CN103980576A - Corrosion-resistant lining chloroprene rubber plate for seawater transportation pipeline - Google Patents

Corrosion-resistant lining chloroprene rubber plate for seawater transportation pipeline Download PDF

Info

Publication number
CN103980576A
CN103980576A CN201410218405.2A CN201410218405A CN103980576A CN 103980576 A CN103980576 A CN 103980576A CN 201410218405 A CN201410218405 A CN 201410218405A CN 103980576 A CN103980576 A CN 103980576A
Authority
CN
China
Prior art keywords
parts
chloroprene rubber
rubber plate
corrosion
resistant lining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201410218405.2A
Other languages
Chinese (zh)
Other versions
CN103980576B (en
Inventor
沈青
吴纪君
陈乔霖
杨权军
冯春元
刘丹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU KAI-YUAN ENVIRONMENTAL TECHNOLOGY ENGINEERING Co Ltd
Original Assignee
JIANGSU KAI-YUAN ENVIRONMENTAL TECHNOLOGY ENGINEERING Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU KAI-YUAN ENVIRONMENTAL TECHNOLOGY ENGINEERING Co Ltd filed Critical JIANGSU KAI-YUAN ENVIRONMENTAL TECHNOLOGY ENGINEERING Co Ltd
Priority to CN201410218405.2A priority Critical patent/CN103980576B/en
Publication of CN103980576A publication Critical patent/CN103980576A/en
Application granted granted Critical
Publication of CN103980576B publication Critical patent/CN103980576B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a corrosion-resistant lining chloroprene rubber plate for a seawater transportation pipeline. The corrosion-resistant lining chloroprene rubber plate is prepared from the following components in parts by weight: 100 parts of chloroprene rubber, 1.5-3 parts of stearic acid, 3-6 parts of resin, 1-2 parts of processing aid, 15-30 parts of semi-reinforcing carbon black, 30-45 parts of thermal decomposition process carbon black, 20-40 parts of talcum powder, 8-15 parts of vacuum third oil, 15-25 parts of lead oxide and 0.5-2 parts of accelerant DM. The corrosion-resistant lining chloroprene rubber plate has excellent performances such as high wear resistance, water hammer impact resistance, acid, base and salt corrosion resistance, high temperature resistance, low scaling speed, high bonding strength, small operation resistance and the like, fills up the domestic blank and can be widely applied to seawater power generation and sweater desalination industries, and all performance indexes of the corrosion-resistant lining chloroprene rubber plate have the same level with foreign products.

Description

Corrosion protective lining chloroprene rubber plate for sea water conveying pipelines
Technical field
The present invention relates to a kind of chloroprene rubber plate, specifically, relate to a kind of sea water conveying pipelines corrosion protective lining chloroprene rubber plate.
Background technology
In sea water desaltination, in the engineering projects such as power generation with sea water, can use seawater and introduce pipeline, owing to containing the chlorion of 20000ppm in seawater, it is a kind of very strong dielectric solution, can produce countless small galvanic cells, corrodibility to steel plate is extremely strong, in seawater, inevitably having in addition marine life exists, these biogenic movements easily produce humic acid, its acidity is extremely strong, the generation of energy corrosion promoting, therefore the work-ing life of reasonable material guarantee seawater pipeline, more conventional material has glass reinforced plastic, duplex stainless steel and carbon steel liner rubber, wherein glass reinforced plastic is because rigidity is bad and the shortcoming such as ultraviolet-resistant aging poor-performing and result of use is bad, and duplex stainless steel price is very expensive, main dependence on import, ordinary priority is used carbon steel liner rubber tubing.
In all rubber kinds, what be typically used as at home corrosion protective lining occasion has two kinds of natural rubber and isoprene-isobutylene rubbers, but for Seawater, require it to there is good resistance to erosion abradability simultaneously, acid resistance, weathering resistance, high-adhesive-strength with steel, the over-all propertieies such as slow fouling performance, all Shortcomings parts of above-mentioned two kinds of rubber, the external general chloroprene rubber that adopts is as backing layer, at home, the neoprene neoprene of some mold pressings also has utilization, but as corrosion protective lining rubber plate, due to external maintaining secrecy to formula and complete processing, main dependence on import.
About the design of chloroprene rubber plate, technology existing relevant in prior art is open, as China Patent No.: CN 201110115153.7, denomination of invention is: chloroprene rubber composition, the component of the disclosed chloroprene rubber plate of this application scheme is: chloroprene rubber, styrene-butadiene rubber(SBR), Sulfur, zinc oxide, anti-aging agent RD, hard (china) clay, semi-reinforcing furnace black, high reactivity carbon black, accelerant CZ, promotor TS, promotor TRA, n-butyl sebacate, diaryl-p-phenylenediamine, γ-sulfydryl propyl trimethoxy silicane, phenyl-β. naphthylamines and diphenyl-para-phenylene diamine's mixture, this application case has improved the winter hardiness of rubber by adding auxiliary agent, but there is no advantage aspect acid and alkali-resistance brine corrosion, be not suitable for sea water conveying pipelines.
In addition, Chinese patent CN 201310590183.2, denomination of invention is: a kind of chloroprene rubber, this application scheme has improved the aging resistance of resistance to dynamic ozone of rubber, is not suitable for equally sea water conveying pipelines.
Therefore, develop a kind of corrosion protective lining that can be suitable for sea water conveying pipelines chloroprene rubber plate, marketable value is very large.
Summary of the invention
1, the technical problem that invention will solve
The object of this invention is to provide a kind of corrosion protective lining chloroprene rubber plate that there is high abrasion, water-fast hammering blow, acid and alkali-resistance brine corrosion and can be suitable for sea water conveying pipelines.
2, technical scheme
For achieving the above object, technical scheme provided by the invention is:
Corrosion protective lining chloroprene rubber plate for sea water conveying pipelines, is made up of the component of following parts by weight:
100 parts of chloroprene rubbers, stearic acid 1.5-3 part, resin 3-6 part, processing aid 1-2 part, semi-reinforcing hydrocarbon black 15-30 part, thermals 30-45 part, talcum powder 20-40 part, subtracts third fractional oil 8-15 part, plumbous oxide 15-25 part, altax 0.5-2 part.
Further, this chloroprene rubber plate is made up of the component of following parts by weight:
100 parts of chloroprene rubbers, 2 parts of stearic acid, 5 parts of resins, 2 parts of processing aids, 20 parts of semi-reinforcing hydrocarbon blacks, 40 parts of thermalss, 30 parts of talcum powder, subtract 10 parts of third fractional oils, 20 parts, plumbous oxide, 1 part of altax.
3, beneficial effect
Adopt technical scheme of the present invention, compared with existing known technology, there is following unusual effect:
(1) formulating of recipe of chloroprene rubber plate for corrosion protective lining of the present invention, fully take into account processing characteristics, adhesiveproperties and the sulfuration process of rubber, select on this basis suitable rubber substrate, consider again the property of sea water resistance medium, select metal oxide+stearic acid as vulcanization system for guarantee medium-resistance promotor, for taking into account reinforcement and insulativity, select half reinforcement+thermals as reinforcement system, softening system is selected and is subtracted third fractional oil
(2) high-performances such as the present invention has high abrasion, water-fast hammering blow, acid and alkali-resistance brine corrosion, high temperature resistance, slow fouling, bonding strength is high, running resistance is little, fill up domestic blank, its property indices and external product, can be extensively at power generation with sea water, sea water desaltination industry applications in peer-level.
(3) isoprene-isobutylene rubber plate chemical property of the present invention is highly stable, and the erosion of the most corrosive mediums of ability and organic solvent is more corrosion-resistant than plastics such as polyethylene, polypropylene, nylon, ABS.Except strong oxidizing property acid solution, the various corrosive mediums of ability (acid, alkali, salt) and organic medium (except naphthalene solvent) in certain temperature and concentration range, in 80 kinds of organic solvents of 20 DEG C and 80 DEG C, soak stagnant 30 days, appearance is without any abnormal phenomena, and other physicals does not also almost change.
(4) antiscale of isoprene-isobutylene rubber plate of the present invention, slow fouling performance are good: the surfaceness of rubber is little, are applied in transport pipe absolute roughness only 0.0267, and relative roughness is 3.311 × 10 -4, clear water resistance coefficient is 0.0165, approximately less by 17 than common steel tube, and rubber has adaptability to the conventional medium such as acid, alkali, can not cause corrosion and fouling.
Embodiment
Below in conjunction with embodiment, the present invention is further detailed explanation.
Embodiment 1
Corrosion protective lining chloroprene rubber plate for sea water conveying pipelines, component by following parts by weight forms: 100 parts of chloroprene rubbers, 2 parts of stearic acid, 5 parts of resins, 2 parts of processing aids, 20 parts of semi-reinforcing hydrocarbon blacks, 40 parts of thermalss, 30 parts of talcum powder, subtract 10 parts of third fractional oils, 20 parts, plumbous oxide, 1 part of altax.
In said components, chloroprene rubber is from the import of NEC chemical company.
This formula through plasticating, the performance detection data of the rubber plate that technological process produces such as mixing, calendering is extruded is as follows:
Embodiment 2
Corrosion protective lining chloroprene rubber plate for sea water conveying pipelines, component by following parts by weight forms: 100 parts of chloroprene rubbers, 1.5 parts of stearic acid, 3 parts of resins, 1 part of processing aid, 15 parts of semi-reinforcing hydrocarbon blacks, 45 parts of thermalss, 20 parts of talcum powder, subtract 8 parts of third fractional oils, 15 parts, plumbous oxide, 0.5 part of altax.
The performance of the rubber plate of this formula through plasticating, in performance test and the embodiment 1 of the rubber plate that technological process produces such as mixing, calendering is extruded is close.
Embodiment 3
Corrosion protective lining chloroprene rubber plate for sea water conveying pipelines, component by following parts by weight forms: 100 parts of chloroprene rubbers, 3 parts of stearic acid, 6 parts of resins, 2 parts of processing aids, 30 parts of semi-reinforcing hydrocarbon blacks, 30 parts of thermalss, 40 parts of talcum powder, subtract 15 parts of third fractional oils, 25 parts, plumbous oxide, 2 parts of altaxs.
The performance of the rubber plate of this formula through plasticating, in performance test and the embodiment 1 of the rubber plate that technological process produces such as mixing, calendering is extruded is close.
Embodiment 4
Corrosion protective lining chloroprene rubber plate for sea water conveying pipelines, component by following parts by weight forms: 100 parts of chloroprene rubbers, 2.25 parts of stearic acid, 4.5 parts of resins, 1.5 parts of processing aids, 22.5 parts of semi-reinforcing hydrocarbon blacks, 37.5 parts of thermalss, 30 parts of talcum powder, subtract 11.5 parts of third fractional oils, 20 parts, plumbous oxide, 1 part of altax.
The performance of the rubber plate of this formula through plasticating, in performance test and the embodiment 1 of the rubber plate that technological process produces such as mixing, calendering is extruded is close.

Claims (2)

1. corrosion protective lining chloroprene rubber plate for sea water conveying pipelines, is characterized in that: the component by following parts by weight forms:
100 parts of chloroprene rubbers, stearic acid 1.5-3 part, resin 3-6 part, processing aid 1-2 part, semi-reinforcing hydrocarbon black 15-30 part, thermals 30-45 part, talcum powder 20-40 part, subtracts third fractional oil 8-15 part, plumbous oxide 15-25 part, altax 0.5-2 part.
2. corrosion protective lining chloroprene rubber plate for sea water conveying pipelines as claimed in claim 1, is characterized in that: the component by following parts by weight forms:
100 parts of chloroprene rubbers, 2 parts of stearic acid, 5 parts of resins, 2 parts of processing aids, 20 parts of semi-reinforcing hydrocarbon blacks, 40 parts of thermalss, 30 parts of talcum powder, subtract 10 parts of third fractional oils, 20 parts, plumbous oxide, 1 part of altax.
CN201410218405.2A 2014-05-22 2014-05-22 Sea water conveying pipelines corrosion protective lining chloroprene rubber plate Active CN103980576B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410218405.2A CN103980576B (en) 2014-05-22 2014-05-22 Sea water conveying pipelines corrosion protective lining chloroprene rubber plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410218405.2A CN103980576B (en) 2014-05-22 2014-05-22 Sea water conveying pipelines corrosion protective lining chloroprene rubber plate

Publications (2)

Publication Number Publication Date
CN103980576A true CN103980576A (en) 2014-08-13
CN103980576B CN103980576B (en) 2015-11-04

Family

ID=51272759

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410218405.2A Active CN103980576B (en) 2014-05-22 2014-05-22 Sea water conveying pipelines corrosion protective lining chloroprene rubber plate

Country Status (1)

Country Link
CN (1) CN103980576B (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104479184A (en) * 2014-12-22 2015-04-01 青岛科技大学 Composite material and preparation method thereof
CN106577430A (en) * 2016-12-19 2017-04-26 浙江海洋大学 Ocean ecological aquaculture net cage
CN106719212A (en) * 2016-12-19 2017-05-31 浙江海洋大学 A kind of Multifunctional marine netting cases for ecological culture
CN110901094A (en) * 2019-12-17 2020-03-24 蒂普拓普(天津)橡胶技术有限公司 Wear-resistant lining plate and manufacturing method and equipment thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1139690A (en) * 1995-07-03 1997-01-08 张庆虎 Room temp. self-sulfurizing rubber-isobutylene lining
CN102206370A (en) * 2011-05-05 2011-10-05 天津鹏翎胶管股份有限公司 Chloroprene rubber composition
CN102993475A (en) * 2012-11-30 2013-03-27 西安致泰橡塑工业有限公司 High-strength slurry pump rubber lining

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1139690A (en) * 1995-07-03 1997-01-08 张庆虎 Room temp. self-sulfurizing rubber-isobutylene lining
CN102206370A (en) * 2011-05-05 2011-10-05 天津鹏翎胶管股份有限公司 Chloroprene rubber composition
CN102993475A (en) * 2012-11-30 2013-03-27 西安致泰橡塑工业有限公司 High-strength slurry pump rubber lining

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
谢忠麟等: "《橡胶实用配方大全 第二版》", 29 February 2004, 化学工业出版社 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104479184A (en) * 2014-12-22 2015-04-01 青岛科技大学 Composite material and preparation method thereof
CN106577430A (en) * 2016-12-19 2017-04-26 浙江海洋大学 Ocean ecological aquaculture net cage
CN106719212A (en) * 2016-12-19 2017-05-31 浙江海洋大学 A kind of Multifunctional marine netting cases for ecological culture
CN110901094A (en) * 2019-12-17 2020-03-24 蒂普拓普(天津)橡胶技术有限公司 Wear-resistant lining plate and manufacturing method and equipment thereof
CN110901094B (en) * 2019-12-17 2021-09-03 蒂普拓普(天津)橡胶技术有限公司 Wear-resistant lining plate and manufacturing method and equipment thereof

Also Published As

Publication number Publication date
CN103980576B (en) 2015-11-04

Similar Documents

Publication Publication Date Title
CN103980576B (en) Sea water conveying pipelines corrosion protective lining chloroprene rubber plate
CN111117423B (en) Elastic epoxy resin coating and preparation method thereof
MX353180B (en) Corrosion resistant equipment for oil and/or gas applications.
CN108485467A (en) A kind of marine anticorrosion composite coating and preparation method thereof
Chandrasekaran Anticorrosive rubber lining: a practical guide for plastics engineers
CN107974172A (en) High-wearing feature anticorrosive paint
CN104405965B (en) The plastic composition pipeline of a kind of biochemical pharmacy
CN104387924A (en) Highly corrosion-resistant shop primer
CN107057519A (en) Anticorrosive paint
CN104277259A (en) Wear-resistant rubber pad
CN106011667A (en) Weather-resistant corrosion-resistant straight seam submerged arc welding steel pipe
CN105504935A (en) Novel anti-corrosive and wear-proof coating layer
CN101875808B (en) Epoxy glass flake anticorrosive paint
CN106833266A (en) Epoxy coal tar anti-corrosive paint
CN204153333U (en) A kind of anticorrosion seamless steel pipe for boats and ships
CN103254738A (en) Flexible corrosion-resistant epoxy resin coating material
CN107641429A (en) Produce a kind of method of the powdery paints for submarine pipeline
CN107629629A (en) A kind of weather-proof water-repellent paint of anti-corrosion
CN103709898A (en) Heavy-sizing type anti-corrosive paint for anti-static hollow glass bead
CN104087164B (en) A kind of Cover of cabin coating
CN103725157A (en) Anti-corrosion abrasion-proof polyethylene pipe
CN218376363U (en) Integrated sleeve milling pipe
CN203628237U (en) Anti-corrosion seamless steel tube
CN216473009U (en) Novel corrosion-resistant die alloy steel
CN107805440A (en) A kind of powdery paints for submarine pipeline

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Chloroprene rubber sheets with anti-corrosion lining for seawater transportation pipelines

Granted publication date: 20151104

Pledgee: Jingjiang sub branch of Postal Savings Bank of China Ltd.

Pledgor: JIANGSU KAI-YUAN ENVIRONMENTAL TECHNOLOGY ENGINEERING Co.,Ltd.

Registration number: Y2024980001642

PE01 Entry into force of the registration of the contract for pledge of patent right