CN114382572A - Marine ammonia gas grading treatment system and ammonia fuel power ship - Google Patents
Marine ammonia gas grading treatment system and ammonia fuel power ship Download PDFInfo
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- CN114382572A CN114382572A CN202210112481.XA CN202210112481A CN114382572A CN 114382572 A CN114382572 A CN 114382572A CN 202210112481 A CN202210112481 A CN 202210112481A CN 114382572 A CN114382572 A CN 114382572A
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- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims abstract description 480
- 229910021529 ammonia Inorganic materials 0.000 title claims abstract description 167
- 239000000446 fuel Substances 0.000 title abstract description 20
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 134
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 134
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 120
- 239000012530 fluid Substances 0.000 claims abstract description 40
- 239000007921 spray Substances 0.000 claims abstract description 34
- 239000000779 smoke Substances 0.000 claims abstract description 22
- 239000006200 vaporizer Substances 0.000 claims description 21
- 238000002347 injection Methods 0.000 claims description 13
- 239000007924 injection Substances 0.000 claims description 13
- 230000001502 supplementing effect Effects 0.000 claims description 5
- 238000000034 method Methods 0.000 abstract description 10
- 230000008569 process Effects 0.000 abstract description 10
- 238000013461 design Methods 0.000 abstract description 4
- 239000007789 gas Substances 0.000 description 29
- 239000007788 liquid Substances 0.000 description 28
- 238000010521 absorption reaction Methods 0.000 description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 238000000926 separation method Methods 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 239000013589 supplement Substances 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000000295 fuel oil Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000002918 waste heat Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 230000008016 vaporization Effects 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000002828 fuel tank Substances 0.000 description 2
- 239000005431 greenhouse gas Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 238000009834 vaporization Methods 0.000 description 2
- 208000009079 Bronchial Spasm Diseases 0.000 description 1
- 208000014181 Bronchial disease Diseases 0.000 description 1
- 206010006482 Bronchospasm Diseases 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 208000002177 Cataract Diseases 0.000 description 1
- 208000009043 Chemical Burns Diseases 0.000 description 1
- 206010008479 Chest Pain Diseases 0.000 description 1
- 208000000059 Dyspnea Diseases 0.000 description 1
- 206010013975 Dyspnoeas Diseases 0.000 description 1
- 206010015150 Erythema Diseases 0.000 description 1
- 208000010412 Glaucoma Diseases 0.000 description 1
- 206010023644 Lacrimation increased Diseases 0.000 description 1
- 208000002193 Pain Diseases 0.000 description 1
- 206010037423 Pulmonary oedema Diseases 0.000 description 1
- 208000004756 Respiratory Insufficiency Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 210000004087 cornea Anatomy 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 230000004317 lacrimation Effects 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 208000005333 pulmonary edema Diseases 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 201000004193 respiratory failure Diseases 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
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- 239000000126 substance Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2066—Selective catalytic reduction [SCR]
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N5/00—Exhaust or silencing apparatus combined or associated with devices profiting by exhaust energy
- F01N5/02—Exhaust or silencing apparatus combined or associated with devices profiting by exhaust energy the devices using heat
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04F—PUMPING OF FLUID BY DIRECT CONTACT OF ANOTHER FLUID OR BY USING INERTIA OF FLUID TO BE PUMPED; SIPHONS
- F04F5/00—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow
- F04F5/02—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow the inducing fluid being liquid
- F04F5/04—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow the inducing fluid being liquid displacing elastic fluids
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F04—POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
- F04F—PUMPING OF FLUID BY DIRECT CONTACT OF ANOTHER FLUID OR BY USING INERTIA OF FLUID TO BE PUMPED; SIPHONS
- F04F5/00—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow
- F04F5/14—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow the inducing fluid being elastic fluid
- F04F5/24—Jet pumps, i.e. devices in which flow is induced by pressure drop caused by velocity of another fluid flow the inducing fluid being elastic fluid displacing liquids, e.g. containing solids, or liquids and elastic fluids
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2590/00—Exhaust or silencing apparatus adapted to particular use, e.g. for military applications, airplanes, submarines
- F01N2590/02—Exhaust or silencing apparatus adapted to particular use, e.g. for military applications, airplanes, submarines for marine vessels or naval applications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/14—Arrangements for the supply of substances, e.g. conduits
- F01N2610/1406—Storage means for substances, e.g. tanks or reservoirs
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2610/00—Adding substances to exhaust gases
- F01N2610/14—Arrangements for the supply of substances, e.g. conduits
- F01N2610/1453—Sprayers or atomisers; Arrangement thereof in the exhaust apparatus
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Treating Waste Gases (AREA)
Abstract
The invention provides a marine ammonia gas grading treatment system which comprises an ammonia discharge pipeline, an ammonia storage tank, a heat exchanger, a first ejector, a water replenishing tank, a cyclone separator, an ammonia water supply storage tank, a second ejector, an ammonia water storage tank, a first water pump, a second water pump, a third water pump, a double-fluid spray gun, an SCR mixer, an SCR reactor, a ship tail gas pipeline and a smoke exhaust pipeline. According to the grading treatment system for the ammonia gas for the ship, provided by the invention, through reasonable design, the ammonia gas discharged in the running process of the ship can be continuously, stably and efficiently absorbed, and finally, no ammonia gas is released from the ship, and the grading treatment system can be used for denitration treatment of ship tail gas, so that the safety of ship navigation is ensured. The invention also provides an ammonia fuel power ship.
Description
Technical Field
The invention relates to the technical field of ships, in particular to a marine ammonia gas grading treatment system and an ammonia fuel power ship.
Background
Along with the countryConcern of the social community on marine environment protection, MarPOL convention 73/78 attached rule VI requires NO of new ships in ECA area 1 month 1 day after 2016XThe emission of (A) is in accordance with the Tier III standard. For SOXFor emission, the sulfur content of fuel oil of a ship sailing in any area after 1 month and 1 day of 2020 must be less than 0.5% m/m. For a ship sailing on ECA, the sulfur content of fuel oil must reach below 0.1% m/m after 1 month and 1 day of 2015. Except that NO is satisfiedXAnd SOXThe emission requirement of (2) also needs to meet the requirement of greenhouse gas emission reduction, the international maritime organization MEPC provides a preliminary strategy of greenhouse gas emission reduction in the meeting, and the unit transportation activity of CO is 20302The emission is reduced by at least 40% in 2008 and 70% in 2050 on average; china proposes the goal of realizing carbon peak reaching in 2030 and carbon neutralization in 2060 on the 75 th joint national meeting, so that marine fuel and post-treatment technology are promoted to show diversified development trends, and the opportunity of vigorously developing clean energy is met globally.
Because ammonia does not contain carbon element and can be used as fuel, the ammonia is widely concerned internationally and has wide market prospect. The international energy agency forecasts that in the net zero emission background, low-carbon electricity, biological energy, hydrogen and ammonia fuel will provide more than 70% of terminal energy demand, and more than 60% of new ships will use ammonia or hydrogen fuel by 2060; the foreign famous ship matching manufacturer Alfa Laval indicates in the white paper for research on marine ammonia gas fuel that ammonia is a marine fuel with high value and low risk, and actually can provide power for at least one third of ships in the world; ABS classification society also suggests that zero-carbon fuels such as ammonia and hydrogen have great potential to reduce the carbon footprint of transportation during the use of ships.
By means of the requirements of MAN-ES company on the on-board parameters, future ammonia-fueled ships need to be reconfigured with a completely new set of ammonia fuel supply systems. Due to its toxicity, low concentrations of ammonia can irritate the eyes, lungs and skin, and high concentrations or direct contact can immediately endanger life, with symptoms including dyspnea, chest pain, bronchospasm, and, most seriously, pulmonary edema, leading to respiratory failure. Exposure of the skin to high concentrations of anhydrous ammonia may result in serious chemical burns. In addition to damage to the cornea, the human eye can also cause pain, lacrimation, redness, glaucoma, cataracts, and the like, with short contact times permitting mass concentrations of no more than 30 ppm. The specifications of classification societies such as DNV clearly state that in order to protect personnel on board a ship from exposure to ammonia gas, the main emphasis is to avoid the discharge of ammonia gas during normal operation, and therefore, it is imperative that ammonia gas discharged during the operation of an ammonia fuel supply system be treated to ensure that there is no discharge of ammonia gas during normal operation of the system, thereby ensuring the safety of the ship during sailing.
Disclosure of Invention
The invention aims to provide a grading treatment system for ammonia gas for ships, which aims to solve or at least partially solve the defects in the prior art, and through reasonable design, the ammonia gas discharged in the running process of the ships can be continuously and stably absorbed, so that no ammonia gas is released from the ships, and the safety of the ships in sailing is ensured.
The invention provides a marine ammonia gas grading treatment system which comprises an ammonia discharge pipeline, an ammonia storage tank, a heat exchanger, a first ejector, a water replenishing tank, a cyclone separator, an ammonia water supply storage tank, a second ejector, an ammonia water storage tank, a first water pump, a second water pump, a third water pump, a double-fluid spray gun, an SCR mixer, an SCR reactor, a ship tail gas pipeline and a smoke exhaust pipeline, wherein the ammonia discharge pipeline is connected with the first ejector;
the ammonia discharge pipeline is communicated with an inlet of the ammonia storage tank, an outlet of the ammonia storage tank is communicated with an ammonia gas inlet of the heat exchanger, an ammonia gas outlet of the heat exchanger is divided into two paths, one path is communicated with the ammonia gas inlet of the two-fluid spray gun through a connecting pipeline, the other path is communicated with an inlet of the first ejector, an outlet of the first ejector is communicated with an inlet of the cyclone separator, and an outlet of the water replenishing tank is communicated with an injection inlet of the first ejector; an outlet at the bottom of the cyclone separator is communicated with an inlet of the ammonia water supply storage tank, and an outlet at the top of the cyclone separator is communicated with an injection inlet of the second injector; an outlet at the bottom of the ammonia water storage tank is communicated with an inlet of the first water pump, an outlet of the first water pump is communicated with an inlet of the second ejector, an outlet of the second ejector is communicated with an inlet of the ammonia water storage tank, and an outlet at the bottom of the ammonia water storage tank is communicated with an inlet of the ammonia water supply storage tank;
an outlet at the bottom of the ammonia water supply storage tank is communicated with an inlet of the second water pump, an outlet of the second water pump is communicated with an ammonia water inlet of the two-fluid spray gun, and the two-fluid spray gun extends into the SCR mixer;
the ship tail gas pipeline is communicated with an inlet of the SCR mixer, an outlet of the SCR mixer is communicated with an inlet of the SCR reactor, and an outlet of the SCR reactor is communicated with the smoke exhaust pipeline; and a heat exchange pipe is arranged in the smoke exhaust pipeline, two ends of the heat exchange pipe are respectively communicated with the heat exchange medium inlet and the heat exchange medium outlet of the heat exchanger, and the third water pump is arranged on the pipeline between the heat exchange pipe and the heat exchange medium inlet or the heat exchange medium outlet of the heat exchanger.
Furthermore, the top outlet of the ammonia water storage tank is communicated to the connecting pipeline, a first pressure sensor and a first ammonia concentration sensor are arranged on the ammonia water storage tank, a first switch valve is arranged on the pipeline between the top outlet of the ammonia water storage tank and the connecting pipeline, a second switch valve is arranged on the pipeline between the bottom outlet of the ammonia water storage tank and the inlet of the ammonia water supply storage tank, the first pressure sensor is in signal connection with the first switch valve, and the first ammonia concentration sensor is in signal connection with the second switch valve.
Furthermore, an outlet at the top of the ammonia water supply storage tank is communicated to the connecting pipeline, a second pressure sensor and a second ammonia concentration sensor are arranged on the ammonia water supply storage tank, an ammonia gas sensor is arranged on the smoke exhaust pipeline, a third switch valve is arranged on a pipeline between the outlet at the top of the ammonia water supply storage tank and the connecting pipeline, a fourth switch valve is arranged on a pipeline between an outlet of the second water pump and an ammonia water inlet of the double-fluid spray gun, the second pressure sensor is in signal connection with the third switch valve, and the ammonia gas sensor and the second ammonia concentration sensor are in signal connection with the fourth switch valve.
Further, the marine ammonia gas stage treatment system also comprises a vaporizer, wherein a bottom outlet of the ammonia storage tank is communicated with a liquid ammonia inlet of the vaporizer, a liquid ammonia outlet of the vaporizer is communicated with an inlet of the ammonia storage tank, and two ends of the heat exchange tube are respectively communicated with a heat exchange medium inlet and a heat exchange medium outlet of the vaporizer.
Further, the marine ammonia gas staged treatment system also comprises a return pipeline, and the return pipeline is communicated with a bottom outlet of the ammonia storage tank; the ammonia storage tank is provided with a first liquid level meter, a fifth switch valve is arranged on a pipeline between a bottom outlet of the ammonia storage tank and a liquid ammonia inlet of the vaporizer, a sixth switch valve is arranged on the return pipeline, and the first liquid level meter is simultaneously in signal connection with the fifth switch valve and the sixth switch valve.
Furthermore, a third pressure sensor is arranged on the ammonia storage tank, a seventh switch valve is arranged on a pipeline between an outlet of the ammonia storage tank and an ammonia gas inlet of the heat exchanger, and the third pressure sensor is in signal connection with the seventh switch valve.
Furthermore, an inverted U-shaped pipe is arranged on a pipeline between the outlet of the water replenishing tank and the injection inlet of the first ejector.
Furthermore, a spraying device is arranged in the ammonia water storage tank, and an outlet of the second ejector is connected with the spraying device.
Further, the marine ammonia gas grading treatment system also comprises an expansion water tank, and an outlet of the expansion water tank is communicated to a pipeline between the heat exchange pipe and a heat exchange medium inlet or a heat exchange medium outlet of the heat exchanger.
The invention also provides an ammonia fuel power ship which comprises the marine ammonia gas grading treatment system.
According to the grading treatment system for the ammonia gas for the ship, provided by the invention, the ammonia gas is completely absorbed by water by arranging the two-stage ejector, the ammonia water supply storage tank and the ammonia water storage tank; meanwhile, the two-stage ejector is respectively linked with the cyclone separator, the heat exchanger and the water replenishing tank, so that ammonia gas is automatically absorbed by water, and the gas-liquid separation effect and ammonia gas absorption efficiency of the ammonia gas and ammonia water are improved; simultaneously, through set up the heat exchange tube in the pipeline of discharging fume, utilize the waste heat heating ammonia of boats and ships tail gas, make the ammonia inflation pressure boost, the ammonia after the pressure boost can be regarded as the main fluid of sprayer and the atomizing air supply of two fluid spray guns, utilize the ammonia of pressure boost can make aqueous ammonia and boats and ships tail gas mix evenly in the SCR blender, need not external air supply and can realize the even injection of ammonia, ammonia treatment jointly goes on with SCR denitration treatment, realizes the complete absorption of ammonia and tail gas denitration treatment. According to the grading treatment system for the ammonia gas for the ship, provided by the invention, through reasonable design, the ammonia gas discharged in the running process of the ship can be continuously, stably and efficiently absorbed, and finally, no ammonia gas is released from the ship, and the grading treatment system can be used for denitration treatment of ship tail gas, so that the safety of ship navigation is ensured.
Drawings
FIG. 1 is a schematic structural diagram of a staged treatment system for marine ammonia gas in an embodiment of the invention.
Detailed Description
The following detailed description of embodiments of the present invention is provided in connection with the accompanying drawings and examples. The following examples are intended to illustrate the invention but are not intended to limit the scope of the invention.
The terms "first," "second," "third," "fourth," and the like in the description and in the claims, if any, are used for distinguishing between similar elements and not necessarily for describing a particular sequential or chronological order.
As shown in fig. 1, the staged ammonia gas treatment system for a ship provided by the embodiment of the present invention includes an ammonia discharge pipeline 11, an ammonia storage tank 1, a heat exchanger 2, a first injector 3, a water replenishment tank 4, a gas-liquid separator 56, an ammonia water supply storage tank 5, a second injector 63, an ammonia water storage tank 6, a first water pump 61, a second water pump 52, a third water pump 73, a two-fluid spray gun 9, an SCR (Selective Catalytic Reduction) mixer 81, an SCR reactor 82, a ship tail gas pipeline 84, and a smoke exhaust pipeline 8;
the ammonia discharge pipeline 11 is communicated with an inlet of the ammonia storage tank 1, an outlet of the ammonia storage tank 1 is communicated with an ammonia inlet of the heat exchanger 2, an ammonia outlet of the heat exchanger 2 is divided into two paths, one path is communicated with the ammonia inlet of the two-fluid spray gun 9 through a connecting pipeline 23, the other path is communicated with an inlet of the first ejector 3, an outlet of the first ejector 3 is communicated with an inlet of the gas-liquid separator 56, and an outlet of the water supplementing tank 4 is communicated with an injection inlet of the first ejector 3; the bottom outlet of the gas-liquid separator 56 is communicated with the inlet of the ammonia water supply storage tank 5, and the top outlet of the gas-liquid separator 56 is communicated with the injection inlet of the second injector 63; the bottom outlet of the ammonia water storage tank 6 is communicated with the inlet of the first water pump 61, the outlet of the first water pump 61 is communicated with the inlet of the second ejector 63, the outlet of the second ejector 63 is communicated with the inlet of the ammonia water storage tank 6, and the bottom outlet of the ammonia water storage tank 6 is communicated with the inlet of the ammonia water supply storage tank 5;
an outlet at the bottom of the ammonia water supply storage tank 5 is communicated with an inlet of a second water pump 52, an outlet of the second water pump 52 is communicated with an ammonia water inlet of a two-fluid spray gun 9, and the two-fluid spray gun 9 extends into the SCR mixer 81;
the ship tail gas pipeline 84 is communicated with an inlet of the SCR mixer 81, an outlet of the SCR mixer 81 is communicated with an inlet of the SCR reactor 82, and an outlet of the SCR reactor 82 is communicated with the smoke exhaust pipeline 8; a heat exchange pipe 83 is arranged in the smoke exhaust pipeline 8, two ends of the heat exchange pipe 83 are respectively communicated with a heat exchange medium inlet and a heat exchange medium outlet of the heat exchanger 2, the third water pump 73 is arranged on a pipeline between the heat exchange pipe 83 and the heat exchange medium inlet or the heat exchange medium outlet of the heat exchanger 2, and the ammonia is heated and expanded through the heat exchange medium by utilizing the heat energy of the waste gas in the smoke exhaust pipeline 8, so that the flow rate of the ammonia is increased.
Specifically, when the engine is operating in the ammonia-fueled mode (i.e., when the engine is operating with ammonia as fuel), there are several ammonia emission conditions: 1. purging ammonia fuel stored in the pipeline by using nitrogen; 2. the ammonia fuel is supplied to the double-stop vent valve to operate and corresponds to the ammonia fuel stored on the vent valve pipeline; 3. the overpressure piping system discharges ammonia fuel through a safety valve during system operation; 4. ammonia vapor in the ammonia fuel tank. The discharged ammonia gas is collected and then enters the ammonia storage tank 1 through the ammonia discharge pipeline 11, and the gas phase and the liquid phase are separated in the ammonia storage tank 1.
Further, as shown in fig. 1, in the present embodiment, the aqueous ammonia storage tank 6 is replenished with water through the tap water supply line 67. The top outlet of the ammonia water storage tank 6 is communicated to the connecting pipeline 23, a first pressure sensor 65 and a first ammonia concentration sensor 68 are arranged on the ammonia water storage tank 6, a first switch valve 66 is arranged on a pipeline between the top outlet of the ammonia water storage tank 6 and the connecting pipeline 23, a second switch valve 69 is arranged on a pipeline between the bottom outlet of the ammonia water storage tank 6 and the inlet of the ammonia water supply storage tank 5, the first pressure sensor 65 is in signal connection with the first switch valve 66, and the first ammonia concentration sensor 68 is in signal connection with the second switch valve 69.
Specifically, in this embodiment, the first ammonia concentration sensor 68 is used for detecting the concentration of the ammonia water in the ammonia water storage tank 6, and when the concentration of the ammonia water in the ammonia water storage tank 6 reaches a set value, the second switch valve 69 is automatically opened, so as to supplement the ammonia water in the ammonia water storage tank 6 into the ammonia water supply storage tank 5. The first pressure sensor 65 is used for detecting the pressure in the ammonia water storage tank 6, and when the pressure in the ammonia water storage tank 6 reaches a set value, the first switch valve 66 is automatically opened, so that residual gases such as nitrogen and the like which are not absorbed by water in the upper space in the ammonia water storage tank 6 are discharged to the connecting pipeline 23, and finally are sprayed into the smoke exhaust pipeline 8 through the two-fluid spray gun 9 to be discharged.
Further, as shown in fig. 1, in this embodiment, a top outlet of the ammonia water supply tank 5 is communicated to the connection pipeline 23, a second pressure sensor 54 and a second ammonia concentration sensor 53 are disposed on the ammonia water supply tank 5, an ammonia gas sensor 85 is disposed on the smoke exhaust pipeline 8, a third switch valve 55 is disposed on a pipeline between the top outlet of the ammonia water supply tank 5 and the connection pipeline 23, a fourth switch valve 51 is disposed on a pipeline between an outlet of the second water pump 52 and an ammonia water inlet of the two-fluid spray gun 9, the second pressure sensor 54 is in signal connection with the third switch valve 55, and the ammonia gas sensor 85 and the second ammonia concentration sensor 53 are both in signal connection with the fourth switch valve 51.
Specifically, in this embodiment, the second ammonia concentration sensor 53 is configured to detect a concentration of ammonia water in the ammonia water supply tank 5, and the ammonia gas sensor 85 is configured to detect a concentration of ammonia gas in the smoke exhaust pipeline 8, and during the denitration process, the opening of the fourth switch valve 51 is controlled by the concentration of ammonia water in the ammonia water supply tank 5 and the concentration of ammonia gas in the smoke exhaust pipeline 8 together, so as to minimize an ammonia escape amount after the denitration reaction (if the supply amount of ammonia water is too large, although the denitration reaction is more complete, the ammonia escape amount is increased, and if the supply amount of ammonia water is too small, the ammonia escape amount is decreased, but the denitration reaction is incomplete, so that the supply amount of ammonia water needs to be adjusted to a proper level). The second pressure sensor 54 is used for detecting the pressure in the ammonia water supply tank 5, and when the pressure in the ammonia water supply tank 5 reaches a set value, the third switch valve 55 is automatically opened, so that residual gases such as nitrogen and the like which are not absorbed by water in the upper space in the ammonia water supply tank 5 are discharged to the connecting pipeline 23, and finally are sprayed into the smoke exhaust pipeline 8 through the two-fluid spray gun 9 to be discharged.
Further, as shown in fig. 1, in the present embodiment, the staged ammonia gas treatment system for a ship further includes a vaporizer 19, a bottom outlet of the ammonia storage tank 1 is communicated with a liquid ammonia inlet of the vaporizer 19, a liquid ammonia outlet of the vaporizer 19 is communicated with an inlet of the ammonia storage tank 1, and two ends of the heat exchange tube 83 are further communicated with a heat exchange medium inlet and a heat exchange medium outlet of the vaporizer 19, respectively.
Specifically, the liquid ammonia in the ammonia tank 1 is heated and vaporized by the vaporizer 19, so that the internal pressure of the ammonia tank 1 is increased, thereby causing the ammonia gas in the ammonia tank 1 to be discharged and increasing the pressure at which the ammonia gas is discharged.
Further, as shown in fig. 1, in the present embodiment, the staged ammonia gas treatment system for a ship further includes a return line 18, and the return line 18 is communicated with the bottom outlet of the ammonia storage tank 1; the ammonia storage tank 1 is provided with a first liquid level meter 15, a pipeline between the bottom outlet of the ammonia storage tank 1 and the liquid ammonia inlet of the vaporizer 19 is provided with a fifth switch valve 16, a return pipeline 18 is provided with a sixth switch valve 17, and the first liquid level meter 15 is simultaneously in signal connection with the fifth switch valve 16 and the sixth switch valve 17.
Specifically, the first liquid level meter 15 is used for monitoring the liquid level of the liquid ammonia in the ammonia storage tank 1, after the liquid ammonia in the ammonia storage tank 1 reaches a certain liquid level height, the sixth switch valve 17 is opened, and the liquid ammonia in the ammonia storage tank 1 returns to the ammonia fuel tank (not shown) through the return line 18.
Further, as shown in fig. 1, in the present embodiment, a third pressure sensor 14 is disposed on the ammonia storage tank 1, a seventh switch valve 13 is disposed on a pipeline between an outlet of the ammonia storage tank 1 and an ammonia gas inlet of the heat exchanger 2, and the third pressure sensor 14 is in signal connection with the seventh switch valve 13.
Further, as shown in fig. 1, in the present embodiment, a second liquid level meter 43 is disposed on the water replenishing tank 4, the water replenishing tank 4 replenishes water through a first water replenishing pipeline (not numbered), a third valve 42 is disposed on the first water replenishing pipeline, and the second liquid level meter 43 is in signal connection with the third valve 42; when the liquid level in the water replenishing tank 4 is too low, the third valve 42 is automatically opened to replenish water into the water replenishing tank 4.
Further, as shown in fig. 1, in the present embodiment, an inverted U-shaped pipe 41 is provided on a pipeline between the outlet of the water replenishing tank 4 and the injection inlet of the first injector 3.
Specifically, in order to prevent the water in the water replenishing tank 4 from directly flowing into the first ejector 3, the inverted U-shaped pipe 41 is arranged, so that when ammonia gas passes through the first ejector 3, the water in the water replenishing tank 4 is injected into the first ejector 3 and then mixed with the ammonia gas in the first ejector 3 to form ammonia water.
Further, as shown in fig. 1, in the present embodiment, a spraying device 64 is provided in the ammonia water storage tank 6, and an outlet of the second injector 63 is connected to the spraying device 64.
Specifically, in the present embodiment, the shower device 64 includes a shower pipe and a shower head, and the shower device 64 is configured to uniformly spray the ammonia water into the ammonia water storage tank 6, so as to absorb the ammonia gas remaining in the upper space in the ammonia water storage tank 6.
Further, as shown in fig. 1, in this embodiment, the staged ammonia gas treatment system for a ship further includes an expansion water tank 7, and an outlet of the expansion water tank 7 is communicated to a pipeline between the heat exchange pipe 83 and a heat exchange medium inlet or a heat exchange medium outlet of the heat exchanger 2.
Specifically, in this embodiment, the expansion water tank 7 is used to supplement the heat exchange medium (in this embodiment, the heat exchange medium is water, but may also be other heat exchange liquids). The expansion water tank 7 supplements water through a second water supplementing pipeline (not numbered in the figure), a fifth valve 72 is arranged on the second water supplementing pipeline, a third liquid level meter 71 is arranged on the expansion water tank 7, and the third liquid level meter 71 is in signal connection with the fifth valve 72; when the liquid level in the expansion water tank 7 is too low, the fifth valve 72 is automatically opened to supplement water into the expansion water tank 7.
Further, as shown in fig. 1, in this embodiment, the system for graded treatment of ammonia gas for a ship further includes a pressure relief pipeline 10, one end of the pressure relief pipeline 10 is communicated with the ammonia storage tank 1, and the other end of the pressure relief pipeline 10 is communicated to a pipeline between an outlet of the ammonia storage tank 1 and an ammonia gas inlet of the heat exchanger 2. The pressure relief pipeline 10 is provided with a safety valve 12, when the pressure in the ammonia storage tank 1 is overpressure and needs emergency pressure relief, the safety valve 12 is automatically opened to discharge the ammonia gas in the ammonia storage tank 1, and therefore the pressure in the ammonia storage tank 1 is reduced.
Further, as shown in fig. 1, in the present embodiment, a first valve 21 is disposed on a pipeline between the ammonia gas outlet of the heat exchanger 2 and the inlet of the first ejector 3, a second valve 22 is disposed on the connecting pipeline 23, a fourth valve 62 is disposed on an outlet pipeline of the first water pump 61, and a sixth valve 74 is disposed on an outlet pipeline of the third water pump 73.
Specifically, the work flow of the marine ammonia gas staged treatment system of the embodiment is as follows:
1. ammonia gas discharged by a ship in the running process is collected and then uniformly enters an ammonia storage tank 1 through an ammonia discharge pipeline 11, and the separation of gas phase and liquid phase is realized in the ammonia storage tank 1; the liquid level of the liquid ammonia in the ammonia storage tank 1 is monitored by the first liquid level meter 15 in real time, after the liquid ammonia in the ammonia storage tank 1 reaches a certain liquid level height, the sixth switch valve 17 is opened, and the liquid ammonia in the ammonia storage tank 1 returns to the ammonia fuel cabin through the return pipeline 18.
2. When the ammonia gas discharge volume is large in the running process of the ammonia fuel supply system, starting the ammonia water preparation process, opening the fifth switch valve 16 based on the liquid level height in the ammonia storage tank 1, and returning the liquid ammonia to the upper part of the ammonia storage tank 1 after the liquid ammonia is heated and vaporized by the vaporizer 19, so that the pressure in the ammonia storage tank 1 is increased; simultaneously through the pressure in the third pressure sensor 14 monitoring ammonia storage tank 1, after certain pressure, open seventh ooff valve 13, the ammonia in the ammonia storage tank 1 is discharged, continues to heat up through heat exchanger 2, and the ammonia volume expands, and the velocity of flow increases, and the ammonia of taking the area this moment can realize two kinds of functions:
a. the first valve 21 is opened, the ammonia gas with high flow rate is used as the main fluid of the first ejector 3 to eject the water in the water replenishing tank 4, the ammonia gas is absorbed in the first ejector 3 to form ammonia water, and then the ammonia water enters the cyclone separator 56 to realize the separation of the residual ammonia gas and the ammonia water; the separated ammonia water flows into the ammonia water supply tank 5, and the remaining ammonia gas is absorbed into water by the second ejector 63. The first injector 3 takes ammonia flowing at high speed as main fluid, water in the water replenishing tank 4 is sucked by negative pressure at the necking position of the first injector 3, and the ammonia is absorbed by the water to form ammonia water. An inverted U-shaped water outlet pipe 41 is arranged between the water replenishing tank 4 and the first ejector 3, water is not replenished when the first ejector 3 does not operate, water is sucked when the first ejector 3 operates, and the function of automatic water replenishing when the first ejector 3 operates is realized.
The inside special circulation passageway that sets up of cyclone 56 realizes the gas-liquid separation of ammonia and aqueous ammonia, and the ammonia is drawn as the ejector stream of second sprayer 63, finally is absorbed by the circulating water in aqueous ammonia storage tank 6 again, and the circulating water flows into as the main fluid in the second sprayer 63 through fourth valve 62 after through the pressure boost of first water pump 61, then sprays evenly to aqueous ammonia storage tank 6 in through spray set 64 in aqueous ammonia storage tank 6, absorbs the remaining ammonia of upper portion space in aqueous ammonia storage tank 6 once more.
The ammonia water storage tank 6 is provided with a first ammonia concentration sensor 68 for detecting the concentration of the ammonia water in the ammonia water storage tank 6, and when the concentration of the ammonia water in the ammonia water storage tank 6 reaches a set value, the second switch valve 69 is automatically opened, so that the ammonia water in the ammonia water storage tank 6 is supplemented into the ammonia water supply storage tank 5. The first pressure sensor 65 is arranged on the ammonia water storage tank 6 to detect the pressure in the ammonia water storage tank 6, and when the pressure in the ammonia water storage tank 6 reaches a set value, the first switch valve 66 is automatically opened, so that residual gases such as nitrogen and the like which are not absorbed by water in the upper space in the ammonia water storage tank 6 are discharged to the connecting pipeline 23, and finally are sprayed into the smoke exhaust pipeline 8 through the two-fluid spray gun 9 to be discharged.
The ammonia water supply tank 5 is provided with a second pressure sensor 54 for detecting the pressure in the ammonia water supply tank 5, and when the pressure in the ammonia water supply tank 5 reaches a set value, the third switch valve 55 is automatically opened, so that residual gases such as nitrogen and the like which are not absorbed by water in the upper space in the ammonia water supply tank 5 are discharged to the connecting pipeline 23 and finally sprayed into the smoke exhaust pipeline 8 through the two-fluid spray gun 9 for discharging.
b. The second valve 22 is opened, and ammonia gas with pressure is used as a power source of the two-fluid spray gun 9 to drive the ammonia water from the ammonia water supply storage tank 5 to be sprayed into the SCR mixer 81 so as to provide ammonia gas for SCR reaction. The ammonia gas and the ammonia water are fully mixed with the flue gas from the ship tail gas pipeline 84 in the SCR mixer 81 and then enter the SCR reactor 82, so that the denitration treatment of the ship tail gas is realized. In the denitration process, ammonia water is pumped into the SCR mixer 81 through the second water pump 52, the ammonia gas concentration in exhaust gas is detected through the ammonia gas sensor 85, the ammonia water concentration is detected through the second ammonia concentration sensor 53, the opening degree of the fourth switch valve 51 is controlled in a closed-loop mode, and the minimum ammonia escape amount after denitration reaction is achieved.
The embodiment of the invention also provides an ammonia fuel power ship which comprises the marine ammonia gas grading treatment system.
According to the grading treatment system for the marine ammonia gas, provided by the embodiment of the invention, the ammonia gas is completely absorbed by water by arranging the two-stage ejector 3/63, the ammonia water supply storage tank 5 and the ammonia water storage tank 6; meanwhile, the two-stage ejector 3/63 is respectively linked with the cyclone separator 56, the heat exchanger 2 and the water replenishing tank 4 to realize automatic ammonia absorption of water, and improve the gas-liquid separation effect of ammonia and ammonia water and the ammonia absorption efficiency; meanwhile, through setting up heat exchange tube 83 in smoke exhaust pipe 8, utilize the waste heat heating ammonia of boats and ships tail gas, make the ammonia inflation pressure boost, the ammonia after the pressure boost can be regarded as the main fluid of first sprayer 3 and the atomizing air supply of two-fluid spray gun 9, utilize the ammonia of pressure boost can make aqueous ammonia and boats and ships tail gas mix evenly in SCR blender 81, need not external air supply and can realize the even injection of ammonia, ammonia treatment jointly goes on with SCR denitration treatment, realize the complete absorption of ammonia and tail gas denitration treatment. According to the grading treatment system for the ammonia gas for the ship, provided by the embodiment of the invention, through reasonable design, the ammonia gas discharged in the running process of the ship can be continuously, stably and efficiently absorbed, and finally, the ship is free from ammonia gas release and can be used for denitration treatment of ship tail gas, so that the safety of ship navigation is ensured. The marine ammonia gas grading treatment system has the advantages that:
1. a two-stage ejector 3/63 is provided to achieve complete ammonia absorption: by arranging the two-stage ejector 3/63, the first ejector 3 adopts ammonia gas as a main fluid and realizes primary absorption of the ammonia gas by guiding water; the second ejector 63 uses water as a main fluid and realizes secondary absorption of ammonia gas by ejecting ammonia gas. By providing the two-stage ejector 3/63, complete absorption of ammonia gas is achieved;
2. the second ejector 63 and the cyclone separator 56 are in linkage action, so that the gas-liquid separation effect is improved: the gas phase outlet of the cyclone separator 56 is connected with the fluid inlet injected by the second injector 63, so that the outlet of the cyclone separator 56 has suction force, and the gas phase separated from the cyclone separator 56 can be injected into a water circulation pipe system by the second injector 63, so that the ammonia gas is absorbed by the water, and the gas-liquid separation effect of the cyclone separator 56 is improved;
3. first sprayer 3 and 2 linkage effect of heat exchanger improve the ammonia absorption effect: the heat exchanger 2 is additionally arranged at the front end of a main fluid inlet of the first ejector 3, so that the temperature of ammonia entering the first ejector 3 is increased, the flow rate of the ammonia is increased, water in the water replenishing tank 4 is better ejected, and the ammonia absorption effect is improved;
4. the first ejector 3 and the water replenishing tank 4 act in a linkage manner to realize that water automatically absorbs ammonia gas: an inverted U-shaped pipe 41 is arranged at the outlet of the water replenishing tank 4, so that when no injection fluid exists, water in the water replenishing tank 4 is in a water sealing state, and no water flows out; when the first ejector 3 works, water in the water replenishing tank 4 can be injected into the first ejector 3, so that the automatic absorption of ammonia gas is realized;
5. the vaporizer 19 and the ammonia storage tank 1 act in a linkage manner to realize the self-pressurization of ammonia gas: the vaporizer 19 is matched with the ammonia storage tank 1 and is used for vaporizing the liquid ammonia at the bottom of the ammonia storage tank 1 into ammonia gas and returning the ammonia gas to the top of the ammonia storage tank 1, so that the internal pressure of the ammonia storage tank 1 is increased, and the pressurized ammonia gas can be used as a main fluid of the first ejector 3 and an atomization gas source of the two-fluid spray gun 9;
6. the waste heat of the ship tail gas is utilized to realize ammonia heating and temperature rising: the heat exchange pipe 83 is arranged in the smoke exhaust pipeline 8, the water in the heat exchange pipe is heated by the waste heat of ship exhaust, the water circulates in the circulation pipeline in a closed mode, the expansion water tank 7 is arranged to realize automatic water supplement, the supply of hot water is ensured, and the heating and the temperature rise of ammonia are realized;
7. ammonia gas treatment and denitration treatment combine, realize ammonia absorption and tail gas denitration treatment: the system is provided with a device for absorbing ammonia gas in multiple stages, ammonia water with a certain concentration is obtained through treatment, and the ammonia water is sprayed into an SCR mixer 81 and an SCR reactor 82 by a reducing agent used in SCR denitration reaction, so that ammonia absorption and tail gas denitration treatment are realized;
8. set up ammonia and aqueous ammonia two-fluid spray gun 9, need not the even injection of outside air supply realization ammonia: set up the two-fluid spray gun 9 of ammonia and aqueous ammonia, through taking the pressure ammonia and aqueous ammonia at the inside mixture of two-fluid spray gun 9 and spraying, under the condition that need not outside air supply, ammonia can evenly spray to SCR reaction unit in, and then fully take place the denitration reaction.
Example one:
when the system starts ammonia gas treatment, liquid ammonia flows into the vaporizer 19 from the ammonia storage tank 1, enters the top of the ammonia storage tank 1 after vaporization, the pressure in the ammonia storage tank 1 is continuously increased, after the set pressure is reached, the seventh switch valve 13 is opened, the first ejector 3 starts to work, ammonia gas flowing at high speed enters the first ejector 3, negative pressure is generated inside the first ejector 3, water in the water supplementing tank 4 automatically flows into the first ejector 3, the ammonia gas is subjected to primary absorption, and a generated gas-liquid mixture flows into the cyclone separator 56 to realize the separation of ammonia water and ammonia gas; at this time, the second ejector 63 uses water as a main fluid to eject gas-phase substances in the cyclone separator 56, thereby realizing secondary absorption of ammonia gas. Through the arrangement of the two-stage ejector, the complete absorption of ammonia gas is realized.
Through the above operation process, it was found that the ammonia gas released in the ammonia storage tank 1 can be completely absorbed.
Example two:
when the system starts denitration treatment, liquid ammonia flows into the vaporizer 19 from the ammonia storage tank 1, enters the top of the ammonia storage tank 1 after vaporization, the pressure in the ammonia storage tank 1 is continuously increased, and when the set pressure is reached, the seventh switch valve 13 is opened, and ammonia is sprayed into the two-fluid spray gun 9; meanwhile, ammonia water is pumped in through the second water pump 52, and at the moment, the ammonia gas and ammonia water mixture is uniformly sprayed into the SCR mixer 81 and then enters the SCR reactor 82, so that the efficient denitration treatment of the ship tail gas is realized.
Through the operation process, the ammonia gas and the ammonia water generated by the system can be found to realize the high-efficiency denitration treatment of the ship tail gas.
The above description is only for the specific embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present invention, and all the changes or substitutions should be covered within the scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the protection scope of the appended claims.
Claims (10)
1. A marine ammonia gas grading treatment system is characterized by comprising an ammonia discharge pipeline (11), an ammonia storage tank (1), a heat exchanger (2), a first ejector (3), a water supplementing tank (4), a cyclone separator (56), an ammonia water supply storage tank (5), a second ejector (63), an ammonia water storage tank (6), a first water pump (61), a second water pump (52), a third water pump (73), a two-fluid spray gun (9), an SCR mixer (81), an SCR reactor (82), a ship tail gas pipeline (84) and a smoke exhaust pipeline (8);
the ammonia discharge pipeline (11) is communicated with an inlet of the ammonia storage tank (1), an outlet of the ammonia storage tank (1) is communicated with an ammonia gas inlet of the heat exchanger (2), an ammonia gas outlet of the heat exchanger (2) is divided into two paths, one path is communicated with the ammonia gas inlet of the two-fluid spray gun (9) through a connecting pipeline (23), the other path is communicated with an inlet of the first ejector (3), an outlet of the first ejector (3) is communicated with an inlet of the cyclone separator (56), and an outlet of the water replenishing tank (4) is communicated with an injection inlet of the first ejector (3); the bottom outlet of the cyclone separator (56) is communicated with the inlet of the ammonia water supply storage tank (5), and the top outlet of the cyclone separator (56) is communicated with the injection inlet of the second injector (63); the bottom outlet of the ammonia water storage tank (6) is communicated with the inlet of the first water pump (61), the outlet of the first water pump (61) is communicated with the inlet of the second ejector (63), the outlet of the second ejector (63) is communicated with the inlet of the ammonia water storage tank (6), and the bottom outlet of the ammonia water storage tank (6) is communicated with the inlet of the ammonia water supply storage tank (5);
the bottom outlet of the ammonia water supply storage tank (5) is communicated with the inlet of the second water pump (52), the outlet of the second water pump (52) is communicated with the ammonia water inlet of the two-fluid spray gun (9), and the two-fluid spray gun (9) extends into the SCR mixer (81);
the ship tail gas pipeline (84) is communicated with an inlet of the SCR mixer (81), an outlet of the SCR mixer (81) is communicated with an inlet of the SCR reactor (82), and an outlet of the SCR reactor (82) is communicated with the smoke exhaust pipeline (8); a heat exchange pipe (83) is arranged in the smoke exhaust pipeline (8), two ends of the heat exchange pipe (83) are respectively communicated with a heat exchange medium inlet and a heat exchange medium outlet of the heat exchanger (2), and the third water pump (73) is arranged on a pipeline between the heat exchange pipe (83) and the heat exchange medium inlet or the heat exchange medium outlet of the heat exchanger (2).
2. The staged ammonia gas treatment system for ships as recited in claim 1, wherein a top outlet of the ammonia water storage tank (6) is connected to the connecting pipeline (23), a first pressure sensor (65) and a first ammonia concentration sensor (68) are arranged on the ammonia water storage tank (6), a first switch valve (66) is arranged on a pipeline between the top outlet of the ammonia water storage tank (6) and the connecting pipeline (23), a second switch valve (69) is arranged on a pipeline between a bottom outlet of the ammonia water storage tank (6) and an inlet of the ammonia water supply storage tank (5), the first pressure sensor (65) is in signal connection with the first switch valve (66), and the first ammonia concentration sensor (68) is in signal connection with the second switch valve (69).
3. A staged ammonia gas treatment system for ships according to claim 1, wherein a top outlet of the ammonia water supply tank (5) is connected to the connecting line (23), a second pressure sensor (54) and a second ammonia concentration sensor (53) are arranged on the ammonia water supply storage tank (5), an ammonia gas sensor (85) is arranged on the smoke exhaust pipeline (8), a third switch valve (55) is arranged on a pipeline between the top outlet of the ammonia water supply storage tank (5) and the connecting pipeline (23), a fourth switch valve (51) is arranged on a pipeline between the outlet of the second water pump (52) and the ammonia water inlet of the two-fluid spray gun (9), the second pressure sensor (54) is in signal connection with the third switching valve (55), the ammonia gas sensor (85) and the second ammonia concentration sensor (53) are in signal connection with the fourth switch valve (51).
4. The staged ammonia gas treatment system for ships as defined in claim 1, further comprising a vaporizer (19), wherein the bottom outlet of the ammonia storage tank (1) is communicated with the liquid ammonia inlet of the vaporizer (19), the liquid ammonia outlet of the vaporizer (19) is communicated with the inlet of the ammonia storage tank (1), and the two ends of the heat exchange tube (83) are further communicated with the heat exchange medium inlet and the heat exchange medium outlet of the vaporizer (19), respectively.
5. A staged marine ammonia gas treatment system according to claim 4, further comprising a return line (18), said return line (18) being in communication with a bottom outlet of the ammonia storage tank (1); be equipped with first level gauge (15) on ammonia storage tank (1), the bottom export of ammonia storage tank (1) with be equipped with fifth ooff valve (16) on the pipeline between the liquid ammonia entry of vaporizer (19), be equipped with sixth ooff valve (17) on return line (18), first level gauge (15) simultaneously with fifth ooff valve (16) with sixth ooff valve (17) signal connection.
6. The staged ammonia gas treatment system for ships according to claim 1, wherein a third pressure sensor (14) is arranged on the ammonia storage tank (1), a seventh switch valve (13) is arranged on a pipeline between the outlet of the ammonia storage tank (1) and the ammonia gas inlet of the heat exchanger (2), and the third pressure sensor (14) is in signal connection with the seventh switch valve (13).
7. The staged ammonia gas treatment system for ships according to claim 1, wherein an inverted U-shaped pipe (41) is arranged on a pipeline between the outlet of the make-up water tank (4) and the injection inlet of the first injector (3).
8. A staged ammonia gas treatment system for ships according to claim 1, wherein a spray device (64) is arranged in the ammonia water storage tank (6), and the outlet of the second ejector (63) is connected with the spray device (64).
9. A staged ammonia gas treatment system for ships as defined in claim 1, further comprising an expansion water tank (7), wherein the outlet of the expansion water tank (7) is connected to the pipeline between the heat exchange pipe (83) and the heat exchange medium inlet or outlet of the heat exchanger (2).
10. An ammonia-fueled marine vessel comprising the marine ammonia gas staged treatment system of any one of claims 1 to 9.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202210112481.XA CN114382572A (en) | 2022-01-29 | 2022-01-29 | Marine ammonia gas grading treatment system and ammonia fuel power ship |
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| CN202210112481.XA CN114382572A (en) | 2022-01-29 | 2022-01-29 | Marine ammonia gas grading treatment system and ammonia fuel power ship |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114933004A (en) * | 2022-06-20 | 2022-08-23 | 青岛双瑞海洋环境工程股份有限公司 | Ship ammonia vapor liquefaction recovery system and ammonia fuel power ship |
| CN114941562A (en) * | 2022-05-24 | 2022-08-26 | 上海交通大学 | Ammonia jet mixer for diesel-ammonia dual-fuel engine DeNOx and injection method |
-
2022
- 2022-01-29 CN CN202210112481.XA patent/CN114382572A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114941562A (en) * | 2022-05-24 | 2022-08-26 | 上海交通大学 | Ammonia jet mixer for diesel-ammonia dual-fuel engine DeNOx and injection method |
| CN114933004A (en) * | 2022-06-20 | 2022-08-23 | 青岛双瑞海洋环境工程股份有限公司 | Ship ammonia vapor liquefaction recovery system and ammonia fuel power ship |
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