CN114276167A - Low-light marble ceramic tile with uniform luminosity and preparation method thereof - Google Patents
Low-light marble ceramic tile with uniform luminosity and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a low-light marble ceramic tile with uniform luminosity and a preparation method thereof, and relates to the technical field of ceramic tiles. The low-light marble ceramic tile with uniform luminosity comprises a blank body and a glaze layer; the glaze layer is formed by superposing a glaze layer, an ink-jet printing layer and a dry particle glaze layer from bottom to top; the overglaze layer comprises the following components in percentage by mass: 98.68 to 99.34 percent of basic overglaze and 0.66 to 1.32 percent of molten aluminum; the ink-jet printing layer is used for printing corresponding patterns and colors on the green brick with the overglaze layer according to the requirement of the surface effect by an ink-jet printer; the dry particle glaze layer consists of the following components: printing oil, printing paste, drying particles and polishing glaze; the weight ratio of dry particles to glaze polishing in the dry particle glaze layer is as follows: and (3) dry granulation: and (1-6: 15-45) polishing. The marble ceramic tile has the advantages of softness, comfort, good wear resistance, simple preparation process, low cost, no need of changing the existing production line and simple popularization.
Description
Technical Field
The invention relates to the technical field of ceramic tiles, in particular to a low-light marble ceramic tile with uniform luminosity and a preparation method thereof.
Background
Along with the improvement of the living standard of people, the requirement on the home decoration effect is higher and higher. In recent years, ceramic tiles have been widely used in various fields, including residential spaces, office spaces, public areas, etc., which is in great demand for decorative ceramic tiles. The ceramic tiles are divided according to glossiness, and matte ceramic tiles, soft ceramic tiles and bright ceramic tiles are available on the market at present; the matte ceramic tile generally refers to a tile with the glossiness of 10-30 degrees; the soft light ceramic tile is a tile with the glossiness of 30-60 degrees; the bright ceramic tile refers to a tile with the glossiness of more than 60 degrees; the bright brick mainly comprises a polished brick and a full-polished glaze. Traditional ceramic tiles have a slightly higher gloss and a cold surface effect, which can cause people who live in such environments for a long time to feel slightly uncomfortable. At present, the main method for changing the surface glossiness of the ceramic tile is polishing, and generally, grinding heads with different meshes and water are adopted to polish the surface glaze layer of the ceramic tile so as to obtain ceramic tile glaze surfaces with different glossiness. But the polishing and grinding amount of the surface of the ceramic tile is high, and a large amount of waste slag is generated.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides the low-gloss marble ceramic tile with uniform luminosity and the preparation method thereof.
In order to achieve the purpose, the invention adopts the technical scheme that: a low-light marble ceramic tile with uniform luminosity comprises a blank body and a glaze layer; the glaze layer is formed by superposing a glaze layer, an ink-jet printing layer and a dry particle glaze layer from bottom to top; the overglaze layer comprises the following components in percentage by mass: 98.68 to 99.34 percent of basic overglaze and 0.66 to 1.32 percent of molten aluminum; the ink-jet printing layer is used for printing corresponding patterns and colors on the green brick with the overglaze layer according to the requirement of the surface effect by an ink-jet printer; the dry particle glaze layer consists of the following components: printing oil, printing paste, drying particles and polishing glaze; the weight ratio of dry particles to glaze polishing in the dry particle glaze layer is as follows: and (3) dry granulation: and (1-6: 15-45) polishing. Through a large amount of researches, the inventor of the application discovers that the roughness of the surface of the ceramic tile can be effectively adjusted by adjusting the proportion of glaze throwing and dry grain in dry grain glaze, so that the surface roughness is in an available range, and the wear resistance of the surface of the ceramic tile is improved. According to the invention, after the aluminum water is added into the overglaze, the melting temperature of the whole glaze is increased. Under the condition of matching with the existing firing temperature of the company for producing the ceramic tiles, the aluminum water content in the overglaze is adjusted on the premise of not influencing the performance of the ceramic tiles, so that the overglaze is not completely fired, the melting amount of dry grains in the dry grain glaze to the overglaze is reduced, and the surface roughness of the ceramic tiles is improved. Through a great deal of research, the inventor of the application finds that when the ratio of dry particles to polished glaze in the dry particle glaze is 1:20, the surface roughness is applicable, the glossiness is low, and the wear resistance is strong.
As a preferred embodiment of the low-light marble ceramic tile with uniform luminosity, the thickness of the overglaze layer is 0.2-0.3 mm; the thickness of the dry particle glaze layer is 0.1-0.2 mm.
As a preferred embodiment of the photometric homogeneous low-light marble ceramic tile according to the present invention, the base overglaze comprises the following components in mass percent: SiO 22 48.33％，Al2O3 26.31％，CaO 6.43％，MgO 3.09％，K2O 1.77％，Na2O 3.22％，ZnO 0.06％，FeO3 0.2％，TiO2 0.1％，BaO 3.69％，P2O5 0.04％，ZrO20.02 percent, 6.71 percent of ignition loss and the balance of impurities.
As a preferred embodiment of the low-light marble ceramic tile with uniform luminosity, the aluminum water comprises the following components in percentage by mass: 51.59 percent of alumina dry powder, 0.39 percent of sodium tripolyphosphate, 0.31 percent of sodium carboxymethyl cellulose and 47.72 percent of water. Through a large amount of researches, the inventor of the application discovers that a certain amount of aluminum water is added into the overglaze, so that the surface glossiness of the ceramic tile can be effectively reduced, a soft and comfortable effect is provided for people as a whole, a certain regulating effect is achieved on the surface roughness, and the adverse effect on the ink jet color effect is not generated.
As a preferred embodiment of the low-light marble ceramic tile with uniform luminosity, the alumina water is subjected to ball milling for 18 hours, the fineness is 325 meshes, the screen residue is less than or equal to 0.4 percent, and the specific gravity is 1.55-1.58 g/ml; the basic overglaze is ball-milled for 12 hours, the fineness is 325 meshes, the screen residue is less than or equal to 0.5 percent, and the specific gravity is 1.79-1.83 g/ml.
As a preferred embodiment of the low-light marble ceramic tile with uniform luminosity, the glaze comprises the following components in percentage by mass: SiO 22 42.42％，Al2O3 21.56％，CaO 7.55％，MgO 5.55％，K2O 2.19％，Na2O 3.64％，ZnO 2.45％，BaO 4.37％，TiO2 0.17％，FeO30.19 percent, 9.11 percent of ignition loss and the balance of impurities; and the glaze polishing is performed with ball milling for 10 hours, the fineness is 325 meshes, the screen residue is less than or equal to 0.05 percent, and the specific gravity is 1.56-1.60 g/ml.
As a preferred embodiment of the photometric homogeneous low-light marble ceramic tile according to the present invention, the dry granules are composed of the following components by mass: SiO 22 51.79％，Al2O3 10.27％，CaO 11.57％，MgO 2.22％，K2O 5％，Na2O 1.24％，ZnO 7.88％，FeO3 0.15％，TiO20.08 percent, 1.69 percent of BaO, 8.02 percent of ignition loss and the balance of impurities; and crushing the dry particles by using fritted glaze, and screening by using a screen with 120-230 meshes, wherein the fineness screen residue is less than or equal to 0.02%. The surface of the ceramic tile prepared by the method has a concave-convex effect, but the maximum glossiness difference is within 5 degrees, and the whole ceramic tile looks soft and is not reflective and dazzling. The reason is that: the dry glaze layer has low content of Ti, Pb, Ba, etc., and the density of the dry glaze layer is reduced, so the refractive index of the reaction is also reducedLow content of Si, Al and Mg, and low refractive index of the oxide, thus the glaze surface has low glossiness. In the dry granules R2The material quantity ratio of O to RO is 2.67, the high temperature viscosity is small, the fluidity is strong, the distribution of each element oxide in the dry grain glaze layer is uniform, and the glossiness of each part is also uniform.
The invention also provides a preparation method of the low-light marble ceramic tile with uniform luminosity, which comprises the following steps:
(1) pressing a ceramic tile green body by using a concave-convex die;
(2) the overglaze is sprayed on the ceramic tile green body in a linear oil spraying way;
(3) printing patterns and colors on the surface of the ceramic tile blank in the step (2) in an ink-jet manner;
(4) printing dry grain glaze on the surface of the ceramic tile in the step (3);
(5) firing the ceramic tile treated in the step (4);
(6) and (5) edging the ceramic tile obtained in the step (5) to obtain the marble ceramic tile.
In the firing process of the marble ceramic tile blank, the oxidation zone of the blank is prolonged to be more than 14min, and the firing curve is more gentle. The ultra-long oxidation zone (generally less than 5min) ensures the full oxidation and exhaust of the green body before sintering. The overglaze ball milling time is long, the granularity is small, the glaze layer is thin, and the probability of generating bubbles in the glaze layer is reduced; the heat preservation time in the firing process is long, and the bubbles in the glaze layer are few, so that the bubbles moving to the surface of the ceramic tile are also few, and meanwhile, Al in the overglaze2O3The content is high, the probability of bluing the surface of the ceramic tile is reduced, and the accuracy and the definition of the color of the layout are ensured.
As a preferred embodiment of the method for producing a low-gloss ceramic tile having a uniform luminosity according to the present invention, the firing procedure in the step (4) is: the temperature is firstly increased from room temperature to 1250 ℃ within 50min, and is kept at 1250 ℃ for 30min, and finally is reduced from 1250 ℃ to 400 ℃ within 8 min.
As a preferred embodiment of the preparation method of the low-light marble ceramic tile with uniform luminosity, the glazing specific gravity of the overglaze in the step (2) is 1.68-1.70 g/ml, the flow rate is 18-20 s, and the glazing amount is 361-388 g/m2(ii) a The glazing specific gravity of the dry granular glaze in the step (4) is 1.56-1.58 g/ml, the flow rate is 6-7 min, and the glazing amount is 185.2-198.1 g/m2。
The invention has the beneficial effects that: (1) according to the ceramic tile, a certain amount of aluminum water is added into the overglaze, so that the surface glossiness of the ceramic tile can be effectively reduced, the prepared ceramic tile has soft and comfortable effects, meanwhile, a certain regulating effect is achieved on the surface roughness, and adverse effects on the ink jet pattern effect are not generated; (2) according to the ceramic tile, the problem that the tile surface of the ceramic tile is blue and foggy is solved by adjusting the adding proportion of the glaze throwing and the dry particles, so that the overall color of the tile surface is clear and rich, the roughness of the surface of the ceramic tile is effectively adjusted, the surface roughness is in an available range, and the wear resistance of the surface of the ceramic tile is improved; (3) the ceramic tile disclosed by the invention is simple in preparation process and low in cost, does not need to change the existing production line, and is simple to popularize; (4) the existing brick with a plurality of concave-convex effect has the glossiness difference of 20-25 degrees, and after strong light is directly radiated, the high-glossiness part can reflect too much light to eyes of people, so that the people feel dazzling. The ceramic tile has uniform luminosity, the maximum luminosity difference of the whole tile is within 5 degrees without polishing, the use comfort of consumers is improved, the generation of waste residues of the ceramic tile is reduced, and the influence on the environment is reduced.
Detailed Description
The present invention will be described in further detail with reference to the following examples. This should not be understood as limiting the scope of the above-described subject matter of the present invention to the following examples. All the technologies realized based on the above contents of the present invention belong to the scope of the present invention.
Examples 1 to 9 and comparative examples 1 to 2
The contents of the respective components in the overglaze and the dry glaze of the marble ceramic tiles of examples 1 to 9 and comparative examples 1 to 2 are shown in table 1.
The base overglaze of the ceramic tiles of examples 1 to 9 and comparative examples 1 to 2 is composed of the following components in percentage by mass：SiO2 48.33％，Al2O3 26.31％，CaO 6.43％，MgO 3.09％，K2O 1.77％，Na2O 3.22％，ZnO 0.06％，FeO3 0.2％，TiO2 0.1％，BaO 3.69％，P2O5 0.04％，ZrO20.02 percent, 6.71 percent of ignition loss and the balance of impurities.
The aluminum water of the marble ceramic tiles of the examples 1-9 and the comparative examples 1-2 consists of the following components in percentage by mass: 51.59 percent of alumina dry powder, 0.39 percent of sodium tripolyphosphate, 0.31 percent of sodium carboxymethyl cellulose and 47.72 percent of water.
The glaze polishing of the marble ceramic tiles of the embodiments 1-9 and the comparative examples 1-2 comprises the following components in percentage by mass: SiO 22 42.42％，Al2O3 21.56％，CaO 7.25％，MgO 5.55％，K2O 2.19％，Na2O 3.64％，ZnO 2.45％，BaO4.37％，TiO2 0.17％，FeO30.19 percent, 9.11 percent ignition loss and the balance of impurities.
The dry particles of the marble ceramic tiles of examples 1 to 9 and comparative examples 1 to 2 were crushed with frit glaze and then sieved with a 120-230 mesh screen. The composite material comprises the following components in percentage by mass: SiO 22 51.79％，Al2O3 10.27％，CaO 11.57％，MgO 2.22％，K2O 5％，Na2O 1.24％，ZnO 7.88％，FeO3 0.15％，TiO20.08 percent of BaO, 1.69 percent of BaO, 8.02 percent of ignition loss and the balance of impurities; and crushing the dry particles by using fritted glaze, and screening by using a screen with 120-230 meshes, wherein the fineness screen residue is less than or equal to 0.02%.
The preparation method of the marble ceramic tiles of the embodiments 1 to 9 and the comparative examples 1 to 2 comprises the following steps:
(1) pressing by using a concave-convex die at the pressure of 4000-4500 t to obtain a ceramic tile blank;
(2) the overglaze is sprayed on the ceramic tile green body in a linear oil spraying way;
(3) printing patterns and colors on the surface of the ceramic tile blank in the step (2) in an ink-jet manner;
(4) printing the dry grain glaze on the surface of the ceramic tile in the step (3) by using a 60-mesh full-through net;
(5) and (5) firing the ceramic tile treated in the step (4) at a high temperature, wherein the firing procedure is as follows: firstly, the temperature is increased from room temperature to 1250 ℃ within 50min, the temperature is kept at 1250 ℃ for 30min, and finally, the temperature is reduced from 1250 ℃ to 400 ℃ within 8 min;
(6) and (5) edging the ceramic tile obtained in the step (5) to obtain the ceramic tile with low glossiness.
TABLE 1
Examples of effects
In the present effect example, the performance of the ceramic tiles of examples 1 to 9 and comparative examples 1 to 2 was tested, and the test results are shown in table 2.
And (3) testing the glossiness: according to the area of the ceramic tile, the ceramic tile is divided into 10 same areas on the average per square meter, the glossiness test is carried out under the direct strong light, the average value of the glossiness of all the areas is used as the glossiness of each ceramic tile, and after 1 whole tile is subjected to the regional glossiness test, the difference value between the maximum value and the minimum value of the measured glossiness data is the glossiness difference.
Wear resistance: according to the method for measuring the wear resistance of the glazed tile in the GB/T3810.7-2015 ceramic tile test method, the ceramic tiles of examples 1-9 and comparative examples 1-2 are detected by using a tile wear resistance detector.
TABLE 2
Finally, it should be noted that the above embodiments are only used for illustrating the technical solutions of the present invention and not for limiting the protection scope of the present invention, and although the present invention is described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions can be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention.
Claims (10)
1. A low-light marble ceramic tile with uniform luminosity is characterized by comprising a blank body and a glaze layer; the glaze layer is formed by superposing a glaze layer, an ink-jet printing layer and a dry particle glaze layer from bottom to top; the overglaze layer comprises the following components in percentage by mass: 98.68 to 99.34 percent of basic overglaze and 0.66 to 1.32 percent of molten aluminum; the ink-jet printing layer is used for printing corresponding patterns and colors on the green brick with the overglaze layer according to the requirement of the surface effect by an ink-jet printer; the dry particle glaze layer consists of the following components: printing oil, printing paste, drying particles and polishing glaze; the weight ratio of dry particles to glaze polishing in the dry particle glaze layer is as follows: and (3) dry granulation: and (1-6: 15-45) polishing.
2. The photometric homogeneous low light marble ceramic tile as claimed in claim 1, wherein the thickness of said overglaze layer is 0.2-0.3 mm; the thickness of the dry particle glaze layer is 0.1-0.2 mm.
3. The photometric homogeneous low light marble ceramic tile as set forth in claim 1, wherein the base overglaze comprises the following components in mass percent: SiO 22 48.33％，Al2O3 26.31％，CaO 6.43％，MgO 3.09％，K2O 1.77％，Na2O 3.22％，ZnO 0.06％，FeO3 0.2％，TiO2 0.1％，BaO 3.69％，P2O5 0.04％，ZrO20.02 percent, 6.71 percent of ignition loss and the balance of impurities.
4. The photometric homogeneous low light marble ceramic tile as set forth in claim 1, wherein the molten aluminum comprises the following components in mass percent: 51.59 percent of alumina dry powder, 0.39 percent of sodium tripolyphosphate, 0.31 percent of sodium carboxymethyl cellulose and 47.72 percent of water.
5. The low-light marble ceramic tile with uniform luminosity according to claim 1, wherein the molten aluminum is ball-milled for 18 hours, the fineness is 325 meshes, the screen residue is less than or equal to 0.4%, and the specific gravity is 1.55-1.58 g/ml; the basic overglaze is ball-milled for 12 hours, the fineness is 325 meshes, the screen residue is less than or equal to 0.5 percent, and the specific gravity is 1.79-1.83 g/ml.
6. The photometric homogeneous low light marble ceramic tile as claimed in claim 1, wherein the glaze consists of the following components in mass percent: SiO 22 42.42％，Al2O3 21.56％，CaO 7.55％，MgO 5.55％，K2O 2.19％，Na2O 3.64％，ZnO 2.45％，BaO 4.37％，TiO2 0.17％，FeO30.19 percent, 9.11 percent of ignition loss and the balance of impurities; and the glaze polishing is performed with ball milling for 10 hours, the fineness is 325 meshes, the screen residue is less than or equal to 0.05 percent, and the specific gravity is 1.56-1.60 g/ml.
7. The photometric homogeneous low light marble ceramic tile as defined in claim 1 wherein the dry pellets are comprised of the following components in mass percent: SiO 22 51.79％，Al2O3 10.27％，CaO 11.57％，MgO 2.22％，K2O 5％，Na2O 1.24％，ZnO 7.88％，FeO3 0.15％，TiO20.08 percent, 1.69 percent of BaO, 8.02 percent of ignition loss and the balance of impurities; and crushing the dry particles by using fritted glaze, and screening by using a screen with 120-230 meshes, wherein the fineness screen residue is less than or equal to 0.02%.
8. The method for preparing a photometric homogeneous low light marble ceramic tile according to any one of claims 1 to 7, comprising the steps of:
(1) pressing a ceramic tile green body by using a concave-convex die;
(2) the overglaze is sprayed on the ceramic tile green body in a linear oil spraying way;
(3) printing patterns and colors on the surface of the ceramic tile blank in the step (2) in an ink-jet manner;
(4) printing dry grain glaze on the surface of the ceramic tile in the step (3);
(5) firing the ceramic tile treated in the step (4);
(6) and (5) edging the ceramic tile obtained in the step (5) to obtain the marble ceramic tile.
9. The method for the preparation of photometric homogeneous low light marble ceramic tile according to claim 8 wherein the procedure of firing in step (4) is: the temperature is firstly increased from room temperature to 1250 ℃ within 50min, and is kept at 1250 ℃ for 30min, and finally is reduced from 1250 ℃ to 400 ℃ within 8 min.
10. The method for preparing a low-light marble ceramic tile with uniform luminosity according to claim 8, wherein the glazing specific gravity of the overglaze in the step (2) is 1.68-1.70 g/ml, the flow rate is 18-20 s, and the glazing amount is 361-388 g/m2(ii) a The glazing specific gravity of the dry granular glaze in the step (4) is 1.56-1.58 g/ml, the flow rate is 6-7 min, and the glazing amount is 185.2-198.1 g/m2。
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