CN114479603A - High-temperature-resistant paint phenolic resin anticorrosive paint - Google Patents

High-temperature-resistant paint phenolic resin anticorrosive paint Download PDF

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Publication number
CN114479603A
CN114479603A CN202210244634.6A CN202210244634A CN114479603A CN 114479603 A CN114479603 A CN 114479603A CN 202210244634 A CN202210244634 A CN 202210244634A CN 114479603 A CN114479603 A CN 114479603A
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CN
China
Prior art keywords
paint
phenolic resin
resistant
temperature
high temperature
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210244634.6A
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Chinese (zh)
Inventor
夏德富
刘素芹
陈洪霞
徐兴亮
孙权
王启博
李绍旭
李庆初
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tianjin Changlu Haijing Group Co Ltd
Original Assignee
Tianjin Changlu Haijing Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Changlu Haijing Group Co Ltd filed Critical Tianjin Changlu Haijing Group Co Ltd
Priority to CN202210244634.6A priority Critical patent/CN114479603A/en
Publication of CN114479603A publication Critical patent/CN114479603A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/04Condensation polymers of aldehydes or ketones with phenols only
    • C09D161/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C09D161/12Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols with polyhydric phenols
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/005Additives being defined by their particle size in general
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a high-temperature-resistant paint phenolic resin anticorrosive paint which comprises a base material and a curing agent, wherein the base material comprises a paint phenolic titanium resin raw material, nano titanium dioxide, a functional pigment filler and a solvent. The paint disclosed by the invention is excellent in performance, acid-resistant, alkali-resistant, high-temperature-resistant, better in heavy corrosion resistance, and grade 1 in adhesive force, and a paint film is impact-resistant 50kg.cm and heat-resistant to 200-300 ℃; and the paint film is convenient to construct, self-dries at normal temperature, has strong adhesive force, high impact resistance and good flexibility, does not have anaphylactic reaction to people, and has the characteristic of ultraviolet aging resistance.

Description

High-temperature-resistant paint phenolic resin anticorrosive paint
Technical Field
The invention belongs to the technical field of anticorrosive coatings, and particularly relates to a high-temperature-resistant paint phenolic resin anticorrosive coating.
Background
In the bittern chemical industry, waste liquor after salt preparation by sun is used as a raw material, products are sodium chloride, potassium chloride, magnesium chloride and the like, and the raw material, the products and the production process are inorganic salts with strong corrosivity. The chloride aqueous solution generates hydrolysis reaction in a high-temperature evaporation chamber, the higher the temperature is, the higher the hydrolysis speed is, hydrogen chloride is generated, the hydrogen chloride is contacted with evaporation mother liquor or evaporated secondary steam to form an acid medium, and the pH value of evaporation secondary steam condensate water can be as low as about 3.5.
Most production equipment facilities in bittern chemical industry are made of carbon steel materials, such as a settler, a part of tanks and the like, which cannot better resist corrosion of production materials and production environment. For example, the most severely corroded equipment in the production of potassium chloride is an evaporation finished liquid heat preservation settler, the temperature of a material liquid in the settler is 105-115 ℃, the material liquid below the liquid level is directly contacted with a shell, and a secondary steam and air with nearly saturated vapor pressure are arranged between the settler and an upper cover; because the operation of brushing the tank and cleaning the overflow ring is required, the liquid level and the temperature in the device fluctuate once every 2 days, the liquid level is reduced by about 300mm, and the temperature at the overflow ring can be reduced to 70-80 ℃ from 105-115 ℃. The production practice shows that the device is made of carbon steel, the device body and the device bottom part with the thickness of 10-12mm are updated about every 10 years, and the upper cover with the thickness of 6mm is updated about every 5 years. The existing paint is used for internal corrosion prevention, and the corrosion prevention service life of the paint is only about 1 year.
At present, only 6 actual production enterprises of domestic salt production waste liquid comprehensive utilization projects remain, and each enterprise has less investment on improvement of production facilities and is basically in a state of maintaining production. Besides selecting partial new materials when equipment is updated, enterprises basically do not carry out deeper research and exploration on the anticorrosion aspect of equipment facilities. Compared with other industries, the maintenance frequency and the maintenance cost are increased due to the serious corrosion of equipment facilities, so that a novel high-temperature-resistant heavy-duty anticorrosive material which accords with the characteristics of the equipment facilities in the industry is urgently needed to solve or slow down the serious corrosion problem of the equipment facilities of the comprehensive utilization project of the salt-making waste liquid, prolong the service life of the equipment facilities, reduce the maintenance frequency and the maintenance cost, improve the economic benefit of enterprises, and change the current situations of safety production and civilized production in enterprises.
Disclosure of Invention
The invention aims to overcome the technical problem of corrosion resistance of carbon steel equipment under high-temperature medium existing in the existing bittern chemical industry, and aims to provide a special high-temperature-resistant paint phenol resin anticorrosive paint for bittern chemical carbon steel equipment.
The invention is realized by the following technical scheme:
the high-temperature-resistant paint phenolic resin anticorrosive paint comprises a base material and a curing agent, wherein the base material comprises the following components in percentage by mass:
60-70% of a urushiol titanium resin raw material;
2% -4% of nano titanium dioxide;
12% -18% of functional pigment filler;
8-20% of a solvent.
In the technical scheme, the urushiol titanium resin raw material is prepared by carrying out condensation reaction on nanometer titanium dioxide and urushiol resin through stirring and dispersion at normal temperature.
In the above technical solution, the solvent is PMA (propylene glycol methyl ether acetate)
In the technical scheme, the functional pigment filler is mica powder and talcum powder, and the mass percentages of the two base materials are as follows: 6-9% of mica powder and 6-9% of talcum powder.
In the technical scheme, the nano titanium dioxide is nano rutile titanium dioxide powder with the particle size of 20 nm-50 nm.
In the technical scheme, the curing agent is T-31 (phenolic aldehyde amine (PAA) epoxy curing agent).
In the above technical scheme, the mass ratio between the base material and the curing agent is 100: (12.5-20).
The invention has the beneficial effects that:
the invention provides a high-temperature-resistant paint phenol resin anticorrosive paint special for bittern chemical carbon steel equipment, which effectively solves the problems of poor high-temperature resistance and low corrosion resistance service life of the existing anticorrosive paint in bittern chemical industry; the coating disclosed by the invention has good substrate binding force with metal, ultrahigh weather resistance, outstanding strong acid, strong alkali, various salts, organic solvents, high temperature resistance, friction performance and the like, can be used at a temperature of 150-200 ℃ for a long time, can be widely applied to equipment components and production devices in industries such as bittern chemical industry, salt chemical industry, marine chemical industry, petroleum, chemical industry, pharmacy, food and the like, can be used as a metal anti-corrosion protective coating, has a service life of 5-10 years, and has higher economic and social benefits.
The paint disclosed by the invention is excellent in performance, acid-resistant, alkali-resistant and high-temperature-resistant, has better heavy-duty corrosion resistance, the adhesive force is grade 1, a paint film is impact-resistant 50kg.cm, and the heat resistance can reach 200-300 ℃; and the paint film is convenient to construct, self-dries at normal temperature, has strong adhesive force, high impact resistance and good flexibility, does not have anaphylactic reaction to people, and has the characteristic of ultraviolet aging resistance.
Detailed Description
In order to make the technical scheme of the present invention better understood by those skilled in the art, the following will further describe the technical scheme of the high temperature resistant paint phenolic resin anticorrosive paint special for bittern chemical carbon steel equipment in the present invention by means of specific embodiments.
Example 1
A high temperature resistant paint phenolic resin anticorrosive paint comprises 125g of curing agent T-31 and 1000g of base material; the 1000g of base material comprises 600g of a urushiol titanium resin raw material, 20g of nano rutile titanium dioxide powder with the particle size of 50nm, 90g of mica powder, 90g of talcum powder and 200g of PMA.
Example 2
A high temperature resistant paint phenolic resin anticorrosive paint comprises 163g of curing agent T-31 and 1000g of base material; the 1000g of base material comprises 650g of a urushiol titanium resin raw material, 30g of nano rutile titanium dioxide powder with the particle size of 40nm, 90g of mica powder, 90g of talcum powder and 140g of PMA.
Example 3
A high temperature resistant paint phenolic resin anticorrosive paint comprises 200g of curing agent T-31 and 1000g of base material; the 1000g of base material comprises 700g of a urushiol titanium resin raw material, 40g of nano rutile titanium dioxide powder with the particle size of 30nm, 90g of mica powder, 90g of talcum powder and 80g of PMA.
Example 4
A high temperature resistant paint phenolic resin anticorrosive paint comprises 200g of curing agent T-31 and 1000g of base material; the 1000g of base material comprises 700g of urushiol titanium resin raw material, 40g of nano rutile titanium dioxide powder with the particle size of 20nm, 60g of mica powder, 75g of talcum powder and 125g of PMA.
Example 5
A high temperature resistant paint phenolic resin anticorrosive paint comprises 200g of curing agent T-31 and 1000g of base material; the 1000g of base material comprises 700g of urushiol titanium resin raw material, 40g of nano rutile titanium dioxide powder with the particle size of 20nm, 75g of mica powder, 60g of talcum powder and 125g of PMA.
The applicant declares that the above description is only a specific embodiment of the present invention, but the scope of the present invention is not limited thereto, and it should be understood by those skilled in the art that any changes or substitutions that can be easily conceived by those skilled in the art within the technical scope of the present invention are within the scope and disclosure of the present invention.

Claims (7)

1. A high temperature resistant paint phenolic resin anticorrosive paint is characterized in that: the coating comprises a base material and a curing agent, wherein the base material comprises the following components in percentage by mass:
60-70% of a urushiol titanium resin raw material;
2% -4% of nano titanium dioxide;
12% -18% of functional pigment filler;
8-20% of a solvent.
2. The high temperature resistant paint phenolic resin anticorrosive paint according to claim 1, characterized in that: the mass ratio of the base material to the curing agent is 100: (12.5-20).
3. The high temperature resistant paint phenolic resin anticorrosive paint according to claim 2, characterized in that: the curing agent is T-31.
4. The high temperature resistant paint phenolic resin anticorrosive paint according to claim 1, characterized in that: the urushiol titanium resin raw material is prepared by carrying out condensation reaction on nanoscale titanium dioxide and urushiol resin through stirring and dispersion at normal temperature.
5. The high temperature resistant paint phenolic resin anticorrosive paint according to claim 1, characterized in that: the solvent is PMA.
6. The high temperature resistant paint phenolic resin anticorrosive paint according to claim 1, characterized in that: the functional pigment filler is mica powder and talcum powder, and the mass percent of the base materials of the mica powder and the talcum powder is as follows: 6-9% of mica powder and 6-9% of talcum powder.
7. The high temperature resistant paint phenolic resin anticorrosive paint according to claim 1, characterized in that: the nano titanium dioxide is nano rutile titanium dioxide powder with the particle size of 20 nm-50 nm.
CN202210244634.6A 2022-03-14 2022-03-14 High-temperature-resistant paint phenolic resin anticorrosive paint Pending CN114479603A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210244634.6A CN114479603A (en) 2022-03-14 2022-03-14 High-temperature-resistant paint phenolic resin anticorrosive paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210244634.6A CN114479603A (en) 2022-03-14 2022-03-14 High-temperature-resistant paint phenolic resin anticorrosive paint

Publications (1)

Publication Number Publication Date
CN114479603A true CN114479603A (en) 2022-05-13

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Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1055550A (en) * 1990-04-09 1991-10-23 福建师范大学 New corrosion resistant coating of phenol-titanium varnish chelated with high polymer
CN1709999A (en) * 2005-07-05 2005-12-21 国家海洋局天津海水淡化与综合利用研究所 Internal wall anticorrosive coating for sea water evaporating installation
CN109294306A (en) * 2018-09-04 2019-02-01 中国石油天然气集团公司 A kind of anticorrosive coating and its manufacture, application method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1055550A (en) * 1990-04-09 1991-10-23 福建师范大学 New corrosion resistant coating of phenol-titanium varnish chelated with high polymer
CN1709999A (en) * 2005-07-05 2005-12-21 国家海洋局天津海水淡化与综合利用研究所 Internal wall anticorrosive coating for sea water evaporating installation
CN109294306A (en) * 2018-09-04 2019-02-01 中国石油天然气集团公司 A kind of anticorrosive coating and its manufacture, application method

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Application publication date: 20220513

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