CN114196460A - Lubricating oil composition - Google Patents
Lubricating oil composition Download PDFInfo
- Publication number
- CN114196460A CN114196460A CN202010982563.0A CN202010982563A CN114196460A CN 114196460 A CN114196460 A CN 114196460A CN 202010982563 A CN202010982563 A CN 202010982563A CN 114196460 A CN114196460 A CN 114196460A
- Authority
- CN
- China
- Prior art keywords
- lubricating oil
- oil composition
- agent
- antioxidant
- demulsifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 31
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 28
- 239000003112 inhibitor Substances 0.000 claims abstract description 10
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 9
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 8
- 239000002199 base oil Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 238000005260 corrosion Methods 0.000 claims abstract description 7
- 230000007797 corrosion Effects 0.000 claims abstract description 7
- 230000000994 depressogenic effect Effects 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- 239000003607 modifier Substances 0.000 claims abstract description 7
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 5
- 239000013556 antirust agent Substances 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- CMGDVUCDZOBDNL-UHFFFAOYSA-N 4-methyl-2h-benzotriazole Chemical compound CC1=CC=CC2=NNN=C12 CMGDVUCDZOBDNL-UHFFFAOYSA-N 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- 239000002480 mineral oil Substances 0.000 claims description 6
- 235000010446 mineral oil Nutrition 0.000 claims description 6
- 150000004867 thiadiazoles Chemical class 0.000 claims description 6
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims description 5
- 239000012990 dithiocarbamate Substances 0.000 claims description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 5
- DMBHHRLKUKUOEG-UHFFFAOYSA-N N-phenyl aniline Natural products C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 4
- -1 alkyl diphenylamine Chemical compound 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 150000003862 amino acid derivatives Chemical group 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- 229920000193 polymethacrylate Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical group FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 239000004254 Ammonium phosphate Substances 0.000 claims 1
- 125000005210 alkyl ammonium group Chemical group 0.000 claims 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims 1
- 235000019289 ammonium phosphates Nutrition 0.000 claims 1
- 239000010720 hydraulic oil Substances 0.000 abstract description 5
- 230000003647 oxidation Effects 0.000 abstract description 5
- 238000007254 oxidation reaction Methods 0.000 abstract description 5
- 239000010802 sludge Substances 0.000 abstract description 4
- 230000007062 hydrolysis Effects 0.000 abstract description 3
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000005299 abrasion Methods 0.000 abstract description 2
- 238000009472 formulation Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 239000013530 defoamer Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000241 scar Toxicity 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
- C10M2203/1025—Aliphatic fractions used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/064—Di- and triaryl amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
- C10M2223/04—Phosphate esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
- C10M2223/063—Ammonium or amine salts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The lubricating oil composition provided by the embodiment of the invention comprises the following raw materials in percentage by weight: 0.45-0.65% of antioxidant, 0.1-0.2% of extreme pressure agent, 0-0.5% of friction modifier, 0.08-0.15% of metal corrosion inhibitor, 0.06-0.1% of antirust agent, 0.05-0.1% of pour point depressant, 0.03-0.05% of demulsifier, 50-100 PPM of defoaming agent and the balance of base oil. The physical and chemical properties of the lubricating oil composition provided by the invention exceed the indexes of GB11118.1-2011L-HM (high pressure) hydraulic oil, key indexes such as abrasion resistance, demulsification, hydrolysis resistance, air release values and the like exceed by times, the oxidation stability can reach 3000 hours, sludge is not produced, and the normal operation of outdoor, water surface and underwater engineering machinery is ensured.
Description
Technical Field
The invention relates to the technical field of lubricating oil, in particular to a lubricating oil composition.
Background
The hydraulic oil which uses oil liquid as a transmission medium and utilizes the pressure energy of the liquid to start a hydraulic system to work has the history of over three hundred years. With the continuous development of hydraulic technology, mechanical equipment moves forward in the direction of high power, small volume and high pressure, so that the requirement on the quality level of hydraulic oil is more strict, and the performance of the hydraulic equipment greatly influences the functional output, the service life and the maintenance of the hydraulic equipment.
Therefore, a lubricating oil with high performance is needed to ensure that the hydraulic system can be reliably protected during high-temperature and high-load long-time operation.
Disclosure of Invention
Accordingly, to overcome at least some of the disadvantages and drawbacks of the prior art described above, the present invention provides a lubricating oil composition to improve the performance of lubricating oils.
The invention provides a lubricating oil composition which is characterized by comprising the following raw materials in percentage by weight: 0.45-0.65% of antioxidant, 0.1-0.2% of extreme pressure agent, 0-0.5% of friction modifier, 0.08-0.15% of metal corrosion inhibitor, 0.06-0.1% of antirust agent, 0.05-0.1% of pour point depressant, 0.03-0.05% of demulsifier, 50-100 PPM of defoaming agent and the balance of base oil.
In one embodiment of the invention, the antioxidant is a complex of an ashless dialkyl dithiocarbamate and an alkyl diphenylamine.
In one embodiment of the invention, the extreme pressure agent is an ammonium alkyl phosphate.
In one embodiment of the invention, the friction modifier is trioctylphosphates.
In one embodiment of the invention, the metal corrosion inhibitor is a compound of methylbenzotriazole and a thiadiazole derivative, and the ratio of the methylbenzotriazole to the thiadiazole derivative is 1-2: 1.
In one embodiment of the invention, the rust inhibitor is an amino acid derivative.
In one embodiment of the invention, the pour point depressant is polymethacrylate.
In one embodiment of the invention, the demulsifier is a propylene oxide copolymer.
In one embodiment of the invention, the defoamer is a non-silicone acrylate ether copolymer.
In one embodiment of the invention, the base oil is a group ii hydrofined mineral oil or a group iii hydrofined mineral oil.
In conclusion, the physical and chemical properties of the lubricating oil composition provided by the invention exceed the indexes of GB11118.1-2011L-HM (high pressure) hydraulic oil, key indexes such as abrasion resistance, demulsification, hydrolysis resistance, air release values and the like are exceeded by times, the oxidation stability can reach 3000 hours, sludge is not produced, and the normal operation of outdoor, water surface and underwater engineering machinery is ensured. In addition, the lubricating oil composition does not contain additives such as 2, 6-di-tert-butylphenol, 2, 6-di-tert-butyl-p-phenol, phenyl alpha-naphthylamine, tricresyl phosphate and the like which are harmful to human bodies and aquatic organisms, so that the environmental protection property of the lubricating oil composition is improved.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The lubricating oil composition provided by the embodiment of the invention comprises the following raw materials in percentage by weight: 0.45-0.65% of antioxidant, 0.1-0.2% of extreme pressure agent, 0-0.5% of friction modifier, 0.08-0.15% of metal corrosion inhibitor, 0.06-0.1% of antirust agent, 0.05-0.1% of pour point depressant, 0.03-0.05% of demulsifier, 50-100 PPM of defoaming agent and the balance of base oil.
In one embodiment of this example, the antioxidant is a complex of an ashless dialkyl dithiocarbamate and an alkyl diphenylamine. The ashless dialkyl dithiocarbamate has excellent functions of oxidation resistance, extreme pressure, friction reduction and the like, has stable sulfur and nitrogen containing structures, meets the requirement of amine antioxidants and has excellent oxidation resistance. Particularly, the ashless dialkyl dithiocarbamate is matched with the alkyl diphenylamine, so that the obtained antioxidant does not generate sludge after being oxidized and has light oil color.
In a specific embodiment of this embodiment, the extreme pressure agent is an ammonium alkyl phosphate, which has excellent wear resistance and rust resistance, and the addition amount is 0.1-0.2%, and the FZG test can reach above grade 12.
In one embodiment of this example, the friction modifier is a trioctyl phosphate that is non-toxic and readily soluble in hydrogenated mineral oil.
In a specific embodiment of this embodiment, the metal corrosion inhibitor is a composite of methylbenzotriazole and a thiadiazole derivative, and a mass ratio of the methylbenzotriazole to the thiadiazole derivative is 1-2: 1.0.
In one embodiment of this example, the rust inhibitor is an amino acid derivative that provides excellent rust protection at low addition levels (e.g., 0.06%) and is synergistic with EP/AW additives.
In one embodiment of this embodiment, the pour point depressant is polymethacrylate.
In one embodiment of this example, the demulsifier is a propylene oxide copolymer.
In one embodiment of this example, the defoamer is a non-silicone acrylate ether copolymer.
In one embodiment of this example, the base oil is a group ii or group iii hydrorefined mineral oil from which impurities such as aromatic hydrocarbons, sulfur, nitrogen, etc. have been removed, resulting in a substantial improvement in quality.
The formulation of the specific sample of the lubricating oil composition and the experimental results provided in the examples of the present invention are shown in the following examples.
[ first embodiment ] A method for manufacturing a semiconductor device
Formulation example:
the experimental results are as follows:
[ second embodiment ]
Formulation example:
the experimental results are as follows:
[ third embodiment ]
Formulation example:
the experimental results are as follows:
[ fourth example ] A
Formulation example:
the experimental results are as follows:
[ fifth embodiment ]
Formulation example:
the experimental results are as follows:
it can be seen from the formula examples and test results of the above embodiments that the physical and chemical properties of the lubricating oil composition provided by the invention exceed the indexes of GB11118.1-2011L-HM (high pressure) hydraulic oil, the FZG friction test exceeds grade 12, the diameter of the four-ball friction test wear scar is less than 0.5mm, the friction is reduced by 70%, the thermal oxidation stability is greatly improved, the hidden danger of sludge generation is solved, key indexes such as wear resistance, emulsion breaking, hydrolysis resistance, air release values and the like exceed by times, and the normal operation of outdoor, water surface and underwater engineering machinery is ensured. In addition, the lubricating oil composition does not contain additives such as 2, 6-di-tert-butylphenol, 2, 6-di-tert-butyl-p-phenol, phenyl alpha-naphthylamine, tricresyl phosphate and the like which are harmful to human bodies and aquatic organisms, so that the environmental protection property of the lubricating oil composition is improved.
In addition, it should be understood that the foregoing embodiments are merely exemplary illustrations of the present invention, and the technical solutions of the embodiments can be arbitrarily combined and collocated without conflict between technical features and structural contradictions, which do not violate the purpose of the present invention.
Finally, it should be noted that: the above examples are only intended to illustrate the technical solution of the present invention, but not to limit it; although the present invention has been described in detail with reference to the foregoing embodiments, it will be understood by those of ordinary skill in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some technical features may be equivalently replaced; and such modifications or substitutions do not depart from the spirit and scope of the corresponding technical solutions of the embodiments of the present invention.
Claims (10)
1. The lubricating oil composition is characterized by comprising the following raw materials in percentage by weight: 0.45-0.65% of antioxidant, 0.1-0.2% of extreme pressure agent, 0-0.5% of friction modifier, 0.08-0.15% of metal corrosion inhibitor, 0.06-0.1% of antirust agent, 0.05-0.1% of pour point depressant, 0.03-0.05% of demulsifier, 50-100 PPM of defoaming agent and the balance of base oil.
2. The lubricating oil composition of claim 1, wherein the antioxidant is a complex of an ashless dialkyl dithiocarbamate and an alkyl diphenylamine.
3. The lubricating oil composition of claim 1, wherein the extreme pressure agent is an alkyl ammonium phosphate.
4. The lubricating oil composition of claim 1, wherein the friction modifier is a trioctylphosphate.
5. The lubricating oil composition of claim 1, wherein the metal corrosion inhibitor is a composite of methylbenzotriazole and a thiadiazole derivative, and the mass ratio of the methylbenzotriazole to the thiadiazole derivative is 1-2: 1.
6. The lubricating oil composition according to claim 1, wherein the rust inhibitor is an amino acid derivative.
7. The lubricating oil composition of claim 1, wherein the pour point depressant is a polymethacrylate.
8. The lubricating oil composition of claim 1, wherein the demulsifier is a propylene oxide copolymer.
9. The lubricating oil composition of claim 1, wherein the anti-foaming agent is a non-silicone acrylate ether copolymer.
10. The lubricating oil composition of claim 1, wherein the base oil is a group ii hydrofined mineral oil or a group iii hydrofined mineral oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010982563.0A CN114196460A (en) | 2020-09-17 | 2020-09-17 | Lubricating oil composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010982563.0A CN114196460A (en) | 2020-09-17 | 2020-09-17 | Lubricating oil composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114196460A true CN114196460A (en) | 2022-03-18 |
Family
ID=80644924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010982563.0A Pending CN114196460A (en) | 2020-09-17 | 2020-09-17 | Lubricating oil composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114196460A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102690717A (en) * | 2011-03-24 | 2012-09-26 | 中国石油化工股份有限公司 | Extreme-pressure long-life lubricant composition for steam turbine |
| US20140045736A1 (en) * | 2011-05-16 | 2014-02-13 | The Lubrizol Corporation | Lubricating Compositions For Turbine And Hydraulic Systems With Improved Antioxidancy |
| US20160068781A1 (en) * | 2014-09-04 | 2016-03-10 | Vanderbilt Chemicals, Llc | Liquid ashless antioxidant additive for lubricating compositions |
| CN107760418A (en) * | 2016-08-19 | 2018-03-06 | 中国科学院宁波材料技术与工程研究所 | A kind of ashless antiwear hydraulic lubricant oil composition and preparation method thereof |
-
2020
- 2020-09-17 CN CN202010982563.0A patent/CN114196460A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102690717A (en) * | 2011-03-24 | 2012-09-26 | 中国石油化工股份有限公司 | Extreme-pressure long-life lubricant composition for steam turbine |
| US20140045736A1 (en) * | 2011-05-16 | 2014-02-13 | The Lubrizol Corporation | Lubricating Compositions For Turbine And Hydraulic Systems With Improved Antioxidancy |
| US20160068781A1 (en) * | 2014-09-04 | 2016-03-10 | Vanderbilt Chemicals, Llc | Liquid ashless antioxidant additive for lubricating compositions |
| CN107760418A (en) * | 2016-08-19 | 2018-03-06 | 中国科学院宁波材料技术与工程研究所 | A kind of ashless antiwear hydraulic lubricant oil composition and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102618360B (en) | Compressor oil composition | |
| CN102277224B (en) | Lubricant composition for transmission system of wind power equipment | |
| CN103097505B (en) | Corrosion inhibiting polyalkylene glycol-based lubricant compositions | |
| CN102399612B (en) | Zinc-free high pressure anti-wear hydraulic oil and preparation method thereof | |
| CN103820192B (en) | Air compressor oil composition and preparation method thereof | |
| CN108102774B (en) | Lubricating oil and application thereof | |
| CN111363608A (en) | High-pressure anti-wear hydraulic oil | |
| CN101851549A (en) | A long-life gasoline engine oil | |
| CN111100738B (en) | Oxidation-resistant long-life zinc-free hydraulic fluid composition and preparation method thereof | |
| CN109439414B (en) | Synthetic flame-retardant hydraulic oil | |
| CN104130845B (en) | A kind of marine gearbox fluid composition | |
| CN112940832A (en) | Coal-based anti-wear hydraulic oil and preparation method thereof | |
| US11242893B2 (en) | Composition of high performance bearing oil for steel plants | |
| CN102337174B (en) | Gasholder sealing oil composition with high corrosion resistance and oxidation resistance | |
| EP2748293A1 (en) | Lubricating oil composition | |
| CN112011387A (en) | SN-grade gasoline and engine oil complexing agent and preparation method thereof | |
| CN103254984B (en) | High water resistance type heavy load industrial gear oil | |
| CN114196460A (en) | Lubricating oil composition | |
| CN102899147A (en) | Lubricating oil composition for gear and preparation method thereof | |
| CN114133976A (en) | Lubricating oil composition | |
| CN114106919A (en) | Cleaning lubricating oil | |
| CN114479996B (en) | Semi-synthetic hydraulic oil composition | |
| CN116804161B (en) | High-pressure long-life engineering machinery hydraulic oil and preparation method thereof | |
| CN113493719B (en) | Gas turbine lubricating oil composition | |
| CN105670747A (en) | Gear oil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220318 |
|
| RJ01 | Rejection of invention patent application after publication |