CN114479723A - High-temperature-resistant fluorine-containing acrylate pressure-sensitive adhesive for bonding fluorine-containing materials - Google Patents
High-temperature-resistant fluorine-containing acrylate pressure-sensitive adhesive for bonding fluorine-containing materials Download PDFInfo
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- CN114479723A CN114479723A CN202210167947.6A CN202210167947A CN114479723A CN 114479723 A CN114479723 A CN 114479723A CN 202210167947 A CN202210167947 A CN 202210167947A CN 114479723 A CN114479723 A CN 114479723A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/24—Homopolymers or copolymers of amides or imides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/33—Applications of adhesives in processes or use of adhesives in the form of films or foils for batteries or fuel cells
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/35—Applications of adhesives in processes or use of adhesives in the form of films or foils for aeronautic or naval applications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a high-temperature-resistant fluorine-containing acrylate pressure-sensitive adhesive for bonding fluorine-containing materials, which is prepared from the following components in parts by mass: 75 parts of soft monomer; 10 parts of hard monomer; 5-30 parts of a fluorine-containing acrylate monomer; 0.6-2.6 parts of heat-resistant monomer; 0.345 parts of thermal initiator; 100 portions and 130 portions of solvent. The invention reduces the surface energy of the polymer by introducing the fluorine-containing acrylate monomer into an acrylate polymerization system so as to improve the wettability of the polymer on the surface of the low-surface-energy substrate. The glass transition temperature of the pressure-sensitive adhesive is controlled by adjusting the ratio of soft and hard monomers in the polymer so as to adapt to the requirements of different use conditions.
Description
Technical Field
The invention belongs to the field of pressure-sensitive adhesives, and particularly relates to a high-temperature-resistant fluorine-containing acrylate pressure-sensitive adhesive for bonding fluorine-containing materials.
Background
The pressure-sensitive adhesive is a kind of adhesive which is sensitive to pressure, can be adhered to an adherend by slight pressure of finger pressure and does not need to use a solvent or other auxiliary means. The acrylate adhesive is widely used by virtue of the advantages of good weather resistance, simple formula and the like, but the common pressure-sensitive adhesive hardly has an adhesive effect on fluorine-containing materials such as polytetrafluoroethylene and the like because the low surface energy characteristics of the fluorine-containing materials such as polytetrafluoroethylene and the like make general adhesive liquid not spread on the surface. Considering that polytetrafluoroethylene generally needs to be pretreated and finally subjected to high-temperature sintering to be applied to the surface of a substrate, the process is complicated, time-consuming and labor-consuming, and the application scenario is greatly limited. Therefore, the development of the pressure-sensitive adhesive which can simply bond the polytetrafluoroethylene and has high temperature resistance has wide market prospect and application potential.
Disclosure of Invention
The invention provides a high-temperature resistant fluorine-containing acrylate pressure-sensitive adhesive for adhering fluorine-containing materials, aiming at overcoming the problem that the fluorine-containing materials such as polytetrafluoroethylene are difficult to adhere to the surfaces of various base materials, and the specific technical scheme is as follows:
a high-temperature-resistant fluorine-containing acrylate pressure-sensitive adhesive for bonding fluorine-containing materials is prepared from the following components in parts by mass:
75 parts of soft monomer;
10 parts of hard monomer;
5-30 parts of a fluorine-containing acrylate monomer;
0.6-2.6 parts of heat-resistant monomer;
0.345 parts of thermal initiator;
100 portions and 130 portions of solvent.
In some embodiments, the soft monomer is one or more of butyl acrylate, isooctyl acrylate, ethyl acrylate, 2-ethylhexyl methacrylate.
In some embodiments, the hard monomer is one or more of acrylic acid, methyl methacrylate, vinyl acetate, ethyl methacrylate, hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxyethyl acrylamide methyl, glycidyl acrylate, styrene.
In some embodiments, the fluorine-containing acrylate monomer is one or more of hexafluorobutyl acrylate, hexafluorobutyl methacrylate, dodecafluoroheptyl acrylate, allyl trifluoroacetate, trifluoroethyl acrylate and heptafluorobutyl acrylate.
In some embodiments, the heat-resistant monomer is maleimide.
In some embodiments, the thermal initiator is one or more of azobisisobutyronitrile, azobisisoheptonitrile, and benzoyl peroxide.
In some embodiments, the solvent is one or more of toluene, ethyl acetate, ethanol, butanone, tetrahydrofuran, acetone, and isopropanol.
The invention also provides a preparation method of the high-temperature-resistant fluorine-containing acrylate pressure-sensitive adhesive, which comprises the following steps:
weighing 75 parts of soft monomer, 10 parts of hard monomer, 5-30 parts of fluorine-containing acrylate monomer, 0.6-2.6 parts of heat-resistant monomer, 0.3 part of thermal initiator and 130 parts of solvent according to the mass parts, and uniformly mixing to obtain monomer mixed solution;
adding 40% of mixed solution into a reaction container, heating, introducing nitrogen gas, stirring, and carrying out heat preservation reaction for 1.5h after cooling reflux occurs, wherein the stirring speed is 140-;
after the reaction is finished, dripping the residual monomer mixed solution into the reaction container within 2 hours, and continuing to perform heat preservation reaction for 2 hours;
and after the reaction is finished, adding 0.045 part of thermal initiator, keeping the temperature for 3 hours, cooling and discharging.
The invention has the beneficial effects that:
1. the invention reduces the surface energy of the polymer by introducing the fluorine-containing acrylate monomer into an acrylate polymerization system so as to improve the wettability of the polymer on the surface of the low-surface-energy substrate. The glass transition temperature of the pressure-sensitive adhesive is controlled by adjusting the ratio of soft and hard monomers in the polymer so as to adapt to the requirements of different use conditions.
2. The invention can realize effective bonding to polytetrafluoroethylene, has strong adhesive force and large stripping force, does not have degumming phenomenon in the using process, creatively solves the bonding problem of the fluorine-containing material, greatly expands the application range of the fluorine-containing material, and provides a practical solution for the fields of lithium battery adhesives, marine base material corrosion resistance protection and the like.
Detailed Description
The description is further elucidated with reference to specific examples. The description is to be regarded as illustrative and explanatory only and should not be taken as limiting the scope of the invention in any way.
Example 1
A high temperature resistant fluorine-containing high temperature resistant acrylate pressure sensitive adhesive for bonding fluorine-containing materials, a preparation method thereof and a preparation method thereof comprise the following steps:
1) accurately weighing 40g of n-butyl acrylate, 30g of isooctyl acrylate, 5g of methyl methacrylate, 5g of vinyl acetate, 5g of ethyl acrylate, 0.6g of maleimide, 5g of hexafluorobutyl acrylate, 0.3g of initiator AIBN and 100g of ethyl acetate solvent, and uniformly mixing the substances to form a mixture solution. And (3) adding 40% of the mixture solution into a four-neck flask with a mechanical stirrer, a thermometer and a condenser, heating to 78 ℃, wherein the stirring speed is 150r/min, and the reaction system is carried out under the protection of nitrogen. When the reaction system is refluxed, the time is counted, and the reaction is timed for 1.5 h.
2) After the reaction, the remaining 60% of the mixture solution was added to the reaction system via a constant pressure dropping funnel for 2 hours, and the reaction was allowed to proceed for 2 hours after the addition was completed.
3) After the reaction, the stirring rate was increased to 240r/min, 0.045g of AIBN initiator was added, and the incubation was continued for 3 h.
4) And after the reaction, cooling and discharging.
5) Weighing part of glue solution, coating the glue solution on the surface of a polytetrafluoroethylene film by using a glass rod, controlling the thickness of a coating film to be 100 mu m, placing the glue solution in an oven at 80 ℃ for 2min, taking out the glue solution, measuring the thickness of the coating film to be 60 +/-5 mu m, and bonding the glue solution with a polytetrafluoroethylene film, a polyimide film and a stainless steel plate respectively to prepare a sample for testing.
Example 2
A high temperature resistant fluorine-containing high temperature resistant acrylate pressure sensitive adhesive for bonding fluorine-containing materials, a preparation method thereof and a preparation method thereof comprise the following steps:
1) accurately weighing 40g of n-butyl acrylate, 30g of isooctyl acrylate, 5g of methyl methacrylate, 5g of vinyl acetate, 5g of ethyl acrylate, 5g of maleimide, 10g of hexafluorobutyl acrylate, 0.3g of initiator AIBNB and 100g of ethyl acetate solvent, and uniformly mixing the substances to form a mixture solution. And (3) adding 40% of the mixture solution into a four-neck flask with a mechanical stirrer, a thermometer and a condenser, heating to 78 ℃, wherein the stirring speed is 150r/min, and the reaction system is carried out under the protection of nitrogen. When the reaction system is refluxed, the time is counted, and the reaction is timed for 1.5 h.
2) After the reaction, the remaining 60% of the mixture solution was added to the reaction system via a constant pressure dropping funnel for 2 hours, and the reaction was allowed to proceed for 2 hours after the addition was completed.
3) After the reaction, the stirring rate was increased to 240r/min, 0.045g of AIBN initiator was added, and the incubation was continued for 3 h.
4) And after the reaction, cooling and discharging.
5) Weighing part of glue solution, coating the glue solution on the surface of a polytetrafluoroethylene film by using a glass rod, controlling the thickness of a coating film to be 100 mu m, placing the glue solution in an oven at 80 ℃ for 2min, taking out the glue solution, measuring the thickness of the coating film to be 60 +/-5 mu m, and bonding the glue solution with a polytetrafluoroethylene film, a polyimide film and a stainless steel plate respectively to prepare a sample for testing.
Example 3
A high temperature resistant fluorine-containing high temperature resistant acrylate pressure sensitive adhesive for bonding fluorine-containing materials, a preparation method thereof and a preparation method thereof comprise the following steps:
1) accurately weighing 40g of n-butyl acrylate, 30g of isooctyl acrylate, 5g of methyl methacrylate, 5g of vinyl acetate, 5g of ethyl acrylate, 2.6g of maleimide, 20g of hexafluorobutyl acrylate, 0.3g of initiator AIBN and 120g of ethyl acetate solvent, and uniformly mixing the substances to form a mixture solution. And (3) adding 40% of the mixture solution into a four-neck flask with a mechanical stirrer, a thermometer and a condenser, heating to 78 ℃, wherein the stirring speed is 150r/min, and the reaction system is carried out under the protection of nitrogen. When the reaction system is refluxed, the time is counted, and the reaction is timed for 1.5 h.
2) After the reaction, the remaining 60% of the mixture solution was added to the reaction system via a constant pressure dropping funnel for 2 hours, and the reaction was allowed to proceed for 2 hours after the addition was completed.
3) After the reaction, the stirring rate was increased to 240r/min, 0.045g of AIBN initiator was added, and the incubation was continued for 3 h.
4) And after the reaction, cooling and discharging.
5) Weighing part of glue solution, coating the glue solution on the surface of a polytetrafluoroethylene film by using a glass rod, controlling the thickness of a coating film to be 100 mu m, placing the glue solution in an oven at 80 ℃ for 2min, taking out the glue solution, measuring the thickness of the coating film to be 60 +/-5 mu m, and bonding the glue solution with a polytetrafluoroethylene film, a polyimide film and a stainless steel plate respectively to prepare a sample for testing.
Example 4
A high temperature resistant fluorine-containing high temperature resistant acrylate pressure sensitive adhesive for bonding fluorine-containing materials, a preparation method thereof and a preparation method thereof comprise the following steps:
1) accurately weighing 40g of n-butyl acrylate, 30g of isooctyl acrylate, 5g of methyl methacrylate, 5g of vinyl acetate, 5g of ethyl acrylate, 1.6g of maleimide, 30g of hexafluorobutyl acrylate, 0.3g of initiator AIBN and 130g of ethyl acetate solvent, and uniformly mixing the substances to form a mixture solution. And (3) adding 40% of the mixture solution into a four-neck flask with a mechanical stirrer, a thermometer and a condenser, heating to 78 ℃, wherein the stirring speed is 150r/min, and the reaction system is carried out under the protection of nitrogen. When the reaction system is refluxed, the time is counted, and the reaction is timed for 1.5 h.
2) After the reaction, the remaining 60% of the mixture solution was added to the reaction system via a constant pressure dropping funnel for 2 hours, and the reaction was allowed to proceed for 2 hours after the addition was completed.
3) After the reaction, the stirring rate was increased to 240r/min, 0.045g of AIBN initiator was added, and the incubation was continued for 3 h.
4) And after the reaction, cooling and discharging.
5) Weighing part of glue solution, coating the glue solution on the surface of a polytetrafluoroethylene film by using a glass rod, controlling the thickness of a coating film to be 100 mu m, placing the glue solution in an oven at 80 ℃ for 2min, taking out the glue solution, measuring the thickness of the coating film to be 60 +/-5 mu m, and bonding the glue solution with a polytetrafluoroethylene film, a polyimide film and a stainless steel plate respectively to prepare a sample for testing.
Comparative example:
a high temperature resistant fluorine-containing high temperature resistant acrylate pressure sensitive adhesive for bonding fluorine-containing materials, a preparation method thereof and a preparation method thereof comprise the following steps:
1) accurately weighing 40g of n-butyl acrylate, 30g of isooctyl acrylate, 5g of methyl methacrylate, 5g of vinyl acetate, 5g of ethyl acrylate, 0.3g of initiator AIBN and 100g of ethyl acetate solvent, and uniformly mixing the substances to form a mixture solution. And (3) adding 40% of the mixture solution into a four-neck flask with a mechanical stirrer, a thermometer and a condenser, heating to 78 ℃, wherein the stirring speed is 150r/min, and the reaction system is carried out under the protection of nitrogen. When the reaction system is refluxed, the time is counted, and the reaction is timed for 1.5 h.
2) After the reaction, the remaining 60% of the mixture solution was added to the reaction system via a constant pressure dropping funnel for 2 hours, and the reaction was allowed to proceed for 2 hours after the addition was completed.
3) After the reaction, the stirring rate was increased to 240r/min, 0.045g of AIBN initiator was added, and the incubation was continued for 3 h.
4) And after the reaction, cooling and discharging.
5) Weighing part of glue solution, coating the glue solution on the surface of a polytetrafluoroethylene film by using a glass rod, controlling the thickness of a coating film to be 100 mu m, placing the glue solution in an oven at 80 ℃ for 2min, taking out the glue solution, measuring the thickness of the coating film to be 60 +/-5 mu m, and bonding the glue solution with a polytetrafluoroethylene film, a polyimide film and a stainless steel plate respectively to prepare a sample for testing.
And (3) performance testing:
the 180 DEG peel strength test method for pressure-sensitive adhesive tapes GB/T2792-1998.
The method for testing the wet heat aging resistance comprises the following steps: the sample preparation method is the same as the 180-degree peel strength test method GB/T2792-1998 of the pressure-sensitive adhesive tape, then the sample is put into a humid heat aging box with 85 ℃ and 85% humidity for 48h, then the sample is taken out and cooled to room temperature, then 180-degree peel strength test is carried out, and the humidity-resistant and heat aging resistance of the pressure-sensitive adhesive tape is evaluated by calculating the peel strength retention rate according to the strength test result.
The heat resistance test method of the pressure-sensitive adhesive comprises the following steps: the sample preparation method is the same as the 180-degree peel strength test method GB/T2792-1998 of the pressure-sensitive adhesive tape, then the sample is placed into a 150 ℃ oven, the sample is taken out after a period of time, the temperature is reduced to room temperature, the sample strip is slowly peeled off from the stainless steel plate, and the condition of residual adhesive on the stainless steel plate at different times is recorded.
The performance characteristics of the examples and comparative examples are shown in the following table:
it can be seen from the results of the examples and comparative examples that, in the adhesion of fluorine-containing materials such as polytetrafluoroethylene, the fluorine-containing acrylate pressure-sensitive adhesive has significantly improved adhesion strength and strong adhesion, and is not easy to come unstuck, wherein in example 3, the peel force between PTFE and PTFE reaches 12.1N/25mm, and good heat resistance is achieved.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (8)
1. The high-temperature-resistant fluorine-containing acrylate pressure-sensitive adhesive for bonding fluorine-containing materials is characterized by being prepared from the following components in parts by mass:
75 parts of soft monomer;
10 parts of hard monomer;
5-30 parts of a fluorine-containing acrylate monomer;
0.6-2.6 parts of heat-resistant monomer;
0.345 parts of thermal initiator;
100 portions and 130 portions of solvent.
2. The high temperature resistant fluoroacrylate pressure sensitive adhesive of claim 1, wherein the soft monomer is one or more of butyl acrylate, isooctyl acrylate, ethyl acrylate, 2-ethylhexyl acrylate, and 2-ethylhexyl methacrylate.
3. The high temperature resistant fluoroacrylate pressure sensitive adhesive as claimed in claim 1 wherein said hard monomer is one or more of acrylic acid, methyl methacrylate, vinyl acetate, ethyl methacrylate, hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxyethyl acrylamide methyl, glycidyl acrylate, styrene.
4. The high temperature resistant fluoroacrylate pressure sensitive adhesive as claimed in claim 1 wherein said fluoroacrylate monomer is one or more of hexafluorobutyl acrylate, hexafluorobutyl methacrylate, dodecafluoroheptyl acrylate, allyl trifluoroacetate, trifluoroethyl acrylate, and heptafluorobutyl acrylate.
5. The high temperature resistant fluoroacrylate pressure sensitive adhesive of claim 1, wherein said heat resistant monomer is maleimide.
6. The high temperature resistant fluoroacrylate pressure sensitive adhesive of claim 1, wherein said thermal initiator is one or more of azobisisobutyronitrile, azobisisoheptonitrile, and benzoyl peroxide.
7. The high temperature resistant fluoroacrylate pressure sensitive adhesive as claimed in claim 1 wherein said solvent is one or more of toluene, ethyl acetate, ethanol, butanone, tetrahydrofuran, acetone, and isopropanol.
8. A method of making the high temperature resistant fluoroacrylate pressure sensitive adhesive of any of claims 1 to 7, comprising the steps of:
weighing 75 parts of soft monomer, 10 parts of hard monomer, 5-30 parts of fluorine-containing acrylate monomer, 0.6-2.6 parts of heat-resistant monomer, 0.3 part of thermal initiator and 130 parts of solvent according to the mass parts, and uniformly mixing to obtain monomer mixed solution;
adding 40% of mixed solution into a reaction container, heating, introducing nitrogen gas, stirring, and carrying out heat preservation reaction for 1.5h after cooling reflux occurs, wherein the stirring speed is 140-;
after the reaction is finished, dripping the residual monomer mixed solution into the reaction container within 2 hours, and continuing to perform heat preservation reaction for 2 hours;
and after the reaction is finished, adding 0.045 part of thermal initiator, keeping the temperature for 3 hours, cooling and discharging.
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| CN202210167947.6A CN114479723A (en) | 2022-02-23 | 2022-02-23 | High-temperature-resistant fluorine-containing acrylate pressure-sensitive adhesive for bonding fluorine-containing materials |
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| CN202210167947.6A CN114479723A (en) | 2022-02-23 | 2022-02-23 | High-temperature-resistant fluorine-containing acrylate pressure-sensitive adhesive for bonding fluorine-containing materials |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115521737A (en) * | 2022-11-03 | 2022-12-27 | 黑龙江省科学院石油化学研究院 | Medium-resistant and high-temperature-resistant acrylate pressure-sensitive adhesive and preparation method thereof |
| CN116041606A (en) * | 2022-12-30 | 2023-05-02 | 东华大学 | Fluorine-containing acrylate polymer adhesive and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102190991A (en) * | 2011-03-24 | 2011-09-21 | 昆山博益鑫成高分子材料有限公司 | PET (poly(ethylene terephthalate)) protection film pressure-sensitive adhesive used for manufacture process of flat panel display, and production method thereof |
| CN102504717A (en) * | 2011-11-07 | 2012-06-20 | 北京天山新材料技术股份有限公司 | Adhesive tape for bonding low-surface-energy material and preparation method thereof |
| CN104449483A (en) * | 2014-11-11 | 2015-03-25 | 哈尔滨工业大学无锡新材料研究院 | Fluorine-containing conductive pressure-sensitive adhesive and preparation method thereof |
| CN106520032A (en) * | 2016-10-18 | 2017-03-22 | 无锡海特新材料研究院有限公司 | High-temperature-resistant and low-peel-strength acrylate pressure-sensitive adhesive and preparation method thereof |
| CN109266257A (en) * | 2018-09-29 | 2019-01-25 | 广州都邦材料科技有限公司 | Acrylic Pressure Sensitive Adhesive and preparation method thereof, electronic product |
-
2022
- 2022-02-23 CN CN202210167947.6A patent/CN114479723A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102190991A (en) * | 2011-03-24 | 2011-09-21 | 昆山博益鑫成高分子材料有限公司 | PET (poly(ethylene terephthalate)) protection film pressure-sensitive adhesive used for manufacture process of flat panel display, and production method thereof |
| CN102504717A (en) * | 2011-11-07 | 2012-06-20 | 北京天山新材料技术股份有限公司 | Adhesive tape for bonding low-surface-energy material and preparation method thereof |
| CN104449483A (en) * | 2014-11-11 | 2015-03-25 | 哈尔滨工业大学无锡新材料研究院 | Fluorine-containing conductive pressure-sensitive adhesive and preparation method thereof |
| CN106520032A (en) * | 2016-10-18 | 2017-03-22 | 无锡海特新材料研究院有限公司 | High-temperature-resistant and low-peel-strength acrylate pressure-sensitive adhesive and preparation method thereof |
| CN109266257A (en) * | 2018-09-29 | 2019-01-25 | 广州都邦材料科技有限公司 | Acrylic Pressure Sensitive Adhesive and preparation method thereof, electronic product |
Non-Patent Citations (1)
| Title |
|---|
| 王霞 等 著: "《现代建筑涂料：树脂合成与配方设计》", 上海：上海交通大学出版社, pages: 22 - 26 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115521737A (en) * | 2022-11-03 | 2022-12-27 | 黑龙江省科学院石油化学研究院 | Medium-resistant and high-temperature-resistant acrylate pressure-sensitive adhesive and preparation method thereof |
| CN115521737B (en) * | 2022-11-03 | 2023-05-16 | 黑龙江省科学院石油化学研究院 | Medium-resistant high-temperature-resistant acrylate pressure-sensitive adhesive and preparation method thereof |
| CN116041606A (en) * | 2022-12-30 | 2023-05-02 | 东华大学 | Fluorine-containing acrylate polymer adhesive and preparation method and application thereof |
| CN116041606B (en) * | 2022-12-30 | 2024-02-27 | 东华大学 | Fluorine-containing acrylate polymer adhesive and preparation method and application thereof |
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