CN114517039A - Novel cold-heat-resistant impact-resistant coating and preparation method thereof - Google Patents

Novel cold-heat-resistant impact-resistant coating and preparation method thereof Download PDF

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Publication number
CN114517039A
CN114517039A CN202210321971.0A CN202210321971A CN114517039A CN 114517039 A CN114517039 A CN 114517039A CN 202210321971 A CN202210321971 A CN 202210321971A CN 114517039 A CN114517039 A CN 114517039A
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Prior art keywords
parts
agent
stirring
resistant coating
novel cold
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CN202210321971.0A
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Chinese (zh)
Inventor
林汉新
林炜凯
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Foshan Shunde District Gudeli Paint Co ltd
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Foshan Shunde District Gudeli Paint Co ltd
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Priority to CN202210321971.0A priority Critical patent/CN114517039A/en
Publication of CN114517039A publication Critical patent/CN114517039A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a novel cold-heat-impact-resistant paint which relates to the technical field of paints and comprises the following raw materials in parts by mass: 25-35 parts of acrylic resin, 0.5 part of dispersing agent, 0.5 part of rheological agent, 26-32 parts of titanium dioxide, 5-10 parts of magnesium strong powder, 2 parts of anti-rolling agent, 1 part of wetting agent, 1-5 parts of modified resin, 1 part of defoaming agent, 1 part of dehydrating agent and 6-12 parts of diluting agent.

Description

Novel cold-heat-impact-resistant paint and preparation method thereof
Technical Field
The invention relates to the technical field of coatings, in particular to a novel cold-heat-resistant impact-resistant coating and a preparation method thereof.
Background
The PU coating is mainly used for coating on the surface of a protected or decorated object, and can form a film under certain conditions to play a role in protecting, decorating, insulating, preventing rust, preventing mildew, resisting heat and other liquid or solid materials.
The existing PU coating has hard and brittle paint film due to insufficient glass transition temperature of acrylic acid or polyurethane resin, and paint film cracking, damage to struck objects or knocking of sports equipment or other products and the like can be easily caused due to inconsistent expansion and contraction rate with a substrate under extremely low temperature or high temperature.
Therefore, a solution is urgently needed.
Disclosure of Invention
The invention aims to provide a novel cold-heat-resistant impact-resistant coating and a preparation method thereof, so as to solve the defects in the background technology.
In order to achieve the purpose, the technical scheme of the invention is as follows:
the novel cold-heat impact-resistant coating comprises the following raw materials in parts by mass: 25-35 parts of acrylic resin, 0.5 part of dispersing agent, 0.5 part of rheological agent, 26-32 parts of titanium dioxide, 5-10 parts of magnesium powder, 2 parts of anti-rolling agent, 1 part of wetting agent, 1-5 parts of modified resin, 1 part of defoaming agent, 1 part of dehydrating agent and 6-12 parts of diluting agent.
Further, the coating comprises the following raw materials in parts by mass: 35 parts of acrylic resin, 0.5 part of dispersing agent, 0.5 part of rheological agent, 32 parts of titanium dioxide, 10 parts of magnesium powder, 2 parts of anti-rolling agent, 1 part of wetting agent, 5 parts of modified resin, 1 part of defoaming agent, 1 part of dehydrating agent and 12 parts of diluting agent.
Further, the acrylic resin is C-305 acrylic resin.
Further, the titanium dioxide is R-706 titanium dioxide.
Furthermore, 8500 magnesium strong powder is adopted as the magnesium strong powder.
Further, the modified resin is C-94PE modified resin.
Further, the diluent is C-PU153 diluent.
In order to further achieve the purpose, the invention also provides the following technical scheme:
a preparation method of a novel cold-heat impact resistant coating comprises the following steps:
s1, weighing 25-35 parts of acrylic resin and 0.5 part of dispersing agent, adding 0.5 part of rheological agent, and uniformly stirring;
s2: after stirring, adding 26-32 parts of titanium dioxide and 5-10 parts of magnesium strong powder, and continuously mixing and stirring for 20-30 minutes by using a high-speed stirrer;
s3: after stirring, uniformly stirring, grinding for 2-3 times to about 15 micrometers in a sand mill, taking out, cooling to normal temperature, and uniformly stirring;
s4: and then adding 2 parts of anti-rolling agent, 1 part of wetting agent and 1 part of dehydrating agent, uniformly stirring by using a high-speed stirrer, adding 1-5 parts of modified resin, mixing and stirring for 10 minutes, adding 6-12 parts of diluent, stirring and mixing for 10 minutes to obtain the novel cold-heat-shock-resistant coating.
The novel cold-heat impact resistant coating and the preparation method thereof have the beneficial effects that: the novel cold-heat-shock-resistant paint prepared from the raw materials effectively improves the structural strength of the paint sprayed on an object by controlling the content of titanium dioxide and magnesium powder, has strong shock resistance, resists severe environments such as high temperature and cold, prolongs the service life of the object after the paint is sprayed, and effectively solves the defects existing in the background technology.
Drawings
FIG. 1 is a graph of experimental results of a shot test;
FIG. 2 is a graph of experimental results of a shot test;
FIG. 3 is a graph showing experimental results of a thermal shock test of three examples;
FIG. 4 is a diagram showing experimental results of a cold and hot impact test of similar products;
figure 5 is a quality detection report for three embodiments.
Detailed Description
Example one
The novel cold-heat impact-resistant coating comprises the following raw materials in parts by mass: 25 parts of acrylic resin, 0.5 part of dispersing agent, 0.5 part of rheological agent, 26 parts of titanium dioxide, 5 parts of magnesium powder, 2 parts of anti-rolling agent, 1 part of wetting agent, 1 part of modified resin, 1 part of defoaming agent, 1 part of dehydrating agent and 6 parts of diluting agent.
Further, the acrylic resin is C-305 acrylic resin.
Further, the titanium dioxide is R-706 titanium dioxide.
Furthermore, 8500 magnesium strong powder is adopted as the magnesium strong powder.
Further, the modified resin is C-94PE modified resin.
Further, the diluent is C-PU153 diluent.
Further, the defoaming agent adopts a C-530 defoaming agent.
Further, the dehydrating agent is N-F51 dehydrating agent.
Further, the dispersant is C-8021 dispersant.
The novel cold-heat impact-resistant paint is prepared by the following preparation method:
s1, weighing 25 parts of acrylic resin and 0.5 part of dispersing agent, adding 0.5 part of rheological agent, and uniformly stirring;
s2: after stirring, adding 26 parts of titanium dioxide and 5 parts of magnesium strong powder, and continuously mixing and stirring for 20-30 minutes by using a high-speed stirrer;
s3: after stirring, uniformly stirring, grinding for 2-3 times to about 15 micrometers in a sand mill, taking out, cooling to normal temperature, and uniformly stirring;
s4: and then adding 2 parts of anti-rolling agent, 1 part of wetting agent and 1 part of dehydrating agent, uniformly stirring by using a high-speed stirrer, adding 1 part of modified resin, mixing and stirring for 10 minutes, adding 6 parts of diluent, stirring and mixing for 10 minutes to obtain the novel cold-heat-impact-resistant coating.
Example two
The novel cold-heat impact-resistant coating comprises the following raw materials in parts by mass: 30 parts of acrylic resin, 0.5 part of dispersing agent, 0.5 part of rheological agent, 28 parts of titanium dioxide, 8 parts of magnesium powder, 2 parts of anti-rolling agent, 1 part of wetting agent, 3 parts of modified resin, 1 part of defoaming agent, 1 part of dehydrating agent and 9 parts of diluting agent.
Further, the acrylic resin is C-305 acrylic resin.
Further, the titanium dioxide is R-706 titanium dioxide.
Furthermore, 8500 magnesium strong powder is adopted as the magnesium strong powder.
Further, the modified resin is C-94PE modified resin.
Further, the diluent is C-PU153 diluent.
Further, the defoaming agent adopts a C-530 defoaming agent.
Further, the dehydrating agent is N-F51 dehydrating agent.
Further, the dispersant is C-8021 dispersant.
The novel cold-heat impact resistant coating is prepared by the following preparation method:
s1, weighing 30 parts of acrylic resin and 0.5 part of dispersing agent, adding 0.5 part of rheological agent, and uniformly stirring;
s2: after stirring, adding 28 parts of titanium dioxide and 5 parts of magnesium strong powder, and continuously mixing and stirring for 20-30 minutes by using a high-speed stirrer;
s3: after stirring, uniformly stirring, grinding for 2-3 times to about 15 micrometers in a sand mill, taking out, cooling to normal temperature, and uniformly stirring;
s4: and then adding 2 parts of anti-rolling agent, 1 part of wetting agent and 1 part of dehydrating agent, uniformly stirring by using a high-speed stirrer, adding 3 parts of modified resin, mixing and stirring for 10 minutes, adding 9 parts of diluent, stirring and mixing for 10 minutes to obtain the novel cold-heat-impact-resistant coating.
EXAMPLE III
The novel cold-heat impact-resistant coating comprises the following raw materials in parts by mass: 35 parts of acrylic resin, 0.5 part of dispersing agent, 0.5 part of rheological agent, 32 parts of titanium dioxide, 10 parts of magnesium powder, 2 parts of anti-rolling agent, 1 part of wetting agent, 5 parts of modified resin, 1 part of defoaming agent, 1 part of dehydrating agent and 12 parts of diluting agent.
Further, the acrylic resin is C-305 acrylic resin.
Further, the titanium dioxide is R-706 titanium dioxide.
Furthermore, 8500 magnesium strong powder is adopted as the magnesium strong powder.
Further, the modified resin adopts C-94PE modified resin.
Further, the diluent is C-PU153 diluent.
Further, the defoaming agent adopts a C-530 defoaming agent.
Further, the dehydrating agent is N-F51 dehydrating agent.
Further, the dispersant is C-8021 dispersant.
The novel cold-heat impact resistant coating is prepared by the following preparation method:
s1, weighing 35 parts of acrylic resin and 0.5 part of dispersing agent, adding 0.5 part of rheological agent, and uniformly stirring;
s2: after stirring, adding 32 parts of titanium dioxide and 10 parts of magnesium strong powder, and continuously mixing and stirring for 20-30 minutes by using a high-speed stirrer;
s3: after stirring, uniformly stirring, grinding for 2-3 times to about 15 micrometers in a sand mill, taking out, cooling to normal temperature, and uniformly stirring;
s4: and then adding 2 parts of anti-rolling agent, 1 part of wetting agent and 1 part of dehydrating agent, uniformly stirring by using a high-speed stirrer, adding 5 parts of modified resin, mixing and stirring for 10 minutes, adding 9 parts of diluent, stirring and mixing for 10 minutes to obtain the novel cold-heat-impact-resistant coating.
Experimental test data: the test experiment selects the common similar products on the market and the three embodiments of the invention for test comparison.
Referring to fig. 1-4, the test environment conditions in fig. 1 are as follows: different aluminum pipes or carbon pipes are prepared, the aluminum pipes are adopted in the experiment, the 4 coatings are sprayed on the different aluminum pipes, after the coatings on the aluminum pipes are completely dried, the spraying condition, the impact resistance and the paint surface cracking condition of the aluminum pipes are observed and compared, and specific experimental results can be seen in figure 1.
In conclusion, the novel cold-heat-shock-resistant paint prepared from the raw materials effectively improves the structural strength of the paint sprayed on an object by controlling the content of the titanium dioxide and the content of the magnesium strong powder, has strong shock resistance, resists severe environments such as high temperature and cold, prolongs the service life of the object after the paint is sprayed, and effectively solves the defects in the background technology.
Variations and modifications to the above-described embodiments may occur to those skilled in the art, which fall within the scope and spirit of the above description. Therefore, the present invention is not limited to the specific embodiments disclosed and described above, and some modifications and variations of the present invention should fall within the scope of the claims of the present invention. Furthermore, although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.

Claims (8)

1. The novel cold-heat impact-resistant coating is characterized by comprising the following raw materials in parts by mass: 25-35 parts of acrylic resin, 0.5 part of dispersing agent, 0.5 part of rheological agent, 26-32 parts of titanium dioxide, 5-10 parts of magnesium powder, 2 parts of anti-rolling agent, 1 part of wetting agent, 1-5 parts of modified resin, 1 part of defoaming agent, 1 part of dehydrating agent and 6-12 parts of diluting agent.
2. The novel cold-heat impact resistant coating as claimed in claim 1, which is characterized by comprising the following raw materials in parts by mass: 35 parts of acrylic resin, 0.5 part of dispersing agent, 0.5 part of rheological agent, 32 parts of titanium dioxide, 10 parts of magnesium powder, 2 parts of anti-rolling agent, 1 part of wetting agent, 5 parts of modified resin, 1 part of defoaming agent, 1 part of dehydrating agent and 12 parts of diluting agent.
3. The novel coating of claim 1, wherein the acrylic resin is a C-305 acrylic resin.
4. The novel paint with cold and hot impact resistance as claimed in claim 1, wherein R-706 titanium dioxide is adopted as the titanium dioxide.
5. The novel cold-hot impact-resistant coating according to claim 1, wherein 8500 magnesium-strength powder is adopted as the magnesium-strength powder.
6. The novel cold-hot impact-resistant coating according to claim 1, wherein the modified resin is a C-94PE modified resin.
7. The novel cold-heat impact resistant coating according to claim 1, wherein the diluent is a C-PU153 diluent.
8. A preparation method of a novel cold-heat impact resistant coating is characterized by comprising the following steps:
s1, weighing 25-35 parts of acrylic resin and 0.5 part of dispersing agent, adding 0.5 part of rheological agent, and uniformly stirring;
s2: after stirring, adding 26-32 parts of titanium dioxide and 5-10 parts of magnesium strong powder, and continuously mixing and stirring for 20-30 minutes by using a high-speed stirrer;
s3: after stirring, uniformly stirring, grinding for 2-3 times to about 15 micrometers in a sand mill, taking out, cooling to normal temperature, and uniformly stirring;
s4: and then adding 2 parts of anti-rolling agent, 1 part of wetting agent and 1 part of dehydrating agent, uniformly stirring by using a high-speed stirrer, adding 1-5 parts of modified resin, mixing and stirring for 10 minutes, adding 6-12 parts of diluent, stirring and mixing for 10 minutes to obtain the novel cold-heat-shock-resistant coating.
CN202210321971.0A 2022-03-29 2022-03-29 Novel cold-heat-resistant impact-resistant coating and preparation method thereof Pending CN114517039A (en)

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Application Number Priority Date Filing Date Title
CN202210321971.0A CN114517039A (en) 2022-03-29 2022-03-29 Novel cold-heat-resistant impact-resistant coating and preparation method thereof

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106009850A (en) * 2016-06-22 2016-10-12 王春莉 High-weather-resistance paint and preparing method thereof
CN107793896A (en) * 2017-11-23 2018-03-13 安徽柏邦钛白粉有限公司 A kind of high-weatherability titanium white powder coating and preparation method thereof
CN111484794A (en) * 2020-06-02 2020-08-04 佛山市顺德区固得丽涂料有限公司 Water-based paint with low VOC content and preparation process thereof
CN111500139A (en) * 2020-06-02 2020-08-07 佛山市顺德区固得丽涂料有限公司 Long-acting colorful cold light paint and preparation process thereof
CN111500178A (en) * 2020-06-02 2020-08-07 佛山市顺德区固得丽涂料有限公司 PU (polyurethane) coating with low VOC (volatile organic compound) content and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106009850A (en) * 2016-06-22 2016-10-12 王春莉 High-weather-resistance paint and preparing method thereof
CN107793896A (en) * 2017-11-23 2018-03-13 安徽柏邦钛白粉有限公司 A kind of high-weatherability titanium white powder coating and preparation method thereof
CN111484794A (en) * 2020-06-02 2020-08-04 佛山市顺德区固得丽涂料有限公司 Water-based paint with low VOC content and preparation process thereof
CN111500139A (en) * 2020-06-02 2020-08-07 佛山市顺德区固得丽涂料有限公司 Long-acting colorful cold light paint and preparation process thereof
CN111500178A (en) * 2020-06-02 2020-08-07 佛山市顺德区固得丽涂料有限公司 PU (polyurethane) coating with low VOC (volatile organic compound) content and preparation method thereof

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