CN114375223B - 改进的热交换流动反应器 - Google Patents

改进的热交换流动反应器 Download PDF

Info

Publication number
CN114375223B
CN114375223B CN202080061339.6A CN202080061339A CN114375223B CN 114375223 B CN114375223 B CN 114375223B CN 202080061339 A CN202080061339 A CN 202080061339A CN 114375223 B CN114375223 B CN 114375223B
Authority
CN
China
Prior art keywords
heat exchange
exchange fluid
flow reactor
module
fluid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202080061339.6A
Other languages
English (en)
Other versions
CN114375223A (zh
Inventor
S·M·F·格雷梅兹
E·D·拉夫瑞克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Corning Inc
Original Assignee
Corning Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Corning Inc filed Critical Corning Inc
Publication of CN114375223A publication Critical patent/CN114375223A/zh
Application granted granted Critical
Publication of CN114375223B publication Critical patent/CN114375223B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/02—Apparatus characterised by being constructed of material selected for its chemically-resistant properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D9/0031—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by paired plates touching each other
    • F28D9/0037—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by paired plates touching each other the conduits for the other heat-exchange medium also being formed by paired plates touching each other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/04—Constructions of heat-exchange apparatus characterised by the selection of particular materials of ceramic; of concrete; of natural stone
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F21/00—Constructions of heat-exchange apparatus characterised by the selection of particular materials
    • F28F21/08—Constructions of heat-exchange apparatus characterised by the selection of particular materials of metal
    • F28F21/081—Heat exchange elements made from metals or metal alloys
    • F28F21/084—Heat exchange elements made from metals or metal alloys from aluminium or aluminium alloys
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F3/00—Plate-like or laminated elements; Assemblies of plate-like or laminated elements
    • F28F3/02—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations
    • F28F3/04—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations the means being integral with the element
    • F28F3/048—Elements or assemblies thereof with means for increasing heat-transfer area, e.g. with fins, with recesses, with corrugations the means being integral with the element in the form of ribs integral with the element or local variations in thickness of the element, e.g. grooves, microchannels
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F7/00—Elements not covered by group F28F1/00, F28F3/00 or F28F5/00
    • F28F7/02—Blocks traversed by passages for heat-exchange media
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00788—Three-dimensional assemblies, i.e. the reactor comprising a form other than a stack of plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00788—Three-dimensional assemblies, i.e. the reactor comprising a form other than a stack of plates
    • B01J2219/0079—Monolith-base structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00822—Metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00858—Aspects relating to the size of the reactor
    • B01J2219/0086—Dimensions of the flow channels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00873—Heat exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00889—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/0204—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components
    • B01J2219/0218—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components of ceramic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/0204—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components
    • B01J2219/0236—Metal based
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
    • B01J2219/0263—Ceramic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/2402—Monolithic-type reactors
    • B01J2219/2403—Geometry of the channels
    • B01J2219/2406—Rectangular
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/2402—Monolithic-type reactors
    • B01J2219/2409—Heat exchange aspects
    • B01J2219/2411—The reactant being in indirect heat exchange with a non reacting heat exchange medium
    • B01J2219/2412—Independent temperature control in various sections of the monolith
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
    • F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
    • F28D2021/0022—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for chemical reactors
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2250/00—Arrangements for modifying the flow of the heat exchange media, e.g. flow guiding means; Particular flow patterns
    • F28F2250/08—Fluid driving means, e.g. pumps, fans
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2265/00—Safety or protection arrangements; Arrangements for preventing malfunction
    • F28F2265/26—Safety or protection arrangements; Arrangements for preventing malfunction for allowing differential expansion between elements

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)

Abstract

一种流动反应器，其包括流动反应器模块，所述流动反应器模块具有热交换流体包壳，所述热交换流体包壳具有密封向工艺流体模块的表面的内表面，所述内表面具有两个或更多个突起的脊，所述脊与从流入端口或位置到流出端口或位置的热交换流动方向交叉，并且在所述两个或更多个突起的脊与工艺模块表面之间具有大于0.1mm的间隙。

Description

改进的热交换流动反应器
相关申请的交叉引用
本申请根据35U.S.C.§119，要求2019年8月31日提交的第62/894,784号美国临时申请的优先权权益，其内容通过引用全文纳入本文。
技术领域
本公开一般地涉及用于流动反应器和流动反应处理的设备和方法，更具体地涉及流动反应器，所述流动反应器包括中心主体，所述中心主体具有从中通过的通道以及第一和第二外主表面，所述流动反应器还包括分别与第一和第二外主表面热接触的第一和第二热控制流体通道，并且具有规定的一个或多个泵以用于供应规定的热控制流体。
背景技术
出于对陶瓷材料(特别是碳化硅)的极高的化学耐性、高的机械强度和极高的导热性的渴望，已经由陶瓷材料(特别是碳化硅)形成了流动反应器的高性能流动模块。在需要严格的反应过程热控制的情况中，一种解决方案使用了如图1所示的大致平面的工艺流体模块10，该工艺流体模块10具有两个外主表面12、14，例如，由两块碳化硅板或其他陶瓷板组成的工艺流体模块，这两块板临时或永久结合并且在这两个半部之间限定了工艺流体通道P，这两块板与如图2所示的热交换包壳16、18一起密封到两个主表面12、14中的每一者，并且与相应的主表面配合限定了与相应主表面接触的热交换流体通道HP。这种热交换包壳的内表面上的小突起或“紊流器”(未示出)已用于增加流过热交换流体通道的热交换流体中的紊流和/或二次流。
发明内容
根据实施方式，一种流动反应器包括流动反应器模块，所述流动反应器模块具有热交换流体包壳，所述热交换流体包壳具有对着工艺流体模块的表面密封的内表面，所述内表面具有两个或更多个突起的脊，所述脊与从流入端口或位置到流出端口或位置的热交换流动方向交叉，并且在所述两个或更多个突起的脊与工艺模块表面之间具有大于0.1mm的间隙。
更具体地，根据更具体的实施方式，根据本公开所述的一种流动反应器包括流动反应器模块，所述流动反应器模块包括：第一，工艺流体模块，其具有从中延伸通过的工艺流体通道，所述工艺流体模块包括延伸的主体，该延伸的主体具有宽度、长度和厚度，所述厚度小于长度且小于宽度，所述工艺流体模块具有在工艺流体模块的相对侧上的第一主表面和第二主表面，所述第一主表面和第二主表面垂直于工艺流体模块的厚度的方向取向；第二，密封向工艺流体模块的第一主表面的第一热交换流体包壳，第一热交换流体包壳包括用于包含向着第一主表面的热交换流体的内表面以形成用于热交换流体的热交换流体路径，所述第一热交换流体包壳还包括用于将热交换流体输送到热交换流体路径的流入端口或位置和用于接收来自热交换流体路径的热交换流体的流出端口或位置，所述流出端口或位置在第一方向上与所述流入端口或位置隔开；以及第三，密封向工艺流体模块的第二主表面的第二热交换流体包壳，第二热交换流体包壳包括用于包含向着第二主表面的热交换流体的内表面，以形成用于热交换流体的热交换流体路径，所述第二热交换流体包壳还包括用于将热交换流体输送到热交换流体路径的流入端口或位置和用于接收来自热交换流体路径的热交换流体的流出端口或位置。所述第一热交换流体包壳的内表面包括在第二方向上延伸的两个或更多个突起的脊，所述第二方向与第一方向至少部分交叉，并且在所述两个或更多个突起的脊中的连续脊之间具有距离，在所述两个或更多个突起的脊与第一主表面之间具有间隙，并且第二热交换流体包壳的内表面还包括在第二方向上延伸的两个或更多个突起的脊，所述第二方向与第一方向至少部分交叉，并且在所述两个或更多个突起的脊中的连续脊之间具有距离，在所述两个或更多个突起的脊与第二主表面之间具有间隙，并且间隙在0.2至0.5mm的范围内，并且距离在10mm至30mm的范围内。
根据实施方式，流动反应器模块可包括陶瓷或者由陶瓷形成或组成。根据实施方式，陶瓷可包括或可以是碳化硅。
根据实施方式，流动反应器模块可以是整体件，即，作为单个工件形成的一个主体，或者如果由多个工件形成，则由永久结合在一起的多个工件形成以使得除了通过切割、研磨或断裂模块外不能被分离，或诸如此类的一个主体。
根据实施方式，第一热交换流体包壳和第二热交换流体包壳可包括金属或者主要或完全由金属形成。根据实施方式，金属可包括或者可以是铝。
根据实施方式，第一热交换流体包壳的内表面包括三个或更多个突起的脊，并且第二热交换流体包壳的内表面包括三个或更多个突起的脊。
根据实施方式，可对距离和间隙进行选择，以在选定的热交换流体内和使用用于提供热交换流体的选定的热交换泵送功率，将在热交换流体路径内的平均雷诺数最大化至可实现最大值的80％以内。
通过下述说明、附图和权利要求书，不难了解其他的实施方式和各种优点。
附图说明
图1(现有技术)是工艺流体模块的图解透视图。
图2(现有技术)是包括工艺流体模块和热交换包壳的流体模块的图解立视图。
图3(现有技术)是示出了工艺流体模块的透视图，该工艺流体模块具有(内部)工艺流体路径的实施方式的细节。
图4(现有技术)是热交换包壳的一个实施方式的透视图。
图5和6是根据本公开所述的具有隔板的热交换器包壳的实施方式的平面图。
图7是根据本公开所述的具有隔板的热交换器包壳的另外的实施方式的平面图。
图8是根据本公开的实施方式所述的流动反应器模块的视图，其包括热交换器包壳以及工艺流体模块的截面图。
图9是对于三种不同的距离D(沿着箭头方向减小)，在特定的泵送功率下，在具有特定的热交换流体的热交换流体路径内获得的相对雷诺数(Reynolds number,Re)根据间隙(G)而变化的图表，该图显示出，对于给定的泵送功率和热交换流体，通过调整(减小)距离D以及调整(扩大超过间隔开所需要的距离)间隙G，可优化雷诺数。
具体实施方式
上面讨论了图1和图2(现有技术)。图3(现有技术)是示出了工艺流体模块10的透视图，该工艺流体模块10具有(内部)工艺流体路径P的实施方式的细节，例如，可以用在本公开的情境中。图4(现有技术)示出了具有一般形状的热交换包壳的实施方式的透视图，该形状是可预想用于本公开的一种形状。
本公开偏离这些现有技术结构，尤其是如图5-8所示。根据本公开的一个方面，具体参考图5-7，在热交换包壳16、18的内表面17、19上包括突起的脊R。脊R经定位以在由密封物S(例如，O形圈或其他密封物)界定的区域内用作挡板。脊可以采取各种构造，如图5和6的实施方式以及图7所示的六个变化形式中所见到的。所有实施方式的共同点是，脊R的数目至少为两个，并且脊R在一定的方向上延伸，该方向至少与从流入端口或位置I到流出端口或位置O的方向部分交叉。
如参考图8所见到的，根据本公开的另一个方面，在第一主表面14的内表面17上的所述两个或更多个凸起的脊R之间存在间隙G。该间隙G是期望的，因为其保护工艺流体模块10的(有利的)陶瓷结构不受诱导损伤或诱导应力。然而，根据本公开，间隙G有意大于在工艺流体模块10的相应主表面12、14与相关的突起脊R之间提供可靠机械分离所需的距离(例如，大于0.1mm)。这是因为，对于给定的热交换流体和给定的泵送功率，通过使间隙大于机械分离所需的距离，可优化热交换性能。有利地，所述间隙大于0.1mm，有利地，其大于0.2mm或者甚至大于0.3mm或0.4mm，同时保持该间隙足够得小，以使得突起的脊仍能转移大量的流量，例如，间隙小于1mm，有利地，小于0.9mm，小于0.8mm，小于0.7mm，小于0.6mm，小于0.5mm，或者甚至在合适的情况中小于0.4mm。
图9是对于三种不同的距离D(沿着箭头方向减小)，在选定的最大泵送功率下，在具有选定的热交换流体的热交换流体路径内获得的相对雷诺数(Re,y轴)根据间隙G(x轴)而变化的图表。该表显示出，对于给定的泵送功率和热交换流体，通过调整(减小)距离D和调整(扩大超过机械上间隔开所需的)间隙G，可优化热交换流体路径HP中的雷诺数(并因此优化热交换性能)。期望地，可对距离(D)和间隙(G)进行选择，以在选定的热交换流体内和用于泵送热交换流体的选定的热交换泵送功率，在热交换流体路径(HP)内的平均雷诺数最大化至可能最大值的80％、90％或者甚至95％以内。
本发明所公开的方法和/或装置通常可用来进行任何工艺，所述工艺包括在微型结构中对流体或流体混合物，包括多相流体混合物进行混合、分离、萃取、结晶、沉淀或其他的工艺过程——包括含有多相流体混合物而该多相流体混合物还含有固体的流体或流体混合物。所述加工可以包括物理加工、化学反应、生物化学加工或者任意其他形式的加工过程，所述化学反应被定义为导致有机物、无机物或者有机物和无机物都发生相互转化的加工。以下列出了可以通过所公开的方法和/或装置进行的反应的非限制性实例：氧化；还原；取代；消除；加成；配体交换；金属交换以及离子交换。更具体地，以下列出了可以通过所公开的方法和/或装置进行的反应的任意非限制性实例：聚合；烷基化；脱烷基化；硝化；过氧化；磺化氧化；环氧化；氨氧化；氢化；脱氢；有机金属反应；贵金属化学/均相催化剂反应；羰基化；硫羰基化；烷氧基化；卤化；脱氢卤化；脱卤化；加氢甲酰化；羧化；脱羧；胺化；芳基化；肽偶联；羟醛缩合；环化缩合；脱氢环化；酯化；酰胺化；杂环合成；脱水；醇解；水解；氨解；醚化；酶合成；缩酮化(ketalization)；皂化；异构化；季铵化；甲酰化；相转移反应；硅烷化；腈合成；磷酸化；臭氧解；叠氮化物化学；复分解；氢化硅烷化；偶联反应；以及酶反应。
尽管在本公开中仅详细描述了一些实施方式，但是可以进行许多修改(例如，各种元件的大小、尺寸、结构、形状和比例或位置；参数的数值；安装布置；材料的使用；取向上的变化)而不实质背离本文所述主题的新颖性教导和优点。例如，根据本文所述的方法，可以对平坦的玻璃制品和弯曲的玻璃制品进行回火。以一体成形示出的一些元件可以由多个零件或元件构造，各元件的位置可以互换或以其他方式变化，并且可以改变或更改离散元件的性质或数量或者位置。任何工艺、逻辑算法或方法步骤的顺序或序列可以根据替代性实施方式来改变或重新排列。还可以对各种示例性实施方式的设计、操作条件和布置进行其他替代、修改、改变和省略，而不背离本发明的技术范围。

Claims (8)

1.一种流动反应器，其包括：
流动反应器模块(100)；
所述流动反应器模块(100)包括：
工艺流体模块(10)，其具有从中延伸通过的工艺流体通道(P)，所述工艺流体模块(10)包括延伸的主体(22)，该延伸的主体(22)具有宽度(W)、长度(L)和厚度(T)，所述厚度(T)小于长度(L)且小于宽度(W)，所述工艺流体模块(10)具有在工艺流体模块(10)的相对侧上的第一和第二主表面(12、14)，所述第一和第二主表面(12、14)垂直于工艺流体模块(10)的厚度(T)的方向取向；和
密封向工艺流体模块的第一主表面(12)的第一热交换流体包壳(16)，第一热交换流体包壳(16)包括用于包含向着第一主表面(12)的热交换流体的第一内表面(17)以形成用于热交换流体的热交换流体路径(HP)，所述第一热交换流体包壳(16)还包括用于将热交换流体输送到热交换流体路径(HP)的流入端口或位置(I)和用于接收来自热交换流体路径(HP)的热交换流体的流出端口或位置(O)，所述流出端口或位置在第一方向上与所述流入端口或位置(I)隔开；和
密封向工艺流体模块(10)的第二主表面(14)的第二热交换流体包壳(18)，第二热交换流体包壳(18)包括用于包含向着第二主表面(14)的热交换流体的第二内表面(19)以形成用于热交换流体的热交换流体路径(HP)，所述第二热交换流体包壳(18)还包括用于将热交换流体输送到热交换流体路径(HP)的流入端口或位置(I)和用于接收来自热交换流体路径(HP)的热交换流体的流出端口或位置(O)；
其中，第一内表面(17)包括在第二方向上延伸的两个或更多个突起的脊(R)，所述第二方向与第一方向至少部分交叉，并且在所述两个或更多个突起的脊中的连续脊之间具有距离(D)，在所述两个或更多个突起的脊(R)与第一主表面(12)之间具有间隙(G)，
其中，第二内表面(19)还包括在第二方向上延伸的两个或更多个突起的脊(R)，所述第二方向与第一方向至少部分交叉，并且在所述两个或更多个突起的脊(R)中的连续脊之间具有距离(D)，在所述两个或更多个突起的脊(R)与第二主表面(14)之间具有间隙(G)，并且
其中，所述间隙(G)在0.2至0.5mm的范围内，并且所述距离(D)在10mm至30mm的范围内。
2.根据权利要求1所述的流动反应器，其中，所述流动反应器模块包括陶瓷。
3.根据权利要求2所述的流动反应器，其中，所述陶瓷包含碳化硅。
4.根据权利要求2所述的流动反应器，其中，所述流动反应器模块是整体件。
5.根据权利要求2所述的流动反应器，其中，第一和第二热交换流体包壳(16、18)包含金属。
6.根据权利要求5所述的流动反应器，其中，所述金属包含铝。
7.根据权利要求1-6中任一项所述的流动反应器，其中，第一内表面(17)包括三个或更多个突起的脊(R)，并且第二内表面(19)包括三个或更多个突起的脊(R)。
8.根据权利要求1-6中任一项所述的流动反应器，其中，距离(D)和间隙(G)是经过选择的，以在选定的热交换流体内和使用用于提供热交换流体的选定的热交换泵送功率，将在热交换流体路径内的平均雷诺数最大化至可实现最大值的80％以内。
CN202080061339.6A 2019-08-31 2020-08-31 改进的热交换流动反应器 Active CN114375223B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201962894784P 2019-08-31 2019-08-31
US62/894,784 2019-08-31
PCT/US2020/048718 WO2021042023A1 (en) 2019-08-31 2020-08-31 Improved heat exchange flow reactor

Publications (2)

Publication Number Publication Date
CN114375223A CN114375223A (zh) 2022-04-19
CN114375223B true CN114375223B (zh) 2024-04-02

Family

ID=72474001

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202080061339.6A Active CN114375223B (zh) 2019-08-31 2020-08-31 改进的热交换流动反应器

Country Status (6)

Country Link
US (1) US11850564B2 (zh)
EP (1) EP4022241A1 (zh)
JP (1) JP2022546049A (zh)
KR (1) KR20220054638A (zh)
CN (1) CN114375223B (zh)
WO (1) WO2021042023A1 (zh)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1128506A (zh) * 1993-07-05 1996-08-07 帕金诺克斯公司 控制反应温度的装置和方法
WO2008078758A1 (ja) * 2006-12-26 2008-07-03 National Institute Of Advanced Industrial Science And Technology 積層一体型自己熱交換構造体を備えた反応器
CN107223070A (zh) * 2015-02-12 2017-09-29 乔治洛德方法研究和开发液化空气有限公司 用于小于10Nm3/h的氢气生产的毫米级交换器‑反应器
CN107810377A (zh) * 2015-06-10 2018-03-16 康宁股份有限公司 耐热串扰的流动反应器
CN107921400A (zh) * 2015-06-10 2018-04-17 康宁股份有限公司 具有可调传热能力的连续流动反应器

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003340273A (ja) * 2002-05-30 2003-12-02 Casio Comput Co Ltd 化学反応装置及び燃料電池システム並びにその製造方法
JP3979219B2 (ja) * 2002-08-07 2007-09-19 カシオ計算機株式会社 小型化学反応装置
DE102006013503A1 (de) 2006-03-23 2008-01-24 Esk Ceramics Gmbh & Co. Kg Plattenwärmetauscher, Verfahren zu dessen Herstellung und dessen Verwendung
US20100086813A1 (en) * 2006-08-30 2010-04-08 Kyocera Corporation Reaction Apparatus, Fuel Cell System and Electronic Device
DE102008048014A1 (de) 2008-09-12 2010-04-15 Esk Ceramics Gmbh & Co. Kg Bauteil aus einem Stapel keramischer Platten
EP2535105A1 (en) 2011-06-14 2012-12-19 Corning Incorporated Systems and methods for scale-up of microreactors
CN102506606B (zh) 2011-10-10 2014-02-12 南通大学 一种具有清污功能的管壳式换热器
CN203572278U (zh) 2013-10-16 2014-04-30 江苏唯益换热器有限公司 一种钎焊板式换热器
CN205664481U (zh) 2016-05-13 2016-10-26 山东建筑大学 一种基于混热水箱的地热供暖系统

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1128506A (zh) * 1993-07-05 1996-08-07 帕金诺克斯公司 控制反应温度的装置和方法
WO2008078758A1 (ja) * 2006-12-26 2008-07-03 National Institute Of Advanced Industrial Science And Technology 積層一体型自己熱交換構造体を備えた反応器
CN107223070A (zh) * 2015-02-12 2017-09-29 乔治洛德方法研究和开发液化空气有限公司 用于小于10Nm3/h的氢气生产的毫米级交换器‑反应器
CN107810377A (zh) * 2015-06-10 2018-03-16 康宁股份有限公司 耐热串扰的流动反应器
CN107921400A (zh) * 2015-06-10 2018-04-17 康宁股份有限公司 具有可调传热能力的连续流动反应器

Also Published As

Publication number Publication date
US20220274082A1 (en) 2022-09-01
WO2021042023A1 (en) 2021-03-04
CN114375223A (zh) 2022-04-19
KR20220054638A (ko) 2022-05-03
JP2022546049A (ja) 2022-11-02
US11850564B2 (en) 2023-12-26
EP4022241A1 (en) 2022-07-06

Similar Documents

Publication Publication Date Title
EP2437881B1 (en) Honeycomb reactor
CN107810377B (zh) 耐热串扰的流动反应器
JP2016047529A (ja) 多流路型マイクロリアクタ・デザイン
US20120082601A1 (en) Honeycomb reactor or heat exchanger mixer
CN102946989B (zh) 用于微反应器模块的流体连接器
EP2435174B1 (en) Flow controlled microfluidic devices
CN114375223B (zh) 改进的热交换流动反应器
CN102686304A (zh) 具有槽形胞间孔的蜂窝状本体装置
CN211329331U (zh) 一种微反应器
CN116324326A (zh) 具有可互换壁结构的热控制流体通道的流动反应器
US20100116429A1 (en) Method for layered glass micro-reactor fabrication
EP2576061A1 (en) Honeycomb-body-based fluidic interconnectors and methods
EP2506961B1 (en) Honeycomb body u-bend mixers
EP3307429B1 (en) Continuous flow reactor with tunable heat transfer capability
EP2988861B1 (en) Disassemblable stacked flow reactor
US8303909B2 (en) Microfluidic assembly
CN112219055A (zh) 流动反应器塞
WO2013082347A1 (en) Fluidic module permanent stack assemblies and methods

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant