CN114441384A - Method, device and system for joint measurement of emulsifying capacity and emulsion stability of rotary fluid - Google Patents
Method, device and system for joint measurement of emulsifying capacity and emulsion stability of rotary fluid Download PDFInfo
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Abstract
This paper relates to petrochemical field, especially relates to a rotary fluid emulsification ability and emulsion stability allies oneself with survey method, device and system, sets up rotatory module in the emulsification test tube, rotatory module is arranged in driving the liquid rotation in the emulsification test tube, includes: respectively injecting a first liquid phase and a second liquid phase into the emulsification test tube to obtain the initial height of the first liquid phase; calculating the emulsification rate of the second liquid relative to the first liquid at a plurality of rotation speeds according to the initial height of the first liquid and the non-emulsification height of the first liquid at each rotation speed of the rotating module; determining the emulsion breaking rate of an emulsion formed by the first liquid phase and the second liquid phase according to the initial height of the first liquid phase and the height of the first liquid phase at a plurality of moments; determining an emulsification coefficient according to the emulsification rate; and determining the demulsification coefficient of the emulsion according to the demulsification rate. The scheme can stably adjust the rotating speed and the emulsifying temperature in the emulsifying process, obtain the dynamic information of the emulsifying process and the demulsifying process and obtain an accurate emulsifying performance joint measurement result.
Description
Technical Field
The invention relates to the field of petrochemical industry, in particular to a method, a device, a system, computer equipment and a storage medium for joint measurement of emulsifying capacity and emulsion stability of a rotary fluid.
Background
The test and evaluation of the oil-water emulsifying capacity and the emulsion stability are widely applied in the fields of food, medicine, chemical synthesis and the like. For example, in the field of petroleum development, especially in chemical flooding process containing surfactant, the evaluation of oil-water emulsifying capacity and emulsion stability plays a crucial role in perfecting the research and application of chemical flooding theory and technology
In the past, the emulsion preparation for testing the stability of the oil-water emulsion mainly adopts a shaking method, a test tube is shaken to enable oil water to vibrate up and down to form emulsion, a dynamic curve for reducing the amount of the emulsion is measured, the half-life period is determined, and the stability of the emulsion is evaluated. The method is simple and convenient. However, the manual shaking method is difficult to achieve scientific specification, the influence of human factors is large, the repeatability of experimental results is poor, and the temperature in the emulsification process cannot be controlled. Also, the emulsifying ability was evaluated by a mechanical shaking method which enables precise control of the emulsifying conditions and the temperature during the emulsification. Although the method for evaluating the stability of the emulsion based on mechanical shaking for preparing milk overcomes the defects of the hand shaking method, the method still has the following defects: firstly, the emulsification process cannot be judged, and only the final emulsification result is obtained; secondly, the test tube is seriously stuck to the wall in the shaking process, so that accurate reading is influenced; after the experiment is finished, the emulsification zone can be read only after standing for a period of time, the emulsification zone is not the original emulsification amount, and the emulsion can be broken in the waiting process; and fourthly, the external input energy in the traditional mechanical milk making process is always constant, so that the minimum disturbance energy generated by emulsification and the influence of the change of the external energy on the emulsification cannot be evaluated.
In addition, the prior art also adopts an ultrasonic emulsification method to evaluate the oil-water emulsification capability. However, due to the characteristics of ultrasonic conduction and the complex influence factors of energy attenuation, the ultrasonic energy and the distribution thereof in the emulsification pipe cannot be accurately controlled and measured, so that the oil-water emulsification part has uncertainty; in addition, the particle size of the emulsion formed by ultrasonic emulsification is very small, so that the emulsion stability cannot be evaluated by using the emulsion, and the joint measurement of the oil-water emulsifying capacity and the emulsion stability cannot be realized.
Aiming at the problem that the existing emulsion preparation method cannot accurately evaluate the oil-water emulsifying capacity and the emulsion stability, a method, a device and a system for jointly measuring the emulsifying capacity of the rotary fluid and the emulsion stability are needed.
Disclosure of Invention
In order to solve the above problems in the prior art, embodiments herein provide a method, an apparatus, a system, a computer device, and a storage medium for jointly measuring emulsion emulsifying capacity and emulsion stability of a rotary fluid, which solve the problems in the prior art.
Embodiments herein provide a method for disposing a rotating module in an emulsification test tube, where the rotating module is used to rotate liquid in the emulsification test tube, and the method includes: respectively injecting a first liquid phase and a second liquid phase into an emulsification test tube, and obtaining the initial height of the first liquid phase in the emulsification test tube; calculating the emulsification rate of the second liquid relative to the first liquid at a plurality of rotation speeds according to the initial height of the first liquid and the non-emulsification height of the first liquid at each rotation speed of the rotating module; calculating the emulsion breaking rate of the emulsion formed by the first liquid phase and the second liquid phase at a plurality of moments according to the initial height of the first liquid phase and the height of the first liquid phase at the plurality of moments after the rotating module stops; determining the emulsification coefficient of the second liquid relative to the first liquid phase according to the emulsification rate; and determining the demulsification coefficient of the emulsion according to the demulsification rate.
According to one aspect of embodiments herein, before injecting the first and second liquid phases into the emulsification test tube, respectively, comprises: determining the interfacial height of the first liquid phase and the second liquid phase according to the following formula:
wherein h isowIs the interfacial height of the first liquid phase and the second liquid phase under the test conditions, howsIs the interfacial height of the first liquid phase and the second liquid phase under standard conditions; etawsIs the viscosity, η, of the second liquid phase under standard conditionswIs the viscosity of the second liquid phase under the test conditions; c is the first and second liquidsPhase interface shear force similarity coefficient; and determining the initial height of the first liquid phase according to the preset ratio of the first liquid phase to the second liquid phase and the height of the interface.
According to one aspect of embodiments herein, calculating the emulsification rate of the second liquid relative to the first liquid at a plurality of rotational speeds according to the initial height of the first liquid and the un-emulsified height of the first liquid at each rotational speed of the rotating module in the emulsification test tube comprises: controlling a rotating module in the emulsification testing tube to rotate according to a preset rotating speed, and determining the non-emulsification height of the first liquid phase at the rotating speed after adjusting the rotating speed of the rotating module each time; according to the initial height of the first liquid phase and the non-emulsified height of the first liquid phase at each rotating speed, calculating the emulsification rate of the second liquid relative to the first liquid phase at each rotating speed by using the following formula:
where wi is the angular velocity of the rotating module, E0(wi) is the emulsification rate corresponding to angular velocity wi, ho0Is the initial height of the first liquid phase, hoi(wi) is the un-emulsified height of the first liquid phase corresponding to the angular velocity wi.
According to one aspect of embodiments herein, calculating the breaking rate of the emulsion formed by the first liquid phase and the second liquid phase at a plurality of times based on the initial height of the first liquid phase and the height of the first liquid phase at the plurality of times after the rotation module is stopped comprises: when the rotating module reaches the maximum rotating speed, acquiring the non-emulsified height of the first liquid phase; controlling a rotating module in the emulsification testing tube to stop rotating, and obtaining the height of a first liquid phase at a plurality of moments in a static state; determining the demulsification amount of the first liquid phase at a plurality of moments according to the non-emulsified height of the first liquid phase and the heights of the first liquid phase at the plurality of moments; determining an initial emulsification amount of the first liquid phase according to the initial height of the first liquid phase and the non-emulsification height of the first liquid phase; and determining the emulsion breaking rate of the emulsion according to the ratio of the emulsion breaking amount to the initial emulsion breaking amount.
According to one aspect of embodiments herein, the emulsion rate is determined from the emulsion rateThe emulsification factor of the second liquid relative to the first liquid phase comprises: determining the curve integral of the emulsification rate of the second liquid relative to the first liquid phase at a plurality of rotating speeds along with the rotating speed; determining the emulsification coefficient according to the curve integral of the emulsification rate with the rotating speed by using the following formula:
wherein EI is the emulsification coefficient,
the integral of the emulsion rate of the second liquid relative to the first liquid at a plurality of rotation speeds, omega, with the curve of said rotation speedsiAt the i-th rotation speed, Eo(ωi) The emulsification rate is corresponding to the ith rotating speed; omega2Is the maximum rotation speed of the plurality of rotation speeds; omega1Is the minimum rotation speed of the plurality of rotation speeds, Eo,stThe emulsion ratio was defined as a reference.
According to one aspect of embodiments herein, determining a breaking coefficient of the emulsion from the breaking rate comprises: determining a curve integral of the emulsion breaking rate of the emulsion at a plurality of times over the time; determining the demulsification coefficient according to the curve integral of the demulsification rate of the emulsion along with the time at a plurality of moments by using the following formula:
wherein DI is the demulsification coefficient,
the breaking rate of emulsion formed by the first liquid phase and the second liquid phase at a plurality of moments after the rotation of the rotating module is stopped is integrated along with the curve of the moments, t is the moment t, D of the rotating module in the stationary state after the rotation is stoppedo(t) the demulsification rate corresponding to the moment t; t is tsIs the s-th time in the plurality of times; do,stAnd (t) is a reference demulsification rate.
The embodiment herein also provides a device is surveyed in rotating fluid emulsification ability and emulsion stability antithetical couplet sets up rotatory module in the emulsification test tube, rotatory module is used for driving liquid in the emulsification test tube rotates, includes: the device comprises a first liquid phase initial height acquisition unit, a second liquid phase acquisition unit and a control unit, wherein the first liquid phase initial height acquisition unit is used for respectively injecting a first liquid phase and a second liquid phase into an emulsification test tube and acquiring the initial height of the first liquid phase in the emulsification test tube; the emulsification rate calculating unit is used for calculating the emulsification rate of the second liquid relative to the first liquid at a plurality of rotating speeds according to the initial height of the first liquid and the non-emulsification height of the first liquid at each rotating speed of the rotating module; the emulsion breaking rate calculation unit is used for calculating the emulsion breaking rate of the emulsion formed by the first liquid phase and the second liquid phase at multiple moments according to the initial height of the first liquid phase and the height of the first liquid phase at multiple moments after the rotation module stops; an emulsification coefficient determining unit for determining an emulsification coefficient of the second liquid relative to the first liquid according to the emulsification rate; and the demulsification coefficient determining unit is used for determining the demulsification coefficient of the emulsion according to the demulsification rate.
The embodiment of the invention also provides a rotary fluid emulsifying capacity and emulsion stability combined measurement device, which comprises an emulsifying test tube, a temperature control module, a rotation control module and a data acquisition module; the emulsification test tube is used for containing a first liquid phase and a second liquid phase; the temperature control module is used for heating the liquid in the emulsification test tube; the rotating module is arranged at the bottom of the emulsification test tube and is used for rotating under the control of the rotating control module so as to drive the first liquid phase and the second liquid phase in the emulsification test tube to rotate; the data acquisition module is aligned with the emulsification test tube, connected with the rotation control module and used for acquiring the initial height of the first liquid phase in the emulsification test tube, the height data of the first liquid phase at each rotating speed and each moment and the height of the first liquid phase at a plurality of moments after the rotation module stops; the calculation module is connected with the data acquisition module and is used for calculating the emulsification rate of the second liquid relative to the first liquid at a plurality of rotating speeds according to the initial height of the first liquid and the non-emulsification height of the first liquid at each rotating speed of the rotating module; determining the emulsion breaking rate of the emulsion formed by the first liquid phase and the second liquid phase at a plurality of moments according to the initial height of the first liquid phase and the height of the first liquid phase at the plurality of moments after the rotation module stops; determining the emulsification coefficient of the second liquid relative to the first liquid phase according to the emulsification rate; and determining the demulsification coefficient of the emulsion according to the demulsification rate.
Embodiments herein also provide a computer device comprising a memory, a processor and a computer program stored on the memory and executable on the processor, the processor implementing the above method when executing the computer program.
Embodiments herein also provide a computer-readable storage medium having stored thereon computer instructions, which when executed by a processor, implement the above-described method.
By the aid of the method, the rotation speed and the emulsification temperature in the emulsification process can be stably adjusted, dynamic information of the emulsification process and the emulsion breaking process can be acquired, the emulsification capacity and the emulsion stability of the emulsifier can be jointly measured, and an accurate emulsification performance joint measurement result can be obtained.
Drawings
In order to more clearly illustrate the embodiments or technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art that other drawings can be obtained according to the drawings without creative efforts.
FIG. 1 is a flow chart of a method for simultaneous measurement of emulsification capacity and emulsion stability of a rotary fluid according to an embodiment of the present disclosure;
FIG. 2 is a flow chart illustrating a method of determining the height of a first liquid phase and a second liquid phase injected into an emulsion test tube according to an embodiment herein;
FIG. 3 is a flow chart illustrating a method for calculating an emulsification rate of a second liquid relative to a first liquid phase at a plurality of rotational speeds in accordance with an embodiment of the disclosure;
FIG. 4 is a flow chart illustrating a method of calculating a breaking rate of an emulsion formed from a first liquid phase and a second liquid phase at a plurality of times in accordance with an embodiment of the disclosure;
FIG. 5 is a flow chart illustrating a method of determining an emulsification factor of a second liquid relative to a first liquid phase according to an embodiment herein;
FIG. 6 is a flow chart illustrating a method of determining the breaking coefficient of an emulsion according to an embodiment herein;
FIG. 7 is a schematic structural diagram of a device for simultaneous measurement of emulsification capacity and emulsion stability of a rotary fluid according to an embodiment of the present disclosure;
FIG. 8 is a schematic structural diagram of a device for simultaneous measurement of emulsifying capacity and emulsion stability of a rotary fluid according to an embodiment of the present disclosure;
FIG. 9 is a schematic diagram illustrating a system for simultaneous measurement of emulsification capacity and emulsion stability of a rotary fluid in accordance with an embodiment of the present disclosure;
FIG. 10A is a highly schematic illustration of the first and second liquid phases at an initial time after an emulsification process in accordance with an embodiment of the disclosure;
FIG. 10B is a highly schematic illustration of the first and second liquid phases read during demulsification in one embodiment herein;
FIG. 11 is a graph illustrating emulsification rate versus rotational angular velocity for an embodiment of the present disclosure;
FIG. 12 is a graph of demulsification rate versus time for an embodiment of the present disclosure;
fig. 13 is a schematic structural diagram of a computer device according to an embodiment of the present disclosure.
Description of the symbols of the drawings:
701. a first liquid phase initial height acquisition unit;
7011. a liquid phase injection module;
7012. an image acquisition module;
7013. a height data processing module;
702. an emulsification rate calculating unit;
7021. a temperature control module;
7022. a rotation control module;
7023. a data acquisition module;
703. a demulsification rate calculating unit;
7031. a time calculation module;
704. an emulsification coefficient determining unit;
705. a demulsification coefficient determining unit;
901. an emulsification testing cylinder;
9012. an emulsification test tube;
9013. a scale;
9021. a thermoelectric tube;
9022. a thermocouple temperature sensor;
9023. a temperature control module;
9024. a display module;
903. a rotation module;
9031. rotating the paddle;
9032. a rotation control module;
904. a data acquisition module;
905. a calculation module;
1002. a computer device;
1004. a processor;
1006. a memory;
1008. a drive mechanism;
1010. an input/output module;
1012. an input device;
1014. an output device;
1016. a presentation device;
1018. a graphical user interface;
1020. a network interface;
1022. a communication link;
1024. a communication bus.
Detailed Description
In order to make the technical solutions in the present specification better understood, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments, but not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments herein without making any creative effort, shall fall within the scope of protection.
It should be noted that the terms "first," "second," and the like in the description and claims herein and in the above-described drawings are used for distinguishing between similar elements and not necessarily for describing a particular sequential or chronological order. It is to be understood that the data so used is interchangeable under appropriate circumstances such that the embodiments herein described are capable of operation in sequences other than those illustrated or described herein. Furthermore, the terms "comprises," "comprising," and "having," and any variations thereof, are intended to cover a non-exclusive inclusion, such that a process, method, apparatus, article, or device that comprises a list of steps or elements is not necessarily limited to those steps or elements expressly listed, but may include other steps or elements not expressly listed or inherent to such process, method, article, or device.
The present specification provides method steps as described in the examples or flowcharts, but may include more or fewer steps based on routine or non-inventive labor. The order of steps recited in the embodiments is merely one manner of performing the steps in a multitude of orders and does not represent the only order of execution. When an actual system or apparatus product executes, it can execute sequentially or in parallel according to the method shown in the embodiment or the figures.
It should be noted that the method for jointly measuring the emulsifying capacity and the emulsion stability of the rotary fluid can be used in the field of petrochemical industry, and can also be used in any fields of medicine, pharmacy, chemistry and the like, and the application fields of the method, the device and the system for jointly measuring the emulsifying capacity and the emulsion stability of the rotary fluid are not limited.
Fig. 1 is a flow chart of a method for jointly measuring the emulsifying capacity and the emulsion stability of a rotary fluid according to an embodiment of the present invention, which specifically includes the following steps:
In some embodiments of the present description, the first liquid phase and the second liquid phase are two liquids that are not normally miscible. The first liquid phase may be an oil phase including, but not limited to, crude oil containing various components, and the second liquid phase may be an aqueous phase including, but not limited to, water containing various minerals and surfactants.
In this step, the second liquid phase may be injected first, and then the first liquid phase may be injected into the emulsion test tube. That is, the water phase is injected into the emulsion test tube first, and then the oil phase is injected. And the initial height of the oil phase in the emulsification test tube was recorded. This initial height corresponds to the amount of oil phase injected into the emulsification test tube, and can be used as a reference height for the first liquid phase in the subsequent steps to calculate the emulsification rate and the emulsion breaking rate.
And 102, calculating the emulsification rate of the second liquid relative to the first liquid at a plurality of rotating speeds according to the initial height of the first liquid and the non-emulsification height of the first liquid at each rotating speed of the rotating module. In this step, the rotating module is a part of a rotating module in an emulsion testing apparatus according to the embodiment of the present disclosure, and the rotating module is configured to rotate the first liquid phase and the second liquid phase in step 101, so as to form a stable shear flow field at a phase interface of the first liquid phase and the second liquid phase. Further emulsifying the first and second liquid phases. In some embodiments of the present description, the first liquid phase and the second liquid phase in a rotating state, which are rotated, may be referred to as a rotating liquid. See figure 9 for a detailed description of the rotation module and the emulsification testing device. The rotating module in this step is the rotating module in fig. 9. The non-emulsified height of the first liquid phase may be understood as the remaining non-emulsified height of the first liquid phase in the emulsification test tube, i.e. the remaining height of the first liquid phase. Wherein, the rotation module can provide different rotational speeds, through record incessant rotational speed down the first liquid phase not emulsify height and the initial height of first liquid phase, can calculate the emulsification rate of second liquid phase to first liquid phase under the different rotational speeds.
103, calculating the emulsion breaking rate of the emulsion formed by the first liquid phase and the second liquid phase at multiple moments according to the initial height of the first liquid phase and the height of the first liquid phase at multiple moments after the rotation module stops. In this step, as the rotation module in the emulsification test tube is stopped, the emulsification state of the first liquid phase and the second liquid phase is also stopped. At a plurality of moments after the rotation module stops, the first liquid phase emulsified in the emulsification test tube before occurs demulsification, the first liquid phase is separated out, and the height of the first liquid phase in the emulsification test tube is gradually increased. Within a certain time range, the heights of the first liquid phase at different times are different, and when the time reaches a certain time, the height of the first liquid phase tends to be stable and does not change any more.
And 104, determining the emulsification coefficient of the second liquid relative to the first liquid phase according to the emulsification rate of the second liquid relative to the first liquid phase at the plurality of rotating speeds. In this step, each rotation speed corresponds to one emulsification rate, and the emulsification coefficients of the second liquid phase and the first liquid phase can be determined according to a plurality of emulsification rates of the second liquid phase relative to the first liquid phase corresponding to the rotation speeds at a plurality of moments. Wherein the emulsification factor allows to evaluate the emulsifying capacity of the second liquid with respect to the first liquid phase. The emulsifying capacity may be understood as the ease with which the first and second liquid phases form an emulsion.
And 105, determining the emulsion breaking coefficient of the emulsion according to the emulsion breaking rate of the emulsion formed by the first liquid phase and the second liquid phase at the plurality of moments. In this step, the emulsion breaking rate of the emulsion formed by one first liquid phase and the second liquid phase corresponds to each time, and the emulsion breaking coefficient of the emulsion formed by the first liquid phase and the second liquid phase in the state can be determined according to a plurality of emulsion breaking rates corresponding to a plurality of times. Wherein the breaking coefficient may evaluate the stability of an emulsion formed by the first liquid phase and the second liquid phase. Specifically, the smaller the value of the breaking coefficient, the stronger the stability of the emulsion.
FIG. 2 is a flow chart illustrating a method of determining the height of the first liquid phase and the second liquid phase injected into the emulsification test tube according to an embodiment herein.
The standard conditions are experimental conditions under preset standard conditions. The standard conditions include: a standard temperature, a standard interface height of the first liquid phase and the second liquid phase, a viscosity of the second liquid phase or the solution of the active agent to be tested, and the like. In some embodiments of the present description, the standard temperature may be 25 ℃, 30 ℃, etc., and the standard interface height of the first liquid phase and the second liquid phase may be 5 cm, 7 cm, 8 cm, etc.; the viscosity of the second liquid phase or the solution of the active agent to be tested is 0.8, etc. The test conditions are conditions in actual experiments, including: the test temperature, the viscosity of the second liquid phase or the solution of the active agent to be tested, etc. For example, if the test condition temperature is 40 ℃, the viscosity of the second liquid phase at the test temperature is 0.6, the standard temperature is 25 ℃, the standard interfacial height of the first liquid phase and the second liquid phase is 5 cm, the viscosity of the second liquid phase is 0.8, and the first and second liquid phase interfacial shear similarity coefficients C are 1, the interfacial height of the first liquid phase and the second liquid phase at the test condition can be determined to be 3.75 cm according to the formula.
FIG. 3 is a flow chart illustrating a method for calculating an emulsification rate of a second liquid relative to a first liquid phase at a plurality of rotational speeds according to an embodiment of the disclosure. The method specifically comprises the following steps:
The formula in this step represents the ratio of the amount of change in the emulsification height of the first liquid phase to the initial height of the first liquid phase at different angular velocities. Wherein, the larger the emulsification degree of the first liquid phase and the non-emulsification height h of the first liquid phase along with the increase of the rotating speedoiThe smaller (w) the emulsification height h of the first liquid phaseo0-hoiThe larger (wi) the emulsification height of the first liquid phase takes up the initial height ho0The larger the specific gravity of (a), i.e., the larger the emulsification rate.
Fig. 4 is a flow chart illustrating a method for calculating a breaking rate of an emulsion formed from a first liquid phase and a second liquid phase at a plurality of times in accordance with an embodiment of the present disclosure.
In this step, hneAfter the rotation of the rotating module is stopped, the height of the first liquid phase is determined at the initial moment. That is, the first liquid phase and the second liquid phase in the emulsification test tube are emulsifiedAt the end of the run, the initial height of the first liquid phase. For example, the initial height of the first liquid phase after the emulsification process of the first liquid phase and the second liquid phase is 0 mm, which indicates that there is no clear first liquid phase in the emulsification test tube after the emulsification process is finished, and the first liquid phase is not separated from the emulsification zone generated in the emulsification process.
And 402, controlling a rotating module in the emulsification test tube to stop rotating, and obtaining the height of the first liquid phase at a plurality of moments in a static state. When the rotation module stops rotating, the first liquid phase and the second liquid phase in the emulsification test tube gradually tend to a static state from a high-speed rotating state. In some embodiments of the present disclosure, after the first liquid phase and the second liquid phase in the emulsification test tube are stopped from rotating at a high speed, the liquid in the emulsification test tube may actually be still after waiting for a very short time due to the influence of liquid inertia and the like. And taking the whole liquid in the emulsification test tube as a first moment when the liquid is in a static state, and recording the height of the first liquid phase and the dynamic change condition of the emulsification zone at a plurality of moments from the first moment. In the moment after the standstill, the height of the first liquid phase will gradually increase and the height of the emulsification zone will gradually decrease with increasing time, and the first liquid phase will gradually separate from the emulsification zone. In some embodiments of the present description, the height of the first liquid phase at multiple moments of the quiescent state is in hdo(t) represents. In this step, hdo(t) is the height of the first liquid phase at a plurality of moments after the rotation of the rotating module is stopped. After the rotation of the rotating module is stopped, the first liquid phase in the emulsification test tube is gradually separated from the emulsification zone, and the demulsification phenomenon starts to be generated. Height h of the first liquid phasedo(t) will gradually increase with time.
And 403, determining the demulsification amount of the first liquid phase at multiple moments according to the non-emulsified height of the first liquid phase and the heights of the first liquid phase at multiple moments. In this step, the emulsion breaking amount of the emulsion formed by the first liquid phase and the second liquid phase is: the difference between the height of the first liquid phase and the non-emulsified height of the first liquid phase at a plurality of times may be represented by hdo(t)-hneAnd (4) showing.
In this step hdo(t)-hneIndicating the height increase of the first liquid phase during the breaking of the emulsion. h isdo(t)-hneA larger value of (a) indicates a larger degree of demulsification of the first liquid phase and a higher degree of separation of the first liquid phase from the second liquid phase. Otherwise, hdo(t)-hneA smaller value of (a) indicates a smaller degree of demulsification of the first liquid phase and a smaller degree of separation of the first liquid phase from the second liquid phase.
FIG. 5 is a flow chart illustrating a method of determining an emulsification factor of a second liquid relative to a first liquid phase according to embodiments herein. The method specifically comprises the following steps:
In this step, ω2-ω1A difference between the maximum rotational speed and the minimum rotational speed, Eo,stThe reference emulsification rate is the linear increase of the relationship between the rotating speed and the emulsification rate at each angular speed. The reference emulsification rate can be considered as a linear function, e.g., a minimum angular velocity of 400 rpm and a maximum angular velocity of 800 rpmIn terms of a/minute. At minimum angular velocity, the emulsification rate is 0; the emulsification rate was 100% at the maximum angular velocity, the angular velocity was independent, and the angular velocity was [400,800 ]]Within the interval, the emulsification rate is linearly increased and is a dependent variable, Eo,stNamely, the emulsion ratio shows a change relationship in which the rotation speed increases and the emulsion ratio linearly increases. In this step, the larger the value of the calculated emulsification coefficient is, the stronger the emulsifying ability of the emulsifier is.
Fig. 6 is a flow chart of a method of determining the breaking coefficient of an emulsion according to an embodiment of the present disclosure. The method specifically comprises the following steps:
In some embodiments of the present description, Do,st(t) indicates that at each time, the relationship between time and emulsion breaking rate increases linearly. Do,st(t) can be considered as a linear function, e.g., with a minimum time of 0 minutes and a maximum time of 60 minutes. Wherein, the minimum time is the starting time when the rotation module in the emulsification test tube stops rotating and is in a static state, and the emulsification rate is 0 at the minimum time; the emulsifying rate is 100% at the maximum time, the time t is independent variable, and the time is [0,60 ]]Within the minute interval, the emulsion breaking rate is linearly increased, the emulsion breaking rate is a dependent variable, Do,stAnd (t) shows that the demulsification rate is in a time-increasing and linear increasing change relationship. In the specification, the emulsifying capacity and the emulsion breaking coefficient of a tested system are evaluated by taking the emulsifying coefficient and the emulsion breaking coefficient as indexes, and the emulsion stability can represent the performance of an emulsion system formed by a first liquid phase and a second liquid phase for maintaining the current state. The larger the emulsification coefficient EI is, the stronger the emulsification capacity of the tested system is; the smaller the breaking coefficient, the stronger the stability of the emulsion tested.
Fig. 7 is a schematic structural diagram of a device for jointly measuring emulsification capacity and emulsion stability of a rotary fluid according to an embodiment of the present disclosure, in which a basic structure of the device for jointly measuring emulsification capacity and emulsion stability of a rotary fluid is described, where functional units and modules may be implemented in a software manner, or may be implemented in a general chip or a specific chip, and a part or all of the functional units and modules may be implemented in static detection hardware or dynamic detection hardware, or a part of the functional units and modules may also be implemented in static detection hardware or dynamic detection hardware, where the device specifically includes:
a first liquid phase initial height obtaining unit 701, configured to inject a first liquid phase and a second liquid phase into an emulsification test tube, respectively, and obtain an initial height of the first liquid phase in the emulsification test tube;
an emulsification rate calculating unit 702, configured to calculate an emulsification rate of the second liquid with respect to the first liquid at a plurality of rotation speeds according to the initial height of the first liquid and an un-emulsified height of the first liquid at each rotation speed of the rotating module in the emulsification testing tube;
the emulsion breaking rate calculation unit 703 is configured to calculate an emulsion breaking rate of an emulsion formed by the first liquid phase and the second liquid phase at multiple times according to the initial height of the first liquid phase and the height of the first liquid phase at multiple times after the rotation module in the emulsification test tube stops;
an emulsification coefficient determining unit 704, configured to determine an emulsification coefficient of the second liquid with respect to the first liquid phase according to the emulsification rate;
and the demulsification coefficient determining unit 705 is used for determining the demulsification coefficient of the emulsion according to the demulsification rate.
The scheme can stably adjust the rotation speed and the emulsification temperature in the emulsification process, can acquire the dynamic information of the emulsification process and the demulsification process, can realize the joint measurement of the emulsifying capacity and the emulsion stability of the emulsifier, and can acquire an accurate joint measurement result of the emulsifying performance.
As an embodiment herein, refer to fig. 8, which is a schematic structural diagram of a system for jointly measuring emulsification capacity and emulsion stability of a rotary fluid in this embodiment.
As an embodiment herein, the first liquid phase initial height acquisition unit 701 further includes:
a liquid phase injection module 7011 for injecting a certain amount of the first liquid phase and the second liquid phase into the emulsion test tube;
the image acquisition module 7012 is configured to acquire a first liquid-phase initial image;
a height data processing module 7013, configured to determine initial height data according to the acquired initial image of the first liquid phase;
as an embodiment herein, the emulsification rate calculation unit 702 further includes: adjusting the rotation speed and temperature of the first liquid phase and the second liquid phase;
the temperature control module 7021 is configured to adjust the temperature of the first liquid phase and the second liquid phase in the emulsification test tube;
a rotation control module 7022 for controlling start and stop of rotation and rotation speed of the first liquid phase and the second liquid phase;
the data acquisition module 7023 is configured to acquire a height change of the first liquid phase and the second liquid phase;
as an embodiment herein, the demulsification rate calculating unit 703 further comprises:
and the time calculating module 7031 is configured to calculate a time of the demulsification process after the rotation is stopped.
Fig. 9 is a schematic structural diagram of a system for simultaneous measurement of emulsifying capacity and emulsion stability of a rotary fluid according to an embodiment of the present disclosure. The device comprises an emulsification testing module, a temperature control module, a rotation control module, a data acquisition module and a calculation module.
As shown, the emulsification testing module includes an emulsification testing cylinder 9011, an emulsification testing tube 9012, and a scale 9013. The emulsification test cylinder 9011 and the emulsification test tube 9012 are both visual temperature-resistant and pressure-resistant tubes, that is, the heights of liquid in the cylinder and the tube, the liquid mixing degree and the liquid separation degree can be clearly observed from the outsides of the emulsification test cylinder 9011 and the emulsification test tube 9012. The emulsification test cylinder 9011 and the emulsification test tube 9012 are high temperature resistant and high pressure resistant. Further, a transparent emulsification test tube is provided in the emulsification test cartridge for storing a first liquid phase (e.g., oil phase) and a second liquid phase (e.g., water phase). Deionized water is added to the emulsion test cartridge and the interior of the annulus formed by the emulsion test cartridge (i.e., the leftmost and rightmost transparent tubes in the emulsion test cartridge) to ensure that the deionized water submerges the oil and gas interface in the emulsion test cartridge. The scale 9013 is disposed in an annular space formed by the emulsification test cartridge and the emulsification test tube, and is used for measuring the height of liquid in the emulsification test tube 9012. The top end of the scale 9013 is connected with the top end and the bottom of the emulsification testing cylinder 9011 respectively, and the scale value of the scale 9013 in the direction from the bottom end to the top end is gradually increased.
The temperature control module comprises a thermoelectric tube 9021, a thermocouple temperature sensor 9022, a temperature control module 9023 and a display module 9024, wherein the thermoelectric tube 9021 and the thermocouple temperature sensor 9022 are electrically connected with the temperature control module 9023, a heating part of the thermoelectric tube 9021 and a measuring part of the thermocouple temperature sensor 9022 are both located in an annular space formed by the emulsification testing cylinder and the emulsification testing cylinder, the thermoelectric tube 9021 is used for heating an annular internal liquid medium formed by the emulsification testing cylinder 9011 and the emulsification testing cylinder 9012, and the thermocouple temperature sensor 9022 can measure the temperature of the liquid medium in real time. In the test process, the temperature control module 9023 is started, the temperature is set to be the test temperature, and the temperature of the first liquid phase and the temperature of the second liquid phase in the emulsification test tube are ensured to reach the set test temperature after being kept at the constant temperature for a period of time. The display module 9024 is electrically connected with the temperature control module and is used for displaying the change condition of the temperature in the emulsification test tube.
The rotating module 903 includes a rotating paddle 9031 and a rotating control module 9032 connected to the rotating paddle 9031. The rotating paddle 9031 is arranged at the bottom of the emulsification testing tube 9012, and is used for rotating under the control of the rotating control module 9032 and forming a stable shearing flow field in the emulsification testing tube. The rotating paddle 9031 continuously increases the rotating speed under the control of the rotating control module 9032 to accelerate the rotation, so as to drive the first liquid phase and the second liquid phase in the emulsification test tube 9012 to rotate at a high speed. The display module 9024 may be electrically connected to the rotation module, and configured to display a rotation speed of the rotation module.
The data collection module 904 is aligned with the emulsification test tube 9012 and connected to the rotation control module 9032, and is configured to collect height data of the first liquid phase at each rotation speed and each time. The data acquisition module 904 comprises a high-speed macro camera, and is configured to acquire changes in heights of the first liquid phase, the second liquid phase, and the emulsification zone in the emulsification test tube at different rotation speeds in the emulsification process, and acquire changes in heights of the first liquid phase, the second liquid phase, and the emulsification zone in the emulsification test tube at different times in the demulsification process. The data acquisition module 904 is electrically connected with the calculation module 905, and the image acquired by the data acquisition module 904 is calculated and processed by the calculation module 905, so as to calculate the emulsification rate of the second liquid relative to the first liquid at a plurality of rotation speeds according to the initial height of the first liquid and the non-emulsified height of the first liquid at each rotation speed of the rotation module; determining the emulsion breaking rate of the emulsion formed by the first liquid phase and the second liquid phase at a plurality of moments according to the initial height of the first liquid phase and the height of the first liquid phase at the plurality of moments after the rotation module stops; determining the emulsification coefficient of the second liquid relative to the first liquid phase according to the emulsification rate; and according to the emulsion breaking rate, determining that the emulsion breaking coefficient display module 9024 of the emulsion can be electrically connected with the calculation module 905 and used for displaying parameters such as the emulsion breaking rate, the emulsion breaking coefficient and the emulsion breaking coefficient obtained by processing equipment.
In the test process, according to the principle that the shearing force applied to the oil-water interface is similar, the height h of the second liquid phase or the activator solution which needs to be added into the emulsification test tube is determinedow(as shown in FIG. 10A), and then the first liquid phase (e.g., oil phase) to be tested is added into the emulsification test tube to a height ho0. Wherein, the height h of the second liquid phase is determined according to the preset ratio of the first liquid phase to the second liquid phaseowThe height h of the first liquid phase to be added can be calculatedo0. The second liquid phase is first added to the emulsion test tube 9012 to a height h according to the predetermined height of the first liquid phase and the second liquid phaseowAfter the second liquid phase is added, the first liquid phase is added into the emulsification test tube 9012 to the height ho0. Deionized water is injected into the annular interior formed by the emulsification test cylinder 9011 and the emulsification test tube 9012, and the added deionized water needs to immerse an oil-gas phase interface in the emulsification test tube 9012.
The temperature control module 9023 is turned on, the temperature is set to the experiment temperature, the thermoelectric tube 9021 is used for heating the deionized water, and the thermocouple temperature sensor 9022 can measure the temperature of the deionized water in real time. Keeping the temperature for a period of time to ensure that the temperature of the first liquid phase and the second liquid phase in the emulsification test tube 9012 reaches the set experimental temperature. In some embodiments of the present disclosure, the constant temperature time may be 10 minutes, 15 minutes, 18 minutes, 20 minutes, etc., and the specific constant temperature time may be adjusted according to the specific situation of the experiment, which is not limited herein.
After keeping the temperature for a period of time, the high-speed macro camera is started, and the initial conditions of the first liquid phase and the second liquid phase in the emulsification test tube 9012 are recorded. Starting the rotation control module 9032 and the display module 9024, setting the lower limit value of the initial rotation speed/rotation speed of the rotating paddle 9031 to be 400 revolutions per minute, simultaneously starting the high-speed macro camera to monitor the change condition of the emulsified amount of the oil and the water, and recording the height h of the un-emulsified first liquid phase at the rotation speed through the high-speed macro camera after the emulsified amount of the oil and the water is stable at the rotation speedoiAs shown in fig. 10B. Adjusting the angular velocity omega of the blade of the rotating propeller 9031 from low to highiThe rotation speed of the rotary paddle 9031 was increased in a gradient of 50 rpm, and the procedure was repeated (after the amount of emulsification of the first and second liquid phases was stabilized, the height of the un-emulsified first liquid phase in the emulsification test tube was collected) until the rotation speed reached 800 rpm, and the un-emulsified height h of the oil phase at 800 rpm was recordedne。
The rotation control module 9032 is closed, the rotating speed of the rotating paddle 9031 is reduced to 0 revolution/minute, and meanwhile the high-speed macro-camera records the oil phase height h in real timedo(t) and dynamic behavior of the emulsification zone. Height h of oil phasedo(t) the experiment was ended when the emulsion zone had disappeared or remained essentially unchanged.
FIG. 11 is a graph showing emulsification rate versus rotational angular velocity for an embodiment of the present disclosure. In the figure, the blade rotation angular velocity of the rotating blade is taken as the abscissa, and the emulsification rate EoAnd drawing a dynamic curve graph of the emulsification rate changing along with the rotating speed for the ordinate. It can be seen from the figure that as the angular velocity approaches ω2When the emulsion is used, the emulsion rate reaches 100 percent, and finally, the emulsion is kept stable and unchanged at 100 percent. In the figure Eo,stThe corresponding dotted line part is a reference emulsification curve showing the reference emulsification rate at different accelerations. The relationship between the angular velocity at the reference emulsification rate and the emulsification rate increases linearly.
FIG. 12 is a graph of demulsification rate versus time according to one embodiment of the present disclosure. The demulsification rate D is plotted by the time t as the abscissaoAs ordinate, the emulsion breaking rate D was plottedoDynamic curve over time. In the figure, Do,st(t)The corresponding dotted line part is a reference demulsification rate curve and shows that the relation between the time and the demulsification rate is increased linearly at each time. Do,st(t) can be considered as a linear function.
As shown in fig. 13, for a computer device provided for embodiments herein, the computer device 1302 may include one or more processors 1304, such as one or more Central Processing Units (CPUs), each of which may implement one or more hardware threads. Computer device 1302 may also include any memory 1306 for storing any kind of information, such as code, settings, data, etc. For example, without limitation, memory 1306 may include any one or more of the following in combination: any type of RAM, any type of ROM, flash memory devices, hard disks, optical disks, etc. More generally, any memory may use any technology to store information. Further, any memory may provide volatile or non-volatile retention of information. Further, any memory may represent fixed or removable components of computer device 1302. In one case, when processor 1304 executes associated instructions that are stored in any memory or combination of memories, computer device 1302 may perform any of the operations of the associated instructions. The computer device 1302 also includes one or more drive mechanisms 1308, such as a hard disk drive mechanism, an optical drive mechanism, etc., for interacting with any memory.
Corresponding to the methods in fig. 1 to 6, the embodiments herein also provide a computer-readable storage medium having stored thereon a computer program, which, when executed by a processor, performs the steps of the above-described method.
Embodiments herein also provide computer readable instructions, wherein when executed by a processor, a program thereof causes the processor to perform the method as shown in fig. 1-6.
It should be understood that, in various embodiments herein, the sequence numbers of the above-mentioned processes do not mean the execution sequence, and the execution sequence of each process should be determined by its function and inherent logic, and should not constitute any limitation to the implementation process of the embodiments herein.
It should also be understood that, in the embodiments herein, the term "and/or" is only one kind of association relation describing an associated object, meaning that three kinds of relations may exist. For example, a and/or B, may represent: a exists alone, A and B exist simultaneously, and B exists alone. In addition, the character "/" herein generally indicates that the former and latter related objects are in an "or" relationship.
Those of ordinary skill in the art will appreciate that the elements and algorithm steps of the examples described in connection with the embodiments disclosed herein may be embodied in electronic hardware, computer software, or combinations of both, and that the components and steps of the examples have been described in a functional general in the foregoing description for the purpose of illustrating clearly the interchangeability of hardware and software. Whether such functionality is implemented as hardware or software depends upon the particular application and design constraints imposed on the implementation. Skilled artisans may implement the described functionality in varying ways for each particular application, but such implementation decisions should not be interpreted as causing a departure from the scope of the present disclosure.
It is clear to those skilled in the art that, for convenience and brevity of description, the specific working processes of the above-described systems, apparatuses and units may refer to the corresponding processes in the foregoing method embodiments, and are not described herein again.
In the several embodiments provided herein, it should be understood that the disclosed system, apparatus, and method may be implemented in other ways. For example, the above-described apparatus embodiments are merely illustrative, and for example, the division of the units is only one logical division, and other divisions may be realized in practice, for example, a plurality of units or components may be combined or integrated into another system, or some features may be omitted, or not executed. In addition, the shown or discussed mutual coupling or direct coupling or communication connection may be an indirect coupling or communication connection through some interfaces, devices or units, and may also be an electric, mechanical or other form of connection.
The units described as separate parts may or may not be physically separate, and parts displayed as units may or may not be physical units, may be located in one position, or may be distributed on multiple network units. Some or all of the units can be selected according to actual needs to achieve the purposes of the embodiments herein.
In addition, functional units in the embodiments herein may be integrated into one processing unit, or each unit may exist alone physically, or two or more units are integrated into one unit. The integrated unit can be realized in a form of hardware, and can also be realized in a form of a software functional unit.
The integrated unit, if implemented in the form of a software functional unit and sold or used as a stand-alone product, may be stored in a computer readable storage medium. Based on such understanding, the technical solutions of the present invention may be implemented in a form of a software product, which is stored in a storage medium and includes several instructions for causing a computer device (which may be a personal computer, a server, or a network device) to execute all or part of the steps of the methods described in the embodiments of the present invention. And the aforementioned storage medium includes: a U-disk, a removable hard disk, a Read-Only Memory (ROM), a Random Access Memory (RAM), a magnetic disk or an optical disk, and other various media capable of storing program codes.
The principles and embodiments of this document are explained herein using specific examples, which are presented only to aid in understanding the methods and their core concepts; meanwhile, for the general technical personnel in the field, according to the idea of this document, there may be changes in the concrete implementation and the application scope, in summary, this description should not be understood as the limitation of this document.
Claims (10)
1. The utility model provides a rotary fluid emulsification ability and emulsion stability allies oneself with surveys method which characterized in that sets up rotatory module in the emulsification test tube, rotatory module is used for driving liquid in the emulsification test tube rotates, includes:
respectively injecting a first liquid phase and a second liquid phase into an emulsification test tube, and obtaining the initial height of the first liquid phase in the emulsification test tube;
calculating the emulsification rate of the second liquid relative to the first liquid at a plurality of rotation speeds according to the initial height of the first liquid and the non-emulsification height of the first liquid at each rotation speed of the rotating module;
calculating the emulsion breaking rate of the emulsion formed by the first liquid phase and the second liquid phase at a plurality of moments according to the initial height of the first liquid phase and the height of the first liquid phase at the plurality of moments after the rotating module stops;
determining the emulsification coefficient of the second liquid relative to the first liquid phase according to the emulsification rate;
and determining the demulsification coefficient of the emulsion according to the demulsification rate.
2. The method of claim 1, wherein the step of injecting the first liquid phase and the second liquid phase into the emulsion test tube comprises:
determining the interfacial height of the first liquid phase and the second liquid phase according to the following formula:
and determining the initial height of the first liquid phase according to the preset ratio of the first liquid phase to the second liquid phase and the height of the interface.
3. The method of claim 1, wherein calculating the emulsification rate of the second liquid relative to the first liquid at a plurality of rotation speeds according to the initial height of the first liquid and the non-emulsified height of the first liquid at each rotation speed of the rotating module in the emulsification test tube comprises:
controlling a rotating module in the emulsification testing tube to rotate according to a preset rotating speed, and determining the non-emulsification height of the first liquid phase at the rotating speed after adjusting the rotating speed of the rotating module each time;
according to the initial height of the first liquid phase and the non-emulsified height of the first liquid phase at each rotating speed, calculating the emulsification rate of the second liquid relative to the first liquid phase at each rotating speed by using the following formula:
4. The method of claim 1, wherein determining the emulsion breaking rate of the emulsion formed by the first liquid phase and the second liquid phase at a plurality of times based on the initial height of the first liquid phase and the height of the first liquid phase at the plurality of times after the rotation module stops comprises:
when the rotating module reaches the maximum rotating speed, acquiring the non-emulsified height of the first liquid phase;
controlling a rotating module in the emulsification testing tube to stop rotating, and obtaining the height of a first liquid phase at a plurality of moments in a static state;
determining the demulsification amount of the first liquid phase at a plurality of moments according to the non-emulsified height of the first liquid phase and the heights of the first liquid phase at the plurality of moments;
determining an initial emulsification amount of the first liquid phase according to the initial height of the first liquid phase and the non-emulsification height of the first liquid phase;
and determining the emulsion breaking rate of the emulsion according to the ratio of the emulsion breaking amount to the initial emulsion breaking amount.
5. The method of claim 1, wherein determining the emulsification coefficient of the second liquid relative to the first liquid according to the emulsification rate comprises:
determining the curve integral of the emulsification rate of the second liquid relative to the first liquid phase at a plurality of rotating speeds along with the rotating speed;
determining the emulsification coefficient from the curve integral using the following equation:
wherein EI is the emulsification coefficient,
the integral of the emulsion rate of the second liquid relative to the first liquid at a plurality of rotation speeds, omega, with the curve of said rotation speedsiAt the i-th rotation speed, Eo(ωi) The emulsification rate is corresponding to the ith rotating speed; omega2Is the maximum rotation speed of the plurality of rotation speeds; omega1Is the minimum rotation speed of the plurality of rotation speeds, Eo,stThe emulsion ratio was defined as a reference.
6. The method for jointly measuring the emulsifying capacity and the emulsion stability of the rotary fluid according to claim 1, wherein determining the emulsion breaking coefficient of the emulsion according to the emulsion breaking rate comprises:
determining a curve integral of the emulsion breaking rate of the emulsion at a plurality of times over the time;
determining the demulsification coefficient by using the following formula according to the curve integral of the demulsification rate along with the time:
wherein DI is the demulsification coefficient,
the breaking rate of emulsion formed by the first liquid phase and the second liquid phase at a plurality of moments after the rotation of the rotating module is stopped is integrated along with the curve of the moments, t is the moment t, D of the rotating module in the stationary state after the rotation is stoppedo(t) the demulsification rate corresponding to the moment t; t is tsIs the s-th time in the plurality of times; do,stAnd (t) is a reference demulsification rate.
7. The utility model provides a rotary fluid emulsification ability and emulsion stability ally oneself with survey device which characterized in that sets up rotation module in the emulsification test tube, rotation module is used for driving liquid in the emulsification test tube rotates, includes:
the device comprises a first liquid phase initial height acquisition unit, a second liquid phase acquisition unit and a control unit, wherein the first liquid phase initial height acquisition unit is used for respectively injecting a first liquid phase and a second liquid phase into an emulsification test tube and acquiring the initial height of the first liquid phase in the emulsification test tube;
the emulsification rate calculating unit is used for calculating the emulsification rate of the second liquid relative to the first liquid at a plurality of rotating speeds according to the initial height of the first liquid and the non-emulsification height of the first liquid at each rotating speed of the rotating module;
the emulsion breaking rate calculation unit is used for calculating the emulsion breaking rate of the emulsion formed by the first liquid phase and the second liquid phase at multiple moments according to the initial height of the first liquid phase and the height of the first liquid phase at multiple moments after the rotation module stops;
an emulsification coefficient determining unit for determining an emulsification coefficient of the second liquid relative to the first liquid according to the emulsification rate;
and the demulsification coefficient determining unit is used for determining the demulsification coefficient of the emulsion according to the demulsification rate.
8. A rotary fluid emulsifying capacity and emulsion stability joint measurement system is characterized by comprising: the device comprises an emulsification test tube, a temperature control module, a rotation control module, a data acquisition module and a calculation module;
the emulsification test tube is used for containing a first liquid phase and a second liquid phase;
the temperature control module is used for heating liquid in the emulsification test tube;
the rotating module is arranged at the bottom of the emulsification test tube and is used for rotating under the control of the rotating control module so as to drive the first liquid phase and the second liquid phase in the emulsification test tube to rotate;
the data acquisition module is aligned with the emulsification test tube, connected with the rotation control module and used for acquiring the initial height of the first liquid phase in the emulsification test tube, the height data of the first liquid phase at each rotating speed and each moment and the height of the first liquid phase at a plurality of moments after the rotation module stops;
the calculation module is connected with the data acquisition module and is used for calculating the emulsification rate of the second liquid relative to the first liquid at a plurality of rotating speeds according to the initial height of the first liquid and the non-emulsification height of the first liquid at each rotating speed of the rotating module; determining the emulsion breaking rate of the emulsion formed by the first liquid phase and the second liquid phase at a plurality of moments according to the initial height of the first liquid phase and the height of the first liquid phase at the plurality of moments after the rotation module stops; determining the emulsification coefficient of the second liquid relative to the first liquid phase according to the emulsification rate; and determining the demulsification coefficient of the emulsion according to the demulsification rate.
9. A computer device comprising a memory, a processor and a computer program stored on the memory and executable on the processor, characterized in that the processor implements the method of any one of claims 1-6 when executing the computer program.
10. A computer-readable storage medium, characterized in that the computer-readable storage medium stores a computer program which, when executed by a processor, implements the method of any one of claims 1-6.
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