CN114340393A - 除草组合物 - Google Patents
除草组合物 Download PDFInfo
- Publication number
- CN114340393A CN114340393A CN202080060513.5A CN202080060513A CN114340393A CN 114340393 A CN114340393 A CN 114340393A CN 202080060513 A CN202080060513 A CN 202080060513A CN 114340393 A CN114340393 A CN 114340393A
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- China
- Prior art keywords
- methyl
- cas
- group
- substituted
- acid
- Prior art date
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- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 137
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 121
- 239000004009 herbicide Substances 0.000 claims abstract description 81
- 150000001875 compounds Chemical class 0.000 claims abstract description 79
- 238000000034 method Methods 0.000 claims abstract description 44
- 150000003839 salts Chemical class 0.000 claims abstract description 32
- -1 ester ketone Chemical class 0.000 claims description 357
- 239000004480 active ingredient Substances 0.000 claims description 183
- 241000196324 Embryophyta Species 0.000 claims description 129
- 229910052731 fluorine Inorganic materials 0.000 claims description 94
- 239000011737 fluorine Substances 0.000 claims description 94
- 239000001257 hydrogen Substances 0.000 claims description 94
- 229910052739 hydrogen Inorganic materials 0.000 claims description 94
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 74
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 73
- 239000000460 chlorine Substances 0.000 claims description 72
- 229910052801 chlorine Inorganic materials 0.000 claims description 72
- 150000002431 hydrogen Chemical class 0.000 claims description 55
- IANUJLZYFUDJIH-UHFFFAOYSA-N flufenacet Chemical compound C=1C=C(F)C=CC=1N(C(C)C)C(=O)COC1=NN=C(C(F)(F)F)S1 IANUJLZYFUDJIH-UHFFFAOYSA-N 0.000 claims description 45
- 239000005531 Flufenacet Substances 0.000 claims description 44
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 39
- 239000002253 acid Substances 0.000 claims description 39
- 229910052736 halogen Inorganic materials 0.000 claims description 36
- 150000002367 halogens Chemical class 0.000 claims description 36
- 229910052760 oxygen Inorganic materials 0.000 claims description 36
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 claims description 34
- 239000001301 oxygen Substances 0.000 claims description 30
- 125000003545 alkoxy group Chemical group 0.000 claims description 27
- 244000038559 crop plants Species 0.000 claims description 26
- 229910052757 nitrogen Inorganic materials 0.000 claims description 26
- 125000000623 heterocyclic group Chemical group 0.000 claims description 24
- FOUWCSDKDDHKQP-UHFFFAOYSA-N flumioxazin Chemical compound FC1=CC=2OCC(=O)N(CC#C)C=2C=C1N(C1=O)C(=O)C2=C1CCCC2 FOUWCSDKDDHKQP-UHFFFAOYSA-N 0.000 claims description 23
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 22
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 22
- IUQAXCIUEPFPSF-UHFFFAOYSA-N tembotrione Chemical compound ClC1=C(COCC(F)(F)F)C(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O IUQAXCIUEPFPSF-UHFFFAOYSA-N 0.000 claims description 22
- 239000005620 Tembotrione Substances 0.000 claims description 21
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 claims description 20
- 230000008569 process Effects 0.000 claims description 20
- 239000005504 Dicamba Substances 0.000 claims description 19
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 19
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 19
- 239000005562 Glyphosate Substances 0.000 claims description 18
- 239000005643 Pelargonic acid Substances 0.000 claims description 18
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 claims description 18
- 239000005499 Clomazone Substances 0.000 claims description 17
- KIEDNEWSYUYDSN-UHFFFAOYSA-N clomazone Chemical compound O=C1C(C)(C)CON1CC1=CC=CC=C1Cl KIEDNEWSYUYDSN-UHFFFAOYSA-N 0.000 claims description 17
- WYEHFWKAOXOVJD-UHFFFAOYSA-N diflufenican Chemical compound FC1=CC(F)=CC=C1NC(=O)C1=CC=CN=C1OC1=CC=CC(C(F)(F)F)=C1 WYEHFWKAOXOVJD-UHFFFAOYSA-N 0.000 claims description 17
- PXDNXJSDGQBLKS-UHFFFAOYSA-N foramsulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=C(NC=O)C=2)C(=O)N(C)C)=N1 PXDNXJSDGQBLKS-UHFFFAOYSA-N 0.000 claims description 17
- 229940097068 glyphosate Drugs 0.000 claims description 17
- KPUREKXXPHOJQT-UHFFFAOYSA-N mesotrione Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O KPUREKXXPHOJQT-UHFFFAOYSA-N 0.000 claims description 17
- PHNUZKMIPFFYSO-UHFFFAOYSA-N propyzamide Chemical compound C#CC(C)(C)NC(=O)C1=CC(Cl)=CC(Cl)=C1 PHNUZKMIPFFYSO-UHFFFAOYSA-N 0.000 claims description 17
- 239000005507 Diflufenican Substances 0.000 claims description 16
- 239000005560 Foramsulfuron Substances 0.000 claims description 16
- 239000005578 Mesotrione Substances 0.000 claims description 16
- 239000005602 Propyzamide Substances 0.000 claims description 16
- 125000003118 aryl group Chemical group 0.000 claims description 16
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 claims description 16
- MGOHCFMYLBAPRN-UHFFFAOYSA-N pinoxaden Chemical compound CCC1=CC(C)=CC(CC)=C1C(C1=O)=C(OC(=O)C(C)(C)C)N2N1CCOCC2 MGOHCFMYLBAPRN-UHFFFAOYSA-N 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 claims description 15
- MAYMYMXYWIVVOK-UHFFFAOYSA-N 2-[(4,6-dimethoxypyrimidin-2-yl)carbamoylsulfamoyl]-4-(methanesulfonamidomethyl)benzoic acid Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=C(CNS(C)(=O)=O)C=2)C(O)=O)=N1 MAYMYMXYWIVVOK-UHFFFAOYSA-N 0.000 claims description 15
- UPMXNNIRAGDFEH-UHFFFAOYSA-N 3,5-dibromo-4-hydroxybenzonitrile Chemical compound OC1=C(Br)C=C(C#N)C=C1Br UPMXNNIRAGDFEH-UHFFFAOYSA-N 0.000 claims description 15
- CTTHWASMBLQOFR-UHFFFAOYSA-N Amidosulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)N(C)S(C)(=O)=O)=N1 CTTHWASMBLQOFR-UHFFFAOYSA-N 0.000 claims description 15
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 15
- QZXATCCPQKOEIH-UHFFFAOYSA-N Florasulam Chemical compound N=1N2C(OC)=NC=C(F)C2=NC=1S(=O)(=O)NC1=C(F)C=CC=C1F QZXATCCPQKOEIH-UHFFFAOYSA-N 0.000 claims description 15
- CAWXEEYDBZRFPE-UHFFFAOYSA-N Hexazinone Chemical compound O=C1N(C)C(N(C)C)=NC(=O)N1C1CCCCC1 CAWXEEYDBZRFPE-UHFFFAOYSA-N 0.000 claims description 15
- 239000005583 Metribuzin Substances 0.000 claims description 15
- 239000005597 Pinoxaden Substances 0.000 claims description 15
- 241001061127 Thione Species 0.000 claims description 15
- DDBMQDADIHOWIC-UHFFFAOYSA-N aclonifen Chemical compound C1=C([N+]([O-])=O)C(N)=C(Cl)C(OC=2C=CC=CC=2)=C1 DDBMQDADIHOWIC-UHFFFAOYSA-N 0.000 claims description 15
- HUBANNPOLNYSAD-UHFFFAOYSA-N clopyralid Chemical compound OC(=O)C1=NC(Cl)=CC=C1Cl HUBANNPOLNYSAD-UHFFFAOYSA-N 0.000 claims description 15
- OYIKARCXOQLFHF-UHFFFAOYSA-N isoxaflutole Chemical compound CS(=O)(=O)C1=CC(C(F)(F)F)=CC=C1C(=O)C1=C(C2CC2)ON=C1 OYIKARCXOQLFHF-UHFFFAOYSA-N 0.000 claims description 15
- VWGAYSCWLXQJBQ-UHFFFAOYSA-N methyl 4-iodo-2-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoylsulfamoyl]benzoate Chemical group COC(=O)C1=CC=C(I)C=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 VWGAYSCWLXQJBQ-UHFFFAOYSA-N 0.000 claims description 15
- GNHDVXLWBQYPJE-UHFFFAOYSA-N saflufenacil Chemical compound C1=C(Cl)C(C(=O)NS(=O)(=O)N(C)C(C)C)=CC(N2C(N(C)C(=CC2=O)C(F)(F)F)=O)=C1F GNHDVXLWBQYPJE-UHFFFAOYSA-N 0.000 claims description 15
- 229920006395 saturated elastomer Polymers 0.000 claims description 15
- AHTPATJNIAFOLR-UHFFFAOYSA-N thifensulfuron-methyl Chemical group S1C=CC(S(=O)(=O)NC(=O)NC=2N=C(OC)N=C(C)N=2)=C1C(=O)OC AHTPATJNIAFOLR-UHFFFAOYSA-N 0.000 claims description 15
- NUPJIGQFXCQJBK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)-5-(methoxymethyl)nicotinic acid Chemical compound OC(=O)C1=CC(COC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 NUPJIGQFXCQJBK-UHFFFAOYSA-N 0.000 claims description 14
- 239000002890 Aclonifen Substances 0.000 claims description 14
- 239000003666 Amidosulfuron Substances 0.000 claims description 14
- 239000005489 Bromoxynil Substances 0.000 claims description 14
- 239000005500 Clopyralid Substances 0.000 claims description 14
- 239000005529 Florasulam Substances 0.000 claims description 14
- 239000005532 Flumioxazine Substances 0.000 claims description 14
- 239000005571 Isoxaflutole Substances 0.000 claims description 14
- 239000005577 Mesosulfuron Substances 0.000 claims description 14
- 239000005623 Thifensulfuron-methyl Substances 0.000 claims description 14
- HYJSGOXICXYZGS-UHFFFAOYSA-N benazolin Chemical compound C1=CC=C2SC(=O)N(CC(=O)O)C2=C1Cl HYJSGOXICXYZGS-UHFFFAOYSA-N 0.000 claims description 14
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 14
- 229910052794 bromium Inorganic materials 0.000 claims description 14
- MEFQWPUMEMWTJP-UHFFFAOYSA-N fluroxypyr Chemical compound NC1=C(Cl)C(F)=NC(OCC(O)=O)=C1Cl MEFQWPUMEMWTJP-UHFFFAOYSA-N 0.000 claims description 14
- 125000001072 heteroaryl group Chemical group 0.000 claims description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 14
- 229940088649 isoxaflutole Drugs 0.000 claims description 14
- 125000006413 ring segment Chemical group 0.000 claims description 14
- 229910052717 sulfur Chemical group 0.000 claims description 14
- YMXOXAPKZDWXLY-QWRGUYRKSA-N tribenuron methyl Chemical group COC(=O)[C@H]1CCCC[C@@H]1S(=O)(=O)NC(=O)N(C)C1=NC(C)=NC(OC)=N1 YMXOXAPKZDWXLY-QWRGUYRKSA-N 0.000 claims description 14
- LNKODIBGKHYUKU-UHFFFAOYSA-N 4-chloro-3-fluoropyridine-2-carboxylic acid Chemical class OC(=O)C1=NC=CC(Cl)=C1F LNKODIBGKHYUKU-UHFFFAOYSA-N 0.000 claims description 13
- 239000005558 Fluroxypyr Substances 0.000 claims description 13
- 239000005566 Imazamox Substances 0.000 claims description 13
- XMQFTWRPUQYINF-UHFFFAOYSA-N bensulfuron-methyl Chemical group COC(=O)C1=CC=CC=C1CS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 XMQFTWRPUQYINF-UHFFFAOYSA-N 0.000 claims description 13
- 229960002939 metizoline Drugs 0.000 claims description 13
- VGHPMIFEKOFHHQ-UHFFFAOYSA-N Metosulam Chemical compound N1=C2N=C(OC)C=C(OC)N2N=C1S(=O)(=O)NC1=C(Cl)C=CC(C)=C1Cl VGHPMIFEKOFHHQ-UHFFFAOYSA-N 0.000 claims description 12
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 12
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 11
- 239000005472 Bensulfuron methyl Substances 0.000 claims description 11
- 239000005582 Metosulam Substances 0.000 claims description 11
- 125000001153 fluoro group Chemical group F* 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- 125000004434 sulfur atom Chemical group 0.000 claims description 11
- WVQBLGZPHOPPFO-UHFFFAOYSA-N 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(C(C)COC)C(=O)CCl WVQBLGZPHOPPFO-UHFFFAOYSA-N 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 10
- RXCPQSJAVKGONC-UHFFFAOYSA-N Flumetsulam Chemical compound N1=C2N=C(C)C=CN2N=C1S(=O)(=O)NC1=C(F)C=CC=C1F RXCPQSJAVKGONC-UHFFFAOYSA-N 0.000 claims description 10
- SYJGKVOENHZYMQ-UHFFFAOYSA-N Penoxsulam Chemical compound N1=C2C(OC)=CN=C(OC)N2N=C1NS(=O)(=O)C1=C(OCC(F)F)C=CC=C1C(F)(F)F SYJGKVOENHZYMQ-UHFFFAOYSA-N 0.000 claims description 10
- 125000004429 atom Chemical group 0.000 claims description 10
- BXIGJZDQFDFASM-UHFFFAOYSA-N cyclopyrimorate Chemical compound N=1N=C(Cl)C=C(OC(=O)N2CCOCC2)C=1OC=1C(C)=CC=CC=1C1CC1 BXIGJZDQFDFASM-UHFFFAOYSA-N 0.000 claims description 10
- 125000005842 heteroatom Chemical group 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- XMTQQYYKAHVGBJ-UHFFFAOYSA-N 3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA Chemical compound CN(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XMTQQYYKAHVGBJ-UHFFFAOYSA-N 0.000 claims description 9
- FCOHEOSCARXMMS-UHFFFAOYSA-N Oxaziclomefone Chemical compound C1OC(C)=C(C=2C=CC=CC=2)C(=O)N1C(C)(C)C1=CC(Cl)=CC(Cl)=C1 FCOHEOSCARXMMS-UHFFFAOYSA-N 0.000 claims description 9
- 239000005592 Penoxsulam Substances 0.000 claims description 9
- VGPYEHKOIGNJKV-UHFFFAOYSA-N asulam Chemical compound COC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 VGPYEHKOIGNJKV-UHFFFAOYSA-N 0.000 claims description 9
- SYJFEGQWDCRVNX-UHFFFAOYSA-N diquat Chemical compound C1=CC=[N+]2CC[N+]3=CC=CC=C3C2=C1 SYJFEGQWDCRVNX-UHFFFAOYSA-N 0.000 claims description 9
- RSMUVYRMZCOLBH-UHFFFAOYSA-N metsulfuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 RSMUVYRMZCOLBH-UHFFFAOYSA-N 0.000 claims description 9
- NQLVQOSNDJXLKG-UHFFFAOYSA-N prosulfocarb Chemical compound CCCN(CCC)C(=O)SCC1=CC=CC=C1 NQLVQOSNDJXLKG-UHFFFAOYSA-N 0.000 claims description 9
- RBSXHDIPCIWOMG-UHFFFAOYSA-N 1-(4,6-dimethoxypyrimidin-2-yl)-3-(2-ethylsulfonylimidazo[1,2-a]pyridin-3-yl)sulfonylurea Chemical compound CCS(=O)(=O)C=1N=C2C=CC=CN2C=1S(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 RBSXHDIPCIWOMG-UHFFFAOYSA-N 0.000 claims description 8
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 claims description 8
- XKJMBINCVNINCA-UHFFFAOYSA-N Alfalone Chemical compound CON(C)C(=O)NC1=CC=C(Cl)C(Cl)=C1 XKJMBINCVNINCA-UHFFFAOYSA-N 0.000 claims description 8
- QNXAVFXEJCPCJO-UHFFFAOYSA-N Diclosulam Chemical compound N=1N2C(OCC)=NC(F)=CC2=NC=1S(=O)(=O)NC1=C(Cl)C=CC=C1Cl QNXAVFXEJCPCJO-UHFFFAOYSA-N 0.000 claims description 8
- 239000005510 Diuron Substances 0.000 claims description 8
- UWVKRNOCDUPIDM-UHFFFAOYSA-N Ethoxysulfuron Chemical compound CCOC1=CC=CC=C1OS(=O)(=O)NC(=O)NC1=NC(OC)=CC(OC)=N1 UWVKRNOCDUPIDM-UHFFFAOYSA-N 0.000 claims description 8
- HWATZEJQIXKWQS-UHFFFAOYSA-N Flazasulfuron Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CN=2)C(F)(F)F)=N1 HWATZEJQIXKWQS-UHFFFAOYSA-N 0.000 claims description 8
- YWBVHLJPRPCRSD-UHFFFAOYSA-N Fluridone Chemical compound O=C1C(C=2C=C(C=CC=2)C(F)(F)F)=CN(C)C=C1C1=CC=CC=C1 YWBVHLJPRPCRSD-UHFFFAOYSA-N 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 239000005584 Metsulfuron-methyl Substances 0.000 claims description 8
- 239000005603 Prosulfocarb Substances 0.000 claims description 8
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 claims description 8
- RQVYBGPQFYCBGX-UHFFFAOYSA-N ametryn Chemical compound CCNC1=NC(NC(C)C)=NC(SC)=N1 RQVYBGPQFYCBGX-UHFFFAOYSA-N 0.000 claims description 8
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 claims description 8
- GINJFDRNADDBIN-FXQIFTODSA-N bilanafos Chemical compound OC(=O)[C@H](C)NC(=O)[C@H](C)NC(=O)[C@@H](N)CCP(C)(O)=O GINJFDRNADDBIN-FXQIFTODSA-N 0.000 claims description 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- PUIYMUZLKQOUOZ-UHFFFAOYSA-N isoproturon Chemical compound CC(C)C1=CC=C(NC(=O)N(C)C)C=C1 PUIYMUZLKQOUOZ-UHFFFAOYSA-N 0.000 claims description 8
- BACHBFVBHLGWSL-UHFFFAOYSA-N methyl 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate Chemical group C1=CC(OC(C)C(=O)OC)=CC=C1OC1=CC=C(Cl)C=C1Cl BACHBFVBHLGWSL-UHFFFAOYSA-N 0.000 claims description 8
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 8
- CHIFOSRWCNZCFN-UHFFFAOYSA-N pendimethalin Chemical compound CCC(CC)NC1=C([N+]([O-])=O)C=C(C)C(C)=C1[N+]([O-])=O CHIFOSRWCNZCFN-UHFFFAOYSA-N 0.000 claims description 8
- NQQVFXUMIDALNH-UHFFFAOYSA-N picloram Chemical compound NC1=C(Cl)C(Cl)=NC(C(O)=O)=C1Cl NQQVFXUMIDALNH-UHFFFAOYSA-N 0.000 claims description 8
- APTZNLHMIGJTEW-UHFFFAOYSA-N pyraflufen-ethyl Chemical group C1=C(Cl)C(OCC(=O)OCC)=CC(C=2C(=C(OC(F)F)N(C)N=2)Cl)=C1F APTZNLHMIGJTEW-UHFFFAOYSA-N 0.000 claims description 8
- IROINLKCQGIITA-UHFFFAOYSA-N terbutryn Chemical compound CCNC1=NC(NC(C)(C)C)=NC(SC)=N1 IROINLKCQGIITA-UHFFFAOYSA-N 0.000 claims description 8
- WVQBLGZPHOPPFO-LBPRGKRZSA-N (S)-metolachlor Chemical compound CCC1=CC=CC(C)=C1N([C@@H](C)COC)C(=O)CCl WVQBLGZPHOPPFO-LBPRGKRZSA-N 0.000 claims description 7
- MZHCENGPTKEIGP-UHFFFAOYSA-N 2-(2,4-dichlorophenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1Cl MZHCENGPTKEIGP-UHFFFAOYSA-N 0.000 claims description 7
- NYRMIJKDBAQCHC-UHFFFAOYSA-N 5-(methylamino)-2-phenyl-4-[3-(trifluoromethyl)phenyl]furan-3(2H)-one Chemical compound O1C(NC)=C(C=2C=C(C=CC=2)C(F)(F)F)C(=O)C1C1=CC=CC=C1 NYRMIJKDBAQCHC-UHFFFAOYSA-N 0.000 claims description 7
- NLYNUTMZTCLNOO-UHFFFAOYSA-N Chlorbromuron Chemical compound CON(C)C(=O)NC1=CC=C(Br)C(Cl)=C1 NLYNUTMZTCLNOO-UHFFFAOYSA-N 0.000 claims description 7
- 239000005497 Clethodim Substances 0.000 claims description 7
- 239000005630 Diquat Substances 0.000 claims description 7
- 239000005514 Flazasulfuron Substances 0.000 claims description 7
- 239000005573 Linuron Substances 0.000 claims description 7
- 239000005574 MCPA Substances 0.000 claims description 7
- FFQPZWRNXKPNPX-UHFFFAOYSA-N N-benzyl-2-[4-fluoro-3-(trifluoromethyl)phenoxy]butanamide Chemical compound C=1C=CC=CC=1CNC(=O)C(CC)OC1=CC=C(F)C(C(F)(F)F)=C1 FFQPZWRNXKPNPX-UHFFFAOYSA-N 0.000 claims description 7
- 239000005591 Pendimethalin Substances 0.000 claims description 7
- 239000005595 Picloram Substances 0.000 claims description 7
- 239000005619 Sulfosulfuron Substances 0.000 claims description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
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- 239000000654 additive Substances 0.000 claims description 7
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- MSHXTAQSSIEBQS-UHFFFAOYSA-N s-[3-carbamoylsulfanyl-2-(dimethylamino)propyl] carbamothioate;hydron;chloride Chemical compound [Cl-].NC(=O)SCC([NH+](C)C)CSC(N)=O MSHXTAQSSIEBQS-UHFFFAOYSA-N 0.000 description 1
- 235000002020 sage Nutrition 0.000 description 1
- 229960000581 salicylamide Drugs 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 125000003548 sec-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229930000044 secondary metabolite Natural products 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000019491 signal transduction Effects 0.000 description 1
- HPYNBECUCCGGPA-UHFFFAOYSA-N silafluofen Chemical compound C1=CC(OCC)=CC=C1[Si](C)(C)CCCC1=CC=C(F)C(OC=2C=CC=CC=2)=C1 HPYNBECUCCGGPA-UHFFFAOYSA-N 0.000 description 1
- MXMXHPPIGKYTAR-UHFFFAOYSA-N silthiofam Chemical compound CC=1SC([Si](C)(C)C)=C(C(=O)NCC=C)C=1C MXMXHPPIGKYTAR-UHFFFAOYSA-N 0.000 description 1
- RTWIRLHWLMNVCC-WQYNNSOESA-M sodium (2S)-2-[[(2S)-2-[[(2S)-2-amino-4-[hydroxy(methyl)phosphoryl]butanoyl]amino]propanoyl]amino]propanoate Chemical compound [Na+].[O-]C(=O)[C@H](C)NC(=O)[C@H](C)NC(=O)[C@@H](N)CCP(C)(O)=O RTWIRLHWLMNVCC-WQYNNSOESA-M 0.000 description 1
- 229940125794 sodium channel blocker Drugs 0.000 description 1
- 239000003195 sodium channel blocking agent Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229920005552 sodium lignosulfonate Polymers 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- UFEIWEXHHOXPGP-UHFFFAOYSA-M sodium;(4,6-dimethoxypyrimidin-2-yl)carbamoyl-[3-(2,2,2-trifluoroethoxy)pyridin-2-yl]sulfonylazanide Chemical compound [Na+].COC1=CC(OC)=NC(NC(=O)[N-]S(=O)(=O)C=2C(=CC=CN=2)OCC(F)(F)F)=N1 UFEIWEXHHOXPGP-UHFFFAOYSA-M 0.000 description 1
- UEFBGOFTQWGYCJ-BNSHTTSQSA-M sodium;(6z)-2-methoxycarbonyl-3,3-dimethyl-5-oxo-6-[1-(prop-2-enoxyamino)butylidene]cyclohexen-1-olate Chemical compound [Na+].C=CCONC(/CCC)=C1\C(=O)CC(C)(C)C(C(=O)OC)=C1[O-] UEFBGOFTQWGYCJ-BNSHTTSQSA-M 0.000 description 1
- KZOJQMWTKJDSQJ-UHFFFAOYSA-M sodium;2,3-dibutylnaphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 KZOJQMWTKJDSQJ-UHFFFAOYSA-M 0.000 description 1
- RFOHRSIAXQACDB-UHFFFAOYSA-M sodium;2-(2,4-dichlorophenoxy)acetate Chemical compound [Na+].[O-]C(=O)COC1=CC=C(Cl)C=C1Cl RFOHRSIAXQACDB-UHFFFAOYSA-M 0.000 description 1
- XWAFIZUTHLRWBE-UHFFFAOYSA-M sodium;2-(2,4-dichlorophenoxy)propanoate Chemical compound [Na+].[O-]C(=O)C(C)OC1=CC=C(Cl)C=C1Cl XWAFIZUTHLRWBE-UHFFFAOYSA-M 0.000 description 1
- STAPBGVGYWCRTF-UHFFFAOYSA-M sodium;2-(4-chloro-2-methylphenoxy)acetate Chemical compound [Na+].CC1=CC(Cl)=CC=C1OCC([O-])=O STAPBGVGYWCRTF-UHFFFAOYSA-M 0.000 description 1
- DHJHUXNTNSRSEX-UHFFFAOYSA-M sodium;2-(4-chloro-2-methylphenoxy)propanoate Chemical compound [Na+].[O-]C(=O)C(C)OC1=CC=C(Cl)C=C1C DHJHUXNTNSRSEX-UHFFFAOYSA-M 0.000 description 1
- NAGWPMWBTLVULC-UHFFFAOYSA-M sodium;2-(4-methyl-5-oxo-4-propan-2-yl-1h-imidazol-2-yl)quinoline-3-carboxylate Chemical compound [Na+].N1C(=O)C(C(C)C)(C)N=C1C1=NC2=CC=CC=C2C=C1C([O-])=O NAGWPMWBTLVULC-UHFFFAOYSA-M 0.000 description 1
- JUNDBKFAZXZKRA-MAFYXNADSA-M sodium;2-[(e)-n-[(3,5-difluorophenyl)carbamoylamino]-c-methylcarbonimidoyl]pyridine-3-carboxylate Chemical compound [Na+].N=1C=CC=C(C([O-])=O)C=1C(/C)=N/NC(=O)NC1=CC(F)=CC(F)=C1 JUNDBKFAZXZKRA-MAFYXNADSA-M 0.000 description 1
- WMWBBXKLYSGKDY-UHFFFAOYSA-M sodium;3-amino-2,5-dichlorobenzoate Chemical compound [Na+].NC1=CC(Cl)=CC(C([O-])=O)=C1Cl WMWBBXKLYSGKDY-UHFFFAOYSA-M 0.000 description 1
- PPKIJAQKBAYNNL-UHFFFAOYSA-M sodium;4-(2,4-dichlorophenoxy)butanoate Chemical compound [Na+].[O-]C(=O)CCCOC1=CC=C(Cl)C=C1Cl PPKIJAQKBAYNNL-UHFFFAOYSA-M 0.000 description 1
- GABUSZPTCJGKGB-UHFFFAOYSA-M sodium;4-(4-chloro-2-methylphenoxy)butanoate Chemical compound [Na+].CC1=CC(Cl)=CC=C1OCCCC([O-])=O GABUSZPTCJGKGB-UHFFFAOYSA-M 0.000 description 1
- RVULBHWZFCBODE-UHFFFAOYSA-M sodium;5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoate Chemical compound [Na+].C1=C([N+]([O-])=O)C(C(=O)[O-])=CC(OC=2C(=CC(=CC=2)C(F)(F)F)Cl)=C1 RVULBHWZFCBODE-UHFFFAOYSA-M 0.000 description 1
- YPMAQKXGDCKXPE-WCCKRBBISA-M sodium;[(3s)-3-amino-3-carboxypropyl]-methylphosphinate Chemical compound [Na+].CP([O-])(=O)CC[C@H](N)C(O)=O YPMAQKXGDCKXPE-WCCKRBBISA-M 0.000 description 1
- JRQGDDUXDKCWRF-UHFFFAOYSA-M sodium;n-(2-methoxycarbonylphenyl)sulfonyl-4-methyl-5-oxo-3-propoxy-1,2,4-triazole-1-carboximidate Chemical compound [Na+].O=C1N(C)C(OCCC)=NN1C(=O)[N-]S(=O)(=O)C1=CC=CC=C1C(=O)OC JRQGDDUXDKCWRF-UHFFFAOYSA-M 0.000 description 1
- 239000004550 soluble concentrate Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229930185156 spinosyn Natural products 0.000 description 1
- WOPFPAIGRGHWAQ-UHFFFAOYSA-N spiropidion Chemical compound CCOC(=O)OC1=C(C=2C(=CC(Cl)=CC=2C)C)C(=O)N(C)C11CCN(OC)CC1 WOPFPAIGRGHWAQ-UHFFFAOYSA-N 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- OORLZFUTLGXMEF-UHFFFAOYSA-N sulfentrazone Chemical compound O=C1N(C(F)F)C(C)=NN1C1=CC(NS(C)(=O)=O)=C(Cl)C=C1Cl OORLZFUTLGXMEF-UHFFFAOYSA-N 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 150000003462 sulfoxides Chemical group 0.000 description 1
- 125000005555 sulfoximide group Chemical group 0.000 description 1
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 description 1
- RJKCKKDSSSRYCB-UHFFFAOYSA-N tebutam Chemical compound CC(C)(C)C(=O)N(C(C)C)CC1=CC=CC=C1 RJKCKKDSSSRYCB-UHFFFAOYSA-N 0.000 description 1
- BCQMBFHBDZVHKU-UHFFFAOYSA-N terbumeton Chemical compound CCNC1=NC(NC(C)(C)C)=NC(OC)=N1 BCQMBFHBDZVHKU-UHFFFAOYSA-N 0.000 description 1
- IWVCMVBTMGNXQD-UHFFFAOYSA-N terramycin dehydrate Natural products C1=CC=C2C(O)(C)C3C(O)C4C(N(C)C)C(O)=C(C(N)=O)C(=O)C4(O)C(O)=C3C(=O)C2=C1O IWVCMVBTMGNXQD-UHFFFAOYSA-N 0.000 description 1
- URHWNXDZOULUHC-UHFFFAOYSA-N tert-butyl n-[6-[[[(1-methyltetrazol-5-yl)-phenylmethylidene]amino]oxymethyl]pyridin-2-yl]carbamate Chemical compound CN1N=NN=C1C(C=1C=CC=CC=1)=NOCC1=CC=CC(NC(=O)OC(C)(C)C)=N1 URHWNXDZOULUHC-UHFFFAOYSA-N 0.000 description 1
- 125000001712 tetrahydronaphthyl group Chemical group C1(CCCC2=CC=CC=C12)* 0.000 description 1
- ZFXYFBGIUFBOJW-UHFFFAOYSA-N theophylline Chemical compound O=C1N(C)C(=O)N(C)C2=C1NC=N2 ZFXYFBGIUFBOJW-UHFFFAOYSA-N 0.000 description 1
- 229960000278 theophylline Drugs 0.000 description 1
- 125000002053 thietanyl group Chemical group 0.000 description 1
- LOQQVLXUKHKNIA-UHFFFAOYSA-N thifensulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C2=C(SC=C2)C(O)=O)=N1 LOQQVLXUKHKNIA-UHFFFAOYSA-N 0.000 description 1
- DNVLJEWNNDHELH-UHFFFAOYSA-N thiocyclam Chemical compound CN(C)C1CSSSC1 DNVLJEWNNDHELH-UHFFFAOYSA-N 0.000 description 1
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical compound COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 1
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 description 1
- 125000000464 thioxo group Chemical group S=* 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- VJQYLJSMBWXGDV-UHFFFAOYSA-N tiadinil Chemical compound N1=NSC(C(=O)NC=2C=C(Cl)C(C)=CC=2)=C1C VJQYLJSMBWXGDV-UHFFFAOYSA-N 0.000 description 1
- IHNSIFFSNUQGQN-UHFFFAOYSA-N tioxazafen Chemical compound C1=CSC(C=2ON=C(N=2)C=2C=CC=CC=2)=C1 IHNSIFFSNUQGQN-UHFFFAOYSA-N 0.000 description 1
- OBZIQQJJIKNWNO-UHFFFAOYSA-N tolclofos-methyl Chemical compound COP(=S)(OC)OC1=C(Cl)C=C(C)C=C1Cl OBZIQQJJIKNWNO-UHFFFAOYSA-N 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 description 1
- ZHYZQXUYZJNEHD-UHFFFAOYSA-N trans-geranic acid Natural products CC(C)=CCCC(C)=CC(O)=O ZHYZQXUYZJNEHD-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000014616 translation Effects 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- VLCQZHSMCYCDJL-UHFFFAOYSA-N tribenuron methyl Chemical compound COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)N(C)C1=NC(C)=NC(OC)=N1 VLCQZHSMCYCDJL-UHFFFAOYSA-N 0.000 description 1
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 description 1
- AKTQJCBOGPBERP-UHFFFAOYSA-N triflusulfuron Chemical compound FC(F)(F)COC1=NC(N(C)C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2C)C(O)=O)=N1 AKTQJCBOGPBERP-UHFFFAOYSA-N 0.000 description 1
- ICESBGJHRQHALQ-UHFFFAOYSA-K trisodium;(carboxymethylamino)methyl-hydroxyphosphinate;2-[[hydroxy(oxido)phosphoryl]methylamino]acetate Chemical compound [Na+].[Na+].[Na+].OC(=O)CNCP(O)([O-])=O.OC(=O)CNCP([O-])([O-])=O ICESBGJHRQHALQ-UHFFFAOYSA-K 0.000 description 1
- KVEQCVKVIFQSGC-UHFFFAOYSA-N tritosulfuron Chemical compound FC(F)(F)C1=NC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(F)(F)F)=N1 KVEQCVKVIFQSGC-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000012873 virucide Substances 0.000 description 1
- 230000001755 vocal effect Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229940048462 zinc phosphide Drugs 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P13/00—Herbicides; Algicides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P13/00—Herbicides; Algicides
- A01P13/02—Herbicides; Algicides selective
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明涉及包含除草活性化合物(A)和(B)的组合物，其中(A)代表一种或多种通式(I)的化合物或其农业化学上可接受的盐[组分(A)]，
Description
本发明属于植物保护剂的技术领域，所述植物保护剂可用于对抗未开垦土地上不希望有的植物生长，用于播种准备或植物作物中，并包含至少两种除草剂的组合作为除草活性成分，其中所述组合物包含除草活性化合物(A)和(B)，其中(A)代表一种或多种通式(I)的化合物或其农业化学上可接受的盐[除草剂(A)或组分(A)]，和(B)代表一种或多种除草剂(组分B)。
来自3-苯基异噁唑啉-5-甲酰胺的结构类别的化合物作为除草剂是已知的(参见，例如，WO2012/130798A)。当在芽前过程中抑或在芽后过程中施用时，这些化合物将有效对抗广谱的有害植物，可以非选择性地用于控制不希望有的植物生长或选择性地用于植物作物中。
这些除草剂对有害植物的功效处于高水平，但通常取决于施用量、相应制剂的形式、有害植物谱、每种情况下待控制的有害植物、气候、和土壤条件等。又一个标准是除草剂的作用持续时间或降解速度。视情况而定，其他考虑因素为有害植物的易感性的变化，这些变化可能在长期使用除草剂时或以受地理限制的方式发生。通过增加除草剂的施用量来在个体植物情况下补偿作用的损失只在有限的程度上是可能的，例如因为这经常会使除草剂的选择性变得更差，或者因为作用未得到改善，甚至在更高施用量的情况下。通常需要以较低的活性成分施用量实现除草作用的方法。较低的施用量不仅减少施用所需的活性成分的量，而且通常还减少所需的配制助剂的量。既降低经济支出，又提高除草剂处理的环境相容性。
改善除草剂的应用特性的一种方式可以是将活性成分与一种或多种有助于期望的附加性质的其他活性成分相组合。然而，在组合施用两种或更多种活性成分的情况下，存在物理和生物不相容性的现象并不罕见，例如共配制物缺乏稳定性、活性成分的分解和/或活性成分的拮抗作用。相比之下，期望的是具有有利的活性特性、高的稳定性和理想地出乎意料的协同增强活性的活性成分组合，与待组合的活性成分的单独施用相比，其允许降低施用量。
本发明的任务在于提供替代的或有利的除草组合物，其具有良好的生物学应用特性并具有尽可能多的上述期望的有利性质。
现已惊奇地发现，该任务可通过使用包含除草活性化合物(A)和(B)的组合物来完成，其中(A)代表一种或多种通式(I)的化合物或其农业化学上可接受的盐[组分(A)]，和(B)代表一种或多种选自除草活性成分(B1)至(B11)的除草剂[组分(B)]。本发明的组合物以特别有利的方式相互作用，例如当使用它们来控制作物植物如小麦(硬质和软质小麦)、玉米、大豆、甜菜、甘蔗、棉花、水稻、豆类(例如，矮菜豆和蚕豆)、亚麻、大麦、燕麦、黑麦、黑小麦、马铃薯和小米/高粱、未开垦的土地、牧场和草地/草坪及种植园作物中不希望有的植物的生长时。
本发明的主题因此是包含除草活性化合物(A)和(B)的组合物，其中(A)代表一种或多种通式(I)的化合物或其农业化学上可接受的盐[组分(A)]，
其中：
G为式OR4或NR11R12的基团；
R1和R2分别彼此独立地为氢、卤素或氰基，
或者
为(C1-C4)-烷基或(C1-C4)-烷氧基，其分别被m个选自卤素和氰基的基团所取代；
R3为氰基或氟，
或者
为(C1-C5)-烷基、(C3-C6)-环烷基、(C2-C5)-烯基、(C2-C5)-炔基或(C1-C5)-烷氧基，其分别被m个选自卤素、氰基、(C1-C5)-烷氧基和羟基的基团所取代；
R4为氢，
或者
为(C1-C12)-烷基、(C3-C7)-环烷基、(C3-C7)-环烷基-(C1-C8)-烷基、(C2-C8)-烯基、(C5-C6)-环烯基或(C2-C8)-炔基，其分别被m个选自卤素、氰基、(C1-C6)-烷氧基、羟基和芳基的基团所取代；
Y为氧或硫；
W为氧或硫；
Z代表被k个选自R10的基团所取代的单不饱和环戊烷环，
其中箭头分别代表朝向式(I)中的C＝W基团的键；
R10为卤素、氰基或CO2R7，
或者
为(C1-C2)-烷基或(C1-C2)-烷氧基，其分别被m个选自氟和氯的基团所取代；
R11、R12分别彼此独立地为氢、氰基、OR7、S(O)nR5、SO2NR6R7、CO2R8、CONR6R8、COR6、NR6R8、NR6COR8、NR6CONR8R8、NR6CO2R8、NR6SO2R8、NR6SO2NR6R8、C(R6)＝NOR8、任选取代的芳基、任选取代的杂芳基和任选取代的杂环基，
或者
为(C1-C12)-烷基、(C3-C8)-环烷基、(C3-C7)-环烷基-(C1-C7)-烷基、(C2-C12)-烯基、(C5-C7)-环烯基或(C2-C12)-炔基，其分别被m个选自卤素、氰基、硝基、OR7、S(O)nR5、SO2NR6R7、CO2R8、CONR6R8、COR6、NR6R8、NR6COR8、NR6CONR8R8、NR6CO2R8、NR6SO2R8、NR6SO2NR6R8、C(R6)＝NOR8、任选取代的芳基、任选取代的杂芳基和任选取代的杂环基的基团所取代，
或者
R11和R12与它们所键合的氮原子一起形成饱和的、部分或完全不饱和的五-、六-或七-元环，所述环任选被选自卤素、氰基、硝基、(C1-C6)-烷基、卤代-(C1-C6)-烷基、氧代、OR7、S(O)nR5、SO2NR6R7、CO2R8、CONR6R8、COR6、NR6R8、NR6COR8、NR6CONR8R8、NR6CO2R8、NR6SO2R8、NR6SO2NR6R8和C(R6)＝NOR8的基团单取代至六取代，并且除了该氮原子外，所述环还含有r个碳原子、o个氧原子、p个硫原子和q个选自NR7和NCOR7的要素作为环原子；
X2、X4和X6分别彼此独立地为氢、卤素或氰基，
或者
为(C1-C2)-烷基，其分别被m个选自氟、氯、溴和(C1-C2)-烷氧基的基团所取代；
X3和X5分别彼此独立地为氢、氟、氯、溴、碘、羟基、氰基、硝基、S(O)nR6或CO2R7，
或者
为(C1-C3)-烷基、(C1-C3)-烷氧基、(C3-C4)-环烷基、(C2-C3)-烯基或(C2-C3)-炔基，其分别被m个选自氟、氯和溴的基团所取代；
R5为(C1-C8)-烷基、(C3-C6)-环烷基或芳基，其分别被m个选自卤素、氰基和羟基的基团所取代；
R6为氢或R5；
R7为氢，
或者
为(C1-C6)-烷基、(C3-C6)-环烷基、(C3-C4)-烯基或(C3-C4)-炔基，其分别被m个选自卤素、氰基和(C1-C2)-烷氧基的基团所取代；
R8为氢，
或者
为(C1-C8)-烷基、(C3-C6)-环烷基、(C3-C8)-烯基或(C3-C8)-炔基，其分别被m个选自卤素、氰基和(C1-C2)-烷氧基的基团所取代；
k为数字0、1或2；其中，当k>1时，R10可独立地相同或不同；
m为数字0、1、2、3、4或5；
n为数字0、1或2；
o为数字0、1或2；
p为数字0或1；
q为数字0或1；和
r为数字3、4、5或6。
和
(B)代表一种或多种选自除草活性成分(B1)至(B11)的除草剂[组分(B)]，其中
(B1)代表来自1,3-二酮化合物的除草活性成分，选自：
(B1.1)禾草灭，(CAS 55634-91-8),(CAS 55635-13-7)
(B1.2)双环吡喃酮，(CAS 352010-68-5)
(B1.3)丁苯草酮，(CAS 138164-12-2)
(B1.4)烯草酮，(CAS 99129-21-2)
(B1.5)噻草酮，(CAS 101205-02-1)
(B1.6)芬喹草酮(CAS 1342891-70-6)
(B1.7)甲基磺草酮，(CAS 104206-82-8)
(B1.8)唑啉草酯，(CAS 243973-20-8)
(B1.9)环苯草酮，(CAS 139001-49-3)
(B1.10)烯禾啶，(CAS 74051-80-2)
(B1.11)磺草酮，(CAS 99105-77-8)
(B1.12)SYP-9121(CAS 1976053-87-8)
(B1.13)特糠酯酮(CAS 473278-76-1)
(B1.14)环磺酮，(CAS 335104-84-2)
(B1.15)吡喃草酮，(CAS 149979-41-9)
(B1.16)三甲苯草酮，(CAS 87820-88-0)
(B1.17)Y13161,(CAS 1639426-14-4)
(B1.18)Y13287；(CAS 1639426-42-8)
(B2)代表来自(磺)酰胺的除草活性成分，选自：
(B2.1)乙草胺，(CAS 34256-82-1)
(B2.2)甲草胺，(CAS 15972-60-8)
(B2.3)酰嘧磺隆，(CAS 120923-37-7)
(B2.4)磺草灵，(CAS 3337-71-1)(CAS 14089-43-1),(CAS 2302-17-2)
(B2.5)四唑嘧磺隆，(CAS 120162-55-2)
(B2.6)氟丁酰草胺，(CAS 113614-08-7),(CAS 113614-09-8)
(B2.7)苄嘧磺隆，(CAS 83055-99-6),(CAS 83055-99-6)
(B2.8)丁草胺，(CAS 23184-66-99)
(B2.9)双酰草胺，(CAS 16118-49-3)
(B2.10)氯嘧磺隆，(CAS 99283-00-8),(CAS 90982-32-4),
(B2.11)氯苯胺灵，(CAS 101-21-3)
(B2.12)氯磺隆，(CAS 64902-72-3)
(B2.13)醚磺隆，(CAS 94593-91-6)
(B2.14)氯酯磺草胺，(CAS159518-97-5),(CAS 147150-35-4)
(B2.15)环丙嘧磺隆，(CAS 136849-15-5)
(B2.16)甜草灵，(CAS 13684-56-5)
(B2.17)双氯磺草胺，(CAS 145701-21-9)
(B2.18)吡氟草胺，(CAS 83164-33-4)
(B2.19)二甲草胺，(CAS 50563-36-5)
(B2.20)二甲噻草胺，(CAS 87674-68-8),(CAS 163515-14-8)
(B2.21)戊草丹(CAS 85785-20-2)
(B2.22)胺苯磺隆，(CAS 111353-84-5),(CAS 97780-06-8)
(B2.23)乙氧嘧磺隆，(CAS 126801-58-9)
(B2.24)啶嘧磺隆，(CAS 104040-78-0)
(B2.25)双氟磺草胺，(CAS 145701-23-1)
(B2.26)氟酮磺隆，(CAS 145026-88-6),(CAS 181274-17-9)
(B2.27)氟吡磺隆，(CAS 412928-75-7)
(B2.28)氟噻草胺，(CAS 142459-58-3)
(B2.29)唑嘧磺草胺，(CAS 98967-40-9)
(B2.30)氟啶嘧磺隆，(CAS 150315-10-9),(CAS 144740-53-4),(CAS 144740-54-5)
(B2.31)甲酰胺磺隆，(CAS 173159-57-4)
(B2.32)氯吡嘧磺隆，(CAS 135397-30-7),(CAS 100784-20-1)
(B2.33)唑吡嘧磺隆，(CAS 122548-33-8)
(B2.34)碘甲磺隆，(CAS 185119-76-0),(CAS 144550-06-1),(CAS 144550-36-7)
(B2.35)艾分卡巴腙，(CAS 212201-70-2)
(B2.36)苯噻酰草胺，(CAS 73250-68-7)
(B2.37)甲基二磺隆，(CAS 400852-66-6),(CAS 208465-21-8)
(B2.38)吡唑草胺，(CAS 67129-08-2)
(B2.39)嗪吡嘧磺隆，(CAS 868680-84-6)
(B2.40)异丙甲草胺，(CAS 51218-45-2)
(B2.41)磺草唑胺，(CAS 139528-85-1)
(B2.42)甲磺隆，(CAS 79510-48-8),(CAS 74223-64-6)
(B2.43)烟嘧磺隆，(CAS 111991-09-4)
(B2.44)嘧苯胺磺隆，(CAS 213464-77-8)
(B2.45)环氧嘧磺隆，(CAS 144651-06-9)
(B2.46)五氟磺草胺，(CAS 219714-96-2)
(B2.47)烯草胺，(CAS 106700-29-2)
(B2.48)甜菜宁，(CAS 13684-63-4)
(B2.49)氯吡酰草胺，(CAS 137641-05-5)
(B2.50)丙草胺，(CAS 51218-49-6)
(B2.51)氟嘧磺隆，(CAS 113036-87-6),(CAS 86209-51-0)
(B2.52)毒草胺，(CAS 1918-16-7)
(B2.53)敌稗，(CAS 709-98-8)
(B2.54)苯胺灵，(CAS 122-42-9)
(B2.55)异丙草胺，(CAS 86763-47-5)
(B2.56)丙苯磺隆，(CAS 145026-81-9),(CAS 181274-15-7)
(B2.57)丙嗪嘧磺隆，(CAS 570415-88-2)
(B2.58)戊炔草胺，(CAS 23950-58-5)
(B2.59)苄草丹，(CAS 52888-80-9)
(B2.60)氟磺隆，(CAS 94125-34-5)
(B2.61)吡嘧磺隆，(CAS 98389-04-9),(CAS 93697-74-6)
(B2.62)啶磺草胺，(CAS 422556-08-9)
(B2.63)砜嘧磺隆，(CAS 122931-48-0)
(B2.64)精异丙甲草胺，(CAS 87392-12-9)
(B2.65)嘧磺隆，(CAS 74223-56-6),(CAS 74222-97-2),(CAS 144651-06-9)
(B2.66)磺酰磺隆，(CAS 141776-32-1)
(B2.67)噻吩草胺，(CAS 96491-05-3)
(B2.68)噻酮磺隆，(CAS 936331-72-5),(CAS 317815-83-1)
(B2.69)噻磺隆，(CAS 79277-67-1),(CAS 79277-27-3)
(B2.70)野麦畏，(CAS 2303-17-5)
(B2.71)醚苯磺隆，(CAS 82097-50-5)
(B2.72)苯磺隆，(CAS 106040-48-6),(CAS 101200-48-0)
(B2.73)三氟啶磺隆，(CAS 145099-21-4,(CAS 199119-58-9)
(B2.74)氟胺磺隆，(CAS 135990-29-3),(CAS 126535-15-7)
(B2.75)三氟甲磺隆，(CAS 142469-14-5)
(B2.76)戊草丹，(CAS 85785-20-2)
(B2.77)氟唑草胺，(CAS 190314-43-3)
(B2.78)野麦畏；(CAS 2303-17-5)
(B3)代表来自芳基腈的除草活性成分，选自：
(B3.1)溴草腈，(CAS 1689-84-5)(CAS 3861-41-4),(CAS 56634-95-8),(CAS1689-99-2),(CAS 2961-68-4)
(B3.2)草克乐，(CAS 1918-13-4)
(B3.3)敌草腈，(CAS 1194-65-6)
(B3.4)碘苯腈，(CAS 1689-83-4),(CAS 2961-61-7),(CAS 3861-47-0),(CAS2961-62-8)
(B3.5)双唑草腈；(CAS 158353-15-2)
(B4)代表来自唑的除草活性成分，选自：
(B4.1)氨唑草酮，(CAS 129909-90-6)
(B4.2)杀草强，(CAS 61-82-5)
(B4.3)唑啶草酮，(CAS 68049-83-2)
(B4.4)吡草酮，(CAS 82692-44-2)
(B4.5)苯唑氟草酮，(CAS 1992017-55-6)
(B4.6)双唑草酮，(CAS 1622908-18-2)
(B4.7)唑草胺，(CAS 125306-83-4)
(B4.8)快灭灵，(CAS 128621-72-7),(CAS128639-02-1)
(B4.9)四唑酰草胺，(CAS 158237-07-1)
(B4.10)咪草酸，(CAS 100728-84-5),(CAS 81405-85-8)
(B4.11)甲氧咪草烟，(CAS 114311-32-9),(CAS 247057-22-3)
(B4.12)甲基咪草烟，(CAS 104098-48-8),(CAS 115136-53-3)
(B4.13)咪唑烟酸，(CAS 81334-34-1),(CAS 81510-83-0)
(B4.14)咪唑喹啉酸，(CAS 81335-37-7),(CAS 81335-47-9),(CAS 81335-43-5),(CAS 81335-46-8)
(B4.15)咪唑乙烟酸，(CAS 81335-77-5),(CAS 101917-66-2)
(B4.16)异噁隆，(CAS 55861-78-4)
(B4.17)异噁草胺，(CAS 82558-50-7)
(B4.18)异噁唑草酮，(CAS 141112-29-0)
(B4.19)丙炔噁草酮，(CAS 39807-15-3)
(B4.20)噁草灵，(CAS 19666-30-9)
(B4.21)吡草醚，(CAS 129630-17-7),(CAS 129630-19-9)
(B4.22)磺酰草吡唑，(CAS 365400-11-9)
(B4.23)吡唑特，(CAS 58011-68-0)
(B4.24)苄草唑，(CAS 71561-11-0)
(B4.25)砜吡草唑，(CAS 447399-55-5)
(B4.26)磺酰唑草酮，(CAS 122836-35-5)
(B4.27)Tolpyralate，(CAS 1101132-67-5)
(B4.28)苯唑草酮，(CAS 210631-68-8)
(B4.29)三唑磺草酮(CAS 1911613-97-2)(QYR-301)，
(B4.30)QYM-201,(CAS 1855925-45-1)
(B4.31)苯卡巴腙，(CAS 173980-17-1)
(B4.32)异丙吡草酯，(CAS 174514-07-9)
(B4.33)氟胺草唑，(CAS 119126-15-7)
(B4.34)异噁氯草酮；(CAS 141112-06-3)
(B5)代表其他除草活性成分，选自：
(B5.1)环丙嘧啶酸，(CAS 858956-08-8),(CAS 858954-83-3),(CAS 858956-35-1)
(B5.2)氯氨吡啶酸，(CAS 150114-71-9),(CAS 566191-87-5),(CAS 566191-89-7)
(B5.3)草除灵，(CAS 3813-05-6),(CAS 38561-76-1),(CAS 25059-80-7),(CAS67338-65-2)
(B5.4)氟草胺，(CAS 1861-40-1)
(B5.5)灭草松，(CAS 25057-89-0),(CAS 50723-80-3)
(B5.6)双环磺草酮，(CAS 156963-66-5)
(B5.7)Bixlozone，(CAS 81777-95-9)
(B5.8)杀草全，(CAS 13181-17-4)
(B5.9)地乐胺，(CAS 33629-47-9)
(B5.10)氯草敏/杀草敏，(CAS 1698-60-8)
(B5.11)氯酞酸，(CAS 2136-79-0),(CAS 1861-32-1),(CAS 887-54-7)
(B5.12)吲哚酮草酯，(CAS 142891-20-1)
(B5.13)环庚草醚，(CAS 87818-31-3)
(B5.14)异噁草松，(CAS 81777-89-1)
(B5.15)Cyclopyrimorate，(CAS 499231-24-2)
(B5.16)氨氟灵，(CAS 29091-05-2)
(B5.17)敌草快，(CAS 2764-72-9),(CAS 85-00-7),(CAS 4032-26-2)
(B5.18)氟硫草定，(CAS 97886-45-8)
(B5.19)乙酸，(CAS 64-19-7)
(B5.20)乙丁烯氟灵，(CAS 55283-68-6)
(B5.21)乙氧呋草黄，(CAS 26225-79-6)
(B5.22)异丙草氟安，(CAS 58667-63-3,(CAS 90134-59-1),(CAS 63782-90-1),(CAS 63729-98-6)
(B5.23)氯氟吡啶酯，(CAS 943832-81-3),(CAS 1390661-72-9)
(B5.24)氟哒嗪草酯，(CAS 188490-07-5),(CAS 188489-07-8)
(B5.25)氟烯草酸，(CAS 87547-04-4),(CAS 87546-18-7)
(B5.26)丙炔氟草胺，(CAS 103361-09-7)
(B5.27)氟啶草酮，(CAS 59756-60-4)
(B5.28)氟咯草酮，(CAS 61213-25-0)
(B5.29)呋草酮，(CAS 96525-23-4)
(B5.30)氟噻乙草酯，(CAS 149253-65-6)
(B5.31)氟氯吡啶酸，(CAS 943832-60-8),(CAS 943831-98-9)
(B5.32)茚草酮，(CAS 13320-30-1)
(B5.33)氟草敏，(CAS 27314-13-2)
(B5.34)油酸，(CAS 112-80-1)
(B5.35)安磺灵，(CAS 19044-88-3)
(B5.36)噁嗪草酮，(CAS 153197-14-9)
(B5.37)对草快，(CAS 4685-14-7),(CAS 1910-42-5),(CAS 2074-50-2)
(B5.38)天竺葵酸，(CAS 112-05-0)
(B5.39)二甲戊灵，(CAS 40487-42-1)
(B5.40)环戊噁草酮，(CAS 110956-75-7)
(B5.41)哒草特代谢物，(CAS 40020-01-7)
(B5.42)哒草特，(CAS 55512-33-9)
(B5.43)Tetflupyrolimet，(CAS 2053901-33-8)
(B5.44)噻唑烟酸，(CAS 117718-60-2)
(B5.45)氟酮磺草胺，(CAS 874195-61-6)
(B5.46)氟乐灵，(CAS 1582-09-8)
(B5.47)4-氨基-3-氯-5-氟-6-(7-氟-1H-吲哚-6-基)吡啶-2-甲酸，
(B5.48)Cyclopyrimorate，(CAS 499231-24-2)
(B5.49)敌草快，(CAS 2764-72-9,CAS 85-00-7,CAS4032-26-2)
(B5.50)噁嗪草酮，(CAS 153197-14-9)
(B5.51)甲氯酰草胺，(CAS 2307-68-8)
(B5.52)牧草胺，(CAS 35256-85-0)
(B5.53)噻二唑草胺，(CAS 123249-43-4)
(B6)代表来自(杂)芳基羧酸的除草活性成分，选自：
(B6.1)草灭平，(CAS 133-90-4),(CAS 1076-46-6),(CAS 53404-16-3),(CAS7286-84-2),(CAS 25182-03-0),(1954-81-0)
(B6.2)二氯吡啶(CAS 1702-17-6),(CAS 1532-24-7),酸，(CAS 57754-85-5),(CAS 58509-83-4),(CAS 73455-09-1)
(B6.3)麦草畏，(CAS 1918-00-9),(CAS 1286239-22-2),(CAS 104040-79-1),(CAS 2300-66-5),(CAS 25059-78-3),(CAS 55871-02-8),(CAS 6597-78-0),(CAS 53404-28-7),(CAS 10007-85-9),(CAS 1982-69-0),(53404-29-8),(CAS 56141-00-5)
(B6.4)氟草定，(CAS 69377-81-7),(CAS-27-8),(CAS 81406-37-3)
(B6.5)毒莠定，(CAS 1918-02-1),(CAS 55870-98-9),(CAS 36374-99-9),(CAS26952-20-5),(CAS 14143-55-6),(CAS 55871-00-6),(CAS 2545-60-0),(CAS 35832-11-2),(CAS 6753-47-5),(CAS 82683-78-1)
(B6.6)二氯喹啉(CAS 84087-01-4),(CAS酸，84087-48-9),(CAS 84087-33-2)
(B6.7)喹草酸，(CAS 90717-03-6)
(B6.8)TBA，(CAS 50-31-7),(CAS 3426-62-8),(CAS 71750-37-3),(CAS 4559-30-2),(CAS 2078-42-4)
(B6.9)三氯吡氧乙(CAS 55335-06-3),(CAS酸；[64700-56-7),(CAS 1048373-85-8),(CAS 60825-27-6),(CAS 57213-69-1)
(B7)代表来自有机磷化合物的除草活性成分，选自：
(B7.1)莎稗磷，(CAS 64249-01-0)
(B7.2)双丙氨磷，(CAS 35597-43-4),(CAS 71048-99-2)
(B7.3)抑草磷，(CAS 36335-67-8)
(B7.4)草铵膦，(CAS 51276-47-2),(CAS 35597-44-5),(CAS 77182-82-2),(CAS35597-44-5),(CAS 70033-13-5)
(B7.5)草甘膦，(CAS 1071-83-6),(CAS 69254-40-6),(CAS 34494-04-7),(CAS38641-94-0),(CAS 40465-66-5),(CAS 39600-42-5),(CAS 70393-85-0),(CAS 81591-81-3)
(B7.6)哌草磷，(CAS 24151-93-7)
(B7.7)草硫膦，(CAS 1591-81-3)
(B7.8)胺草磷，(CAS 33857-23-7,CAS 36001-88-4)
(B8)代表来自苯基醚的除草活性成分，选自：
(B8.1)2,4-D，(CAS 94-75-7),(CAS 2307-55-3),(CAS 1929-73-3),(CAS 1320-18-9),(CAS 1928-45-6),(CAS 94-80-4),(CAS 1048373-72-3),(CAS 20940-37-8),(CAS2008-39-1),(CAS 5742-19-8),(CAS 2212-54-6),(CAS 533-23-3),(CAS 1928-43-4),(CAS 37102-63-9),(CAS 713-15-1),(CAS 25168-26-7),(CAS 94-11-1),(CAS 5742-17-6),(CAS 3766-27-6),(CAS 1917-97-1),(CAS 1928-38-7),(CAS 1928-44-5),(CAS 1917-92-6),(CAS 1928-61-6),(CAS 2702-72-9),(CAS 15146-99-3),(CAS 28685-18-9),(CAS2646-78-8),(CAS 18584-79-7),(CAS 2569-01-9),(CAS 215655-76-8)
(B8.2)2,4-DB,(CAS 94-82-6),(CAS 2758-42-1),(CAS 1320-15-6),(CAS19480-40-1),(CAS 10433-59-7)
(B8.3)2,4-DP,(CAS 120-36-5),(CAS 53404-31-2),(CAS 53404-32-3),(CAS79270-78-3),(CAS 28631-35-8),(CAS 57153-17-0),(CAS 5746-17-8),(CAS 39104-30-8)
(B8.4)三氟羧草醚，(CAS 50594-66-6),(CAS 50594-67-7),(CAS 62476-59-9)
(B8.5)苯草醚，(CAS 74070-46-5)
(B8.6)治草醚，(CAS 42576-02-3)
(B8.7)甲氧除草醚，(CAS 32861-85-1)
(B8.8)炔草酯，(CAS 114420-56-3),(CAS 105512-06-9)
(B8.9)氯甲酰草胺，(CAS 84496-56-0)
(B8.10)氰氟草酯，(CAS 122008-78-0),(CAS 122008-85-9)
(B8.11)禾草灵，(CAS 40843-25-2),(CAS 51338-27-3)
(B8.12)氟乳醚，(CAS 188634-90-4),(CAS 131086-42-5)
(B8.13)噁唑禾草灵，(CAS 95617-09-7),(CAS 113158-40-0),(CAS 71283-80-2)
(B8.14)吡氟禾草灵，(CAS 69335-91-7),(CAS 83066-88-0),(CAS 79241-46-6)
(B8.15)乙羧氟草醚，(CAS 77501-60-1),(CAS 77501-90-7)
(B8.16)氟磺胺草醚，(CAS 72178-02-0),(CAS 108731-70-0)
(B8.17)氟硝磺酰胺，(CAS 77227-69-1)
(B8.18)氟吡禾灵，(CAS 69806-34-4),(CAS 95977-29-0),(CAS 72619-32-0)
(B8.19)乳氟禾草灵，(CAS 77501-63-4)
(B8.20)MCPA，(CAS 94-74-6),(CAS 19480-43-4),(CAS 1713-12-8),(CAS 2039-46-5),(CAS 20405-19-0),(CAS 2698-38-6),(CAS 29450-45-1),(CAS 1713-11-7),(CAS26544-20-7),(CAS 2698-40-0),(CAS 2436-73-9),(CAS 6365-62-4),(CAS 5221-16-9),(CAS 3653-48-3),(CAS 42459-68-7)
(B8.21)MCPB，(CAS 94-81-5),(CAS 10443-70-6),(CAS 57153-18-1),(CAS6062-26-6)
(B8.22)2-甲-4-氯丙酸，(CAS 93-65-2),(CAS 32351-70-5),(CAS 1432-14-0),(CAS 71526-69-7),(CAS 28473-03-2),(CAS 2786-19-8),(CAS 1929-86-8),(CAS 19095-88-6),(CAS 53404-61-8),(CAS 16484-77-8)
(B8.23)噁唑酰草胺，(CAS 256412-89-2)
(B8.24)乙氧氟草醚，(CAS 42874-03-3)
(B8.25)喔草酯，(CAS 111479-05-1)
(B8.26)喹禾灵，(CAS 76578-12-6),(CAS 76578-14-8),
(B8.27)精喹禾灵，(CAS 94051-08-8),(CAS 100646-51-3),(CAS 200509-41-7)
(B8.28)双苯嘧草酮；(CAS 158755-95-4)
(B9)代表来自嘧啶的除草活性成分，选自：
(B9.1)双草醚，(CAS 125401-92-5)
(B9.2)除草定，(CAS 314-40-9),(CAS 53404-19-6),(CAS 69484-12-4)
(B9.3)氟丙嘧草酯，(CAS 134605-64-4)
(B9.4)环草定，(CAS 2164-08-1)
(B9.5)嘧啶肟草醚，(CAS 168088-61-7)
(B9.6)环酯草醚，(CAS 135186-78-6)
(B9.7)嘧草醚，(CAS 136191-56-5),(CAS 136191-64-5)
(B9.8)吡硫磺，(CAS 221205-90-9)
(B9.9)嘧草硫醚，(CAS 123342-93-8),(CAS 123343-16-8)
(B9.10)苯嘧磺草胺，(CAS 372137-35-4)
(B9.11)特草定，(CAS 5902-51-2)
(B9.12)氟嘧硫草酯，(CAS 1220411-29-9)
(B9.13)三氟草嗪，(CAS 1258836-72-4)
(B9.14)[3-[2-氯-4-氟-5-(1-甲基-6-三氟甲基-2,4-二氧代-1,2,3,4-四氢嘧啶-3-基)苯氧基]-2-吡啶氧基]乙酸乙酯；
(B10)代表来自(硫)脲的除草活性成分，选自：
(B10.1)氯溴隆，(CAS 13360-45-7)
(B10.2)绿麦隆，(CAS 15545-48-9)
(B10.3)杀草隆，(CAS 42609-52-9)
(B10.4)噁唑隆，(CAS 34205-21-5)
(B10.5)敌草隆，(CAS 330-54-1)
(B10.6)氟吡草腙，(CAS 1957168-02-3)
(B10.7)氟草隆，(CAS 2164-17-2)
(B10.8)异丙隆，(CAS 34123-59-6)
(B10.9)利谷隆，(CAS 330-55-2)
(B10.10)甲基苯噻隆，(CAS 18691-97-9)
(B10.11)溴谷隆，(CAS 3060-89-7)
(B10.12)甲氧隆，(CAS 19937-59-8)
(B10.13)绿谷隆，(CAS 1746-81-2)
(B10.14)草不隆，(CAS 555-37-3)
(B10.15)环草隆，(CAS 1982-49-6)
(B10.16)丁唑隆，(CAS 34014-18-1)
(B10.17)非草隆，(CAS 101-42-8)
(B10.18)枯草隆，(CAS 1982-47-4)
(B10.19)氟吡草腙，(CAS 1957168-02-3,CAS 109293-98-3)
(B10.20)磺噻隆；(CAS 30043-49-3)
(B11)代表来自三嗪的除草活性成分，选自：
(B11.1)莠灭净，(CAS 834-12-8)
(B11.2)莠去津，(CAS 1912-24-9)
(B11.3)草净津，(CAS 21725-46-2)
(B11.4)异戊净，(CAS 22936-75-0)
(B11.5)环嗪酮，(CAS 51235-04-2)
(B11.6)茚嗪氟草胺，(CAS 950782-86-2)
(B11.7)苯嗪草酮，(CAS 41394-05-2)
(B11.8)赛克津，(CAS 21087-64-9)
(B11.9)扑灭通，(CAS 1610-18-0)
(B11.10)扑草净，(CAS 7287-19-6)
(B11.11)扑灭津，(CAS 139-40-2)
(B11.12)西玛津，(CAS 122-34-9)
(B11.13)西草净，(CAS 1014-70-6)
(B11.14)特丁通，(CAS 33693-04-8)
(B11.15)特丁津，(CAS 5915-41-3)
(B11.16)特丁净，(CAS 886-50-0)
(B11.17)三嗪氟草胺，(CAS 131475-57-5)
(B11.18)草达津，(CAS 1912-26-1)
(B11.19)敌草净(CAS 1014-69-3)。
上面列出的除草剂的名称(通用名称)由括号内的“CAS RN”(化学文摘社登记号)(简称“CAS”)补充。CAS RN是一种广泛使用的参考编号，允许所讨论物质的明确指定，因为“CAS RN”特别区分异构体(包括立体异构体)及盐和酯。对于以各种形式存在的活性成分，上述列表中在各种情况下均给出中性化合物的名称。括号内给出的CAS针对的是活性成分的这些及所有其他已知的形式。下文仅提及中性化合物，并因此涵盖如所列的所有现有形式，除非活性成分的特定形式在特定上下文中、例如在针对生物功效的下表实施例中是相关的。
本发明的组合物可还含有其他组分，例如对抗有害生物体如有害植物、损害植物的动物或损害植物的真菌的其他活性成分，尤其是选自除草剂、杀真菌剂、杀昆虫剂、杀螨剂、杀线虫剂和杀疥虫药的活性成分及相关物质，抑或用于作物保护的其他种类活性成分(例如，抗病诱导剂)、植物生长调节剂和/或在植物保护中惯用的添加剂和/或配制助剂。这里，可将这些组分配制于一起(即用型配制物)并原样采用，或者可分开配制它们并一起采用(例如在桶混物中)或顺序施用。
作为组分(A)存在的单独的通式(I)的除草活性成分在下文中也称为化合物(A)、活性成分(A)、组分(A)或除草剂(A)。相应地，作为组分(B)存在的单独的除草活性成分在下文中也称为化合物(B)、活性成分(B)、组分(B)或除草剂(B)。
根据本发明的除草剂(A)和(B)的组合的有利性质表现为活性成分(A)与(B)彼此相容，这意味着它们可一起采用而不会在活性成分(A)和/或(B)之间发生导致一种或多种活性成分的破坏的显著化学不相容性。这将避免配制物或喷雾液中活性成分含量的任何减少。有利的相容性还扩展到组合使用时活性成分的生物学性质。例如，在用本发明的活性成分组合控制有害植物的情况下通常没有观察到拮抗作用。因此，活性成分(A)和(B)特别适合与用于作物保护的其他活性成分或农业化学品一起使用或者在除用于作物保护的其他活性成分或农业化学品之外还使用活性成分(A)和(B)。启用的组合施用将允许实现有利的效果，例如，加宽施用时将控制的有害植物谱，或者与所讨论的除草剂在单独施用情况下的相应施用量相比降低各个除草剂(A)或(B)的施用量。因此可以影响活性成分的降解特性并为随后作物植物的生长取得更有利的条件。又一个优点被认为是通过组合具有不同作用机制的活性成分，通常可显著降低或避免有害植物对活性成分产生抵抗性。
更特别地，在对大量经济上重要的有害植物组合使用活性成分(A)和(B)的情况下，令人惊奇地发生了超加和(＝协同)效应。这里，组合中的活性高于所使用的一种一种单独的除草剂的活性的预期总和。协同效应允许进一步降低施用量，控制更广谱的阔叶型杂草和杂草，除草作用起效更快，持续时间更长，仅一次或少数几次施用就能更好地控制有害植物以及扩展可能的施用时间段。有时，所述产品的使用也减少有害成分如氮或油酸的量以及它们向土壤中的引入。
所述性质和优点在实际杂草控制中是期望的，以便使农作物摆脱不希望有的竞争性植物并因此在质量和数量方面确保和/或提高产量。就所描述的性质而言，所述新型组合明显优于技术标准。
在共同应用活性成分(A)和(B)的情况下观察到协同效应，但在错时施用(分开施用)的情况下也可经常发生。还可以分多份施用除草剂(A)或(B)或除草剂组合物(A)和(B)(顺序施用)。例如，可在一次或多次芽前过程施用之后跟着芽后过程施用，或者可在早期的芽后过程施用之后跟着中晚期或晚期的芽后过程施用。优选同时施用或紧跟着连续施用相应组合的活性成分，如果适合分若干份的话。但组合的各个活性成分在不同的时间施用也是可能的，并且在个别情况下可能是有利的。还可以将其他作物保护剂整合到用于施用的体系中，例如所提到的其他活性成分(其他除草剂、杀真菌剂、杀昆虫剂、杀螨剂等)和/或各种助剂、佐剂和/或肥料的施用。
根据其中使用该术语的上下文，在芽前过程中或在芽后过程中的施用分别理解为是指在有害植物可见地出现于地面上之前和之后施用活性成分，或在作物植物的出芽之前和作物植物的出芽之后使用对抗有害植物的活性成分。
在除草活性成分(A)的化合物的式(I)和所有随后的式中，以下定义适用：
烷基表示具有分别指定的碳原子数的饱和直链或支链烃基基团，例如C1-C6-烷基，如甲基、乙基、丙基、1-甲基乙基、丁基、1-甲基丙基、2-甲基丙基、1,1-二甲基乙基、戊基、1-甲基丁基、2-甲基丁基、3-甲基丁基、2,2-二甲基丙基、1-乙基丙基、己基、1,1-二甲基丙基、1,2-二甲基丙基、1-甲基戊基、2-甲基戊基、3-甲基戊基、4-甲基戊基、1,1-二甲基丁基、1,2-二甲基丁基、1,3-二甲基丁基、2,2-二甲基丁基、2,3-二甲基丁基、3,3-二甲基丁基、1-乙基丁基、2-乙基丁基、1,1,2-三甲基丙基、1,2,2-三甲基丙基、1-乙基-1-甲基丙基和1-乙基-2-甲基丙基。
卤素取代的烷基表示直链或支链的烷基基团，其中这些基团中的一些或全部氢原子可被替换为卤素原子，例如C1-C2-卤代烷基，如氯甲基、溴甲基、二氯甲基、三氯甲基、氟甲基、二氟甲基、三氟甲基、氯氟甲基、二氯氟甲基、氯二氟甲基、1-氯乙基、1-溴乙基、1-氟乙基、2-氟乙基、2,2-二氟乙基、2,2,2-三氟乙基、2-氯-2-氟乙基、2-氯-2-二氟乙基、2,2-二氯-2-氟乙基、2,2,2-三氯乙基、五氟乙基和1,1,1-三氟丙-2-基。
烯基表示不饱和的直链或支链烃基基团，其具有分别述及的碳原子数和在任何位置中的一个双键，例如C2-C6-烯基，如乙烯基、1-丙烯基、2-丙烯基、1-甲基乙烯基、1-丁烯基、2-丁烯基、3-丁烯基、1-甲基-1-丙烯基、2-甲基-1-丙烯基、1-甲基-2-丙烯基、2-甲基-2-丙烯基、1-戊烯基、2-戊烯基、3-戊烯基、4-戊烯基、1-甲基-1-丁烯基、2-甲基-1-丁烯基、3-甲基-1-丁烯基、1-甲基-2-丁烯基、2-甲基-2-丁烯基、3-甲基-2-丁烯基、1-甲基-3-丁烯基、2-甲基-3-丁烯基、3-甲基-3-丁烯基、1,1-二甲基-2-丙烯基、1,2-二甲基-1-丙烯基、1,2-二甲基-2-丙烯基、1-乙基-1-丙烯基、1-乙基-2-丙烯基、1-己烯基、2-己烯基、3-己烯基、4-己烯基、5-己烯基、1-甲基-1-戊烯基、2-甲基-1-戊烯基、3-甲基-1-戊烯基、4-甲基-1-戊烯基、1-甲基-2-戊烯基、2-甲基-2-戊烯基、3-甲基-2-戊烯基、4-甲基-2-戊烯基、1-甲基-3-戊烯基、2-甲基-3-戊烯基、3-甲基-3-戊烯基、4-甲基-3-戊烯基、1-甲基-4-戊烯基、2-甲基-4-戊烯基、3-甲基-4-戊烯基、4-甲基-4-戊烯基、1,1-二甲基-2-丁烯基、1,1-二甲基-3-丁烯基、1,2-二甲基-1-丁烯基、1,2-二甲基-2-丁烯基、1,2-二甲基-3-丁烯基、1,3-二甲基-1-丁烯基、1,3-二甲基-2-丁烯基、1,3-二甲基-3-丁烯基、2,2-二甲基-3-丁烯基、2,3-二甲基-1-丁烯基、2,3-二甲基-2-丁烯基、2,3-二甲基-3-丁烯基、3,3-二甲基-1-丁烯基、3,3-二甲基-2-丁烯基、1-乙基-1-丁烯基、1-乙基-2-丁烯基、1-乙基-3-丁烯基、2-乙基-1-丁烯基、2-乙基-2-丁烯基、2-乙基-3-丁烯基、1,1,2-三甲基-2-丙烯基、1-乙基-1-甲基-2-丙烯基、1-乙基-2-甲基-1-丙烯基和1-乙基-2-甲基-2-丙烯基。
炔基表示直链或支链的烃基基团，其具有分别指定的碳原子数和在任何位置中的一个三键，例如C2-C6-炔基，如乙炔基、1-丙炔基、2-丙炔基(或炔丙基)、1-丁炔基、2-丁炔基、3-丁炔基、1-甲基-2-丙炔基、1-戊炔基、2-戊炔基、3-戊炔基、4-戊炔基、3-甲基-1-丁炔基、1-甲基-2-丁炔基、1-甲基-3-丁炔基、2-甲基-3-丁炔基、1,1-二甲基-2-丙炔基、1-乙基-2-丙炔基、1-己炔基、2-己炔基、3-己炔基、4-己炔基、5-己炔基、3-甲基-1-戊炔基、4-甲基-1-戊炔基、1-甲基-2-戊炔基、4-甲基-2-戊炔基、1-甲基-3-戊炔基、2-甲基-3-戊炔基、1-甲基-4-戊炔基、2-甲基-4-戊炔基、3-甲基-4-戊炔基、1,1-二甲基-2-丁炔基、1,1-二甲基-3-丁炔基、1,2-二甲基-3-丁炔基、2,2-二甲基-3-丁炔基、3,3-二甲基-1-丁炔基、1-乙基-2-丁炔基、1-乙基-3-丁炔基、2-乙基-3-丁炔基和1-乙基-1-甲基-2-丙炔基。
环烷基表示优选具有3-8个环碳原子的碳环饱和环系统，例如环丙基、环丁基、环戊基或环己基。在任选取代的环烷基的情况下，包括具有取代基的环状系统，还包括在环烷基基团上具有双键的取代基，例如亚烷基基团如亚甲基。
在任选取代的环烷基的情况下，还包括多环脂族体系，例如双环[1.1.0]丁-1-基、双环[1.1.0]丁-2-基、双环[2.1.0]戊-1-基、双环[2.1.0]戊-2-基、双环[2.1.0]戊-5-基、双环[2.2.1]庚-2-基(降冰片基)、金刚烷-1-基和金刚烷-2-基。
在取代的环烷基的情况下，还包括螺环脂族体系，例如螺[2.2]戊-1-基、螺[2.3]己-1-基、螺[2.3]己-4-基、3-螺[2.3]己-5-基。
环烯基表示具有优选4-8个碳原子的碳环、非芳族、部分不饱和的环系统，例如1-环丁烯基、2-环丁烯基、1-环戊烯基、2-环戊烯基、3-环戊烯基或1-环己烯基、2-环己烯基、3-环己烯基、1,3-环己二烯基或1,4-环己二烯基，还包括在环烯基基团上具有双键的取代基，例如亚烷基基团如亚甲基。在任选取代的环烯基的情况下，对取代的环烷基的说明相应地适用。
烷氧基表示具有分别指定的碳原子数的饱和直链或支链烷氧基基团，例如C1-C6-烷氧基，如甲氧基、乙氧基、丙氧基、1-甲基乙氧基、丁氧基、1-甲基丙氧基、2-甲基丙氧基、1,1-二甲基乙氧基、戊氧基、1-甲基丁氧基、2-甲基丁氧基、3-甲基丁氧基、2,2-二甲基丙氧基、1-乙基丙氧基、己氧基、1,1-二甲基丙氧基、1,2-二甲基丙氧基、1-甲基戊氧基、2-甲基戊氧基、3-甲基戊氧基、4-甲基戊氧基、1,1-二甲基丁氧基、1,2-二甲基丁氧基、1,3-二甲基丁氧基、2,2-二甲基丁氧基、2,3-二甲基丁氧基、3,3-二甲基丁氧基、1-乙基丁氧基、2-乙基丁氧基、1,1,2-三甲基丙氧基、1,2,2-三甲基丙氧基、1-乙基-1-甲基丙氧基和1-乙基-2-甲基丙氧基。卤素取代的烷氧基表示具有分别指定的碳原子数的直链或支链烷氧基基团，其中这些基团中的一些或全部氢原子可被替换为如上所指定的卤素原子，例如C1-C2-卤代烷氧基，如氯甲氧基、溴甲氧基、二氯甲氧基、三氯甲氧基、氟甲氧基、二氟甲氧基、三氟甲氧基、氯氟甲氧基、二氯氟甲氧基、氯二氟甲氧基、1-氯乙氧基、1-溴乙氧基、1-氟乙氧基、2-氟乙氧基、2,2-二氟乙氧基、2,2,2-三氟乙氧基、2-氯-2-氟乙氧基、2-氯-1,2-二氟乙氧基、2,2-二氯-2-氟乙氧基、2,2,2-三氯乙氧基、五氟乙氧基和1,1,1-三氟丙-2-氧基。
术语“芳基”表示具有优选6至14、尤其是6至10个环碳原子的任选取代的单环、双环或多环芳族体系，例如苯基、萘基、蒽基、菲基等，优选苯基。
术语“任选取代的芳基”还包括多环体系，如四氢萘基、茚基、茚满基、芴基、联苯基，其中键合位点在芳族体系上。在系统术语中，术语“任选取代的苯基”通常也涵盖“芳基”。
上面列出的芳基优选独立地被单取代至五取代，例如被氢、卤素、烷基、卤代烷基、羟基、烷氧基、环烷氧基、芳氧基、烷氧基烷基、烷氧基烷氧基、环烷基、卤代环烷基、芳基、芳基烷基、杂芳基、杂环基、烯基、烷基羰基、环烷基羰基、芳基羰基、杂芳基羰基、烷氧基羰基、羟基羰基、环烷氧基羰基、环烷基烷氧基羰基、烷氧基羰基烷基、芳基烷氧基羰基、芳基烷氧基羰基烷基、炔基、炔基烷基、烷基炔基、三烷基甲硅烷基炔基、硝基、氨基、氰基、卤代烷氧基、卤代烷硫基、烷硫基、氢硫基、羟烷基、杂芳基烷氧基、芳基烷氧基、杂环基烷氧基、杂环基烷硫基、杂环氧基、杂环硫基、杂芳氧基、双烷基氨基、烷基氨基、环烷基氨基、羟基羰基烷基氨基、烷氧基羰基烷基氨基、芳基烷氧基羰基烷基氨基、烷氧基羰基烷基(烷基)氨基、氨基羰基、烷基氨基羰基、双烷基氨基羰基、环烷基氨基羰基、羟基羰基烷基氨基羰基、烷氧基羰基烷基氨基羰基、芳基烷氧基羰基烷基氨基羰基单取代至五取代。
杂环基团(杂环基)含有至少一个饱和、不饱和、部分饱和或杂芳族的杂环环(＝其中至少一个碳原子已被替换为杂原子、优选替换为选自N、O、S、P的杂原子的碳环环)并且可以是未取代的或取代的，在取代的情况下，键合位点位于环原子上。如果杂环基基团或杂环环是任选取代的，则其可与其他碳环或杂环环稠合。在任选取代的杂环基的情况下，还包括多环体系，例如8-氮杂双环[3.2.1]辛基、8-氮杂双环[2.2.2]辛基或1-氮杂双环[2.2.1]庚基。在任选取代的杂环基的情况下，还包括螺环体系，例如1-氧杂-5-氮杂螺[2.3]己基。除非另有定义，否则杂环环在杂环环中优选含有3至9个环原子、尤其是3至6个环原子，和一个或多个、优选地1至4个、尤其是1、2或3个优选选自N、O和S的杂原子，但不应有两个氧原子例如与来自N、O和S的一个杂原子直接相邻：1-或2-或3-吡咯烷基、3,4-二氢-2H-吡咯-2-或3-基、2,3-二氢-1H-吡咯-1-或2-或3-或4-或5-基；2,5-二氢-1H-吡咯-1-或2-或3-基、1-或2-或3-或4-哌啶基；2,3,4,5-四氢吡啶-2-或3-或4-或5-基或6-基；1,2,3,6-四氢吡啶-1-或2-或3-或4-或5-或6-基；1,2,3,4-四氢吡啶-1-或2-或3-或4-或5-或6-基；1,4-二氢吡啶-1-或2-或3-或4-基；2,3-二氢吡啶-2-或3-或4-或5-或6-基；2,5-二氢吡啶-2-或3-或4-或5-或6-基、1-或2-或3-或4-氮杂环庚烷基；2,3,4,5-四氢-1H-氮杂
-1-或2-或3-或4-或5-或6-或7-基；2,3,4,7-四氢-1H-氮杂
-1-或2-或3-或4-或5-或6-或7-基；2,3,6,7-四氢-1H-氮杂
-1-或2-或3-或4-基；3,4,5,6-四氢-2H-氮杂
-2-或3-或4-或5-或6-或7-基；4,5-二氢-1H-氮杂
-1-或2-或3-或4-基；2,5-二氢-1H-氮杂
-1-或-2-或3-或4-或5-或6-或7-基；2,7-二氢-1H-氮杂
-1-或-2-或3-或4-基；2,3-二氢-1H-氮杂
-1-或-2-或3-或4-或5-或6-或7-基；3,4-二氢-2H-氮杂
-2-或3-或4-或5-或6-或7-基；3,6-二氢-2H-氮杂
-2-或3-或4-或5-或6-或7-基；5,6-二氢-2H-氮杂
-2-或3-或4-或5-或6-或7-基；4,5-二氢-3H-氮杂
-2-或3-或4-或5-或6-或7-基；1H-氮杂
-1-或-2-或3-或4-或5-或6-或7-基；2H-氮杂
-2-或3-或4-或5-或6-或7-基；3H-氮杂
-2-或3-或4-或5-或6-或7-基；4H-氮杂
-2-或3-或4-或5-或6-或7-基、2-或3-氧杂环戊烷基(＝2-或3-四氢呋喃基)；2,3-二氢呋喃-2-或3-或4-或5-基；2,5-二氢呋喃-2-或3-基、2-或3-或4-噁烷基(＝2-或3-或4-四氢吡喃基)；3,4-二氢-2H-吡喃-2-或3-或4-或5-或6-基；3,6-二氢-2H-吡喃-2-或3-或4-或5-或6-基；2H-吡喃-2-或3-或4-或5-或6-基；4H-吡喃-2-或3-或4-基、2-或3-或4-氧杂环庚烷基；2,3,4,5-四氢氧杂
-2-或3-或4-或5-或6-或7-基；2,3,4,7-四氢氧杂
-2-或3-或4-或5-或6-或7-基；2,3,6,7-四氢氧杂
-2-或3-或4-基；2,3-二氢氧杂
-2-或3-或4-或5-或6-或7-基；4,5-二氢氧杂
-2-或3-或4-基；2,5-二氢氧杂
-2-或3-或4-或5-或6-或7-基；氧杂
-2-或3-或4-或5-或6-或7-基；2-或3-四氢噻吩基；2,3-二氢噻吩-2-或3-或4-或5-基；2,5-二氢噻吩-2-或3-基；四氢-2H-噻喃-2-或3-或4-基；3,4-二氢-2H-噻喃-2-或3-或4-或5-或6-基；3,6-二氢-2H-噻喃-2-或3-或4-或5-或6-基；2H-噻喃-2-或3-或4-或5-或6-基；4H-噻喃-2-或3-或4-基。优选的3-元和4-元杂环有例如1-或2-氮杂环丙基、氧杂环丙烷基、硫杂环丙烷基、1-或2-或3-氮杂环丁烷基、2-或3-氧杂环丁烷基、2-或3-硫杂环丁烷基、1,3-二氧杂环丁烷-2-基。“杂环基”的更多实例有具有两个选自N、O和S的杂原子的部分或完全氢化杂环基团，例如，1-或2-或3-或4-吡唑烷基；4,5-二氢-3H-吡唑-3-或4-或5-基；4,5-二氢-1H-吡唑-1-或3-或4-或5-基；2,3-二氢-1H-吡唑-1-或2-或3-或4-或5-基；1-或2-或3-或4-咪唑烷基；2,3-二氢-1H-咪唑-1-或2-或3-或4-基；2,5-二氢-1H-咪唑-1-或2-或4-或5-基；4,5-二氢-1H-咪唑-1-或2-或4-或5-基；六氢哒嗪-1-或2-或3-或4-基；1,2,3,4-四氢哒嗪-1-或2-或3-或4-或5-或6-基；1,2,3,6-四氢哒嗪-1-或2-或3-或4-或5-或6-基；1,4,5,6-t四氢哒嗪-1-或3-或4-或5-或6-基；3,4,5,6-四氢哒嗪-3-或4-或5-基；4,5-二氢哒嗪-3-或4-基；3,4-二氢哒嗪-3-或4-或5-或6-基；3,6-二氢哒嗪-3-或4-基；1,6-二氢哒嗪-1-或3-或4-或5-或6-基；六氢嘧啶-1-或2-或3-或4-基；1,4,5,6-四氢嘧啶-1-或2-或4-或5-或6-基；1,2,5,6-四氢嘧啶-1-或2-或4-或5-或6-基；1,2,3,4-四氢嘧啶-1-或2-或3-或4-或5-或6-基；1,6-二氢嘧啶-1-或2-或4-或5-或6-基；1,2-二氢嘧啶-1-或2-或4-或5-或6-基；2,5-二氢嘧啶-2-或4-或5-基；4,5-二氢嘧啶-4-或5-或6-基；1,4-二氢嘧啶-1-或2-或4-或5-或6-基；1-或2-或3-哌嗪基；1,2,3,6-四氢吡嗪-1-或2-或3-或5-或6-基；1,2,3,4-四氢吡嗪-1-或2-或3-或4-或5-或6-基；1,2-二氢吡嗪-1-或2-或3-或5-或6-基；1,4-二氢吡嗪-1-或2-或3-基；2,3-二氢吡嗪-2-或3-或5-或6-基；2,5-二氢吡嗪-2-或3-基；1,3-二氧杂环戊烷-2-或4-或5-基；1,3-间二氧杂环戊烯-2-或4-基；1,3-二噁烷-2-或4-或5-基；4H-1,3-二噁英-2-或4-或5-或6-基；1,4-二噁烷-2-或3-或5-或6-基；2,3-二氢-1,4-二噁英-2-或3-或5-或6-基；1,4-二噁英-2-或3-基；1,2-二硫杂环戊烷-3-或4-基；3H-1,2-二硫杂环戊二烯-3-或4-或5-基；1,3-二硫杂环戊烷-2-或4-基；1,3-二硫杂环戊二烯-2-或4-基；1,2-二噻烷-3-或4-基；3,4-二氢-1,2-二噻烯-3-或4-或5-或6-基；3,6-二氢-1,2-二噻烯-3-或4-基；1,2-二噻烯-3-或4-基；1,3-二噻烷-2-或4-或5-基；4H-1,3-二噻烯-2-或4-或5-或6-基；异噁唑烷-2-或3-或4-或5-基；2,3-二氢异噁唑-2-或3-或4-或5-基；2,5-二氢异噁唑-2-或3-或4-或5-基；4,5-二氢异噁唑-3-或4-或5-基；1,3-噁唑烷-2-或3-或4-或5-基；2,3-二氢-1,3-噁唑-2-或3-或4-或5-基；2,5-二氢-1,3-噁唑-2-或4-或5-基；4,5-二氢-1,3-噁唑-2-或4-或5-基；1,2-噁嗪烷-2-或3-或4-或5-或6-基；3,4-二氢-2H-1,2-噁嗪-2-或3-或4-或5-或6-基；3,6-二氢-2H-1,2-噁嗪-2-或3-或4-或5-或6-基；5,6-二氢-2H-1,2-噁嗪-2-或3-或4-或5-或6-基；5,6-二氢-4H-1,2-噁嗪-3-或4-或5-或6-基；2H-1,2-噁嗪-2-或3-或4-或5-或6-基；6H-1,2-噁嗪-3-或4-或5-或6-基；4H-1,2-噁嗪-3-或4-或5-或6-基；1,3-噁嗪烷-2-或3-或4-或5-或6-基；3,4-二氢-2H-1,3-噁嗪-2-或3-或4-或5-或6-基；3,6-二氢-2H-1,3-噁嗪-2-或3-或4-或5-或6-基；5,6-二氢-2H-1,3-噁嗪-2-或4-或5-或6-基；5,6-二氢-4H-1,3-噁嗪-2-或4-或5-或6-基；2H-1,3-噁嗪-2-或4-或5-或6-基；6H-1,3-噁嗪-2-或4-或5-或6-基；4H-1,3-噁嗪-2-或4-或5-或6-基；吗啉-2-或3-或4-基；3,4-二氢-2H-1,4-噁嗪-2-或3-或4-或5-或6-基；3,6-二氢-2H-1,4-噁嗪-2-或3-或5-或6-基；2H-1,4-噁嗪-2-或3-或5-或6-基；4H-1,4-噁嗪-2-或3-基；1,2-氧氮杂环庚烷-2-或3-或4-或5-或6-或7-基；2,3,4,5-四氢-1,2-氧氮杂
-2-或3-或4-或5-或6-或7-基；2,3,4,7-四氢-1,2-氧氮杂
-2-或3-或4-或5-或6-或7-基；2,3,6,7-四氢-1,2-氧氮杂
-2-或3-或4-或5-或6-或7-基；2,5,6,7-四氢-1,2-氧氮杂
-2-或3-或4-或5-或6-或7-基；4,5,6,7-四氢-1,2-氧氮杂
-3-或4-或5-或6-或7-基；2,3-二氢-1,2-氧氮杂
-2-或3-或4-或5-或6-或7-基；2,5-二氢-1,2-氧氮杂
-2-或3-或4-或5-或6-或7-基；2,7-二氢-1,2-氧氮杂
-2-或3-或4-或5-或6-或7-基；4,5-二氢-1,2-氧氮杂
-3-或4-或5-或6-或7-基；4,7-二氢-1,2-氧氮杂
-3-或4-或5-或6-或7-基；6,7-二氢-1,2-氧氮杂
-3-或4-或5-或6-或7-基；1,2-氧氮杂
-3-或4-或5-或6-或7-基；1,3-氧氮杂环庚烷-2-或3-或4-或5-或6-或7-基；2,3,4,5-四氢-1,3-氧氮杂
-2-或3-或4-或5-或6-或7-基；2,3,4,7-四氢-1,3-氧氮杂
-2-或3-或4-或5-或6-或7-基；2,3,6,7-四氢-1,3-氧氮杂
-2-或3-或4-或5-或6-或7-基；2,5,6,7-四氢-1,3-氧氮杂
-2-或4-或5-或6-或7-基；4,5,6,7-四氢-1,3-氧氮杂
-2-或4-或5-或6-或7-基；2,3-二氢-1,3-氧氮杂
-2-或3-或4-或5-或6-或7-基；2,5-二氢-1,3-氧氮杂
-2-或4-或5-或6-或7-基；2,7-二氢-1,3-氧氮杂
-2-或4-或5-或6-或7-基；4,5-二氢-1,3-氧氮杂
-2-或4-或5-或6-或7-基；4,7-二氢-1,3-氧氮杂
-2-或4-或5-或6-或7-基；6,7-二氢-1,3-氧氮杂
-2-或4-或5-或6-或7-基；1,3-氧氮杂
-2-或4-或5-或6-或7-基；1,4-氧氮杂环庚烷-2-或3-或5-或6-或7-基；2,3,4,5-四氢-1,4-氧氮杂
-2-或3-或4-或5-或6-或7-基；2,3,4,7-四氢-1,4-氧氮杂
-2-或3-或4-或5-或6-或7-基；2,3,6,7-四氢-1,4-氧氮杂
-2-或3-或5-或6-或7-基；2,5,6,7-四氢-1,4-氧氮杂
-2-或3-或5-或6-或7-基；4,5,6,7-四氢-1,4-氧氮杂
-2-或3-或4-或5-或6-或7-基；2,3-二氢-1,4-氧氮杂
-2-或3-或5-或6-或7-基；2,5-二氢-1,4-氧氮杂
-2-或3-或5-或6-或7-基；2,7-二氢-1,4-氧氮杂
-2-或3-或5-或6-或7-基；4,5-二氢-1,4-氧氮杂
-2-或3-或4-或5-或6-或7-基；4,7-二氢-1,4-氧氮杂
-2-或3-或4-或5-或6-或7-基；6,7-二氢-1,4-氧氮杂
-2-或3-或5-或6-或7-基；1,4-氧氮杂
-2-或3-或5-或6-或7-基；异噻唑烷-2-或3-或4-或5-基；2,3-二氢异噻唑-2-或3-或4-或5-基；2,5-二氢异噻唑-2-或3-或4-或5-基；4,5-二氢异噻唑-3-或4-或5-基；1,3-噻唑烷-2-或3-或4-或5-基；2,3-二氢-1,3-噻唑-2-或3-或4-或5-基；2,5-二氢-1,3-噻唑-2-或4-或5-基；4,5-二氢-1,3-噻唑-2-或4-或5-基；1,3-噻嗪烷-2-或3-或4-或5-或6-基；3,4-二氢-2H-1,3-噻嗪-2-或3-或4-或5-或6-基；3,6-二氢-2H-1,3-噻嗪-2-或3-或4-或5-或6-基；5,6-二氢-2H-1,3-噻嗪-2-或4-或5-或6-基；5,6-二氢4H-1,3-噻嗪-2-或4-或5-或6-基；2H-1,3-四氢-2-或4-或5-或6-基；6H-1,3-噻嗪-2-或4-或5-或6-基；4H-1,3-噻嗪-2-或4-或5-或6-基。“杂环基”的更多实例有具有3个选自N、O和S的杂原子的部分或完全氢化杂环基团，例如，1,4,2-二噁唑烷-2-或3-或5-基；1,4,2-二噁唑-3-或5-基；1,4,2-二噁嗪烷-2-或-3-或5-或6-基；5,6-二氢-1,4,2-二噁嗪-3-或5-或6-基；1,4,2-二噁嗪-3-或5-或6-基；1,4,2-二氧氮杂环庚烷-2-或3-或5-或6-或7-基；6,7-二氢-5H-1,4,2-二氧氮杂
-3-或5-或6-或7-基；2,3-二氢-7H-1,4,2-二氧氮杂
-2-或3-或5-或6-或7-基；2,3-二氢-5H-1,4,2-二氧氮杂
-2-或3-或5-或6-或7-基；5H-1,4,2-二氧氮杂
-3-或5-或6-或7-基；7H-1,4,2-二氧氮杂
-3-或5-或6-或7-基。
上面列出的杂环优选独立地被单取代至六取代，例如被氢、卤素、烷基、卤代烷基、羟基、烷氧基、环烷氧基、芳氧基、烷氧基烷基、烷氧基烷氧基、环烷基、卤代环烷基、芳基、芳基烷基、杂芳基、杂环基、烯基、烷基羰基、环烷基羰基、芳基羰基、杂芳基羰基、烷氧基羰基、羟基羰基、环烷氧基羰基、环烷基烷氧基羰基、烷氧基羰基烷基、芳基烷氧基羰基、芳基烷氧基羰基烷基、炔基、炔基烷基、烷基炔基、三烷基甲硅烷基炔基、硝基、氨基、氰基、卤代烷氧基、卤代烷硫基、烷硫基、氢硫基、羟烷基、氧代、杂芳基烷氧基、芳基烷氧基、杂环基烷氧基、杂环基烷硫基、杂环氧基、杂环硫基、杂芳氧基、双烷基氨基、烷基氨基、环烷基氨基、羟基羰基烷基氨基、烷氧基羰基烷基氨基、芳基烷氧基羰基烷基氨基、烷氧基羰基烷基(烷基)氨基、氨基羰基、烷基氨基羰基、双烷基氨基羰基、环烷基氨基羰基、羟基羰基烷基氨基羰基、烷氧基羰基烷基氨基羰基、芳基烷氧基羰基烷基氨基羰基单取代至六取代。
当基础结构被选自基团列表或一般定义的基团组的“一个或多个基团”所取代时，这分别都包括同时被多个相同和/或结构上不同的基团取代。
在部分或完全饱和的氮杂环的情况下，这可经由碳或经由氮与分子的其余部分连接。
取代的杂环基团的合适取代基有下面进一步指定的取代基，另外还有氧代和硫代。作为环碳原子上的取代基的氧代基团则为例如杂环环中的羰基基团。因此，优选还包括内酯和内酰胺。氧代基团也可出现在环杂原子上，其可以不同的氧化态存在，例如在N和S的情况下，并且在该情况下形成例如杂环环中的二价-N(O)-、-S(O)-(也简称为SO)和S(O)2(也简称为SO2)基团。在-N(O)-和-S(O)-基团的情况下，两种对映异构体分别包括在内。
根据本发明，表述“杂芳基”代表杂芳族化合物，即完全不饱和的芳族杂环化合物，优选地具有1至4个、优选1或2个相同或不同的杂原子(优选地，O、S或N)的5-至7-元环。本发明的杂芳基有例如1H-吡咯-1-基；1H-吡咯-2-基；1H-吡咯-3-基；呋喃-2-基；呋喃-3-基；噻吩-2-基；噻吩-3-基；1H-咪唑-1-基；1H-咪唑-2-基；1H-咪唑-4-基；1H-咪唑-5-基；1H-吡唑-1-基；1H-吡唑-3-基；1H-吡唑-4-基；1H-吡唑-5-基、1H-1,2,3-三唑-1-基、1H-1,2,3-三唑-4-基、1H-1,2,3-三唑-5-基、2H-1,2,3-三唑-2-基、2H-1,2,3-三唑-4-基、1H-1,2,4-三唑-1-基、1H-1,2,4-三唑-3-基、4H-1,2,4-三唑-4-基、1,2,4-噁二唑-3-基、1,2,4-噁二唑-5-基、1,3,4-噁二唑-2-基、1,2,3-噁二唑-4-基、1,2,3-噁二唑-5-基、1,2,5-噁二唑-3-基、氮杂
基、吡啶-2-基、吡啶-3-基、吡啶-4-基、吡嗪-2-基、吡嗪-3-基、嘧啶-2-基、嘧啶-4-基、嘧啶-5-基、哒嗪-3-基、哒嗪-4-基、1,3,5-三嗪-2-基、1,2,4-三嗪-3-基、1,2,4-三嗪-5-基、1,2,4-三嗪-6-基、1,2,3-三嗪-4-基、1,2,3-三嗪-5-基、1,2,4-、1,3,2-、1,3,6-和1,2,6-噁嗪基、异噁唑-3-基、异噁唑-4-基、异噁唑-5-基、1,3-噁唑-2-基、1,3-噁唑-4-基、1,3-噁唑-5-基、异噻唑-3-基、异噻唑-4-基、异噻唑-5-基、1,3-噻唑-2-基、1,3-噻唑-4-基、1,3-噻唑-5-基、氧杂
基、噻平基、1,2,4-三唑酮基和1,2,4-二氮杂
基、2H-1,2,3,4-四唑-5-基、1H-1,2,3,4-四唑-5-基、1,2,3,4-噁三唑-5-基、1,2,3,4-噻三唑-5-基、1,2,3,5-噁三唑-4-基、1,2,3,5-噻三唑-4-基。本发明的杂芳基基团也可被一个或多个相同或不同的基团所取代。如果两个相邻的碳原子为另一个芳族环的一部分，则该体系为稠合的杂芳族体系，如苯并稠合的或多重稠合的杂芳族化合物。
优选的实例是喹啉类(例如，喹啉-2-基、喹啉-3-基、喹啉-4-基、喹啉-5-基、喹啉-6-基、喹啉-7-基、喹啉-8-基)；异喹啉类(例如，异喹啉-1-基、异喹啉-3-基、异喹啉-4-基、异喹啉-5-基、异喹啉-6-基、异喹啉-7-基、异喹啉-8-基)；喹喔啉；喹唑啉；噌啉；1,5-萘啶；1,6-萘啶；1,7-萘啶；1,8-萘啶；2,6-萘啶；2,7-萘啶；酞嗪；吡啶并吡嗪类；吡啶并嘧啶类；吡啶并哒嗪类；蝶啶类；嘧啶并嘧啶类。杂芳基的实例还有选自以下的5-或6-元苯并稠合环：1H-吲哚-1-基、1H-吲哚-2-基、1H-吲哚-3-基、1H-吲哚-4-基、1H-吲哚-5-基、1H-吲哚-6-基、1H-吲哚-7-基、1-苯并呋喃-2-基、1-苯并呋喃-3-基、1-苯并呋喃-4-基、1-苯并呋喃-5-基、1-苯并呋喃-6-基、1-苯并呋喃-7-基、1-苯并噻吩-2-基、1-苯并噻吩-3-基、1-苯并噻吩-4-基、1-苯并噻吩-5-基、1-苯并噻吩-6-基、1-苯并噻吩-7-基、1H-吲唑-1-基、1H-吲唑-3-基、1H-吲唑-4-基、1H-吲唑-5-基、1H-吲唑-6-基、1H-吲唑-7-基、2H-吲唑-2-基、2H-吲唑-3-基、2H-吲唑-4-基、2H-吲唑-5-基、2H-吲唑-6-基、2H-吲唑-7-基、2H-异吲哚-2-基、2H-异吲哚-1-基、2H-异吲哚-3-基、2H-异吲哚-4-基、2H-异吲哚-5-基、2H-异吲哚-6-基、2H-异吲哚-7-基、1H-苯并咪唑-1-基、1H-苯并咪唑-2-基、1H-苯并咪唑-4-基、1H-苯并咪唑-5-基、1H-苯并咪唑-6-基、1H-苯并咪唑-7-基、1,3-苯并噁唑-2-基、1,3-苯并噁唑-4-基、1,3-苯并噁唑-5-基、1,3-苯并噁唑-6-基、1,3-苯并噁唑-7-基、1,3-苯并噻唑-2-基、1,3-苯并噻唑-4-基、1,3-苯并噻唑-5-基、1,3-苯并噻唑-6-基、1,3-苯并噻唑-7-基、1,2-苯并异噁唑-3-基、1,2-苯并异噁唑-4-基、1,2-苯并异噁唑-5-基、1,2-苯并异噁唑-6-基、1,2-苯并异噁唑-7-基、1,2-苯并异噻唑-3-基、1,2-苯并异噻唑-4-基、1,2-苯并异噻唑-5-基、1,2-苯并异噻唑-6-基、1,2-苯并异噻唑-7-基。
优选彼此独立地，上面列出的杂芳基优选被单取代至四取代，例如被氢、卤素、烷基、卤代烷基、羟基、烷氧基、环烷氧基、芳氧基、烷氧基烷基、烷氧基烷氧基、环烷基、卤代环烷基、芳基、芳基烷基、杂芳基、杂环基、烯基、烷基羰基、环烷基羰基、芳基羰基、杂芳基羰基、烷氧基羰基、羟基羰基、环烷氧基羰基、环烷基烷氧基羰基、烷氧基羰基烷基、芳基烷氧基羰基、芳基烷氧基羰基烷基、炔基、炔基烷基、烷基炔基、三烷基甲硅烷基炔基、硝基、氨基、氰基、卤代烷氧基、卤代烷硫基、烷硫基、氢硫基、羟烷基、氧代、杂芳基烷氧基、芳基烷氧基、杂环基烷氧基、杂环基烷硫基、杂环氧基、杂环硫基、杂芳氧基、双烷基氨基、烷基氨基、环烷基氨基、羟基羰基烷基氨基、烷氧基羰基烷基氨基、芳基烷氧基羰基烷基氨基、烷氧基羰基烷基(烷基)氨基、氨基羰基、烷基氨基羰基、双烷基氨基羰基、环烷基氨基羰基、羟基羰基烷基氨基羰基、烷氧基羰基烷基氨基羰基、芳基烷氧基羰基烷基氨基羰基单取代至四取代。
术语“卤素”指的是氟、氯、溴或碘。如果该术语用于基团，则“卤素”是指氟-、氯-、溴-或碘原子。
根据取代基的类型和它们连接的方式，式(I)的化合物可以立体异构体存在。例如，如果存在一个或多个不对称取代的碳原子和/或亚砜，则可能出现对映异构体和非对映异构体。立体异构体可从制备中获得的混合物通过惯用分离方法获得，例如通过色谱分离过程获得。同样可以通过使用采用光学活性原料和/或助剂的立体选择性反应选择性地制备立体异构体。
本发明还涉及由式(I)涵盖但未明确定义的所有立体异构体及其混合物。然而，为了简单起见，下文将始终提及式(I)的化合物，但这不仅指纯化合物，而且任选地还指具有不同比例的异构化合物的混合物。
根据以上定义的取代基的类型，式(I)的化合物具有酸性性质并可与无机或有机碱或与金属离子形成盐，任选地还可形成内盐或加合物。如果式(I)的化合物带有羟基、羧基或其他诱导酸性性质的基团，则这些化合物可与碱反应得到盐。合适的碱有例如碱金属和碱土金属的氢氧化物、碳酸盐、碳酸氢盐，尤其是钠、钾、镁和钙的氢氧化物、碳酸盐、碳酸氢盐，及此外氨、具有(C1-C4)-烷基基团的伯胺、仲胺和叔胺、(C1-C4)-烷醇的单-、二-和三烷醇胺、胆碱和氯胆碱，以及有机胺，如三烷基胺、吗啉、哌啶或吡啶。这些盐为其中酸性氢被替换为农业上合适的阳离子的化合物，例如金属盐，尤其是碱金属盐或碱土金属盐，尤其是钠盐和钾盐，抑或是铵盐、与有机胺的盐或季铵盐，例如具有式[NRR′R″R″′]+的阳离子，其中R至R″′分别彼此独立地为有机基团，尤其是烷基、芳基、芳烷基或烷基芳基。还合适的有烷基锍和烷基氧化锍盐，如(C1-C4)-三烷基锍-和(C1-C4)-三烷基氧化锍盐。
式(I)的化合物可通过向碱性基团例如氨基、烷基氨基、二烷基氨基、哌啶基、吗啉基或吡啶基上加合合适的无机或有机酸来形成盐，例如无机酸，例如HCl、HBr、H2SO4、H3PO4或HNO3，或有机酸，例如羧酸如甲酸、乙酸、丙酸、草酸、乳酸或水杨酸或磺酸，例如对甲苯磺酸。在这样的情况下，这些盐包含酸的共轭碱作为阴离子。
以去质子化形式存在的合适的取代基，例如磺酸或羧酸，可与其部分可被质子化的基团如氨基基团形成内盐。
如果基团被基团多取代，则这意味着该基团被一个或多个与所提及的那些相同或不同的基团所取代。
在下文指定的所有式中，除非另有不同定义，否则取代基和符号具有与除草剂(A)的通式(I)中所述相同的含义。化学式中的箭头表示其与分子的其余部分的连接点。
下面描述如上所示通式(I)的除草剂(A)的各个取代基中的每一个的优选、更优选和甚至更优选的含义。下文未指定的通式(I)的除草剂(A)的其他取代基具有上文给出的定义。
在本发明的第一实施方案中，
R1和R2优选分别彼此独立地为氢、氟、氯或氰基，或者为(C1-C3)-烷基或(C1-C3)-烷氧基，其分别被m个选自氟、氯、溴和氰基的基团所取代。
特别优选地，R1和R2分别彼此独立地为氢、氟、氯或氰基，或者为甲基或甲氧基，其分别被m个选自氟和氯的基团所取代。
最优选地，R1和R2分别为氢。
在本发明的第二实施方案中，
R3优选为氰基，或者(C1-C4)-烷基、(C3-C5)-环烷基、(C2-C4)-烯基、(C2-C4)-炔基或(C1-C4)-烷氧基，其分别被m个选自氟、氯、溴、氰基、(C1-C4)-烷氧基和羟基的基团所取代。
特别优选地，R3为(C1-C3)-烷基、(C3-C4)-环烷基、(C2-C3)-烯基或(C1-C3)-烷氧基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代。
在本发明的第三实施方案中，
R4优选为氢，或者(C1-C6)-烷基、(C3-C6)-环烷基、(C3-C6)-环烷基-(C1-C6)-烷基、(C2-C6)-烯基、(C5-C6)-环烯基或(C2-C6)-炔基，其分别被m个选自氟、氯、溴、氰基、(C1-C4)-烷氧基、羟基和芳基的基团所取代。
优选地，R4为氢，或者(C1-C3)-烷基或(C2-C6)-烯基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代。
在本发明的第四实施方案中，Y为氧。
在本发明的第五实施方案中，W为氧。
在本发明的第六实施方案中，
Z优选为Z-1至Z-22基团，其中Z-1至Z-22如下定义：
其中箭头分别代表朝向式(I)的基团C＝W的键。
特别优选地，Z为Z-1至Z-12基团，其中Z-1至Z-12如下定义：
其中箭头分别代表朝向式(I)的基团C＝W的键。
最优选地，Z为Z-1、Z-4和Z-6：
其中箭头分别代表朝向式(I)的基团C＝W的键。
在本发明的第七实施方案中，
R10优选为氟、氯、氰基、CO2H、CO2CH3或CO2CH2CH3、或(C1-C2)-烷基或(C1-C2)-烷氧基，其分别被m个选自氟和氯的基团所取代。
在本发明的第八实施方案中，
R11优选为氢，或者(C1-C3)-烷基或(C3-C6)-环烷基，其分别被m个选自氟和氯的基团所取代。
特别优选地，R11为氢或(C1-C3)-烷基。
最优选地，R11为氢。
在本发明的第九实施方案中，
R12优选为氢、氰基、OR7、S(O)n R5、SO2NR6R7、COR6、NR6R8、NR6COR8或NR6SO2R8、或(C1-C6)-烷基、(C3-C6)-环烷基、(C2-C3)-烯基或(C2-C3)-炔基，其分别被m个选自氟、氯、溴、氰基、OR7、S(O)nR5、NR6R8和NR6CO2R8的基团所取代。
特别优选地，R12为OR7、S(O)nR5、SO2NR6R7或分别被m个选自氟、氯、氰基、OR7和S(O)nR5的基团所取代的(C1-C6)-烷基。
在本发明的第十实施方案中，
R11和R12与它们所键合至的氮原子一起优选地形成饱和的、部分或完全不饱和的五-、六-或七-元环，所述环任选被选自卤素、氰基、硝基、(C1-C6)-烷基、卤代-(C1-C6)-烷基、氧代、OR7、S(O)nR5、CO2R8、COR6、NR6COR8和NR6SO2R8的基团单取代至六取代，并且除了该氮原子外，所述环还含有r个碳原子、o个氧原子、p个硫原子和q个选自NR7和NCOR7的要素作为环原子。
特别优选地，R11和R12与它们所键合至的氮原子一起形成饱和的、部分或完全不饱和的五-、六-或七-元环，所述环任选被选自卤素、氰基、硝基、(C1-C6)-烷基、卤代-(C1-C6)-烷基、氧代、OR7、CO2R8和NR6SO2R8的基团单取代至六取代，并且除了该氮原子外，所述环还含有r个碳原子、o个氧原子、p个硫原子和q个选自NR7和NCOR7的要素作为环原子。
最优选地，R11和R12与它们所键合至的氮原子一起形成饱和的、部分或完全不饱和的五-或六-元环，所述环任选被选自卤素、(C1-C6)-烷基、卤代-(C1-C6)-烷基和氧代的基团单取代至三取代，并且除了该氮原子外，所述环还含有r个碳原子、o个氧原子、p个硫原子和q个选自NR7和NCOR7的要素作为环原子。
在本发明的第十一实施方案中，
X2、X4和X6优选分别彼此独立地为氢、氟、氯、溴或氰基，或者为甲基或甲氧基，其分别被m个选自氟和氯的基团所取代。
特别优选地，X2、X4和X6独立地为氢或氟。
最优选地，X2、X4和X6为氢。
在本发明的第十二实施方案中，
X3和X5优选分别彼此独立地为氢、氟、氯、溴、羟基或氰基，或者为(C1-C3)-烷基、(C1-C3)-烷氧基、(C3-C4)-环烷基、(C2-C3)-烯基或(C2-C3)-炔基，其分别被m个选自氟、氯和溴的基团所取代。
特别优选地，X3和X5分别彼此独立地为氢、氟、氯、氰基、CF3、CHF2或甲基。
最优选地，X3和X5分别彼此独立地为氢、氟、氰基或甲基。
更最优选地，X3和X5分别为氟。
在本发明的第十三实施方案中，
R5优选为(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟和氯的基团所取代。
在本发明的第十四实施方案中，
R7优选为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代。
在本发明的第十五实施方案中，
R8优选为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代。
在本发明的第十六实施方案中，
m优选为数字0、1、2或3。
在本发明的上下文中，取代基R1至R8、R10至R12、X2至X6、W、Y和Z及数字k、m、n、o、p、q和r的单独的优选、特别优选和最优选定义可根据需要彼此组合。
这意味着本发明涵盖这样的通式(I)的化合物，其中，例如，取代基R1具有优选的定义而取代基R5至R7具有一般的定义，抑或取代基R2具有优选的定义、取代基R3具有更优选或甚至更优选的定义而其余的取代基具有一般的定义。
下面通过实例示意了上文对取代基R1至R8、R10至R12、X2至X6、W、Y和Z及对数字k、m、n、o、p、q和r给出的定义的这些组合中的六个，并且它们中的每一个作为进一步的实施方案公开：
在本发明的第十七实施方案中，
G为式OR4的基团；
R1和R2分别彼此独立地为氢、氟、氯或氰基，或者为(C1-C3)-烷基或(C1-C3)-烷氧基，其分别被m个选自氟、氯、溴和氰基的基团所取代；
R3为氰基，或者(C1-C3)-烷基、(C3-C4)-环烷基、(C2-C3)-烯基、(C2-C3)-炔基或(C1-C3)-烷氧基，其分别被m个选自氟、氯、溴、氰基、(C1-C2)-烷氧基和羟基的基团所取代；
R4为氢，或者(C1-C6)-烷基、(C3-C6)-环烷基、(C3-C6)-环烷基-(C1-C6)-烷基、(C2-C6)-烯基、(C5-C6)-环烯基或(C2-C6)-炔基，其分别被m个选自氟、氯、溴、氰基、(C1-C4)-烷氧基、羟基和芳基的基团所取代；
Y为氧；
W为氧；
Z为Z-1至Z-12基团，其中Z-1至Z-12如下定义：
其中箭头分别代表朝向式(I)的基团C＝W的键；
X2、X4和X6分别彼此独立地为氢、氟、氯、溴或氰基，或者为甲基或甲氧基，其分别被m个选自氟和氯的基团所取代；
X3和X5分别彼此独立地为氢、氟、氰基或甲基；和
m为数字0、1、2或3。
在本发明的第十八实施方案中，
G为式OR4的基团；
R1和R2分别为氢；
R3为(C1-C3)-烷基、(C3-C4)-环烷基、(C2-C3)-烯基或(C1-C3)-烷氧基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R4为氢，或者(C1-C3)-烷基或(C2-C4)-烯基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
Y为氧；
W为氧；
Z为基团Z-1、Z-4和Z-6：
其中箭头分别代表朝向式(I)的基团C＝W的键；
X2、X4和X6分别彼此独立地为氢或氟；
X3和X5分别彼此独立地为氢、氟、氰基或甲基；和
m为数字0、1、2或3。
在本发明的第十九实施方案中，
G为式OR4的基团；
R1和R2分别为氢；
R3为(C1-C3)-烷基、(C3-C4)-环烷基、(C2-C3)-烯基或(C1-C3)-烷氧基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R4为氢，或者(C1-C3)-烷基或(C2-C4)-烯基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
Y为氧；
W为氧；
Z为基团Z-1、Z-4和Z-6：
其中箭头分别代表朝向式(I)的基团C＝W的键；
X2、X4和X6分别为氢；
X3和X5分别为氟；和
m为数字0、1、2或3。
在本发明的第二十实施方案中，
G为式NR11R12的基团；
R1和R2分别彼此独立地为氢、氟、氯或氰基，或者为(C1-C3)-烷基或(C1-C3)-烷氧基，其分别被m个选自氟、氯、溴和氰基的基团所取代；
R3为氰基，或(C1-C3)-烷基、(C3-C4)-环烷基、(C2-C3)-烯基或(C1-C3)-烷氧基，其分别被m个选自氟、氯、溴、氰基、(C1-C2)-烷氧基和羟基的基团所取代；
Y为氧；
W为氧；
Z为Z-1至Z-12基团，其中Z-1至Z-12如下定义：
其中箭头分别代表朝向式(I)的基团C＝W的键；
X2、X4和X6分别彼此独立地为氢、氟、氯、溴或氰基，或者为甲基或甲氧基，其分别被m个选自氟和氯的基团所取代；
X3和X5分别彼此独立地为氢、氟、氰基或甲基；和
R5为(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟和氯的基团所取代；
R6为氢或R5；
R7为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R8为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R11为氢，或者(C1-C3)-烷基或(C3-C6)-环烷基，其分别被m个选自氟和氯的基团所取代；
R12优选为氢、氰基、OR7、S(O)n R5、SO2NR6R7、COR6、NR6R8、NR6COR8或NR6SO2R8、或(C1-C6)-烷基、(C3-C6)-环烷基、(C2-C3)-烯基或(C2-C3)-炔基，其分别被m个选自氟、氯、溴、氰基、OR7、S(O)nR5、NR6R8和NR6CO2R8的基团所取代；
或者
R11和R12与它们所附连至的氮原子一起形成饱和的、部分或完全不饱和的五-、六-或七-元环，所述环任选被选自卤素、氰基、硝基、(C1-C6)-烷基、卤代-(C1-C6)-烷基、氧代、OR7、CO2R8和NR6SO2R8的基团单取代至六取代，并且除了该氮原子外，所述环还含有r个碳原子、o个氧原子、p个硫原子和q个选自NR7和NCOR7的要素作为环原子；
m为数字0、1、2或3；
n为数字0、1或2；
o为数字0、1或2；
p为数字0或1；
q为数字0或1；和
r为数字3、4或5。
在本发明的第二十一实施方案中，
G为式NR11R12的基团；
R1和R2分别为氢；
R3为(C1-C3)-烷基、(C3-C4)-环烷基、(C2-C3)-烯基或(C1-C3)-烷氧基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
Y为氧；
W为氧；
Z为基团Z-1、Z-4和Z-6：
其中箭头分别代表朝向式(I)的基团C＝W的键；
X2、X4和X6分别彼此独立地为氢或氟；
X3和X5分别彼此独立地为氢、氟、氰基或甲基；
R5为(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟和氯的基团所取代；
R6为氢或R5；
R7为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R8为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R11为氢或(C1-C3)-烷基；
R12为OR7、S(O)nR5、SO2NR6R7或分别被m个选自氟、氯、氰基、OR7和S(O)nR5的基团所取代的(C1-C6)-烷基；
或者
R11和R12与它们所键合至的氮原子一起形成饱和的、部分或完全不饱和的五-或六-元环，所述环任选被选自卤素、(C1-C6)-烷基、卤代-(C1-C6)-烷基和氧代的基团单取代至三取代，并且除了该氮原子外，所述环还含有r个碳原子、o个氧原子、p个硫原子和q个选自NR7和NCOR7的要素作为环原子；
m为数字0、1、2或3；
n为数字0、1或2；
o为数字0、1或2；
p为数字0或1；
q为数字0或1；和
r为数字3、4或5。
在本发明的第二十二实施方案中，
G为式NR11R12的基团；
R1和R2分别为氢；
R3为(C1-C3)-烷基、(C3-C4)-环烷基、(C2-C3)-烯基或(C1-C3)-烷氧基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
Y为氧；
W为氧；
Z为基团Z-1、Z-4和Z-6：
其中箭头分别代表朝向式(I)的基团C＝W的键；
X2、X4和X6分别为氢；
X3和X5分别为氟；
R5为(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟和氯的基团所取代；
R6为氢或R5；
R7为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R8为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R11为氢；
R12为OR7、S(O)nR5、SO2NR6R7或分别被m个选自氟、氯、氰基、OR7和S(O)nR5的基团所取代的(C1-C6)-烷基；
或者
R11和R12与它们所键合至的氮原子一起形成饱和的、部分或完全不饱和的五-或六-元环，所述环任选被选自卤素、(C1-C6)-烷基、卤代-(C1-C6)-烷基和氧代的基团单取代至三取代，并且除了该氮原子外，所述环还含有r个碳原子、o个氧原子、p个硫原子和q个选自NR7和NCOR7的要素作为环原子；
m为数字0、1、2或3；
n为数字0、1或2；
o为数字0、1或2；
p为数字0或1；
q为数字0或1；和
r为数字3、4或5。
在本发明的第二十三实施方案中，所述除草组合物除了至少一种如上定义的组分(B)之外还优选包含(A)一种或多种根据表1的通式(I)的化合物[组分(A)][除草剂(A)]。
表1：优选的式(I)化合物(除草剂(A))的IUPAC名称和结构式
在表1中，化合物由主要组分的化学式标识，该组分以优选至少为化合物的重量的95％的化学纯度存在。化合物自然也可以较低的纯度使用。尤其是当化合物的次要组分完全或主要由相应化合物(A)的立体异构体组成时，在施用时将取得功效。优选的除草剂(A)因此也是两种或更多种本发明的化合物(A)的混合物。
当在表1中定义了碳原子处的立体化学取向时，化合物的主要组分为在所讨论的碳原子处具有R或S构型的立体异构体或立体异构体混合物。
如果没有定义立体化学，则该化合物为外消旋物。如果存在多个立体中心并且每个立体中心的构型被标识为R或S，则这些化合物是在所讨论的中心处具有所述的立体化学的化合物。
如果没有为多个中心指定R或S构型，则化合物为外消旋混合物，即其中存在的镜像立体异构体(一对对映异构体的对映异构体)以相等的比例存在于混合物中。除非特别说明，否则在表1中，在具有多个立体中心的外消旋化合物(A)的情况下，非对映异构体组分以近似相等的比例存在。然而，对于实际应用，在具有多个立体中心的外消旋化合物的情况下，存在具有不同比例的非对映异构体组分的非对映异构体混合物。
这里优选所列的相应化合物还以60％至100％、优选70-100％、尤其是80％至100％的立体化学纯度存在。
还优选立体异构化合物(A)的所列出的混合物。
式(I)的化合物可自申请PCT/EP2019/051333获知，该申请在本申请的优先权日尚未公开，并可通过其中描述的方法制备。
除草剂(A)的施用量在0.01至2000g活性物质每公顷(下文中，ga.i./ha)的范围内，优选0.02至1000g a.i./ha，尤其是0.5至750g a.i./ha。在本发明的组合中，在与单独施用相比提及的施用量范围内，相应活性成分的所需施用量通常较低，优选0.01至1000ga.i./ha，尤其是0.02至500g a.i./ha，和最优选5至250g a.i./ha。
合适的组合配对物(B)[＝组分(B)或除草剂(B)]原则上为来自亚组(B1)至(B11)的所有活性成分，其中除草活性成分主要根据参考文献"The Pesticide Manual"14thed.,British Crop Protection Council 2006(缩写为"PM")以其通用名称(在英语注释中)或者根据标准命名法(IUPAC或化学文摘)以其化学名称命名。
然而，已惊奇地发现一些除草剂(B)是特别好的组合配对物。优选的、特别优选的和最优选的除草剂(B)将在下文作为本发明的进一步的实施方案列出。
在本发明的第二十四实施方案中，优选除草活性成分(B1)：
(B1.2)双环吡喃酮，
(B1.4)烯草酮，
(B1.7)甲基磺草酮，
(B1.8)唑啉草酯，
(B1.10)烯禾啶，
(B1.11)磺草酮，
(B1.14)环磺酮，和
(B1.16)三甲苯草酮。
特别优选的是除草活性成分
(B1.7)甲基磺草酮，
(B1.8)唑啉草酯，和
(B1.14)环磺酮。
在本发明的第二十五实施方案中，优选除草活性成分(B2)：
(B2.1)乙草胺，
(B2.3)酰嘧磺隆，
(B2.4)磺草灵，
(B2.6)氟丁酰草胺，
(B2.10)氯嘧磺隆，
(B2.12)氯磺隆，
(B2.14)氯酯磺草胺，
(B2.17)双氯磺草胺，
(B2.18)吡氟草胺，
(B2.23)乙氧嘧磺隆，
(B2.24)啶嘧磺隆，
(B2.25)双氟磺草胺，
(B2.26)氟酮磺隆，
(B2.28)氟噻草胺，
(B2.29)唑嘧磺草胺，
(B2.30)氟啶嘧磺隆，
(B2.31)甲酰胺磺隆，
(B2.34)碘甲磺隆，
(B2.37)甲基二磺隆，
(B2.40)异丙甲草胺，
(B2.41)磺草唑胺，
(B2.42)甲磺隆，
(B2.46)五氟磺草胺，
(B2.49)氯吡酰草胺，
(B2.56)丙苯磺隆，
(B2.58)戊炔草胺，
(B2.59)苄草丹，
(B2.60)氟磺隆，
(B2.62)啶磺草胺，
(B2.63)砜嘧磺隆，
(B2.64)精异丙甲草胺，
(B2.65)嘧磺隆，
(B2.66)磺酰磺隆，
(B2.68)噻酮磺隆，
(B2.69)噻磺隆，
(B2.72)苯磺隆，
(B2.76)戊草丹
(B2.78)野麦畏。
特别优选
(B2.3)酰嘧磺隆，
(B2.18)吡氟草胺，
(B2.24)啶嘧磺隆，
(B2.25)双氟磺草胺，
(B2.26)氟酮磺隆，
(B2.28)氟噻草胺，
(B2.31)甲酰胺磺隆，
(B2.34)碘甲磺隆，
(B2.37)甲基二磺隆，
(B2.58)戊炔草胺，
(B2.68)噻酮磺隆，
(B2.69)噻磺隆，
(B2.72)苯磺隆。
在本发明的第二十六实施方案中，优选除草活性成分(B3)：
(B3.1)溴草腈，和
(B3.4)碘苯腈。
在本发明的第二十七实施方案中，优选除草活性成分(B4)：
(B4.2)杀草强，
(B4.8)快灭灵，
(B4.10)咪草酸，
(B4.11)甲氧咪草烟，
(B4.12)甲基咪草烟，
(B4.13)咪唑烟酸，
(B4.15)咪唑乙烟酸，
(B4.17)异噁草胺，
(B4.18)异噁唑草酮，
(B4.21)吡草醚，
(B4.22)磺酰草吡唑，
(B4.25)砜吡草唑，和
(B4.28)苯唑草酮，
(B4.33)氟胺草唑。
特别优选
(B4.18)异噁唑草酮，和
(B4.25)砜吡草唑，
(B4.22)磺酰草吡唑。
在本发明的第二十八实施方案中，优选除草活性成分(B5)：
(B5.1)环丙嘧啶酸，
(B5.2)氯氨吡啶酸，
(B5.3)氯噻草灵，
(B5.5)灭草松，
(B5.7)Bixlozone，
(B5.12)吲哚酮草酯，
(B5.13)环庚草醚，
(B5.14)异噁草松，
(B5.21)乙氧呋草黄，
(B5.22)异丙草氟安，
(B5.23)氯氟吡啶酯，
(B5.26)丙炔氟草胺，
(B5.27)氟啶草酮，
(B5.28)氟咯草酮，
(B5.29)呋草酮，
(B5.31)氟氯吡啶酸，
(B5.32)茚草酮，
(B5.37)对草快，
(B5.38)天竺葵酸，
(B5.39)二甲戊灵，
(B5.45)氟酮磺草胺和
(B5.46)氟乐灵，
(B5.47)4-氨基-3-氯-5-氟-6-(7-氟-1H-吲哚-6-基)吡啶-2-甲酸，
(B5.48)Cyclopyrimorate，
(B5.49)敌草快，
(B5.50)噁嗪草酮。
特别优选
(B5.7)Bixlozone，
(B5.23)氯氟吡啶酯，
(B5.31)氟氯吡啶酸，和
(B5.38)天竺葵酸。
在本发明的第二十九实施方案中，优选除草活性成分(B6)：
(B6.2)二氯吡啶酸，
(B6.3)麦草畏，
(B6.4)氟草定，和
(B6.5)毒莠定。
特别优选
(B6.2)二氯吡啶酸，
(B6.3)麦草畏，和
(B6.4)氟草定。
在本发明的第三十实施方案中，优选除草活性成分(B7)：
(B7.2)双丙氨磷，
(B7.4)草铵膦，
(B7.5)草甘膦，和
(B7.7)草硫膦。
特别优选
(B7.4)草铵膦，和
(B7.5)草甘膦。
在本发明的第三十一实施方案中，优选除草活性成分(B8)：
(B8.1)2,4-D，
(B8.3)2,4-DP,
(B8.5)苯草醚，
(B8.8)炔草酯，
(B8.11)禾草灵，
(B8.13)噁唑禾草灵，
(B8.20)MCPA，
(B8.22)2-甲-4-氯丙酸，
(B8.26)喹禾灵，和
(B8.27)喹禾灵。
特别优选
(B8.1)2,4-D，和
(B8.5)苯草醚。
在本发明的第三十二实施方案中，优选除草活性成分(B9)：
(B9.10)苯嘧磺草胺，
(B9.11)特草定，
(B9.13)三氟草嗪和
(B9.14)[3-[2-氯-4-氟-5-(1-甲基-6-三氟甲基-2,4-二氧代-1,2,3,4-四氢嘧啶-3-基)苯氧基]-2-吡啶氧基]乙酸乙酯。
最优选(B9.10)苯嘧磺草胺。
在本发明的第三十三实施方案中，优选除草活性成分(B10)：
(B10.1)氯溴隆，
(B10.2)绿麦隆，
(B10.5)敌草隆，
(B10.8)异丙隆，
(B10.9)利谷隆，
(B10.10)甲基苯噻隆，
(B10.11)溴谷隆，
(B10.12)甲氧隆，和
(B10.13)绿谷隆。
在本发明的第三十四实施方案中，优选除草活性成分(B11)：
(B11.1)莠灭净，
(B11.2)莠去津，
(B11.5)环嗪酮，
(B11.6)茚嗪氟草胺，
(B11.8)赛克津，
(B11.12)西玛津，
(B11.15)特丁津，和
(B11.16)特丁净。
特别优选
(B11.5)环嗪酮，
(B11.6)茚嗪氟草胺，和
(B11.8)赛克津。
在本发明的第三十五实施方案中，优选除草活性成分(B1)至(B11)：
(B1.2)双环吡喃酮，
(B1.4)烯草酮，
(B1.7)甲基磺草酮，
(B1.8)唑啉草酯，
(B1.10)烯禾啶，
(B1.11)磺草酮，
(B1.14)环磺酮(Tembotrione)，
(B1.16)三甲苯草酮；
(B2.1)乙草胺，
(B2.3)酰嘧磺隆，
(B2.4)磺草灵，
(B2.6)氟丁酰草胺，
(B2.10)氯嘧磺隆，
(B2.12)氯磺隆，
(B2.14)氯酯磺草胺，
(B2.17)双氯磺草胺，
(B2.18)吡氟草胺，
(B2.23)乙氧嘧磺隆，
(B2.24)啶嘧磺隆，
(B2.25)双氟磺草胺，
(B2.26)氟酮磺隆，
(B2.28)氟噻草胺，
(B2.29)唑嘧磺草胺，
(B2.30)氟啶嘧磺隆，
(B2.31)甲酰胺磺隆，
(B2.34)碘甲磺隆，
(B2.37)甲基二磺隆，
(B2.40)异丙甲草胺，
(B2.41)磺草唑胺，
(B2.42)甲磺隆，
(B2.46)五氟磺草胺，
(B2.49)氯吡酰草胺，
(B2.56)丙苯磺隆，
(B2.58)戊炔草胺，
(B2.59)苄草丹，
(B2.60)氟磺隆，
(B2.62)啶磺草胺，
(B2.63)砜嘧磺隆，
(B2.64)精异丙甲草胺，
(B2.65)嘧磺隆，
(B2.66)磺酰磺隆，
(B2.68)噻酮磺隆，
(B2.69)噻磺隆，
(B2.72)苯磺隆，
(B2.76)戊草丹
(B2.78)野麦畏；
(B3.1)溴草腈，
(B3.4)碘苯腈；
(B4.2)杀草强，
(B4.8)快灭灵，
(B4.10)咪草酸，
(B4.11)甲氧咪草烟，
(B4.12)甲基咪草烟，
(B4.13)咪唑烟酸，
(B4.15)咪唑乙烟酸，
(B4.17)异噁草胺，
(B4.18)异噁唑草酮，
(B4.21)吡草醚，
(B4.22)磺酰草吡唑，
(B4.25)砜吡草唑，
(B4.28)苯唑草酮，
(B4.33)氟胺草唑；
(B5.1)环丙嘧啶酸，
(B5.2)氯氨吡啶酸，
(B5.3)氯噻草灵，
(B5.5)灭草松，
(B5.7)Bixlozone，
(B5.12)吲哚酮草酯，
(B5.13)环庚草醚，
(B5.14)异噁草松，
(B5.21)乙氧呋草黄，
(B5.22)异丙草氟安，
(B5.23)氯氟吡啶酯，
(B5.26)丙炔氟草胺，
(B5.27)氟啶草酮，
(B5.28)氟咯草酮，
(B5.29)呋草酮，
(B5.31)氟氯吡啶酸，
(B5.32)茚草酮，
(B5.37)对草快，
(B5.38)天竺葵酸，
(B5.39)二甲戊灵，
(B5.45)氟酮磺草胺，
(B5.46)氟乐灵，
(B5.47)4-氨基-3-氯-5-氟-6-(7-氟-1H-吲哚-6-基)吡啶-2-甲酸，
(B5.48)Cyclopyrimorate，
(B5.49)敌草快，
(B5.50)噁嗪草酮；
(B6.2)二氯吡啶酸，
(B6.3)麦草畏，
(B6.4)氟草定，
(B6.5)毒莠定；
(B7.2)双丙氨磷，
(B7.4)草铵膦，
(B7.5)草甘膦，
(B7.7)草硫膦；
(B8.1)2,4-D，
(B8.3)2,4-DP,
(B8.5)苯草醚，
(B8.8)炔草酯，
(B8.11)禾草灵，
(B8.13)噁唑禾草灵，
(B8.20)MCPA，
(B8.22)2-甲-4-氯丙酸，
(B8.26)喹禾灵，
(B8.27)喹禾灵；
(B9.10)苯嘧磺草胺，
(B9.11)特草定，
(B9.13)三氟草嗪，
(B9.14)[3-[2-氯-4-氟-5-(1-甲基-6-三氟甲基-2,4-二氧代-1,2,3,4-四氢嘧啶-3-基)苯氧基]-2-吡啶氧基]乙酸乙酯；
(B10.1)氯溴隆，
(B10.2)绿麦隆，
(B10.5)敌草隆，
(B10.6)氟吡草腙，
(B10.8)异丙隆，
(B10.9)利谷隆，
(B10.10)甲基苯噻隆，
(B10.11)溴谷隆，
(B10.12)甲氧隆，
(B10.13)绿谷隆；
(B11.1)莠灭净，
(B11.2)莠去津，
(B11.5)环嗪酮，
(B11.6)茚嗪氟草胺，
(B11.8)赛克津，
(B11.12)西玛津，
(B11.15)特丁津，
(B11.16)特丁净。
特别优选：
(B1.7)甲基磺草酮，
(B1.8)唑啉草酯，
(B1.14)环磺酮；
(B2.3)酰嘧磺隆，
(B2.18)吡氟草胺，
(B2.24)啶嘧磺隆，
(B2.25)双氟磺草胺，
(B2.26)氟酮磺隆，
(B2.28)氟噻草胺，
(B2.31)甲酰胺磺隆，
(B2.34)碘甲磺隆，
(B2.37)甲基二磺隆，
(B2.58)戊炔草胺，
(B2.68)噻酮磺隆，
(B2.69)噻磺隆，
(B2.72)苯磺隆；
(B3.1)溴草腈，
(B4.18)异噁唑草酮，
(B4.22)磺酰草吡唑，
(B4.25)砜吡草唑。
(B5.7)Bixlozone，
(B5.23)氯氟吡啶酯，
(B5.38)天竺葵酸，
(B6.2)二氯吡啶酸，
(B6.3)麦草畏，
(B6.4)氟草定，
(B7.4)草铵膦，
(B7.5)草甘膦，
(B8.1)2,4-D，
(B8.5)苯草醚，
(B9.10)苯嘧磺草胺，
(B11.5)环嗪酮，
(B11.6)茚嗪氟草胺，
(B11.8)赛克津。
在本发明的上下文中，可以根据需要将各个优选的、特别优选的和最优选的实施方案彼此组合。这意味着本发明涵盖包含(A)一种或多种通式(I)的化合物或其农业化学上可接受的盐[组分(A)]和(B)一种或多种选自除草活性成分(B1)至(B11)的除草剂[组分(B)]的除草组合物，其中可如上文所详述的那样彼此组合任何期望的所公开的优选、特别优选和最优选实施方案。
令人惊奇地，包含(A)一种或多种通式(I)的除草活性化合物(A)或其农业化学上可接受的盐[除草剂(A)]和除草剂(B)的一些二元组合物已经证明是特别有利的。优选的、特别优选的和最优选的二元体系将在下文作为本发明的进一步的实施方案列出。
在本发明的第三十六实施方案中，所述组合物优选包含
(A)通式(I)的化合物或其农业化学上可接受的盐[除草剂(A)]
其中：
G为式OR4的基团；
R1和R2分别为氢；
R3为(C1-C3)-烷基、(C3-C4)-环烷基、(C2-C3)-烯基或(C1-C3)-烷氧基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R4为氢，或者(C1-C3)-烷基或(C2-C4)-烯基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
Y为氧；
W为氧；
Z为基团Z-1、Z-4和Z-6：
其中箭头分别代表朝向式(I)的基团C＝W的键；
X2、X4和X6分别彼此独立地为氢或氟；
X3和X5分别彼此独立地为氢、氟、氰基或甲基；和
m为数字0、1、2或3；
和
(B)选自以下的除草剂[组分(B)]
(B1.2)双环吡喃酮，
(B1.4)烯草酮，
(B1.7)甲基磺草酮，
(B1.8)唑啉草酯，
(B1.10)烯禾啶，
(B1.11)磺草酮，
(B1.14)环磺酮(Tembotrione)，
(B1.16)三甲苯草酮；
(B2.1)乙草胺，
(B2.3)酰嘧磺隆，
(B2.4)磺草灵，
(B2.6)氟丁酰草胺，
(B2.10)氯嘧磺隆，
(B2.12)氯磺隆，
(B2.14)氯酯磺草胺，
(B2.17)双氯磺草胺，
(B2.18)吡氟草胺，
(B2.23)乙氧嘧磺隆，
(B2.24)啶嘧磺隆，
(B2.25)双氟磺草胺，
(B2.26)氟酮磺隆，
(B2.28)氟噻草胺，
(B2.29)唑嘧磺草胺，
(B2.30)氟啶嘧磺隆，
(B2.31)甲酰胺磺隆，
(B2.34)碘甲磺隆，
(B2.37)甲基二磺隆，
(B2.40)异丙甲草胺，
(B2.41)磺草唑胺，
(B2.42)甲磺隆，
(B2.46)五氟磺草胺，
(B2.49)氯吡酰草胺，
(B2.56)丙苯磺隆，
(B2.58)戊炔草胺，
(B2.59)苄草丹，
(B2.60)氟磺隆，
(B2.62)啶磺草胺，
(B2.63)砜嘧磺隆，
(B2.64)精异丙甲草胺，
(B2.65)嘧磺隆，
(B2.66)磺酰磺隆，
(B2.68)噻酮磺隆，
(B2.69)噻磺隆，
(B2.72)苯磺隆，
(B2.76)戊草丹
(B2.78)野麦畏；
(B3.1)溴草腈，
(B3.4)碘苯腈；
(B4.2)杀草强，
(B4.8)快灭灵，
(B4.10)咪草酸，
(B4.11)甲氧咪草烟，
(B4.12)甲基咪草烟，
(B4.13)咪唑烟酸，
(B4.15)咪唑乙烟酸，
(B4.17)异噁草胺，
(B4.18)异噁唑草酮，
(B4.21)吡草醚，
(B4.22)磺酰草吡唑，
(B4.25)砜吡草唑，
(B4.28)苯唑草酮，
(B4.33)氟胺草唑；
(B5.1)环丙嘧啶酸，
(B5.2)氯氨吡啶酸，
(B5.3)氯噻草灵，
(B5.5)灭草松，
(B5.7)Bixlozone，
(B5.12)吲哚酮草酯，
(B5.13)环庚草醚，
(B5.14)异噁草松，
(B5.21)乙氧呋草黄，
(B5.22)异丙草氟安，
(B5.23)氯氟吡啶酯，
(B5.26)丙炔氟草胺，
(B5.27)氟啶草酮，
(B5.28)氟咯草酮，
(B5.29)呋草酮，
(B5.31)氟氯吡啶酸，
(B5.32)茚草酮，
(B5.37)对草快，
(B5.38)天竺葵酸，
(B5.39)二甲戊灵，
(B5.45)氟酮磺草胺，
(B5.46)氟乐灵，
(B5.47)4-氨基-3-氯-5-氟-6-(7-氟-1H-吲哚-6-基)吡啶-2-甲酸，
(B5.48)Cyclopyrimorate，
(B5.49)敌草快，
(B5.50)噁嗪草酮；
(B6.2)二氯吡啶酸，
(B6.3)麦草畏，
(B6.4)氟草定，
(B6.5)毒莠定；
(B7.2)双丙氨磷，
(B7.4)草铵膦，
(B7.5)草甘膦，
(B7.7)草硫膦；
(B8.1)2,4-D，
(B8.3)2,4-DP,
(B8.5)苯草醚，
(B8.8)炔草酯，
(B8.11)禾草灵，
(B8.13)噁唑禾草灵，
(B8.20)MCPA，
(B8.22)2-甲-4-氯丙酸，
(B8.26)喹禾灵，
(B8.27)喹禾灵；
(B9.10)苯嘧磺草胺，
(B9.11)特草定，
(B9.13)三氟草嗪，
(B9.14)[3-[2-氯-4-氟-5-(1-甲基-6-三氟甲基-2,4-二氧代-1,2,3,4-四氢嘧啶-3-基)苯氧基]-2-吡啶氧基]乙酸乙酯；
(B10.1)氯溴隆，
(B10.2)绿麦隆，
(B10.5)敌草隆，
(B10.6)氟吡草腙，
(B10.8)异丙隆，
(B10.9)利谷隆，
(B10.10)甲基苯噻隆，
(B10.11)溴谷隆，
(B10.12)甲氧隆，
(B10.13)绿谷隆；
(B11.1)莠灭净，
(B11.2)莠去津，
(B11.5)环嗪酮，
(B11.6)茚嗪氟草胺，
(B11.8)赛克津，
(B11.12)西玛津，
(B11.15)特丁津，
(B11.16)特丁净。
在本发明的第三十七实施方案中，所述组合物优选包含
(A)通式(I)的化合物或其农业化学上可接受的盐[除草剂(A)]
其中：
G为式OR4的基团；
R1和R2分别为氢；
R3为(C1-C3)-烷基、(C3-C4)-环烷基、(C2-C3)-烯基或(C1-C3)-烷氧基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R4为氢，或者(C1-C3)-烷基或(C2-C4)-烯基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
Y为氧；
W为氧；
Z为基团Z-1、Z-4和Z-6：
其中箭头分别代表朝向式(I)的基团C＝W的键；
X2、X4和X6分别为氢；
X3和X5分别为氟；和
m为数字0、1、2或3；
和
(B)选自以下的除草剂[组分(B)]
(B1.7)甲基磺草酮，
(B1.8)唑啉草酯，
(B1.14)环磺酮(Tembotrione)，
(B2.3)酰嘧磺隆，
(B2.18)吡氟草胺，
(B2.24)啶嘧磺隆，
(B2.25)双氟磺草胺，
(B2.26)氟酮磺隆，
(B2.28)氟噻草胺，
(B2.31)甲酰胺磺隆，
(B2.34)碘甲磺隆，
(B2.37)甲基二磺隆，
(B2.58)戊炔草胺，
(B2.68)噻酮磺隆，
(B2.69)噻磺隆，
(B2.72)苯磺隆，
(B3.1)溴草腈，
(B4.18)异噁唑草酮，
(B4.22)磺酰草吡唑，
(B4.25)砜吡草唑，
(B5.7)Bixlozone，
(B5.23)氯氟吡啶酯，
(B5.31)氟氯吡啶酸，
(B5.38)天竺葵酸，
(B6.2)二氯吡啶酸，
(B6.3)麦草畏，
(B6.4)氟草定，
(B7.4)草铵膦，
(B7.5)草甘膦，
(B8.1)2,4-D，
(B8.5)苯草醚，
(B9.10)苯嘧磺草胺，
(B11.5)环嗪酮，
(B11.6)茚嗪氟草胺，
(B11.8)赛克津。
在本发明的第三十八实施方案中，所述组合物优选包含
(A)通式(I)的化合物或其农业化学上可接受的盐[除草剂(A)]
其中：
G为式NR11R12的基团；
R1和R2分别为氢；
R3为(C1-C3)-烷基、(C3-C4)-环烷基、(C2-C3)-烯基或(C1-C3)-烷氧基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
Y为氧；
W为氧；
Z为基团Z-1、Z-4和Z-6：
其中箭头分别代表朝向式(I)的基团C＝W的键；
X2、X4和X6分别彼此独立地为氢或氟；
X3和X5分别彼此独立地为氢、氟、氰基或甲基；
R5为(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟和氯的基团所取代；
R6为氢或R5；
R7为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R8为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R11为氢或(C1-C3)-烷基；
R12为OR7、S(O)nR5、SO2NR6R7或分别被m个选自氟、氯、氰基、OR7和S(O)nR5的基团所取代的(C1-C6)-烷基；
或者
R11和R12与它们所键合至的氮原子一起形成饱和的、部分或完全不饱和的五-或六-元环，所述环任选被选自卤素、(C1-C6)-烷基、卤代-(C1-C6)-烷基和氧代的基团单取代至三取代，并且除了该氮原子外，所述环还含有r个碳原子、o个氧原子、p个硫原子和q个选自NR7和NCOR7的要素作为环原子；
m为数字0、1、2或3；
n为数字0、1或2；
o为数字0、1或2；
p为数字0或1；
q为数字0或1；和
r为数字3、4或5；
和
(B)选自以下的除草剂[组分(B)]
(B1.2)双环吡喃酮，
(B1.4)烯草酮，
(B1.7)甲基磺草酮，
(B1.8)唑啉草酯，
(B1.10)烯禾啶，
(B1.11)磺草酮，
(B1.14)环磺酮(Tembotrione)，
(B1.16)三甲苯草酮；
(B2.1)乙草胺，
(B2.3)酰嘧磺隆，
(B2.4)磺草灵，
(B2.6)氟丁酰草胺，
(B2.10)氯嘧磺隆，
(B2.12)氯磺隆，
(B2.14)氯酯磺草胺，
(B2.17)双氯磺草胺，
(B2.18)吡氟草胺，
(B2.23)乙氧嘧磺隆，
(B2.24)啶嘧磺隆，
(B2.25)双氟磺草胺，
(B2.26)氟酮磺隆，
(B2.28)氟噻草胺，
(B2.29)唑嘧磺草胺，
(B2.30)氟啶嘧磺隆，
(B2.31)甲酰胺磺隆，
(B2.34)碘甲磺隆，
(B2.37)甲基二磺隆，
(B2.40)异丙甲草胺，
(B2.41)磺草唑胺，
(B2.42)甲磺隆，
(B2.46)五氟磺草胺，
(B2.49)氯吡酰草胺，
(B2.56)丙苯磺隆，
(B2.58)戊炔草胺，
(B2.59)苄草丹，
(B2.60)氟磺隆，
(B2.62)啶磺草胺，
(B2.63)砜嘧磺隆，
(B2.64)精异丙甲草胺，
(B2.65)嘧磺隆，
(B2.66)磺酰磺隆，
(B2.68)噻酮磺隆，
(B2.69)噻磺隆，
(B2.72)苯磺隆，
(B2.76)戊草丹
(B2.78)野麦畏；
(B3.1)溴草腈，
(B3.4)碘苯腈；
(B4.2)杀草强，
(B4.8)快灭灵，
(B4.10)咪草酸，
(B4.11)甲氧咪草烟，
(B4.12)甲基咪草烟，
(B4.13)咪唑烟酸，
(B4.15)咪唑乙烟酸，
(B4.17)异噁草胺，
(B4.18)异噁唑草酮，
(B4.21)吡草醚，
(B4.22)磺酰草吡唑，
(B4.25)砜吡草唑，
(B4.28)苯唑草酮，
(B4.33)氟胺草唑；
(B5.1)环丙嘧啶酸，
(B5.2)氯氨吡啶酸，
(B5.3)氯噻草灵，
(B5.5)灭草松，
(B5.7)Bixlozone，
(B5.12)吲哚酮草酯，
(B5.13)环庚草醚，
(B5.14)异噁草松，
(B5.21)乙氧呋草黄，
(B5.22)异丙草氟安，
(B5.23)氯氟吡啶酯，
(B5.26)丙炔氟草胺，
(B5.27)氟啶草酮，
(B5.28)氟咯草酮，
(B5.29)呋草酮，
(B5.31)氟氯吡啶酸，
(B5.32)茚草酮，
(B5.37)对草快，
(B5.38)天竺葵酸，
(B5.39)二甲戊灵，
(B5.45)氟酮磺草胺，
(B5.46)氟乐灵，
(B5.47)4-氨基-3-氯-5-氟-6-(7-氟-1H-吲哚-6-基)吡啶-2-甲酸，
(B5.48)Cyclopyrimorate，
(B5.49)敌草快，
(B5.50)噁嗪草酮；
(B6.2)二氯吡啶酸，
(B6.3)麦草畏，
(B6.4)氟草定，
(B6.5)毒莠定；
(B7.2)双丙氨磷，
(B7.4)草铵膦，
(B7.5)草甘膦，
(B7.7)草硫膦；
(B8.1)2,4-D，
(B8.3)2,4-DP,
(B8.5)苯草醚，
(B8.8)炔草酯，
(B8.11)禾草灵，
(B8.13)噁唑禾草灵，
(B8.20)MCPA，
(B8.22)2-甲-4-氯丙酸，
(B8.26)喹禾灵，
(B8.27)喹禾灵；
(B9.10)苯嘧磺草胺，
(B9.11)特草定，
(B9.13)三氟草嗪，
(B9.14)[3-[2-氯-4-氟-5-(1-甲基-6-三氟甲基-2,4-二氧代-1,2,3,4-四氢嘧啶-3-基)苯氧基]-2-吡啶氧基]乙酸乙酯；
(B10.1)氯溴隆，
(B10.2)绿麦隆，
(B10.5)敌草隆，
(B10.6)氟吡草腙，
(B10.8)异丙隆，
(B10.9)利谷隆，
(B10.10)甲基苯噻隆，
(B10.11)溴谷隆，
(B10.12)甲氧隆，
(B10.13)绿谷隆；
(B11.1)莠灭净，
(B11.2)莠去津，
(B11.5)环嗪酮，
(B11.6)茚嗪氟草胺，
(B11.8)赛克津，
(B11.12)西玛津，
(B11.15)特丁津，
(B11.16)特丁净。
在本发明的第三十九实施方案中，所述组合物优选包含
(A)通式(I)的化合物或其农业化学上可接受的盐[除草剂(A)]
其中：
G为式NR11R12的基团；
R1和R2分别为氢；
R3为(C1-C3)-烷基、(C3-C4)-环烷基、(C2-C3)-烯基或(C1-C3)-烷氧基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
Y为氧；
W为氧；
Z为基团Z-1、Z-4和Z-6：
其中箭头分别代表朝向式(I)的基团C＝W的键；
X2、X4和X6分别为氢；
X3和X5分别为氟；
R5为(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟和氯的基团所取代；
R6为氢或R5；
R7为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R8为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R11为氢；
R12为OR7、S(O)nR5、SO2NR6R7或分别被m个选自氟、氯、氰基、OR7和S(O)nR5的基团所取代的(C1-C6)-烷基；
或者
R11和R12与它们所键合至的氮原子一起形成饱和的、部分或完全不饱和的五-或六-元环，所述环任选被选自卤素、(C1-C6)-烷基、卤代-(C1-C6)-烷基和氧代的基团单取代至三取代，并且除了该氮原子外，所述环还含有r个碳原子、o个氧原子、p个硫原子和q个选自NR7和NCOR7的要素作为环原子；
m为数字0、1、2或3；
n为数字0、1或2；
o为数字0、1或2；
p为数字0或1；
q为数字0或1；和
r为数字3、4或5，
和
(B)选自以下的除草剂[组分(B)]
(B1.7)甲基磺草酮，
(B1.8)唑啉草酯，
(B1.14)环磺酮(Tembotrione)，
(B2.3)酰嘧磺隆，
(B2.18)吡氟草胺，
(B2.24)啶嘧磺隆，
(B2.25)双氟磺草胺，
(B2.26)氟酮磺隆，
(B2.28)氟噻草胺，
(B2.31)甲酰胺磺隆，
(B2.34)碘甲磺隆，
(B2.37)甲基二磺隆，
(B2.58)戊炔草胺，
(B2.68)噻酮磺隆，
(B2.69)噻磺隆，
(B2.72)苯磺隆，
(B3.1)溴草腈，
(B4.18)异噁唑草酮，
(B4.22)磺酰草吡唑，
(B4.25)砜吡草唑，
(B5.7)Bixlozone，
(B5.23)氯氟吡啶酯，
(B5.31)氟氯吡啶酸，
(B5.38)天竺葵酸，
(B6.2)二氯吡啶酸，
(B6.3)麦草畏，
(B6.4)氟草定，
(B7.4)草铵膦，
(B7.5)草甘膦，
(B8.1)2,4-D，
(B8.5)苯草醚，
(B9.10)苯嘧磺草胺，
(B11.5)环嗪酮，
(B11.6)茚嗪氟草胺，
(B11.8)赛克津。
本发明的上下文中特别优选的组合物为下表2.1-2.9中列出的组合物：
表2.1：包含(A1)的特别优选的二元组合物
表2.2：包含(A2)的特别优选的二元组合物
表2.3：包含(A3)的特别优选的二元组合物
表2.4：包含(A4)的特别优选的二元组合物
表2.5：包含(A5)的特别优选的二元组合物
表2.6：包含(A6)的特别优选的二元组合物
表2.7：包含(A7)的特别优选的二元组合物
表2.8：包含(A8)的特别优选的二元组合物
表2.9：包含(A1)的其他特别优选的二元组合物
| 二元组合物 | 化合物(A) | 化合物(B) |
| Z257 | A1 | (B3.1) |
| Z258 | A1 | (B2.58) |
| Z259 | A1 | (B4.22) |
此外，本发明的组合可与其他活性成分如所提及的活性成分(除草剂、杀真菌剂、杀昆虫剂、杀螨剂等)和/或选自在植物保护中惯用的添加剂的植物生长调节剂或助剂如佐剂和配制辅助剂一起使用。在此，包含活性成分(A)和(B)的植物保护剂活性成分与任选的其他的活性成分的组合在这里简称为“除草剂组合”。它们的使用形式如配制物或桶混物为除草产品(组合物)。
本发明因此还提供了除草产品，其包含本发明的活性成分组合与在植物保护中惯用的添加剂，如佐剂和配制辅助剂，及任选的其他植物保护剂活性成分。
本发明还提供了使用本发明的活性成分组合作为除草剂和植物生长调节剂的用途或施用方法，优选作为存在协同活性含量的相应活性成分组合的除草剂和植物生长调节剂。
除草剂(B)的施用量原则上是已知的并通常在0.01至4000g a.i./ha的范围内，优选在0.02至2000g a.i./ha的范围内，尤其是1至2000g a.i./ha。对于来自组(B5)的活性成分天竺葵酸(B5.38)，施用量在1至100,000g a.i./ha的范围内。
在本发明的混合物中，在提到施用量的上下文中，与单独施用相比，各种活性成分的所需施用量通常较低。
对于来自组(B1)的活性成分，施用量优选在5至250g a.i./ha的范围内，尤其是在5至150g/ha的范围内，最优选在5至60g a.i./ha的范围内。
对于来自组(B2)的活性成分，施用量优选在1至4000g a.i./ha的范围内，尤其是在1至2000g a.i./ha的范围内，最优选在1至400g a.i./ha的范围内。
对于来自组(B3)的活性成分，施用量优选在10至1000g a.i./ha的范围内，尤其是在10至500g a.i./ha的范围内，最优选在10至300g a.i./ha的范围内。
对于来自组(B4)的活性成分，施用量优选在1至700g a.i./ha的范围内，尤其是在1至400g a.i./ha的范围内，最优选在1至200g a.i./ha的范围内。
对于来自组(B5)的活性成分，除了天竺葵酸(B5.38)外，施用量优选在1至2400ga.i./ha的范围内，尤其是在1至1200g a.i./ha的范围内，最优选在1至400g a.i./ha的范围内。对于天竺葵酸(B5.38)，施用量优选为1至100,000g a.i./ha，更优选1至40,000ga.i./ha，尤其是在1至30,000g a.i./ha的范围内。
对于来自组(B6)的活性成分，施用量优选在10至1000g a.i./ha的范围内，尤其是在10至600g a.i./ha的范围内。
对于来自组(B7)的活性成分，施用量优选在20至3500g a.i./ha的范围内，尤其是在20至2500g a.i./ha的范围内，最优选在20至2000g a.i./ha的范围内。
对于来自组(B8)的活性成分，施用量优选在5至1500g a.i./ha的范围内，尤其是在5至1000g a.i./ha的范围内，最优选在5至900g a.i./ha的范围内。
对于来自组(B9)的活性成分，施用量优选在2至2000g a.i./ha的范围内，尤其是在2至1000g a.i./ha的范围内，更优选在2至200g a.i./ha的范围内，最优选在2至50ga.i./ha的范围内。
对于来自组(B10)的活性成分，施用量优选在20至3500g a.i./ha的范围内，尤其是在20至2000g a.i./ha的范围内。
对于来自组(B11)的活性成分，施用量优选在25至3000g a.i./ha的范围内，尤其是在25至2500g a.i./ha的范围内，最优选在25至2000g a.i./ha的范围内。
取决于有效施用量，基于重量计的(A):(B)比率通常在1:100,000至2000:1的范围内，优选1:40,000至750:1，尤其是在1:15,000至500:1的范围内，甚至更优选在1:300至400:1的范围内。
对于来自组(B1)至(B11)的活性成分，优选的重量比(A):(B)为如下：
(A):(B1)优选在30:1至1:30的范围内，尤其是15:1至1:15；
(A):(B2)优选在400:1至1:400的范围内，尤其是200:1至1:200；
(A):(B3)优选在30:1至1:30的范围内，尤其是15:1至1:15；
(A):(B4)优选在300:1至1:300的范围内，尤其是150:1至1:150；
(A):(B5)优选在400:1至1:300的范围内，尤其是300:1至1:150；
(A):(B6)优选在60:1至1:60的范围内，尤其是30:1至1:30；
(A):(B7)优选在10:1至1:200的范围内，尤其是1:1至1:100；
(A):(B8)优选在30:1至1:300的范围内，尤其是10:1至1:80；
(A):(B9)优选在80:1至1:200的范围内，尤其是40:1至1:100；
(A):(B10)优选在10:1至1:300的范围内，尤其是3:1至1:150；
(A):(B11)优选在30:1至1:300的范围内，尤其是15:1至1:150。
本发明的除草组合物还可与其他除草剂和植物生长调节剂组合，例如以补充活性谱。可在混合配制物中或在桶混物中作为根据本发明的化合物的组合配对物使用的有例如基于抑制例如乙酰乳酸合酶、乙酰辅酶A羧化酶、纤维素合酶、烯醇丙酮莽草酸-3-磷酸合酶、谷氨酰胺合成酶、对羟基苯基丙酮酸双加氧酶、八氢番茄红素去饱和酶、光系统I、光系统II、原卟啉原氧化酶的已知活性成分，如自例如Weed Research 26(1986)441-445或“ThePesticide Manual”(第14版，The British Crop Protection Council and the RoyalSoc.of Chemistry,2006)、相应的“e-Pesticide Manual Version 4(2006)”及其中引用的文献所知。更多的商品名称和“通用名称”列在“Compendium of Pesticide Common Names”(可在互联网上于http://www.alanwood.net/pesticides获得)中。
可与本发明的化合物组合的已知除草剂的实例包括以下活性成分(注：这些化合物或按根据国际标准化组织(ISO)的“通用名称”或按化学名称命名，在一些情况下连同标准代码编号一起)，并且总是涵盖所有使用形式，如酸、盐、酯和异构体，如立体异构体和旋光异构体。该列表包括一种应用形式，在一些情况下还包括不止一种应用形式：
2,4-D、乙草胺、三氟羧草醚、杂草焚、苯草醚、甲草胺、禾草灭、禾草灭、莠灭净、氨唑草酮、酰嘧磺隆、杀草强、莎稗磷、磺草灵、莠去津、唑啶草酮、四唑嘧磺隆、氟丁酰草胺、氯噻草灵、草除灵、呋草黄、苄嘧磺隆、灭草松、双苯嘧草酮、双环磺草酮、吡草酮、治草醚、双丙氨膦、双草醚、除草定、溴丁酰草胺、杀草全、溴草腈、丁草胺、氟丙嘧草酯、丁烯草胺、地乐胺、丁苯草酮、丁草特、唑草胺、双酰草胺、快灭灵、甲氧除草醚、氯草敏、氯嘧磺隆、草枯醚、绿麦隆、氯磺隆、吲哚酮草酯、环庚草醚、醚磺隆、环苯草酮、烯草酮、炔草酯、异噁草松、氯甲酰草胺、二氯吡啶酸、氯酯磺草胺、苄草隆、氰草津、环丙嘧磺隆、噻草酮、氰氟草酯、甜草灵、麦草畏、敌草腈、2,4-滴丙酸、精2,4-滴丙酸、2,4-滴苯丙酸甲酯、双氯磺草胺、苯敌快、吡氟草胺、氟吡草腙、敌草克、噁唑隆、哌草丹、二甲草胺、异戊净、二甲噻草胺、三嗪氟草胺、敌草快、氟硫草定、敌草隆、杀草隆、EPTC、戊草丹、乙丁烯氟灵、胺苯磺隆、氟乳醚、乙氧嘧磺隆、抑酰胺、噁唑禾草灵乙酯、噁唑禾草灵、四唑酰草胺、异丙草氟安-异丙酯、异丙草氟安-甲酯、啶嘧磺隆、双氟磺草胺、吡氟禾草灵、稳杀得、稳杀得、异丙吡草酯、氟酮磺隆、氟吡磺隆、氯乙氟灵、氟噻草胺、氟哒嗪草酯、唑嘧磺草胺、氟胺草酯、丙炔氟草胺、氟草隆、氟咯草酮、乙羧氟草醚、氟胺草唑、氟啶嘧磺隆、氟啶草酮、氟草定、氟草烟-丁氧基丙酯、氟草烟异辛酯、氟嘧醇、呋草酮、氟噻乙草酯、氟磺胺草醚、甲酰胺磺隆、草铵膦、草丁鳞、草甘膦、氯吡嘧磺隆、氟吡禾灵、氟吡乙禾灵、氟吡甲禾灵、高效氟吡甲禾灵、环嗪酮、咪草酸、甲氧咪草烟(imazamox)、甲氧咪草烟(imazapic)、咪唑烟酸、咪唑喹啉酸、咪唑乙烟酸、唑吡嘧磺隆、茚草酮、碘甲磺隆钠盐、碘苯腈、异丙隆、异噁隆、异噁草胺、异噁氯草酮、异噁唑草酮、ketospiradox、乳氟禾草灵、环草定、利谷隆、MCPA、2-甲-4-氯丙酸、精2-甲-4-氯丙酸、苯噻酰草胺、甲甲基二磺隆、甲基磺草酮、噁唑酰草胺、苯嗪草酮、吡唑草胺、甲基苯噻隆、甲基杀草隆、溴谷隆、异丙甲草胺、磺草唑胺、甲氧隆、赛克津、甲磺隆、禾草特、绿谷隆、萘丙胺、敌草胺、草不隆、烟嘧磺隆、氟草敏、坪草丹、安磺灵、丙炔噁草酮、噁草灵、环氧嘧磺隆、噁嗪草酮、乙氧氟草醚、对草快、天竺葵酸、二甲戊灵、pendralin、环戊噁草酮、烯草胺、甜菜宁、毒莠定、氯吡酰草胺、唑啉草酯、哌草磷、丙草胺、氟嘧磺隆甲酯、氟唑草胺、环苯草酮、扑草净、毒草胺、敌稗、喔草酯、异丙甲草胺、丙苯磺隆、戊炔草胺、苄草丹、氟磺隆、双唑草腈、吡草醚、吡唑特、吡嘧磺隆、苄草唑、嘧啶肟草醚、稗草丹、哒草特代谢物、哒草特、环酯草醚、嘧草醚、嘧草硫醚、二氯喹啉酸、喹草酸、灭藻醌、禾草克、精禾草克、喹禾糠酯、砜嘧磺隆、烯禾啶、西玛津、西草净、精异丙甲草胺、磺草酮、磺酰唑草酮、甲嘧磺隆、草硫膦、磺酰磺隆、丁唑隆、吡喃草酮、特丁津、特丁净、噻吩草胺、噻唑烟酸、噻磺隆、禾草丹、仲草丹、三甲苯草酮、野麦畏、醚苯磺隆、苯磺隆、定草酯、灭草环、三氟啶磺隆、氟乐灵、氟胺磺酯、三氟甲磺隆、WL110547(即5-苯氧基-1-[3-(三氟甲基)苯基]-1H-四唑)；HOK-201、HOK-202、UBH-509；D-489；LS 82-556；KPP-300；NC-324；NC-330；KH-218；DPX-N8189；SC-0774；TH-547、DOWCO-535；DK-8910；V-53482；PP-600；MBH-001；KIH-9201；ET-751；KIH-6127；KIH-2023和KIH5996。
如果相应的通用名称涵盖不止一种形式的活性成分，则该名称优选定义市售可获得的形式。
所提到的每一种其他活性成分(＝活性成分(C*)、(C1*)、(C2*)等)然后可优选与根据本发明的二元组合中之一根据方案(A)+(B)+(C*)抑或根据方案(A)+(B)+(C1*)+(C2*)等组合。
所述的量为施用量(g a.i./ha＝每公顷的活性物质克数)并因此也定义了组合的活性成分的共配制物、预混物、桶混物中或顺序施用的比率。
这些组合既可在芽前过程中又可在芽后过程中施用。这既适用于有害植物的芽前过程和芽后过程，在有害植物的选择性控制情况下，也适用于作物植物的芽前过程和芽后过程。混合形式也是可能的，例如在作物植物的芽后过程在有害植物的芽前过程或芽后过程控制有害植物。
本发明的除草剂组合可还包含其他组分，例如针对有害生物体如有害植物、损害植物的动物或损害植物的真菌的其他活性成分，在此情况下尤其是来自除草剂、杀真菌剂、杀昆虫剂、杀螨剂、杀线虫剂、杀疥虫药和相关物质的活性成分。
可与本发明的除草剂组合组合使用的杀真菌活性化合物优选为标准的市售活性成分，例如(与除草剂类似，这些化合物通常以其通用名称提及)：
1)麦角甾醇生物合成抑制剂，例如(1.001)环丙唑醇、(1.002)苯醚甲环唑、(1.003)氟环唑、(1.004)环酰菌胺、(1.005)苯锈定、(1.006)丁苯吗啉、(1.007)胺苯吡菌酮、(1.008)氟喹唑、(1.009)粉唑醇、(1.010)抑霉唑、(1.011)硫酸抑霉唑、(1.012)种菌唑、(1.013)叶菌唑、(1.014)腈菌唑、(1.015)多效唑、(1.016)丙氯灵、(1.017)丙环唑、(1.018)丙硫菌唑、(1.019)啶菌噁唑、(1.020)螺环菌胺、(1.021)戊唑醇、(1.022)四氟醚唑、(1.023)三唑醇、(1.024)克啉菌、(1.025)灭菌唑、(1.026)(1R,2S,5S)-5-(4-氯苄基)-2-(氯甲基)-2-甲基-1-(1H-1,2,4-三唑-1-基甲基)环戊醇、(1.027)(1S,2R,5R)-5-(4-氯苄基)-2-(氯甲基)-2-甲基-1-(1H-1,2,4-三唑-1-基甲基)环戊醇、(1.028)(2R)-2-(1-氯环丙基)-4-[(1R)-2,2-二氯环丙基]-1-(1H-1,2,4-三唑-1-基)丁烷-2-醇、(1.029)(2R)-2-(1-氯环丙基)-4-[(1S)-2,2-二氯环丙基]-1-(1H-1,2,4-三唑-1-基)丁烷-2-醇、(1.030)(2R)-2-[4-(4-氯苯氧基)-2-(三氟甲基)苯基]-1-(1H-1,2,4-三唑-1-基)丙烷-2-醇、(1.031)(2S)-2-(1-氯环丙基)-4-[(1R)-2,2-二氯环丙基]-1-(1H-1,2,4-三唑-1-基)丁烷-2-醇、(1.032)(2S)-2-(1-氯环丙基)-4-[(1S)-2,2-二氯环丙基]-1-(1H-1,2,4-三唑-1-基)丁烷-2-醇、(1.033)(2S)-2-[4-(4-氯苯氧基)-2-(三氟甲基)苯基]-1-(1H-1,2,4-三唑-1-基)丙烷-2-醇、(1.034)(R)-[3-(4-氯-2-氟苯基)-5-(2,4-二氟苯基)-1,2-噁唑-4-基](吡啶-3-基)甲醇、(1.035)(S)-[3-(4-氯-2-氟苯基)-5-(2,4-二氟苯基)-1,2-噁唑-4-基](吡啶-3-基)甲醇、(1.036)[3-(4-氯-2-氟苯基)-5-(2,4-二氟苯基)-1,2-噁唑-4-基](吡啶-3-基)甲醇、(1.037)1-({(2R,4S)-2-[2-氯-4-(4-氯苯氧基)苯基]-4-甲基-1,3-二氧杂环戊烷-2-基}甲基)-1H-1,2,4-三唑、(1.038)1-({(2S,4S)-2-[2-氯-4-(4-氯苯氧基)苯基]-4-甲基-1,3-二氧杂环戊烷-2-基}甲基)-1H-1,2,4-三唑、(1.039)1-{[3-(2-氯苯基)-2-(2,4-二氟苯基)氧杂环丙烷-2-基]甲基}-1H-1,2,4-三唑-5-基硫代氰酸盐、(1.040)1-{[rel(2R,3R)-3-(2-氯苯基)-2-(2,4-二氟苯基)氧杂环丙烷-2-基]甲基}-1H-1,2,4-三唑-5-基硫代氰酸盐、(1.041)1-{[rel(2R,3S)-3-(2-氯苯基)-2-(2,4-二氟苯基)氧杂环丙烷-2-基]甲基}-1H-1,2,4-三唑-5-基硫代氰酸盐、(1.042)2-[(2R,4R,5R)-1-(2,4-二氯苯基)-5-羟基-2,6,6-三甲基庚烷-4-基]-2,4-二氢-3H-1,2,4-三唑-3-硫酮、(1.043)2-[(2R,4R,5S)-1-(2,4-二氯苯基)-5-羟基-2,6,6-三甲基庚烷-4-基]-2,4-二氢-3H-1,2,4-三唑-3-硫酮、(1.044)2-[(2R,4S,5R)-1-(2,4-二氯苯基)-5-羟基-2,6,6-三甲基庚烷-4-基]-2,4-二氢-3H-1,2,4-三唑-3-硫酮、(1.045)2-[(2R,4S,5S)-1-(2,4-二氯苯基)-5-羟基-2,6,6-三甲基庚烷-4-基]-2,4-二氢-3H-1,2,4-三唑-3-硫酮、(1.046)2-[(2S,4R,5R)-1-(2,4-二氯苯基)-5-羟基-2,6,6-三甲基庚烷-4-基]-2,4-二氢-3H-1,2,4-三唑-3-硫酮、(1.047)2-[(2S,4R,5S)-1-(2,4-二氯苯基)-5-羟基-2,6,6-三甲基庚烷-4-基]-2,4-二氢-3H-1,2,4-三唑-3-硫酮、(1.048)2-[(2S,4S,5R)-1-(2,4-二氯苯基)-5-羟基-2,6,6-三甲基庚烷-4-基]-2,4-二氢-3H-1,2,4-三唑-3-硫酮、(1.049)2-[(2S,4S,5S)-1-(2,4-二氯苯基)-5-羟基-2,6,6-三甲基庚烷-4-基]-2,4-二氢-3H-1,2,4-三唑-3-硫酮、(1.050)2-[1-(2,4-二氯苯基)-5-羟基-2,6,6-三甲基庚烷-4-基]-2,4-二氢-3H-1,2,4-三唑-3-硫酮、(1.051)2-[2-氯-4-(2,4-二氯苯氧基)苯基]-1-(1H-1,2,4-三唑-1-基)丙烷-2-醇、(1.052)2-[2-氯-4-(4-氯苯氧基)苯基]-1-(1H-1,2,4-三唑-1-基)丁烷-2-醇、(1.053)2-[4-(4-氯苯氧基)-2-(三氟甲基)苯基]-1-(1H-1,2,4-三唑-1-基)丁烷-2-醇、(1.054)2-[4-(4-氯苯氧基)-2-(三氟甲基)苯基]-1-(1H-1,2,4-三唑-1-基)戊烷-2-醇、(1.055)2-[4-(4-氯苯氧基)-2-(三氟甲基)苯基]-1-(1H-1,2,4-三唑-1-基)丙烷-2-醇、(1.056)2-{[3-(2-氯苯基)-2-(2,4-二氟苯基)氧杂环丙烷-2-基]甲基}-2,4-二氢-3H-1,2,4-三唑-3-硫酮、(1.057)2-{[rel(2R,3R)-3-(2-氯苯基)-2-(2,4-二氟苯基)氧杂环丙烷-2-基]甲基}-2,4-二氢-3H-1,2,4-三唑-3-硫酮、(1.058)2-{[rel(2R,3S)-3-(2-氯苯基)-2-(2,4-二氟苯基)氧杂环丙烷-2-基]甲基}-2,4-二氢-3H-1,2,4-三唑-3-硫酮、(1.059)5-(4-氯苄基)-2-(氯甲基)-2-甲基-1-(1H-1,2,4-三唑-1-基甲基)环戊醇、(1.060)5-(烯丙基硫烷基)-1-{[3-(2-氯苯基)-2-(2,4-二氟苯基)氧杂环丙烷-2-基]甲基}-1H-1,2,4-三唑、(1.061)5-(烯丙基硫烷基)-1-{[rel(2R,3R)-3-(2-氯苯基)-2-(2,4-二氟苯基)氧杂环丙烷-2-基]甲基}-1H-1,2,4-三唑、(1.062)5-(烯丙基硫烷基)-1-{[rel(2R,3S)-3-(2-氯苯基)-2-(2,4-二氟苯基)氧杂环丙烷-2-基]甲基}-1H-1,2,4-三唑、(1.063)N'-(2,5-二甲基-4-{[3-(1,1,2,2-四氟乙氧基)苯基]硫烷基}苯基)-N-乙基-N-甲基亚氨基甲酰胺、(1.064)N'-(2,5-二甲基-4-{[3-(2,2,2-三氟乙氧基)苯基]硫烷基}苯基)-N-乙基-N-甲基亚氨基甲酰胺、(1.065)N'-(2,5-二甲基-4-{[3-(2,2,3,3-四氟丙氧基)苯基]硫烷基}苯基)-N-乙基-N-甲基亚氨基甲酰胺、(1.066)N'-(2,5-二甲基-4-{[3-(五氟乙氧基)苯基]硫烷基}苯基)-N-乙基-N-甲基亚氨基甲酰胺、(1.067)N'-(2,5-二甲基-4-{3-[(1,1,2,2-四氟乙基)硫烷基]苯氧基}苯基)-N-乙基-N-甲基亚氨基甲酰胺、(1.068)N'-(2,5-二甲基-4-{3-[(2,2,2-三氟乙基)硫烷基]苯氧基}苯基)-N-乙基-N-甲基亚氨基甲酰胺、(1.069)N'-(2,5-二甲基-4-{3-[(2,2,3,3-四氟丙基)硫烷基]苯氧基}苯基)-N-乙基-N-甲基亚氨基甲酰胺、(1.070)N'-(2,5-二甲基-4-{3-[(五氟乙基)硫烷基]苯氧基}苯基)-N-乙基-N-甲基亚氨基甲酰胺、(1.071)N'-(2,5-二甲基-4-苯氧基苯基)-N-乙基-N-甲基亚氨基甲酰胺、(1.072)N'-(4-{[3-(二氟甲氧基)苯基]硫烷基}-2,5-二甲基苯基)-N-乙基-N-甲基亚氨基甲酰胺、(1.073)N'-(4-{3-[(二氟甲基)硫烷基]苯氧基}-2,5-二甲基苯基)-N-乙基-N-甲基亚氨基甲酰胺、(1.074)N'-[5-溴-6-(2,3-二氢-1H-茚-2-基氧)-2-甲基吡啶-3-基]-N-乙基-N-甲基亚氨基甲酰胺、(1.075)N'-{4-[(4,5-二氯-1,3-噻唑-2-基)氧]-2,5-二甲基苯基}-N-乙基-N-甲基亚氨基甲酰胺、(1.076)N'-{5-溴-6-[(1R)-1-(3,5-二氟苯基)乙氧基]-2-甲基吡啶-3-基}-N-乙基-N-甲基亚氨基甲酰胺、(1.077)N'-{5-溴-6-[(1S)-1-(3,5-二氟苯基)乙氧基]-2-甲基吡啶-3-基}-N-乙基-N-甲基亚氨基甲酰胺、(1.078)N'-{5-溴-6-[(顺式-4-异丙基环己基)氧]-2-甲基吡啶-3-基}-N-乙基-N-甲基亚氨基甲酰胺、(1.079)N'-{5-溴-6-[(反式-4-异丙基环己基)氧]-2-甲基吡啶-3-基}-N-乙基-N-甲基亚氨基甲酰胺、(1.080)N'-{5-溴-6-[1-(3,5-二氟苯基)乙氧基]-2-甲基吡啶-3-基}-N-乙基-N-甲基亚氨基甲酰胺、(1.081)氯氟醚菌唑、(1.082)Ipfentrifluconazole。
2)复合物I或II中呼吸链的抑制剂，例如(2.001)苯并烯氟菌唑、(2.002)联苯吡菌胺、(2.003)啶酰菌胺、(2.004)萎锈灵、(2.005)氟吡菌酰胺、(2.006)氟酰胺、(2.007)氟唑菌酰胺、(2.008)呋吡菌胺、(2.009)Isofetamid、(2.010)吡唑萘菌胺(反式-差向异构体1R,4S,9S)、(2.011)吡唑萘菌胺(反式-差向异构体1S,4R,9R)、(2.012)吡唑萘菌胺(反式-差向异构外消旋物1RS,4SR,9SR)、(2.013)吡唑萘菌胺(顺式-差向异构外消旋物1RS,4SR,9RS与反式-差向异构外消旋物1RS,4SR,9SR的混合物)、(2.014)吡唑萘菌胺(顺式-差向异构体1R,4S,9R)、(2.015)吡唑萘菌胺(顺式-差向异构体1S,4R,9S)、(2.016)吡唑萘菌胺(顺式-差向异构外消旋物1RS,4SR,9RS)、(2.017)氟唑菌苯胺、(2.018)吡噻菌胺、(2.019)氟唑菌酰羟胺、(2.020)联苯吡嗪菌胺、(2.021)氟唑环菌胺、(2.022)1,3-二甲基-N-(1,1,3-三甲基-2,3-二氢-1H-茚-4-基)-1H-吡唑-4-甲酰胺、(2.023)1,3-二甲基-N-[(3R)-1,1,3-三甲基-2,3-二氢-1H-茚-4-基]-1H-吡唑-4-甲酰胺、(2.024)1,3-二甲基-N-[(3S)-1,1,3-三甲基-2,3-二氢-1H-茚-4-基]-1H-吡唑-4-甲酰胺、(2.025)1-甲基-3-(三氟甲基)-N-[2'-(三氟甲基)联苯-2-基]-1H-吡唑-4-甲酰胺、(2.026)2-氟-6-(三氟甲基)-N-(1,1,3-三甲基-2,3-二氢-1H-茚-4-基)苯甲酰胺、(2.027)3-(二氟甲基)-1-甲基-N-(1,1,3-三甲基-2,3-二氢-1H-茚-4-基)-1H-吡唑-4-甲酰胺、(2.028)3-(二氟甲基)-1-甲基-N-[(3R)-1,1,3-三甲基-2,3-二氢-1H-茚-4-基]-1H-吡唑-4-甲酰胺、(2.029)3-(二氟甲基)-1-甲基-N-[(3S)-1,1,3-三甲基-2,3-二氢-1H-茚-4-基]-1H-吡唑-4-甲酰胺、(2.030)3-(二氟甲基)-N-(7-氟-1,1,3-三甲基-2,3-二氢-1H-茚-4-基)-1-甲基-1H-吡唑-4-甲酰胺、(2.031)3-(二氟甲基)-N-[(3R)-7-氟-1,1,3-三甲基-2,3-二氢-1H-茚-4-基]-1-甲基-1H-吡唑-4-甲酰胺、(2.032)3-(二氟甲基)-N-[(3S)-7-氟-1,1,3-三甲基-2,3-二氢-1H-茚-4-基]-1-甲基-1H-吡唑-4-甲酰胺、(2.033)5,8-二氟-N-[2-(2-氟-4-{[4-(三氟甲基)吡啶-2-基]氧}苯基)乙基]喹唑啉-4-胺、(2.034)N-(2-环戊基-5-氟苄基)-N-环丙基-3-(二氟甲基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺、(2.035)N-(2-叔丁基-5-甲基苄基)-N-环丙基-3-(二氟甲基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺、(2.036)N-(2-叔丁基苄基)-N-环丙基-3-(二氟甲基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺、(2.037)N-(5-氯-2-乙基苄基)-N-环丙基-3-(二氟甲基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺、(2.038)N-(5-氯-2-异丙基苄基)-N-环丙基-3-(二氟甲基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺、(2.039)N-[(1R,4S)-9-(二氯亚甲基)-1,2,3,4-四氢-1,4-甲烷萘-5-基]-3-(二氟甲基)-1-甲基-1H-吡唑-4-甲酰胺、(2.040)N-[(1S,4R)-9-(二氯亚甲基)-1,2,3,4-四氢-1,4-甲烷萘-5-基]-3-(二氟甲基)-1-甲基-1H-吡唑-4-甲酰胺、(2.041)N-[1-(2,4-二氯苯基)-1-甲氧基丙烷-2-基]-3-(二氟甲基)-1-甲基-1H-吡唑-4-甲酰胺、(2.042)N-[2-氯-6-(三氟甲基)苄基]-N-环丙基-3-(二氟甲基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺、(2.043)N-[3-氯-2-氟-6-(三氟甲基)苄基]-N-环丙基-3-(二氟甲基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺、(2.044)N-[5-氯-2-(三氟甲基)苄基]-N-环丙基-3-(二氟甲基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺、(2.045)N-环丙基-3-(二氟甲基)-5-氟-1-甲基-N-[5-甲基-2-(三氟甲基)苄基]-1H-吡唑-4-甲酰胺、(2.046)N-环丙基-3-(二氟甲基)-5-氟-N-(2-氟-6-异丙基苄基)-1-甲基-1H-吡唑-4-甲酰胺、(2.047)N-环丙基-3-(二氟甲基)-5-氟-N-(2-异丙基-5-甲基苄基)-1-甲基-1H-吡唑-4-甲酰胺、(2.048)N-环丙基-3-(二氟甲基)-5-氟-N-(2-异丙基苄基)-1-甲基-1H-吡唑-4-碳硫酰胺、(2.049)N-环丙基-3-(二氟甲基)-5-氟-N-(2-异丙基苄基)-1-甲基-1H-吡唑-4-甲酰胺、(2.050)N-环丙基-3-(二氟甲基)-5-氟-N-(5-氟-2-异丙基苄基)-1-甲基-1H-吡唑-4-甲酰胺、(2.051)N-环丙基-3-(二氟甲基)-N-(2-乙基-4,5-二甲基苄基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺、(2.052)N-环丙基-3-(二氟甲基)-N-(2-乙基-5-氟苄基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺、(2.053)N-环丙基-3-(二氟甲基)-N-(2-乙基-5-甲基苄基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺、(2.054)N-环丙基-N-(2-环丙基-5-氟苄基)-3-(二氟甲基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺、(2.055)N-环丙基-N-(2-环丙基-5-甲基苄基)-3-(二氟甲基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺、(2.056)N-环丙基-N-(2-环丙基苄基)-3-(二氟甲基)-5-氟-1-甲基-1H-吡唑-4-甲酰胺。
3)作用于复合物III的呼吸链抑制剂，例如(3.001)苯唑嘧菌胺、(3.002)吲唑磺菌胺、(3.003)嘧菌酯、(3.004)甲香菌酯、(3.005)丁香菌酯、(3.006)氰霜唑、(3.007)醚菌胺、(3.008)烯肟菌酯、(3.009)噁唑菌酮、(3.010)咪唑菌酮、(3.011)氟菌螨酯、(3.012)氟嘧菌酯、(3.013)醚菌酯、(3.014)苯氧菌胺、(3.015)肟醚菌胺、(3.016)啶氧菌酯、(3.017)吡唑醚菌酯、(3.018)唑胺菌酯、(3.019)唑菌酯、(3.020)肟菌酯、(3.021)(2E)-2-{2-[({[(1E)-1-(3-{[(E)-1-氟-2-苯基乙烯基]氧}苯基)亚乙基]氨基}氧)甲基]苯基}-2-(甲氧基亚氨基)-N-甲基乙酰胺、(3.022)(2E,3Z)-5-{[1-(4-氯苯基)-1H-吡唑-3-基]氧}-2-(甲氧基亚氨基)-N,3-二甲基戊-3-烯酰胺、(3.023)(2R)-2-{2-[(2,5-二甲基苯氧基)甲基]苯基}-2-甲氧基-N-甲基乙酰胺、(3.024)(2S)-2-{2-[(2,5-二甲基苯氧基)甲基]苯基}-2-甲氧基-N-甲基乙酰胺、(3.025)(3S,6S,7R,8R)-8-苄基-3-[({3-[(异丁酰氧基)甲氧基]-4-甲氧基吡啶-2-基}羰基)氨基]-6-甲基-4,9-二氧代-1,5-二氧戊环-7-基2-甲基丙酸酯、(3.026)2-{2-[(2,5-二甲基苯氧基)甲基]苯基}-2-甲氧基-N-甲基乙酰胺、(3.027)N-(3-乙基-3,5,5-三甲基环己基)-3-甲酰氨基-2-羟基苯甲酰胺、(3.028)(2E,3Z)-5-{[1-(4-氯-2-氟苯基)-1H-吡唑-3-基]氧}-2-(甲氧基亚氨基)-N,3-二甲基戊-3-烯酰胺、(3.029){5-[3-(2,4-二甲基苯基)-1H-吡唑-1-基]-2-甲基苄基}氨基甲酸甲酯。
4)有丝分裂和细胞分裂抑制剂，例如(4.001)多菌灵、(4.002)乙霉威、(4.003)噻唑菌胺、(4.004)氟吡菌胺、(4.005)戊菌隆、(4.006)噻菌灵、(4.007)甲基硫菌灵、(4.008)苯酰菌胺、(4.009)3-氯-4-(2,6-二氟苯基)-6-甲基-5-苯基哒嗪、(4.010)3-氯-5-(4-氯苯基)-4-(2,6-二氟苯基)-6-甲基哒嗪、(4.011)3-氯-5-(6-氯吡啶-3-基)-6-甲基-4-(2,4,6-三氟苯基)哒嗪、(4.012)4-(2-溴-4-氟苯基)-N-(2,6-二氟苯基)-1,3-二甲基-1H-吡唑-5-胺、(4.013)4-(2-溴-4-氟苯基)-N-(2-溴-6-氟苯基)-1,3-二甲基-1H-吡唑-5-胺、(4.014)4-(2-溴-4-氟苯基)-N-(2-溴苯基)-1,3-二甲基-1H-吡唑-5-胺、(4.015)4-(2-溴-4-氟苯基)-N-(2-氯-6-氟苯基)-1,3-二甲基-1H-吡唑-5-胺、(4.016)4-(2-溴-4-氟苯基)-N-(2-氯苯基)-1,3-二甲基-1H-吡唑-5-胺、(4.017)4-(2-溴-4-氟苯基)-N-(2-氟苯基)-1,3-二甲基-1H-吡唑-5-胺、(4.018)4-(2-氯-4-氟苯基)-N-(2,6-二氟苯基)-1,3-二甲基-1H-吡唑-5-胺、(4.019)4-(2-氯-4-氟苯基)-N-(2-氯-6-氟苯基)-1,3-二甲基-1H-吡唑-5-胺、(4.020)4-(2-氯-4-氟苯基)-N-(2-氯苯基)-1,3-二甲基-1H-吡唑-5-胺、(4.021)4-(2-氯-4-氟苯基)-N-(2-氟苯基)-1,3-二甲基-1H-吡唑-5-胺、(4.022)4-(4-氯苯基)-5-(2,6-二氟苯基)-3,6-二甲基哒嗪、(4.023)N-(2-溴-6-氟苯基)-4-(2-氯-4-氟苯基)-1,3-二甲基-1H-吡唑-5-胺、(4.024)N-(2-溴苯基)-4-(2-氯-4-氟苯基)-1,3-二甲基-1H-吡唑-5-胺、(4.025)N-(4-氯-2,6-二氟苯基)-4-(2-氯-4-氟苯基)-1,3-二甲基-1H-吡唑-5-胺。
5)具有多位点活性的化合物，例如(5.001)波尔多混合剂、(5.002)敌菌丹、(5.003)克菌丹、(5.004)百菌清、(5.005)氢氧化铜、(5.006)环烷酸铜、(5.007)氧化铜、(5.008)王铜、(5.009)硫酸铜(2+)、(5.010)二噻农、(5.011)多果定、(5.012)灭菌丹、(5.013)代森锰锌、(5.014)代森锰、(5.015)代森联、(5.016)代森联锌(zinc metiram)、(5.017)羟基喹啉铜、(5.018)甲基代森锌、(5.019)硫和包含多硫化钙的硫制剂、(5.020)福美双、(5.021)代森锌、(5.022)福美锌、(5.023)6-乙基-5,7-二氧代-6,7-二氢-5H-吡咯并[3',4':5,6][1,4]二硫杂环己烯并[2,3-c][1,2]噻唑-3-甲腈。
6)能够触发宿主防御的化合物，例如(6.001)苯并噻二唑、(6.002)异噻菌胺、(6.003)烯丙苯噻唑、(6.004)噻酰菌胺。
7)氨基酸和/或蛋白质生物合成抑制剂，例如(7.001)嘧菌环胺、(7.002)春雷霉素、(7.003)春雷霉素盐酸盐水合物、(7.004)土霉素、(7.005)嘧霉胺、(7.006)3-(5-氟-3,3,4,4-四甲基-3,4-二氢异喹啉-1-基)喹啉。
8)ATP产生抑制剂，例如(8.001)硅噻菌胺。
9)细胞壁合成抑制剂，例如(9.001)苯噻菌胺、(9.002)烯酰吗啉、(9.003)氟吗啉、(9.004)异丙菌胺、(9.005)双炔酰菌胺、(9.006)丁吡吗啉、(9.007)霜霉灭、(9.008)(2E)-3-(4-叔丁基苯基)-3-(2-氯吡啶-4-基)-1-(吗啉-4-基)丙-2-烯-1-酮、(9.009)(2Z)-3-(4-叔丁基苯基)-3-(2-氯吡啶-4-基)-1-(吗啉-4-基)丙-2-烯-1-酮。
10)脂质和膜合成抑制剂，例如(10.001)霜霉威、(10.002)霜霉威盐酸盐、(10.003)甲基立枯磷。
11)黑色素生物合成抑制剂，例如(11.001)三环唑、(11.002)2,2,2-三氟乙基-{3-甲基-1-[(4-甲基苯甲酰)氨基]丁烷-2-基}氨基甲酸酯。
12)核酸合成抑制剂，例如(12.001)苯霜灵、(12.002)精苯霜灵(Kiralaxyl)、(12.003)甲霜灵、(12.004)精甲霜灵(Mefenoxam)。
13)信号转导抑制剂，例如(13.001)咯菌腈、(13.002)异菌脲、(13.003)腐霉利、(13.004)丙氧喹啉、(13.005)喹氧灵、(13.006)乙烯菌核利。
14)可充当解偶联剂的化合物，例如(14.001)氟啶胺、(14.002)消螨多。
15)其他化合物，例如(15.001)脱落酸、(15.002)苯噻硫氰、(15.003)bethoxazin、(15.004)卡巴西霉素(capsimycin)、(15.005)香芹酮、(15.006)灭螨猛、(15.007)硫杂灵、(15.008)环氟菌胺、(15.009)霜脲氰、(15.010)环丙磺酰胺、(15.011)氟噻菌净(flutianil)、(15.012)三乙膦酸铝、(15.013)三乙膦酸钙、(15.014)三乙膦酸钠、(15.015)异硫氰酸甲酯、(15.016)苯菌酮、(15.017)灭粉霉素、(15.018)纳他霉素、(15.019)二甲基二硫代氨基甲酸镍、(15.020)酞菌酯、(15.021)oxamocarb、(15.022)氟噻唑吡乙酮、(15.023)oxyfenthiin、(15.024)五氯苯酚和盐、(15.025)膦酸及其盐、(15.026)霜霉威乙膦酸盐、(15.027)甲氧苯唳菌(chlazafenone)、(15.028)tebufloquin、(15.029)叶枯酞、(15.030)甲磺菌胺、(15.031)1-(4-{4-[(5R)-5-(2,6-二氟苯基)-4,5-二氢-1,2-噁唑-3-基]-1,3-噻唑-2-基}哌啶-1-基)-2-[5-甲基-3-(三氟甲基)-1H-吡唑-1-基]乙酮、(15.032)1-(4-{4-[(5S)-5-(2,6-二氟苯基)-4,5-二氢-1,2-噁唑-3-基]-1,3-噻唑-2-基}哌啶-1-基)-2-[5-甲基-3-(三氟甲基)-1H-吡唑-1-基]乙酮、(15.033)2-(6-苄基吡啶-2-基)喹唑啉、(15.034)2,6-二甲基-1H,5H-[1,4]二硫杂环己烯并[2,3-c:5,6-c']二吡咯-1,3,5,7(2H,6H)-四酮、(15.035)2-[3,5-双(二氟甲基)-1H-吡唑-1-基]-1-[4-(4-{5-[2-(丙-2-炔-1-基氧)苯基]-4,5-二氢-1,2-噁唑-3-基}-1,3-噻唑-2-基)哌啶-1-基]乙酮、(15.036)2-[3,5-双(二氟甲基)-1H-吡唑-1-基]-1-[4-(4-{5-[2-氯-6-(丙-2-炔-1-基氧)苯基]-4,5-二氢-1,2-噁唑-3-基}-1,3-噻唑-2-基)哌啶-1-基]乙酮、(15.037)2-[3,5-双(二氟甲基)-1H-吡唑-1-基]-1-[4-(4-{5-[2-氟-6-(丙-2-炔-1-基氧)苯基]-4,5-二氢-1,2-噁唑-3-基}-1,3-噻唑-2-基)哌啶-1-基]乙酮、(15.038)2-[6-(3-氟-4-甲氧基苯基)-5-甲基吡啶-2-基]喹唑啉、(15.039)2-{(5R)-3-[2-(1-{[3,5-双(二氟甲基)-1H-吡唑-1-基]乙酰}哌啶-4-基)-1,3-噻唑-4-基]-4,5-二氢-1,2-噁唑-5-基}-3-氯苯基甲磺酸盐、(15.040)2-{(5S)-3-[2-(1-{[3,5-双(二氟甲基)-1H-吡唑-1-基]乙酰}哌啶-4-基)-1,3-噻唑-4-基]-4,5-二氢-1,2-噁唑-5-基}-3-氯苯基甲磺酸盐、(15.041)2-{2-[(7,8-二氟-2-甲基喹啉-3-基)氧]-6-氟苯基}丙烷-2-醇、(15.042)2-{2-氟-6-[(8-氟-2-甲基喹啉-3-基)氧]苯基}丙烷-2-醇、(15.043)2-{3-[2-(1-{[3,5-双(二氟甲基)-1H-吡唑-1-基]乙酰}哌啶-4-基)-1,3-噻唑-4-基]-4,5-二氢-1,2-噁唑-5-基}-3-氯苯基甲磺酸盐、(15.044)2-{3-[2-(1-{[3,5-双(二氟甲基)-1H-吡唑-1-基]乙酰}哌啶-4-基)-1,3-噻唑-4-基]-4,5-二氢-1,2-噁唑-5-基}苯基甲磺酸盐、(15.045)2-苯基苯酚及其盐、(15.046)3-(4,4,5-三氟-3,3-二甲基-3,4-二氢异喹啉-1-基)喹啉、(15.047)3-(4,4-二氟-3,3-二甲基-3,4-二氢异喹啉-1-基)喹啉、(15.048)4-氨基-5-氟嘧啶-2-醇(互变异构形式：4-氨基-5-氟嘧啶-2(1H)-酮)、(15.049)4-氧代-4-[(2-苯乙基)氨基]丁酸、(15.050)5-氨基-1,3,4-噻二唑-2-硫醇、(15.051)5-氯-N'-苯基-N'-(丙-2-炔-1-基)噻吩2-磺酰肼、(15.052)5-氟-2-[(4-氟苄基)氧]嘧啶-4-胺、(15.053)5-氟-2-[(4-甲基苄基)氧]嘧啶-4-胺、(15.054)9-氟-2,2-二甲基-5-(喹啉-3-基)-2,3-二氢-1,4-苯并氧氮杂
(15.055)丁-3-炔-1-基{6-[({[(Z)-(1-甲基-1H-四唑-5-基)(苯基)亚甲基]氨基}氧)甲基]吡啶-2-基}氨基甲酸酯、(15.056)(2Z)-3-氨基-2-氰基-3-苯基丙烯酸乙酯、(15.057)吩嗪-1-羧酸、(15.058)3,4,5-三羟基苯甲酸丙酯、(15.059)喹啉-8-醇、(15.060)喹啉-8-醇硫酸酯、(2:1),(15.061){6-[({[(1-甲基-1H-四唑-5-基)(苯基)亚甲基]氨基}氧)甲基]吡啶-2-基}氨基甲酸叔丁酯、(15.062)5-氟-4-亚氨基-3-甲基-1)磺酰]-3,4-二氢嘧啶-2(1H)-酮。
优选的杀真菌剂选自苯霜灵、联苯三唑醇、糠菌唑、敌菌丹、多菌灵、环丙酰菌胺、氰霜唑、环丙唑醇、乙霉威、克瘟散、丁苯吗啉、三苯锡(fentine)、氟喹唑、三乙膦酸、氟里醚、灭菌丹、双胍辛醋酸盐、异菌脲、异丙菌胺、春雷霉素、代森锰、代森钠、戊菌隆、丙氯灵、霜霉威、甲基代森锌、嘧霉胺、螺环菌胺、五氯硝基苯、戊唑醇、对甲抑菌灵、三唑酮、三唑醇、肟菌酯、代森锌。
杀昆虫剂、杀螨剂、杀线虫剂、杀疥虫药和相关的活性成分有例如(与除草剂和杀真菌剂类似，如果可能，这些化合物以其通用名称提及)：
(1)乙酰胆碱酯酶(AChE)抑制剂，优选氨基甲酸酯类，选自棉铃威(alanycarb)、涕灭威(aldicarb)、噁虫威(bendiocarb)、丙硫克百威(benfuracarb)、丁酮威(butocarboxim)、丁酮砜威(butoxycarboxim)、胺甲萘(carbaryl)、卡巴呋喃(carbofuran)、丁硫克百威(carbosulfan)、乙硫苯威(ethiofencarb)、仲丁威(fenobucarb)、伐虫脒(formetanate)、呋线威(furathiocarb)、异丙威(isoprocarb)、灭虫威(methiocarb)、灭多威(methomyl)、速灭威(metolcarb)、杀线威(oxamyl)、抗蚜威(pirimicarb)、残杀威(propoxur)、硫双威(thiodicarb)、久效威(thiofanox)、唑蚜威(triazamate)、混杀威(trimethacarb)、灭除威(XMC)和灭杀威(xylylcarb)；或有机磷酸酯类，选自高灭磷(acephate)、甲基吡噁磷(azamethiphos)、乙基谷硫磷(azinphos-ethyl)、谷硫磷(azinphos-methyl)、硫线磷(cadusafos)、氯氧磷(chlorethoxyfos)、毒虫畏(chlorfenvinphos)、氯甲硫磷(chlormephos)、甲基毒死蜱(chloropyrifos-methyl)、蝇毒磷(coumaphos)、杀螟腈(cyanophos)、甲基内吸磷(demeton-S-methyl)、二嗪农(diazinon)、敌敌畏(dichlorvos/DDVP)、百治磷(dicrotophos)、乐果(dimethoate)、甲基毒虫畏(dimethylvinphos)、乙拌磷(disulfoton)、苯硫磷(EPN)、乙硫磷(ethion)、灭线磷(ethoprophos)、伐灭磷(famphur)、苯线磷(fenamiphos)、杀螟松(fenitrothion)、倍硫磷(fenthion)、噻唑磷(fosthiazate)、庚烯磷(heptenophos)、imicyafos、异柳磷(isofenphos)、邻-(甲氧基氨基硫代磷酰基)水杨酸异丙酯、异噁唑啉(isoxathion)、马拉硫磷(malathion)、灭蚜磷(mecarbam)、甲胺磷(methamidophos)、杀扑磷(methidathion)、速灭磷(mevinphos)、久效磷(monocrotophos)、二溴磷(naled)、氧乐果(omethoate)、亚砜磷(oxydemeton-methyl)、对硫磷甲酯(parathion-methyl)、稻丰散(phenthoate)、甲拌磷(phorate)、伏杀磷(phosalone)、亚胺硫磷(phosmet)、磷胺(phosphamidon)、肟硫磷(phoxim)、甲基嘧啶磷(pirimiphos-methyl)、丙溴磷(profenofos)、胺丙畏(propetamphos)、丙硫磷(prothiofos)、吡唑硫磷(pyraclofos)、哒嗪硫磷(pyridaphenthion)、喹硫磷(quinalphos)、治螟磷(sulfotep)、丁基嘧啶磷(tebupirimfos)、双硫磷(temephos)、特丁硫磷(terbufos)、司替罗磷(tetrachlorvinphos)、甲基乙拌磷(thiometon)、三唑磷(triazophos)、triclorfon和蚜灭磷(vamidothion)。
(2)GABA-门控氯离子通道拮抗剂，优选环戊二烯有机氯类，选自氯丹(chlordane)和硫丹(endosulfan)；或苯基吡唑类(fiproles)，选自乙虫腈(ethiprole)和氟虫腈(fipronil)。
(3)钠通道调节剂，优选拟除虫菊酯(pyrethroid)类，选自氟丙菊酯(acrinathrin)、丙烯除虫菊酯(allethrin)、d-顺-反丙烯除虫菊酯(d-cis-transallethrin)、d-反丙烯除虫菊酯(d-transallethrin)、联苯菊酯(bifenthrin)、生物烯丙菊酯(bioallethrin)、生物烯丙菊酯S-环戊烯基异构体(bioallethrin S-cyclopentenylisomer)、除虫菊酯(bioresmethrin)、乙氰菊酯(cycloprothrin)、氟氯氰菊酯(cyfluthrin)、β-氟氯氰菊酯(beta-cyfluthrin)、三氟氯氰菊酯(cyhalothrin)、λ-三氟氯氰菊酯(lambda-cyhalothrin)、γ-三氟氯氰菊酯(gamma-cyhalothrin)、氯氰菊酯(cypermethrin)、α-氯氰菊酯(alpha-cypermethrin)、β-氯氰菊酯(beta-cypermethrin)、θ-氯氰菊酯(theta-cypermethrin)、ζ-氯氰菊酯(zeta-cypermethrin)、苯醚氰菊酯[(1R)-反式异构体](cyphenothrin[(1R)-trans isomers])、溴氰菊酯(deltamethrin)、右旋烯炔菊酯[(EZ)-(1R)异构体](empenthrin[(EZ)-(1R)isomers])、高氰戊菊酯(esfenvalerate)、依芬普司(etofenprox)、甲氰菊酯(fenpropathrin)、氰戊菊酯(fenvalerate)、氟氰戊菊酯(flucythrinate)、氟氯苯菊酯(flumethrin)、τ-氟胺氰菊酯(tau-fluvalinate)、苄螨醚(halfenprox)、炔咪菊酯(imiprothrin)、噻嗯菊酯(kadethrin)、momfluorothrin、苄氯菊酯(permethrin)、苯醚菊酯[(1R)-反式异构体](phenothrin[(1R)-trans isomer])、炔丙菊酯(prallethrin)、除虫菊酯(pyrethrine、pyrethrum)、苄呋菊酯(resmethrin)、氟硅菊酯(silafluofen)、七氟菊酯(tefluthrin)、胺菊酯(tetramethrin)、胺菊酯[(1R)异构体)](tetramethrin[(1R)isomers])、四溴菊酯(tralomethrin)和四氟苯菊酯(transfluthrin)；或DDT；或甲氧氯。
(4)烟碱型乙酰胆碱受体(nAChR)竞争性调节剂，优选新烟碱类(neonicotinoids)，选自啶虫脒(acetamiprid)、噻虫胺(clothianidin)、呋虫胺(dinotefuran)、吡虫啉(imidacloprid)、烯啶虫胺(nitenpyram)、噻虫啉(thiacloprid)和噻虫嗪(thiamethoxam)或尼古丁(nicotine)；或亚砜亚胺类，选自氟啶虫胺腈(sulfoxaflor)；或丁烯酸内酯类，选自氟吡呋喃酮(flupyradifurone)。
(5)烟碱乙酰胆碱受体(nAChR)变构调节剂，优选多杀菌素类(spinosyns)，选自乙基多杀菌素(spinetoram)和多杀菌素(spinosad)。
(6)谷氨酸门控氯离子通道(GluCl)变构调节剂，优选阿维菌素类/米尔倍霉素类(avermectins/milbemycins)，选自阿维菌素(abamectin)、甲氨基阿维菌素苯甲酸盐(emamectin benzoate)、雷皮菌素(lepimectin)和灭螨菌素(milbemectin)。
(7)保幼激素模仿物，优选保幼激素类似物，选自烯虫乙酯(hydroprene)、烯虫炔酯(kinoprene)和烯虫酯(methoprene)或苯氧威(fenoxycarb)或蚊蝇醚(pyriproxyfen)。
(8)其他非特异性(多位点)抑制剂，优选烷基卤化物，选自甲基溴化物和其他烷基卤化物；或氯化苦(chloropicrine)或硫酰氟或硼砂或吐酒石(tartar emetic)；或异氰酸甲酯生成剂类，选自diazomet和威百亩(metam)。
(9)声音器官的TRPV通道调节剂，选自吡蚜酮(pymetrozine)和氟虫吡喹(pyrifluquinazon)。
(10)螨生长抑制剂，选自四螨嗪(clofentezine)、噻螨酮(hexythiazox)、氟螨嗪(diflovidazin)和乙螨唑(etoxazole)。
(11)昆虫中肠膜的微生物干扰剂，选自苏云金芽孢杆菌以色列亚种(Bacillusthuringiensis subspecies israelensis)、球形芽孢杆菌(Bacillus sphaericus)、苏云金芽胞杆菌鲇泽亚种(Bacillus thuringiensis subspecies aizawai)、苏云金芽孢杆菌库尔斯塔克亚种(Bacillus thuringiensis subspecies kurstaki)、苏云金芽孢杆菌拟步行甲亚种(Bacillus thuringiensis subspecies tenebrionis)和B.t.植物蛋白：Cry1Ab、Cry1Ac、Cry1Fa、Cry1A.105、Cry2Ab、VIP3A、mCry3A、Cry3Ab、Cry3Bb和Cry34Ab1/35Ab1。
(12)线粒体ATP合成酶的抑制剂，优选ATP干扰剂，选自丁醚脲；或有机锡化合物，选自三唑锡(azocyclotin)、三环锡(cyhexatin)和苯丁锡(fenbutatin oxide)；或克螨特(propargite)或四氯杀螨砜(tetradifon)。
(13)经由中断质子梯度的氧化磷酸化去耦剂，选自虫螨腈(chlorfenapyr)、二硝甲酚(DNOC)和氟虫胺(sulfluramid)。
(14)烟碱型乙酰胆碱受体通道阻断剂，选自杀虫磺(bensultap)、杀螟丹盐酸盐(cartap hydrochloride)、杀虫环(thiocyclam)和杀虫双(thiosultap-sodium)。
(15)0型几丁质生物合成抑制剂，选自双三氟虫脲(bistrifluron)、定虫隆(chlofluazuron)、二氟脲(diflubenzuron)、氟环脲(flucycloxuron)、氟虫脲(flufenoxuron)、氟铃脲(hexaflumuron)、氯芬奴隆(lufenuron)、双苯氟脲(novaluron)、多氟脲(noviflumuron)、氟苯脲(teflubenzuron)和杀铃脲(triflumuron)。
(16)1型几丁质生物合成抑制剂，选自噻嗪酮(buprofezin)。
(17)蜕皮干扰剂(尤其是在双翅目情况下)，选自灭蝇胺(cyromazine)。
(18)蜕皮激素受体激动剂，选自环虫酰胺(chromafenozide)、氯虫酰肼(halofenozide)、甲氧虫酰肼(methoxyfenozide)和虫酰肼(tebufenozide)。
(19)章鱼胺受体激动剂，选自双甲脒(amitraz)。
(20)线粒体复合物-III电子传递抑制剂，选自氟蚁腙(hydramethylnone)，或灭螨醌(acequinocyl)和嘧螨酯(fluacrypyrim)。
(21)线粒体复合物-I电子传递抑制剂，优选METI杀螨剂，选自喹螨醚(fenazaquin)、唑螨酯(fenpyroximate)、嘧螨醚(pyrimidifen)、哒螨灵(pyridaben)、吡螨胺(tebufenpyrad)和唑虫酰胺(tolfenpyrad)；或鱼藤酮(rotenone)(鱼藤属)。
(22)电压依赖性钠通道阻断剂，选自茚虫威(indoxacarb)和氰氟虫腙(metaflumizone)。
(23)乙酰基-CoA羧化酶的抑制剂，优选季酮酸(tetronic)和特特拉姆酸(tetramic acid)衍生物，选自螺螨酯(spirodiclofen)、螺甲螨酯(spiromesifen)和螺虫乙酯(spirotetramat)。
(24)线粒体复合物IV电子传递抑制剂，优选膦类，选自磷化铝、磷化钙、膦化氢和磷化锌；或氰化物类，选自氰化钙、氰化钾和氰化钠。
(25)线粒体复合物II电子传递抑制剂，优选β-酮腈衍生物，选自腈吡螨酯(cyenopyrafen)和丁氟螨酯(cyflumetofen)；或羧苯胺类，选自pyflubumide。
(28)利阿诺定受体调节剂，优选二酰胺类，选自氯虫苯甲酰胺(chlorantraniliprole)、溴氰虫酰胺(cyantraniliprole)和氟虫酰胺(flubendiamide)。
(29)声音器官的调节剂(具有未定义的靶结构)，选自氟啶虫酰胺(flonicamid)。
(30)其他活性成分，选自acynonapyr、afidopyropen、阿福拉纳(afoxolaner)、印楝素(azadirachtin)、benclothiaz、苯螨特(benzoximate)、benzpyrimoxan、联苯肼酯(bifenazate)、溴虫氟苯双酰胺(broflanilide)、溴螨酯(bromopropylate)、灭螨锰(chinomethionat)、倍速菊酯(chloroprallethrin)、冰晶石(cryolite)、环溴虫酰胺(cyclaniliprole)、环氧虫啶(cycloxaprid)、氯氟氰虫酰胺(cyhalodiamide)、二氯噻吡嘧啶(dicloromezotiaz)、三氯杀螨醇(dicofol)、ε-甲氧苄氟菊酯(epsilon metofluthrin)、epsilon momfluthrin、flometoquin、三氟咪啶酰胺(fluazaindolizine)、氟噻虫砜(fluensulphone)、嘧虫胺(flufenerim)、氟菌螨酯(flufenoxystrobin)、丁虫腈(flufiprole)、fluhexafon、氟吡菌酰胺(fluopyram)、flupyrimin、氟雷拉纳(fluralaner)、fluxametamide、呋喃虫酰肼(fufenozide)、戊吡虫胍(guadipyr)、heptafluthrin、氯噻啉(imidaclothiz)、异菌脲(iprodione)、κ-联苯菊酯(kappabifenthrin)、κ-七氟菊酯(kappa tefluthrin)、洛替拉纳(lotilaner)、氯氟醚菊酯(meperfluthrin)、oxazosulfyl、哌虫啶(paichongding)、三氟甲吡醚(pyridalyl)、pyrifluquinazon、嘧螨胺(pyriminostrobin)、螺螨双酯(spirobudiclofen)、甲氧哌啶乙酯(spiropidion)、四氟醚菊酯(tetramethylfluthrin)、四唑虫酰胺(tetraniliprole)、四氯虫酰胺(tetrachlorantraniliprole)、tigolaner、tioxazafen、硫氟肟醚(thiofluoximate)、三氟苯嘧啶(triflumezopyrim)和碘甲烷(iodomethane)；另外，基于坚强芽孢杆菌(Bacillus firmus,I-1582,BioNeem,Votivo)的制剂，以及下列化合物：1-{2-氟-4-甲基-5-[(2,2,2-三氟乙基)亚磺酰基]苯基}-3-(三氟甲基)-1H-1,2,4-三唑-5-胺(由WO2006/043635已知)(CAS 885026-50-6)、{1'-[(2E)-3-(4-氯苯基)丙-2-烯-1-基]-5-氟螺[吲哚-3,4'-哌啶]-1(2H)-基}(2-氯吡啶-4-基)甲酮(由WO2003/106457已知)(CAS637360-23-7)、2-氯-N-[2-{1-[(2E)-3-(4-氯苯基)丙-2-烯-1-基]哌啶-4-基}-4-(三氟甲基)苯基]异烟酰胺(由WO2006/003494已知)(CAS 872999-66-1)、3-(4-氯-2,6-二甲基苯基)-4-羟基-8-甲氧基-1,8-二氮杂螺[4.5]癸-3-烯-2-酮(由WO 2010052161已知)(CAS1225292-17-0)、3-(4-氯-2,6-二甲基苯基)-8-甲氧基-2-氧代-1,8-二氮杂螺[4.5]癸-3-烯-4-基乙基碳酸酯(由EP 2647626已知)(CAS-1440516-42-6)、4-(丁-2-炔-1-基氧)-6-(3,5-二甲基哌啶-1-基)-5-氟嘧啶(由WO2004/099160已知)(CAS 792914-58-0)、PF1364(由JP2010/018586已知)(CAS登记号1204776-60-2)、(3E)-3-[1-[(6-氯-3-吡啶基)甲基]-2-亚吡啶基]-1,1,1-三氟丙烷-2-酮(由WO2013/144213已知)(CAS 1461743-15-6)、N-[3-(苄基氨基甲酰)-4-氯苯基]-1-甲基-3-(五氟乙基)-4-(三氟甲基)-1H-吡唑-5-甲酰胺(由WO2010/051926已知)(CAS 1226889-14-0)、5-溴-4-氯-N-[4-氯-2-甲基-6-(甲基氨基甲酰)苯基]-2-(3-氯-2-吡啶基)吡唑-3-甲酰胺(由CN103232431已知)(CAS 1449220-44-3)、4-[5-(3,5-二氯苯基)-4,5-二氢-5-(三氟甲基)-3-异噁唑基]-2-甲基-N-(顺-1-氧桥-3-噻丁环基)苯甲酰胺、4-[5-(3,5-二氯苯基)-4,5-二氢-5-(三氟甲基)-3-异噁唑基]-2-甲基-N-(反-1-氧桥-3-噻丁环基)苯甲酰胺和4-[(5S)-5-(3,5-二氯苯基)-4,5-二氢-5-(三氟甲基)-3-异噁唑基]-2-甲基-N-(顺-1-氧桥-3-噻丁环基)苯甲酰胺(由WO 2013/050317A1已知)(CAS 1332628-83-7)、N-[3-氯-1-(3-吡啶基)-1H-吡唑-4-基]-N-乙基-3-[(3,3,3-三氟丙基)亚磺酰基]丙酰胺、(+)-N-[3-氯-1-(3-吡啶基)-1H-吡唑-4-基]-N-乙基-3-[(3,3,3-三氟丙基)亚磺酰基]丙酰胺和(-)-N-[3-氯-1-(3-吡啶基)-1H-吡唑-4-基]-N-乙基-3-[(3,3,3-三氟丙基)亚磺酰基]丙酰胺(由WO 2013/162715 A2、WO 2013/162716 A2、US 2014/0213448 A1已知)(CAS 1477923-37-7)、5-[[(2E)-3-氯-2-丙烯-1-基]氨基]-1-[2,6-二氯-4-(三氟甲基)苯基]-4-[(三氟甲基)亚磺酰基]-1H-吡唑-3-腈(由CN101337937 A已知)(CAS 1105672-77-2)、3-溴-N-[4-氯-2-甲基-6-[(甲基氨基)硫氧代甲基]苯基]-1-(3-氯-2-吡啶基)-1H-吡唑-5-甲酰胺(Liudaibenjiaxuanan，由CN 103109816A已知)(CAS 1232543-85-9)；N-[4-氯-2-[[(1,1-二甲基乙基)氨基]羰基]-6-甲基苯基]-1-(3-氯-2-吡啶基)-3-(氟甲氧基)-1H-吡唑-5-甲酰胺(由WO 2012/034403 A1已知)(CAS1268277-22-0)、N-[2-(5-氨基-1,3,4-噻二唑-2-基)-4-氯-6-甲基苯基]-3-溴-1-(3-氯-2-吡啶基)-1H-吡唑-5-甲酰胺(由WO 2011/085575 A1已知)(CAS 1233882-22-8)、4-[3-[2,6-二氯-4-[(3,3-二氯-2-丙烯-1-基)氧]苯氧基]丙氧基]-2-甲氧基-6-(三氟甲基)嘧啶(由CN 101337940 A已知)(CAS 1108184-52-6)；(2E)-和2(Z)-2-[2-(4-氰基苯基)-1-[3-(三氟甲基)苯基]亚乙基]-N-[4-(二氟甲氧基)苯基]肼羧酰胺(由CN 101715774 A已知)(CAS 1232543-85-9)；环丙烷羧酸3-(2,2-二氯乙烯基)-2,2-二甲基-4-(1H-苯并咪唑-2-基)苯基酯(由CN 103524422 A已知)(CAS 1542271-46-4)；(4aS)-7-氯-2,5-二氢-2-[[(甲氧基羰基)[4-[(三氟甲基)硫代]苯基]氨基]羰基]茚并[1,2-e][1,3,4]噁二嗪-4a(3H)-羧酸甲酯(由CN 102391261 A已知)(CAS 1370358-69-2)；6-脱氧-3-O-乙基-2,4-二-O-甲基-1-[N-[4-[1-[4-(1,1,2,2,2-五氟乙氧基)苯基]-1H-1,2,4-三唑-3-基]苯基]氨基甲酸酯]-α-L-甘露吡喃糖(由US 2014/0275503 A1已知)(CAS 1181213-14-8)；8-(2-环丙基甲氧基-4-三氟甲基苯氧基)-3-(6-三氟甲基哒嗪-3-基)-3-氮杂双环[3.2.1]辛烷(CAS1253850-56-4)、(8-反)-8-(2-环丙基甲氧基-4-三氟甲基苯氧基)-3-(6-三氟甲基哒嗪哒嗪-3-基)-3-氮杂双环[3.2.1]辛烷(CAS 933798-27-7)、(8-顺)-8-(2-环丙基甲氧基-4-三氟甲基苯氧基)-3-(6-三氟甲基哒嗪-3-基)-3-氮杂双环[3.2.1]辛烷(由WO 2007040280A1、WO 2007040282 A1已知)(CAS 934001-66-8)、N-[3-氯-1-(3-吡啶基)-1H-吡唑-4-基]-N-乙基-3-[(3,3,3-三氟丙基)硫代]丙酰胺(由WO 2015/058021 A1、WO 2015/058028 A1已知)(CAS 1477919-27-9)和N-[4-(氨基硫氧代甲基)-2-甲基-6-[(甲基氨基)羰基]苯基]-3-溴-1-(3-氯-2-吡啶基)-1H-吡唑-5-甲酰胺(由CN 103265527 A已知)(CAS 1452877-50-7)、5-(1,3-二噁烷-2-基)-4-[[4-(三氟甲基)苯基]甲氧基]嘧啶(由WO 2013/115391 A1已知)(CAS 1449021-97-9)、3-(4-氯-2,6-二甲基苯基)-8-甲氧基-1-甲基-1,8-二氮杂螺[4.5]癸烷-2,4-二酮(由WO 2014/187846 A1已知)(CAS 1638765-58-8)、3-(4-氯-2,6-二甲基苯基)-8-甲氧基-1-甲基-2-氧代-1,8-二氮杂螺[4.5]癸-3-烯-4-基甲酸乙酯(由WO2010/066780 A1、WO 2011151146 A1已知)(CAS 1229023-00-0)、4-[(5S)-5-(3,5-二氯-4-氟苯基)-4,5-二氢-5-(三氟甲基)-3-异噁唑基]-N-[(4R)-2-乙基-3-氧代-4-异噁唑烷基]-2-甲基苯甲酰胺(由WO 2011/067272、WO2013/050302已知)(CAS 1309959-62-3)。
可优选与除草剂一起使用的杀昆虫剂是例如如下：
啶虫脒(acetamiprid)、氟丙菊酯(acrinathrin)、涕灭威(aldicarb)、双甲脒(amitraz)、acinphos-methyl、氟氯氰菊酯(cyfluthrin)、胺甲萘(carbaryl)、氯氰菊酯(cypermethrin)、溴氰菊酯(deltamethrin)、硫丹(endosulfan)、灭线磷(ethoprophos)、苯线磷(fenamiphos)、倍硫磷(fenthion)、氟虫腈(fipronil)、吡虫啉(imidacloprid)、甲胺磷(methamidophos)、甲硫威(methiocarb)、氯硝柳胺(niclosamide)、亚砜磷(oxydemeton-methyl)、丙硫磷(prothiophos)、氟硅菊酯(silafluofen)、噻虫啉(thiacloprid)、硫双威(thiodicarb)、四溴菊酯(tralomethrin)、三唑磷(triazophos)、敌百虫(trichlorfon)、杀铃脲(triflumuron)、特丁磷(terbufos)、地虫磷(fonofos)、甲拌磷(phorate)、毒死蜱(chlorpyriphos)、卡巴呋喃(carbofuran)、七氟菊酯(tefluthrin)。
本发明的活性成分组合适合于控制未开垦的土地上、道路上、铁路轨道上、工业区中(“工业杂草控制”)或种植园作物中如温和、亚热带和热带气候或地理区域中的广谱杂草。种植园作物的实例有油棕榈、坚果类(例如，杏仁、榛子、胡桃、澳洲坚果)、椰子、浆果、橡胶树、柑橘类(例如，橙子、柠檬、柑橘)、香蕉、菠萝、棉花、甘蔗、茶、咖啡、可可等。它们同样适合用于果树栽培(例如，苹果、梨、樱桃、芒果和猕猴桃等仁果类)和葡萄栽培中。所述组合物还可用于播种准备(“灭生性”、“免耕”或“零耕”方法)或用于收割后的处理(“化学休耕”)。活性成分组合的可能用途还扩展到树木作物中的杂草控制，例如幼龄圣诞树作物或桉树作物，分别在种植前或种植后施用(包括顶部处理(“over-top”))。
还可以使用所述组合物来控制经济上重要的作物植物如小麦(硬质和软质小麦)、玉米、大豆、甜菜、甘蔗、棉花、水稻、豆类(例如，矮菜豆和蚕豆)、亚麻、大麦、燕麦、黑麦、黑小麦、马铃薯和小米/高粱、牧场和草地/草坪及种植园作物中不希望有的植物生长。种植园作物尤其是有仁果类(苹果、梨、木瓜)、醋栗属物种(黑莓、覆盆子)、柑橘类、李属物种(樱桃、油桃、杏树)、坚果类(胡桃、山核桃、榛子、腰果、澳洲坚果)、芒果、可可、咖啡、葡萄藤(用于食用或酿酒)、棕榈树(如油棕榈、椰枣树、椰子树)、桉树、柿树、柿子、天然橡胶、菠萝、香蕉、鳄梨、荔枝、森林培育物(桉科、松科、云杉科、楝科等)。
本发明的除草活性成分组合，在相应的使用形式(＝除草产品)中，在除草作用和选择性方面具有协同作用，并且在杂草谱方面具有有利的作用。它们对广谱的经济上重要的单子叶和双子叶一年生有害植物具有优异的除草功效。所述活性成分还对难以控制的多年生有害植物具有良好的控制作用并从根茎、根状茎或其他多年生性器官产生幼苗。
对于施用，可将活性成分组合应用到植物(例如，有害植物如单子叶或双子叶杂草或不希望有的作物植物)、种子(例如，谷粒、种子或营养繁殖器官如块茎或有芽苞的幼苗的一部分)或植物生长的区域(例如，生长区域)上。
所述物质可在播种前(任选也可通过掺入到土壤中)、芽前过程或芽后过程应用。在种植园作物中，优先通过早期播种后芽前过程方法或芽后过程方法来使用以对抗尚未出苗或已经出苗的有害植物。也可将施用整合到杂草管理系统中，分批多次施用(顺序施用)。
可由根据本发明的活性成分组合控制的单子叶和双子叶杂草植物群的一些代表的具体实例有如下，但该列举并不旨在对特定物种施加限制。
在单子叶杂草物种中，例如，一年生的涵盖有山羊草属、冰草属、剪股颖属、看麦娘属、假剪股颖属、燕麦属、臂形草属(Brachicaria)、雀麦属、狗牙根属、龙爪茅属、马唐属、稗属、荸荠属、穇属、画眉草属、野黍属、羊茅属、飘拂草属、白茅属、鸭嘴草属、异蕊花属、白茅属、千金子属、黑麦草属、雨久花属、黍属、雀稗属、虉草属、梯牧草属、早熟禾属、筒轴茅属、慈姑属、藨草属、狗尾草属、高粱属、尖瓣花属和莎草属种类。
在双子叶杂草物种的情况下，作用谱扩展到物种如苘麻属、苋属、豚草属、单花葵属(Anoda)、春黄菊属、霓裳草属(Aphanes)、蒿属、滨藜属、雏菊属、鬼针草属、荠属、飞廉属、决明属、矢车菊属、黎属、蓟属、旋花植物、曼陀罗属、山蚂蝗属、角刺酸模属、牻牛儿苗属、糖芥属、大戟属、鼬瓣花属、牛膝菊属、拉拉藤属、老鹳草属、木槿属、番薯属、野芝麻属、独荇菜属、母草属、母菊属、薄荷属、山靛属、粟米草属、勿忘草属、罂粟属、牵牛属、车前属、蓼属、马齿苋属、毛茛属、萝卜属、蔊菜属、节节菜属、酸模属、猪毛菜属、千里光属、田菁属、黄花稔属、百芥属、茄属、苦苣菜属、楔瓣花属、繁缕属、蒲公英属、菥蓂属、车轴草属、荨麻属、婆婆纳属、堇菜属、苍耳属。
如果在萌芽前将本发明的活性成分组合施用于土壤表面，则要么完全阻止杂草幼苗的出苗，要么杂草生长直至达到子叶阶段，但随后停止生长并最终在过去三至四个星期后完全死亡。
如果在植物的绿色部分芽后过程施用活性成分，则生长将在处理后停止，并且有害植物将停留在施用时的生长阶段，或在一定时间后完全死亡，因此，这将很早就并以持续的方式消除对作物植物有害的杂草的竞争。
本发明的除草产品以起效快速且除草作用持续时间长而突出。通常，本发明的组合中活性成分的耐雨性是有利的。一个特别的优点在于可将组合中使用的化合物(A)和(B)的有效剂量调节到低至其土壤作用最佳地低的水平。因此，不仅能够将其用于敏感作物，而且还将实际上防止地下水污染。本发明的活性成分的组合允许显著降低活性成分的所需施用量。
除草剂(A)和(B)的组合使用取得的应用技术性质超越了基于构成其组合的一种单独的除草剂的已知性质而预期的应用技术性质。例如，对特定的有害植物物种的除草效果超过了如可通过标准方法(例如，根据Colby或其他外推方法)估计的预期值。
任何时候只要活性成分组合的效果(这里，除草效果)大于单独施用的活性成分的效果的总和时，就存在协同效应。两种活性成分的给定组合的预期活性可根据S.R.Colby(“Calculating Synergistic and Antagonistic Responses of HerbicideCombinations”,Weeds 15(1967),20-22)(见下文)计算。
协同效应因此允许例如减少单个活性成分的施用量、在相同施用量下更高的功效、控制尚未涵盖(空白)的有害植物物种、提高残留作用、延长功效期、提高作用速度、延长施用期和/或减少所需的单独施用的次数，以及-对用户的结果是-杂草控制系统在经济和生态上更有利。
尽管本发明的组合对单子叶和双子叶杂草具有优异的除草活性，但取决于本发明的相应活性成分组合的结构及其施用量，许多经济上重要的作物植物仅受到微不足道的损害(如果有的话)。这里，经济上重要的作物有例如来自花生属、甜菜属、芸薹属、黄瓜属、南瓜属、向日葵属、胡萝卜属、棉属、番薯属、莴苣属、亚麻属、番茄属、烟草属、菜豆属、茄属的双子叶作物或者来自葱属、凤梨属、天门冬属、燕麦属、大麦属、稻属、黍属、甘蔗属、黑麦属、高粱属、黑小麦属、小麦属和玉米属的单子叶作物。
另外，本发明的产品在一些情况下在作物植物中具有突出的生长调节性质。它们通过调节作用干预植物自身的新陈代谢，并因此可用于植物成分的受控影响和促进收成，例如通过引发干燥和矮化生长。此外，它们还适合于不希望有的营养生长的一般控制和抑制而不在此过程中杀死植物。营养生长的抑制对许多单子叶和双子叶作物起着重要作用，因为这可减少或完全防止倒伏。
由于它们的除草和植物生长调节性质，故可使用该组合物来控制已知植物作物中或仍有待开发、已通过常规诱变修饰或遗传修饰的抗性作物植物中的有害植物。通常，转基因植物除了对本发明的组合物的抵抗性之外，还以特定的有利性质为特征，例如对植物病害或引起植物病害的生物如某些昆虫或微生物如真菌、细菌或病毒的抵抗性。其他特别的性质涉及例如收成物的数量、质量、可储存性、组成和特定成分方面。例如，已知淀粉含量升高或淀粉质量改变的转基因植物，或者收成物中脂肪酸组成不同的那些。其他特别的性质可为对非生物压力源的抗性或抵抗性，例如热、低温、干旱、盐度和紫外辐射。
本发明的活性成分组合可优选地用作经济植物作物中的除草剂，所述作物对除草剂的植物毒性作用具有抵抗性或已通过基因工程使得其对除草剂的植物毒性作用具有抵抗性。
产生与现有植物相比具有改良性质的新植物的常规方法包括例如传统栽培方法和突变体的产生。或者，可借助于重组方法来产生具有改良性质的新植物(参见，例如，EP-A-0221044、EP-A-0131624)。例如，已有若干情况的描述：
-以修饰植物中合成的淀粉为目的的作物植物遗传修饰(例如，WO 92/11376、WO92/14827、WO 91/19806)，
-表现出对其他除草剂、例如对磺酰脲的抵抗性的转基因作物植物(EP-A-0257993、US-A-5013659)，
-具有产生苏云金芽孢杆菌毒素(Bt毒素)的能力的转基因作物植物，该能力使得植物对特定的害虫具有抵抗性(EP-A-0142924、EP-A-0193259)，
-具有修饰的脂肪酸组成的转基因作物植物(WO 91/13972)，
-具有新成分或次生代谢物例如新的植物抗毒素的遗传改性作物植物，这可提高抗病性(EPA 309862、EPA0464461)，
-光呼吸减少的遗传改性植物，其具有更高的产量和更高的耐逆性(EPA0305398)，
-产生药学或诊断上重要的蛋白质的转基因作物植物(“分子农业医药”)，
-具有更高产量或更好质量的转基因作物植物，
-具有例如上述新性质的组合(“基因叠加”)的转基因作物植物。
可用于产生具有改良性质的新型转基因植物的许多分子生物学技术原则上是已知的；参见例如I.Potrykus和G.Spangenberg(编者)Gene Transfer to Plants,SpringerLab Manual(1995),Springer Verlag Berlin,Heidelberg；或Christou,"Trends inPlant Science"1(1996)423-431。
对于这样的基因技术操作，可将允许通过DNA序列的重组进行诱变或序列改变的核酸分子引入到质粒中。借助标准方法，可以例如进行碱基交换、去除部分序列或添加天然或合成序列。为了将DNA片段彼此连接起来，可以向片段添加接头或连接子；例如参见Sambrook等人,1989,Molecular Cloning,A Laboratory Manual,2nd ed.,Cold SpringHarbor Laboratory Press,Cold Spring Harbor,NY；或Winnacker"Gene und Klone”,VCHWeinheim，第二版，1996。
例如，可通过表达至少一种相应的反义RNA、用于实现共抑制作用的正义RNA，或通过表达至少一种适当构建的特异性切割上述基因产物的转录物的核酶，来产生基因产物活性降低的植物细胞。
为此，首先可以使用涵盖基因产物的整个编码序列(包括可能存在的任何侧翼序列)的DNA分子，和此外仅涵盖部分编码序列的DNA分子，其中这些部分必须足够长以在细胞中具有反义效应。也可以使用与基因产物的编码序列具有高度同源性但不与其完全相同的DNA序列。
当在植物中表达核酸分子时，合成的蛋白质可位于植物细胞的任何期望的区室中。然而，为了实现在特定区室中的定位，可以例如将编码区与将确保在特定区室中定位的DNA序列联结。这样的序列是本领域技术人员已知的(参见例如Braun等人,EMBO J.11(1992),3219-3227；Wolter等人,Proc.Natl.Acad.Sci.USA 85(1988),846-850；Sonnewald等人,Plant J.1(1991),95-106)。核酸分子也可在植物细胞的细胞器中表达。
转基因植物细胞可通过已知的技术再生以产生完整的植物。原则上，转基因植物可以是任何期望的植物物种的植物，即不仅可以是单子叶植物，而且可以是双子叶植物。以这种方式可获得性质通过同源(＝天然)基因或基因序列的过表达、压制或抑制或者异源(＝外源)基因或基因序列的表达而改变的转基因植物。
本发明的活性成分组合可优选用于对所用活性成分具有抗性或已被赋予抗性的转基因作物中。
本发明的活性成分组合还可优选用于对生长调节剂例如麦草畏或者对将抑制必需植物酶的除草剂例如乙酰乳酸合酶(ALS)、EPSP合酶、谷氨酰胺合酶(GS)或羟基苯基丙酮酸双加氧酶(HPPD)或者对来自磺酰脲类、草甘膦类、草铵膦类或苯甲酰异噁唑类及类似活性成分的除草剂具有抵抗性的转基因作物中。
本发明的主题因此还是一种控制不希望有的植物生长的方法，任选地在经济植物作物中，优选地在未开垦的土地上或在种植园作物中，其特征在于将一种或多种类型(A)的除草剂与一种或多种类型(B)的除草剂一起施用于有害植物、植物的部分或植物种子(籽)或施用于生长区域。
本发明的主题还是化合物(A)+(B)的新组合用于控制有害植物的用途，任选地在经济植物作物中，优选地在未开垦的土地和种植园作物上，但也用于在后续作物植物的播种之前控制有害植物，如特别是用于播种准备(“灭生性施用”)。
本发明的活性成分组合可呈所述两种组分、任选与其他的活性成分、添加剂和/或惯用配制助剂的混合配制物的形式，其然后以惯用方式用水稀释施用，或者可通过用水共同稀释分开配制或部分地分开配制的组分而制备为所谓的桶混物。
化合物(A)和(B)或其组合可根据需要的生物学和/或物理化学参数以各种方式配制。一般的配制物选项的实例有：喷雾粉剂(WP)、水溶性粉剂(SP)、可乳化浓缩物(EC)、水溶性浓缩物、水溶液(SL)、乳液(EW)如水包油和油包水乳液、可喷雾溶液或乳液、基于油或水的分散体、油分散体(OD)、悬浮乳液、悬浮浓缩物(SC)、油混溶溶液、胶囊悬浮液(CS)、喷粉产品(DP)、敷料、用于土壤施用或撒播的颗粒、微粒形式的颗粒(GR)、喷雾颗粒、吸收和吸附颗粒、水分散性颗粒(WG)、水溶性颗粒(SG)、ULV配制物、微胶囊或蜡。
本发明的主题因此还是含有本发明的活性成分组合的除草和植物生长调节组合物。
各个类型的配制物原则上是已知的并见述于例如：Winnacker-Küchler,"Chemische Technologie",第7卷,C.Hanser Verlag Munich,第四版1986；vanValkenburg,"Pesticides Formulations",Marcel Dekker,N.Y.,1973；K.Martens,"SprayDrying Handbook",第三版，1979,G.Goodwin Ltd.London中。
所需的配制助剂，如惰性材料、表面活性剂、溶剂和其他添加剂，同样是已知的并见述于例如：Watkins,"Handbook of Insecticide Dust Diluents and Carriers",第二版,Darland Books,Caldwell N.J.；H.v.Olphen,"Introduction to Clay ColloidChemistry"；第二版,J.Wiley&Sons,N.Y.Marsden,"Solvents Guide",第二版,Interscience,N.Y.1963；McCutcheon's"Detergents and Emulsifiers Annual",MCPubl.Corp.,Ridgewood N.J.；Sisley and Wood,"Encyclopedia of Surface ActiveAgents",Chem.Publ.Co.Inc.,N.Y.1964,
Wiss.Verlagsgesell.,Stuttgart 1976；Winnacker-Küchler,"Chemische Technologie”,第7卷,C.Hanser Verlag Munich,第四版，1986中。
在这些配制物的基础上，还可以生产与其他杀虫活性物质的组合，如其他除草剂、杀真菌剂、杀昆虫剂或其他杀害虫剂(例如，杀螨剂、杀线虫剂、杀软体动物剂、灭鼠剂、杀蚜剂、杀鸟剂、杀幼虫剂、杀卵剂、杀菌剂、杀病毒剂等)，并也可与肥料和/或生长调节剂组合，例如以成品配制物或以桶混物的形式。
喷雾粉剂为可均匀分散在水中的制剂，除了活性成分，在除稀释剂或惰性物质之外，还包含离子型和/或非离子型的表面活性剂(润湿剂、分散剂)，例如聚氧乙基化烷基酚、聚氧乙基化脂肪醇、聚氧乙基化脂肪胺、脂肪醇聚乙二醇醚硫酸盐、链烷磺酸盐、烷基苯磺酸盐、木质素磺酸钠、2,2'-二萘基甲烷-6,6'-二磺酸钠、二丁基萘磺酸钠抑或油酰甲基牛磺酸钠。为了产生喷雾粉剂，将除草活性成分磨细，例如在惯用装置如锤磨机、鼓风磨机和喷气磨机中，并同时或随后与配制助剂混合。
可乳化浓缩物通过将活性成分溶解在有机溶剂例如丁醇、环己酮、二甲基甲酰胺、二甲苯抑或相对高沸点的芳烃或烃或有机溶剂的混合物中并添加一种或多种离子和/或非离子表面活性剂(乳化剂)来制备。可使用的乳化剂的实例有：烷基芳基磺酸钙盐，如十二烷基苯磺酸钙，或非离子乳化剂如脂肪酸聚乙二醇酯、烷基芳基聚乙二醇醚、脂肪醇聚乙二醇醚、环氧丙烷-环氧乙烷缩合产物、烷基聚醚，失水山梨醇酯，例如失水山梨醇脂肪酸酯或例如聚氧乙烯失水山梨醇脂肪酸酯。
喷粉产品通过将活性成分与精细分布的固体例如滑石、天然粘土如高岭土、膨润土和叶蜡石或硅藻土一起研磨获得。
悬浮浓缩物可以是基于水的或基于油的。它们可例如通过借助于商业珠磨机湿磨并任选地添加如已在上文例如针对其他配制物类型列出的表面活性剂来产生。
乳液剂，例如水包油乳液(EW)，可例如借助于搅拌器、胶体磨和/或静态混合器使用水性有机溶剂和任选地如已在上文例如针对其他配制物类型列出的表面活性剂来产生。
颗粒剂可通过将活性成分喷洒到能够吸附的颗粒状惰性材料上或通过借助于粘合剂例如聚乙烯醇、聚丙烯酸钠抑或矿物油向载体物质如砂、高岭土或颗粒状惰性材料的表面施加活性成分浓缩物来制备。合适的活性成分也可以生产肥料颗粒的惯用方式造粒——如果需要作为与肥料的混合物的话。
水分散性颗粒通常通过方法如喷雾干燥、流化床造粒、盘式造粒、用高速混合器混合和挤出来生产而不用固体惰性材料。
农业化学制剂通常含有0.1至99重量％、尤其是0.2重量％至95重量％的类型(A)和/或(B)的活性成分，取决于配制物的类型，以下浓度是惯用的：
在喷雾粉剂中，活性成分浓度为例如约10重量％至95重量％，至100重量％的其余部分由惯用的配制成分组成。在可乳化浓缩物的情况下，活性成分浓度可为约1重量％至90重量％，优选5至80重量％。
呈粉剂形式的配制物通常含有5重量％至20重量％的活性成分；可喷雾溶液含有约0.05至80、优选2至50重量百分数(重量％)的活性成分。
在颗粒剂如可分散颗粒的情况下，活性成分含量部分取决于活性化合物是呈液体还是固体形式以及所使用的造粒助剂和填料。通常，水分散性颗粒中的含量在1重量％与95重量％之间，优选在10重量％与80重量％之间。
另外，所提及的活性成分配制物任选地包含相应的惯用粘合剂、润湿剂、分散剂、乳化剂、渗透剂、防腐剂、防冻剂和溶剂、填料、着色剂和载体、消泡剂、蒸发抑制剂和pH值或粘度调节剂。
对于施用，任选以惯用的方式稀释市售形式的配制物，例如在喷雾粉剂、可乳化浓缩物、分散体和水分散性颗粒的情况下用水稀释。粉剂类型制剂、用于土壤施用或撒播的颗粒剂和可喷雾溶液在施用前通常不用其他惰性物质进一步稀释。
活性成分可应用到植物、植物部分、植物种子或栽培区域(土壤)上，优选应用在绿色植物和植物部分上，并任选地还应用到土壤上。
一种可能的使用是以桶混物的形式共同施用活性成分，其中将各活性成分的最佳配制的浓缩配制物一起在桶中与水混合，并应用所获得的喷雾液。
根据本发明的活性成分(A)和(B)的组合的共同除草配制物的优点在于它可更容易地施用，因为已将组分的量相对于彼此设置在正确的比率下。此外，配制物中的助剂可相对于彼此最佳地调节，而不同配制物的桶混可能导致不希望的助剂组合。
A.通用类型的配制物实施例
a)通过混合10重量份的活性成分(A)或(B)或活性成分混合物(A)+(B)(和任选地其他活性成分组分)和/或其盐及90重量份作为惰性物质的滑石并在打浆磨机中粉碎来获得喷粉产品。
b)通过混合25重量份的活性成分/活性成分混合物、64重量份作为惰性物质的含高岭土石英、10重量份的木质素磺酸钾和1重量份作为润湿剂和分散剂的油酰甲基牛磺酸钠并在针盘磨机中研磨该混合物来获得易于在水中分散的喷雾粉剂。
c)通过混合20重量份的活性成分/活性成分混合物与6重量份的烷基酚聚乙二醇醚(
X 207)、3重量份的异十三醇聚乙二醇醚(8EO)和71重量份的石蜡矿物油(沸程例如大约255至277℃)并在摩擦球磨机中研磨该混合物至低于5微米的细度来获得易于在水中分散的分散体浓缩物。
d)由15重量份的活性成分/活性成分混合物、75重量份作为溶剂的环己酮和10重量份作为乳化剂的氧乙基化壬基酚得到可乳化浓缩物。
e)通过混合75重量份的活性成分/活性成分混合物、10重量份的木质素磺酸钙、5重量份的月桂基硫酸钠、3重量份的聚乙烯醇和7重量份的高岭土，在针盘磨机中研磨该混合物并在流化床中通过喷洒水作为造粒液对粉末造粒来获得水分散性颗粒。
f)还通过在胶体磨中均化并预粉碎25重量份的活性成分/活性成分混合物、5重量份的2,2’-二萘基甲烷-6,6’-二磺酸钠、2重量份的油酰甲基牛磺酸钠、1重量份的聚乙烯醇、17重量份的碳酸钙和50重量份的水，然后在珠磨机中研磨该混合物并在喷雾塔中借助于一段式喷嘴雾化和干燥所得悬浮体来获得水分散性颗粒。
B.生物学实施例
在采用本发明的组合时，经常观察到对有害植物物种的除草作用超过所存在的除草剂在单独施用时的作用的形式总和。或者，在一些情况下，可以观察到，与单独的制剂相比，除草剂组合需要较小的施用量即可达到对有害植物物种相同的效果。这样的作用的增加或有效性的增加或施用量的降低是协同效应的强烈指示。
当观察到的功效已超过采用单独施用的试验的值的形式总和时，它们也超过了根据Colby的预期值(该预期值使用以下公式计算)，并同样被视为协同作用的指示(参见S.R.Colby；在Weeds 15(1967)第20至22页中)：
EC＝A+B-(A·B/100)
其中：
A＝活性成分(A)在a g a.i./ha的施用量下的功效(％)；
B＝活性成分(B)在b g a.i./ha的施用量下的功效(％)；
EC＝组合(A)+(B)在组合施用量a+b g a.i./ha下的效果的预期值(％)。
给定合适的低剂量，来自实验的观察值(EA)表明组合的效果超过了根据Colby的预期值(Δ)。
1.对杂草的芽后过程作用
将单子叶和双子叶杂草的种子或根茎块放在盆中的砂壤土中，用土壤覆盖并在生长条件(温度、空气湿度、供水)良好的温室中生长。播种后三周，在三叶期用本发明的组合物处理试验植物。将配制为喷雾粉末或乳液浓缩物的本发明的组合物以各种剂量用折合300至800l/ha的水施用量喷洒到绿色植物部分上。在让试验植物在温室中于最佳生长条件下留置约3至4周后，以目测方式与未经处理的对照相比地对制剂的作用进行评分。本发明的组合物还对广谱的经济上重要的杂草和阔叶杂草具有良好的芽后过程除草有效性。
这里经常观察到本发明的组合的效果超过在单独施用除草剂的情况下的效果的形式总和。给定合适的低剂量，来自实验的观察值表明组合的效果超过了根据Colby的预期值。
2.芽前过程和芽后过程除草作用(田间试验)
根据第1节的温室实验在室外地块上进行实验。评定与第1节中的实验类似。
3.除草作用和作物植物相容性(田间试验)
通过布置典型的有害植物的种子或根茎块或者利用天然杂草植物群，在室外地块上于自然室外条件下种植作物植物。用本发明的组合物的处理在有害植物和作物植物出苗之后进行，一般在2叶至4叶期时进行；在一些情况下(如所指定)，在芽前过程施用或者以部分芽前过程和/或芽后过程的顺序处理施用单独的活性成分或活性成分组合。
在种植园作物的情况下，通常仅用活性成分处理各作物植物之间的土壤。
施用后，例如施用后2、4、6和8周，以目测方式通过与未经处理的对照相比地评定制剂的效果。本发明的组合物也在田间试验中对广谱的经济上重要的杂草和阔叶杂草具有协同除草活性。比较表明，本发明的组合通常具有比单独的除草剂的效果的总和更大、在一些情况下显著更大的除草作用，并因此表明了协同作用。评定期间大部分时间的效果也高于根据Colby的预期值，因此同样表明了协同作用。相比之下，作为用除草产品处理的结果，作物植物没有受到损害或者仅受到微不足道的损害。
4.具体试用实施例
在随后的描述和表格中使用了以下缩写：
g a.i./ha＝每公顷的活性物质(活性成分)(＝100％活性成分)克数；
单独施用的效果的总和以EA报告；
根据Colby的预期值分别以EC报告。
根据本发明的组合物的生物学结果汇总于表3.1-3.2中。评定期以施用后的天数(DAT)报告。
表3.1：在芽后过程中施用的包含来自组B2的除草剂的除草二元组合物的协同效应(Δ)
表3.2：在芽后过程中施用的包含来自组B7的除草剂的除草二元组合物的协同效应(Δ)
根据本发明的组合物的进一步的生物学结果汇总于表3.3-3.4中。评定期以施用后的天数(DAT)报告。
表3.3：在芽后过程中施用的包含除草剂A1的除草二元组合物的协同效应(Δ)
表3.4：在芽后过程中施用的包含除草剂A8的除草二元组合物的协同效应(Δ)
Claims (19)
1.包含除草活性化合物(A)和(B)的组合物，其中
(A)代表一种或多种通式(I)的化合物或其农业化学上可接受的盐[除草剂(A)]，
其中：
G为式OR4或NR11R12的基团；
R1和R2分别彼此独立地为氢、卤素或氰基，
或者
为(C1-C4)-烷基或(C1-C4)-烷氧基，其分别被m个选自卤素和氰基的基团所取代；
R3为氰基或氟，
或者
为(C1-C5)-烷基、(C3-C6)-环烷基、(C2-C5)-烯基、(C2-C5)-炔基或(C1-C5)-烷氧基，其分别被m个选自卤素、氰基、(C1-C5)-烷氧基和羟基的基团所取代；
R4为氢，
或者
为(C1-C12)-烷基、(C3-C7)-环烷基、(C3-C7)-环烷基-(C1-C8)-烷基、(C2-C8)-烯基、(C5-C6)-环烯基或(C2-C8)-炔基，其分别被m个选自卤素、氰基、(C1-C6)-烷氧基、羟基和芳基的基团所取代；
Y为氧或硫；
W为氧或硫；
Z代表被k个选自R10的基团所取代的单不饱和环戊烷环，
其中箭头分别代表朝向式(I)的基团C＝W的键；
R10为卤素、氰基或CO2R7，
或者
为(C1-C2)-烷基或(C1-C2)-烷氧基，其分别被m个选自氟和氯的基团所取代；
R11、R12分别彼此独立地为氢、氰基、OR7、S(O)nR5、SO2NR6R7、CO2R8、CONR6R8、COR6、NR6R8、NR6COR8、NR6CONR8R8、NR6CO2R8、NR6SO2R8、NR6SO2NR6R8、C(R6)＝NOR8、任选取代的芳基、任选取代的杂芳基和任选取代的杂环基，
或者
为(C1-C12)-烷基、(C3-C8)-环烷基、(C3-C7)-环烷基-(C1-C7)-烷基、(C2-C12)-烯基、(C5-C7)-环烯基或(C2-C12)-炔基，其分别被m个选自卤素、氰基、硝基、OR7、S(O)nR5、SO2NR6R7、CO2R8、CONR6R8、COR6、NR6R8、NR6COR8、NR6CONR8R8、NR6CO2R8、NR6SO2R8、NR6SO2NR6R8、C(R6)＝NOR8、任选取代的芳基、任选取代的杂芳基和任选取代的杂环基的基团所取代，
或者
R11和R12与它们所键合的氮原子一起形成饱和的、部分或完全不饱和的五-、六-或七-元环，所述环任选被选自卤素、氰基、硝基、(C1-C6)-烷基、卤代-(C1-C6)-烷基、氧代、OR7、S(O)nR5、SO2NR6R7、CO2R8、CONR6R8、COR6、NR6R8、NR6COR8、NR6CONR8R8、NR6CO2R8、NR6SO2R8、NR6SO2NR6R8和C(R6)＝NOR8的基团单取代至六取代，并且除了该氮原子外，所述环还含有r个碳原子、o个氧原子、p个硫原子和q个选自NR7和NCOR7的要素作为环原子；
X2、X4和X6分别彼此独立地为氢、卤素或氰基，
或者
为(C1-C2)-烷基，其分别被m个选自氟、氯、溴和(C1-C2)-烷氧基的基团所取代；
X3和X5分别彼此独立地为氢、氟、氯、溴、碘、羟基、氰基、硝基、S(O)nR6或CO2R7，
或者
为(C1-C3)-烷基、(C1-C3)-烷氧基、(C3-C4)-环烷基、(C2-C3)-烯基或(C2-C3)-炔基，其分别被m个选自氟、氯和溴的基团所取代；
R5为(C1-C8)-烷基、(C3-C6)-环烷基或芳基，其分别被m个选自卤素、氰基和羟基的基团所取代；
R6为氢或R5；
R7为氢，
或者
为(C1-C6)-烷基、(C3-C6)-环烷基、(C3-C4)-烯基或(C3-C4)-炔基，其分别被m个选自卤素、氰基和(C1-C2)-烷氧基的基团所取代；
R8为氢，
或者
为(C1-C8)-烷基、(C3-C6)-环烷基、(C3-C8)-烯基或(C3-C8)-炔基，其分别被m个选自卤素、氰基和(C1-C2)-烷氧基的基团所取代；
k为数字0、1或2；其中，当k>1时，R10可彼此独立地相同或不同；
m为数字0、1、2、3、4或5；
n为数字0、1或2；
o为数字0、1或2；
p为数字0或1；
q为数字0或1；和
r为数字3、4、5或6；
和
(B)代表一种或多种选自除草活性成分(B1)至(B11)的除草剂[组分(B)]，其中
(B1)代表来自1,3-二酮化合物的除草活性成分，选自：
(B1.1)禾草灭，
(B1.2)双环吡喃酮，
(B1.3)丁苯草酮，
(B1.4)烯草酮，
(B1.5)噻草酮，
(B1.6)芬喹草酮，
(B1.7)甲基磺草酮，
(B1.8)唑啉草酯，
(B1.9)环苯草酮，
(B1.10)烯禾啶，
(B1.11)磺草酮，
(B1.12)SYP-9121
(B1.13)特糠酯酮，
(B1.14)环磺酮(Tembotrione)，
(B1.15)吡喃草酮，
(B1.16)三甲苯草酮，
(B1.17)Y13161,
(B1.18)Y13287；
(B2)代表来自(磺)酰胺的除草活性成分，选自：
(B2.1)乙草胺，
(B2.2)甲草胺，
(B2.3)酰嘧磺隆，
(B2.4)磺草灵，
(B2.5)四唑嘧磺隆，
(B2.6)氟丁酰草胺，
(B2.7)苄嘧磺隆，
(B2.8)丁草胺，
(B2.9)双酰草胺，
(B2.10)氯嘧磺隆，
(B2.11)氯苯胺灵，
(B2.12)氯磺隆，
(B2.13)醚磺隆，
(B2.14)氯酯磺草胺，
(B2.15)环丙嘧磺隆，
(B2.16)甜草灵，
(B2.17)双氯磺草胺，
(B2.18)吡氟草胺，
(B2.19)二甲草胺，
(B2.20)二甲噻草胺，
(B2.21)戊草丹
(B2.22)胺苯磺隆，
(B2.23)乙氧嘧磺隆，
(B2.24)啶嘧磺隆，
(B2.25)双氟磺草胺，
(B2.26)氟酮磺隆，
(B2.27)氟吡磺隆，
(B2.28)氟噻草胺，
(B2.29)唑嘧磺草胺，
(B2.30)氟啶嘧磺隆，
(B2.31)甲酰胺磺隆，
(B2.32)氯吡嘧磺隆，
(B2.33)唑吡嘧磺隆，
(B2.34)碘甲磺隆，
(B2.35)艾分卡巴腙，
(B2.36)苯噻酰草胺，
(B2.37)甲基二磺隆，
(B2.38)吡唑草胺，
(B2.39)嗪吡嘧磺隆，
(B2.40)异丙甲草胺，
(B2.41)磺草唑胺，
(B2.42)甲磺隆，
(B2.43)烟嘧磺隆，
(B2.44)嘧苯胺磺隆，
(B2.45)环氧嘧磺隆，
(B2.46)五氟磺草胺，
(B2.47)烯草胺，
(B2.48)甜菜宁，
(B2.49)氯吡酰草胺，
(B2.50)丙草胺，
(B2.51)氟嘧磺隆，
(B2.52)毒草胺，
(B2.53)敌稗，
(B2.54)苯胺灵；
(B2.55)异丙草胺，
(B2.56)丙苯磺隆，
(B2.57)丙嗪嘧磺隆，
(B2.58)戊炔草胺，
(B2.59)苄草丹，
(B2.60)氟磺隆，
(B2.61)吡嘧磺隆，
(B2.62)啶磺草胺，
(B2.63)砜嘧磺隆，
(B2.64)精异丙甲草胺，
(B2.65)嘧磺隆，
(B2.66)磺酰磺隆，
(B2.67)噻吩草胺，
(B2.68)噻酮磺隆，
(B2.69)噻磺隆，
(B2.70)野麦畏，
(B2.71)醚苯磺隆，
(B2.72)苯磺隆，
(B2.73)三氟啶磺隆，
(B2.74)氟胺磺隆，
(B2.75)三氟甲磺隆，
(B2.76)戊草丹，
(B2.77)氟唑草胺，
(B2.78)野麦畏；
(B3)代表来自芳基腈的除草活性成分，选自：
(B3.1)溴草腈，
(B3.2)草克乐，
(B3.3)敌草腈，
(B3.4)碘苯腈，
(B3.5)双唑草腈；
(B4)代表来自唑的除草活性成分，选自：
(B4.1)氨唑草酮，
(B4.2)杀草强，
(B4.3)唑啶草酮，
(B4.4)吡草酮，
(B4.5)苯唑氟草酮，
(B4.6)双唑草酮，
(B4.7)唑草胺，
(B4.8)快灭灵，
(B4.9)四唑酰草胺，
(B4.10)咪草酸，
(B4.11)甲氧咪草烟，
(B4.12)甲基咪草烟，
(B4.13)咪唑烟酸，
(B4.14)咪唑喹啉酸，
(B4.15)咪唑乙烟酸，
(B4.16)异噁隆，
(B4.17)异噁草胺，
(B4.18)异噁唑草酮，
(B4.19)丙炔噁草酮，
(B4.20)噁草灵，
(B4.21)吡草醚，
(B4.22)磺酰草吡唑，
(B4.23)吡唑特，
(B4.24)苄草唑，
(B4.25)砜吡草唑，
(B4.26)磺酰唑草酮，
(B4.27)Tolpyralate，
(B4.28)苯唑草酮，
(B4.29)三唑磺草酮(QYR-301)，
(B4.30)QYM-201,
(B4.31)苯卡巴腙，
(B4.32)异丙吡草酯，
(B4.33)氟胺草唑，
(B4.34)异噁氯草酮；
(B5)代表其他除草活性成分，选自：
(B5.1)环丙嘧啶酸，
(B5.2)氯氨吡啶酸，
(B5.3)草除灵，
(B5.4)氟草胺，
(B5.5)灭草松，
(B5.6)双环磺草酮，
(B5.8)杀草全，
(B5.9)地乐胺，
(B5.10)氯草敏/杀草敏，
(B5.11)氯酞酸，
(B5.12)吲哚酮草酯，
(B5.13)环庚草醚，
(B5.14)异噁草松，
(B5.15)Cyclopyrimorate，
(B5.16)氨氟灵，
(B5.17)敌草快，
(B5.18)氟硫草定，
(B5.19)乙酸，
(B5.20)乙丁烯氟灵，
(B5.21)乙氧呋草黄，
(B5.22)异丙草氟安，
(B5.23)氯氟吡啶酯，
(B5.24)氟哒嗪草酯，
(B5.25)氟烯草酸，
(B5.26)丙炔氟草胺，
(B5.27)氟啶草酮，
(B5.28)氟咯草酮，
(B5.29)呋草酮，
(B5.30)氟噻乙草酯，
(B5.31)氟氯吡啶酸，
(B5.32)茚草酮，
(B5.33)氟草敏，
(B5.34)油酸，
(B5.35)安磺灵，
(B5.36)噁嗪草酮，
(B5.37)对草快，
(B5.38)天竺葵酸，
(B5.39)二甲戊灵，
(B5.40)环戊噁草酮，
(B5.41)哒草特代谢物，
(B5.42)哒草特，
(B5.43)Tetflupyrolimet，
(B5.44)噻唑烟酸，
(B5.45)氟酮磺草胺，
(B5.46)氟乐灵；
(B5.47)4-氨基-3-氯-5-氟-6-(7-氟-1H-吲哚-6-基)吡啶-2-甲酸，
(B5.48)Cyclopyrimorate，
(B5.49)敌草快，
(B5.50)噁嗪草酮，
(B5.51)甲氯酰草胺，
(B5.52)牧草胺，
(B5.53)噻二唑草胺；
(B6)代表来自(杂)芳基羧酸的除草活性成分，选自：
(B6.1)草灭平，
(B6.2)二氯吡啶酸，
(B6.3)麦草畏，
(B6.4)氟草定，
(B6.5)毒莠定，
(B6.6)二氯喹啉酸，
(B6.7)喹草酸，
(B6.8)TBA，
(B6.9)三氯吡氧乙酸；
(B7)代表来自有机磷化合物的除草活性成分，选自：
(B7.1)莎稗磷，
(B7.2)双丙氨磷，
(B7.3)抑草磷，
(B7.4)草铵膦，
(B7.5)草甘膦，
(B7.6)哌草磷，
(B7.7)草硫膦，
(B7.8)胺草磷，
(B8)代表来自苯基醚的除草活性成分，选自：
(B8.1)2,4-D，
(B8.2)2,4-DB,
(B8.3)2,4-DP,
(B8.4)三氟羧草醚，
(B8.5)苯草醚，
(B8.6)治草醚，
(B8.7)甲氧除草醚，
(B8.8)炔草酯，
(B8.9)氯甲酰草胺，
(B8.10)氰氟草酯，
(B8.11)禾草灵，
(B8.12)氟乳醚，
(B8.13)噁唑禾草灵，
(B8.14)吡氟禾草灵，
(B8.15)乙羧氟草醚，
(B8.16)氟磺胺草醚，
(B8.17)氟硝磺酰胺，
(B8.18)氟吡禾灵，
(B8.19)乳氟禾草灵，
(B8.20)MCPA，
(B8.21)MCPB，
(B8.22)2-甲-4-氯丙酸，
(B8.23)噁唑酰草胺，
(B8.24)乙氧氟草醚，
(B8.25)喔草酯，
(B8.26)喹禾灵，
(B8.27)精喹禾灵，
(B8.28)双苯嘧草酮；
(B9)代表来自嘧啶的除草活性成分，选自：
(B9.1)双草醚，
(B9.2)除草定，
(B9.3)氟丙嘧草酯，
(B9.4)环草定，
(B9.5)嘧啶肟草醚，
(B9.6)环酯草醚，
(B9.7)嘧草醚，
(B9.8)吡硫磺，
(B9.9)嘧草硫醚，
(B9.10)苯嘧磺草胺，
(B9.11)特草定，
(B9.12)氟嘧硫草酯，
(B9.13)三氟草嗪；
(B9.14)[3-[2-氯-4-氟-5-(1-甲基-6-三氟甲基-2,4-二氧代-1,2,3,4-四氢嘧啶-3-基)苯氧基]-2-吡啶氧基]乙酸乙酯；
(B10)代表来自(硫)脲的除草活性成分，选自：
(B10.1)氯溴隆，
(B10.2)绿麦隆，
(B10.3)杀草隆，
(B10.4)噁唑隆，
(B10.5)敌草隆，
(B10.6)氟吡草腙，
(B10.7)氟草隆，
(B10.8)异丙隆，
(B10.9)利谷隆，
(B10.10)甲基苯噻隆，
(B10.11)溴谷隆，
(B10.12)甲氧隆，
(B10.13)绿谷隆，
(B10.14)草不隆，
(B10.15)环草隆，
(B10.16)丁唑隆，
(B10.17)非草隆，
(B10.18)枯草隆，
(B10.19)氟吡草腙，
(B10.20)磺噻隆；
(B11)代表来自三嗪的除草活性成分，选自：
(B11.1)莠灭净，
(B11.2)莠去津，
(B11.3)草净津，
(B11.4)异戊净，
(B11.5)环嗪酮，
(B11.6)茚嗪氟草胺，
(B11.7)苯嗪草酮，
(B11.8)赛克津，
(B11.9)扑灭通，
(B11.10)扑草净，
(B11.11)扑灭津，
(B11.12)西玛津，
(B11.13)西草净，
(B11.14)特丁通，
(B11.15)特丁津，
(B11.16)特丁净，
(B11.17)三嗪氟草胺，
(B11.18)草达津，
(B11.19)敌草净。
2.根据权利要求1所述的组合物，其中所述通式(I)的组分(A)定义如下：
G为式OR4的基团；
R1和R2分别为氢；
R3为(C1-C3)-烷基、(C3-C4)-环烷基、(C2-C3)-烯基或(C1-C3)-烷氧基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R4为氢，或者(C1-C3)-烷基或(C2-C4)-烯基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
Y为氧；
W为氧；
Z代表基团Z-1、Z-4和Z-6：
其中箭头分别代表朝向式(I)的基团C＝W的键；
X2、X4和X6分别彼此独立地为氢或氟；
X3和X5分别彼此独立地为氢、氟、氰基或甲基；和
m为数字0、1、2或3。
3.根据权利要求1所述的组合物，其中所述通式(I)的组分(A)定义如下：
G为式NR11R12的基团；
R1和R2分别为氢；
R3为(C1-C3)-烷基、(C3-C4)-环烷基、(C2-C3)-烯基或(C1-C3)-烷氧基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
Y为氧；
W为氧；
Z为基团Z-1、Z-4和Z-6：
其中箭头分别代表朝向式(I)的基团C＝W的键；
X2、X4和X6分别彼此独立地为氢或氟；
X3和X5分别彼此独立地为氢、氟、氰基或甲基；
R5为(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟和氯的基团所取代；
R6为氢或R5；
R7为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R8为氢，或者(C1-C6)-烷基或(C3-C6)-环烷基，其分别被m个选自氟、氯和(C1-C2)-烷氧基的基团所取代；
R11为氢或(C1-C3)-烷基；
R12为OR7、S(O)nR5、SO2NR6R7或分别被m个选自氟、氯、氰基、OR7和S(O)nR5的基团所取代的(C1-C6)-烷基；
或者
R11和R12与它们所键合至的氮原子一起形成饱和的、部分或完全不饱和的五-或六-元环，所述环任选被选自卤素、(C1-C6)-烷基、卤代-(C1-C6)-烷基和氧代的基团单取代至三取代，并且除了该氮原子外，所述环还含有r个碳原子、o个氧原子、p个硫原子和q个选自NR7和NCOR7的要素作为环原子；
m为数字0、1、2或3；
n为数字0、1或2；
o为数字0、1或2；
p为数字0或1；
q为数字0或1；和
r为数字3、4或5。
4.根据权利要求1至3中任一项所述的组合物，其中组分(B)为一种或多种选自以下的活性成分：
(B1.7)甲基磺草酮，
(B1.8)唑啉草酯，
(B1.14)环磺酮(Tembotrione)，
(B2.3)酰嘧磺隆，
(B2.18)吡氟草胺，
(B2.24)啶嘧磺隆，
(B2.25)双氟磺草胺，
(B2.26)氟酮磺隆，
(B2.28)氟噻草胺，
(B2.31)甲酰胺磺隆，
(B2.34)碘甲磺隆，
(B2.37)甲基二磺隆，
(B2.58)戊炔草胺，
(B2.68)噻酮磺隆，
(B2.69)噻磺隆，
(B2.72)苯磺隆，
(B3.1)溴草腈，
(B4.18)异噁唑草酮，
(B4.22)磺酰草吡唑，
(B4.25)砜吡草唑，
(B5.23)氯氟吡啶酯，
(B5.31)氟氯吡啶酸，
(B5.38)天竺葵酸，
(B6.2)二氯吡啶酸，
(B6.3)麦草畏，
(B6.4)氟草定，
(B7.4)草铵膦，
(B7.5)草甘膦，
(B8.1)2,4-D，
(B8.5)苯草醚，
(B9.10)苯嘧磺草胺，
(B11.5)环嗪酮，
(B11.6)茚嗪氟草胺，
(B11.8)赛克津。
5.根据权利要求1所述的组合物，所述组合物包含组分(A)，其选自：
A1、A2、A3、A4、A5、A6、A7和A8或这些化合物的农业化学上可接受的盐，其中所述化合物A1-A8定义如下：
A1
A2
A3
A4
A5
A6
A7
A8
和
一种或多种组分(B)，其选自：
(B1.7)甲基磺草酮，
(B1.8)唑啉草酯，
(B1.14)环磺酮(Tembotrione)，
(B2.3)酰嘧磺隆，
(B2.18)吡氟草胺，
(B2.24)啶嘧磺隆，
(B2.25)双氟磺草胺，
(B2.26)氟酮磺隆，
(B2.28)氟噻草胺，
(B2.31)甲酰胺磺隆，
(B2.34)碘甲磺隆，
(B2.37)甲基二磺隆，
(B2.58)戊炔草胺，
(B2.68)噻酮磺隆，
(B2.69)噻磺隆，
(B2.72)苯磺隆，
(B3.1)溴草腈，
(B4.18)异噁唑草酮，
(B4.22)磺酰草吡唑，
(B4.25)砜吡草唑，
(B5.23)氯氟吡啶酯，
(B5.31)氟氯吡啶酸，
(B5.38)天竺葵酸，
(B6.2)二氯吡啶酸，
(B6.3)麦草畏，
(B6.4)氟草定，
(B7.4)草铵膦，
(B7.5)草甘膦，
(B8.1)2,4-D，
(B8.5)苯草醚，
(B9.10)苯嘧磺草胺，
(B11.5)环嗪酮，
(B11.6)茚嗪氟草胺，
(B11.8)赛克津。
6.根据权利要求1所述的组合物，所述组合物包含组分(A)，其选自：
A1和A8或这些化合物的农业化学上可接受的盐，其中所述化合物A1和A8定义如下：
A1
和
A8
一种或多种组分(B)，其选自：
(B1.7)甲基磺草酮，
(B1.8)唑啉草酯，
(B1.14)环磺酮(Tembotrione)，
(B2.3)酰嘧磺隆，
(B2.18)吡氟草胺，
(B2.24)啶嘧磺隆，
(B2.25)双氟磺草胺，
(B2.26)氟酮磺隆，
(B2.28)氟噻草胺，
(B2.31)甲酰胺磺隆，
(B2.34)碘甲磺隆，
(B2.37)甲基二磺隆，
(B2.58)戊炔草胺，
(B2.68)噻酮磺隆，
(B2.69)噻磺隆，
(B2.72)苯磺隆，
(B3.1)溴草腈，
(B4.18)异噁唑草酮，
(B4.22)磺酰草吡唑，
(B4.25)砜吡草唑，
(B5.23)氯氟吡啶酯，
(B5.31)氟氯吡啶酸，
(B5.38)天竺葵酸，
(B6.2)二氯吡啶酸，
(B6.3)麦草畏，
(B6.4)氟草定，
(B7.4)草铵膦，
(B7.5)草甘膦，
(B8.1)2,4-D，
(B8.5)苯草醚，
(B9.10)苯嘧磺草胺，
(B11.5)环嗪酮，
(B11.6)茚嗪氟草胺，
(B11.8)赛克津。
7.根据权利要求1所述的组合物，所述组合物包含组分(A)：
A1或这些化合物的农业化学上可接受的盐，其中所述化合物A1定义如下：
A1
一种或多种组分(B)，其选自：
(B1.7)甲基磺草酮，
(B1.8)唑啉草酯，
(B1.14)环磺酮(Tembotrione)，
(B2.3)酰嘧磺隆，
(B2.18)吡氟草胺，
(B2.24)啶嘧磺隆，
(B2.25)双氟磺草胺，
(B2.26)氟酮磺隆，
(B2.28)氟噻草胺，
(B2.31)甲酰胺磺隆，
(B2.34)碘甲磺隆，
(B2.37)甲基二磺隆，
(B2.58)戊炔草胺，
(B2.68)噻酮磺隆，
(B2.69)噻磺隆，
(B2.72)苯磺隆，
(B3.1)溴草腈，
(B4.18)异噁唑草酮，
(B4.22)磺酰草吡唑，
(B4.25)砜吡草唑，
(B5.23)氯氟吡啶酯，
(B5.31)氟氯吡啶酸，
(B5.38)天竺葵酸，
(B6.2)二氯吡啶酸，
(B6.3)麦草畏，
(B6.4)氟草定，
(B7.4)草铵膦，
(B7.5)草甘膦，
(B8.1)2,4-D，
(B8.5)苯草醚，
(B9.10)苯嘧磺草胺，
(B11.5)环嗪酮，
(B11.6)茚嗪氟草胺，
(B11.8)赛克津。
8.根据权利要求1所述的组合物，所述组合物包含组分(A)：
A1或这些化合物的农业化学上可接受的盐，其中所述化合物A1定义如下：
A1
一种或多种组分(B)，其选自：
(B2.18)吡氟草胺，
(B2.28)氟噻草胺，
(B2.31)甲酰胺磺隆，
(B2.37)甲基二磺隆，
(B2.58)戊炔草胺，
(B2.68)噻酮磺隆，
(B3.1)溴草腈，
(B4.22)磺酰草吡唑，
(B5.31)氟氯吡啶酸，
(B7.4)草铵膦，
(B7.5)草甘膦，
(B11.6)茚嗪氟草胺。
9.根据权利要求1至8中任一项所述的除草组合物，其中以1:100000至2000:1的重量比包含活性成分组分(A)和(B)。
10.根据权利要求1至8中任一项所述的除草组合物，其中以1:15000至500:1的重量比包含活性成分组分(A)和(B)。
11.根据权利要求1至10中任一项所述的除草组合物，其中包含一种或多种来自其他种类的植物保护剂活性成分的其他组分。
12.包含根据权利要求1至11中任一项所述的除草组合物和一种或多种在植物保护中惯用的添加剂的除草产品。
13.控制有害植物或调节植物生长的方法，其中向所述植物、植物部分、植物种子或栽培区域施用根据权利要求1至12中任一项所述的除草组合物或除草产品的所述活性成分组分。
14.根据权利要求13所述的方法，其中将根据权利要求1至12中任一项所述的除草组合物或除草产品的所述活性成分组分在芽前过程、芽后过程或在芽前和芽后过程中共同地或分开地施用于所述植物、植物部分、植物种子或栽培区域。
15.根据权利要求13或14所述的方法，其中所述除草剂组分(A)以0.01至1000g a.i./ha的施用量施用。
16.根据权利要求13或14所述的方法，其中所述除草剂组分(B)以0.01至4000g a.i./ha的施用量施用，不同的是天竺葵酸，其以1至100,000g a.i./ha的施用量施用。
17.根据权利要求13至16中任一项所述的方法，用于通过在作物植物的播种前和在种植园作物中以及在未开垦的土地上处理来控制有害植物。
18.根据权利要求13至17中任一项所述的方法，其中所述除草组合物的所述活性成分以包含一种或多种在植物保护中惯用的添加剂的根据权利要求12所述的除草产品的形式任选地在用水稀释后施用。
19.根据权利要求1至12中任一项所述的除草组合物或除草产品用于控制有害植物或用于调节植物生长的用途。
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| CA3145581A1 (en) | 2021-01-07 |
| MX2022000119A (es) | 2022-05-18 |
| US20220386605A1 (en) | 2022-12-08 |
| CL2024001064A1 (es) | 2024-08-30 |
| EP4378314A3 (de) | 2024-08-14 |
| EP3993626A1 (de) | 2022-05-11 |
| CO2021017742A2 (es) | 2022-01-17 |
| CL2021003520A1 (es) | 2022-08-12 |
| AU2020299262A1 (en) | 2022-02-03 |
| CR20210684A (es) | 2022-02-15 |
| ZA202201533B (en) | 2024-02-28 |
| EP4378314A2 (de) | 2024-06-05 |
| WO2021001273A1 (de) | 2021-01-07 |
| DOP2022000001A (es) | 2022-04-18 |
| BR112021026545A2 (pt) | 2022-05-03 |
| IL289583A (en) | 2022-03-01 |
| CN114340393B (zh) | 2024-05-24 |
| AR119335A1 (es) | 2021-12-09 |
| JP2022539536A (ja) | 2022-09-12 |
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