司 Epoxy polyamide adhesive and preparation method thereof
CN209534386U (en) * 2018-10-12 2019-10-25 明冠新材料股份有限公司 A kind of anticorrosive heat insulating film-covered metal plate
CN110126379A (en) * 2019-04-29 2019-08-16 江苏派恩新型材料有限公司 A kind of precoated metal watt of high-strength and high-weather-resistance

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
"《粘胶修理技术》", 浙江科学技术出版社, pages: 33 - 34 *

Similar Documents

Publication Publication Date Title
JP3228022B2 (en) Composite metal plate and method of manufacturing the same
CN201354917Y (en) Anticorrosive pipe with modified asphalt
CN114571818A (en) High-heat-insulation laminated tile and preparation method thereof
CN208867659U (en) Anticorrosive heat insulating aluminium steel plate
CN210881238U (en) Multi-functional color-coated sheet for building
CN210482597U (en) Heat-insulating and moisture-proof special board
CN205804776U (en) A kind of novel color steel plate
CN106915092A (en) A kind of many lamination composite anti-corrosive techniques
CN110183112B (en) Three-glass two-cavity glass capable of preventing water mist condensation and preparation process thereof
CN113119559A (en) Corrosion-resistant laminated tile and preparation method thereof
CN209176277U (en) A kind of anti-aging composite water-proof coiled material
CN208827251U (en) A kind of Novel roller coating film metal plate
CN209799037U (en) Building wall insulation structure
CN113845812A (en) Environment-friendly heat-insulation wall glaze and preparation method thereof
CN205631571U (en) Silicon various steel sheet of modifying
CN214449127U (en) Anti-aging heat insulation tile
CN110682648A (en) Novel heat-preservation waterproof environment-friendly building material
CN213425002U (en) Metal backboard and photovoltaic component
CN220598769U (en) Waterproof gypsum board
CN213509062U (en) Anti-aging aerated concrete block
CN218894294U (en) Waterproof color steel plate
CN208832745U (en) A kind of boiler insulation board
CN2503143Y (en) Steel-aluminium composite board
CN220923472U (en) Tetrafluoroethylene fluorine diaphragm plate
CN106193461B (en) The excellent roof panels of thermal insulation, roof and building

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination