CN114471132B - Additive for carbon mineralization product and preparation method and application thereof - Google Patents
Additive for carbon mineralization product and preparation method and application thereof Download PDFInfo
- Publication number
- CN114471132B CN114471132B CN202111674577.7A CN202111674577A CN114471132B CN 114471132 B CN114471132 B CN 114471132B CN 202111674577 A CN202111674577 A CN 202111674577A CN 114471132 B CN114471132 B CN 114471132B
- Authority
- CN
- China
- Prior art keywords
- carbon
- additive
- change material
- phase change
- solid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 62
- 239000000654 additive Substances 0.000 title claims abstract description 36
- 230000000996 additive effect Effects 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 5
- 230000033558 biomineral tissue development Effects 0.000 title abstract description 39
- 239000000463 material Substances 0.000 claims abstract description 26
- 239000011148 porous material Substances 0.000 claims description 27
- 230000008859 change Effects 0.000 claims description 21
- 239000007791 liquid phase Substances 0.000 claims description 19
- 239000012782 phase change material Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 12
- 239000002131 composite material Substances 0.000 claims description 11
- 239000002893 slag Substances 0.000 claims description 11
- 229920001684 low density polyethylene Polymers 0.000 claims description 9
- 239000004702 low-density polyethylene Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000012071 phase Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 238000004806 packaging method and process Methods 0.000 claims description 5
- 230000007704 transition Effects 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 238000005538 encapsulation Methods 0.000 claims description 4
- 239000003365 glass fiber Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 238000001179 sorption measurement Methods 0.000 claims description 4
- 239000010451 perlite Substances 0.000 claims description 3
- 235000019362 perlite Nutrition 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 3
- 239000004642 Polyimide Substances 0.000 claims description 2
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 239000008262 pumice Substances 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims description 2
- 238000007873 sieving Methods 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 14
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 7
- 239000001569 carbon dioxide Substances 0.000 abstract description 7
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 238000003763 carbonization Methods 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 13
- 239000002994 raw material Substances 0.000 description 9
- 230000008569 process Effects 0.000 description 8
- 239000002440 industrial waste Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000003094 microcapsule Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000009417 prefabrication Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention belongs to the technical field of carbon dioxide mineralization, and in particular relates to an additive for a carbon mineralization product, a preparation method and application thereof. The additive is applied to a carbon mineralization product, can assist the carbon mineralization product to establish an effective carbon mineralization channel, improves the homogeneity of materials, obviously improves the carbon fixing capability of the carbon mineralization product and has lower production energy consumption.
Description
Technical Field
The invention belongs to the technical field of carbon dioxide mineralization, and particularly relates to an additive for a carbon mineralization product, and a preparation method and application thereof.
Background
In recent years, atmospheric CO has been affected by human activities such as fossil fuel combustion 2 The content is increased suddenly, and the global threat of climate warming, sea level rising and the like is caused by the heat preservation effect. Carbon dioxide sequestration is becoming a research hotspot, where carbon mineralization technology is considered to be the most powerful carbon sequestrationSealing technology for potential and application prospect, which seals CO 2 Is fixed in carbon-carrying substances to achieve the aim of efficiently sealing CO 2 Is a target of (a).
However, the carbon mineralization reaction has the characteristic of diffusion carbonization from outside to inside, and as the carbon mineralization reaction proceeds, the surface density of the material increases, the carbon mineralization channels gradually decrease, and CO is prevented 2 Diffuse into the interior of the material, thereby affecting the carbon fixation effect and the quality of the carbon mineralized product. Conditions affecting the carbon mineralization reaction at the present stage include pressure, solid-liquid ratio, gas humidity, solid particle size and the like, but optimizing the reaction conditions cannot fundamentally solve the influence of a product carbon mineralization channel, carbon mineralization efficiency and carbon mineralization depth on the later carbonization maintenance of the product.
Disclosure of Invention
In view of the above, the present invention provides an additive for a carbon mineralization product, which can assist the carbon mineralization product to establish an effective carbon mineralization channel, accelerate the absorption rate of carbon dioxide, and significantly improve the carbon fixation effect.
The technical scheme of the invention is as follows:
in one aspect, the invention provides an additive for a carbon mineralization article, the additive comprising a solid-liquid phase change material and a porous material, the solid-liquid phase change material being wrapped on the surface of the porous material.
Preferably, the phase transition temperature interval of the solid-liquid phase transition material is 35-70 ℃.
Preferably, the solid-liquid phase change material is one of paraffin, paraffin-expanded perlite composite phase change material, paraffin-low density polyethylene composite phase change material, polyimide and binary fatty acid.
Preferably, the porous material is one or more of hollow glass fiber, zeolite, mesoporous silica, slag, gangue slag, pumice and the like. It should be noted that the size of the porous material in the additive is related to the size of the finished product of the carbonaceous mineralized product and the size of the particle size of the raw material, especially the larger the size of the finished product is, the larger the size of the carbonaceous mineralized product is, and the larger the maximum size of the porous material can be, the proper size can be determined through a limited number of experiments, and the invention is not limited in this respect.
The second aspect of the present invention provides a process for preparing the above additive comprising the steps of:
s1, rapidly stirring a solid-liquid phase change material under heat treatment until the solid-liquid phase change material is completely in a liquid state;
s2, sieving the porous material, and adding the sieved porous material into the liquid phase change material according to a certain proportion for uniform mixing;
s3, packaging the mixture obtained in the step S2.
Preferably, the temperature of the heat treatment is 50-100 ℃, and the time of the heat treatment is 10-30 min.
Preferably, the mass ratio of the porous material to the solid-liquid phase material in the step S2 is 100:5-20.
Preferably, the encapsulation treatment mode is one of soaking adsorption, shaping of high polymer and microencapsulation; more preferably, the encapsulation treatment is microencapsulation. It should be noted that, the above packaging manner is a common packaging manner of phase change materials, and specific operations may refer to the prior art and will not be described again.
In a third aspect, the invention provides the use of said additive in the preparation of a carbon mineralized article, the additive being added in an amount of greater than 0 and less than or equal to 30% by weight. The carbon mineralization product is capable of fixing CO 2 Specifically comprising the fixation of CO by adsorption 2 And using CO 2 Reacts with silicate minerals (natural minerals or industrial waste rich in Ca, mg and the like) to generate stable carbonate products so as to fix CO 2 Is a product of (a).
The beneficial effects of the invention are as follows: the additive can establish a carbonization channel in the carbon mineralization product, so that the uniform maintenance of carbon dioxide is realized, the homogeneity of the material is improved, and the condition of clamping is avoided; the porous material is utilized to establish a moisture channel, and the opening and closing of the channel are controlled through the state change of the phase change material, so that the free exchange of water vapor is realized, and the defect of expansion stress caused by overlarge internal vapor pressure is avoided; under the same pressure, the additive can make the mineralization depth of carbon in the mineralized product prefabricated member deeper, the carbonization is more complete, and the carbonization energy consumption is lower.
Detailed Description
The present invention will be described in further detail with reference to the following examples in order to make the objects, technical solutions and advantages of the present invention more apparent. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the invention.
Example 1
An additive for a carbon mineralized article, the preparation process comprising: taking 500 parts of slag and 50 parts of paraffin-low density polyethylene composite phase-change material, stirring the paraffin-low density polyethylene composite phase-change material at 80 ℃ for 20min, adding the slag, uniformly mixing, and carrying out microencapsulation treatment.
Adding the additive into the raw materials of the carbon mineralized product according to the mixing amount of 0%, 2%, 4%, 6%, 8% and 10% (mass fraction) of the carbon mineralized product, stirring and mixing uniformly, and carbonizing the formed product prefabricated member for 24 hours under the carbonization pressure of 0.1MPa and the carbonization temperature of 50 ℃ to obtain the finished product. The raw material of the carbon mineralized products in this example is industrial waste containing silicate.
Example 2
An additive for a carbon mineralized article, the preparation process comprising: taking 600 parts of slag and 100 parts of paraffin-low density polyethylene, stirring the paraffin-low density polyethylene composite phase-change material at 80 ℃ for 20min, adding the slag, uniformly mixing, and carrying out microencapsulation treatment.
The additive is added into raw materials (industrial waste material same as that of the example 1) of the carbon mineralized product according to the mixing amount of 0 percent and 6 percent (mass fraction) of the carbon mineralized product, and the mixture is stirred and mixed uniformly, and a pressing process is adopted to carry out 1h, 12h, 24h, 36h, 48h and 72h on a formed product prefabricated member under the condition of the carbonization pressure of 0.1MPa and 50 ℃.
Example 3
An additive for a carbon mineralized article, the preparation process comprising: taking 300 parts of hollow glass fiber and 20 parts of paraffin-expanded perlite composite phase-change material, stirring the paraffin-low density polyethylene composite phase-change material at 70 ℃ for 30min, adding the hollow glass fiber, uniformly mixing, and carrying out microencapsulation treatment.
The additive is added into raw materials of a carbon mineralized product (the same industrial waste as in example 1) according to the doping amount of 6 percent of the carbon mineralized product, and the raw materials are stirred and mixed uniformly, and a pressing process is adopted to carbonize the formed product prefabricated member for 24 hours under the condition of the carbonization pressure of 0.1MPa and the temperature of 50 ℃ to obtain a finished product.
Example 4
An additive for a carbon mineralized article, the preparation process comprising: taking 500 parts of slag and 50 parts of paraffin-low density polyethylene composite phase-change material, stirring the paraffin-low density polyethylene composite phase-change material at 80 ℃ for 20min, adding the slag, uniformly mixing, and carrying out soaking adsorption treatment.
The additive is added into raw materials (same industrial waste as in example 1) of the carbon mineralized product according to the doping amount of 8 percent of the carbon mineralized product, and the raw materials are stirred and mixed uniformly, and the formed product prefabricated member is carbonized for 24 hours under the condition of the carbonization pressure of 0.1MPa and the carbonization pressure of 50 ℃ to obtain a finished product.
The carbon fixation rates of the products prepared in the above examples at different additive amounts in example 1 are shown in table 1, wherein the carbon fixation rate is measured by:
carbon fixation = (oven dry mass of carbonized product-oven dry mass of carbonized product)/(oven dry mass of carbonized product).
TABLE 1
| Additive amount (%) | 0 | 2 | 4 | 6 | 8 | 10 |
| Carbon fixation (percent) | 5 | 10 | 16 | 23 | 31 | 38 |
The carbon mineralization depth test was carried out by the burn-out method using the products of example 1 with 0% and 8% of the additive, and the test results are shown in table 2.
TABLE 2
| Mineralization depth (cm) | 1 | 2 | 3 | 4 | 5 |
| Degree of carbonization without additives (%) | 20 | 18 | 10 | 6 | 3 |
| The additive content was 8% carbonization (%) | 37 | 35 | 30 | 25 | 15 |
The products prepared in example 2 at different carbonization times were subjected to flexural and compressive strength tests, and the results are shown in Table 3.
TABLE 3 Table 3
| Carbonization time (h) | 1 | 12 | 24 | 36 | 48 | 72 |
| Compressive Strength (MPa) at 6% blend | 9 | 13 | 16 | 18 | 20 | 23 |
| Additive-free compressive Strength (MPa) | 5 | 6.8 | 11 | 13 | 15.5 | 17 |
| Flexural strength (MPa) of 6% by weight | 1.5 | 2.8 | 4.2 | 4.4 | 4.6 | 5 |
| Flexural Strength (MPa) without additives | 0.8 | 1.8 | 2.5 | 3 | 3.2 | 3.4 |
From the conclusion, the additive prepared by the invention can effectively improve the depth and degree of carbon mineralization of the product, and ensures that the product has enough compression resistance and bending strength.
According to the invention, the porous material is taken as a framework, and is modified by adopting the solid-liquid phase change material, and the modified porous material can construct a carbon mineralization reaction channel in the prefabricated member, so that moisture and carbon dioxide gas can freely migrate in the carbon mineralization process, and the rapid and uniform reaction of carbon dioxide in the prefabricated member under the low pressure condition is realized, thereby solving the problem of 'inside-outside difference' caused by different carbonization degrees of the prefabricated member.
More importantly, the phase change material introduced by the invention solidifies and plugs pores at normal temperature, avoids the negative influence of high water absorbability of the pores on the working performance of the material, and generates phase change reaction under the thermal condition of carbon mineralization reaction (exothermic reaction), thereby realizing the regulation and control of the pore state of the porous material, and specifically comprises the following steps: in the carbon mineralization process, the phase change material is melted, a channel is opened, free exchange and migration of water and gas are realized, and the defect of internal expansion stress of the material caused by overhigh internal water vapor pressure due to overhigh carbon mineralization reaction speed is avoided; after mineralization reaction is completed, when the temperature is restored to normal temperature, the phase change material is solidified to block the air holes, thereby blocking the corrosion and pollution of harmful impurities in the environment to the inside of the product and improving the durability of the carbonized product. In addition, the product prepared in the example 4 is slightly lower than the products prepared in the examples 1 and 2 in terms of carbon fixation rate and fracture and compression strength, which shows that the microencapsulation mode is more beneficial to playing the role of the additive; the microcapsule packaging mode continuously wraps the surface of the porous material with a film formed by the phase change material, so that the structural performance of the porous material is not damaged in the prefabrication process, the microcapsule form is damaged due to carbonization pressure and flow friction of gas in the carbon mineralization process, and the part of the porous material is exposed, so that the function of constructing a carbon mineralization water-gas channel is achieved.
It should be noted that the phase transition temperature of the solid-liquid phase change material has an important influence on the additive effect, and the solid-liquid phase change material should realize solid-liquid state transition under the reaction heat of the product carbon mineralization process, so as to ensure the opening of the pores of the porous material, and after the reaction is finished and the normal temperature is restored, the solid-liquid phase change material is solidified again to form a solid, so that the pores of the porous material are plugged. Therefore, according to the reaction heat in the carbon mineralization process, the phase change temperature interval of the solid-liquid phase change material is determined to be 35-70 ℃, and when the inventors use the phase change material with the phase change temperature interval of more than 70 ℃ to encapsulate slag, the formed additive is in an equivalent doping amount (the raw materials of the used carbon mineralization product are the same as those of the embodiment 1), and the carbon fixation rate of the obtained product is obviously lower than that of the embodiment 1.
The above-described embodiments of the present invention do not limit the scope of the present invention. Any other corresponding changes and modifications made in accordance with the technical idea of the present invention shall be included in the scope of the claims of the present invention.
Claims (6)
1. An additive for a carbon mineralized article, characterized in that the additive comprises a solid-liquid phase change material and a porous material, the solid-liquid phase change material being wrapped on the surface of the porous material; the porous material is one or more of hollow glass fiber, zeolite, mesoporous silica, slag, gangue slag and pumice, the phase transition temperature interval of the solid-liquid phase change material is 35-70 ℃, and the solid-liquid phase change material is one of paraffin, paraffin-expanded perlite composite phase change material, paraffin-low density polyethylene composite phase change material, polyimide and binary fatty acid.
2. A process for preparing the additive of claim 1, comprising the steps of:
s1, rapidly stirring a solid-liquid phase change material under heat treatment until the solid-liquid phase change material is completely in a liquid state;
s2, sieving the porous material, and then adding the sieved porous material into the solid-liquid phase-change material for uniform mixing;
s3, packaging the mixture.
3. The method according to claim 2, wherein the temperature of the heat treatment is 50-100 ℃, and the time of the heat treatment is 10-30 min.
4. The method of claim 2, wherein the encapsulation is performed by one of soaking adsorption, shaping of a polymer, and microencapsulation.
5. The method of claim 4, wherein the encapsulation is by microencapsulation.
6. The use of the additive according to claim 1 for the preparation of a carbon mineralized article, wherein the additive is added in an amount of more than 0 and less than or equal to 30% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111674577.7A CN114471132B (en) | 2021-12-31 | 2021-12-31 | Additive for carbon mineralization product and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111674577.7A CN114471132B (en) | 2021-12-31 | 2021-12-31 | Additive for carbon mineralization product and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114471132A CN114471132A (en) | 2022-05-13 |
| CN114471132B true CN114471132B (en) | 2023-10-24 |
Family
ID=81508469
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111674577.7A Active CN114471132B (en) | 2021-12-31 | 2021-12-31 | Additive for carbon mineralization product and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114471132B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115433337B (en) * | 2022-08-31 | 2023-06-27 | 合肥工业大学 | Induced mineralizing agent and application thereof in inducing mineralization to promote regeneration of micro powder carbon fixation |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1896173A (en) * | 2006-06-24 | 2007-01-17 | 浙江华特实业集团华特化工有限公司 | Production of inorganic-phase variable composite material of membrane-coated porous adsorptive |
| JP2010142679A (en) * | 2008-12-16 | 2010-07-01 | Aisan Ind Co Ltd | Heat storage medium-imparted combined adsorbing material and method for producing the same |
| CN103102869A (en) * | 2011-11-09 | 2013-05-15 | 中国石油化工股份有限公司 | Manufacturing method of phase change material |
| CN103752239A (en) * | 2014-02-11 | 2014-04-30 | 北京科技大学 | Preparation method of metal organic framework coated phase-change material microcapsule |
| CN106622140A (en) * | 2015-11-03 | 2017-05-10 | 中国石油化工股份有限公司 | Composite zeolitic imidazolate framework material as well as preparation method and application thereof |
| CN109650805A (en) * | 2018-11-26 | 2019-04-19 | 徐州工程学院 | A method of carbon sequestration fill paste is prepared using discarded concrete |
| CN110804422A (en) * | 2019-11-18 | 2020-02-18 | 中南大学 | Preparation method of paraffin-cement-based shape-stabilized phase change material |
-
2021
- 2021-12-31 CN CN202111674577.7A patent/CN114471132B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1896173A (en) * | 2006-06-24 | 2007-01-17 | 浙江华特实业集团华特化工有限公司 | Production of inorganic-phase variable composite material of membrane-coated porous adsorptive |
| JP2010142679A (en) * | 2008-12-16 | 2010-07-01 | Aisan Ind Co Ltd | Heat storage medium-imparted combined adsorbing material and method for producing the same |
| CN103102869A (en) * | 2011-11-09 | 2013-05-15 | 中国石油化工股份有限公司 | Manufacturing method of phase change material |
| CN103752239A (en) * | 2014-02-11 | 2014-04-30 | 北京科技大学 | Preparation method of metal organic framework coated phase-change material microcapsule |
| CN106622140A (en) * | 2015-11-03 | 2017-05-10 | 中国石油化工股份有限公司 | Composite zeolitic imidazolate framework material as well as preparation method and application thereof |
| CN109650805A (en) * | 2018-11-26 | 2019-04-19 | 徐州工程学院 | A method of carbon sequestration fill paste is prepared using discarded concrete |
| CN110804422A (en) * | 2019-11-18 | 2020-02-18 | 中南大学 | Preparation method of paraffin-cement-based shape-stabilized phase change material |
Non-Patent Citations (1)
| Title |
|---|
| "Development of leak-free phase change material aggregates";Sarra Drissi et al.;《Construction and Building Materials》;第230卷;全文 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114471132A (en) | 2022-05-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN114471132B (en) | Additive for carbon mineralization product and preparation method and application thereof | |
| CN108003960B (en) | Biomass fuel for iron ore sintering and preparation method and application thereof | |
| CN103691399A (en) | Preparation method of high-performance carbon molecular sieve for separating carbon dioxide/methane | |
| CN110745825A (en) | Preparation method of high-performance biomass-based shaddock peel oriented activated carbon VOCs adsorbent | |
| CN101961644A (en) | Chloride-carbonaceous skeleton composite adsorbent and preparation method thereof | |
| CN107804848B (en) | Preparation method of straw-based porous activated carbon with activated surface | |
| CN114797766A (en) | Porous biochar and preparation method and application thereof | |
| CN111847938A (en) | Method for producing environment-friendly ceramsite by utilizing biogas residue hydrothermal carbon | |
| CN114538408A (en) | Method for preparing high electrocatalytic activity biochar through micro-aerobic pyrolysis | |
| CN110801821A (en) | High-temperature hydrogen sulfide removal composite adsorbent and preparation method and application thereof | |
| CN111994908B (en) | Preparation method of biomass charcoal for reducing nitrogen and phosphorus in soil | |
| CN109467070A (en) | Nitrogenous porous carbon aerogels of one kind and preparation method thereof | |
| CN115124273A (en) | Carbonized internal curing agent and preparation method and application thereof | |
| CN115626798B (en) | Carbon capturing concrete based on metal organic framework material and preparation method thereof | |
| CN113735118B (en) | Preparation method for improving production efficiency of coal-based activated carbon | |
| CN109179372B (en) | High-performance biological cellulose carbon aerogel and preparation method and application thereof | |
| CN100588457C (en) | Shaping method for super absorbent charcoal powder body for adsorbing CO2 | |
| CN116553542A (en) | Method for preparing high-performance coconut shell activated carbon through gasification activation and application of high-performance coconut shell activated carbon | |
| CN115974076A (en) | Preparation method and application of hydrothermal nitrogen-doped cork-based activated carbon | |
| CN107445590B (en) | Preparation method of sintered hollow brick | |
| GB2619195A (en) | Preparation method for carbon dioxide capture agent, and application thereof | |
| CN115404079A (en) | Method for preparing soil conditioner by virtue of co-pyrolysis of ceramsite and biochar | |
| CN114572980A (en) | Porous activated carbon material and preparation method and application thereof | |
| CN113893815A (en) | Ceramsite-zeolite composite high-performance adsorbing material and preparation method thereof | |
| Yeshun et al. | Study on preparation and desulfurization characteristics of biomass activated carbon by microwave heating CO2 activation method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |