CN114350222A - Green and environment-friendly wood paint and preparation method thereof - Google Patents

Green and environment-friendly wood paint and preparation method thereof Download PDF

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Publication number
CN114350222A
CN114350222A CN202111624328.7A CN202111624328A CN114350222A CN 114350222 A CN114350222 A CN 114350222A CN 202111624328 A CN202111624328 A CN 202111624328A CN 114350222 A CN114350222 A CN 114350222A
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wood paint
emulsion
friendly wood
parts
water
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CN202111624328.7A
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杜卫东
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Sichuan Yadu Furniture Co ltd
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Sichuan Yadu Furniture Co ltd
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Abstract

The invention belongs to the technical field of wood paint, and particularly relates to green environment-friendly wood paint and a preparation method thereof, wherein the wood paint comprises the following raw material components in parts by mass: 120-150 parts of modified water-based acrylic emulsion, 60-80 parts of modified water-based polyurethane emulsion, 1-3 parts of adhesion promoter, 1-3 parts of wetting agent, 0.5-2 parts of flatting agent, 1-3 parts of film-forming assistant, 0.5-1 part of thickening agent and 10-15 parts of deionized water. The green environment-friendly wood paint provided by the invention has scientific and reasonable formula design, wherein the modified water-based acrylic emulsion and the modified water-based polyurethane emulsion are mixed according to a certain proportion, and the advantages of quick drying, light resistance and weather resistance of the water-based acrylic resin, toughness of the water-based polyurethane, low-temperature film-forming property and the like are combined, so that the coating has better hardness and toughness, and the hardness and scratch resistance of the coating are improved.

Description

Green and environment-friendly wood paint and preparation method thereof
Technical Field
The invention belongs to the technical field of wood paint, and particularly relates to green environment-friendly wood paint and a preparation method thereof.
Background
Wood lacquers are essential to wood and wood-based materials and impart desirable aesthetic properties such as color, luster, etc. to wood materials, but more importantly, resist damage from moisture, radiation, biodegradation, and mechanochemical damage. The water-based wood paint takes water as a diluent, does not contain substances such as benzene, toluene and the like which are harmful to human bodies, has no peculiar smell, is non-toxic or low-toxicity and extremely low in VOC content, is the safest and most environment-friendly wood paint at present, and can ensure the safety and environment-friendly degree of home decoration to the greatest extent. The water-based wood lacquer does not contain harmful substances and can not volatilize into the air, so that the problem of paint film yellowing caused by continuous slow release of the harmful substances like the oily wood lacquer can be avoided. Therefore, the waterborne wood paint has better yellowing resistance and the paint film is as new as possible.
The wood lacquer mainly comprises acrylic emulsion wood lacquer and water-based polyurethane coating, wherein the acrylic emulsion has the characteristics of high solid content, high drying speed, low cost, good weather resistance and the like, but has the defects of poor film forming property, high minimum film forming temperature, solvent intolerance, hot adhesion, cold brittleness and the like, and the decorative effect is poor. The aqueous polyurethane coating can be divided into an aqueous polyurethane dispersion coating and a two-component aqueous polyurethane coating according to film forming performance, wherein the aqueous polyurethane dispersion has good adhesive force and wear resistance, the acrylic resin has excellent weather resistance and chemical resistance and good wettability to pigments, and the mixing of the aqueous polyurethane dispersion coating and the acrylic resin to obtain the composite coating with excellent performance becomes a driving force for people to search, but the mixing effect of the aqueous polyurethane dispersion coating and the acrylic resin is not ideal, and in addition, the coating film has low hardness and poor scratch resistance and still needs to be effectively improved.
Disclosure of Invention
The invention aims to overcome the problems in the prior art and provide a green environment-friendly wood paint and a preparation method thereof.
In order to achieve the technical purpose and achieve the technical effect, the invention is realized by the following technical scheme:
the green environment-friendly wood paint comprises the following raw material components in parts by mass:
Figure BDA0003439274880000021
further, in the above green environmental-friendly wood paint, the preparation method of the modified aqueous acrylic emulsion comprises: adding methyl methacrylate, an emulsifier, a mesoporous inorganic silica suspension and deionized water into a pre-emulsification kettle with a stirrer for pre-emulsification to obtain pre-emulsion; adding 40-50 wt% of the obtained pre-emulsion and sodium hydroxide into a reaction kettle, stirring the reaction kettle and heating to 70-72 ℃; when blue light emulsion is formed, dropwise adding the rest pre-emulsion into the reaction kettle by using a peristaltic pump, reacting for 2-3h at 86-88 ℃, cooling to 40-50 ℃, adding formic acid for neutralization, and filtering to obtain the modified water-based acrylic emulsion.
Further, in the green environment-friendly wood paint, the mesoporous inorganic silica suspension is prepared by grinding hydrothermally synthesized mesoporous silica nanoparticles into superfine powder to prepare a silica solution with a solid-to-liquid ratio of 2%, adjusting the pH value to 9.1-9.3 with inorganic base, transferring the solution into a reaction kettle, controlling the reaction temperature and stirring time, washing with centrifugal and absolute ethyl alcohol to obtain a powder product, re-dispersing the powder product in absolute ethyl alcohol, and performing ultrasonic treatment to obtain a colloidal stable mesoporous silica suspension.
Further, in the above green environmental-friendly wood paint, the preparation method of the modified aqueous polyurethane emulsion comprises: uniformly mixing diphenylmethane diisocyanate, dimethylolpropionic acid, acrylate, polycaprolactone diol and dibutyl tin dilaurate, heating to 80-84 ℃, preserving heat for 2-3h, adding trimethylolpropane, triethylamine and nano-silica, uniformly mixing, cooling, and emulsifying by using dispersed water to obtain the modified waterborne polyurethane emulsion.
Further, in the green environment-friendly wood paint, the weight ratio of diphenylmethane diisocyanate, dimethylolpropionic acid, acrylate, polycaprolactone diol, dibutyl tin dilaurate, trimethylolpropane, triethylamine and nano silicon dioxide is 10-12: 4-6: 3-5: 4-6: 6-8: 2-4: 1-3: 4-6.
Further, in the green environment-friendly wood paint, the adhesion promoter is glycerol ether oxypropyl methyl diethoxysilane.
Further, in the above green environment-friendly wood paint, the wetting agent is trisiloxane.
Further, in the green environment-friendly wood paint, the leveling agent is an aqueous leveling agent DC-57.
Further, in the green environment-friendly wood paint, the film-forming aid is dipropylene glycol butyl ether, and the thickener is an associated polyurethane thickener RM 2020.
The preparation method of the green environment-friendly wood paint comprises the following steps:
1) weighing the raw material components in parts by weight according to a ratio, adding the modified water-based acrylic emulsion, the modified water-based polyurethane emulsion and deionized water into a reaction kettle, heating to 55-58 ℃, stirring at a low speed, reacting for 0.5-4h, and cooling to normal temperature;
2) adding the wetting agent and the flatting agent while stirring, and continuously stirring for 0.5-1 h;
3) adding the adhesion promoter and the film-forming assistant while stirring, continuously stirring for 0.2-0.5h, adding the thickening agent, adjusting the viscosity to 55-60ku, and filtering to obtain the product.
The invention has the beneficial effects that:
the modified waterborne acrylic emulsion and the modified waterborne polyurethane emulsion in the environment-friendly wood paint provided by the invention are mixed according to a certain proportion, and the advantages of quick drying, light resistance and weather resistance of waterborne acrylic resin, toughness of waterborne polyurethane, low-temperature film-forming property and the like are combined, so that the coating has better hardness and toughness, and the hardness and scratch resistance of the coating are improved.
Of course, it is not necessary for any one product that embodies the invention to achieve all of the above advantages simultaneously.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The green environment-friendly wood paint comprises the following raw material components in parts by mass:
Figure BDA0003439274880000041
in the invention, the preparation method of the modified water-based acrylic emulsion comprises the following steps: adding methyl methacrylate, an emulsifier, a mesoporous inorganic silica suspension and deionized water into a pre-emulsification kettle with a stirrer for pre-emulsification to obtain pre-emulsion; adding 45 wt% of the obtained pre-emulsion and sodium hydroxide into a reaction kettle, stirring the reaction kettle and heating to 70 ℃; when blue light emulsion is formed, dropwise adding the rest pre-emulsion into a reaction kettle by using a peristaltic pump, reacting for 2 hours at 86-88 ℃, cooling to 45 ℃, adding formic acid for neutralization, and filtering to obtain the modified water-based acrylic emulsion.
In the invention, the mesoporous inorganic silica suspension is prepared by grinding hydrothermal-synthesized mesoporous silica nanoparticles into superfine powder to prepare a silica solution with a solid-to-liquid ratio of 2%, adjusting the pH value to 9.2 by using inorganic base, transferring the solution into a reaction kettle, controlling the reaction temperature and the stirring time, obtaining a powder product by centrifuging and washing with absolute ethyl alcohol, re-dispersing the product in the absolute ethyl alcohol, and carrying out ultrasonic treatment to obtain the colloidal stable mesoporous silica suspension.
In the invention, the preparation method of the modified waterborne polyurethane emulsion comprises the following steps: diphenylmethane diisocyanate, dimethylol propionic acid, acrylate, polycaprolactone diol and dibutyl tin dilaurate in a weight ratio of 11: 5: 4: 5: 7: 3: 2: 5, uniformly mixing, heating to 82 ℃, keeping the temperature for 3 hours, then adding trimethylolpropane, triethylamine and nano-silica, uniformly mixing, cooling, and emulsifying by using dispersed water to obtain the modified waterborne polyurethane emulsion.
In the invention, the adhesion promoter is glycerol ether oxypropyl methyl diethoxy silane, the wetting agent is trimeric siloxane, the flatting agent is an aqueous flatting agent DC-57, the film-forming assistant is dipropylene glycol butyl ether, and the thickening agent is associated polyurethane thickening agent RM 2020.
The preparation method of the green environment-friendly wood paint comprises the following steps:
1) weighing the raw material components in parts by weight according to a ratio, adding the modified water-based acrylic emulsion, the modified water-based polyurethane emulsion and deionized water into a reaction kettle, heating to 56 ℃, stirring at a low speed, reacting for 2 hours, and cooling to normal temperature;
2) adding the wetting agent and the flatting agent while stirring, and continuously stirring for 1 h;
3) adding the adhesion promoter and the film-forming assistant while stirring, continuously stirring for 0.5h, adding the thickening agent, adjusting the viscosity to 60ku, and filtering to obtain the product.
The following embodiments are relevant to the present invention:
example 1
The green environment-friendly wood paint comprises the following raw material components in parts by mass:
Figure BDA0003439274880000051
example 2
The green environment-friendly wood paint comprises the following raw material components in parts by mass:
Figure BDA0003439274880000061
example 3
The green environment-friendly wood paint comprises the following raw material components in parts by mass:
Figure BDA0003439274880000062
example 4
The green environment-friendly wood paint comprises the following raw material components in parts by mass:
Figure BDA0003439274880000063
Figure BDA0003439274880000071
example 5
The green environment-friendly wood paint comprises the following raw material components in parts by mass:
Figure BDA0003439274880000072
after the green environment-friendly wood paint obtained in examples 1-5 is coated on a wood product, a correlation performance test is carried out, and the test results are shown in table 1:
TABLE 1
Figure BDA0003439274880000073
The preferred embodiments of the invention disclosed above are intended to be illustrative only. The preferred embodiments are not intended to be exhaustive or to limit the invention to the precise embodiments disclosed. Obviously, many modifications and variations are possible in light of the above teaching. The embodiments were chosen and described in order to best explain the principles of the invention and the practical application, to thereby enable others skilled in the art to best utilize the invention. The invention is limited only by the claims and their full scope and equivalents.

Claims (10)

1. The green environment-friendly wood paint is characterized by comprising the following raw material components in parts by mass:
Figure FDA0003439274870000011
2. the green environment-friendly wood paint as claimed in claim 1, wherein the modified aqueous acrylic emulsion is prepared by the following steps: adding methyl methacrylate, an emulsifier, a mesoporous inorganic silica suspension and deionized water into a pre-emulsification kettle with a stirrer for pre-emulsification to obtain pre-emulsion; adding 40-50 wt% of the obtained pre-emulsion and sodium hydroxide into a reaction kettle, stirring the reaction kettle and heating to 70-72 ℃; when blue light emulsion is formed, dropwise adding the rest pre-emulsion into the reaction kettle by using a peristaltic pump, reacting for 2-3h at 86-88 ℃, cooling to 40-50 ℃, adding formic acid for neutralization, and filtering to obtain the modified water-based acrylic emulsion.
3. The green environmental-friendly wood paint according to claim 2, characterized in that: the mesoporous inorganic silica suspension is prepared by grinding mesoporous silica nano particles synthesized by a hydrothermal method into superfine powder, preparing a silica solution with a solid-to-liquid ratio of 2%, adjusting the pH value to be 9.1-9.3 by using inorganic base, transferring the solution into a reaction kettle, controlling the reaction temperature and stirring time, washing by using centrifugal and absolute ethyl alcohol to obtain a powder product, re-dispersing the powder product into absolute ethyl alcohol, and performing ultrasonic treatment to obtain a colloidal stable mesoporous silica suspension.
4. The green environment-friendly wood paint as claimed in claim 1, wherein the modified aqueous polyurethane emulsion is prepared by the following steps: uniformly mixing diphenylmethane diisocyanate, dimethylolpropionic acid, acrylate, polycaprolactone diol and dibutyl tin dilaurate, heating to 80-84 ℃, preserving heat for 2-3h, adding trimethylolpropane, triethylamine and nano-silica, uniformly mixing, cooling, and emulsifying by using dispersed water to obtain the modified waterborne polyurethane emulsion.
5. The green environmental-friendly wood paint according to claim 4, wherein: the weight ratio of the diphenylmethane diisocyanate to the dimethylolpropionic acid to the acrylate to the polycaprolactone diol to the dibutyl tin dilaurate to the trimethylolpropane to the triethylamine to the nano silicon dioxide is 10-12: 4-6: 3-5: 4-6: 6-8: 2-4: 1-3: 4-6.
6. The green environmental-friendly wood paint according to claim 1, wherein: the adhesion promoter is glycerol ether oxygen propyl methyl diethoxy silane.
7. The green environmental-friendly wood paint according to claim 1, wherein: the wetting agent is a trisiloxane.
8. The green environmental-friendly wood paint according to claim 1, wherein: the leveling agent is an aqueous leveling agent DC-57.
9. The green environmental-friendly wood paint according to claim 1, wherein: the film-forming aid is dipropylene glycol butyl ether, and the thickener is an associated polyurethane thickener RM 2020.
10. The method for preparing green environmental-friendly wood paint according to any one of claims 1-9, comprising the following steps:
1) weighing the raw material components in parts by weight according to a ratio, adding the modified water-based acrylic emulsion, the modified water-based polyurethane emulsion and deionized water into a reaction kettle, heating to 55-58 ℃, stirring at a low speed, reacting for 0.5-4h, and cooling to normal temperature;
2) adding the wetting agent and the flatting agent while stirring, and continuously stirring for 0.5-1 h;
3) adding the adhesion promoter and the film-forming assistant while stirring, continuously stirring for 0.2-0.5h, adding the thickening agent, adjusting the viscosity to 55-60ku, and filtering to obtain the product.
CN202111624328.7A 2021-12-28 2021-12-28 Green and environment-friendly wood paint and preparation method thereof Pending CN114350222A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111624328.7A CN114350222A (en) 2021-12-28 2021-12-28 Green and environment-friendly wood paint and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111624328.7A CN114350222A (en) 2021-12-28 2021-12-28 Green and environment-friendly wood paint and preparation method thereof

Publications (1)

Publication Number Publication Date
CN114350222A true CN114350222A (en) 2022-04-15

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Application Number Title Priority Date Filing Date
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Country Link
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