CN114256147A - Method for manufacturing semiconductor structure - Google Patents

Method for manufacturing semiconductor structure Download PDF

Info

Publication number
CN114256147A
CN114256147A CN202011003762.9A CN202011003762A CN114256147A CN 114256147 A CN114256147 A CN 114256147A CN 202011003762 A CN202011003762 A CN 202011003762A CN 114256147 A CN114256147 A CN 114256147A
Authority
CN
China
Prior art keywords
catalytic metal
nanowire
doped
forming
doped amorphous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202011003762.9A
Other languages
Chinese (zh)
Other versions
CN114256147B (en
Inventor
余林蔚
孙莹
王军转
刘俊彦
陈英杰
刘至哲
吴欣凯
刘云飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honor Device Co Ltd
Original Assignee
Honor Device Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Honor Device Co Ltd filed Critical Honor Device Co Ltd
Priority to CN202011003762.9A priority Critical patent/CN114256147B/en
Publication of CN114256147A publication Critical patent/CN114256147A/en
Application granted granted Critical
Publication of CN114256147B publication Critical patent/CN114256147B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
    • H01L21/82Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/0657Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body
    • H01L29/0665Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body the shape of the body defining a nanostructure
    • H01L29/0669Nanowires or nanotubes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Nanotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Computer Hardware Design (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Vapour Deposition (AREA)
  • Catalysts (AREA)

Abstract

The embodiment of the application provides a preparation method of a semiconductor structure, relates to the technical field of microelectronics, and can form a P-type heavily doped nanowire or an N-type doped nanowire under a process environment at a lower temperature, so that the cost is lower. The preparation method of the semiconductor structure comprises the following steps: forming a base material layer, and forming at least one groove on the surface of the base material layer; forming a catalytic metal in the trench; depositing a doped amorphous precursor on the surface of the substrate layer at a position including the trench, the doped amorphous precursor contacting the catalytic metal; and annealing the substrate layer formed with the catalytic metal and the doped amorphous precursor, so that the catalytic metal moves along the corresponding groove and absorbs the doped amorphous precursor to form the doped nanowire along the way.

Description

Method for manufacturing semiconductor structure
Technical Field
The application relates to the technical field of microelectronics, in particular to a semiconductor structure preparation method.
Background
With the development of microelectronic technology, crystalline semiconductor nanowires can be stacked and arranged due to their extremely low defect states and good charge transport capabilities, and thus become the mainstream choice of semiconductor technology. However, the current methods for doping nanowires, such as ion implantation, molecular diffusion, etc., all require high-temperature annealing (>600 ℃) to activate the doping atoms, which is costly.
Disclosure of Invention
The technical scheme provides a semiconductor structure preparation method, which can form a P-type heavily doped nanowire or an N-type doped nanowire under a low-temperature process environment and is low in cost.
In a first aspect, a technical solution of the present application provides a method for manufacturing a semiconductor structure, including: forming a base material layer, and forming at least one groove on the surface of the base material layer; forming a catalytic metal in the trench; depositing a doped amorphous precursor on the surface of the substrate layer at a position including the trench, the doped amorphous precursor contacting the catalytic metal; and annealing the substrate layer formed with the catalytic metal and the doped amorphous precursor, so that the catalytic metal moves along the corresponding groove and absorbs the doped amorphous precursor to form the doped nanowire along the way.
In one possible embodiment, the process of forming the substrate layer and forming the at least one trench on the surface of the substrate layer includes: forming a substrate layer, and forming at least one groove with the depth of d and the width of w on the surface of the substrate layer, wherein d is more than or equal to 50nm and less than or equal to 1 mu m, and w is more than or equal to 1 mu m and less than or equal to 100 mu m.
In one possible embodiment, the process of forming the catalytic metal in the trench includes: depositing catalytic metal with the thickness h1 in the groove, wherein h is more than or equal to 5nm and less than or equal to 200 nm.
In one possible embodiment, after forming the catalytic metal in each trench, the method further includes: and (3) treating the catalytic metal by using plasma in an environment with the temperature above the melting point of the catalytic metal, so that an oxide layer on the surface of the catalytic metal is removed, and the catalytic metal is converted into the catalytic metal in a discrete liquid state.
In one possible embodiment, the process of depositing the doped amorphous precursor on the surface of the substrate layer at a location including the trench comprises: and under the environment of the temperature below the melting point of the catalytic metal, depositing a doped amorphous precursor with the thickness of h1 at the position including the groove on the surface of the substrate layer, wherein h2 is more than or equal to 10nm and less than or equal to 200 nm.
In one possible embodiment, the annealing process of the substrate layer formed with the catalytic metal and the doped amorphous precursor, so that the catalytic metal moves along the corresponding trench and absorbs the doped amorphous precursor, and the doped nanowires are formed along the substrate layer, includes:
and annealing the substrate layer on which the catalytic metal and the doped amorphous precursor are formed at a temperature above the melting point of the catalytic metal and in a non-oxygen environment, so that the catalytic metal moves along the corresponding groove and absorbs the doped amorphous precursor to form the doped nanowire along the way.
In one possible embodiment, the catalytic metal is an alloy of one or more of the following metals: indium, tin, bismuth, gallium, and aluminum.
In one possible embodiment, the doped amorphous precursor is a heterogeneous stack of one or more of the following: doped amorphous silicon, doped amorphous germanium and doped amorphous carbon.
In one possible embodiment, the doping element in the doped amorphous precursor is phosphorus or boron.
In one possible embodiment, the doped nanowire is an N-type doped nanowire or a P-type heavily doped nanowire.
In one possible embodiment, the nanowire includes two end portions and an intermediate portion between the two end portions, and after forming the doped nanowire, the method further includes:
forming a source metal covering one end portion of the nanowire, the source metal being connected to one end portion of the nanowire, forming a drain metal covering the other end portion of the nanowire, the drain metal being connected to the other end portion of the nanowire;
forming a gate dielectric layer covering the middle part of the nanowire;
after the gate dielectric layer is formed, the method further comprises the following steps: and forming a gate metal covering the middle part of the nanowire, wherein a gate dielectric layer is positioned between the nanowire and the gate metal.
The preparation method can directly grow the N-type doped or P-type heavily doped nanowire without doping process, and the process temperature in the nanowire growth process is lower and can not exceed 600 ℃, so that the compatibility is higher, the cost is low, in addition, because the nanowire grows along the groove, the growth direction of the nanowire can be controlled in the whole process, the appearance of the nanowire is controlled, and the doping atoms in the nanowire are uniformly distributed, thus the preparation method is suitable for high-performance semiconductor devices.
Drawings
FIG. 1 is a flow chart of a method for fabricating a semiconductor structure according to an embodiment of the present application;
fig. 2a is a schematic structural diagram of a semiconductor structure after a substrate layer is formed in a method for manufacturing the semiconductor structure according to an embodiment of the present disclosure;
FIG. 2b is a schematic diagram of the structure of FIG. 2a after forming a trench;
FIG. 2c is a schematic diagram of the structure of FIG. 2b after deposition of a catalytic metal;
FIG. 2d is a schematic diagram of the structure of FIG. 2c after plasma treatment;
FIG. 2e is a schematic diagram of the structure of FIG. 2d after deposition of a doped amorphous precursor;
FIG. 2f is a schematic diagram of the structure of FIG. 2e after annealing to form doped nanowires;
FIG. 3 is a schematic cross-sectional view of each of FIGS. 2a to 2 f;
FIG. 4 is a schematic structural diagram of another trench in the embodiment of the present application;
FIG. 5 is a flow chart of another method of fabricating a semiconductor structure according to an embodiment of the present application;
FIG. 6a is a schematic diagram of the structure of FIG. 2f after source and drain metal deposition;
FIG. 6b is a schematic diagram illustrating the structure of FIG. 6a after a gate dielectric layer is deposited thereon;
fig. 6c is a schematic structural diagram of the structure in fig. 6b after gate metal deposition.
Detailed Description
The terminology used in the description of the embodiments section of the present application is for the purpose of describing particular embodiments of the present application only and is not intended to be limiting of the present application.
Before describing the embodiments of the present application, a description will be given of a problem finding process of the related art. In the process of doping the nanowire to form the N-type and P-type structures, the doping process can be performed at a high temperature, but for flexible electronic products, most of the adopted substrates are Polyimide (PI) materials, the maximum temperature which can be borne by the PI materials is about 400 ℃, and the temperature required by the current doping process exceeds 600 ℃, so that the compatibility of the method for forming the doped nanowire through the doping process is poor. Another method for obtaining doped nanowires is to directly grow doped nanowires, but the doped nanowires are directly grown by Vapor-liquid-solid (VLS) growth, which, on one hand, is difficult to control the growth direction of the nanowires, and on the other hand, may generate an amorphous layer on the sidewalls of the nanowires, affecting the quality of the nanowires. In addition, only P-type lightly doped nanowires can be obtained through other growth modes, and P-type heavily doped nanowires or N-type doped nanowires cannot be obtained through growth. In order to solve the above problems, the inventors provide the technical solutions of the embodiments of the present application, and the technical solutions of the embodiments of the present application are explained below.
An embodiment of the present application provides a method for manufacturing a semiconductor structure, as shown in fig. 1, fig. 2a to fig. 2f, and fig. 3, the method including:
step 101, forming a substrate layer 1, and forming at least one groove 11 on the surface of the substrate layer 1;
the trench 11 may be formed on the surface of the substrate layer 1 by photolithography and etching.
Step 102, forming a catalytic metal 2 In the trench 11, wherein the catalytic metal 2 may be indium In, for example;
103, depositing a doped amorphous precursor 3 at a position including the groove 11 on the surface of the substrate layer 1, wherein the doped amorphous precursor 3 contacts the catalytic metal 2;
the doped amorphous precursor 3 in the embodiment of the present application refers to an amorphous precursor 3 with a doping concentration different from 0. The doped amorphous precursor 3 may be, for example, amorphous silicon doped with phosphorus or boron, the doped amorphous precursor 3 at least covers the trench 11 and the catalytic metal 2 in the trench 11, for example, a whole layer of the doped amorphous precursor 3 may be formed on the surface of the substrate layer 1, and it should be noted that, in the embodiment of the present application, the order of the step 102 and the step 103 is not limited, for example, the catalytic metal 2 may be deposited first, and then the doped amorphous precursor 3 may be deposited; it is also possible to deposit the doped amorphous precursor 3 first and then the catalytic metal 2 as long as the catalytic metal 2 contacts the doped amorphous precursor 3 in the trench 11.
Step 104, annealing the substrate layer 1 on which the catalytic metal 2 and the doped amorphous precursor 3 are formed, so that the catalytic metal 2 moves along the corresponding trench 11 and absorbs the doped amorphous precursor 3, thereby forming the doped nanowire 4 along the way.
The annealing process in step 104 may be performed in a non-oxygen environment, and the annealing temperature is above the melting point of the catalytic metal 2, for example, 300 ℃, at which time the catalytic metal 2 droplet melts and absorbs the nearby doped amorphous precursor 3, and when the silicon atom concentration reaches a supersaturated concentration, the doped nanowire 4 is precipitated at the rear end of the catalytic metal 2 droplet, and the doped nanowire 4 grows along the trench 11. It should be noted that the cross-sectional views of fig. 2a to 2e in fig. 3 are schematic cross-sectional structures along AA ', and the cross-sectional view of fig. 2f in fig. 3 is a schematic cross-sectional structure along BB'. Wherein the doping concentration and type of the nanowire 4 are related to the doping concentration and type of the amorphous precursor, for example, if the N-type doped amorphous precursor 3 is used, the N-type doped nanowire 4 can be grown, and if the P-type heavily doped amorphous precursor 3 is used, the P-type lightly doped nanowire 4 can be grown. It should be noted that, in fig. 2f, only one nanowire 4 in each trench 11 is illustrated, and in fig. 3, two nanowires 4 in each trench 11 are illustrated, and the number of nanowires 4 in one trench 11 is not limited in the embodiment of the present application, when the width of the trench 11 is large, two nanowires 4 may be formed therein along two sidewalls of the trench 11, and when the width of the trench 11 is small, only one nanowire 4 may be formed in one trench 11.
According to the preparation method of the semiconductor structure in the embodiment of the application, the catalytic metal and the doped amorphous precursor are deposited in the groove through the groove, then annealing is carried out to enable the catalytic metal to move along the groove and absorb the doped amorphous precursor, and the doped nanowire extending along the groove is grown.
It is emphasized that, by the semiconductor structure preparation method of the embodiment of the present application, the corresponding heavily doped nanowires can be grown by absorbing the amorphous precursor, while if the intrinsic amorphous precursor is used, although the nanowires can be grown by absorbing the catalytic metal, only lightly doped nanowires can be grown, and thus the semiconductor structure preparation method of the embodiment of the present application has stronger compatibility and can be used for manufacturing more types of nanowires.
In addition, the above-mentioned toolsIn the process, if the doped amorphous precursor is changed to be the intrinsic amorphous precursor, the P-type atoms In the catalytic metal, such as In metal, are absorbed during the growth process of the nanowire, so that the formed nanowire is the P-type lightly doped nanowire, and on the basis, if the conventional VLS process is used for reference, the doped nanowire is easily conceived to be In the doping gas atmosphere (such as the P-doped PH)3Atmosphere) growth of nanowires, but in a practical process, PH3The reaction with catalytic metal to generate stable InP can not realize the doping of the nano-wire and stop the growth of the nano-wire.
In a possible embodiment, the step 101 of forming the substrate layer 1 and forming the at least one groove 11 on the surface of the substrate layer 1 includes: forming a substrate layer 1, and forming at least one groove 11 with the depth d and the width w on the surface of the substrate layer 1, wherein d is more than or equal to 50nm and less than or equal to 1 mu m, and w is more than or equal to 1 mu m and less than or equal to 100 mu m. For example, a trench 11 having a depth d of 100nm and a width w of 2 μm is formed on the surface of the base material layer 1 made of a silicon dioxide material by photolithography. The process of forming the trench 11 may adopt dry Etching processes such as photolithography, Inductively Coupled Plasma (ICP) Etching, Reactive Ion Etching (RIE) Etching, and the like, or adopt an alkaline Etching system such as potassium hydroxide (KOH), sodium hydroxide (NaOH), and the like, or an acidic Etching system such as hydrofluoric acid + nitric acid (HF + HNO3), hydrofluoric acid + nitric acid + acetic acid (HF + HNO3+ CH3COOH), and the like, or a wet Etching process of a system such as ethylenediamine Pyrocatechol (Ethylene Diamine Pyrocatechol), and the like.
In one possible embodiment, the step 102 of forming the catalytic metal 2 in the trench 11 includes: depositing the catalytic metal 2 with the thickness h1 in the groove 11, wherein h is more than or equal to 5nm and less than or equal to 200 nm. For example, the position to be deposited of the catalytic metal 2 is first defined by a photolithography process, and then a metal of, for example, 20nm is deposited at a certain position of the trench 11 by a thermal evaporation method.
In a possible embodiment, after the step 103 of forming the catalytic metal 2 in each trench 11, the method further includes: in an environment at a temperature above the melting point of the catalytic metal 2,the catalytic metal 2 is treated with plasma so that the oxide layer on the surface of the catalytic metal 2 is removed and the catalytic metal 2 is converted into the catalytic metal 2 in a separate liquid state. For example, after step 102, the substrate layer 1 on which the catalytic metal 2 is deposited is first placed in a Plasma Enhanced Chemical Vapor Deposition (PECVD) apparatus, heated to a temperature higher than the melting point of the catalytic metal 2 (about 200 ℃), and H is used2The plasma treats the surface oxide layer of the catalytic metal 2, for example, in a range of 3min to 20min, and converts the catalytic metal 2 into discrete catalytic metal 2 droplets in, for example, 5 minutes and 30 seconds.
In one possible embodiment, the step 103 of depositing the doped amorphous precursor 3 on the surface of the substrate layer 1 at the position including the trench 11 comprises: under the environment of the temperature below the melting point of the catalytic metal 2, depositing a doped amorphous precursor 3 with the thickness h1 at the position including the groove 11 on the surface of the substrate layer 1, wherein h2 is more than or equal to 10nm and less than or equal to 200 nm. For example, a doped amorphous precursor 3, for example 15nm, is deposited at a temperature of around 100 ℃.
In one possible embodiment, the step 104 of annealing the substrate layer 1 formed with the catalytic metal 2 and the doped amorphous precursor 3, so that the catalytic metal 2 moves along the corresponding trench and absorbs the doped amorphous precursor 3, and the doped nanowires 4 are formed along the way, includes: the substrate layer 1 on which the catalytic metal 2 and the doped amorphous precursor 3 are formed is annealed at a temperature higher than the melting point of the catalytic metal 2 and in a non-oxygen atmosphere, so that the catalytic metal 2 moves along the corresponding groove 11 and absorbs the doped amorphous precursor 3 to form the doped nanowire 4 along the way.
In one possible embodiment, the catalytic metal 2 is an alloy of one or more of the following metals: indium, tin, bismuth, gallium, and aluminum.
In one possible embodiment, the doped amorphous precursor 3 is a heterogeneous stack of one or more of the following: doped amorphous silicon, doped amorphous germanium and doped amorphous carbon. For example, if the doped amorphous precursor 3 is doped amorphous silicon, the nanowire 4 prepared by the above method is a doped silicon nanowire; if the doped amorphous precursor 3 is doped amorphous germanium, the nanowire 4 prepared by the method is the doped germanium nanowire 4; if the doped amorphous precursor 3 is a heterogeneous stack of doped amorphous germanium and doped amorphous silicon, the nanowire 4 prepared by the above method is a heterogeneous stack nanowire 4 of doped silicon and germanium.
In one possible embodiment, the doping element in the doped amorphous precursor 3 is phosphorus or boron, i.e. the doped amorphous precursor 3 may be an N-type doped amorphous precursor 3, to grow N-type doped nanowires 4; the doped amorphous precursor 3 can also be a P-type doped amorphous precursor 3 to grow a P-type heavily doped nanowire 4.
It should be noted that, in the above embodiments, the trench 11 is a straight-line structure, but the structure of the trench 11 is not limited in the embodiments of the present application, and since the doped nanowire 4 grows along the trench 11, the structure of the trench 11 determines the structure of the doped nanowire 4, as shown in fig. 4, in other realizable embodiments, the trench 11 has a bent or curved structure, and correspondingly, the doped nanowire 4 growing along the trench 11 also has a corresponding bent or curved structure, so as to meet the requirement on the morphology of the doped nanowire 4.
In the above embodiment, a process of growing a nanowire by the semiconductor structure manufacturing method provided in the embodiment of the present application is described, and a process of manufacturing a semiconductor device based on the semiconductor structure manufacturing method provided in the embodiment of the present application is further described below, in a possible implementation manner, as shown in fig. 2f, fig. 5, and fig. 6a to fig. 6c, the nanowire 4 includes two end portions 41 and an intermediate portion 42 located between the two end portions 41, and after forming the doped nanowire 4, the method further includes:
step 201, forming a source metal 51 covering one end portion 41 of the nanowire 4, wherein the source metal 51 is connected to the one end portion 41 of the nanowire 4, forming a drain metal 52 covering the other end portion 41 of the nanowire 4, and the drain metal 52 is connected to the other end portion 41 of the nanowire 4;
step 202, forming a gate dielectric layer 6 covering the middle portion 42 of the nanowire 4; after the gate dielectric layer 6 is formed, the method further comprises the following steps:
step 203, forming a gate metal 7 covering the middle portion 42 of the nanowire 4, wherein the gate dielectric layer 6 is located between the nanowire 4 and the gate metal 7.
Specifically, after step 203, in order to facilitate the top wiring of the overall structure, the gate dielectric layer 6 above the source metal 51 and the drain metal 52 may be further etched by an etching process, so as to expose the source metal 51 and the drain metal 52 on the upper surface of the overall structure, so as to facilitate the electrical connection between the transistor and other devices. After the above steps 101 to 203, a transistor structure is formed, in which the doped nanowire 4 is used as a channel of a transistor, and the embodiment of the present application is not limited to the specific structure of the transistor, for example, the structure shown in fig. 6c is a transistor with a top gate structure, but in other realizable implementations, a transistor with a bottom gate structure or a transistor with other structures may also be formed by using the generated doped nanowire 4 as a channel.
In the embodiments of the present application, "at least one" means one or more, "a plurality" means two or more. "and/or" describes the association relationship of the associated objects, and means that there may be three relationships, for example, a and/or B, and may mean that a exists alone, a and B exist simultaneously, and B exists alone. Wherein A and B can be singular or plural. The character "/" generally indicates that the former and latter associated objects are in an "or" relationship. "at least one of the following" and similar expressions refer to any combination of these items, including any combination of singular or plural items. For example, at least one of a, b, and c may represent: a, b, c, a-b, a-c, b-c, or a-b-c, wherein a, b, c may be single or multiple.
The above description is only a preferred embodiment of the present application and is not intended to limit the present application, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, improvement and the like made within the spirit and principle of the present application shall be included in the protection scope of the present application.

Claims (11)

1. A method for fabricating a semiconductor structure, comprising:
forming a base material layer, and forming at least one groove on the surface of the base material layer;
forming a catalytic metal in the trench;
depositing a doped amorphous precursor on the surface of the substrate layer at a location including the trench, the doped amorphous precursor contacting the catalytic metal;
and annealing the substrate layer formed with the catalytic metal and the doped amorphous precursor, so that the catalytic metal moves along the corresponding groove and absorbs the doped amorphous precursor to form a doped nanowire along the way.
2. The method of claim 1,
the process of forming a substrate layer and forming at least one trench on a surface of the substrate layer includes:
forming a substrate layer, and forming at least one groove with the depth of d and the width of w on the surface of the substrate layer, wherein d is more than or equal to 50nm and less than or equal to 1 mu m, and w is more than or equal to 1 mu m and less than or equal to 100 mu m.
3. The method of claim 2,
the process of forming a catalytic metal in the trench includes:
and depositing catalytic metal with the thickness h1 in the groove, wherein h is more than or equal to 5nm and less than or equal to 200 nm.
4. The method of claim 3,
after forming the catalytic metal in each of the trenches, further comprising:
and under the environment of the temperature above the melting point of the catalytic metal, treating the catalytic metal by using plasma to remove an oxide layer on the surface of the catalytic metal and convert the catalytic metal into the catalytic metal in a discrete liquid state.
5. The method of claim 4,
the process of depositing a doped amorphous precursor on the surface of the substrate layer at a location including the trench comprises:
and under the environment of the temperature below the melting point of the catalytic metal, depositing a doped amorphous precursor with the thickness of h1 at the position including the groove on the surface of the substrate layer, wherein h2 is more than or equal to 10nm and less than or equal to 200 nm.
6. The method of claim 5,
the process of annealing the substrate layer formed with the catalytic metal and the doped amorphous precursor, so that the catalytic metal moves along the corresponding groove and absorbs the doped amorphous precursor, and the doped nanowire is formed along the way includes:
and annealing the substrate layer on which the catalytic metal and the doped amorphous precursor are formed at a temperature above the melting point of the catalytic metal and in a non-oxygen environment, so that the catalytic metal moves along the corresponding groove and absorbs the doped amorphous precursor to form doped nanowires along the way.
7. The method according to any one of claims 1 to 6,
the catalytic metal is an alloy of one or more of the following metals: indium, tin, bismuth, gallium, and aluminum.
8. The method according to any one of claims 1 to 6,
the doped amorphous precursor is a heterogeneous stack of one or more of: doped amorphous silicon, doped amorphous germanium and doped amorphous carbon.
9. The method of claim 8,
the doping element in the doped amorphous precursor is phosphorus or boron.
10. The method of claim 1,
the doped nanowire is an N-type doped nanowire or a P-type heavily doped nanowire.
11. The method according to any one of claims 1 to 6,
the nanowire comprises two end portions and an intermediate portion between the two end portions, and after forming the doped nanowire, further comprises:
forming a source metal covering one end portion of the nanowire, the source metal being connected to one end portion of the nanowire, forming a drain metal covering the other end portion of the nanowire, the drain metal being connected to the other end portion of the nanowire;
forming a gate dielectric layer covering the middle part of the nanowire;
after the gate dielectric layer is formed, the method further comprises the following steps: and forming a gate metal covering the middle part of the nanowire, wherein the gate dielectric layer is positioned between the nanowire and the gate metal.
CN202011003762.9A 2020-09-22 2020-09-22 Method for preparing semiconductor structure Active CN114256147B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202011003762.9A CN114256147B (en) 2020-09-22 2020-09-22 Method for preparing semiconductor structure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202011003762.9A CN114256147B (en) 2020-09-22 2020-09-22 Method for preparing semiconductor structure

Publications (2)

Publication Number Publication Date
CN114256147A true CN114256147A (en) 2022-03-29
CN114256147B CN114256147B (en) 2023-05-23

Family

ID=80788432

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202011003762.9A Active CN114256147B (en) 2020-09-22 2020-09-22 Method for preparing semiconductor structure

Country Status (1)

Country Link
CN (1) CN114256147B (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100276667A1 (en) * 2007-02-23 2010-11-04 Korea University Industrial & Academic Collaboration Foundation Nonvolatile memory electronic device including nanowire channel and nanoparticle-floating gate nodes and a method for fabricating the same
US20110233512A1 (en) * 2005-08-16 2011-09-29 The Regents Of The University Of California Vertical integrated silicon nanowire field effect transistors and methods of fabrication
CN102822971A (en) * 2010-03-25 2012-12-12 国际商业机器公司 A p-FET with a strained nanowire channel and embedded SiGe source and drain stressors
US20140353574A1 (en) * 2012-05-17 2014-12-04 The Board Of Trustees Of The University Of Illinois Field effect transistor structure comprising a stack of vertically separated channel nanowires
CN105239156A (en) * 2015-09-15 2016-01-13 南京大学 Method for preparing plane semiconductor nanowire through epitaxial orientated growth, transfer and integration
CN108217591A (en) * 2018-01-04 2018-06-29 南京大学 A kind of method of heterogeneous alternative stacked step guiding growing three-dimensional slope surface nano-wire array
CN108231542A (en) * 2018-01-09 2018-06-29 南京大学 A kind of plane germanium silicon based on heterogeneous lamination noncrystal membrane and related nanowire growth method
CN108557758A (en) * 2018-02-08 2018-09-21 南京大学 A kind of method of cycle alternation etching homogeneity multistage slope step guiding growth nano-wire array

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110233512A1 (en) * 2005-08-16 2011-09-29 The Regents Of The University Of California Vertical integrated silicon nanowire field effect transistors and methods of fabrication
US20100276667A1 (en) * 2007-02-23 2010-11-04 Korea University Industrial & Academic Collaboration Foundation Nonvolatile memory electronic device including nanowire channel and nanoparticle-floating gate nodes and a method for fabricating the same
CN102822971A (en) * 2010-03-25 2012-12-12 国际商业机器公司 A p-FET with a strained nanowire channel and embedded SiGe source and drain stressors
US20140353574A1 (en) * 2012-05-17 2014-12-04 The Board Of Trustees Of The University Of Illinois Field effect transistor structure comprising a stack of vertically separated channel nanowires
CN105239156A (en) * 2015-09-15 2016-01-13 南京大学 Method for preparing plane semiconductor nanowire through epitaxial orientated growth, transfer and integration
CN108217591A (en) * 2018-01-04 2018-06-29 南京大学 A kind of method of heterogeneous alternative stacked step guiding growing three-dimensional slope surface nano-wire array
CN108231542A (en) * 2018-01-09 2018-06-29 南京大学 A kind of plane germanium silicon based on heterogeneous lamination noncrystal membrane and related nanowire growth method
CN108557758A (en) * 2018-02-08 2018-09-21 南京大学 A kind of method of cycle alternation etching homogeneity multistage slope step guiding growth nano-wire array

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
HAN YIN ET AL.: "High Performance Si Nanowire TFTs With Ultrahigh on/off Current Ratio and Steep Subthreshold Swing", 《IEEE ELECTRON DEVICE LETTERS》 *

Also Published As

Publication number Publication date
CN114256147B (en) 2023-05-23

Similar Documents

Publication Publication Date Title
US8119434B2 (en) Fast p-i-n photodetector with high responsitivity
US9431494B2 (en) Low interfacial defect field effect transistor
US8557670B1 (en) SOI lateral bipolar junction transistor having a wide band gap emitter contact
US8586441B1 (en) Germanium lateral bipolar junction transistor
US7999251B2 (en) Nanowire MOSFET with doped epitaxial contacts for source and drain
US8198706B2 (en) Multi-level nanowire structure and method of making the same
US7737534B2 (en) Semiconductor devices that include germanium nanofilm layer disposed within openings of silicon dioxide layer
US7785922B2 (en) Methods for oriented growth of nanowires on patterned substrates
US20060019472A1 (en) Systems and methods for nanowire growth and harvesting
AU2006343556A1 (en) Methods for oriented growth of nanowires on patterned substrates
KR20140082839A (en) Silicon Carbide Epitaxy
US9293474B2 (en) Dual channel hybrid semiconductor-on-insulator semiconductor devices
US9647063B2 (en) Nanoscale chemical templating with oxygen reactive materials
US9852938B1 (en) Passivated germanium-on-insulator lateral bipolar transistors
US8928107B2 (en) Light detection devices and methods of manufacturing the same
US9752251B2 (en) Self-limiting selective epitaxy process for preventing merger of semiconductor fins
CN114256147B (en) Method for preparing semiconductor structure
CN114256148B (en) Semiconductor structure preparation method
Nam et al. Germanium on insulator (GOI) structure using hetero-epitaxial lateral overgrowth on silicon
CN114256325B (en) Semiconductor structure preparation method, semiconductor device and electronic device
KR940010915B1 (en) Manufacturing method of homo-,hetero-bipolar transistor
CN110896027A (en) Semiconductor device nanowire and preparation method thereof
CN111048627A (en) Method for manufacturing semiconductor device
KR20090097533A (en) Method for formation nanowire, laminated structure formed nanowire and method for manufacturing vertical semiconductor device and interconnect structure using thereof and vertical semiconductor device and interconnect structure comprising thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant