CN114471105A - Solid waste incinerator tail gas treatment process - Google Patents
Solid waste incinerator tail gas treatment process Download PDFInfo
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- CN114471105A CN114471105A CN202111650421.5A CN202111650421A CN114471105A CN 114471105 A CN114471105 A CN 114471105A CN 202111650421 A CN202111650421 A CN 202111650421A CN 114471105 A CN114471105 A CN 114471105A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/54—Nitrogen compounds
- B01D53/56—Nitrogen oxides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/02—Particle separators, e.g. dust precipitators, having hollow filters made of flexible material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
- B01D47/06—Spray cleaning
- B01D47/08—Spray cleaning with rotary nozzles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/38—Removing components of undefined structure
- B01D53/40—Acidic components
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C3/00—Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
- B03C3/017—Combinations of electrostatic separation with other processes, not otherwise provided for
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/206—Organic halogen compounds
- B01D2257/2064—Chlorine
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
Abstract
The invention provides a process for treating tail gas of a solid waste incinerator, which comprises a denitration unit, a primary dedusting and deacidification unit, a hazardous waste adsorption unit, a secondary dedusting unit and a discharge unit which are sequentially connected through a flue. According to the invention, the primary dust removal device is added before the activated carbon adsorbs dangerous solid wastes such as dioxin, heavy metals and the like, so that part of common solid wastes are collected, the integral dust removal rate is improved, and the content of the common solid wastes in the dangerous wastes collected by the secondary dust removal device is reduced, thereby reducing the treatment capacity of the dangerous wastes and reducing the treatment cost.
Description
Technical Field
The invention belongs to the field of tail gas treatment, and particularly relates to a process for treating tail gas of a solid waste incinerator.
Background
In recent years, with the development of the economic level of China and the improvement of the living standard of people, various solid waste garbage is increasing day by day. At present, the treatment of solid waste is mainly sanitary landfill and incineration. In recent years, the solid waste treatment market is developed rapidly, the market prospect is wide, and incineration power generation gradually replaces landfill and becomes a main mode of solid waste treatment. The solid waste mainly comprises domestic waste and production waste, the solid waste has complex general components, high water content and low heat value, and the solid waste is burnt insufficiently and is easy to generate secondary pollution. The tail gas after solid waste incineration mostly contains acidic gases (such as NO)X、HCl、SOXHF, etc.), dioxin (PCDDS/PCDFS), and heavy metals (Hg, Pb), which would cause serious environmental pollution if discharged directly without treatment.
The paper "research on waste incineration flue gas purification process" (LinYuze; Yangchang; Sungqi; Zhang break Yu; Huangyueqin; research on waste incineration flue gas purification process [ J ]; scientific technological innovation; 32 years 2018; page 151-) -152) indicates that:
the Shanghai Jiangqiao domestic waste incineration plant adopts the processes of 'SNCR (urea) + dry method + bag-type dust remover + wet washing tower', and simultaneously sprays slaked lime and activated carbon in front of the bag-type dust remover to treat flue gas, and the energy expansion project is characterized in that a wet deacidification system is added behind the dust remover, and the dry method + wet method process can ensure that the removal rates of HCl and SO2 are respectively 99% and 97%.
A large-roof mountain garbage incineration plant in a large continuous development area adopts the processes of SNCR (urea), a semi-dry method, a dry method (sodium bicarbonate), activated carbon injection and a bag-type dust remover, an absorbent is lime slurry, the sodium bicarbonate is reserved, and the index of flue gas after treatment is far ahead of the national standard.
A waste incineration power plant in Haian county of Nantong city of Jiangsu province adopts the processes of SNCR (urea), a semi-dry method, a dry method (sodium bicarbonate), activated carbon injection, a bag type dust collector and SCR, and adopts a low-temperature SCR technology and TiO2 as a catalyst carrier, so that various pollutants can meet the requirements of European Union environmental standard system 2000.
At present, the waste incineration plants in China mainly adopt the processes of SNCR, semi-dry deacidification, activated carbon injection and bag-type dust remover to treat smoke, and can meet the current national emission standard of pollutants in smoke. However, the content of dust in the flue gas at the outlet of the incinerator is generally 20g/Nm3, the dust is mostly non-combustible inorganic matter, combustible components are changed into gas through combustion, and the gas contains a lot of acidic substances, and toxic gases such as dioxin (PCDDS/PCDFS) and heavy metals (Hg and Pb) and the like. Although the toxic gas can be removed by the process, the toxic and harmful gas pollutants are completely collected into the dedusting ash by the bag-type dust collector, so that a large amount of dedusting ash cannot be comprehensively utilized, the yield of the dedusting ash is high, and the treatment cost is increased due to large amount of the dedusting ash during treatment.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides a process for treating tail gas of a solid waste incinerator so as to reduce the treatment capacity of hazardous waste.
In order to achieve the purpose, the invention adopts the following technical scheme:
the utility model provides a solid useless incinerator tail gas treatment process, include the denitration unit that connects gradually through the flue, one-level dust removal deacidification unit, the useless adsorption unit of danger, second grade dust removal unit and discharge unit, burn the useless produced tail gas of solid in the boiler and remove nitric oxide through the denitration unit earlier, then remove ordinary solid useless and acid gas at one-level dust removal deacidification unit, after the useless adsorption unit of danger adsorbs the dangerous solid useless, second grade dust removal unit will be dangerous and useless admittedly handle, tail gas discharges through the discharge unit at last.
Further, the denitration unit is an SNCR denitration device.
Further, the primary dedusting and deacidifying unit comprises an SDA deacidifying tower, a flue gas distributor is arranged at the top of the SDA deacidifying tower, a rotary atomizer is arranged at the top of the SDA deacidifying tower, and an ash bucket of the SDA deacidifying tower is connected with a fly ash conveying and storing system.
Further, the primary dedusting and deacidifying unit also comprises a first bag-type dust remover, the gas outlet of the SDA deacidifying tower is communicated with the inlet of the first bag-type dust remover, and the ash hopper of the first bag-type dust remover is also connected with a fly ash conveying and storing system.
Further, the primary dedusting and deacidifying unit further comprises an electric dust remover, the electric dust remover is arranged in an inlet flue of the SDA deacidifying tower, and an ash hopper of the electric dust remover is also connected with a fly ash conveying and storing system.
Furthermore, the dangerous waste adsorption unit is an activated carbon injection system, and an activated carbon nozzle of the activated carbon injection system is connected into a flue between the primary dedusting and deacidifying unit and the secondary dedusting unit.
Further, the secondary dust removal unit comprises a second bag-type dust remover, and an ash bucket of the second bag-type dust remover is connected with a dangerous solid waste conveying and storing system.
Further, the discharge unit comprises a chimney, and an induced draft fan is arranged in an inlet flue of the chimney.
Compared with the prior art, the invention has the beneficial effects that: according to the invention, the primary dust removal device is added before the activated carbon adsorbs dangerous solid wastes such as dioxin (PCDDS/PCDFS) and heavy metals (Hg, Pb) to collect part of common solid wastes, so that the overall dust removal rate is improved, the load of the dust remover is reduced, and the content of the common solid wastes in the dangerous wastes collected by the secondary dust removal device is reduced, thereby reducing the treatment capacity of the dangerous wastes and reducing the treatment cost.
Drawings
FIG. 1 is a schematic structural view of example 1 of the present invention;
FIG. 2 is a schematic structural diagram of example 2 of the present invention;
in the drawings, the components represented by the respective reference numerals are listed below:
1. SNCR denitrification facility, 2, SDA deacidification tower, 3, flue gas distributor, 4, flying dust transport storage system, 5, first sack cleaner, 6, electrostatic precipitator, 7, active carbon injection system, 8, second sack cleaner, 9, dangerous solid useless transport storage system, 10, chimney, 11, draught fan, 12, rotatory atomizer.
Detailed Description
The present invention is further described in detail below with reference to specific examples so that those skilled in the art can more clearly understand the present invention.
Example 1
The process for treating the tail gas of the solid waste incinerator shown in fig. 1 comprises an SNCR denitration device 1, an SDA deacidification tower 2, a first bag-type dust remover 5, an activated carbon injection system 7, a second bag-type dust remover 8 and a chimney 10 which are connected in sequence.
The ash bucket of the SDA deacidification tower 2 is connected with a fly ash conveying and storing system 4, the ash bucket of the first bag-type dust collector 5 is also connected with the fly ash conveying and storing system 4 to collect common solid waste, and the ash bucket of the second bag-type dust collector 8 is connected with a dangerous solid waste conveying and storing system 9 to collect dangerous solid waste.
The flue gas generated by incineration reacts under the action of the SNCR denitration device 1, so that nitrogen oxides in the flue gas are reduced by urea to form carbon dioxide and nitrogen, and the denitrated flue gas enters the SDA deacidification tower 2.
The SDA deacidification tower 2 removes acidic substances (sulfur dioxide, hydrogen chloride and hydrogen fluoride) in the flue gas by adopting a slaked lime slurry atomization spraying mode, partial dust in the flue gas is stored in an ash hopper at the lower part of the SDA deacidification tower 2 together with a deacidification product under the action of gravity, and a flue gas outlet is arranged at the lower part of the ash hopper of the SDA deacidification tower 2.
Specifically, the top of the SDA deacidification tower 2 is provided with a flue gas distributor 3 for guiding inlet flue gas, and the upper part in the SDA deacidification tower 2 is provided with a rotary atomizer 12 for atomizing and spraying lime slurry.
The flue gas after deacidification enters a first bag-type dust collector 5 through a flue gas outlet of an SDA deacidification tower 2 to remove particles in the flue gas, the first bag-type dust collector 5 is connected with a second bag-type dust collector 8 through a flue, an activated carbon nozzle of an activated carbon injection system 7 is connected into the flue between the first bag-type dust collector 5 and the second bag-type dust collector 8, activated carbon is injected into the flue between the first bag-type dust collector 5 and the second bag-type dust collector 8, and the injected activated carbon and dioxin (PCDDS/PCDFS) and heavy metals (Hg, Pb) in the flue gas are rapidly adsorbed and enter the second bag-type dust collector 8 along with the flue gas. The second bag-type dust collector 8 collects and stores activated carbon, dioxin (PCDDS/PCDFS), heavy metals (Hg, Pb), and the like in the flue gas in an ash hopper of the second bag-type dust collector 8.
The chimney 10 is provided with an induced draft fan 11 to accelerate the emission of the treated flue gas.
This embodiment sets up first sack cleaner 5 and second sack cleaner 8 respectively through the process around active carbon injection system 7, and ordinary solid useless is collected to first sack cleaner 5, and second sack cleaner 8 then collects the dangerous solid useless of active carbon adsorption, thereby reduce the ordinary content of giving up admittedly in the dangerous solid useless, thereby reduce the dangerous handling capacity of giving up admittedly, the use amount of curing agents such as cement promptly, reduce the treatment cost, simultaneously ordinary solid useless also can be according to the direct landfill of demand and handle or retrieve.
Example 2
The solid waste incinerator tail gas treatment process shown in fig. 2 comprises an SNCR denitration device 1, an electric dust remover 6, an SDA deacidification tower 2, an activated carbon injection system 7, a second bag-type dust remover 8 and a chimney 10 which are connected in sequence.
The ash bucket of the SDA deacidification tower 2 is connected with a fly ash conveying and storing system 4, the bottom ash bucket of the electric dust remover 6 is also connected with the fly ash conveying and storing system 4 to collect common solid waste, and the ash bucket of the second bag-type dust remover 8 is connected with a dangerous solid waste conveying and storing system 9 to collect dangerous solid waste.
The produced flue gas of burning reacts under the effect of SNCR denitrification facility 1 for nitrogen oxide in the flue gas is reduced by urea, forms carbon dioxide and nitrogen gas, and the flue gas after the denitration gets into electrostatic precipitator 6 and removes dust, gets rid of the non-organic matter dust that the burning produced in the flue gas, and this part dust is saved and is collected through electrostatic precipitator 6's ash bucket.
The SDA deacidification tower 2 removes acidic substances (sulfur dioxide and hydrogen chloride) in the flue gas by adopting a slaked lime slurry atomization spraying mode, the deacidification product is stored in an ash hopper at the lower part of the SDA deacidification tower 2, and a flue gas outlet is formed in the lower part of the ash hopper of the SDA deacidification tower 2.
Specifically, the top of the SDA deacidification tower 2 is provided with a flue gas distributor 3 for guiding inlet flue gas, and the upper part in the SDA deacidification tower 2 is provided with a rotary atomizer 12 for atomizing and spraying lime slurry.
The deacidified flue gas enters a second bag-type dust collector 8 through a flue gas outlet of the SDA deacidification tower 2, an activated carbon nozzle of the activated carbon injection system 7 is connected into a flue between the SDA deacidification tower 2 and the second bag-type dust collector 8, and the injected activated carbon, dioxin (PCDDS/PCDFS) and heavy metals (Hg, Pb) in the flue gas are quickly adsorbed and enter the second bag-type dust collector 8 along with the flue gas. The second bag-type dust collector 8 collects and stores activated carbon, dioxin (PCDDS/PCDFS), heavy metals (Hg, Pb), and the like in the flue gas in an ash hopper of the second bag-type dust collector 8.
The chimney 10 is provided with an induced draft fan 11 to accelerate the emission of the treated flue gas.
This embodiment sets up electrostatic precipitator 6 and second sack cleaner 8 respectively through the process around active carbon injection system 7, and electrostatic precipitator 6 collects ordinary useless admittedly, and second sack cleaner 8 then collects the dangerous useless admittedly of active carbon adsorption to reduce the content of the ordinary useless admittedly in the dangerous solid useless, thereby reduce the dangerous useless handling capacity admittedly, the quantity of use of curing agents such as cement promptly, reduce the treatment cost, simultaneously ordinary useless admittedly also can be according to the direct landfill of demand and handle or retrieve.
The mechanisms, components and parts of the present invention which are not described in detail are all the existing structures which exist in the prior art. Can be purchased directly from the market.
The above description is only for the preferred embodiment of the present invention, and is not intended to limit the scope of the present invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (8)
1. The utility model provides a solid useless incinerator tail gas treatment process, a serial communication port, include the denitration unit that connects gradually through the flue, one-level dust removal deacidification unit, the useless adsorption unit of danger, second grade dust removal unit and discharge unit, burn the produced tail gas of solid useless in the boiler and remove nitric oxide through denitration unit earlier, then remove ordinary solid useless and acid gas at one-level dust removal deacidification unit, after dangerous useless adsorption unit adsorbs dangerous solid useless through the danger, second grade dust removal unit will be dangerous and useless admittedly handle, tail gas discharges through discharge unit at last.
2. The solid waste incinerator tail gas treatment process according to claim 1, characterized in that said denitration unit is an SNCR denitration device (1).
3. The tail gas treatment process of the solid waste incinerator according to claim 1, wherein the primary dedusting and deacidification unit comprises an SDA deacidification tower (2), a flue gas distributor (3) is arranged at the top of the SDA deacidification tower (2), a rotary atomizer (12) is arranged at the top in the SDA deacidification tower (2), and a fly ash conveying and storing system (4) is connected to an ash hopper of the SDA deacidification tower (2).
4. The tail gas treatment process of the solid waste incinerator according to claim 3, wherein the primary dedusting and deacidification unit further comprises a first bag-type dust remover (5), the gas outlet of the SDA deacidification tower (2) is communicated with the inlet of the first bag-type dust remover (5), and the ash hopper of the first bag-type dust remover (5) is also connected with the fly ash conveying and storing system (4).
5. The tail gas treatment process of the solid waste incinerator according to claim 3, wherein the primary dedusting and deacidification unit further comprises an electric dust collector (6), the electric dust collector (6) is arranged in an inlet flue of the SDA deacidification tower (2), and an ash hopper of the electric dust collector is also connected with the fly ash conveying and storing system (4).
6. The tail gas treatment process of the solid waste incinerator according to claim 1, wherein the hazardous waste adsorption unit is an activated carbon injection system (7), and an activated carbon nozzle of the activated carbon injection system (7) is connected into a flue between the primary dedusting and deacidification unit and the secondary dedusting unit.
7. The solid waste incinerator tail gas treatment process according to claim 1, characterized in that the secondary dust removal unit comprises a second bag-type dust remover (8), and an ash bucket of the second bag-type dust remover (8) is connected with a dangerous solid waste conveying and storing system (9).
8. The solid waste incinerator tail gas treatment process according to claim 1, characterized in that said emission unit comprises a chimney (10), and an induced draft fan (11) is arranged in an inlet flue of said chimney (10).
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CN202111650421.5A CN114471105A (en) | 2021-12-30 | 2021-12-30 | Solid waste incinerator tail gas treatment process |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111006221A (en) * | 2019-12-02 | 2020-04-14 | 中节能清洁技术发展有限公司 | System and method for hazardous waste incineration |
CN210814645U (en) * | 2019-10-17 | 2020-06-23 | 同兴环保科技股份有限公司 | Waste incineration flue gas ultralow emission purification system |
CN112121614A (en) * | 2020-09-23 | 2020-12-25 | 山鹰国际控股股份公司 | Stable ultralow emission device and method for solid waste incineration flue gas |
CN112797429A (en) * | 2021-01-04 | 2021-05-14 | 冯承湖 | Double-dry deacidification method and system for hazardous waste incineration flue gas |
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- 2021-12-30 CN CN202111650421.5A patent/CN114471105A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN210814645U (en) * | 2019-10-17 | 2020-06-23 | 同兴环保科技股份有限公司 | Waste incineration flue gas ultralow emission purification system |
CN111006221A (en) * | 2019-12-02 | 2020-04-14 | 中节能清洁技术发展有限公司 | System and method for hazardous waste incineration |
CN112121614A (en) * | 2020-09-23 | 2020-12-25 | 山鹰国际控股股份公司 | Stable ultralow emission device and method for solid waste incineration flue gas |
CN112797429A (en) * | 2021-01-04 | 2021-05-14 | 冯承湖 | Double-dry deacidification method and system for hazardous waste incineration flue gas |
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