CN114334977A - Semiconductor device and manufacturing method thereof - Google Patents
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 44
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 25
- 239000003990 capacitor Substances 0.000 claims abstract description 99
- 239000000758 substrate Substances 0.000 claims description 44
- 239000004020 conductor Substances 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 28
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- 239000007772 electrode material Substances 0.000 claims description 11
- 238000001039 wet etching Methods 0.000 claims description 6
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- 238000009413 insulation Methods 0.000 abstract description 2
- 238000003475 lamination Methods 0.000 abstract 2
- 239000010410 layer Substances 0.000 description 153
- 238000003860 storage Methods 0.000 description 33
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- 229910021421 monocrystalline silicon Inorganic materials 0.000 description 2
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- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 229910003697 SiBN Inorganic materials 0.000 description 1
- 238000013500 data storage Methods 0.000 description 1
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Abstract
Description
技术领域technical field
本发明涉及半导体制造技术领域,尤其涉及一种半导体器件及其制造方法。The present invention relates to the technical field of semiconductor manufacturing, and in particular, to a semiconductor device and a manufacturing method thereof.
背景技术Background technique
电容器(Capacitor)是一种可以存储电量和电能的元件。可以通过在电容器的两个电极上施加不同的电压,使得电容器内储存不同数量的电荷。在此基础上,可以通过电容器来实现对不同数据的存储。由此可见,电容器的品质直接影响半导体器件的数据存储性能。A capacitor is a component that can store electricity and electrical energy. Different amounts of charge can be stored in a capacitor by applying different voltages to the two electrodes of the capacitor. On this basis, the storage of different data can be realized through capacitors. It can be seen that the quality of the capacitor directly affects the data storage performance of the semiconductor device.
为了提升存储器的驱动性能,需要增加电容器的电容。一般增加电容器电容的方式是增加电容器的高度。然而电容器的高度增高,会导致电容器的高宽比(Aspect Ratio)增加。电容器的高宽比增加,就容易在Wet Clean(湿法清洗)工艺进行时,出现电容器倾斜、弯曲甚至塌陷等问题。In order to improve the driving performance of the memory, the capacitance of the capacitor needs to be increased. The general way to increase the capacitance of a capacitor is to increase the height of the capacitor. However, as the height of the capacitor increases, the aspect ratio (Aspect Ratio) of the capacitor increases. When the aspect ratio of the capacitor increases, it is easy to have problems such as tilting, bending and even collapse of the capacitor during the Wet Clean process.
发明内容SUMMARY OF THE INVENTION
本发明提供了一种半导体器件及其制造方法,可以有效提升电容器的电荷存储量,同时可有效防止电容器倾斜、弯曲或坍塌。The invention provides a semiconductor device and a manufacturing method thereof, which can effectively increase the charge storage capacity of the capacitor, and at the same time can effectively prevent the capacitor from tilting, bending or collapsing.
第一方面,本发明提供了一种半导体器件,该半导体器件包括一基底、层叠在基底上的第一绝缘叠层、以及层叠在第一绝缘叠层上的第二绝缘叠层。其中,第一绝缘叠层上开设有第一接触孔,第一接触孔内从下向上填充有堆置接触塞,且堆置接触塞未填满第一接触孔。在第二绝缘叠层上开设有与第一接触孔连通的第二接触孔。该半导体器件还包括形成在第二绝缘叠层上方的下电极,且下电极还向下依次延伸到第二接触孔及第一接触孔内与堆置接触塞接触。In a first aspect, the present invention provides a semiconductor device including a substrate, a first insulating stack stacked on the substrate, and a second insulating stack stacked on the first insulating stack. Wherein, a first contact hole is opened on the first insulating layer, the first contact hole is filled with stacking contact plugs from bottom to top, and the stacking contact plug is not filled with the first contact hole. A second contact hole communicated with the first contact hole is opened on the second insulating stack. The semiconductor device further includes a lower electrode formed over the second insulating stack, and the lower electrode further extends downward into the second contact hole and the first contact hole in order to contact the stacked contact plugs.
在上述的方案中,通过去除第二接触孔内的导体膜及与导体膜接触的着陆焊盘(Landing Pad,简称LP),还去除第一接触孔内的部分堆置接触塞(Buried Contact,简称BC),将形成在两个绝缘叠层上方的下电极还向下延伸到第一接触孔及第二接触孔内与保留的堆置接触塞接触,使与堆置接触塞接触的部分下电极形成一个类似锚的结构,能够对整个下电极进行支撑,防止整个下电极倾斜。后续工序中在下电极上沉积介质层及上电极时,下电极中类似锚的结构部分还能够防止整个下电极弯曲变形,从而防止电容器坍塌。且延伸到第一接触孔及第二接触孔内的部分下电极能够增大下电极的表面积,从而提高电容器的电荷存储量,提高电容器的电容,提高存储性能。且通过下电极向下延伸到第一接触孔及第二接触孔直接与保留的堆置接触塞接触,取代了下电极通过着陆焊盘、导体膜与堆置接触塞接触的方式,减少了不同层之间的接触个数,降低了层间电流传输的电阻。在应用时,由于下电极中类似锚的结构部分对整个下电极进行支撑,电容器结构较为牢固,可以适当增大堆叠电容器的高宽比,以增大电容器的电容,进一步提高存储性能。In the above solution, by removing the conductor film in the second contact hole and the Landing Pad (LP) in contact with the conductor film, part of the stacked contact plug (Buried Contact, LP) in the first contact hole is also removed. (abbreviated as BC), the lower electrode formed above the two insulating stacks is also extended downward into the first contact hole and the second contact hole to contact the remaining stacking contact plugs, so that the part in contact with the stacking contact plugs is lower The electrode forms an anchor-like structure, which can support the entire lower electrode and prevent the entire lower electrode from tilting. When the dielectric layer and the upper electrode are deposited on the lower electrode in the subsequent process, the anchor-like structure portion in the lower electrode can also prevent the entire lower electrode from being bent and deformed, thereby preventing the capacitor from collapsing. And the part of the lower electrode extending into the first contact hole and the second contact hole can increase the surface area of the lower electrode, thereby increasing the charge storage capacity of the capacitor, increasing the capacitance of the capacitor, and improving the storage performance. And through the lower electrode extending down to the first contact hole and the second contact hole, it directly contacts with the remaining stacked contact plugs, instead of the way that the lower electrode contacts the stacked contact plugs through the landing pad and the conductor film, reducing the difference. The number of contacts between layers reduces the resistance of current transfer between layers. In application, since the entire lower electrode is supported by the anchor-like structural part in the lower electrode, the capacitor structure is relatively firm, and the aspect ratio of the stacked capacitor can be appropriately increased to increase the capacitance of the capacitor and further improve the storage performance.
在一个具体的实施方式中,延伸到第二接触孔及第一接触孔的孔壁的下电极沉积在第一接触孔及第二接触孔的孔壁上,延伸到堆置接触塞的上端面的下电极沉积在堆置接触塞的上端面上,以提高下电极与接触孔的孔壁及堆置接触塞接触的强度,提高对整个下电极的支撑效果。In a specific embodiment, the lower electrode extending to the second contact hole and the hole wall of the first contact hole is deposited on the hole wall of the first contact hole and the second contact hole, and extends to the upper end surface of the stacked contact plug The lower electrode is deposited on the upper end surface of the stacked contact plug, so as to improve the contact strength of the lower electrode with the hole wall of the contact hole and the stacked contact plug, and improve the supporting effect of the entire lower electrode.
在一个具体的实施方式中,下电极的形成为筒状;其中,下电极的底壁沉积在堆置接触塞的上端面上;下电极的侧壁部分沉积在第一接触孔及第二接触孔的孔壁上,部分外露于第一接触孔及第二接触孔外。通过采用筒状的下电极,以提高下电极的表面积,提高电容器的电荷存储量,提高电容器的电容。In a specific embodiment, the lower electrode is formed into a cylindrical shape; wherein, the bottom wall of the lower electrode is deposited on the upper end surface of the stacked contact plug; the sidewall of the lower electrode is partially deposited on the first contact hole and the second contact A part of the hole wall of the hole is exposed outside the first contact hole and the second contact hole. By adopting the cylindrical lower electrode, the surface area of the lower electrode is increased, the charge storage capacity of the capacitor is increased, and the capacitance of the capacitor is increased.
在一个具体的实施方式中,在下电极的底壁、内侧壁、以及外露于第一接触孔及第二接触孔外部分的外侧壁上均形成有上电极、以及将上述下电极与上电极绝缘隔离的介质层。通过在下电极的内外侧均设置电容器结构,以提高电容器的电荷存储量,提高电容器的电容,提高存储效果。In a specific embodiment, an upper electrode is formed on the bottom wall, inner sidewall, and outer sidewall of the lower electrode exposed to the outer parts of the first contact hole and the second contact hole, and the lower electrode is insulated from the upper electrode. isolated dielectric layer. By arranging capacitor structures on both the inner and outer sides of the lower electrode, the charge storage capacity of the capacitor is increased, the capacitance of the capacitor is increased, and the storage effect is improved.
在一个具体的实施方式中,堆置接触塞的高度为h1,第一接触孔的高度为h2,其中,20%×h2≤h1≤80%×h2。以保证下电极延伸到第一接触孔内的部分与第一接触孔的侧壁具有较大的接触表面,保证所形成的类似锚的结构对整个下电极的支撑效果。同时保证堆置接触塞的高度,使堆置接触塞与下电极具有较稳定的粘接状态。In a specific embodiment, the height of the stacked contact plugs is h1, and the height of the first contact hole is h2, wherein 20%×h2≤h1≤80%×h2. In order to ensure that the part of the lower electrode extending into the first contact hole has a larger contact surface with the side wall of the first contact hole, and to ensure the supporting effect of the formed anchor-like structure on the entire lower electrode. At the same time, the height of the stacked contact plugs is ensured, so that the stacked contact plugs and the lower electrode have a relatively stable bonding state.
在一个具体的实施方式中,在第二绝缘叠层上还沉积有刻蚀阻挡层,第二接触孔还贯穿刻蚀阻挡层。通过在第二绝缘叠层上沉积刻蚀阻挡层,以防止后续刻蚀或清洗等操作对基底造成影响,确保基底及绝缘叠层的品质。In a specific embodiment, an etch barrier layer is further deposited on the second insulating stack, and the second contact hole also penetrates the etch barrier layer. By depositing an etch stop layer on the second insulating stack, the substrate and the quality of the insulating stack are ensured to prevent subsequent operations such as etching or cleaning from affecting the substrate.
在一个具体的实施方式中,半导体器件为动态随机存储器,以防止动态随机存取存储器中由于下电极的倾斜、弯曲等引起电容器坍塌。In a specific embodiment, the semiconductor device is a dynamic random access memory, so as to prevent the collapse of the capacitor in the dynamic random access memory due to inclination, bending, etc. of the lower electrode.
第二方面,本发明还提供了一种半导体器件的制造方法,该制造方法包括:In a second aspect, the present invention also provides a method for manufacturing a semiconductor device, the method comprising:
提供一基底;provide a base;
在基底上层叠绝缘层;Laminate an insulating layer on the substrate;
在绝缘层中开设有接触孔;A contact hole is opened in the insulating layer;
在接触孔内填充有堆置接触塞、与堆置接触塞导电连接的着陆焊盘;The contact holes are filled with stacked contact plugs, and the landing pads are conductively connected with the stacked contact plugs;
去除着陆焊盘;remove the landing pad;
从上向下去除部分堆置接触塞;Remove partially stacked contact plugs from top to bottom;
在绝缘层的上方形成下电极,且下电极还向下延伸到接触孔内与保留的堆置接触塞接触。A lower electrode is formed over the insulating layer, and the lower electrode also extends down into the contact hole to make contact with the remaining stacked contact plugs.
在上述的方案中,通过去除接触孔内的着陆焊盘,还去除接触孔内的部分堆置接触塞,将形成在绝缘层上方的下电极还向下延伸到接触孔内与保留的堆置接触塞接触,使与堆置接触塞接触的部分下电极形成一个类似锚的结构,能够对整个下电极进行支撑,防止整个下电极倾斜。后续工序中在下电极上沉积介质层及上电极时,下电极中类似锚的结构部分还能够防止整个下电极弯曲变形,从而防止电容器坍塌。且延伸到接触孔内的部分下电极能够增大下电极的表面积,从而提高电容器的电荷存储量,提高电容器的电容,提高存储性能。且通过下电极向下延伸到接触孔直接与保留的堆置接触塞接触,取代了下电极通过着陆焊盘、导体膜与堆置接触塞接触的方式,减少了不同层之间的接触个数,降低了层间电流传输的电阻。在应用时,由于下电极中类似锚的结构部分对整个下电极进行支撑,电容器结构较为牢固,可以适当增大堆叠电容器的高宽比,以增大电容器的电容,进一步提高存储性能。In the above solution, by removing the landing pads in the contact holes, and also removing part of the stacked contact plugs in the contact holes, the lower electrodes formed above the insulating layer are also extended down into the contact holes and the remaining stacked contact plugs are also removed. The contact plugs are in contact, so that the part of the lower electrode in contact with the stacked contact plugs forms an anchor-like structure, which can support the entire lower electrode and prevent the entire lower electrode from tilting. When the dielectric layer and the upper electrode are deposited on the lower electrode in the subsequent process, the anchor-like structure portion in the lower electrode can also prevent the entire lower electrode from being bent and deformed, thereby preventing the capacitor from collapsing. And the part of the lower electrode extending into the contact hole can increase the surface area of the lower electrode, thereby increasing the charge storage capacity of the capacitor, increasing the capacitance of the capacitor, and improving the storage performance. And through the lower electrode extending down to the contact hole, it directly contacts with the remaining stacked contact plugs, instead of the way that the lower electrode contacts the stacked contact plugs through the landing pad and the conductor film, reducing the number of contacts between different layers. , which reduces the resistance of interlayer current transfer. In application, since the entire lower electrode is supported by the anchor-like structural part in the lower electrode, the capacitor structure is relatively firm, and the aspect ratio of the stacked capacitor can be appropriately increased to increase the capacitance of the capacitor and further improve the storage performance.
在一个具体的实施方式中,在接触孔内填充有堆置接触塞、与堆置接触塞导电连接的着陆焊盘具体为:在接触孔内填充有堆置接触塞;在接触孔内填充有与堆置接触塞接触的导体膜;在接触孔内填充有与导体膜接触的着陆焊盘。在去除着陆焊盘之后,在从上向下去除部分堆置接触塞之前,该制造方法还包括:去除导体膜。In a specific embodiment, the contact holes are filled with stacked contact plugs and the landing pads that are electrically connected to the stacked contact plugs are specifically: the contact holes are filled with stacked contact plugs; the contact holes are filled with The conductor film in contact with the stacked contact plugs; the contact holes are filled with landing pads in contact with the conductor film. After removing the landing pad, and before removing the partially stacked contact plug from top to bottom, the manufacturing method further includes removing the conductor film.
在一个具体的实施方式中,去除着陆焊盘、导体膜及部分堆置接触塞具体为:采用湿法刻蚀或远程等离子体干法清洗工艺从上向下去除接触孔内的着陆焊盘、导体膜及部分堆置接触塞。以在不影响其他膜质的情况下将之去除。In a specific embodiment, the removal of the landing pad, the conductor film and the partially stacked contact plug is specifically: removing the landing pad, Conductor film and partially stacked contact plugs. to remove it without affecting other membranes.
在一个具体的实施方式中,在接触孔内填充有堆置接触塞、与堆置接触塞导电连接的着陆焊盘之后,去除着陆焊盘之前,该制造方法还包括:在绝缘层上层叠牺牲膜层;在牺牲膜层中开设有与着陆焊盘连通的电容孔。在绝缘层的上方形成下电极,且下电极向下延伸到接触孔内与保留的部分堆置接触塞接触具体为:在电容孔及接触孔的孔壁、保留的部分堆置接触塞的上端面上均形成与保留的堆置接触塞接触的下电极。In a specific embodiment, after the contact holes are filled with stacked contact plugs and the landing pads electrically connected to the stacked contact plugs, and before the landing pads are removed, the manufacturing method further includes: stacking a sacrificial layer on the insulating layer The film layer; the sacrificial film layer is provided with a capacitor hole communicating with the landing pad. The lower electrode is formed above the insulating layer, and the lower electrode extends downward into the contact hole and contacts with the remaining partially stacked contact plugs. Lower electrodes in contact with the remaining stacked contact plugs are formed on the end faces.
在一个具体的实施方式中,在电容孔及接触孔的孔壁、保留的部分堆置接触塞的上端面上均形成与保留的堆置接触塞接触的下电极具体为:在牺牲膜层表面、电容孔及接触孔的孔壁、保留的部分堆置接触塞的上端面上沉积下电极材料层;去除牺牲膜层表面的下电极材料层,形成与保留的堆置接触塞接触的下电极。以便于形成下电极,且提高下电极与接触孔的孔壁及保留的堆置接触塞的上端面接触的强度,提高对整个下电极进行支撑的效果。In a specific embodiment, forming a lower electrode in contact with the reserved stacked contact plug on the hole wall of the capacitor hole and the contact hole, and on the upper end surface of the reserved partial stacked contact plug is specifically: on the surface of the sacrificial film layer The lower electrode material layer is deposited on the hole wall of the capacitor hole and the contact hole, and the upper end surface of the reserved part of the stacked contact plug; the lower electrode material layer on the surface of the sacrificial film layer is removed to form a lower electrode in contact with the reserved stacked contact plug. . In order to facilitate the formation of the lower electrode, the strength of the contact between the lower electrode and the hole wall of the contact hole and the upper end surface of the remaining stacked contact plugs is improved, and the effect of supporting the entire lower electrode is improved.
在一个具体的实施方式中,在绝缘层的上方形成下电极之后,该制造方法还包括:去除牺牲膜层,以便于后续在下电极的内外侧均形成电容结构,提高电容器的电容、提高存储性能。In a specific embodiment, after the lower electrode is formed above the insulating layer, the manufacturing method further includes: removing the sacrificial film layer, so as to subsequently form a capacitor structure on both the inner and outer sides of the lower electrode, so as to improve the capacitance of the capacitor and improve the storage performance. .
附图说明Description of drawings
图1a为现有技术中制造电容器的其中一步工序的示意图;FIG. 1a is a schematic diagram of one of the steps of manufacturing a capacitor in the prior art;
图1b为现有技术中制造电容器的其中另一步工序的示意图;FIG. 1b is a schematic diagram of another step in the process of manufacturing a capacitor in the prior art;
图2为本发明实施例提供的一种半导体器件的结构示意图;FIG. 2 is a schematic structural diagram of a semiconductor device according to an embodiment of the present invention;
图3为本发明实施例提供的一种半导体器件的制造方法中的一步工序的示意图;FIG. 3 is a schematic diagram of a step in a method for manufacturing a semiconductor device according to an embodiment of the present invention;
图4为本发明实施例提供的一种半导体器件的制造方法中的另一步工序的示意图;4 is a schematic diagram of another step in a manufacturing method of a semiconductor device provided by an embodiment of the present invention;
图5为本发明实施例提供的一种半导体器件的制造方法中的另一步工序的示意图;5 is a schematic diagram of another step in a method for manufacturing a semiconductor device provided by an embodiment of the present invention;
图6为本发明实施例提供的一种半导体器件的制造方法中的另一步工序的示意图。FIG. 6 is a schematic diagram of another step in a method for manufacturing a semiconductor device according to an embodiment of the present invention.
图1a~图1b中的附图标记:Reference numerals in Figures 1a to 1b:
1-基底 2-牺牲膜层 3-电容孔 4-着陆焊盘 5-下电极1-substrate 2-sacrificial film layer 3-capacitor hole 4-landing pad 5-bottom electrode
图2~图6中的附图标记:Reference numerals in Figures 2 to 6:
10-基底 21-第一绝缘叠层 211-堆置接触塞 212-绝缘部10-substrate 21-first insulating stack 211-stacking contact plugs 212-insulation
22-第二绝缘叠层 221-导体膜 222-着陆焊盘 223-隔离部22-Second insulating laminate 221-Conductor film 222-Landing pad 223-Isolation
31-第一接触孔 32-第二接触孔 40-下电极 50-牺牲膜层31-first contact hole 32-second contact hole 40-lower electrode 50-sacrificial film layer
60-电容孔 70-刻蚀阻挡层 80-支撑层 81-支撑结构60-capacitor hole 70-etch barrier 80-support layer 81-support structure
具体实施方式Detailed ways
为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the purposes, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments It is only a part of the embodiments of the present invention, but not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts shall fall within the protection scope of the present invention.
为了方便理解本发明实施例提供的半导体器件,下面首先说明一下本发明实施例提供的半导体器件的应用场景,该半导体器件应用于具有电容器的存储器中。下面结合附图对该半导体器件进行详细的叙述。In order to facilitate understanding of the semiconductor device provided by the embodiment of the present invention, the following first describes an application scenario of the semiconductor device provided by the embodiment of the present invention, where the semiconductor device is applied to a memory having a capacitor. The semiconductor device will be described in detail below with reference to the accompanying drawings.
参考图2,本发明实施例提供的半导体器件包括一基底10、层叠在基底10上的第一绝缘叠层21、以及层叠在第一绝缘叠层21上的第二绝缘叠层22。其中,第一绝缘叠层21中开设有第一接触孔31,第一接触孔31内从下向上填充有堆置接触塞211,且堆置接触塞211未填满第一接触孔31。在第二绝缘叠层22中开设有与第一接触孔31连通的第二接触孔32。该半导体器件还包括形成在第二绝缘叠层22上方的下电极40,且下电极40还向下依次延伸到第二接触孔32及第一接触孔31内与堆置接触塞211接触。Referring to FIG. 2 , a semiconductor device provided by an embodiment of the present invention includes a
在上述的方案中,通过去除第二接触孔32内的导体膜221及与导体膜221接触的着陆焊盘222,还去除第一接触孔31内的部分堆置接触塞211,将形成在两个绝缘叠层上方的下电极40还向下延伸到第一接触孔31及第二接触孔32内与保留的堆置接触塞211接触,使与堆置接触塞211接触的部分下电极40形成一个类似锚的结构,能够对整个下电极40进行支撑,防止整个下电极40倾斜。后续工序中在下电极40上沉积介质层及上电极时,下电极40中类似锚的结构部分还能够防止整个下电极40弯曲变形,从而防止电容器坍塌。且延伸到第一接触孔31及第二接触孔32内的部分下电极40能够增大下电极40的表面积,从而提高电容器的电荷存储量,提高电容器的电容,提高存储性能。且通过下电极40向下延伸到第一接触孔31及第二接触孔32直接与保留的堆置接触塞211接触,取代了下电极40通过着陆焊盘222、导体膜221与堆置接触塞211接触的方式,减少了不同层之间的接触个数,降低了层间电流传输的电阻。在应用时,由于下电极40中类似锚的结构部分对整个下电极40进行支撑,电容器结构较为牢固,可以适当增大堆叠电容器的高宽比,以增大电容器的电容,进一步提高存储性能。下面结合附图对上述各个结构的设置进行详细的介绍。In the above solution, by removing the
在设置基底10时,该基底10可以是包括单一半导体材料的结构,如单晶硅基底10、多晶硅基底10等。该基底10也可以是已经形成有部分半导体结构的叠层结构。例如,基底10可以至少包括半导体衬底、晶体管、位线结构等。晶体管可以形成在半导体器件的半导体衬底上。位线结构可以形成在晶体管的上方。When the
参考图2,在基底10的上方还层叠有第一绝缘叠层21,第一绝缘叠层21中还开设有第一接触孔31,即第一接触孔31连通第一绝缘叠层21的上表面及下表面。在第一接触孔31内从下向上填充有堆置接触塞211,且堆置接触塞211未填满第一接触孔31。即堆置接触塞211位于第一接触孔31内的下端,且堆置接触塞211并未填满第一接触孔31。在应用时,堆置接触塞211与晶体管所具有的源区或漏区接触。参考图2,在第一绝缘叠层21中还形成有隔离相邻的两个堆置接触塞211的绝缘部212,堆置接触塞211和绝缘部212形成在相邻位线结构之间。Referring to FIG. 2 , a first insulating
继续参考图2,在第一绝缘叠层21的上方还层叠有第二绝缘叠层22,在第二绝缘叠层22中还开设有与第一接触孔31连通的第二接触孔32。即第二接触孔32贯穿第二绝缘叠层22的上、下表面,且第二接触孔32的下端还与第一接触孔31连通。第一接触孔31与第二接触孔32的孔沿可以重合设置,使第一接触孔31与第二接触孔32的连接处的孔口大小相等,且孔沿重合相对。第一接触孔31与第二接触孔32的孔沿还可以至少部分交叉,以使第一接触孔31与第二接触孔32至少部分连通。当然,还可以使第一接触孔31与第二接触孔32的连接处,一个接触孔的孔口大,另一个接触孔的孔口小,使孔口小的接触孔套在孔口大的接触孔内。Continuing to refer to FIG. 2 , a second insulating
如图2所示,在设置下电极40时,下电极40主要包括两个部分,其中一个部分为形成在第二绝缘叠上方的部分,该部分外露于第一接触孔31及第二接触孔32外。另一个部分为向下依次延伸到第二接触孔32及第一接触孔31内与堆置接触塞211接触的部分,该部分位于第一接触孔31及第二接触孔32内。As shown in FIG. 2 , when the
现有技术中电容器的制造方法如图1a~图1b所示,参考图1a,首先在基底1上沉积牺牲膜层2;之后,刻蚀牺牲膜层2形成电容孔3,电容孔3与基底1中的着陆焊盘4连通;之后,在牺牲膜层2、电容孔3内壁及着陆焊盘4的上端面上沉积下电极材料层;之后,参考图1b,去除电容孔3外的下电极材料层,形成下电极5;之后,参考图1b,去除牺牲膜层2;后续在下电极5上沉积介质层及上电极,形成电容器。如图1b所示出的半导体器件,下电极5的下端仅仅与着陆焊盘4接触,接触面积比较小,从而使下电极5的根基较差,容易倾斜、倾倒甚至弯曲。在去除牺牲膜层2后,下电极5容易倾斜甚至倾倒。在下电极5上沉积介质层及上电极时,下电极4由于承受介质层及上电极的重量,容易弯曲,从而造成整个电容器的塌陷。The manufacturing method of a capacitor in the prior art is shown in FIG. 1a to FIG. 1b. Referring to FIG. 1a, first, a
相比现有技术中图1b中的方案,本申请中的方案去除了第二接触孔32内的导体膜221及与导体膜221接触的着陆焊盘222,还去除第一接触孔31内的部分堆置接触塞211,将形成在两个绝缘叠层上方的下电极40还向下延伸到第一接触孔31及第二接触孔32内与保留的堆置接触塞211接触,使与堆置接触塞211接触的部分下电极40形成一个类似锚的结构,能够对整个下电极40进行支撑,防止整个下电极40倾斜。后续工序中在下电极40上沉积介质层及上电极时,下电极40中类似锚的结构部分还能够防止整个下电极40弯曲变形,从而防止电容器坍塌。且延伸到第一接触孔31及第二接触孔32内的部分下电极40能够增大下电极40的表面积,从而提高电容器的电荷存储量,提高电容器的电容,提高存储性能。且通过下电极40向下延伸到第一接触孔31及第二接触孔32直接与保留的堆置接触塞211接触,取代了下电极40通过着陆焊盘222、导体膜221与堆置接触塞211接触的方式,减少了不同层之间的接触个数,降低了层间电流传输的电阻。在应用时,由于下电极40中类似锚的结构部分对整个下电极40进行支撑,电容器结构较为牢固,可以适当增大堆叠电容器的高宽比,以增大电容器的电容,进一步提高存储性能。Compared with the solution in FIG. 1 b in the prior art, the solution in the present application removes the
再具体,使下电极40上延伸到第一接触孔31及第二接触孔32内的部分与堆置接触塞211接触时,可以使延伸到堆置接触塞211上端面的下电极40沉积在堆置接触塞211的上端面上,以提高下电极40与堆置接触塞211接触的强度,提高对整个下电极40的支撑效果。同时还可以使延伸到第一接触孔31及第二接触孔32的孔壁的下电极40沉积在第一接触孔31及第二接触孔32的孔壁上,即下电极40中延伸到第一接触孔31及第二接触孔32内的部分不仅与堆置接触塞211接触,还与第一接触孔31及第二接触孔32的孔壁接触,接触的方式采用沉积的方式,从而提高下电极40与两个接触孔及堆置接触塞211接触的面积及接触的强度,提高对整个下电极40的支撑效果。More specifically, when the portion of the
在设置下电极40时,下电极40的形状可以为一个中空的筒状结构,该筒状结构包括一个薄壁的筒底、以及与筒底连通的侧壁。可以使下电极40的底壁沉积在堆置接触塞211的上端面上,即下电极40的筒底沉积在堆置接触塞211的上端面上。下电极40的侧壁部分沉积在第一接触孔31及第二接触孔32的孔壁上,部分外露于第一接触孔31及第二接触孔32外。即下电极40的侧壁中位于第一接触孔31及第二接触孔32内的部分沉积在第一接触孔31及第二接触孔32的孔壁上,外露于第一接触孔31及第二接触孔32的部分竖向立在第二绝缘叠层22的上方。通过采用筒状的下电极40,以提高下电极40的表面积,提高电容器的电荷存储量,提高电容器的电容。When the
在下电极40上形成介质层及上电极时,可以在下电极40的底壁、内侧壁、以及外露于第一接触孔31及第二接触孔32外部分的外侧壁上均形成有上电极、以及将下电极40与上电极绝缘隔离的介质层,以完成电容器的制造。即在下电极40上位于第一接触孔31及第二接触孔32的部分仅仅在内侧壁及底壁上形成有介质层及上电极,在下电极40上外露于第一接触孔31及第二接触孔32外的部分不仅在内侧壁上形成有介质层及上电极,在外侧壁上也形成有介质层及上电极。通过在下电极40的内外侧均设置电容器结构,以提高电容器的电荷存储量,提高电容器的电容,提高存储效果。应当理解的是,设置介质层及上电极的方式并不限于上述的方式,除此之外,还可以采用其他的方式。例如,还可以仅在下电极40的内侧壁及底壁上形成介质层及上电极,在下电极40的外侧壁上不形成介质层及上电极。When the dielectric layer and the upper electrode are formed on the
在确定堆置接触塞211占整个第一接触孔31的高度时,可以假定堆置接触塞211的高度为h1,即堆置接触塞211的下表面到堆置接触塞211的上表面之间的垂直距离为h1;第一接触孔31的高度为h2,即第一接触孔31的上孔沿到第一接触孔31的下孔沿之间的垂直距离为h2。可以设置:20%×h2≤h1≤80%×h2。具体的,可以设置堆置接触塞211的高度h1=20%×h2、h1=25%×h2、h1=30%×h2、h1=35%×h2、h1=40%×h2、h1=45%×h2、h1=50%×h2、h1=55%×h2、h1=60%×h2、h1=65%×h2、h1=70%×h2、h1=75%×h2、h1=80%×h2等介于第一接触孔31的高度h2的20%~80%之间的任意值。以保证下电极40延伸到第一接触孔31内的部分与第一接触孔31的侧壁具有较大的接触表面,保证所形成的类似锚的结构对整个下电极40的支撑效果。同时保证堆置接触塞211的高度,使堆置接触塞211与下电极40具有较稳定的粘接状态。When determining the height of the stacked contact plugs 211 occupying the entire
另外,如图2所示,可以将第二接触孔32的形状设置为上端大、中间小、下端大的形状,第一接触孔31设置为与第二接触孔32的下端的孔口等大的孔口,第一接触孔31的上下端的孔口可以等大,且第一接触孔31的外沿与第二接触孔32的外沿重合。通过采用上述设置方式,以提高下电极40与第二接触孔32的侧壁接触的表面积,提高位于第一接触孔31及第二接触孔32内的下电极40对整个下电极40的支撑效果。且第一接触孔31的下端较大,可以增大下电极40与堆置接触塞211接触的面积,减小层间电流传输的电阻。第二接触孔32的上端大,可以使外露于第一接触孔31及第二接触孔32外的下电极40具有较大的表面积,从而提高电容器的电荷存储量,提高电容器的电容,提高存储性能。当然,还可以将第一接触孔31及第二接触孔32均设置为一个呈空心的圆柱状通孔。In addition, as shown in FIG. 2 , the shape of the
参考图2,可以在第二绝缘叠层22上还沉积有刻蚀阻挡层70,此时,第二接触孔32还贯穿刻蚀阻挡层70。通过在第二绝缘叠层22上沉积刻蚀阻挡层70,以防止后续刻蚀或清洗等操作对基底10及两个绝缘叠层造成影响,确保基底10及绝缘叠层的品质。在确定刻蚀阻挡层70的材料时,刻蚀阻挡层70的材料可以选择SiN、SiBN或SiCN,以提高刻蚀时的阻挡效果。Referring to FIG. 2 , an
可以使第一绝缘叠层21及第二绝缘叠层22之间直接接触。还可以在第一绝缘叠层21与第二绝缘叠层22之间沉积刻蚀阻挡层,即此时第一绝缘叠层21与第二绝缘叠层22非直接层叠在一起,在两者之间还沉积有一层刻蚀阻挡层。对应的,此时在第一绝缘叠层21与第二绝缘叠层22之间的刻蚀阻挡层上也开设有接触孔连通第一接触孔31及第二接触孔32。且下电极40延伸到第一接触孔31及第二接触孔32内的部分还沉积在开设在刻蚀阻挡层上的接触孔的侧壁上。通过在两者之间沉积刻蚀阻挡层,以便于在制造过程中,刻蚀阻挡层对第一绝缘叠层21及基底10进行保护,防止后续刻蚀或清洗等操作对基底10及两个绝缘叠层造成影响,确保基底10及绝缘叠层的品质。Direct contact between the first insulating
如图2所示,还可以在刻蚀阻挡层70的上方设置支撑下电极40的支撑结构81,该支撑结构81环绕在下电极40的外侧壁上,以提高对下电极40的支撑效果。具体设置支撑结构81时,支撑结构81可以设置在下电极40的偏上端,也可以设置在下电极40的偏中间位置,且可以同时在下电极40的不同位置均设置支撑结构81。As shown in FIG. 2 , a
在确定该半导体器件的类型时,半导体器件可以为动态随机存取存储器(DRAM),以防止动态随机存取存储器中由于下电极40的倾斜、弯曲等引起电容器坍塌。该半导体器件还可以为静态静态随机存取存储器(Static Random-Access Memory,SRAM)、快闪存储器(flash memory)等采用电容器作为存储单元的存储器。In determining the type of the semiconductor device, the semiconductor device may be a dynamic random access memory (DRAM) to prevent the collapse of capacitors in the DRAM due to inclination, bending, etc. of the
通过去除第二接触孔32内的导体膜221及与导体膜221接触的着陆焊盘222,还去除第一接触孔31内的部分堆置接触塞211,将形成在两个绝缘叠层上方的下电极40还向下延伸到第一接触孔31及第二接触孔32内与保留的堆置接触塞211接触,使与堆置接触塞211接触的部分下电极40形成一个类似锚的结构,能够对整个下电极40进行支撑,防止整个下电极40倾斜。后续工序中在下电极40上沉积介质层及上电极时,下电极40中类似锚的结构部分还能够防止整个下电极40弯曲变形,从而防止电容器坍塌。且延伸到第一接触孔31及第二接触孔32内的部分下电极40能够增大下电极40的表面积,从而提高电容器的电荷存储量,提高电容器的电容,提高存储性能。且通过下电极40向下延伸到第一接触孔31及第二接触孔32直接与保留的堆置接触塞211接触,取代了下电极40通过着陆焊盘222、导体膜221与堆置接触塞211接触的方式,减少了不同层之间的接触个数,降低了层间电流传输的电阻。在应用时,由于下电极40中类似锚的结构部分对整个下电极40进行支撑,电容器结构较为牢固,可以适当增大堆叠电容器的高宽比,以增大电容器的电容,进一步提高存储性能。By removing the
另外,本发明实施例还提供了一种半导体器件的制造方法,该制造方法包括:In addition, an embodiment of the present invention also provides a method for manufacturing a semiconductor device, the method comprising:
步骤一:提供一基底10;Step 1: provide a
步骤二:在基底10上层叠绝缘层;Step 2: stacking an insulating layer on the
步骤三:在绝缘层中开设有接触孔;Step 3: opening a contact hole in the insulating layer;
步骤四:在接触孔内填充有堆置接触塞211、与堆置接触塞211导电连接的着陆焊盘222;Step 4: Filling the contact holes with stacked contact plugs 211 and
步骤五:去除着陆焊盘222;Step 5: remove the
步骤六:从上向下去除部分堆置接触塞211;Step 6: Remove some of the stacked contact plugs 211 from top to bottom;
步骤七:在绝缘层的上方形成下电极40,且下电极40还向下延伸到接触孔内与保留的堆置接触塞211接触。Step 7: The
在上述的方案中,通过去除接触孔内的着陆焊盘222,还去除接触孔内的部分堆置接触塞211,将形成在绝缘层上方的下电极40还向下延伸到接触孔内与保留的堆置接触塞211接触,使与堆置接触塞211接触的部分下电极40形成一个类似锚的结构,能够对整个下电极40进行支撑,防止整个下电极40倾斜。后续工序中在下电极40上沉积介质层及上电极时,下电极40中类似锚的结构部分还能够防止整个下电极40弯曲变形,从而防止电容器坍塌。且延伸到接触孔内的部分下电极40能够增大下电极40的表面积,从而提高电容器的电荷存储量,提高电容器的电容,提高存储性能。且通过下电极40向下延伸到接触孔直接与保留的堆置接触塞211接触,取代了下电极40通过着陆焊盘222、导体膜221与堆置接触塞211接触的方式,减少了不同层之间的接触个数,降低了层间电流传输的电阻。在应用时,由于下电极40中类似锚的结构部分对整个下电极40进行支撑,电容器结构较为牢固,可以适当增大堆叠电容器的高宽比,以增大电容器的电容,进一步提高存储性能。下面结合附图对上述各个步骤的具体操作进行详细的介绍。In the above solution, by removing the
首先,参考图3,提供一基底10,该基底10可以是包括单一半导体材料的结构,如单晶硅基底10、多晶硅基底10等。该基底10也可以是已经形成有部分半导体结构的叠层结构。例如,基底10可以至少包括半导体衬底、晶体管、位线结构等。晶体管可以形成在半导体器件的半导体衬底上。位线结构可以形成在晶体管的上方。First, referring to FIG. 3 , a
接下来,在基底10上层叠有绝缘层。参考图3,该绝缘层可以为一次沉积形成的层结构,还可以为如前述关于半导体器件部分的描述中提到的由第一绝缘叠层21及第二绝缘叠层22分两次沉积形成的层结构。当然,该绝缘层还可以为由第一绝缘叠层21及第二绝缘叠层22、以及两者之间的刻蚀阻挡层组成的层结构,此时,绝缘层分至少三次沉积形成层结构。Next, an insulating layer is laminated on the
接下来,在绝缘层上开设有接触孔。该接触孔可以为开设在一次沉积形成的绝缘层上的通孔,也可以为分至少两次沉积形成的绝缘层上的通孔。参考图3,在绝缘层由前述的第一绝缘叠层21及第二绝缘叠层22层叠形成时,该接触孔包括位于下方的第一接触孔31、和位于上方的第二接触孔32。Next, contact holes are formed on the insulating layer. The contact hole may be a through hole opened on the insulating layer formed by one deposition, or may be a through hole formed on the insulating layer formed by at least two depositions. Referring to FIG. 3 , when the insulating layer is formed by stacking the aforementioned first insulating
接下来,参考图3,在接触孔内填充有堆置接触塞211、与堆置接触塞211导电连接的着陆焊盘222。具体的,参考图3,可以先在接触孔内填充有堆置接触塞;之后,在接触孔内填充有与堆置接触塞接触的导体膜;之后,在接触孔内填充有与导体膜接触的着陆焊盘。即从下向上堆置接触塞211、导体膜221及着陆焊盘222依次填充在接触孔内。其中,导体膜221的材质可以为金属硅化物,着陆焊盘222的材质可以为金属材质,以增加着陆焊盘24与堆置接触塞11之间的导电性能。Next, referring to FIG. 3 , the contact holes are filled with stacked contact plugs 211 , and
如图3所示的基底10,堆置接触塞211是填满第一接触孔31的,导体膜221及着陆焊盘222是填充在第二接触孔32内,且导体膜221及着陆焊盘222填满第二接触孔32。导体膜221与堆置接触塞211接触,着陆焊盘222与导体膜221接触。In the
在应用时,堆置接触塞211与晶体管所具有的源区或漏区接触。每个着陆焊盘222形成在与之对应的堆置接触塞211上。着陆焊盘222通过导体膜221及堆置接触塞211与晶体管所具有的源区或漏区电连接。参考图3,在第一绝缘叠层21中还形成有隔离相邻的两个堆置接触塞211的绝缘部212,堆置接触塞211和绝缘部212形成在相邻位线结构之间。在第二绝缘叠层22中还形成有隔离部223,隔离部223用于隔离相邻的两个着陆焊盘222。When applied, the stacked contact plugs 211 are in contact with the source or drain regions of the transistors. Each
接下来,参考图4,去除着陆焊盘222。去除着陆焊盘222时,可以采用湿法刻蚀或远程等离子体干法清洗工艺去除着陆焊盘222,以在不影响其他膜质的情况下将之去除。参考图5,在接触孔内从下向上依次填充有堆置接触塞211、导体膜221及着陆焊盘222时,还可以去除导体膜221。去除导体膜221时,可以采用湿法刻蚀或远程等离子体干法清洗工艺去除导体膜221,以在不影响其他膜质的情况下将之去除。Next, referring to FIG. 4 , the
接下来,参考图6,从上向下去除部分堆置接触塞211。具体去除时,可以采用湿法刻蚀或远程等离子体干法清洗工艺从上向下去除接触孔内的部分堆置接触塞211,以在不影响其他膜质的情况下将之去除。在去除接触孔内的堆置接触塞211时,还需要保留部分堆置接触塞211,该部分堆置接触塞211位于接触孔的最下方,以使后续形成的下电极40与保留的堆置接触塞211接触。Next, referring to FIG. 6 , the partially stacked contact plugs 211 are removed from top to bottom. During specific removal, wet etching or remote plasma dry cleaning process may be used to remove some of the stacked contact plugs 211 in the contact holes from top to bottom, so as to remove them without affecting other film qualities. When removing the stacked contact plugs 211 in the contact holes, it is also necessary to retain a part of the stacked contact plugs 211 , and the partially stacked contact plugs 211 are located at the bottom of the contact holes, so that the
接下来,参考图2,在绝缘层的上方形成下电极40,且下电极40还向下延伸到接触孔内与保留的堆置接触塞211接触。具体的,参考图3,在接触孔内填充有堆置接触塞211、与堆置接触塞211导电连接的着陆焊盘222之后,去除着陆焊盘222之前,可以在绝缘层上还层叠有牺牲膜层50,牺牲膜层50中开设有与着陆焊盘222连通的电容孔60。在将牺牲膜层50沉积在绝缘层上时,可以使牺牲膜层50直接沉积在绝缘层上。还可以在牺牲膜层50与绝缘层之间沉积刻蚀阻挡层70,此时,电容孔60贯穿牺牲膜层50及刻蚀阻挡层70后与着陆焊盘222连通。通过在牺牲膜层50与绝缘层之间沉积刻蚀阻挡层70,以便于后续工序中去除牺牲膜层50后,刻蚀阻挡层70能够防止后续刻蚀或清洗等操作对基底10及绝缘层造成影响,确保基底10及绝缘层的品质。Next, referring to FIG. 2 , the
如图3所示,还可以在牺牲膜层50的内部或上方形成至少一层支撑层80,此时,电容孔60不仅贯穿牺牲膜层50及刻蚀阻挡层70,还贯穿每一层支撑层80后与着陆焊盘222连通。在后续工序中形成下电极40后,去除牺牲膜层50过程中,还去除部分支撑层80,保留的部分支撑层80作为支撑结构81对下电极40进行支撑。As shown in FIG. 3 , at least one supporting
在绝缘层的上方形成下电极40时,可以在电容孔60及接触孔的孔壁、保留的部分堆置接触塞211的上端面上均形成与堆置接触塞211接触的下电极40。具体的,首先,可以在牺牲膜层50表面、电容孔60及接触孔的孔壁、保留的部分堆置接触塞211的上端面上沉积下电极材料层。之后,去除牺牲膜层50表面的下电极材料层,形成与保留的部分堆置接触塞211接触的下电极40,具体可以采用等离子体刻蚀或湿法刻蚀的方式去除牺牲膜层50表面的下电极材料层。如图6所示,如果在牺牲膜层50的上方沉积有支撑层80,则此时,下电极材料层不是沉积在牺牲膜层50的表面,而是沉积在顶部支撑层80的表面。同样地,也不是去除牺牲膜层50表面的下电极材料层,而是去除顶部支撑层80表面的下电极材料层。通过采用沉积的方式形成下电极40,以便于形成下电极40,且提高下电极40与接触孔的孔壁及堆置接触塞211的上端面接触的强度,提高对整个下电极40进行支撑的效果。When the
在形成下电极40后,还可以去除牺牲膜层50,形成如图2所示的半导体器件。具体可以采用等离子体刻蚀或湿法刻蚀的方式去除牺牲膜层50。在牺牲膜层50中还形成有至少一层支撑层80时,还需要去除每一层支撑层80的部分支撑层80,且保留每一层中与下电极40的外壁连接的部分支撑层80,作为支撑下电极40的支撑结构81,且该支撑结构81环绕至少环绕下电极40的外壁一圈。After the
通过去除接触孔内的着陆焊盘222,还去除接触孔内的部分堆置接触塞211,将形成在绝缘层上方的下电极40还向下延伸到接触孔内与保留的堆置接触塞211接触,使与堆置接触塞211接触的部分下电极40形成一个类似锚的结构,能够对整个下电极40进行支撑,防止整个下电极40倾斜。后续工序中在下电极40上沉积介质层及上电极时,下电极40中类似锚的结构部分还能够防止整个下电极40弯曲变形,从而防止电容器坍塌。且延伸到接触孔内的部分下电极40能够增大下电极40的表面积,从而提高电容器的电荷存储量,提高电容器的电容,提高存储性能。且通过下电极40向下延伸到接触孔直接与保留的堆置接触塞211接触,取代了下电极40通过着陆焊盘222、导体膜221与堆置接触塞211接触的方式,减少了不同层之间的接触个数,降低了层间电流传输的电阻。在应用时,由于下电极40中类似锚的结构部分对整个下电极40进行支撑,电容器结构较为牢固,可以适当增大堆叠电容器的高宽比,以增大电容器的电容,进一步提高存储性能。By removing the
以上所述,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到的变化或替换,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应该以权利要求的保护范围为准。The above are only specific embodiments of the present invention, but the protection scope of the present invention is not limited thereto. Any person skilled in the art who is familiar with the technical scope disclosed by the present invention can easily think of changes or substitutions. All should be included within the protection scope of the present invention. Therefore, the protection scope of the present invention should be subject to the protection scope of the claims.
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