CN114521175A - 具有其中加入了包含紫外线墨的织物的聚乙烯醇缩丁醛层的层压玻璃板 - Google Patents
具有其中加入了包含紫外线墨的织物的聚乙烯醇缩丁醛层的层压玻璃板 Download PDFInfo
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Abstract
本发明涉及一种层压玻璃板,其至少包括第一和第二玻璃片,通过聚乙烯醇缩丁醛(PVB)的粘合夹层粘合,在该粘合夹层中加入了织物,其特征在于,该织物包含紫外线(UV)墨;涉及一种制造这种层压玻璃板的方法及其在车辆、在建筑、在城市家具、在室内设计或在家用电器中的应用。
Description
本发明涉及一种发光层压玻璃板,例如用于汽车(车顶、挡风玻璃、后窗、侧玻璃板)或建筑(温室、正面)。所述玻璃板或者包括由图案组成的发光装饰,或者是在其整个表面上。在适当的情况下,图案只是装饰性的,或者描述了商标、标识,或者提供关于层压玻璃板的技术特征的信息,或者是建筑应用,例如在机场、火车站中的路径指示,或指示办公室中的人数等。
其中加入了发光二极管(LED)的发光层压玻璃板,尤其是作为汽车车顶,是众所周知的,但这种技术呈现出对于装饰、外观和提供信息的必然受限的可能性。
发明人已经试图拓宽对于可以由发光层压玻璃板提供的美学外观和信息的可能性。他们已通过本发明实现了这一目标,因此,本发明的主题是一种发光层压玻璃板,其至少包括第一和第二块玻璃片,该玻璃板通过聚乙烯醇缩丁醛(PVB)的粘合夹层粘合,在该粘合夹层中加入了织物,其特征在于,所述织物包括墨,所述墨在产生紫外线(UV)辐射的灯的照射下发光。
玻璃片由无机玻璃制成,这些无机玻璃例如是浮法玻璃、钠钙玻璃、铝硅酸盐玻璃、硼硅酸盐玻璃等,它们是任选地热钢化的,化学增强的。紫外(UV)墨是在产生紫外线辐射的灯的照射下发光的墨。
层压玻璃板至少包括第一和第二玻璃片,即不打算从本发明中排除包含多于两个玻璃片的任何层压结构,两个这样的相邻玻璃片通过PVB层粘合。
在根据本发明的变体中,光纤加入到粘合夹层中。通过将某些光纤连接到具有特定颜色的照射,并且任选地将其他光纤连接到具有另一种颜色的照射,所提供的美学效果被显著拓宽。
然后,织物本身可以包括光纤,该光纤或者加入到织物中,构成所述织物的至少一部分纤维为光纤,或者通过粘合剂粘合或一些其他工艺固定到织物表面。
在本发明的一个有利实施方案中,所述第一和第二玻璃片中的一个具有功能层或功能层堆栈。这可以是薄膜(从几纳米到几十纳米厚)或薄膜堆栈,例如在减压下通过磁控管阴极溅射产生的,例如热控制堆栈,例如太阳能保护或低发射堆栈。另一方面,可提及厚度最高几微米的层,例如通过液体沉积、溶胶-凝胶沉积、化学气相沉积(CVD)产生的层,例如疏水的、亲水的、有色的、光催化自清洁的(TiO2锐钛矿)层等。
然后,所述第一和第二玻璃片的另一个有利地具有搪瓷,例如黑色搪瓷,尤其是在外围条中,以便将玻璃板的胶线隐藏在其安装环境中(例如车身)。这种搪瓷可以通过例如丝网印刷的印刷工艺生产。
本发明的另一个主题由一种生产上述发光层压玻璃板的方法组成,其特征在于,在两个PVB层之间安置织物,该织物包含墨,该墨在产生紫外线辐射的灯的照射下发光,特征在于这样获得的组件安置在至少第一和第二玻璃片之间,然后特征在于通过使这些要素温度升高和压力升高或降低来进行层压。两个PVB层及其之间放置的织物安置在至少第一和第二个玻璃片之间意指一个或多个其他玻璃片可以组装到这两个前片上,应理解,组件中的每对相邻玻璃片包括PVB夹层,其在层压后提供整个层压玻璃板的结合力。
优选地,通过丝网印刷、喷墨印刷、移印、胶印、柔版印刷或任何其他印刷工艺通过用在产生紫外线辐射的灯的照射下发光的墨印刷,或通过任何液体沉积工艺,如旋涂、喷涂、幕涂等沉积在产生紫外线辐射的灯的照射下发光的墨的层预先获得含有这种墨的织物。
本发明的另一个主题是上述层压玻璃板在陆地、汽车、铁路、水中或空中运输车辆、在建筑、在城市家具、在室内设计或家用电器中的应用,尤其是作为车顶。
现在下面的示例性实施方式说明了本发明。
实施例
采用任何合适的技术,使用UV墨印刷不同的织物样品。在该印刷之前,一些织物包括浮雕图案或纹理图案。UV墨印刷精确应用于这些图案中的一些,但不应用于其他没有UV墨的图案,以及在另一侧,UV墨印刷应用于这些图案的外部。
这些印刷织物样品中的几个样品分别放置在两个0.38 mm厚的PVB片之间,然后将由此获得的组件放置在两个2.1 mm厚的透明玻璃片之间,该透明玻璃片由圣戈班玻璃公司以注册商标Planiclear®出售。
朝向两块玻璃片中第一块的层压结构内部的面旨在在组装位置朝向汽车外部,并具有黑色搪瓷框架作为外围条。朝向另一(第二)玻璃片的层压结构内部的面旨在在组装位置朝向汽车乘客舱,并涂有低发射(low-e)或太阳能保护薄膜的堆栈,其包括几个银薄膜,这取决于样品而定。
通过在炉中执行第一循环来进行层压,包括在真空下(相对于大气压力降低压力)放置,在30°C下加热并保持,在120°C下加热并保持,将温度降低至75°C并停止真空,然后在高压釜中进行第二循环,包括将温度升高至140°C,将压力升高并保持在11.5巴,将温度降低至50°C,以及返回大气压力。其他层压条件是可能的,这在本技术领域是众所周知的。
观察到层压没有影响织物的浮雕图案或纹理图案,无论是在其轮廓或界限上,还是在其浮雕外观上。
然后将层压玻璃板样品暴露在紫外线辐射下的照射下。观察到使用UV墨印刷的织物的那些浮雕或纹理图案根据墨仔细放置其上的初始图案的精确轮廓发光。因此,在层压操作之后没有观察到墨的迁移。
此外,在织物的浮雕或纹理图案外部上的UV墨印刷上,观察到初始印刷的图案被保持了,印刷的图案具有出色的清晰度和分辨率,这与文本(例如用于信息或安全通知的文本)的印刷兼容。
Claims (9)
1.发光层压玻璃板,其至少包括第一和第二玻璃片,通过聚乙烯醇缩丁醛(PVB)的粘合夹层粘合,在所述粘合夹层中加入了织物,其特征在于,所述织物包括墨,该墨在产生紫外线(UV)辐射的灯的照射下发光。
2.根据权利要求1所述的层压玻璃板,其特征在于,所述光纤加入到所述粘合夹层中。
3.根据权利要求2所述的层压玻璃板,其特征在于,所述织物包括光纤。
4.根据前述权利要求任一项所述的层压玻璃板,其特征在于,所述第一和第二玻璃片中的一个具有功能层或功能层堆栈。
5.根据权利要求4所述的层压玻璃板,其特征在于,所述第一和第二玻璃片中的另一个具有搪瓷。
6.用于生产根据前述权利要求任一项所述的发光层压玻璃板的方法,其特征在于,在两个PVB层之间安置织物,该织物包含墨,该墨在产生紫外线辐射的灯的照射下发光,特征在于这样获得的组件安置在至少第一和第二玻璃片之间,然后特征在于通过使这些要素温度升高和压力升高或降低来进行层压。
7.根据权利要求6所述的方法,其特征在于,通过丝网印刷、喷墨印刷、移印、胶印或柔版印刷通过用在产生紫外线辐射的灯的照射下发光的墨印刷,或通过任何液体沉积工艺,如旋涂、喷涂或幕涂沉积在产生紫外线辐射的灯的照射下发光的墨的层预先获得含有这种墨的织物。
8.根据权利要求1至5任一项所述的层压玻璃板在陆地、汽车、铁路、水中或空中运输车辆、在建筑、在城市家具、在室内设计或在家用电器中的应用。
9.根据权利要求8所述的应用,该应用是作为汽车车顶。
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FR2008750A FR3113674A1 (fr) | 2020-08-27 | 2020-08-27 | Vitrage feuilleté ayant une couche de polyvinylbutyral dans laquelle est intégré un tissu comportant une encre ultraviolet |
FR2008750 | 2020-08-27 | ||
PCT/FR2021/051470 WO2022043630A1 (fr) | 2020-08-27 | 2021-08-17 | Vitrage feuillete ayant une couche de polyvinylbutyral dans laquelle est integre un tissu comportant une encre ultraviolet |
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Publication number | Priority date | Publication date | Assignee | Title |
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US6113861A (en) * | 1996-07-02 | 2000-09-05 | Tao, Inc. | Photocatalyst sheet |
RU2416529C1 (ru) * | 2010-04-30 | 2011-04-20 | Елена Юрьевна Кутузова | Способ получения декоративного покрытия, содержащего люминофоры (варианты) |
CN107074148A (zh) * | 2015-09-11 | 2017-08-18 | 法国圣戈班玻璃厂 | 运输工具的发光窗玻璃及其制造 |
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FR2909159A1 (fr) * | 2006-11-24 | 2008-05-30 | Alstom Transport Sa | Composant d'eclairage |
FR2914070B1 (fr) * | 2007-03-23 | 2009-05-08 | Saint Gobain | Dispositif de visualisation tete haute. |
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2020
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Publication number | Priority date | Publication date | Assignee | Title |
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US6113861A (en) * | 1996-07-02 | 2000-09-05 | Tao, Inc. | Photocatalyst sheet |
RU2416529C1 (ru) * | 2010-04-30 | 2011-04-20 | Елена Юрьевна Кутузова | Способ получения декоративного покрытия, содержащего люминофоры (варианты) |
CN107074148A (zh) * | 2015-09-11 | 2017-08-18 | 法国圣戈班玻璃厂 | 运输工具的发光窗玻璃及其制造 |
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