CN114250334B - Desulfurization slag modifier and molten iron desulfurization method - Google Patents
Desulfurization slag modifier and molten iron desulfurization method Download PDFInfo
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- CN114250334B CN114250334B CN202111486012.6A CN202111486012A CN114250334B CN 114250334 B CN114250334 B CN 114250334B CN 202111486012 A CN202111486012 A CN 202111486012A CN 114250334 B CN114250334 B CN 114250334B
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 180
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 162
- 230000023556 desulfurization Effects 0.000 title claims abstract description 162
- 239000002893 slag Substances 0.000 title claims abstract description 144
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 91
- 239000003607 modifier Substances 0.000 title claims abstract description 82
- 238000000034 method Methods 0.000 title claims abstract description 28
- 239000000843 powder Substances 0.000 claims abstract description 84
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 32
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 32
- 239000004571 lime Substances 0.000 claims abstract description 32
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 28
- 239000010436 fluorite Substances 0.000 claims abstract description 28
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 23
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims description 24
- 229910004261 CaF 2 Inorganic materials 0.000 claims description 2
- 230000008901 benefit Effects 0.000 abstract description 10
- 238000001816 cooling Methods 0.000 abstract description 2
- 230000000717 retained effect Effects 0.000 abstract description 2
- 229910000831 Steel Inorganic materials 0.000 description 22
- 239000010959 steel Substances 0.000 description 22
- 230000000694 effects Effects 0.000 description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 14
- 229910052717 sulfur Inorganic materials 0.000 description 14
- 239000011593 sulfur Substances 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000002245 particle Substances 0.000 description 9
- 238000000498 ball milling Methods 0.000 description 8
- 238000012546 transfer Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 238000007790 scraping Methods 0.000 description 5
- 230000003009 desulfurizing effect Effects 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000009628 steelmaking Methods 0.000 description 4
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000011819 refractory material Substances 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C1/00—Refining of pig-iron; Cast iron
- C21C1/02—Dephosphorising or desulfurising
- C21C1/025—Agents used for dephosphorising or desulfurising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/0037—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00 by injecting powdered material
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/064—Dephosphorising; Desulfurising
- C21C7/0645—Agents used for dephosphorising or desulfurising
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Abstract
The invention provides a desulfurization methodThe slag modifier and the molten iron desulphurization method comprise the following raw material components in parts by weight based on 100 parts by weight: na (Na) 2 CO 3 60 to 75 weight portions of soda powder with the weight percentage content not less than 90 weight percent; 15-25 parts by weight of lime powder with the weight percentage content of CaO not less than 80wt%; caF 2 10 to 15 weight portions of fluorite powder with the weight percentage content not less than 80 weight percent. When the desulfurization slag modifier provided by the invention is used for desulfurization, a part of front slag can be retained in a ladle, and the desulfurization slag modifier can modify the front slag to improve the desulfurization capability of the front slag, so that the slag skimming time of the front slag is reduced, the excessive cooling of molten iron is avoided, the desulfurization efficiency is effectively improved, and the obvious economic benefit is brought to enterprises.
Description
Technical Field
The application relates to the technical field of molten iron pretreatment, in particular to a desulfurization slag modifier and a molten steel desulfurization method.
Background
With the rapid development of science and technology and the steel industry, the modern industry has higher and higher requirements on the quality of steel, S is a harmful element in steel, the plasticity and the toughness of the steel can be reduced, and the steel product is easy to generate hot brittleness. The pretreatment desulphurization of the molten iron is an important process means for improving the quality of steel products, expanding the variety of steel products and reducing the cost in the modern steelmaking production. The current common methods for pretreating and desulfurizing molten iron mainly comprise a blowing method and a KR method.
Before KR-method desulfurization is carried out by using the existing desulfurizer, front slag in a ladle must be completely removed, otherwise, the desulfurized slag is too much and difficult to remove, and resulfurization occurs during steelmaking, so that the mechanical property of steel is poor. Generally, a long time is consumed for slagging-off before desulfurization, the temperature of molten iron is seriously reduced, the subsequent desulfurization efficiency is reduced, and the economic benefit of iron and steel enterprises is seriously influenced.
Disclosure of Invention
The application provides a desulfurization slag modifier and a molten steel desulfurization method, and aims to solve the problems that the temperature of molten iron is seriously reduced and the desulfurization efficiency of the molten steel is influenced due to overlong slagging-off time before the molten steel desulfurization.
On one hand, the embodiment of the application provides a desulfurization slag modifier, which comprises the following raw material components in parts by weight based on 100 parts by weight: na (Na) 2 CO 3 60 to 75 weight portions of soda powder with the weight percentage content not less than 90 weight percent; 15-25 parts by weight of lime powder with the weight percentage of CaO not less than 80wt%; caF 2 10 to 15 weight portions of fluorite powder with the weight percentage content not less than 80 weight percent.
Optionally, the desulfurization slag modifier is a powder mixture with an average particle size of not more than 1 mm.
Optionally, the content of S in the lime powder and the fluorite powder is not higher than 0.1wt%.
Optionally, the desulfurization degree of the desulfurization slag modifier is 89-94%.
On the other hand, the embodiment of the application provides a molten iron desulphurization method, which comprises the following steps:
(1) Adding the desulfurization slag modifier into a ladle, and scraping front slag in the ladle so as to enable the desulfurization modifier to fully react with the front slag;
(2) And stirring the molten iron in the ladle so as to fully desulfurize the molten iron.
Optionally, before the step (1), the method further comprises the step of slagging-off the pre-slag in the foundry ladle, and retaining 10-15 wt% of the pre-slag in the foundry ladle.
Optionally, the time for raking the pre-slag in the step (1) is 20-30 s.
Optionally, the stirring time in the step (2) is 9-10 min, and the stirring speed is 90-110 r/min.
Optionally, after desulfurization, the consumption of the desulfurization slag modifier relative to molten iron is 6-10 Kg/T.
Optionally, after the desulfurization, the loss amount of the molten iron is 1.8-2.5%.
Compared with the prior art, the invention at least has the following beneficial effects:
the invention adopts 60 to 75 weight portions of Na 2 CO 3 The soda powder with the weight percentage content of not less than 90wt% is used as the main raw material of the desulfurization residue modifier. The soda powder with the content has strong desulfurization capability, can reduce the melting point and viscosity of the desulfurization slag, and can play a role in dephosphorization at the same time. In a molten iron environment of 1300 ℃, na 2 CO 3 Decomposition into Na 2 O，Na 2 Reaction of O with S to form Na 2 And S, realizing desulfurization.
In order to improve the desulfurization effect and alkalinity of the desulfurization slag modifier, 15-25 parts by weight of lime powder with the weight percentage content of CaO not less than 80wt% is adopted as one of the raw materials of the desulfurization slag modifier. The lime powder with the content not only can desulfurize and dephosphorize, but also desiliconize the product SiO 2 The CaO in the lime powder is also needed to adjust the basicity in the molten iron. In addition, the content of the lime powder can not only improve the O content in the slag 2- The activity of (2) can also reduce the viscosity of the slag to ensure that S is contained in the slag 2- The speed of diffusion mass transfer from the slag-metal interface to the slag is accelerated, so that the slag desulfurization capability is improved.
The desulfurization residue modifier also comprises 10-15 parts by weight of CaF 2 Fluorite powder with the weight percentage content of not less than 80wt percent. The fluorite powder itself does not have the desulfurization ability, but the fluorite powder in the above content can be extractedHigh slag content of O 2- The activity of the calcium sulfate can obviously increase the desulfurization speed of the lime powder, and the fluorite powder can also reduce the melting point of the desulfurization slag and improve the fluidity of the desulfurization slag.
When the desulfurization slag modifier provided by the invention is used for desulfurization, the desulfurization effect is good, part of the front slag can be retained in the ladle, and the desulfurization slag modifier can modify the front slag, so that the desulfurization capability of the front slag is improved, the slag skimming time of the front slag is reduced, the excessive cooling of molten iron is avoided, the desulfurization efficiency is effectively improved, and the obvious economic benefit is brought to enterprises.
Detailed Description
In order to make the objects, technical solutions and advantageous technical effects of the present invention more clear, the present invention is further described in detail with reference to the following embodiments. It should be understood that the embodiments described in this specification are only for the purpose of explaining the present invention and are not intended to limit the present invention.
For the sake of brevity, only a few numerical ranges are explicitly disclosed herein. However, any lower limit may be combined with any upper limit to form ranges not explicitly recited; and any lower limit may be combined with any other lower limit to form a range not explicitly recited, and similarly any upper limit may be combined with any other upper limit to form a range not explicitly recited. Also, although not explicitly recited, each point or individual value between endpoints of a range is encompassed within the range. Thus, each point or individual value may, as its lower or upper limit, be combined with any other point or individual value or with other lower or upper limits to form ranges not explicitly recited.
The above summary of the present invention is not intended to describe each disclosed embodiment or every implementation of the present invention. The following description more particularly exemplifies illustrative embodiments. At various points throughout this application, guidance is provided through lists of examples, which examples can be used in various combinations. In various embodiments, the lists are provided as representative groups and should not be construed as exhaustive.
S is a harmful element in steel, reduces the plasticity and toughness of steel, and easily causes hot embrittlement of steel products. The pretreatment desulphurization of the molten iron is an important process means for improving the quality of steel products, expanding the variety of steel products and reducing the cost in the modern steelmaking production.
The KR method is a common desulphurization method for molten iron pretreatment, and specifically comprises the steps of inserting a baked cross-shaped stirring head which is cast with refractory materials into a molten iron tank with a certain amount of molten iron to rotate, so that the molten iron forms a vortex, and then adding a weighed desulfurizer into the rotating molten iron through a vibrating feeder (or a rotary feeder). After entering the molten iron tank, the desulfurizer is quickly involved into the molten iron by vortex and fully reacts with S in the molten iron in the continuous stirring process, thereby achieving the aim of desulfurization. The KR method has the advantages of strong deep desulfurization capability, low equipment cost, short production flow, high treatment capacity and the like. Although KR molten iron desulphurization can control the S content of molten iron within a reasonable range, the pre-slag in the ladle must be removed before desulphurization. However, in the actual production operation process, the pre-slag in the ladle is difficult to completely remove, the slag removing time is long, and the temperature of the molten iron is seriously reduced, so that the subsequent desulfurization efficiency is directly influenced, and the economic benefit of the iron and steel enterprises is seriously influenced.
The desulfurization residue modifier provided by the invention can solve the problems, and is specifically described below by combining with an embodiment.
Desulfurization slag modifier
The embodiment of the first aspect of the invention provides a desulfurization slag modifier, which comprises the following raw material components in parts by weight based on 100 parts by weight: na (Na) 2 CO 3 60 to 75 weight portions of soda powder with the weight percentage content not less than 90 weight percent; 15-25 parts by weight of lime powder with the weight percentage content of CaO not less than 80wt%; caF 2 10 to 15 weight portions of fluorite powder with the weight percentage content not less than 80 weight percent.
According to the embodiment of the invention, na is contained in the molten iron environment of 1300 DEG C 2 CO 3 Decomposition into Na 2 O，Na 2 Reaction of O with S to form Na 2 And S, realizing desulfurization. Thereby increasing Na in the slag 2 O can obviously improve the sulfide content in the slagAnd the content of the sulfur and the chemical reaction in the slag phase are accelerated, so that the thermodynamic and kinetic conditions of the sulfur removal reaction of the whole molten pool are improved. The experimental research shows that under the same experimental conditions, the slag is added with 3 percent of Na 2 CO 3 Compared with unmodified slag, the sulfur content in the slag is increased by 121%, the sulfur content in the molten iron is reduced by 50%, the transfer of sulfur elements in the molten iron to the slag is promoted, and the desulfurization efficiency of the molten iron is obviously improved.
Meanwhile, the soda powder has strong desulfurization capability, can reduce the melting point and viscosity of the desulfurization slag, and can also play a role in increasing the alkalinity of the slag. But due to Na 2 CO 3 Has certain corrosiveness to refractory materials of a hot metal ladle, so the adding amount of the refractory materials of the hot metal ladle must be controlled within a reasonable range.
In the application, the weight portion of the desulfurization residue modifier is 60-75 parts by weight of soda powder based on 100 parts by weight. For example, soda powder is 60 parts by weight, 62 parts by weight, 65 parts by weight, 68 parts by weight, 70 parts by weight, 72 parts by weight, and 75 parts by weight. The content of soda powder can be any combination range of the above numerical values.
In the present application, na is contained in soda powder in order to improve the desulfurization effect of soda powder 2 CO 3 The weight percentage of the component (A) is not less than 90wt%. For example, na 2 CO 3 In an amount of 90wt%, 92wt%, 95wt% or more.
According to the embodiment of the invention, lime powder is another main raw material of the desulfurization slag modifier. The lime powder not only can remove sulfur and phosphorus, but also can remove silicon to produce SiO 2 The CaO in the lime powder is also needed to adjust the basicity in the molten iron. In addition, the lime powder can also improve O in the slag 2- Activity of (2) and reducing viscosity of slag, S in slag 2- The speed of diffusion mass transfer from the slag iron interface to the slag is accelerated, so that the slag desulfurization capability is improved. Experimental research shows that the binary basicity (CaO and SiO) of the slag is equal to that of the slag under the same experimental conditions 2 Ratio) is increased from 0.5 to 2, the sulfur content in the slag is increased by 136.7 percent, the sulfur content in the molten iron is reduced by 42.7 percent, the transfer of sulfur element in the molten iron to the slag is promoted, and the desulfurization effect of the molten iron is obviously improvedAnd (4) rate.
In the application, the weight portion of the desulfurization residue modifier is 15-25 parts by weight based on 100 parts by weight of lime powder. For example, the lime powder is 15 parts by weight, 17 parts by weight, 19 parts by weight, 20 parts by weight, 22 parts by weight, or 25 parts by weight. The content of the lime powder can be any combination range of the above numerical values.
In the application, in order to improve the slag desulfurization capability, the weight percentage content of CaO in the lime powder is not less than 80wt%. For example, the weight percent CaO content can be 80, 83, 85, 88, 90, 92, or more.
According to the embodiment of the invention, the fluorite powder does not have the desulfurization capability, but the fluorite powder is mixed into the desulfurization slag modifier, so that the O content in the slag can be increased 2- The activity of the method is to accelerate the desulfurization reaction of the slag-iron interface, further promote the transfer of sulfur element to slag, accelerate the migration speed of sulfur element in molten iron and improve the desulfurization efficiency of the molten iron. Meanwhile, the addition of fluorite powder can also reduce the melting point of the desulfurization slag and improve the fluidity of the desulfurization slag. However, the excessive amount of fluorite powder causes a problem of a large amount of liquid phase in the desulfurized slag, so that the desulfurized slag is likely to adhere to the stirrer to form a large slag ring.
In the application, the weight portion of the fluorite powder is 10-15 parts based on 100 parts by weight of the desulfurization slag modifier. For example, the fluorite powder is 10 parts by weight, 11 parts by weight, 12 parts by weight, 13 parts by weight, 14 parts by weight, or 15 parts by weight. The content of the lime powder can be any combination range of the above numerical values.
According to the embodiment of the invention, the mutual synergistic effect of soda powder, lime powder and fluorite powder in the desulfurization slag modifier achieves the purpose of increasing Na in slag 2 The content of O, the alkalinity of the slag, the viscosity of the slag and other comprehensive effects are improved, the sulfur element capacity of the slag is obviously improved, the molten iron desulphurization reaction of a slag-iron interface is promoted, and the molten pool desulphurization effect is improved. When the desulfurization slag modifier provided by the invention is used for desulfurization, the pre-slag in the ladle does not need to be completely removed, a part of the pre-slag can be remained for continuous desulfurization operation, the slag removing time is short, the temperature of molten iron is reduced little, and the desulfurization efficiency is high, so that the economic benefit of iron and steel enterprises is improvedThe purpose of (1).
In some embodiments, the devulcanized slag modifier is a powder mixture having an average particle size of no greater than 1 mm.
According to the embodiment of the invention, the reaction interface of the desulfurization slag modifier with the average particle size of not more than 1mm is larger, so that the reaction efficiency can be effectively improved. For example, the average particle size of the devulcanized slag modifier may be 0.8mm, 0.6mm, 0.5mm, 0.3mm, or less. At the moment, each raw material component in the desulfurization residue modifier fully plays a respective role, and the desulfurization efficiency is high and the desulfurization effect is good.
In some embodiments, the S content of both the lime powder and the fluorite powder is no greater than 0.1wt%.
According to the embodiment of the invention, when the S content in the lime powder and the fluorite powder is not higher than 0.1wt%, the influence on the desulfurization effect is negligible.
In some embodiments, the desulfurization rate of the desulfurization residue modifier is 89 to 94%.
According to the embodiment of the invention, when the desulfurization rate of the desulfurization slag modifier reaches 89-94% in the molten iron desulfurization stage, the molten iron can enter a steel-making furnace for smelting in the next step, and a steel billet with good mechanical property and surface quality can be obtained.
Preparation of desulfurization slag modifier
The preparation method of the desulfurization residue modifier comprises the following steps: and ball-milling and uniformly mixing the soda powder, the lime powder and the fluorite powder according to the proportion by a ball-milling mixer to prepare the desulfurization residue modifier.
In some embodiments, the ball milling time and the ball milling speed of the ball mill can be controlled to obtain the desulfurization slag modifier with the required particle size.
According to the embodiment of the invention, the preparation method of the desulfurization slag modifier is simple in process, and the prepared desulfurization slag modifier is stable in material system.
Molten iron desulphurization method
An embodiment of another aspect of the present invention provides a molten iron desulphurization method, including the following steps:
(1) Adding the desulfurization slag modifier into a ladle, and scraping front slag in the ladle so as to enable the desulfurization modifier to fully react with the front slag;
(2) And stirring the molten iron in the ladle so as to fully desulfurize the molten iron.
In some embodiments, the slag modifier is added to the center of the ladle so that the slag modifier spreads on the surface of the molten iron.
In some embodiments, in order to allow the desulfurization slag modifier to sufficiently react with the molten iron pre-slag, the molten iron pre-slag after the addition of the desulfurization slag modifier is raked by the raking plate. And after the desulfurization slag modifier fully reacts with the slag before the molten iron, stirring and desulfurizing the mixture by using a stirring head at a normal speed.
In some embodiments, step (1) is preceded by slagging off the pre-slag in the ladle, and retaining 10-15 wt% of the pre-slag in the ladle.
According to the embodiment of the invention, generally speaking, 10-15 wt% of the front slag is reserved in the ladle, so that the time can be saved by 2-3 min, and the temperature of the molten iron can be prevented from being reduced by 1-2 ℃. The higher temperature of the molten iron is beneficial to improving the efficiency of the subsequent desulfurization reaction, thereby improving the economic benefit.
In some embodiments, the time for raking the pre-slag in the step (1) is 20-30 s.
According to the embodiment of the invention, the front slag is raked for 20-30 s, so that the front slag is fully contacted and reacted with the desulfurization modifier, the transfer of sulfur elements to the front slag can be promoted, and the molten iron desulfurization efficiency is improved.
In some embodiments, the stirring time in step (2) is 9-10 min, and the stirring speed is 90-110 r/min.
According to the embodiment of the invention, the stirring head is stirred according to the stirring speed and the stirring time, so that the desulfurization residue modifier can fully react with molten iron, and the desulfurization efficiency is improved.
In some embodiments, after desulfurization, the consumption of the desulfurization residue modifier relative to molten iron is 6 to 10Kg/T.
According to the embodiment of the invention, when the desulfurization slag modifier provided by the invention is used for desulfurizing molten iron, the consumption of the desulfurization slag modifier is low, and the method has a good industrial prospect.
In some embodiments, the amount of molten iron lost after desulfurization is 1.8 to 2.5%.
According to the embodiment of the invention, when the desulfurization slag modifier provided by the invention is used for desulfurizing molten iron, the loss amount of the molten iron is small, and the economic benefit is obvious.
Examples
Example 1
The raw material components of the desulfurization residue modifier comprise: 60-70 wt% of soda powder, 20-25 wt% of lime powder and 10-15 wt% of fluorite powder, wherein Na in the soda powder 2 CO 3 The weight percentage content of the component (A) is not less than 90wt%; the weight percentage content of CaO in the lime powder is not less than 80wt%; caF in fluorite powder 2 The weight percentage of the component (A) is not less than 80wt%.
Ball-milling the raw material components in the proportion in a ball mill, and uniformly mixing until the desulfurization residue modifier with the average particle size of not more than 1mm is obtained.
The desulfurization by using the desulfurization residue modifier comprises the following steps:
(1) Keeping 10-15 wt% of the pre-slag in a foundry ladle, adding the desulfurization slag modifier into the foundry ladle, and scraping the pre-slag in the foundry ladle for 20-30 s;
(2) And stirring the molten iron in the ladle by using a stirring head so as to fully desulfurize the molten iron.
The detection results show that: after the desulfurization is finished, the temperature of the molten iron in the ladle is reduced to 20 ℃; the desulfurization time is 12min; the desulfurization rate is 91%; the loss of molten iron is 2.1 percent; the consumption of the desulfurization residue modifier is 7.5Kg/T.
Example 2
The raw material components of the desulfurization residue modifier comprise: 60-70 wt% of soda powder, 15-20 wt% of lime powder and 10-15 wt% of fluorite powder, wherein Na in the soda powder 2 CO 3 The weight percentage content of the component (A) is not less than 90wt%; the weight percentage content of CaO in the lime powder is not less than 80wt%; caF in fluorite powder 2 The weight percentage of the component (A) is not less than 80wt%.
Ball-milling the raw material components in the proportion in a ball mill, and uniformly mixing until the desulfurization residue modifier with the average particle size of not more than 1mm is obtained.
The desulfurization by using the desulfurization residue modifier comprises the following steps:
(1) Retaining 10-15 wt% of the pre-slag in a foundry ladle, adding the desulfurization slag modifier into the foundry ladle, and skimming the pre-slag in the foundry ladle for 20-30 s;
(2) And stirring the molten iron in the ladle by using a stirring head so as to fully desulfurize the molten iron.
Detecting to obtain the molten iron temperature in the ladle, and reducing the molten iron temperature to 25 ℃ after the desulfurization is finished; the desulfurization time is 13min; the desulfurization rate was 89%; the loss of molten iron is 2.5 percent; the consumption of the desulfurization residue modifier is 10.0Kg/T.
Example 3
The raw material components of the desulfurization residue modifier comprise: 65-75 wt% of soda powder, 20-25 wt% of lime powder and 10-15 wt% of fluorite powder, wherein Na in the soda powder 2 CO 3 The weight percentage content of the component (A) is not less than 90wt%; the weight percentage content of CaO in the lime powder is not less than 80wt%; caF in fluorite powder 2 The weight percentage of the component (A) is not less than 80wt%.
Ball-milling the raw material components in the proportion in a ball mill, and uniformly mixing until the desulfurization residue modifier with the average particle size of not more than 1mm is obtained.
The desulfurization by using the desulfurization residue modifier comprises the following steps:
(1) Keeping 10-15 wt% of the pre-slag in a foundry ladle, adding the desulfurization slag modifier into the foundry ladle, and scraping the pre-slag in the foundry ladle for 20-30 s;
(2) And stirring the molten iron in the ladle by using a stirring head so as to fully desulfurize the molten iron.
Detecting to obtain the product, and after the desulfurization is finished, reducing the temperature of the molten iron in the ladle to 16 ℃; the desulfurization time is 10min; the desulfurization rate was 94%; the loss of molten iron is 1.8%; the consumption of the desulfurization residue modifier is 6.0Kg/T.
Example 4
The raw material components of the desulfurization residue modifier comprise: 65-75 wt% soda powder and 15-20 wt% lime powder10-15 wt% of fluorite powder, wherein Na is contained in soda powder 2 CO 3 The weight percentage content of the (B) is not less than 90wt%; the weight percentage content of CaO in the lime powder is not less than 80wt%; caF in fluorite powder 2 The weight percentage content of the compound is not less than 80wt%.
Ball-milling the raw material components in the proportion in a ball mill, and uniformly mixing until the desulfurization residue modifier with the average particle size of not more than 1mm is obtained.
The desulfurization by using the desulfurization residue modifier comprises the following steps:
(1) Keeping 10-15 wt% of the pre-slag in a foundry ladle, adding the desulfurization slag modifier into the foundry ladle, and scraping the pre-slag in the foundry ladle for 20-30 s;
(2) And stirring the molten iron in the ladle by using a stirring head so as to fully desulfurize the molten iron.
Detecting to obtain that the temperature of the molten iron in the ladle is reduced to 22 ℃ after the desulfurization is finished; the desulfurization time is 12min; the desulfurization rate is 90 percent; the loss of molten iron is 2.2%; the consumption of the desulfurization residue modifier is 8.5Kg/T.
Therefore, when the desulfurization slag modifier provided by the invention is used for desulfurization, the pre-slag does not need to be scraped completely, and 10-15 wt% of the pre-slag can be remained for continuous desulfurization operation, so that the pre-slag skimming time is obviously reduced, and the problem of excessive temperature drop of molten iron is avoided. The raw material components of the desulfurization residue modifier provided by the invention are mutually matched and promoted by soda powder, lime powder and fluorite powder, and Na in desulfurization residue is increased 2 The content of O, the alkalinity of the slag, the viscosity of the slag and other comprehensive effects are improved, the content of sulfur elements in the slag is obviously improved, the molten iron desulphurization reaction of a slag-iron interface is promoted, and the desulphurization effect of a molten pool is improved. The desulfurization slag modifier has the advantages of low production cost, high desulfurization efficiency, low consumption of the desulfurization slag modifier and the like, effectively improves the economic benefit of iron and steel enterprises, and has good industrial application prospect.
While the present application has been described with reference to preferred embodiments, various modifications may be made and equivalents may be substituted for elements thereof without departing from the scope of the present application, and in particular, features shown in the various embodiments may be combined in any manner as long as there is no structural conflict. The present application is not intended to be limited to the particular embodiments disclosed herein, but rather to cover all embodiments falling within the scope of the appended claims.
Claims (5)
1. A molten iron desulphurization method is characterized by comprising the following steps:
(1) Carrying out slag skimming treatment on the front slag in the ladle, reserving 10-15 wt% of the front slag in the ladle, adding a desulfurization slag modifier into the ladle, and skimming the front slag in the ladle so as to enable the desulfurization slag modifier to fully react with the front slag;
the desulfurization slag modifier comprises the following raw material components in parts by weight:
Na 2 CO 3 60 to 75 weight portions of soda powder with the weight percentage content not less than 90 weight percent;
15-25 parts by weight of lime powder with the weight percentage content of CaO not less than 80wt%;
CaF 2 10-15 parts by weight of fluorite powder with the weight percentage content not less than 80wt%;
(2) And stirring the molten iron in the ladle so as to fully desulfurize the molten iron.
2. The desulfurization method according to claim 1, wherein the time for raking the pre-slag in the step (1) is 20 to 30 seconds.
3. The desulfurization method according to claim 1, wherein the stirring time in the step (2) is 9 to 10min, and the stirring speed is 90 to 110r/min.
4. The desulfurization method according to claim 1, wherein the consumption of the desulfurization residue modifier with respect to molten iron after desulfurization is 6 to 10Kg/T.
5. The desulfurization method according to claim 1, wherein the loss amount of the molten iron after desulfurization is 1.8 to 2.5%.
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