CN114351449A - Mildew-proof cloth and preparation method thereof - Google Patents
Mildew-proof cloth and preparation method thereof Download PDFInfo
- Publication number
- CN114351449A CN114351449A CN202210084929.1A CN202210084929A CN114351449A CN 114351449 A CN114351449 A CN 114351449A CN 202210084929 A CN202210084929 A CN 202210084929A CN 114351449 A CN114351449 A CN 114351449A
- Authority
- CN
- China
- Prior art keywords
- cloth
- parts
- mildew
- agent
- essential oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
- D06M11/71—Salts of phosphoric acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/74—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/005—Compositions containing perfumes; Compositions containing deodorants
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/55—Epoxy resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/06—After-treatment with organic compounds containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The application relates to a mildew-proof cloth and a preparation method thereof, wherein the mildew-proof cloth comprises a cloth body and a mildew preventive, and the mildew preventive comprises the following components in parts by mass: 1-1.5 parts of tea tree essential oil, 8-10 parts of an encapsulating agent, 5-8 parts of tween-805.5, 60-75 parts of a phosphate aqueous solution, 16-20 parts of a slow release auxiliary agent, 3-7 parts of a color fixing agent and 2-3 parts of an anti-wear agent. In the application, the tea tree essential oil has a sterilization function, and after the mildew preventive is attached to the surface of the cloth, the cloth has an antibacterial effect, so that the phenomenon that the cloth is corroded by fungi is reduced; the slow release auxiliary agent can coat the tea tree essential oil, so that the tea tree essential oil can be slowly released, and the tea tree essential oil has a long-term antibacterial effect.
Description
Technical Field
The application relates to the field of cloth, in particular to mildew-proof cloth and a preparation method thereof.
Background
The cloth is a material commonly used in decorative materials. Cloth plays a considerable role in decorative displays, often a major non-negligible effort in the overall sales space.
Chinese application patent publication No. CN103522712A discloses a flame-retardant breathable fabric, which comprises an upper layer and a lower layer, wherein the upper layer is connected with the lower layer, the upper layer is a flame-retardant fabric, the lower layer is a breathable fabric, the flame-retardant fabric is made of Nomex fibers, cotton fibers and pecan fibers, the breathable fibers are made of aramid fibers and soybean fibers, the flame-retardant fabric is woven by using Nomex fibers and cotton fibers as warps and pecan fibers as wefts; the cloth has the effects of ventilation and flame retardance.
In view of the above-mentioned related technologies, the inventor thinks that the cloth is generally stored in a cool place when stored, but mold is easily grown in the cool environment, and after the mold is attached to the cloth, the cloth is in contact with a human body in the subsequent use, which causes great harm to the health of the human body.
Disclosure of Invention
In order to improve the mildew-resistant function of the cloth, the application provides the mildew-resistant cloth and the preparation method thereof.
In a first aspect, the application provides a mould proof cloth, which adopts the following technical scheme:
the mildew-proof cloth comprises a cloth body and a mildew-proof agent, wherein the mildew-proof agent comprises the following components in parts by mass:
1-1.5 parts of tea tree essential oil
8-10 parts of encapsulating agent
Tween-805.5-8 weight portions
60-75 parts of phosphate aqueous solution
16-20 parts of slow release auxiliary agent
3-7 parts of color fixing agent
2-3 parts of an anti-wear agent.
The tea tree essential oil has an antibacterial effect, and after the mildew preventive is attached to the surface of the cloth, the antibacterial effect of the cloth can be improved, so that the phenomenon that the cloth is corroded by fungi is reduced; the encapsulant can coat the tea tree essential oil, so that the stability of the tea tree essential oil is improved, and the tea tree essential oil can be slowly released, thereby achieving the effect of lasting antibiosis; tween-80 is a surfactant, and can improve the encapsulation efficiency of the encapsulant, so that the tea tree essential oil is more stable; the slow release auxiliary agent can further coat the tea tree essential oil, so that the stability of the tea tree essential oil is further improved; the color fixing agent can improve the color fastness of the cloth, so that the color fading phenomenon of the cloth can be reduced; the wear-resistant agent can improve the wear-resistant performance of the surface of the cloth and reduce the phenomenon of quality reduction of the cloth after the cloth is worn.
Preferably, the encapsulating agent comprises soy phospholipids and cholesterol.
The cholesterol is a derivative of cyclopentane polyhydrophenanthrene, and can form a liposome membrane after being matched with soybean phospholipid, and the cholesterol can improve the ordering of lipid bilayer arrangement, so that the membrane fluidity is reduced, the liposome membrane is more stable, and the encapsulation rate of tea tree essential oil is improved.
Preferably, the mass ratio of the soybean phospholipids to the cholesterol is (3.5-4.5): 1.
the encapsulation efficiency of the encapsulant can be improved by controlling the mass ratio of the soybean phospholipids to the cholesterol within the above range.
Preferably, the slow release auxiliary agent comprises chitosan and sodium tripolyphosphate.
The tea tree essential oil is volatile and unstable, the chitosan and the sodium tripolyphosphate are gelatinized to form the nanocapsule, the nanocapsule further coats the tea tree essential oil to form tiny particles, the nanocapsule has good dispersibility, the uniformity of antibacterial components is improved, the stability of the tea tree essential oil is improved, and the nanocapsule can slowly release the tea tree essential oil, so that the tea tree essential oil has a long-acting antibacterial effect, and the antibacterial and mildewproof effects of the cloth are improved; meanwhile, the chitosan surface is provided with amino groups, so that the chitosan has certain antibacterial performance, and under the combined action of the chitosan and the tea tree essential oil, the antibacterial strength is improved, and the antibacterial durability is improved.
Preferably, the mass ratio of the chitosan to the sodium tripolyphosphate is (5-5.5): 1.
the mass ratio of the chitosan to the sodium tripolyphosphate is controlled within the range, so that the stability of the slow-release auxiliary agent can be improved.
The color fixing agent comprises the following components in parts by mass:
2-5 parts of chitosan
3-6 parts of hydroxypropyl trimethyl ammonium chloride.
Chitosan self has a large amount of alkaline amino, and adsorptivity, film forming ability and moisture absorption moisturizing performance are all good, have good fixation effect to the dyestuff, carry out quaternary ammonium salt cationization through hydroxypropyl trimethyl ammonium chloride to chitosan and modify, can promote chitosan's amino content, can improve the electronegativity on cloth surface simultaneously, promote the dyestuff to dye to can promote the colour fastness of cloth, and then promote the fixation effect of cloth.
Preferably, the anti-wear agent comprises the following components in parts by mass:
14-16 parts of epoxy resin
And 2-4 parts of graphene oxide.
The epoxy resin is a high molecular polymer and has good wear resistance, so that the wear resistance effect of the cloth is improved; the graphene oxide is added into the epoxy resin for modification to prepare the epoxy resin composite coating, so that the interface structure between the graphene oxide and the epoxy resin is enhanced, the wear resistance of the wear-resistant agent can be further improved, and the wear resistance of the cloth body is improved.
Preferably, the preparation method of the mildew preventive comprises the following steps:
s1, adding the tea tree essential oil and tween-80 into a phosphate aqueous solution for mixing, preheating, mixing with an encapsulant, and performing ultrasonic treatment to obtain tea tree essential oil liposome suspension;
s2, mixing the tea tree essential oil liposome suspension with a slow release auxiliary agent, and obtaining a nano capsule solution through ionic gelation;
and S3, adding the color fixing agent and the wear-resisting agent into the nano-capsule solution, and fully stirring and mixing to obtain the mildew preventive.
After the tea tree essential oil is encapsulated by the encapsulant, the stability of the tea tree essential oil can be improved, and the volatilization of the tea tree essential oil is reduced, so that the tea tree essential oil achieves a long-acting bacteriostatic action; the mixed solution and the sustained-release auxiliary agent are subjected to ion gelation to obtain a nano capsule solution, and the tea tree essential oil liposome suspension can be coated, so that the sustained-release effect of the tea tree essential oil is enhanced, and the antibacterial durability of the mildew preventive is improved.
Preferably, the preparation method of the anti-wear agent comprises the following steps:
weighing graphene oxide, grinding, adding a solvent for dispersion, then adding epoxy resin, fully stirring to completely dissolve the epoxy resin, then carrying out ultrasonic oscillation, and heating to raise the temperature so as to completely evaporate the solvent, thereby obtaining the wear-resistant agent.
The surface of the graphene oxide contains a large number of oxygen-containing functional groups, and the graphene oxide has good compatibility after being combined with epoxy resin, so that the strength of the epoxy resin can be improved.
In a second aspect, the present application provides a method for manufacturing a mildew-proof fabric, which adopts the following technical scheme:
a method for manufacturing mildew-proof cloth comprises the following steps:
blending: selecting and blending woven warp yarns and woven weft yarns to obtain blended yarns;
compiling: weaving the blended yarns to obtain grey cloth;
finishing: removing fluff on the surface of the grey cloth, inspecting the flaw point, damage and width of the grey cloth, and carrying out mercerization treatment to obtain pretreated grey cloth;
dyeing: placing the pre-treated grey cloth and the pretreated grey cloth in a dyeing cylinder for dyeing to obtain a primary grey cloth;
and (3) mildew-proof treatment: soaking the primary grey cloth in a mildew preventive for 1-2h, and drying in a drying box again after soaking to obtain finished cloth;
winding: and according to the process requirements, rechecking the finished cloth to obtain qualified cloth, ironing the qualified cloth to keep the qualified cloth flat, then rolling the qualified cloth, and storing.
After dyeing, the primary cloth is soaked into the mildew preventive, and after the cloth is fully contacted with the mildew preventive, the mildew preventive effect of the cloth can be improved, the erosion of fungi and the like to the cloth in the subsequent storage process is reduced, and the mildew preventive effect of the cloth is further improved.
In summary, the present application includes at least one of the following beneficial technical effects:
1. the tea tree essential oil has good antibacterial performance, is natural plant essential oil, has little harm to human bodies, and is safe and environment-friendly; the tea tree essential oil is coated by the encapsulant, so that the stability of the tea tree essential oil is improved and the tea tree essential oil is slowly released, the tea tree essential oil and the encapsulant are coated by the slow-release auxiliary agent, the stability of the tea tree essential oil is greatly improved under the combined action of the encapsulant and the slow-release auxiliary agent, the slow-release fabric has a strong slow-release effect, and the fabric can achieve a long-acting and lasting antibacterial effect; the color fixing agent can promote the loading of dye, so that the color fastness of the cloth is effectively improved; the wear-resistant agent can improve the wear-resistant effect of the whole cloth, so that the wear-resistant effect of the cloth can be improved;
2. the chitosan and sodium tripolyphosphate ions are gelatinized to form nano capsules, and the tea tree essential oil is coated, so that the tea tree essential oil can be slowly released in the subsequent process, and a long-term antibacterial effect is achieved; meanwhile, the chitosan has a certain amino group, has antibacterial performance, and can enhance the antibacterial performance of the mildew inhibitor under the combined action of the chitosan and the tea tree essential oil.
Detailed Description
The embodiment of the application discloses mildew-proof cloth and a preparation method thereof, wherein epoxy resin is E44.
Preparation example 1
An encapsulant is prepared by weighing soybean phospholipid and cholesterol at a mass ratio of 3.5:1, adding chloroform as solvent, mixing, ultrasonically dissolving, performing rotary evaporation at 15rpm with a rotary evaporator, and removing solvent to obtain the encapsulant.
A color fixing agent is prepared by weighing 2g of chitosan and 3g of hydroxypropyl trimethyl ammonium chloride, dispersing the hydroxypropyl trimethyl ammonium chloride in water to obtain a hydroxypropyl trimethyl ammonium chloride aqueous solution, adding chitosan into the hydroxypropyl trimethyl ammonium chloride aqueous solution, reacting at 65 ℃ for 30min, and filtering and airing a product to obtain the color fixing agent.
14g of epoxy resin and 2g of graphene oxide are weighed, the graphene oxide is ground and dispersed into an ethanol solution, then the epoxy resin is added into the graphene oxide, the graphene oxide is stirred fully and then subjected to ultrasonic oscillation, and then the mixture is heated until the ethanol solution is completely evaporated, so that the wear-resistant agent is obtained.
A mildew preventive is prepared by weighing 1g of tea tree essential oil, 8g of the encapsulant and 5.5g of tween-80, dissolving phosphate in water to obtain a phosphate aqueous solution with the concentration of 12mmol/L, weighing 60g of the phosphate aqueous solution, adding the weighed tea tree essential oil, the encapsulant and the tween-80 into the phosphate aqueous solution, mixing, preheating, and performing constant-temperature ultrasound to obtain tea tree essential oil liposome suspension;
dispersing 2.65g of sodium tripolyphosphate into 10ml of water to obtain a sodium tripolyphosphate aqueous solution, then adding the tea tree essential oil liposome suspension into the sodium tripolyphosphate aqueous solution, and homogenizing to obtain a mixed solution;
mixing 13.35g of chitosan with 30ml of acetic acid, and then carrying out ultrasonic dissolution to obtain ultrasonic dissolved solution; mixing the ultrasonic dissolving liquid with the mixed liquid, and then performing ion gelation to obtain a nano capsule solution;
and weighing 3g of the color fixing agent and 2g of the wear-resisting agent, adding the color fixing agent and the wear-resisting agent into the nano-capsule liquid, and fully stirring and mixing to obtain the mildew preventive.
Preparation example 2
An encapsulant is prepared by weighing soybean phospholipid and cholesterol at a mass ratio of 4.5:1, adding chloroform as solvent, mixing, ultrasonically dissolving, performing rotary evaporation at 15rpm with a rotary evaporator, and removing solvent to obtain the encapsulant.
A color fixing agent is prepared by weighing 5g of chitosan and 6g of hydroxypropyl trimethyl ammonium chloride, dispersing the hydroxypropyl trimethyl ammonium chloride in water to obtain a hydroxypropyl trimethyl ammonium chloride aqueous solution, adding chitosan into the hydroxypropyl trimethyl ammonium chloride aqueous solution, reacting at 65 ℃ for 30min, and drying the product in the air to obtain the color fixing agent.
A wear-resistant agent is prepared by weighing 16g of epoxy resin and 4g of graphene oxide, grinding the graphene oxide, dispersing the graphene oxide into an ethanol solution, adding the epoxy resin into the graphene oxide, fully stirring, performing ultrasonic oscillation, and heating until the ethanol solution is completely evaporated to obtain the wear-resistant agent.
A mildew preventive is prepared by weighing 1.5g of tea tree essential oil, 10g of the encapsulant and 8g of tween-80, diluting phosphate with water to obtain a phosphate aqueous solution with the concentration of 12mmol/L, weighing 75g of the phosphate aqueous solution, adding the weighed tea tree essential oil, the encapsulant and the tween-80 into the phosphate aqueous solution for mixing and preheating, and then carrying out constant temperature ultrasound to obtain tea tree essential oil liposome suspension;
dispersing 3g of sodium tripolyphosphate into 20ml of water to obtain a sodium tripolyphosphate aqueous solution, then adding the tea tree essential oil liposome suspension into the sodium tripolyphosphate aqueous solution, and homogenizing to obtain a mixed solution;
mixing 17g of chitosan with 50ml of acetic acid, then carrying out ultrasonic dissolution to obtain ultrasonic dissolved solution, mixing the ultrasonic dissolved solution with the mixed solution, and then carrying out ion gelation to obtain nano capsule solution;
and weighing 7g of the color fixing agent and 3g of the wear-resisting agent, adding the color fixing agent and the wear-resisting agent into the nanocapsule solution, and fully stirring and mixing to obtain the mildew preventive.
Preparation example 3
An encapsulant is prepared by weighing soybean phospholipid and cholesterol at a mass ratio of 4:1, adding chloroform as solvent, mixing, dissolving with ultrasonic wave, performing rotary evaporation at 15rpm with a rotary evaporator, and removing solvent to obtain the encapsulant.
A color fixing agent is prepared by weighing 4g of chitosan and 4g of hydroxypropyl trimethyl ammonium chloride, dispersing the hydroxypropyl trimethyl ammonium chloride in water to obtain a hydroxypropyl trimethyl ammonium chloride aqueous solution, adding chitosan into the hydroxypropyl trimethyl ammonium chloride aqueous solution, reacting at 65 ℃ for 30min, and drying the product in the air to obtain the color fixing agent.
15g of epoxy resin and 3g of graphene oxide are weighed, the graphene oxide is ground and dispersed into an ethanol solution, then the epoxy resin is added into the graphene oxide, the graphene oxide is stirred fully and then subjected to ultrasonic oscillation, and then the mixture is heated until the ethanol solution is completely evaporated, so that the wear-resistant agent is obtained.
A mildew preventive is prepared by weighing 1.1g of tea tree essential oil, 9g of the encapsulant and 6g of tween-80, diluting phosphate with water to obtain a phosphate aqueous solution with a concentration of 12mmol/L, weighing 68g of the phosphate aqueous solution, adding the weighed tea tree essential oil, the encapsulant and the tween-80 into the phosphate aqueous solution for mixing and preheating, and then carrying out constant temperature ultrasound to obtain tea tree essential oil liposome suspension;
dispersing 2.85g of sodium tripolyphosphate into 15ml of water to obtain a sodium tripolyphosphate aqueous solution, then adding the tea tree essential oil liposome suspension into the sodium tripolyphosphate aqueous solution, and homogenizing to obtain a mixed solution;
mixing 15.15g of chitosan with 40ml of acetic acid, then carrying out ultrasonic dissolution to obtain ultrasonic dissolved solution, mixing the ultrasonic dissolved solution with the mixed solution, and then carrying out ion gelation to obtain nano capsule solution;
and weighing 5g of the color fixing agent and 3g of the wear-resisting agent, adding the color fixing agent and the wear-resisting agent into the nano capsule solution, and fully stirring and mixing to obtain the mildew preventive.
Preparation example 4
Preparation 4 is based on preparation 3, and preparation 4 differs from preparation 3 only in that: the mass ratio of the soybean lecithin to the cholesterol in the encapsulating agent is 5: 1.
Preparation example 5
Preparation 5 is based on preparation 3, and preparation 5 differs from preparation 3 only in that: a mildew preventive is prepared by weighing 1.1g of tea tree essential oil and 6g of tween-80, diluting phosphate with water to obtain a phosphate aqueous solution with a concentration of 12mmol/L, weighing 68g of the phosphate aqueous solution, adding the weighed tea tree essential oil and tween-80 into the phosphate aqueous solution, mixing, preheating, and performing constant-temperature ultrasound to obtain tea tree essential oil liposome suspension;
dispersing 4.31g of sodium tripolyphosphate into 15ml of water to obtain a sodium tripolyphosphate aqueous solution, then adding the tea tree essential oil liposome suspension into the sodium tripolyphosphate aqueous solution, and homogenizing to obtain a mixed solution;
mixing 22.7g of chitosan with 40ml of acetic acid, then carrying out ultrasonic dissolution to obtain ultrasonic dissolved solution, mixing the ultrasonic dissolved solution with the mixed solution, and then carrying out ion gelation to obtain nano capsule solution;
weighing 5g of color fixing agent and 3g of wear-resisting agent, adding the color fixing agent and the wear-resisting agent into the nanocapsule solution, and fully stirring and mixing to obtain the mildew preventive;
wherein, the encapsulating agent, the color fixing agent and the wear-resisting agent are all based on the preparation example 3.
Preparation example 6
Preparation 6 is based on preparation 3, and preparation 6 differs from preparation 3 only in that: a mildew preventive is prepared by weighing 1.1g of tea tree essential oil, 27g of encapsulant and 6g of tween-80, diluting phosphate with water to obtain a phosphate aqueous solution with a concentration of 12mmol/L, weighing 68g of phosphate aqueous solution, adding the weighed tea tree essential oil, encapsulant and tween-80 into the phosphate aqueous solution, mixing, preheating, and performing constant temperature ultrasound to obtain tea tree essential oil liposome suspension;
weighing 5g of color fixing agent and 3g of wear-resisting agent, adding the color fixing agent and the wear-resisting agent into the tea tree essential oil liposome suspension, and fully stirring and mixing to obtain the mildew preventive;
wherein, the encapsulating agent, the color fixing agent and the wear-resisting agent are all based on the preparation example 3.
Preparation example 7
Preparation 7 is based on preparation 3, and preparation 7 differs from preparation 3 only in that: a mildew preventive is prepared by weighing 1.1g of tea tree essential oil, 9g of encapsulant and 10g of tween-80, diluting phosphate with water to obtain a phosphate aqueous solution with a concentration of 12mmol/L, weighing 64g of phosphate aqueous solution, adding the weighed tea tree essential oil, encapsulant and tween-80 into the phosphate aqueous solution, mixing, preheating, and performing constant temperature ultrasound to obtain tea tree essential oil liposome suspension;
dispersing 2.85g of sodium tripolyphosphate into 15ml of water to obtain a sodium tripolyphosphate aqueous solution, then adding the tea tree essential oil liposome suspension into the sodium tripolyphosphate aqueous solution, and homogenizing to obtain a mixed solution;
mixing 15.15g of chitosan with 40ml of acetic acid, then carrying out ultrasonic dissolution to obtain ultrasonic dissolved solution, mixing the ultrasonic dissolved solution with the mixed solution, and then carrying out ion gelation to obtain nano capsule solution;
weighing 5g of color fixing agent and 3g of wear-resisting agent, adding the color fixing agent and the wear-resisting agent into the nanocapsule solution, and fully stirring and mixing to obtain the mildew preventive;
wherein, the encapsulating agent, the color fixing agent and the wear-resisting agent are all based on the preparation example 3.
Preparation example 8
Preparation 8 is based on preparation 3, and preparation 8 differs from preparation 3 only in that: in the mildew preventive, the mass ratio of chitosan to sodium tripolyphosphate is 6: 1.
Preparation example 9
Preparation 9 is based on preparation 3, and preparation 9 differs from preparation 3 only in that: a color fixing agent is prepared by weighing 4g of diethylenetriamine and 4g of hydroxypropyl trimethyl ammonium chloride, dispersing the hydroxypropyl trimethyl ammonium chloride in water to obtain a hydroxypropyl trimethyl ammonium chloride aqueous solution, adding the diethylenetriamine into the hydroxypropyl trimethyl ammonium chloride aqueous solution, reacting at 65 ℃ for 30min, and drying the product to obtain the color fixing agent.
Preparation example 10
Preparation 10 is based on preparation 3, and preparation 10 differs from preparation 3 only in that: no cholesterol was added to the encapsulant.
Preparation example 11
Preparation 11 is based on preparation 3, and preparation 11 differs from preparation 3 only in that: the fixing agent is only chitosan.
Preparation example 12
Preparation 12 is based on preparation 3, and preparation 12 differs from preparation 3 only in that: the abrasion resistant agent is only epoxy resin.
Example 1
A mildew-proof cloth is characterized in that weaving warps and weaving wefts are selected for blending, wherein the weaving warps can be cotton threads, the weaving wefts can be terylene, blended yarns are obtained, and the blended yarns are woven to obtain grey cloth; removing fluff on the surface of the grey cloth, inspecting blemishes, damages and widths of the surface of the grey cloth, and performing mercerization to obtain pretreated grey cloth; placing the pretreated gray fabric in a dyeing vat for dyeing, and obtaining a primary gray fabric after dyeing is finished; soaking the primary grey cloth into the mildew preventive for 1-2h, and then sending the primary grey cloth into a drying box for drying to obtain finished cloth; according to the process requirements, the finished plain cloth is inspected again to obtain qualified cloth, the qualified cloth is ironed and then wound, and the mildew-proof cloth can be obtained;
wherein the antifungal agent is selected from preparation example 1.
Example 2
Example 2 is based on example 1, and example 2 differs from example 1 only in that: the mildewcide is selected from preparation example 2.
Example 3
Example 3 is based on example 1, and example 3 differs from example 1 only in that: the mildewcide is selected from preparation example 3.
Example 4
Example 4 is based on example 1, and example 4 differs from example 1 only in that: the mildewcide is selected from preparation example 4.
Example 5
Example 5 is based on example 1, and example 5 differs from example 1 only in that: the antifungal agent was selected from preparation example 5.
Example 6
Example 6 is based on example 1, and example 6 differs from example 1 only in that: the antifungal agent was selected from preparation example 6.
Example 7
Example 7 is based on example 1, and example 7 differs from example 1 only in that: the antifungal agent was selected from preparation example 7.
Example 8
Example 8 is based on example 1, example 8 differing from example 7 only in that: preparation example 8 was selected as the mildewcide.
Comparative example 1
Comparative example 1 is based on example 1, which differs from example 1 only in that: the antifungal agent was selected from preparation example 9.
Comparative example 2
Comparative example 2 is based on example 1, comparative example 2 differing from example 1 only in that: the antifungal agent was selected from preparation example 10.
Comparative example 3
Comparative example 3 is based on example 1, comparative example 3 differing from example 1 only in that: the antifungal agent was selected from preparation example 11.
Comparative example 4
Comparative example 4 is based on example 1, comparative example 4 differing from example 1 only in that: the antifungal agent was selected from preparation example 12.
Performance test experiment
The mildew-proof cloth of examples 1 to 8 and comparative examples 1 to 4 was sampled, and the mildew-proof property test and the color fastness test were performed on the samples.
(1) Test for mold resistance
Selecting GB/T24346-2009 mildew-proof performance evaluation as a standard, making a square test piece with the side length of 3.8cm, making 6 test pieces for each sample, sterilizing the test pieces for 15min by high-pressure steam at the temperature of 121 ℃ and under the pressure of 103kPa, detecting the test pieces, averaging the detected test pieces, and filling the test results into a table 1.
(2) Color fastness test
Selecting GB/T3920 + 2008 textile color fastness test rubbing color fastness and GB/T251 + 2008 textile color fastness test assessment staining gray sample card as standards, testing each sample for 6 times, taking an average value after testing, and filling test results in table 1.
TABLE 1
| Test items | Mildew resistance test/rating | Color fastness Performance test/grade |
| Example 1 | 0 | 5 |
| Example 2 | 0 | 5 |
| Example 3 | 0 | 5 |
| Example 4 | 2 | 5 |
| Example 5 | 3 | 5 |
| Example 6 | 4 | 4 |
| Example 7 | 2 | 5 |
| Example 8 | 1 | 5 |
| Comparative example 1 | 3 | 3 |
| Comparative example 2 | 2 | 5 |
| Comparative example 3 | 0 | 3 |
| Comparative example 4 | 0 | 4 |
And (3) analysis of detection data:
as can be seen from table 1, the mildew-proof grades of examples 1 to 3 are 0 grade, so that the mildew-proof cloth prepared by the application has a good mildew-proof effect; the color fastness grades of the examples 1-3 are 5 grades, so that the mildew-proof cloth prepared by the application has better color fixing effect and wear-resisting effect.
As can be seen from table 1, example 3 differs from example 4 in that: the mass ratio of soybean phospholipid to cholesterol in example 3 is 4:1, the mass ratio of soybean phospholipid to cholesterol in example 4 is 5:1, the mildew-proof grade in example 3 is 0, the mildew-proof grade in example 4 is 2, and the mildew-proof effect in example 4 is reduced compared with example 3, because the content of cholesterol is reduced after the mass ratio of soybean phospholipid is increased, the stability of the fluidity of the liposome membrane is poor, so that the stability of tea tree essential oil is reduced, the encapsulation efficiency of the encapsulating agent is reduced, the liposome membrane is easy to break, the tea tree essential oil is easy to volatilize, the effect of inhibiting and inactivating bacteria for a long time is difficult to achieve, and the mildew-proof effect of the cloth is reduced.
As can be seen from table 1, example 3 differs from example 5 only in that: the mildew preventive in the embodiment 3 contains 9g of the encapsulating agent and 18g of the slow release auxiliary agent, the mildew preventive in the embodiment 5 is not added with the encapsulating agent, the dosage of the slow release auxiliary agent is 27g, the mildew prevention grade in the embodiment 3 is 0 grade, the mildew prevention grade in the embodiment 5 is 3 grade, and the mildew prevention effect of the embodiment 5 is reduced compared with that of the embodiment 3 because the encapsulating agent is a liposome membrane formed by matching soybean phospholipid and cholesterol, so that the tea tree essential oil is coated, when the encapsulating agent is not added, only the slow release auxiliary agent coats the tea tree essential oil, the single coating effect weakens the stability of the tea tree essential oil, the solubility of the tea tree essential oil is reduced, the antibacterial activity of the tea tree essential oil is difficult to improve and the like, the long-term antibacterial effect is difficult to achieve, and the mildew prevention effect of the cloth is reduced.
As can be seen from table 1, example 3 differs from example 6 only in that: the mildew preventive in the embodiment 3 is added with 9g of the encapsulant and contains 18g of the slow release auxiliary agent, the mass of the encapsulant in the mildew preventive in the embodiment 6 is 27g, the slow release auxiliary agent is not added, the mildew prevention grade of the embodiment 3 is 0 grade, the mildew prevention grade of the embodiment 6 is 4 grade, and the mildew prevention effect of the embodiment 6 is reduced compared with that of the embodiment 3, because the encapsulant is selected as a single coating material, the stability of the tea tree essential oil is weak, the activity of the tea tree essential oil is protected, and after a period of time, the antibacterial activity of the tea tree essential oil is difficult to maintain, so that the antibacterial effect of the tea tree essential oil is reduced; meanwhile, the chitosan has an antibacterial effect, after the slow-release auxiliary agent is reduced, the antibacterial component in the mildew preventive is reduced, and the mildew-proof effect of the cloth is obviously reduced.
The color fastness grade of the example 3 is 5 grades, the color fastness grade of the example 6 is 4 grades, and the color fastness grade of the example 6 is reduced compared with the example 3, because the content of chitosan is reduced, the content of amino in the mildew preventive is reduced and the cationic performance is weakened after the slow release auxiliary agent is not added, the dye uptake is reduced, and the color fastness is reduced after the cloth is rubbed.
As can be seen from table 1, example 3 differs from example 7 only in that: the addition amount of tween-80 in example 3 was 6g, the addition amount of the phosphate aqueous solution was 68g, the addition amount of tween-80 in example 7 was 10g, the addition amount of the phosphate aqueous solution was 64g, the mildew resistance rating of example 3 was 0, the mildew resistance rating of example 7 was 2, and the mildew resistance effect of example 7 was reduced compared with example 3 because tween-80, which is a surfactant, was able to form a hydrophilic layer on the surface of the liposome of tea tree essential oil after addition, thereby slowing down the release rate of tea tree essential oil, but tween-80 also had the ability to disturb the order of the molecular arrangement of phospholipids, which changed the fluidity of the liposome membrane, and when the addition amount of tween-80 was excessive, the liposome membrane was destroyed, thereby causing the turbidity of the encapsulant to drop sharply, at which the encapsulation rate of the encapsulant was reduced, the tea tree essential oil is difficult to encapsulate by the encapsulant, the stability of the tea tree essential oil is reduced, the tea tree essential oil is volatilized quickly, the long-term inhibition effect on the fungus is difficult to perform, the fungus is difficult to kill in the follow-up process, and therefore the mildew-resistant effect of the cloth is reduced.
As can be seen from table 1, example 3 differs from example 8 only in that: the mass ratio of chitosan to sodium tripolyphosphate in example 3 is 5.3:1, the mass ratio of chitosan to sodium tripolyphosphate in example 8 is 6:1, the mildew-proof grade of example 3 is 0, the mildew-proof grade of example 8 is 1, and the mildew-proof effect of example 8 is reduced compared with that of example 1, because the ratio of chitosan to sodium tripolyphosphate is increased, the content of nanocapsules which can be formed is reduced after the content of sodium tripolyphosphate is reduced, the amount of tea tree essential oil liposome which is coated is reduced, the stability of tea tree essential oil liposome which is not coated is difficult to be improved, the volatilization speed is high, the antibacterial component in the mildew preventive is reduced after a period of time, the lasting antibacterial performance of cloth is reduced, and the mildew-proof effect is reduced.
As can be seen from table 1, example 3 differs from comparative example 1 only in that: the fixing agent in example 3 is chitosan and hydroxypropyl trimethyl ammonium chloride, the fixing agent in comparative example 1 is diethylenetriamine and hydroxypropyl trimethyl ammonium chloride, the mildew-proof grade in example 3 is 0 grade, the mildew-proof grade in comparative example 1 is 3 grade, and the mildew-proof grade in comparative example 1 is reduced compared with that in example 3, because diethylenetriamine does not have antibacterial performance, and after the diethylenetriamine and the hydroxypropyl trimethyl ammonium chloride are used as the fixing agent, antibacterial components in the mildew-proof agent are reduced, so that the mildew-proof performance of the cloth is reduced.
The color fastness grade of the example 3 is 5 grades, the color fastness grade of the comparative example 1 is 3 grades, and the color fastness grade of the comparative example 1 is reduced compared with the example 3, because after the diethylenetriamine is combined with the epoxy group in the epoxy resin, the positive charge property and the electrostatic attraction force of the dye are reduced, the stability of the dye is reduced, so that the color fastness of the cloth is reduced, and the color fastness grade of the cloth is reduced.
As can be seen from table 1, example 3 differs from comparative example 2 only in that: the encapsulation agent in example 3 is soybean phospholipid and cholesterol, the encapsulation agent in comparative example 2 is only soybean phospholipid, the mildew-proof grade of example 3 is 0 grade, the mildew-proof grade of comparative example 2 is 2 grade, and the mildew-proof grade of comparative example 3 is reduced compared with that of example 3, because a liposome membrane is difficult to form with the soybean phospholipid after the cholesterol is removed, the lipid bilayers of the soybean phospholipid are disordered, the fluidity of the soybean phospholipid membrane is high, the stability is poor, the encapsulation rate of tea tree essential oil is difficult to improve, the tea tree essential oil is free and easy to volatilize, and a lasting antibacterial effect is difficult to achieve, so that the mildew-proof performance of the cloth is reduced.
As can be seen from table 1, example 3 differs from comparative example 3 only in that: the fixing agent in the embodiment 3 is chitosan and hydroxypropyl trimethyl ammonium chloride, the fixing agent in the comparative example 3 is only chitosan, the color fastness grade of the embodiment 3 is 5 grade, the color fastness grade of the comparative example 3 is 3 grade, and compared with the embodiment 3, the color fastness is reduced to some extent, because the chitosan molecules are not subjected to cationization modification by quaternary ammonium salt, the cationic performance of the fixing agent is difficult to improve, the binding capacity between the fixing agent and the cloth is poor, the negative charge reduction effect of the cloth is difficult to improve, and the stabilizing effect of the dye is weak; meanwhile, the ionic bond binding capacity of the chitosan which is not subjected to quaternary ammonium salt ionization modification and the anionic groups in the dye is poor, the water solubility of the dye is difficult to reduce, and the color fastness is reduced to some extent.
As can be seen from table 1, example 3 differs from comparative example 4 only in that: the wear-resisting agent in example 3 is epoxy resin and graphene oxide, the wear-resisting agent in comparative example 4 is epoxy resin, the color fastness grade of example 3 is 5 grade, the color fastness grade of comparative example 4 is 4 grade, and the color fastness grade of comparative example 4 is reduced compared with that of example 3, because the wear rate of the epoxy resin is high, the epoxy resin can be rapidly failed after being rubbed with an external object, meanwhile, the improvement capability of the bonding surface between the epoxy resin and the fiber is weak, a better interface structure is difficult to form, and at the moment, the dye component in the cloth is exposed to the outside, the dye is separated from the cloth fiber after being worn, and the color fastness of the cloth is reduced.
The above embodiments are preferred embodiments of the present application, and the protection scope of the present application is not limited by the above embodiments, so: all equivalent changes made according to the structure, shape and principle of the present application shall be covered by the protection scope of the present application.
Claims (10)
1. The utility model provides a mould proof cloth which characterized in that: the anti-mildew agent comprises a cloth body and a mildew-proof agent, wherein the mildew-proof agent comprises the following components in parts by mass:
1-1.5 parts of tea tree essential oil
8-10 parts of encapsulating agent
Tween-805.5-8 weight portions
60-75 parts of phosphate aqueous solution
16-20 parts of slow release auxiliary agent
3-7 parts of color fixing agent
2-3 parts of an anti-wear agent.
2. The mold-resistant cloth according to claim 1, wherein: the encapsulating agent comprises soybean phospholipid and cholesterol.
3. The mold-resistant cloth according to claim 2, wherein: the mass ratio of the soybean phospholipids to the cholesterol is (3.5-4.5): 1.
4. the mold-resistant cloth according to claim 1, wherein: the slow release auxiliary agent comprises chitosan and sodium tripolyphosphate.
5. The mold-proof cloth according to claim 4, wherein: the mass ratio of the chitosan to the sodium tripolyphosphate is (5-5.5): 1.
6. the mold-resistant cloth according to claim 1, wherein: the color fixing agent comprises the following components in parts by mass:
2-5 parts of chitosan
3-6 parts of hydroxypropyl trimethyl ammonium chloride.
7. The mold-resistant cloth according to claim 1, wherein: the wear-resisting agent comprises the following components in parts by mass:
14-16 parts of epoxy resin
And 2-4 parts of graphene oxide.
8. The mold-resistant cloth according to claim 1, wherein: the preparation method of the mildew preventive comprises the following steps:
s1, adding the tea tree essential oil and tween-80 into a phosphate aqueous solution for mixing, preheating, mixing with an encapsulant, and performing ultrasonic treatment to obtain tea tree essential oil liposome suspension;
s2, mixing the tea tree essential oil liposome suspension with a slow release auxiliary agent, and obtaining a nano capsule solution through ionic gelation;
and S3, adding the color fixing agent and the wear-resisting agent into the nano-capsule solution, and fully stirring and mixing to obtain the mildew preventive.
9. The mold-resistant cloth according to claim 7, wherein: the preparation method of the wear-resisting agent comprises the following steps:
weighing graphene oxide, grinding, adding a solvent for dispersion, then adding epoxy resin, fully stirring to completely dissolve the epoxy resin, then carrying out ultrasonic oscillation, and heating until the solvent is completely evaporated to obtain the wear-resistant agent.
10. A method for manufacturing the mold-proof cloth as claimed in claim 1, characterized in that: the method comprises the following steps:
blending: selecting and blending woven warp yarns and woven weft yarns to obtain blended yarns;
compiling: weaving the blended yarns to obtain grey cloth;
finishing: removing fluff on the surface of the grey cloth, inspecting the flaw point, damage and width of the grey cloth, and carrying out mercerization treatment to obtain pretreated grey cloth;
dyeing: placing the pretreated gray fabric in a dyeing vat for dyeing to obtain a primary gray fabric;
and (3) mildew-proof treatment: soaking the primary grey cloth in a mildew preventive for 1-2h, and drying in a drying box after soaking to obtain finished cloth;
winding: and according to the process requirements, rechecking the finished cloth to obtain qualified cloth, ironing the qualified cloth to keep the qualified cloth flat, then rolling the qualified cloth, and storing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210084929.1A CN114351449B (en) | 2022-01-25 | 2022-01-25 | Mildew-proof cloth and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210084929.1A CN114351449B (en) | 2022-01-25 | 2022-01-25 | Mildew-proof cloth and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114351449A true CN114351449A (en) | 2022-04-15 |
| CN114351449B CN114351449B (en) | 2023-09-15 |
Family
ID=81094250
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210084929.1A Active CN114351449B (en) | 2022-01-25 | 2022-01-25 | Mildew-proof cloth and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114351449B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117845306A (en) * | 2024-03-07 | 2024-04-09 | 深圳万佳原精化科技股份有限公司 | Hole sealing technology for improving alkali resistance of dyed aluminum alloy anodic oxide film |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103966847A (en) * | 2014-04-16 | 2014-08-06 | 南通大学 | Method for finishing fabric through plant essential oil thermosensitive liposomes |
| CN104784743A (en) * | 2015-05-11 | 2015-07-22 | 南通大学 | Preparation method for aromatic and bacteriostatic chitosan-based wound dressing |
| US20150202304A1 (en) * | 2012-07-13 | 2015-07-23 | Tufts University | Encapsulation of immiscible phases in silk fibroin biomaterials |
| CN105287379A (en) * | 2015-08-10 | 2016-02-03 | 江苏大学 | High-stability antibacterial agent containing tea tree oil nanoliposomes and method for preparing high-stability antibacterial agent containing tea tree oil essential oil nanoliposomes |
| CN109046192A (en) * | 2018-08-28 | 2018-12-21 | 浙江大学 | A kind of plants essential oil chitosan nano mcirocapsule and its preparation method and application |
| CN109566954A (en) * | 2018-12-29 | 2019-04-05 | 华南理工大学 | A kind of liposome/chitosan anti-bacteria, anti-oxidant coating liquid and preparation method and application embedding laurin oil and nano silver |
| WO2019094700A1 (en) * | 2017-11-10 | 2019-05-16 | Cocoon Biotech Inc. | Silk-based products and methods of use |
| CN110144150A (en) * | 2019-05-15 | 2019-08-20 | 杨茂本 | Antibacterial barrier coat compositions and preparation method thereof for medical inspection platform |
| CN112535181A (en) * | 2020-12-04 | 2021-03-23 | 江苏省农业科学院 | Chrysanthemum essential oil microcapsule and preparation method and application thereof |
-
2022
- 2022-01-25 CN CN202210084929.1A patent/CN114351449B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150202304A1 (en) * | 2012-07-13 | 2015-07-23 | Tufts University | Encapsulation of immiscible phases in silk fibroin biomaterials |
| CN103966847A (en) * | 2014-04-16 | 2014-08-06 | 南通大学 | Method for finishing fabric through plant essential oil thermosensitive liposomes |
| CN104784743A (en) * | 2015-05-11 | 2015-07-22 | 南通大学 | Preparation method for aromatic and bacteriostatic chitosan-based wound dressing |
| CN105287379A (en) * | 2015-08-10 | 2016-02-03 | 江苏大学 | High-stability antibacterial agent containing tea tree oil nanoliposomes and method for preparing high-stability antibacterial agent containing tea tree oil essential oil nanoliposomes |
| WO2019094700A1 (en) * | 2017-11-10 | 2019-05-16 | Cocoon Biotech Inc. | Silk-based products and methods of use |
| CN109046192A (en) * | 2018-08-28 | 2018-12-21 | 浙江大学 | A kind of plants essential oil chitosan nano mcirocapsule and its preparation method and application |
| CN109566954A (en) * | 2018-12-29 | 2019-04-05 | 华南理工大学 | A kind of liposome/chitosan anti-bacteria, anti-oxidant coating liquid and preparation method and application embedding laurin oil and nano silver |
| CN110144150A (en) * | 2019-05-15 | 2019-08-20 | 杨茂本 | Antibacterial barrier coat compositions and preparation method thereof for medical inspection platform |
| CN112535181A (en) * | 2020-12-04 | 2021-03-23 | 江苏省农业科学院 | Chrysanthemum essential oil microcapsule and preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李远颂;朱莉;邱月丰;: "壳聚糖-植物精油复合保鲜液对圣女果保鲜效果的影响", 食品工业, no. 08, pages 119 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117845306A (en) * | 2024-03-07 | 2024-04-09 | 深圳万佳原精化科技股份有限公司 | Hole sealing technology for improving alkali resistance of dyed aluminum alloy anodic oxide film |
| CN117845306B (en) * | 2024-03-07 | 2024-05-17 | 深圳万佳原精化科技股份有限公司 | Hole sealing technology for improving alkali resistance of dyed aluminum alloy anodic oxide film |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114351449B (en) | 2023-09-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP7162347B2 (en) | Bio-based PEC compositions as binders for textile substrates, textiles, woven and non-woven materials | |
| EP1359247B1 (en) | Fibres and textile fabrics finished with microcapsules | |
| EP3504264A1 (en) | Bio-based polyelectrolyte complex compositions comprising non-water soluble particles | |
| CN114351449A (en) | Mildew-proof cloth and preparation method thereof | |
| US8551371B2 (en) | Method and composition | |
| EP3543396B1 (en) | Organic antimicrobial textile | |
| Mahltig et al. | Silver containing sol-gel coatings on polyamide fabrics as antimicrobial finish-description of a technical application process for wash permanent antimicrobial effect | |
| CN112647285B (en) | Preparation process of anti-static high-strength polyester fabric | |
| Chattopadhyay et al. | Improvement in properties of cotton fabric through synthesized nano-chitosan application | |
| US6997960B1 (en) | Textile treatments and fibers and textile goods treated therewith | |
| CN114481632B (en) | Long-acting biological antibacterial washable human cotton crepe and preparation method thereof | |
| JP2008266829A (en) | Functional fiber structure and method for producing the same | |
| CN112626843B (en) | Preparation process of super-soft all-cotton woven fabric and fabric thereof | |
| Shahin et al. | Enhancement of dyeability and antibacterial characteristics of silk fabrics using chitosan nano-particles | |
| Mohamed et al. | Enhancement of Dyeing and Antimicrobial Properties of Chitosan and Chitosan Nanoparticles-Treated Cotton and Viscose Fabrics with Acid Dyes | |
| SE1651138A1 (en) | Bio-based polyelectrolyte complex compositions comprising non-water soluble particles | |
| EP3246462B1 (en) | Colour transfer-inhibiting material | |
| CN113106756A (en) | Fibroin coating liquid and application thereof in fiber or fabric surface modification | |
| CN112725970A (en) | Processing technology of garment fabric | |
| US8586143B2 (en) | Capsules with a modified surface for grafting onto fibres | |
| TW200839056A (en) | Microcapsule composition, manufacturing method and application thereof | |
| Pervez et al. | A novel study on UV protection and antibacterial properties of washed denim garment | |
| US20200299514A1 (en) | Dryer sheet for incorporating ultraviolet radiation protection and antimicrobial protection into clothing | |
| RU2773599C2 (en) | Method for making clothes from linen fabrics | |
| RU2776057C1 (en) | Method for producing antimicrobial silver-containing material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |