CN114570333A - Organic constant-pressure deoxidizer - Google Patents

Organic constant-pressure deoxidizer Download PDF

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Publication number
CN114570333A
CN114570333A CN202111586807.4A CN202111586807A CN114570333A CN 114570333 A CN114570333 A CN 114570333A CN 202111586807 A CN202111586807 A CN 202111586807A CN 114570333 A CN114570333 A CN 114570333A
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China
Prior art keywords
deoxidizer
calcium hydroxide
purified water
sodium
sodium bicarbonate
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Pending
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CN202111586807.4A
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Chinese (zh)
Inventor
焦豫东
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Jinan Lanyi Desiccant Co ltd Qihe Branch
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Jinan Lanyi Desiccant Co ltd Qihe Branch
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Priority to CN202111586807.4A priority Critical patent/CN114570333A/en
Publication of CN114570333A publication Critical patent/CN114570333A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3409Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor
    • A23L3/3418Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O
    • A23L3/3427Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of gases, e.g. fumigation; Compositions or apparatus therefor in a controlled atmosphere, e.g. partial vacuum, comprising only CO2, N2, O2 or H2O in which an absorbent is placed or used
    • A23L3/3436Oxygen absorbent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)

Abstract

The invention relates to an organic constant-pressure deoxidizer which consists of purified water, D-sodium erythorbate, baking soda, calcium hydroxide and silicon dioxide. The invention has the following advantages: the same amount of carbon dioxide can be released when oxygen is absorbed and the outer package is not deformed.

Description

Organic constant-pressure deoxidizer
Technical Field
The invention relates to the technical field of deoxidizers, in particular to an organic constant-pressure deoxidizer.
Background
The deoxidizer is also called as an oxygen scavenger, and removes free oxygen in a package or a container through the quick chemical reaction of the deoxidizer and oxygen, so that the stored object is in an anaerobic environment, the harm of aerobic microorganisms and insect pests is inhibited, and the quality oxidation fission is prevented, thereby achieving the purpose of safe storage.
When the existing deoxidizer absorbs oxygen in a packaging bag, the same amount of carbon dioxide cannot be released, so that the deformation of an outer package can be caused, and the use is influenced.
Disclosure of Invention
In order to overcome the defects of the prior art, the invention provides an organic constant pressure deoxidizer to solve the problems in the background art.
In order to achieve the purpose, the technical scheme provided by the invention is as follows: an organic constant pressure deoxidizer comprises purified water, D-sodium erythorbate, sodium bicarbonate, calcium hydroxide and silicon dioxide.
As an improvement: the weight percentages of the raw materials are respectively as follows:
Figure BDA0003428114060000011
the preparation method of the organic constant-pressure deoxidizer comprises the following steps:
s1: taking the raw materials according to the weight percentage, wherein the purified water: 40-60%, sodium D-erythorbate: 10-15%, baking soda: 5-20%, calcium hydroxide: 5-10%, silica: 1 to 5 percent;
s2: mixing silicon dioxide and purified water, stirring to fully dissolve, and uniformly dissolving;
s3: stirring D-sodium erythorbate, calcium hydroxide and sodium bicarbonate until the D-sodium erythorbate, the calcium hydroxide and the sodium bicarbonate are fully mixed;
s4: the materials obtained in the above steps S2 and S3 were mixed to prepare the oxygen scavenger disclosed in the present invention.
After the technical scheme is adopted, the invention has the beneficial effects that: the same amount of carbon dioxide can be released when oxygen is absorbed and the outer package is not deformed.
Detailed Description
The present invention will be described in further detail with reference to examples.
Example 1: an organic constant pressure deoxidizer comprises purified water, D-sodium erythorbate, sodium bicarbonate, calcium hydroxide and silicon dioxide.
The weight percentages of the raw materials are respectively as follows:
Figure BDA0003428114060000021
the invention also discloses a preparation method of the deoxidizer, which comprises the following steps:
s1: taking the raw materials according to the weight percentage, wherein the purified water: 40%, sodium D-erythorbate: 10%, baking soda: 5%, calcium hydroxide: 5%, silica: 1 percent;
s2: mixing silicon dioxide with purified water, stirring to dissolve completely, and making concentration uniform;
s3: stirring D-sodium erythorbate, calcium hydroxide and sodium bicarbonate until the D-sodium erythorbate, the calcium hydroxide and the sodium bicarbonate are fully mixed;
s4: the materials obtained in the above steps S2 and S3 were mixed to prepare the oxygen scavenger disclosed in the present invention.
In summary, the organic constant pressure deoxidizer provided by the above embodiment of the invention adopts D-sodium erythorbate as a main component, and additionally, calcium hydroxide, sodium bicarbonate and silicon dioxide are added and dissolved in purified water, wherein the purified water is an electrolyte, the silicon dioxide is a water retention agent, and the calcium hydroxide and the sodium bicarbonate have the function of adjusting the PH value.
In this embodiment of the present invention, before deoxidation with the deoxidizer, the initial oxygen concentration was 25%, the carbon dioxide was 1.7%, and after 15 days of deoxidation the oxygen concentration was 2%, and the carbon dioxide was 24.7%. Therefore, the carbon dioxide with about the same quantity can be released while oxygen is absorbed, the gas balance is achieved, and the shrinkage deformation of a packaged container and the influence on the appearance of food are effectively prevented. In addition, the deoxidizer has the non-metal characteristic due to the low metal content in the raw materials, so that the deoxidizer can be detected through metal, food containing the deoxidizer in the package can be detected through the metal, the food containing the deoxidizer does not need to be unsealed and checked, and the passing efficiency is improved.
Example 2: an organic constant pressure deoxidizer comprises purified water, D-sodium erythorbate, sodium bicarbonate, calcium hydroxide and silicon dioxide.
The weight percentages of the raw materials are respectively as follows:
Figure BDA0003428114060000022
Figure BDA0003428114060000031
the invention also discloses a preparation method of the deoxidizer, which comprises the following steps:
s1: taking the raw materials according to the weight percentage, wherein the purified water: 50%, sodium D-erythorbate: 13%, sodium bicarbonate: 10%, calcium hydroxide: 7%, silica: 3 percent;
s2: mixing silicon dioxide with purified water, stirring to dissolve completely, and making concentration uniform;
s3: stirring D-sodium erythorbate, calcium hydroxide and sodium bicarbonate until the D-sodium erythorbate, the calcium hydroxide and the sodium bicarbonate are fully mixed;
s4: the materials obtained in the above steps S2 and S3 were mixed to prepare the oxygen scavenger disclosed in the present invention.
In summary, the organic constant pressure deoxidizer provided by the above embodiment of the invention adopts D-sodium erythorbate as a main component, and additionally, calcium hydroxide, sodium bicarbonate and silicon dioxide are added and dissolved in purified water, wherein the purified water is an electrolyte, the silicon dioxide is a water retention agent, and the calcium hydroxide and the sodium bicarbonate have the function of adjusting the PH value.
In this embodiment of the present invention, before deoxidation with the deoxidizer, the initial oxygen concentration was 21.4%, the carbon dioxide was 2.1%, and after 15 days of deoxidation the oxygen concentration became 2.3%, and the carbon dioxide was 21.2%. Therefore, approximately equal amount of carbon dioxide can be released while oxygen is absorbed, so that gas balance is achieved, and the packaged container is effectively prevented from shrinking and deforming and affecting the appearance of food. In addition, the deoxidizer has the non-metal characteristic due to the low metal content in the raw materials, so that the deoxidizer can be detected through metal, food containing the deoxidizer in the package can be detected through the metal, the food containing the deoxidizer does not need to be unsealed and checked, and the passing efficiency is improved.
Example 3: an organic constant pressure deoxidizer comprises purified water, D-sodium erythorbate, sodium bicarbonate, calcium hydroxide and silicon dioxide.
The weight percentages of the raw materials are respectively as follows:
Figure BDA0003428114060000032
the invention also discloses a preparation method of the deoxidizer, which comprises the following steps:
s1: taking the raw materials according to the weight percentage, wherein the purified water: 60%, sodium D-erythorbate: 15%, baking soda: 20%, calcium hydroxide: 10%, silica: 5 percent;
s2: mixing silicon dioxide with purified water, stirring to dissolve completely, and making concentration uniform;
s3: stirring D-sodium erythorbate, calcium hydroxide and sodium bicarbonate until the D-sodium erythorbate, the calcium hydroxide and the sodium bicarbonate are fully mixed;
s4: the materials obtained in the above steps S2 and S3 were mixed to prepare the oxygen scavenger disclosed in the present invention.
In summary, the organic constant pressure deoxidizer provided by the above embodiment of the invention adopts D-isoascorbic acid sodium as a main component, and further includes calcium hydroxide, sodium bicarbonate, and silicon dioxide, which are dissolved in purified water, wherein the purified water is an electrolyte, the silicon dioxide is a water retention agent, and the calcium hydroxide and the sodium bicarbonate have the function of adjusting the PH value.
In this embodiment of the present invention, before deoxidation with the deoxidizer, the initial oxygen concentration was 22.8%, the carbon dioxide was 1.3%, and after 15 days of deoxidation the oxygen concentration became 1%, and the carbon dioxide was 22%. Therefore, the carbon dioxide with about the same quantity can be released while oxygen is absorbed, the gas balance is achieved, and the shrinkage deformation of a packaged container and the influence on the appearance of food are effectively prevented. In addition, the content of the metal in the raw materials is less, so that the deoxidizer has non-metal characteristics, and therefore, the deoxidizer can pass metal detection, so that the food containing the deoxidizer in the package can pass the metal detection, the unsealing inspection is not needed, and the passing efficiency is improved.
While the foregoing specification illustrates and describes the preferred embodiments of this invention, it is to be understood that the invention is not limited to the forms disclosed herein, but is not to be construed as limited to other embodiments, and is capable of use in various other combinations, modifications, and environments and is capable of changes within the scope of the inventive concept as expressed herein, commensurate with the above teachings, or the skill or knowledge of the relevant art. And that modifications and variations may be effected by those skilled in the art without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (2)

1. An organic constant pressure deoxidizer is characterized in that: consists of purified water, D-sodium erythorbate, sodium bicarbonate, calcium hydroxide and silicon dioxide.
2. The organic constant pressure deoxidizer of claim 1, which is characterized in that: the weight percentages of the raw materials are respectively as follows:
Figure FDA0003428114050000011
CN202111586807.4A 2021-12-23 2021-12-23 Organic constant-pressure deoxidizer Pending CN114570333A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115444089A (en) * 2022-09-15 2022-12-09 广东胜和发智能科技有限公司 Antibacterial constant-pressure deoxidizer and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102807036A (en) * 2011-06-03 2012-12-05 王代梅 Device and method for protecting clothing made of natural fiber such as wool, leather and silk against mildew and moths and moth eggs
CN109588611A (en) * 2018-11-20 2019-04-09 东莞市欣荣天丽科技实业有限公司 A kind of edible oxygen absorber composition and deoxidant packing body
CN113632908A (en) * 2021-08-06 2021-11-12 广东广益科技实业有限公司 Alcohol preservation card with deoxidation function and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102807036A (en) * 2011-06-03 2012-12-05 王代梅 Device and method for protecting clothing made of natural fiber such as wool, leather and silk against mildew and moths and moth eggs
CN109588611A (en) * 2018-11-20 2019-04-09 东莞市欣荣天丽科技实业有限公司 A kind of edible oxygen absorber composition and deoxidant packing body
CN113632908A (en) * 2021-08-06 2021-11-12 广东广益科技实业有限公司 Alcohol preservation card with deoxidation function and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115444089A (en) * 2022-09-15 2022-12-09 广东胜和发智能科技有限公司 Antibacterial constant-pressure deoxidizer and preparation method and application thereof

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Application publication date: 20220603

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