CN114314511A - Biological hydrogen purification device based on hydrate method - Google Patents
Biological hydrogen purification device based on hydrate method Download PDFInfo
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- CN114314511A CN114314511A CN202210121192.6A CN202210121192A CN114314511A CN 114314511 A CN114314511 A CN 114314511A CN 202210121192 A CN202210121192 A CN 202210121192A CN 114314511 A CN114314511 A CN 114314511A
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- cover body
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 35
- 239000001257 hydrogen Substances 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000000746 purification Methods 0.000 title claims abstract description 22
- 239000002101 nanobubble Substances 0.000 claims abstract description 21
- 239000007789 gas Substances 0.000 claims abstract description 20
- 238000003860 storage Methods 0.000 claims abstract description 13
- 238000001816 cooling Methods 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims description 26
- 230000033228 biological regulation Effects 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 11
- 230000006911 nucleation Effects 0.000 abstract description 9
- 238000010899 nucleation Methods 0.000 abstract description 9
- 230000001105 regulatory effect Effects 0.000 abstract description 7
- 230000006698 induction Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 230000003647 oxidation Effects 0.000 abstract 1
- 230000000149 penetrating effect Effects 0.000 abstract 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 238000009434 installation Methods 0.000 description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 238000001035 drying Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005842 biochemical reaction Methods 0.000 description 1
- VTVVPPOHYJJIJR-UHFFFAOYSA-N carbon dioxide;hydrate Chemical compound O.O=C=O VTVVPPOHYJJIJR-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 238000005120 petroleum cracking Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
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Abstract
The application discloses biological hydrogen purification device based on hydrate method belongs to energy purification technical field, and it includes first reactor, second reactor, lid, subassembly, gas storage subassembly, pressure adjustment subassembly and receives bubble generator a little. The second reactor is sleeved outside the first reactor, and a cooling cavity is formed between the second reactor and the first reactor. The cover body is covered on the first reactor and the second reactor, and the air inlet assembly and the air storage assembly are communicated with the first reactor after penetrating through the cover body. The pressure regulating assembly and the micro-nano bubble generator are both arranged in the first reactor. The device for purifying the biological hydrogen based on the hydrate method comprises the micro-nano bubble generator, the micro-nano bubble generator can enable the oxidation sleeve to be mixed with water to form a micro-nano bubble solution, the micro-nano bubble solution can shorten the hydrate induction time by about 80%, and the average nucleation rate is improved by 4 times, so that the hydrogen purification time is greatly shortened, and the hydrogen purification efficiency is improved.
Description
Technical Field
The invention relates to the technical field of energy purification, in particular to a biological hydrogen purification device based on a hydrate method.
Background
With the rapid development of social economy, a large amount of fossil energy is consumed, meanwhile, the ecological environment is rapidly deteriorated, and the exploration of renewable clean energy by people is an important measure of a sustainable development strategy. Hydrogen is one of the elements rich in the earth, and the hydrogen has the advantages of high heat value, no pollution in combustion and various utilization forms and is considered as the most ideal clean energy.
The biological hydrogen is hydrogen prepared by taking biomass as a raw material to perform biochemical reaction under an anaerobic condition by microorganisms, and compared with industrial hydrogen preparation methods which depend on electrolytic water, a water gas method, petroleum cracking and the like to consume electric energy and fossil energy, the biological hydrogen preparation has the advantages of being renewable, low in pollution and rich in raw materials, and is generally concerned by people in recent years. At present, researchers mainly focus on the pretreatment of raw materials and the hydrogen production process, and the prepared hydrogen still contains a certain proportion of carbon dioxide, which can affect the combustion and use of the biological hydrogen. Therefore, the absorption and fixation of carbon dioxide in the biological hydrogen to obtain pure hydrogen not only respond to the strategic goals of 'carbon peak reaching and carbon neutralization' in China, but also are the key strategies that the biological hydrogen can be directly used as energy for efficient utilization.
The existing hydrogen purification device generally leads the mixed gas to generate nucleation reaction in deionized water, and leads carbon dioxide to be dissolved in water, thereby leading hydrogen and carbon dioxide to be separated, but the dissolution speed of the carbon dioxide is slower.
Disclosure of Invention
The invention discloses a biological hydrogen purification device based on a hydrate method, which aims to solve the problems.
The technical scheme adopted by the invention for solving the technical problems is as follows:
based on the above purpose, the invention discloses a biological hydrogen purification device based on a hydrate method, which comprises:
a first reactor comprising a reaction chamber;
a second reactor, wherein the second reactor is wrapped outside the first reactor, and a cooling cavity is formed between the second reactor and the first reactor;
the cover body is detachably connected with the first reactor and the second reactor, and is provided with an air inlet and an air outlet;
the gas inlet assembly is communicated with the reaction cavity through the gas inlet;
the gas storage component is communicated with the reaction cavity through the gas outlet;
a pressure regulation assembly mounted within the first reactor; and
the micro-nano bubble generator is arranged in the first reactor.
Optionally: the first reactor is provided with at least two first guide rods which are arranged at intervals along the circumferential direction of the first reactor;
the cover body is provided with a first guide hole which is used for being matched with the first guide rod at a position corresponding to the first guide rod, and the first guide hole is in inserting fit with the first guide rod.
Optionally: the first guide rod comprises a first rod and a second rod, one end of the first rod is connected with the first reactor, the second rod is rotatably connected with one end of the first rod, which is far away from the first reactor, and the rotating axis of the second rod is tangent to the first reactor;
the cover body is provided with a first clamping groove, the first clamping groove is arranged along the radial direction of the cover body, and the second rod is matched with the first clamping groove in a clamping mode.
Optionally: be provided with the control knob on the lid, the control knob is located on the rotation route of second pole, the control knob with the lid rotates to be connected, on the control knob with the position that first guide bar corresponds is provided with and is used for supplying the opening that the second pole passes through, just open-ended quantity with the quantity of first guide bar equals, the opening is followed the axis direction of lid runs through the control knob rotates the control knob so that the opening with first draw-in groove intercommunication or stagger.
Optionally: the second reactor is provided with at least two second guide rods which are arranged at intervals along the circumferential direction of the second reactor;
and a second guide hole matched with the second guide rod is formed in the position, corresponding to the second guide rod, of the cover body, and the second guide hole is in inserting fit with the second guide rod.
Optionally: the number of the second guide rods is equal to that of the first guide rods, an included angle between two adjacent second guide rods is equal to that between two adjacent first guide rods, each second guide rod comprises a third rod and a fourth rod, one end of each third rod is connected with the second reactor, the fourth rod is rotatably connected with one end of the third rod, which is far away from the second reactor, and the rotating axis of each fourth rod is tangent to the second reactor;
the cover body is provided with a second clamping groove, the second clamping groove is arranged along the radial direction of the cover body, the second clamping groove is arranged along the circumferential interval of the cover body with the first clamping groove, the opening can be communicated with the second clamping groove or staggered when the control knob is rotated, and the fourth rod is matched with the second clamping groove in a clamping mode.
Optionally: the first guide rods are uniformly arranged along the circumferential direction of the first reactor, and the second reaction rods are uniformly arranged along the circumferential direction of the second reactor.
Optionally: the reactor comprises a cover body, and is characterized by further comprising a self-locking structure, wherein the self-locking structure is arranged in the cover body and used for limiting the first reactor, so that the first reactor can be separated from the cover body only after the second reactor is completely separated from the cover body.
Optionally: the cover body is provided with a first annular groove, a second annular groove and at least two connecting grooves, the diameter of the first annular groove is smaller than that of the second annular groove, the first guide hole is communicated with the first annular groove, the second guide hole is communicated with the second annular groove, two ends of each connecting groove are respectively communicated with the first annular groove and the second annular groove, the connecting grooves are located at positions corresponding to the second annular groove and the second guide hole, the first reactor is in clamping fit with the first annular groove, clamping holes are formed in positions corresponding to the first reactor and the connecting grooves, and the second reactor is in clamping fit with the second annular groove;
the self-locking structure comprises a clamping block and an elastic piece, the clamping block is in sliding fit with the connecting groove, two ends of the elastic piece are respectively connected with the cover body and the clamping block, the elastic piece enables the clamping block to have a trend of moving towards the second annular groove, and when the second guide rod or the second reactor enters the second guide groove, the clamping block can be pushed to be clamped into the clamping hole.
Optionally: an inclined plane is arranged at one end, facing the second annular groove, of the fixture block, the inclined plane is located on one side, facing the second reactor, of the fixture block, and the length of the inclined plane is larger than or equal to the width of the second annular groove.
Compared with the prior art, the invention has the following beneficial effects:
the invention discloses a hydrate method-based biological hydrogen purification device which comprises a micro-nano bubble generator, wherein the micro-nano bubble generator can enable a di-oxidation sleeve to be mixed with water to form a micro-nano bubble solution, the micro-nano bubble solution can increase a gas-liquid interface, enhance mass transfer and provide nucleation driving force, compared with nucleation reaction in deionized water, the micro-nano bubble solution can shorten the hydrate induction time by about 80%, and improve the average nucleation rate by 4 times, so that the hydrogen purification time is greatly shortened, and the hydrogen purification efficiency is improved.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present application, the drawings that are required to be used in the embodiments will be briefly described below, it should be understood that the following drawings only illustrate some embodiments of the present application and therefore should not be considered as limiting the scope, and for those skilled in the art, other related drawings can be obtained from the drawings without inventive effort.
Fig. 1 shows a cross-sectional view of a biological hydrogen purification apparatus based on a hydrate method according to an embodiment of the present invention at a first view;
FIG. 2 shows an enlarged view of a portion of FIG. 1 in accordance with an embodiment of the present disclosure;
fig. 3 is a sectional view of a biological hydrogen purification apparatus based on a hydrate method according to an embodiment of the present disclosure;
FIG. 4 shows a schematic view of a first reactor disclosed in an embodiment of the present invention;
FIG. 5 shows a schematic diagram of a second reactor disclosed in an embodiment of the present invention;
FIG. 6 illustrates a cross-sectional view of a cover disclosed in an embodiment of the present invention at a first perspective;
FIG. 7 illustrates a cross-sectional view of a cover disclosed in an embodiment of the present invention at a second perspective;
FIG. 8 illustrates a top view of a cover disclosed in an embodiment of the present invention;
fig. 9 illustrates a bottom view of the cover disclosed in an embodiment of the present invention.
In the figure:
110-a first reactor; 111-a reaction chamber; 112-a clamping hole; 113-a first guide bar; 1131 — first bar; 1132 — a second rod; 120-a second reactor; 121-a cooling chamber; 122-a second guide bar; 1221-a third rod; 1222-a fourth rod; 130-a cover body; 131-control knob; 1311-opening; 132-a first annular groove; 133-a second annular groove; 134-a first guide hole; 135-a first card slot; 136-a second pilot hole; 137-a second card slot; 138-a connecting trough; 1391-air inlet; 1392-vent; 140-an air intake assembly; 141-biological hydrogen gas storage tank; 142-a first connection tube; 143-a gas flow meter; 144-a first valve; 150-a gas storage component; 151-hydrogen gas cylinder; 152-a second connecting tube; 153-soda lime drying tube; 154-a second valve; 160-micro nano bubble generator; 170-temperature control component; 180-self-locking structure; 181-a fixture block; 1811-inclined plane; 182-elastic member.
Detailed Description
The present invention will be described in further detail below with reference to specific embodiments and with reference to the attached drawings.
In order to make the objects, technical solutions and advantages of the embodiments of the present application clearer, the technical solutions in the embodiments of the present application will be clearly and completely described below with reference to the drawings in the embodiments of the present application, and it is obvious that the described embodiments are some embodiments of the present application, but not all embodiments. The components of the embodiments of the present application, generally described and illustrated in the figures herein, can be arranged and designed in a wide variety of different configurations.
Thus, the following detailed description of the embodiments of the present application, as disclosed in the accompanying drawings, is not intended to limit the scope of the claimed application, but is merely representative of selected embodiments of the application. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present application.
It should be noted that the embodiments and features of the embodiments in the present application may be combined with each other without conflict.
It should be noted that: like reference numbers and letters refer to like items in the following figures, and thus, once an item is defined in one figure, it need not be further defined and explained in subsequent figures.
In the description of the embodiments of the present application, it should be noted that the indication of orientation or positional relationship is based on the orientation or positional relationship shown in the drawings, or the orientation or positional relationship which is usually placed when the product of the application is used, or the orientation or positional relationship which is usually understood by those skilled in the art, or the orientation or positional relationship which is usually placed when the product of the application is used, and is only for the convenience of describing the application and simplifying the description, but does not indicate or imply that the indicated device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the application. Furthermore, the terms "first," "second," "third," and the like are used solely to distinguish one from another and are not to be construed as indicating or implying relative importance.
In the description of the embodiments of the present application, it should also be noted that, unless otherwise explicitly stated or limited, the terms "disposed," "mounted," and "connected" are to be construed broadly, and may for example be fixedly connected, detachably connected, or integrally connected; may be directly connected or indirectly connected through an intermediate. The specific meaning of the above terms in the present application can be understood in a specific case by those of ordinary skill in the art.
Example (b):
referring to fig. 1 to 3, an embodiment of the present invention discloses a biological hydrogen purification apparatus based on a hydrate method, which includes a first reactor 110, a second reactor 120, a cover 130, an air intake assembly 140, an air storage assembly 150, a pressure regulating assembly, and a micro-nano bubble generator 160. The second reactor 120 is sleeved outside the first reactor 110, and a cooling cavity 121 is formed between the second reactor 120 and the first reactor 110. The cover 130 covers the first reactor 110 and the second reactor 120, and both the gas inlet assembly 140 and the gas storage assembly 150 pass through the cover 130 and then communicate with the first reactor 110. The pressure regulating assembly and the micro-nano bubble generator 160 are installed in the first reactor 110.
The biological hydrogen purification device based on the hydrate method disclosed by the embodiment comprises the micro-nano bubble generator 160, the micro-nano bubble generator 160 can enable the dioxide sleeve to be mixed with water to form a micro-nano bubble solution, the micro-nano bubble solution can increase a gas-liquid interface, enhance mass transfer and provide nucleation driving force, compared with nucleation reaction in deionized water, the micro-nano bubble solution can shorten the hydrate induction time by about 80%, and the average nucleation rate is improved by 4 times, so that the hydrogen purification time is greatly shortened, and the hydrogen purification efficiency is improved.
Referring to fig. 1, 4 and 5, the first reactor 110 has a circular cross-section, and the first reactor 110 includes a reaction chamber 111. The second reactor 120 is also circular in cross-section and the diameter of the second reactor 120 is greater than the diameter of the first reactor 110. The second reactor 120 is sleeved outside the first reactor 110, a cooling cavity 121 is formed between the first reactor 110 and the second reactor 120, the temperature control component 170 is communicated with the cooling cavity 121, and the temperature of the reaction cavity 111 can be adjusted by using the temperature control component 170, so that the reaction cavity 111 maintains a low-temperature environment required by the hydrate reaction. A pressure regulating assembly is provided in the reaction chamber 111, by which the pressure in the reaction chamber 111 can be regulated, so that the pressure in the reaction chamber 111 is regulated to a pressure required for nucleation of carbon dioxide hydrate. The micro-nano bubble generator 160 is arranged in the middle of the pressure regulating assembly. A temperature sensor and a pressure sensor can be further installed in the first reactor 110, both of which are connected to a computer, so that the real-time temperature parameters and pressure parameters in the reaction chamber 111 can be transmitted to the computer, and an operator can know the degree of reaction progress conveniently.
Referring to fig. 1 and 3, the cover 130 covers the first reactor 110 and the second reactor 120, and the cover 130 is detachably connected to the first reactor 110 and the second reactor 120. The cover 130 can close the reaction chamber 111 and the cooling chamber 121 after being mounted on the first reactor 110 and the second reactor 120. Referring to fig. 9, the cover 130 has a first annular groove 132 and a second annular groove 133 at the bottom, the diameter of the first annular groove 132 is smaller than that of the second annular groove 133, the first reactor 110 is snap-fitted into the first annular groove 132, and the second reactor 120 is snap-fitted into the second annular groove 133.
Referring to fig. 4, at least two first guide rods 113 are disposed at the top of the first reactor 110, the first guide rods 113 are disposed at intervals along the circumferential direction of the first reactor 110, and the first guide rods 113 are uniformly disposed along the circumferential direction of the first reactor 110, so that the installation is more convenient, and the connection with the cover 130 is more stable. Wherein, the first guiding rod 113 comprises a first rod 1131 and a second rod 1132, the bottom of the first rod 1131 is connected with the first reactor 110, the second rod 1132 is rotatably connected with the top of the first rod 1131, and the rotation axis of the second rod 1132 is tangent to the first reactor 110, that is, the second rod 1132 can rotate to a position parallel to the radial direction of the first reactor 110.
Referring to fig. 7 to 9, a first guide hole 134 is formed in the cover 130 at a position corresponding to the first guide rod 113, the first guide hole 134 is communicated with the first annular groove 132, and one end of the first guide hole 134 facing away from the first annular groove 132 penetrates through the top of the cover 130. The cover 130 is further provided with a first engaging groove 135, one end of the first engaging groove 135 is communicated with the first guiding hole 134, and the other end of the first engaging groove 135 extends toward the axis of the cover 130, that is, the first engaging groove 135 is disposed along the radial direction of the cover 130. The number of the first engaging grooves 135 and the number of the first guiding holes 134 are equal to the number of the first guiding rods 113, and the first engaging grooves 135, the first guiding holes 134 and the first guiding rods 113 are arranged in a one-to-one correspondence manner. In this embodiment, only two first guide rods 113, two first guide holes 134, and two first engaging grooves 135 are provided, and in other embodiments, more first guide rods 113, two first guide holes 134, and two first engaging grooves 135 may be provided.
Referring to fig. 7, a control knob 131 is further disposed on the top of the cover 130, the control knob 131 is disposed coaxially with the cover 130, the control knob 131 is rotatably connected to the cover 130, a plurality of openings 1311 are disposed on the control knob 131, and the number of the openings 1311 is equal to the number of the first guide rods 113. An end of the opening 1311 facing away from the axis of the control knob 131 extends to a side wall of the control knob 131, and the opening 1311 penetrates the control knob 131 in the axial direction of the control knob 131. When the control knob 131 is rotated, the opening 1311 and the first card slot 135 can be communicated or staggered, when the opening 1311 and the first card slot 135 are communicated, the second rod 1132 is rotated, one end of the second rod 1132, which is far away from the first rod 1131, can penetrate through the opening 1311 and then be clamped into the first card slot 135, at this moment, the control knob 131 is rotated, the opening 1311 and the first card slot 135 are staggered, namely, the second rod 1132 is limited in the first card slot 135, at this moment, the first reactor 110 is installed on the cover 130, and at this moment, the first reactor 110 cannot be separated from the cover 130.
Referring to fig. 5, at least two second guide rods 122 are disposed at the top of the second reactor 120, the second guide rods 122 are disposed at intervals along the circumferential direction of the second reactor 120, and the second guide rods 122 are uniformly disposed along the circumferential direction of the second reactor 120 (of course, it is only an embodiment of this embodiment that the first guide rods 113 and the second guide rods 122 are uniformly disposed, in other embodiments, it is also possible that the plurality of first guide rods 113 are not uniformly disposed, and it is only necessary that an included angle between two adjacent second guide rods 122 is equal to an included angle between two adjacent first guide rods 113 during installation), which is more convenient and is more stable after being connected with the cover 130. Wherein the second guide bar 122 includes a third bar 1221 and a fourth bar 1222, the bottom of the third bar 1221 is connected to the second reactor 120, the fourth bar 1222 is rotatably connected to the top of the third bar 1221, and the rotation axis of the fourth bar 1222 is tangential to the second reactor 120, i.e., the fourth bar 1222 can be rotated to a position parallel to the radial direction of the second reactor 120.
Referring to fig. 7 to 9, a second guide hole 136 is formed in the cover 130 at a position corresponding to the second guide rod 122, the second guide hole 136 is communicated with the second annular groove 133, and an end of the second guide hole 136, which is away from the second annular groove 133, penetrates through a top of the cover 130. The cover 130 is further provided with a second engaging groove 137, one end of the second engaging groove 137 is communicated with the second guiding hole 136, the other end of the second engaging groove 137 extends toward the axis of the cover 130, that is, the second engaging groove 137 is radially disposed along the cover 130, and the second engaging groove 137 and the first engaging groove 135 are circumferentially spaced along the cover 130. One end of the second locking groove 137 facing away from the second guide groove extends to a position below the control knob 131, that is, when the control knob 131 rotates, the opening 1311 on the control knob 131 can be communicated with or staggered from the second locking groove 137. When the opening 1311 is communicated with the second slot 137, the fourth rod 1222 is rotated, one end of the fourth rod 1222, which is away from the third rod 1221, can pass through the opening 1311 and then be clamped into the second slot 137, at this time, the control knob 131 is rotated, the opening 1311 and the second slot 137 are staggered, that is, the fourth rod 1222 is limited in the second slot 137, at this time, the second reactor 120 is installed on the cover 130, and at this time, the second reactor 120 cannot be separated from the cover 130.
In the present embodiment, the number of the second guide rods 122 is equal to that of the first guide rods 113, so that the control of the control knob 131 is more convenient.
Referring to fig. 2 and 6, the self-locking structure 180 is installed in the cover 130, and the self-locking structure 180 is used for limiting the first reactor 110, so that the first reactor 110 can be separated from the cover 130 only after the second reactor 120 is completely separated from the cover 130, and when the second reactor 120 is not completely separated from the cover 130, the first reactor 110 can be firmly locked on the cover 130 by the self-locking structure 180, so as to prevent the first reactor 110 from being separated from the cover 130 due to a fault when the cover 130 is separated from the second reactor 120, and further prevent the first reactor 110 from colliding with the second reactor 120.
At least two connecting grooves 138 are further disposed on the cover 130, the number of the connecting grooves 138 is equal to the number of the second guiding holes 136, the plurality of connecting grooves 138 and the plurality of second guiding holes 136 are disposed in a one-to-one correspondence, and projections of the connecting grooves 138 and the second guiding holes 136 in the axial direction of the cover 130 are located on the same radius of the cover 130. One end of the connection groove 138 communicates with the first annular groove 132, and the other end of the connection groove 138 communicates with the second annular groove 133.
Referring to fig. 2, the first reactor 110 is provided with a plurality of engaging holes 112, the number of the engaging holes 112 is equal to the number of the second guiding holes 136, and the engaging holes 112 are disposed at positions corresponding to the first reactor 110 and the connecting slots 138.
The self-locking assembly includes a locking block 181 and an elastic member 182, the locking block 181 is slidably engaged with the connecting groove 138, two ends of the elastic member 182 are respectively connected with the cover 130 and the locking block 181, the elastic member 182 makes the locking block 181 have a tendency of moving toward the second annular groove 133, and when the second guide rod 122 or the second reactor 120 enters the second guide groove, the locking block 181 can be pushed to be locked into the locking hole 112.
The number of the self-locking components is multiple, and the plurality of self-locking components and the plurality of connecting grooves 138 are arranged in a one-to-one correspondence manner.
Referring to fig. 2, an inclined surface 1811 is disposed at an end of the latch 181 facing the second annular groove 133, the inclined surface 1811 is located at a side of the latch 181 facing the second reactor 120, and a length of the inclined surface 1811 is greater than or equal to a width of the second annular groove 133. The inclined plane 1811 can make the installation of the second reactor 120 more convenient, and when the second reactor 120 is installed, the second guide rod 122 can push the clamping block 181 into the clamping hole 112 by using the inclined plane 1811 only by inserting the second guide rod 122 into the second guide hole 136.
Referring to fig. 8, an air inlet 1391 and an air outlet 1392 are formed in the cover 130, and the air inlet 1391 and the air outlet 1392 are staggered from the first engaging groove 135 and the second engaging groove 137. The air intake assembly 140 includes a first connection pipe 142 of the bio-hydrogen gas storage tank 141, a gas flow meter 143, and a first valve 144. One end of the first connection pipe 142 is communicated with the bio-hydrogen gas storage tank 141, the other end of the first connection pipe 142 is communicated with the reaction chamber 111 through the gas inlet 1391, and the gas flow meter 143 and the first valve 144 are installed on the first connection pipe 142. The gas storage module 150 includes a hydrogen gas storage cylinder 151, a second connection pipe 152, a soda lime drying pipe 153, and a second valve 154. One end of the second connection pipe 152 is connected to the hydrogen gas storage cylinder 151, the other end of the second connection pipe 152 is connected to the reaction chamber 111 through the gas outlet 1392, and the soda lime drying pipe 153 and the second valve 154 are installed on the second connection pipe 152.
The biological hydrogen purification device based on the hydrate method disclosed in the embodiment is disassembled and assembled as follows:
when the installation is performed, firstly deionized water is injected into the first reactor 110, then the first guide rod 113 is clamped into the first guide hole 134, then the cover 130 is made to approach the first reactor 110, after the first reactor 110 is clamped into the first annular groove 132, the control knob 131 is twisted, the opening 1311 is communicated with the first clamping groove 135, at this time, the second rod 1132 is rotated, the second rod 1132 is clamped into the second clamping groove 137, then the control knob 131 is twisted, the opening 1311 is staggered with the second clamping groove 137, and the installation of the first reactor 110 is completed.
Then, cooling water is injected into the second reactor 120, and the second guide rod 122 is engaged into the second guide hole 136. After the second guiding rod 122 is clamped into the second guiding hole 136, the second guiding rod 122 can push the clamping block 181 back to the connecting groove 138, and one end of the clamping block 181 departing from the second guiding rod 122 is clamped into the clamping hole 112 of the first reactor 110.
Then, the second reaction vessel 120 is moved toward the cover 130, and after the second reaction vessel 120 is engaged in the second annular groove 133, the control knob 131 is twisted to communicate the opening 1311 with the second engaging groove 137, and at this time, the fourth rod 1222 is rotated to engage in the second engaging groove 137. And the control knob 131 is turned again to stagger the opening 1311 and the second slot 137, thereby completing the installation of the second reactor 120. At this time, since one end of the latch 181 is located in the latching hole 112 of the first reactor 110 and the other end of the latch 181 is located in the connecting groove 138, the first reactor 110 cannot be separated from the lid 130, even though the control knob 131 rotates to connect the opening 1311 thereof with the first latching groove 135, the first reactor 110 cannot be separated from the lid 130.
When disassembling, the control knob 131 is first twisted to align the opening 1311 with the second slot 137, and then the fourth rod 1222 is rotated to be perpendicular to the axis of the lid 130, so that the second reactor 120 can be separated from the lid 130, thereby facilitating the replacement of the cooling water.
When the second reactor 120 and the second guide rod 122 are not completely separated from the cover 130, the latch 181 is always restricted in the latch hole 112 of the first reactor 110, so that the first reactor 110 is not separated from the cover 130 by mistake.
When the second reactor 120 and the second guide rod 122 are completely separated from the cover 130, the cover 130 and the first reactor 110 may be removed from the second reactor 120, and after the first reactor 110 is moved to a proper position, the cover 130 is separated from the first reactor 110, so that the used deionized water may be poured into a designated container for recycling. After the second reactor 120 and the second guide rod 122 are completely separated from the cover 130, the latch 181 is separated from the range of the latch hole 112 under the action of the elastic member 182, that is, the first reactor 110 and the cover 130 can be separated only by rotating the second guide rod 122 to the vertical state.
The above description is only a preferred embodiment of the present application and is not intended to limit the present application, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, improvement and the like made within the spirit and principle of the present application shall be included in the protection scope of the present application.
Claims (10)
1. A biological hydrogen purification device based on a hydrate method is characterized by comprising:
a first reactor comprising a reaction chamber;
a second reactor, wherein the second reactor is wrapped outside the first reactor, and a cooling cavity is formed between the second reactor and the first reactor;
the cover body is detachably connected with the first reactor and the second reactor, and is provided with an air inlet and an air outlet;
the gas inlet assembly is communicated with the reaction cavity through the gas inlet;
the gas storage component is communicated with the reaction cavity through the gas outlet;
a pressure regulation assembly mounted within the first reactor; and
the micro-nano bubble generator is arranged in the first reactor.
2. The device for purifying biological hydrogen gas based on the hydrate method according to claim 1, wherein the first reactor is provided with at least two first guide rods, and the at least two first guide rods are arranged at intervals along the circumferential direction of the first reactor;
the cover body is provided with a first guide hole which is used for being matched with the first guide rod at a position corresponding to the first guide rod, and the first guide hole is in inserting fit with the first guide rod.
3. The device for purifying biological hydrogen gas based on the hydrate method according to claim 2, wherein the first guide rod comprises a first rod and a second rod, one end of the first rod is connected with the first reactor, the second rod is rotatably connected with one end of the first rod, which is far away from the first reactor, and the rotation axis of the second rod is tangential to the first reactor;
the cover body is provided with a first clamping groove, the first clamping groove is arranged along the radial direction of the cover body, and the second rod is matched with the first clamping groove in a clamping mode.
4. The device for purifying biological hydrogen gas based on a hydrate method according to claim 3, wherein a control knob is arranged on the cover body, the control knob is located on a rotation path of the second rod, the control knob is rotatably connected with the cover body, openings for the second rod to pass through are arranged at positions on the control knob corresponding to the first guide rods, the number of the openings is equal to that of the first guide rods, the openings penetrate through the control knob along the axial direction of the cover body, and the control knob is rotated to enable the openings to be communicated with the first clamping grooves or staggered.
5. The device for purifying biological hydrogen gas based on the hydrate method according to claim 4, wherein the second reactor is provided with at least two second guide rods, and the at least two second guide rods are arranged at intervals along the circumferential direction of the second reactor;
and a second guide hole matched with the second guide rod is formed in the position, corresponding to the second guide rod, of the cover body, and the second guide hole is in inserting fit with the second guide rod.
6. The device for purifying biohydrogen based on the hydrate method according to claim 5, wherein the number of the second guide bars is equal to the number of the first guide bars, the included angle between two adjacent second guide bars is equal to the included angle between two adjacent first guide bars, the second guide bars comprise a third bar and a fourth bar, one end of the third bar is connected with the second reactor, the fourth bar is rotatably connected with one end of the third bar, which is far away from the second reactor, and the rotation axis of the fourth bar is tangential to the second reactor;
the cover body is provided with a second clamping groove, the second clamping groove is arranged along the radial direction of the cover body, the second clamping groove is arranged along the circumferential interval of the cover body with the first clamping groove, the opening can be communicated with the second clamping groove or staggered when the control knob is rotated, and the fourth rod is matched with the second clamping groove in a clamping mode.
7. The device for purifying biological hydrogen gas based on the hydrate method according to claim 6, wherein the first guide rods are uniformly arranged along the circumferential direction of the first reactor, and the second reaction rods are uniformly arranged along the circumferential direction of the second reactor.
8. The device for purifying biological hydrogen gas based on the hydrate method according to claim 6, further comprising a self-locking structure, wherein the self-locking structure is installed in the cover body, and the self-locking structure is used for limiting the first reactor, so that the first reactor can be separated from the cover body only after the second reactor is completely separated from the cover body.
9. The device for purifying biological hydrogen based on the hydrate method according to claim 8, wherein the cover body is provided with a first annular groove, a second annular groove and at least two connecting grooves, the diameter of the first annular groove is smaller than that of the second annular groove, the first guide hole is communicated with the first annular groove, the second guide hole is communicated with the second annular groove, two ends of each connecting groove are respectively communicated with the first annular groove and the second annular groove, the connecting grooves are located at positions corresponding to the second annular groove and the second guide hole, the first reactor is in clamping fit with the first annular groove, clamping holes are arranged at positions corresponding to the first reactor and the connecting grooves, and the second reactor is in clamping fit with the second annular groove;
the self-locking structure comprises a clamping block and an elastic piece, the clamping block is in sliding fit with the connecting groove, two ends of the elastic piece are respectively connected with the cover body and the clamping block, the elastic piece enables the clamping block to have a trend of moving towards the second annular groove, and when the second guide rod or the second reactor enters the second guide groove, the clamping block can be pushed to be clamped into the clamping hole.
10. The device for purifying biological hydrogen gas based on the hydrate method according to claim 9, wherein an inclined surface is provided at one end of the fixture block facing the second annular groove, the inclined surface is located at one side of the fixture block facing the second reactor, and the length of the inclined surface is greater than or equal to the width of the second annular groove.
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