CN114275771B - Scanning device for laser-induced graphene - Google Patents

Scanning device for laser-induced graphene Download PDF

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CN114275771B
CN114275771B CN202111511672.5A CN202111511672A CN114275771B CN 114275771 B CN114275771 B CN 114275771B CN 202111511672 A CN202111511672 A CN 202111511672A CN 114275771 B CN114275771 B CN 114275771B
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pair
laser
scanning
outer frame
guide roller
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CN114275771A (en
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周素超
陈韵吉
孙宝国
杨玉娜
陈彦鹏
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Alkene New Material Beijing Technology Co ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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Abstract

The invention discloses a scanning device for laser-induced graphene, which comprises a foil conveying structure and a laser scanning structure, wherein the laser scanning structure is arranged at the upper part of the foil conveying structure; the scanning device for the laser-induced graphene has the beneficial effects that the scanning device for the laser-induced graphene is simple in structure, the energy density of the laser focal spot, the laser scanning speed and the moving speed of the substrate material with the surface coated with the carbon source are controlled, so that the porous graphene can be formed on the surface of the substrate material by the carbon source, the laser scanning position can be calibrated through the arrangement of suitability, the structure of ensuring the flatness of the scanning position of the guide roller is ensured, the operation efficiency is improved, and the device is suitable for batch production.

Description

Scanning device for laser-induced graphene
Technical Field
The invention relates to the technical field of graphene processing equipment, in particular to a scanning device for laser-induced graphene.
Background
Compared with graphene monocrystal, the graphene with the three-dimensional porous structure has unique physical and chemical properties and has huge potential application in the fields of biology, materials, energy sources, information and the like. In recent years, therefore, the potential application of porous graphene in the fields of biology, materials, energy sources, information and the like and the preparation technology thereof are receiving a great deal of attention. Porous graphene can be fabricated in situ on a substrate surface by chemical vapor deposition and plasma enhanced chemical vapor deposition. However, the high temperature conditions required for the process either limit the substrate type or impair the mechanical properties of the substrate. Methods of treating functionalized graphene solutions are also widely used, but the graphene prepared by such methods requires additional coating processes.
The laser can be used for inducing photochemical and photo-thermal reactions, can be used for carrying out local processing in the atmospheric environment, has the characteristics of quick heating and quick cooling, and is an ideal heat source. In 2014, researchers have proposed a laser induced graphene technique (LIG). LIG has equally excellent electrical conductivity, thermal conductivity, chemical stability, and ultra-high surface area compared to conventional two-dimensional graphene. However, the existing laser generating device cannot directly act on the induction production of graphene, and the existing laser generating device lacks corresponding production equipment, and the existing single-point laser irradiation has poor continuity, so that a graphene laser induction scanning device suitable for LIG technology application is needed.
Disclosure of Invention
The invention aims to solve the problems, designs a scanning device for laser-induced graphene, and solves the problems of the prior art.
The technical scheme of the invention for achieving the purpose is as follows: the scanning device for the laser-induced graphene comprises a foil conveying structure and a laser scanning structure, wherein the laser scanning structure is arranged at the upper part of the foil conveying structure;
the foil conveying structure comprises an unreeling machine, a guide roller and a reeling machine, wherein the unreeling machine, the guide roller and the reeling machine are sequentially arranged in parallel in the axis direction, and the foil conveying structure is suitable for reeling and supporting a foil coated with a carbon source;
the laser scanning structure comprises a laser and a scanning focusing head, wherein the laser is connected to the scanning focusing head, and the scanning focusing head is arranged above the guide roller and is suitable for scanning coiled materials passing through the guide roller.
A scanning device for laser-induced graphene, further comprising: the device comprises an outer frame, a laser fine adjustment and calibration mechanism and a coiled material tensioning and feeding mechanism;
the unreeling machine, the guide roller and the reeling machine are sequentially arranged on the outer frame, the laser and the scanning focusing head are arranged on the outer frame and are positioned at the upper part of the guide roller, a laser fine adjustment and calibration mechanism is arranged between the scanning focusing head and the outer frame, a pair of coiled material tensioning and feeding mechanisms are symmetrically arranged on two sides of the guide roller, and a control power mechanism is arranged on the outer side of the outer frame;
the coiled material tensioning and feeding mechanism comprises: the device comprises a pair of supporting seats, a pair of through pipes, a bottom roll shaft, a pair of inserted bars, a pair of support plates, a pair of tension springs, a pair of pressing rollers, a pair of sliding grooves, a pair of adjusting seats and a pair of connecting bolts;
the guide roller is characterized in that a pair of symmetrical supporting seats are respectively arranged on two sides of the guide roller and are arranged on the outer frame, a pair of vertical through pipes are arranged on the supporting seats, a pair of bottom roller shafts are connected between the supporting seats, a pair of inserting rods are inserted into the through pipes, a pair of support plates are arranged at the top ends of the inserting rods, a pair of tensioning springs are embedded into the through pipes and are connected with the inserting rods, a pair of symmetrical pressing rollers are arranged on one side of each support plate, the pressing rollers are symmetrically arranged at two ends of the bottom roller shafts, a pair of sliding grooves are symmetrically arranged on two sides of the outer frame, the supporting seats are arranged on the pair of sliding grooves, a pair of adjusting seats are arranged on the sliding grooves, and a pair of connecting bolts are arranged on the adjusting seats and are connected with the supporting seats.
The laser fine adjustment calibration mechanism comprises: the device comprises an adjusting slide block, a pair of adjusting blocks, a pair of movable bearings, a pair of jacking bolts, an adjusting screw rod and a rotating knob;
the scanning focusing head is provided with an adjusting slide block, a pair of adjusting blocks are movably mounted on the outer frame, a pair of movable bearings are arranged in the adjusting blocks, a pair of jacking bolts are arranged on the adjusting blocks and connected with the sliding bearings, a pair of adjusting screw rods are embedded in the movable bearings and connected with the adjusting slide block in a threaded mode, and rotating knobs are arranged at the end portions of the adjusting screw rods.
The control power mechanism includes: a first power motor, a second power motor, and a pair of linear speed sensors;
the outer side of the outer frame is provided with a first power motor which is connected with the shaft end of the unreeling machine, the shaft end of the outer side of the reeling machine is connected with a second power motor, and the driving ends of the first power motor and the second power motor are provided with a pair of linear speed sensors.
The rectangular shells with the pair of adjusting blocks in the cavity structure are fixedly and symmetrically arranged on two sides of the outer frame.
The guide roller surface material of the conveying device is rubber and other high friction coefficient materials.
The sliding grooves are through holes with long round structures, one sides of the supporting seats are provided with a pair of limiting sliding blocks which are assembled in the sliding grooves, and the connecting bolts are connected with the limiting sliding blocks.
The bottom ends of the pair of inserted bars are provided with a pair of limiting plates, and the top ends of the pair of sleeves are provided with a pair of limiting ring grooves.
The laser generated by the laser is modulated pulse laser, and the laser wavelength is 10.6 mu m.
The scanning width of the scanning focusing head is larger than the width of the foil material coated with the carbon source.
The scanning device for the laser-induced graphene, which is manufactured by the technical scheme of the invention, has a simple structure, can enable the surface carbon source of the substrate material to form porous graphene by controlling the energy density of the laser focal spot, the laser scanning speed and the moving speed of the substrate material with the surface coated with the carbon source, can calibrate the laser scanning position and ensure the structure of the flatness of the scanning position of the guide roller by setting the suitability, improves the operation efficiency, and is suitable for batch production.
Drawings
Fig. 1 is a schematic diagram of a front view structure of a scanning device for laser-induced graphene according to the present invention.
Fig. 2 is a schematic side view of a scanning device for laser-induced graphene according to the present invention.
Fig. 3 is a schematic diagram of a partial side-view cross-sectional structure of a scanning device for laser-induced graphene according to the present invention.
Fig. 4 is a schematic diagram of a partial cross-sectional structure of a scanning device for laser-induced graphene according to the present invention.
Fig. 5 is a schematic diagram of a partial enlarged structure of a scanning device for laser-induced graphene according to the present invention.
In the figure: 1. an outer frame; 2. a foil conveying structure; 3. a laser scanning structure; 4. a laser fine adjustment calibration mechanism; 5. a coiled material tensioning and feeding mechanism; 6. controlling a power mechanism; 201. an unreeling machine; 202. a guide roller; 203. a winding machine; 301. a laser; 302. scanning a focusing head; 401. an adjusting slide block; 402. an adjusting block; 403. a movable bearing; 404. jacking a bolt; 405. adjusting a screw rod; 406. rotating a knob; 501. a support base; 502. a through pipe; 503. a bottom roller shaft; 504. a rod; 505. a support plate; 506. tensioning the spring; 507. pressing down the roller; 508. a sliding groove; 509. an adjusting seat; 510. a connecting bolt; 511. a limiting plate; 601. a first power motor; 602. a second power motor; 603. a linear velocity sensor.
Detailed Description
The present invention will be described in detail with reference to the accompanying drawings, as shown in fig. 1 to 5.
All electric components in the scheme are connected with an adaptive power supply through wires by a person skilled in the art, and an appropriate controller is selected according to actual conditions so as to meet control requirements, specific connection and control sequences, and the electric connection is completed by referring to the following working principles in the working sequence among the electric components, wherein the detailed connection means are known in the art, and the following main description of the working principles and processes is omitted from the description of electric control.
Examples: as can be seen from fig. 1-5 of the specification, the present application is a scanning device for laser-induced graphene, which comprises a foil conveying structure 2 and a laser scanning structure 3, wherein the laser scanning structure 3 is mounted on the upper portion of the foil conveying structure 2, and in a specific implementation process, the foil conveying structure 2 transmits a material under the laser scanning structure 3, and then the laser scanning structure 3 is used for scanning a foil;
as can be seen from fig. 1 to 5 of the specification, the foil conveying structure 2 includes an unreeling machine 201, a guide roller 202 and a reeling machine 203, the unreeling machine 201, the guide roller 202 and the reeling machine 203 are sequentially arranged in parallel in the axis direction, and are suitable for reeling and supporting a foil coated with a carbon source, the foil is wound on the unreeling machine 201, and the foil can uniformly pass through the guide roller 202 through the synchronous linear velocity motion of the unreeling machine 201 and the reeling machine 203, and then is scanned by utilizing a laser scanning structure 3 above the guide roller 202;
as can be seen from fig. 1 to 5 of the specification, the laser scanning structure 3 includes a laser 301 and a scanning focusing head 302, the laser 301 is connected to the scanning focusing head 302, the scanning focusing head 302 is installed above the guide roller 202, and is suitable for scanning a coil passing through the guide roller 202, the laser 301 provides a laser source for the scanning focusing head 302, the scanner scans along a direction perpendicular to a movement direction of a foil, a laser focal spot focused on a surface of the foil wound around the surface of the guide roller 202 forms a scanning belt, a decomposition and synthesis reaction occurs under a laser thermal effect of a carbon source in the scanning belt, a porous graphene layer is generated in situ, the surface of the guide roller 202 of the conveying device is made of a material with a high friction coefficient such as rubber, the foil is kept flat on the surface of the guide roller 202 under the action of tension and high friction force, the in-situ porous graphene foil with a flat surface can be finally obtained, the laser generated by the laser 301 is modulated pulse laser, the laser wavelength is 10.6 μm, and the scanning width of the laser scanner is greater than the width of the foil coated with the carbon source.
As can be seen from fig. 1 to 5 of the specification, a scanning device for laser-induced graphene further comprises: an outer frame 1, a laser fine adjustment calibration mechanism 4 and a coiled material tensioning and feeding mechanism 5;
the unreeling machine 201, the guide roller 202 and the reeling machine 203 are sequentially arranged on the outer frame 1, the laser 301 and the scanning focusing head 302 are arranged on the outer frame 1 and are positioned at the upper part of the guide roller 202, a laser fine adjustment calibration mechanism 4 is arranged between the scanning focusing head 302 and the outer frame 1, a pair of coiled material tensioning and feeding mechanisms 5 are symmetrically arranged on two sides of the guide roller 202, and a control power mechanism 6 is arranged on the outer side of the outer frame 1;
in the specific implementation process, the outer frame 1 is used as an external support of the unreeling machine 201, the reeling machine 203 and the guide roller 202, the laser 301 and the scanner are also arranged on the upper part of the outer frame 1, a laser fine adjustment and calibration mechanism 4 is arranged between the scanning focusing head 302 and the outer frame 1, the position of the scanning head can be finely adjusted for calibration, a pair of coiled material tensioning and feeding mechanisms 5 which are symmetrically arranged on two sides of the guide roller 202 can be used for adjusting the tensioning and the laying of the foil on the guide roller 202, and the linear speed balance between the unreeling machine 201 and the reeling machine 203 can be ensured through a control power mechanism 6 of the outer frame 1;
as can be seen from fig. 1 to 5 of the specification, the coil tensioning and feeding mechanism 5 comprises: a pair of supporting seats 501, a pair of through pipes 502, a bottom roller shaft 503, a pair of inserting rods 504, a pair of supporting plates 505, a pair of tension springs 506, a pair of pressing rollers 507, a pair of sliding grooves 508, a pair of adjusting seats 509 and a pair of connecting bolts 510, the connection and the positional relationship of which are as follows;
a pair of symmetrical supporting seats 501 are respectively arranged at two sides of the guide roller 202 and are installed on the outer frame 1, a pair of vertical through pipes 502 are arranged on the pair of supporting seats 501, a bottom roller shaft 503 is connected between the pair of supporting seats 501, a pair of inserting rods 504 are inserted into the pair of through pipes 502, a pair of support plates 505 are arranged at the top ends of the pair of inserting rods 504, a pair of tensioning springs 506 are embedded into the pair of through pipes 502 and are connected with the pair of inserting rods 504, a pair of symmetrical pressing rollers 507 are arranged at one side of the pair of support plates 505, the pair of pressing rollers 507 are symmetrically arranged at two ends of the bottom roller shaft 503, a pair of sliding grooves 508 are symmetrically arranged at two sides of the outer frame 1, the pair of supporting seats 501 are installed on the pair of sliding grooves 508, a pair of adjusting seats 509 are arranged on the pair of adjusting seats 509, and a pair of connecting bolts 510 are arranged on the pair of adjusting seats 509 and are connected with the pair of supporting seats 501;
in a specific implementation process, a pair of supporting seats 501 on two sides of the guide roller 202 are symmetrically arranged, the bottom roller 503 can be supported, through adjusting a pair of connecting bolts 510, the adjusting seats 509 and the connecting bolts 510 can move in a threaded manner, the adjusting seats 509 drive the supporting seats 501 to slide in the sliding grooves 508, the pair of sliding grooves 508 are through holes with an oblong structure, a pair of limit sliding blocks are arranged on one side of the pair of supporting seats 501 and are assembled in the pair of sliding grooves 508, the pair of connecting bolts 510 are connected with the pair of limit sliding blocks, the upper and lower positions of the bottom roller 503 can be changed, the bottom roller 503 is attached to the bottom surface of a packaging material, a pair of limit plates 511 are arranged at the bottom ends of the pair of inserting rods 504, a pair of limit ring grooves are arranged at the top ends of the pair of sleeves, the pair of inserting rods 504 can be pulled to slide up and down by using a pair of tension springs 506, the pair of inserting rods 504 can be pulled to be extruded on the top surface of a foil by a pair of lower pressure rollers 507, and the foil is tensioned by using a pair of coil tensioning mechanisms 5 which are symmetrically arranged.
As can be seen from fig. 1 to 5 of the specification, the laser trimming calibration mechanism 4 includes: the connection relationship and the position relationship of the adjusting slide block 401, the pair of adjusting blocks 402, the pair of movable bearings 403, the pair of jacking bolts 404, the adjusting screw rod 405 and the rotating knob 406 are as follows;
an adjusting slide block 401 is arranged on the scanning focusing head 302, a pair of adjusting blocks 402 are movably arranged on the outer frame 1, a pair of movable bearings 403 are arranged in the pair of adjusting blocks 402, a pair of jacking bolts 404 are arranged on the pair of adjusting blocks 402 and connected with a pair of sliding bearings, an adjusting screw rod 405 is embedded and connected in the pair of movable bearings 403, the adjusting screw rod 405 is in threaded connection with the adjusting slide block 401, and a rotating knob 406 is arranged at the end part of the adjusting screw rod 405;
in a specific implementation process, the adjusting screw rod 405 and the adjusting slide block 401 can be driven to move in a threaded manner through the adjusting rotating knob 406, so that the transverse position of the scanning focusing head 302 is adjusted, a sliding groove is formed in the top surface of the adjusting slide block 401 and matched with a sliding rod on the outer frame 1, two ends of the adjusting screw rod 405 are respectively fixed through a pair of movable bearings 403, the adjusting screw rod 405 is conveniently rotated, a pair of jacking bolts 404 are arranged on the pair of adjusting blocks 402 and connected with the sliding bearings, the jacking bolts 404 can be rotated to drive the adjusting slide block 401 to slide up and down, and therefore the upper position and the lower position of the scanning focusing head 302 are adjusted, and the pair of adjusting blocks 402 are fixedly and symmetrically arranged on two sides of the outer frame 1 in a rectangular shell with a cavity structure.
As can be seen from fig. 1 to 5 of the specification, the control power mechanism 6 includes: a first power motor 601, a second power motor 602, and a pair of linear velocity sensors 603, the connection and positional relationship of which are as follows;
the outer side of the outer frame 1 is provided with a first power motor 601 which is connected with the shaft end of the unreeling machine 201, the shaft end of the outer side of the reeling machine 203 is connected with a second power motor 602, and the driving ends of the first power motor 601 and the second power motor 602 are provided with a pair of linear speed sensors 603;
in a specific implementation process, the first power motor 601 on one side of the outer frame 1 drives the unreeling machine 201 to move, the second power motor 602 drives the reeling machine 203 to move, and the reeling machine 203 and the unreeling machine 201 detect the linear speeds of the first power motor 601 and the second power motor 602 through the linear speed sensor 603 respectively, so that the linear speeds of the first power motor 601 and the second power motor 602 are ensured to be synchronous.
In summary, the scanning device for laser-induced graphene has a simple structure, and can enable the surface carbon source of the substrate material to form porous graphene by controlling the energy density of the laser focal spot, the laser scanning speed and the moving speed of the substrate material with the surface coated with the carbon source, and the arrangement of suitability can calibrate the laser scanning position and ensure the structure of the evenness of the scanning position of the guide roller 202, thereby improving the working efficiency and being suitable for mass production.
The above technical solution only represents the preferred technical solution of the present invention, and some changes that may be made by those skilled in the art to some parts of the technical solution represent the principles of the present invention, and the technical solution falls within the scope of the present invention.

Claims (8)

1. A scanning device for laser-induced graphene, comprising a foil conveying structure (2) and a laser scanning structure (3), characterized in that the laser scanning structure (3) is mounted on the upper part of the foil conveying structure (2);
the foil conveying structure (2) comprises an unreeling machine (201), a guide roller (202) and a reeling machine (203), wherein the unreeling machine (201), the guide roller (202) and the reeling machine (203) are sequentially arranged in parallel in the axis direction, and the foil conveying structure is suitable for reeling and supporting a foil coated with a carbon source;
the laser scanning structure (3) comprises a laser (301) and a scanning focusing head (302), wherein the laser (301) is connected to the scanning focusing head (302), and the scanning focusing head (302) is arranged above the guide roller (202) and is suitable for scanning coiled materials passing through the guide roller (202);
further comprises: an outer frame (1), a laser fine adjustment and calibration mechanism (4) and a coiled material tensioning and feeding mechanism (5);
the unreeling machine (201), the guide roller (202) and the reeling machine (203) are sequentially arranged on the outer frame (1), the laser (301) and the scanning focusing head (302) are arranged on the outer frame (1) and are positioned at the upper part of the guide roller (202), a laser fine adjustment calibrating mechanism (4) is arranged between the scanning focusing head (302) and the outer frame (1), a pair of coiled material tensioning feeding mechanisms (5) are symmetrically arranged on two sides of the guide roller (202), and a control power mechanism (6) is arranged on the outer side of the outer frame (1);
the coiled material tensioning and feeding mechanism (5) comprises: a pair of supporting seats (501), a pair of through pipes (502), a bottom roll shaft (503), a pair of inserting rods (504), a pair of supporting plates (505), a pair of tensioning springs (506), a pair of pressing rollers (507), a pair of sliding grooves (508), a pair of adjusting seats (509) and a pair of connecting bolts (510);
the guide roller (202) both sides are equipped with a pair of symmetrical supporting seat (501) respectively and install on outer frame (1), a pair of be equipped with a pair of vertical siphunculus (502) on supporting seat (501), a pair of be connected with bottom roller (503) between supporting seat (501), a pair of inserted bar (504) are equipped with in siphunculus (502), a pair of the top of inserted bar (504) is equipped with a pair of extension board (505), a pair of inserted bar (502) are embedded to be equipped with a pair of tensioning spring (506) and are connected with a pair of inserted bar (504), a pair of one side of extension board (505) is equipped with a pair of symmetrical push down gyro wheel (507), a pair of push down gyro wheel (507) symmetrical arrangement is in the both ends of bottom roller (503), a pair of sliding groove (508) have been seted up to outer frame (1) both sides symmetry, a pair of supporting seat (501) are installed on a pair of sliding groove (508), a pair of be equipped with on sliding groove (508), a pair of adjusting seat (509) are equipped with on the sliding groove (508) a pair of adjusting seat (509) are equipped with a pair of connecting bolt (510).
2. Scanning device for laser-induced graphene according to claim 1, characterized in that the laser trimming calibration mechanism (4) comprises: an adjusting slide block (401), a pair of adjusting blocks (402), a pair of movable bearings (403), a pair of jacking bolts (404), an adjusting screw rod (405) and a rotating knob (406);
be equipped with adjusting slide (401) on scanning focusing head (302), movable mounting has a pair of regulating block (402) on outer frame (1), a pair of be equipped with a pair of movable bearing (403) in regulating block (402), a pair of be equipped with a pair of jack-up bolt (404) on regulating block (402) and be connected with a pair of slide bearing, a pair of movable bearing (403) are embedded to be connected with accommodate the lead screw (405), accommodate the lead screw (405) and accommodate the slider (401) threaded connection, the tip of accommodate the lead screw (405) is equipped with rotation knob (406).
3. Scanning device for laser-induced graphene according to claim 1, characterized in that the control power mechanism (6) comprises: a first power motor (601), a second power motor (602), and a pair of linear speed sensors (603);
the outer frame (1) outside is equipped with first power motor (601) and is connected with the axle head of unreeling machine (201), the outside axle head of rolling machine (203) is connected with second power motor (602), be equipped with a pair of linear velocity sensor (603) on the driving end of first power motor (601) and second power motor (602).
4. The scanning device for laser-induced graphene according to claim 2, wherein a pair of the adjusting blocks (402) are fixedly and symmetrically arranged on two sides of the outer frame (1) in a rectangular shell with a cavity structure.
5. The scanning device for laser-induced graphene according to claim 1, wherein the surface material of the guide roller (202) of the foil conveying structure (2) is a rubber high friction coefficient material.
6. The scanning device for laser-induced graphene according to claim 2, wherein the pair of sliding grooves (508) are through holes with an oblong structure, a pair of limit sliders are arranged on one side of the pair of supporting seats (501) and are assembled in the pair of sliding grooves (508), and the pair of connecting bolts (510) are connected with the pair of limit sliders.
7. A scanning device for laser-induced graphene according to claim 1, characterized in that the laser light generated by the laser (301) is modulated pulsed laser light with a laser wavelength of 10.6 μm.
8. A scanning device for laser-induced graphene according to claim 1, wherein the scanning focusing head (302) has a scanning width that is greater than the width of the carbon source coated foil.
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Inventor after: Zhou Suchao

Inventor after: Sun Baoguo

Inventor after: Yang Yuna

Inventor after: Chen Yanpeng

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