CN114230375A - Ceramic substrate surface metallization coating composition - Google Patents
Ceramic substrate surface metallization coating composition Download PDFInfo
- Publication number
- CN114230375A CN114230375A CN202210000629.0A CN202210000629A CN114230375A CN 114230375 A CN114230375 A CN 114230375A CN 202210000629 A CN202210000629 A CN 202210000629A CN 114230375 A CN114230375 A CN 114230375A
- Authority
- CN
- China
- Prior art keywords
- percent
- coating
- coating composition
- nickel
- surface metallization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000919 ceramic Substances 0.000 title claims abstract description 20
- 238000001465 metallisation Methods 0.000 title claims abstract description 16
- 239000008199 coating composition Substances 0.000 title claims abstract description 14
- 239000000758 substrate Substances 0.000 title claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 33
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 17
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 12
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052802 copper Inorganic materials 0.000 claims abstract description 12
- 239000010949 copper Substances 0.000 claims abstract description 12
- 229910052593 corundum Inorganic materials 0.000 claims abstract description 12
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 12
- 239000011572 manganese Substances 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 12
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 229910001845 yogo sapphire Inorganic materials 0.000 claims abstract description 12
- 239000003607 modifier Substances 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 11
- 239000011159 matrix material Substances 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 4
- 238000000576 coating method Methods 0.000 abstract description 22
- 239000011248 coating agent Substances 0.000 abstract description 18
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 229910000906 Bronze Inorganic materials 0.000 abstract description 3
- 229910009043 WC-Co Inorganic materials 0.000 abstract description 3
- 239000010974 bronze Substances 0.000 abstract description 3
- 229910010293 ceramic material Inorganic materials 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007751 thermal spraying Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/88—Metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/51—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal
- C04B41/5188—Metallising, e.g. infiltration of sintered ceramic preforms with molten metal organic
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
- C22C30/02—Alloys containing less than 50% by weight of each constituent containing copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/001—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides
- C22C32/0015—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides with only single oxides as main non-metallic constituents
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
Abstract
The invention relates to the technical field of ceramic metallization, in particular to a ceramic matrix surface metallization coating composition which is prepared by mixing the following raw materials in percentage by mass: 30-40% of copper, 5-8% of manganese and Al2O315-20% of powder and TiO23.6 to 5.6 percent of nickel, 3 to 5 percent of nickel, 0.02 to 0.1 percent of rare earth element, 1 to 3 percent of chemical resistance modifier and the balance of aluminum. The bonding strength of the coating and the base material is more than 1.5 times of that of a WC-Co coating, a TiC-Ni coating and an Al-bronze coating, and the coating is not easy to fall off and has excellent wear resistance, corrosion resistance and impact resistance.
Description
Technical Field
The invention relates to the technical field of ceramic metallization, in particular to a ceramic matrix surface metallization coating composition.
Background
Modern new technologies are developing without material separation and place ever higher demands on the material. With the development of material science and process technology, modern ceramic materials have been developed from traditional silicate materials to those involving force, heat, electricity, sound, light and their combination, and the surface of the ceramic material is metallized to have the characteristics of ceramic and the properties of metal, which is the mainstream of the development of the ceramic materials at present.
When the metallized coating on the surface of the ceramic matrix is designed, the reasonable selection of a material system is very important. In addition to considering the performance requirements of the metallized coating, the material system should be selected in consideration of physical matching between the ceramic particles and the metallized coating, wetting and chemical reaction between the particles and the liquid metal, interfacial bonding between the coating and the substrate (substrate), and the like, so as to obtain the optimal combination of physical and mechanical properties between the composite components. The structure and performance of the composite layer formed by different base materials and different metallized coatings are far from each other.
Disclosure of Invention
The invention aims to provide a ceramic matrix surface metallization coating composition which is not easy to fall off and has excellent wear resistance, corrosion resistance and impact resistance.
In order to achieve the purpose, the invention adopts the technical scheme that:
the ceramic matrix surface metallization coating composition is prepared by mixing the following raw materials in percentage by mass:
30-40% of copper, 5-8% of manganese and Al2O315-20% of powder and TiO2 3.6 to 5.6 percent of nickel, 3 to 5 percent of nickel, 0.02 to 0.1 percent of rare earth element, 1 to 3 percent of chemical resistance modifier and the balance of aluminum.
Preferably, the material is obtained by mixing the following raw materials in percentage by mass:
30% of copper, 5% of manganese and Al2O3Powder 15%, TiO2 3.6 percent of nickel, 3 percent of rare earth element, 1 percent of chemical resistance modifier and the balance of aluminum.
Preferably, the material is obtained by mixing the following raw materials in percentage by mass:
copper 40%, manganese 8%, Al2O320% of powder and TiO2 5.6 percent of nickel, 5 percent of rare earth element, 3 percent of chemical resistance modifier and the balance of aluminum.
Preferably, the material is obtained by mixing the following raw materials in percentage by mass:
35% of copper, 6.5% of manganese and Al2O3Powder 17.5%, TiO2 4.6 percent of nickel, 4 percent of rare earth element, 2 percent of chemical resistance modifier and the balance of aluminum.
Further, the chemical resistance modifier is an acrylic additive containing perfluoroalkyl groups.
The bonding strength of the coating and the base material is more than 1.5 times of that of a WC-Co coating, a TiC-Ni coating and an Al-bronze coating, and the coating is not easy to fall off and has excellent wear resistance, corrosion resistance and impact resistance.
Detailed Description
The present invention will be described in detail with reference to specific examples. The following examples will assist those skilled in the art in further understanding the invention, but are not intended to limit the invention in any way. It should be noted that variations and modifications can be made by persons skilled in the art without departing from the spirit of the invention. All falling within the scope of the present invention.
Example 1
The ceramic matrix surface metallization coating composition is prepared by mixing the following raw materials in percentage by mass:
30% of copper, 5% of manganese and Al2O3Powder 15%, TiO2 3.6 percent of nickel, 3 percent of rare earth element, 1 percent of acrylic acid additive containing perfluoroalkyl and the balance of aluminum.
Example 2
The ceramic matrix surface metallization coating composition is prepared by mixing the following raw materials in percentage by mass:
copper 40%, manganese 8%, Al2O320% of powder and TiO2 5.6 percent of nickel, 5 percent of rare earth element, 3 percent of acrylic acid additive containing perfluoroalkyl, and the balance of aluminum.
Example 3
The ceramic matrix surface metallization coating composition is prepared by mixing the following raw materials in percentage by mass:
35% of copper, 6.5% of manganese and Al2O3Powder 17.5%, TiO2 4.6 percent of nickel, 4 percent of rare earth element, 0.06 percent of acrylic acid series additive containing perfluoroalkyl2 percent of agent and the balance of aluminum.
In the specific implementation, a thermal spraying method is adopted to prepare the ceramic matrix metallized coating, and the detection shows that the bonding strength of the coatings obtained in the examples 1, 2 and 3 and the base material is more than 1.5 times that of a WC-Co coating, a TiC-Ni coating and an Al-bronze coating, the coatings are not easy to fall off, and the coatings have excellent wear resistance, corrosion resistance and impact resistance.
The foregoing description of specific embodiments of the present invention has been presented. It is to be understood that the present invention is not limited to the specific embodiments described above, and that various changes or modifications may be made by one skilled in the art within the scope of the appended claims without departing from the spirit of the invention. The embodiments and features of the embodiments of the present application may be combined with each other arbitrarily without conflict.
Claims (5)
1. Ceramic matrix surface metallization coating composition characterized by: the material is prepared by mixing the following raw materials in percentage by mass:
30-40% of copper, 5-8% of manganese and Al2O315-20% of powder and TiO2 3.6 to 5.6 percent of nickel, 3 to 5 percent of nickel, 0.02 to 0.1 percent of rare earth element, 1 to 3 percent of chemical resistance modifier and the balance of aluminum.
2. The ceramic substrate surface metallization coating composition of claim 1, wherein: the material is prepared by mixing the following raw materials in percentage by mass:
30% of copper, 5% of manganese and Al2O3Powder 15%, TiO2 3.6 percent of nickel, 3 percent of rare earth element, 1 percent of chemical resistance modifier and the balance of aluminum.
3. The ceramic substrate surface metallization coating composition of claim 1, wherein: the material is prepared by mixing the following raw materials in percentage by mass:
copper 40%, manganese 8%, Al2O320% of powder and TiO2 5.6 percent of nickel, 5 percent of rare earth element, 3 percent of chemical resistance modifier and the balance of aluminum.
4. The ceramic substrate surface metallization coating composition of claim 1, wherein: the material is prepared by mixing the following raw materials in percentage by mass:
35% of copper, 6.5% of manganese and Al2O3Powder 17.5%, TiO2 4.6 percent of nickel, 4 percent of rare earth element, 2 percent of chemical resistance modifier and the balance of aluminum.
5. A ceramic substrate surface metallization coating composition as in any one of claims 1 to 4, wherein: the chemical resistance modifier is an acrylic additive containing perfluoroalkyl.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210000629.0A CN114230375A (en) | 2022-01-04 | 2022-01-04 | Ceramic substrate surface metallization coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210000629.0A CN114230375A (en) | 2022-01-04 | 2022-01-04 | Ceramic substrate surface metallization coating composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114230375A true CN114230375A (en) | 2022-03-25 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210000629.0A Pending CN114230375A (en) | 2022-01-04 | 2022-01-04 | Ceramic substrate surface metallization coating composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114230375A (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101875255A (en) * | 2009-04-30 | 2010-11-03 | 邦迪管路系统有限公司 | Multilayer corrosion-resistance coating and part comprising same |
| CN102557682A (en) * | 2011-12-21 | 2012-07-11 | 赵志海 | High-temperature-resistant far infrared radiation coating |
| CN102776492A (en) * | 2011-05-13 | 2012-11-14 | 比亚迪股份有限公司 | Selective metallization method of surface of ceramic, and ceramic and its application |
| CN103205607A (en) * | 2012-01-17 | 2013-07-17 | 中航商用航空发动机有限责任公司 | Anti-cavitation coating material, and high-speed fuel oil centrifugal pump with anti-cavitation coating |
| CN103304276A (en) * | 2012-03-14 | 2013-09-18 | 比亚迪股份有限公司 | Method for metalizing ceramic substrate surface and high-power LED (light-emitting display) base |
| CN103373860A (en) * | 2012-04-27 | 2013-10-30 | 比亚迪股份有限公司 | Surface metalized coating composition of ceramic matrix, surface metalizing method of ceramic matrix, and coating and ceramic prepared from ceramic matrix |
| CN105712708A (en) * | 2016-01-12 | 2016-06-29 | 西南民族大学 | High-efficiency energy-saving ceramic material |
| CN106971847A (en) * | 2017-04-27 | 2017-07-21 | 莆田学院 | A kind of thin film capacitor |
| CN110563484A (en) * | 2019-08-26 | 2019-12-13 | 泰州市光明电子材料有限公司 | Ceramic surface metallization process |
-
2022
- 2022-01-04 CN CN202210000629.0A patent/CN114230375A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101875255A (en) * | 2009-04-30 | 2010-11-03 | 邦迪管路系统有限公司 | Multilayer corrosion-resistance coating and part comprising same |
| CN102776492A (en) * | 2011-05-13 | 2012-11-14 | 比亚迪股份有限公司 | Selective metallization method of surface of ceramic, and ceramic and its application |
| CN102557682A (en) * | 2011-12-21 | 2012-07-11 | 赵志海 | High-temperature-resistant far infrared radiation coating |
| CN103205607A (en) * | 2012-01-17 | 2013-07-17 | 中航商用航空发动机有限责任公司 | Anti-cavitation coating material, and high-speed fuel oil centrifugal pump with anti-cavitation coating |
| CN103304276A (en) * | 2012-03-14 | 2013-09-18 | 比亚迪股份有限公司 | Method for metalizing ceramic substrate surface and high-power LED (light-emitting display) base |
| CN103373860A (en) * | 2012-04-27 | 2013-10-30 | 比亚迪股份有限公司 | Surface metalized coating composition of ceramic matrix, surface metalizing method of ceramic matrix, and coating and ceramic prepared from ceramic matrix |
| CN105712708A (en) * | 2016-01-12 | 2016-06-29 | 西南民族大学 | High-efficiency energy-saving ceramic material |
| CN106971847A (en) * | 2017-04-27 | 2017-07-21 | 莆田学院 | A kind of thin film capacitor |
| CN110563484A (en) * | 2019-08-26 | 2019-12-13 | 泰州市光明电子材料有限公司 | Ceramic surface metallization process |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220325 |