CN114395328A - High-hardness wear-resistant anti-sticking ceramic coating and preparation and use methods thereof - Google Patents

High-hardness wear-resistant anti-sticking ceramic coating and preparation and use methods thereof Download PDF

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Publication number
CN114395328A
CN114395328A CN202111491499.7A CN202111491499A CN114395328A CN 114395328 A CN114395328 A CN 114395328A CN 202111491499 A CN202111491499 A CN 202111491499A CN 114395328 A CN114395328 A CN 114395328A
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China
Prior art keywords
parts
ceramic coating
coating
substrate
sticking
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CN202111491499.7A
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Chinese (zh)
Inventor
沈国平
陶善豪
郑磊
黄磊
顾举鑫
万恒祥
汤惠清
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Saina Chemical Taicang Co ltd
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Saina Chemical Taicang Co ltd
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Priority to CN202111491499.7A priority Critical patent/CN114395328A/en
Publication of CN114395328A publication Critical patent/CN114395328A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/16Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/28Nitrogen-containing compounds
    • C08K2003/282Binary compounds of nitrogen with aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a high-hardness wear-resistant anti-sticking ceramic coating and preparation and use methods thereof. The high hardness wear resistant anti-sticking ceramic coating includes silazane resin solid mixture 20 weight portions and dispersant 80 weight portions. The invention has the beneficial effects that the ceramic coating is a nano composite ceramic coating, can be insulated for 30min at 250 ℃, realizes compact and smooth vitrification, is water-based, safe and environment-friendly, has no toxicity or harm, and has strong wear resistance on the surface of the coating; the surface of the coating is hydrophobic and oleophobic, and the coating has excellent non-stick property, strong anti-fouling performance and excellent anti-sticking capability; can resist salt fog and acid and alkali.

Description

High-hardness wear-resistant anti-sticking ceramic coating and preparation and use methods thereof
Technical Field
The invention belongs to the technical field of nano ceramic coatings, and particularly relates to a high-hardness wear-resistant anti-sticking ceramic coating and preparation and use methods thereof.
Background
The domestic coffee powder distributor is mainly made of stainless steel, and only a few coffee powder distributors are provided with Teflon anti-sticking coatings on the surfaces; the coffee powder distributor with the surface made of stainless steel materials has the defects that the coffee powder distributor is not treated by an anti-sticking coating, so that the situation of uneven powder distribution occurs in the using process, and dust, dirt and the like are easily adhered to the surface of the stainless steel coffee powder distributor to influence the use; and the coffee powder distributor of the surface using the Teflon anti-sticking coating, because the hardness of the anti-sticking Teflon is lower, if the coffee powder distributor is collided in the using process, scratches and pits are easily left on the surface of the coffee powder distributor, and the subsequent use and cleaning are influenced. There is therefore a need for a solution to the above problems.
The above description is included in the technical recognition scope of the inventors, and does not necessarily constitute the prior art.
Disclosure of Invention
In order to solve the above problems, it is an object of the present invention to provide a high hardness wear-resistant anti-sticking ceramic coating and methods of making and using the same.
In order to achieve the purpose, the invention provides a high-hardness wear-resistant anti-sticking ceramic coating which is characterized by comprising 20 parts of silazane resin solid mixture and 80 parts of dispersing agent.
In one example, a method of making a high hardness, wear resistant, and anti-stick ceramic coating includes the steps of:
(1) weighing 1-3 parts of nano-scale iron-chromium brown, 1-6 parts of nano-scale titanium dioxide, 0.5-16 parts of aluminum nitride, 3-8 parts of nano-scale silicon carbide and 5 parts of silazane resin, and uniformly mixing to obtain a solid filler mixture;
(2) weighing 15-35 parts of silazane resin, 50-70 parts of n-heptane and 2-6 parts of stabilizing additive, and uniformly mixing to obtain a dispersing agent;
(3) and (3) taking 20% of the solid filler mixture and 80% of the dispersing agent according to the mass percentage, and uniformly stirring the mixture and the dispersing agent in a rolling stirring device at 400rpm to obtain the anti-sticking ceramic coating.
In one example, a method of using a high hardness wear resistant anti-stick ceramic coating includes the steps of:
I. cleaning the substrate by using an organic solvent to remove grease on the surface of the substrate;
II. Carrying out sand blasting treatment on the surface of the substrate to ensure that the roughness of the surface of the substrate is not lower than Sa2.5 grade;
III, cleaning the substrate subjected to sand blasting by using the organic solvent again, and removing dust and grease on the surface of the substrate;
and IV, placing the substrate to be coated at room temperature, keeping the surface of the substrate dry, uniformly coating the obtained anti-sticking ceramic coating on the surface of the substrate to form a coating, and waiting for the coating to be cured.
In one example, the optimal thickness of the coating in step IV is 15-45 μm.
In one example, the coating curing in step IV requires air drying after 1h of incubation at a temperature of 150 ℃ to 250 ℃ or standing at dry room temperature for 7 days.
The high-hardness wear-resistant anti-sticking ceramic coating and the preparation and use methods thereof provided by the invention can bring the following beneficial effects:
1. the ceramic coating is water-based, safe, environment-friendly and non-toxic, and passes FDA (food grade) detection standards;
2. the ceramic coating is a nano composite ceramic coating, can be insulated for 30min at 250 ℃, realizes compact, smooth and porcelainizing, saves energy and is beautiful;
3. the surface of the coating has strong wear resistance (10000 times of wiping by 1.5KG force scouring pad without bottom), and the scratch hardness of the pencil can reach 7-9H;
4. the surface of the coating is hydrophobic and oleophobic, and the coating has excellent non-stick property, strong anti-fouling performance and excellent anti-sticking capability; 5. can resist salt fog and acid and alkali.
Detailed Description
In the description of the present invention, it is to be understood that the terms "central," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," "axial," "radial," "circumferential," and the like are used in an orientation or positional relationship indicated to facilitate describing the invention and to simplify the description, but are not intended to indicate or imply that the referenced device or element must have a particular orientation, be constructed and operated in a particular orientation, and are not to be construed as limiting the invention.
Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include one or more of that feature. In the description of the present invention, "a plurality" means two or more unless specifically defined otherwise.
In the present invention, unless otherwise expressly stated or limited, the terms "mounted," "connected," "secured," and the like are to be construed broadly and can, for example, be fixedly connected, detachably connected, or integrally formed; the connection can be mechanical connection, electrical connection or communication; either directly or indirectly through intervening media, either internally or in any other relationship. The specific meanings of the above terms in the present invention can be understood by those skilled in the art according to specific situations.
In the present invention, unless otherwise expressly stated or limited, the first feature "on" or "under" the second feature may be directly contacting the first and second features or indirectly contacting the first and second features through an intermediate. In the description of the present specification, reference to the description of the terms "one aspect," "some aspects," "an example," "a specific example," or "some examples" or the like means that a particular feature, structure, material, or characteristic described in connection with the aspect or example is included in at least one aspect or example of the present invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same solution or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more aspects or examples.
Example 1
The high-hardness wear-resistant anti-sticking ceramic coating is characterized by comprising 20 parts of silazane resin solid mixture and 80 parts of dispersing agent.
In one example, a method of making a high hardness, wear resistant, and anti-stick ceramic coating includes the steps of:
(1) weighing 1-3 parts of nano-scale iron-chromium brown, 1-6 parts of nano-scale titanium dioxide, 0.5-16 parts of aluminum nitride, 3-8 parts of nano-scale silicon carbide and 5 parts of silazane resin, and uniformly mixing to obtain a solid filler mixture;
(2) weighing 15-35 parts of silazane resin, 50-70 parts of n-heptane and 2-6 parts of stabilizing additive, and uniformly mixing to obtain a dispersing agent;
(3) and (3) taking 20% of the solid filler mixture and 80% of the dispersing agent according to the mass percentage, and uniformly stirring the mixture and the dispersing agent in a rolling stirring device at 400rpm to obtain the anti-sticking ceramic coating.
The obtained cured ceramic coating is black and matte, and has moderate brittleness, high wear resistance and hardness of 9H.
Example 2
The high-hardness wear-resistant anti-sticking ceramic coating is characterized by comprising 40 parts of silazane resin solid mixture and 60 parts of dispersing agent.
In one example, a method of making a high hardness, wear resistant, and anti-stick ceramic coating includes the steps of:
(1) weighing 1-3 parts of nano-scale iron-chromium brown, 1-6 parts of nano-scale titanium dioxide, 0.5-16 parts of aluminum nitride, 3-8 parts of nano-scale silicon carbide and 5 parts of silazane resin, and uniformly mixing to obtain a solid filler mixture;
(2) weighing 15-35 parts of silazane resin, 50-70 parts of n-heptane and 2-6 parts of stabilizing additive, and uniformly mixing to obtain a dispersing agent;
(3) and (3) taking 20% of the solid filler mixture and 80% of the dispersing agent according to the mass percentage, and uniformly stirring the mixture and the dispersing agent in a rolling stirring device at 400rpm to obtain the anti-sticking ceramic coating.
The obtained cured ceramic coating is black and bright, and has high brittleness, high wear resistance and hardness up to 7H.
Example 3
The high-hardness wear-resistant anti-sticking ceramic coating is characterized by comprising 15 parts of silazane resin solid mixture and 85 parts of dispersing agent.
In one example, a method of making a high hardness, wear resistant, and anti-stick ceramic coating includes the steps of:
(1) weighing 1-3 parts of nano-scale iron-chromium brown, 1-6 parts of nano-scale titanium dioxide, 0.5-16 parts of aluminum nitride, 3-8 parts of nano-scale silicon carbide and 5 parts of silazane resin, and uniformly mixing to obtain a solid filler mixture;
(2) weighing 15-35 parts of silazane resin, 50-70 parts of n-heptane and 2-6 parts of stabilizing additive, and uniformly mixing to obtain a dispersing agent;
(3) and (3) taking 20% of the solid filler mixture and 80% of the dispersing agent according to the mass percentage, and uniformly stirring the mixture and the dispersing agent in a rolling stirring device at 400rpm to obtain the anti-sticking ceramic coating.
The obtained cured ceramic coating is black and bright, has weak brittleness, smooth surface and high wear resistance, and has hardness of 9H but uneven color distribution.
The high-hardness wear-resistant anti-sticking ceramic coating and the preparation and use methods thereof provided by the invention can bring the following beneficial effects:
1. the ceramic coating is water-based, safe, environment-friendly and non-toxic, and passes FDA (food grade) detection standards;
2. the ceramic coating is a nano composite ceramic coating, can be insulated for 30min at 250 ℃, realizes compact, smooth and porcelainizing, saves energy and is beautiful;
3. the surface of the coating is wear-resistant (the surface of the coating is not exposed after being wiped for 10000 times by 1.5KG force scouring pad), and the scratch hardness of the pencil can reach 7-9H;
4. the surface of the coating is hydrophobic and oleophobic, and the coating has excellent non-stick property, strong anti-fouling performance and excellent anti-sticking capability.
5. Can resist salt fog and acid and alkali.
The embodiments in the present specification are described in a progressive manner, and the same and similar parts among the embodiments are referred to each other, and each embodiment focuses on the differences from the other embodiments. In particular, for the system embodiment, since it is substantially similar to the method embodiment, the description is simple, and for the relevant points, reference may be made to the partial description of the method embodiment.
The above description is only an example of the present invention, and is not intended to limit the present invention. Various modifications and alterations to this invention will become apparent to those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the scope of the claims of the present invention.

Claims (5)

1. The high-hardness wear-resistant anti-sticking ceramic coating is characterized by comprising 20 parts of silazane resin solid mixture and 80 parts of dispersing agent.
2. The method for preparing a high-hardness wear-resistant anti-sticking ceramic coating according to claim 1, characterized by comprising the following steps:
(1) weighing 1-3 parts of nano-scale iron-chromium brown, 1-6 parts of nano-scale titanium dioxide, 0.5-16 parts of aluminum nitride, 3-8 parts of nano-scale silicon carbide and 5 parts of silazane resin, and uniformly mixing to obtain a solid filler mixture;
(2) weighing 15-35 parts of silazane resin, 50-70 parts of n-heptane and 2-6 parts of stabilizing additive, and uniformly mixing to obtain a dispersing agent;
(3) and (3) taking 20% of the solid filler mixture and 80% of the dispersing agent according to the mass percentage, and uniformly stirring the mixture and the dispersing agent in a rolling stirring device at 400rpm to obtain the anti-sticking ceramic coating.
3. The use method of the high-hardness wear-resistant anti-sticking ceramic coating is characterized by comprising the following steps of:
I. cleaning the substrate by using an organic solvent to remove grease on the surface of the substrate;
II. Carrying out sand blasting treatment on the surface of the substrate to ensure that the roughness of the surface of the substrate is not lower than Sa2.5 grade;
III, cleaning the substrate subjected to sand blasting by using the organic solvent again, and removing dust and grease on the surface of the substrate;
and IV, placing the substrate to be coated at room temperature, keeping the surface of the substrate dry, uniformly coating the obtained anti-sticking ceramic coating on the surface of the substrate to form a coating, and waiting for the coating to be cured.
4. The use of a high hardness wear resistant anti-stick ceramic coating according to claim 3, wherein the optimal thickness of the coating in step IV is 15-45 μm.
5. The use method of the high-hardness abrasion-resistant anti-sticking ceramic coating according to claim 3, wherein in the step IV, the coating is cured by air drying after being kept at a temperature of 150 ℃ to 250 ℃ for 1 hour, or is kept at a dry room temperature for 7 days.
CN202111491499.7A 2021-12-08 2021-12-08 High-hardness wear-resistant anti-sticking ceramic coating and preparation and use methods thereof Pending CN114395328A (en)

Priority Applications (1)

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CN202111491499.7A CN114395328A (en) 2021-12-08 2021-12-08 High-hardness wear-resistant anti-sticking ceramic coating and preparation and use methods thereof

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Application Number Priority Date Filing Date Title
CN202111491499.7A CN114395328A (en) 2021-12-08 2021-12-08 High-hardness wear-resistant anti-sticking ceramic coating and preparation and use methods thereof

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CN114395328A true CN114395328A (en) 2022-04-26

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100785428B1 (en) * 2007-03-27 2007-12-13 주식회사 보명 Method for painting ceramic coating agent on a surface of streetlight pole
CN113717639A (en) * 2021-09-15 2021-11-30 库贝化学(上海)有限公司 Polysilazane high-temperature resistant paint for carbon fiber composite material and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100785428B1 (en) * 2007-03-27 2007-12-13 주식회사 보명 Method for painting ceramic coating agent on a surface of streetlight pole
CN113717639A (en) * 2021-09-15 2021-11-30 库贝化学(上海)有限公司 Polysilazane high-temperature resistant paint for carbon fiber composite material and preparation method thereof

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Application publication date: 20220426