CN1141895A - Aqueous-emulsion type co-mixed anti-corrosion anti-rust material, mortar and production method thereof - Google Patents

Aqueous-emulsion type co-mixed anti-corrosion anti-rust material, mortar and production method thereof Download PDF

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Publication number
CN1141895A
CN1141895A CN 95107915 CN95107915A CN1141895A CN 1141895 A CN1141895 A CN 1141895A CN 95107915 CN95107915 CN 95107915 CN 95107915 A CN95107915 A CN 95107915A CN 1141895 A CN1141895 A CN 1141895A
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China
Prior art keywords
weight quota
emulsion
quota
weight
corrosion
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Pending
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CN 95107915
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Chinese (zh)
Inventor
何鸣
韩连敬
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Zhongxin Guoan Anti-Corrosion New Tech Corp
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Zhongxin Guoan Anti-Corrosion New Tech Corp
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Priority to CN 95107915 priority Critical patent/CN1141895A/en
Publication of CN1141895A publication Critical patent/CN1141895A/en
Pending legal-status Critical Current

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  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a corrosion-proofing and rust-proofing material for reinforced concrete. Said material is made up by mixing water, polymer emulsion, polyvinyl acetal adhesive, thickening agent, anti-corrosion and anti-rust adjuvant and antifoaming agent. Said material canb e mixed with the invented powder preparation, and in which the high-grade cement and mid-sand are added, then those can be made into an aqueous emulsion type mixed anti-corrosion and anti-rust mortar. Said invention is low in cost, and has the good stability and construction properties.

Description

Aqueous-emulsion type co-mixed anti-corrosion anti-rust material, mortar and manufacture method thereof
The present invention relates to be used to protect skeleton construction in order to avoid the impregnating material that is damaged by corrosion is specifically related to a kind of aqueous-emulsion type co-mixed anti-corrosion anti-rust material mortar and manufacture method thereof.
The normal swelling owing to the external corrosion medium of the skeleton construction of industry and civil building corrodes, or steel bar corrosion generation concrete cracking behind the harmful ion intrusion concrete, peels off serious threat safety of whole building thus and weather resistance.In order to avoid be damaged by corrosion, some impregnating material have appearred in succession on market in order to protect reinforced concrete buildings.These impregnating material are used to protect reinforced concrete buildings can play certain antiseptic and rustproof effect, but there is following problem in they taken as a whole: 1) batch poor stability, and workability is not good; 2) price is higher; 3) only focus on single antiseptic property, antiseptic and rustproof over-all properties is noted inadequately; 4) package stability is relatively poor.
In order to overcome the problems referred to above of existing Steel Concrete impregnating material, therefore the object of the present invention is to provide a kind of anti-corrosion anti-rust material, mortar and manufacture method thereof that is used for skeleton construction, the batch of its finished product stability and having good workability, cost is lower than like product, can be anticorrosion all sidedly and antirust and effect is remarkable, easy construction and storage and transportation stability are good.
Above-mentioned purpose of the present invention is achieved like this, promptly obtain a kind of aqueous-emulsion type co-mixed anti-corrosion anti-rust material by development, the emulsion that it is made up of following ingredients at least: the water of 40 to 80 weight quota, the polymer emulsion of 50 to 160 weight quota, the polyvinylacetal tackiness agent of 20 to 100 weight quota, the thickening material of 5 to 16 weight quota, the antiseptic and rustproof auxiliary agent of 1 to 14 weight quota and the defoamer of 0.5 to 3 weight quota.
Resulting emulsion can be used as the anti-corrosive protecting agent that is applied to concrete surface; also can be used: the light filler of 70 to 100 weight quota with the pulvis of following component; the nitrite of 10 to 30 weight quota; 0.5 phosphoric acid salt to 14 weight quota; 0.3 vitriol to 11 weight quota; 0.1 to the urotropine of 6 weight quota, the stablizer of 1 to 5 weight quota, the powdery oxygen absorbent of the water reducer of 0.3 to 10 weight quota and 0.01 to 2 weight quota.
Polymer emulsion in above-mentioned anti-corrosion anti-rust material is the ethene-vinyl acetate copolymer emulsion, benzene emulsion, ACRYLIC EMULSION, a kind of in the neoprene latex or two or more blend wherein.
The manufacture method of above-mentioned aqueous-emulsion type co-mixed anti-corrosion anti-rust material of the present invention is: get the ethene-vinyl acetate copolymer emulsion in advance, benzene emulsion, ACRYLIC EMULSION, a kind of polymer emulsion in the neoprene latex or the weight quota of the blending emulsion 50 to 160 of two or more polymkeric substance wherein, and in advance with the water of 40 to 100 weight quota, the polyvinylacetal tackiness agent of 20 to 100 weight quota, the thickening material of 5 to 16 weight quota, the antiseptic and rustproof auxiliary agent of 1 to 14 weight quota and the miscible one-tenth miscible fluid of the defoamer of 0.5 to 3 weight quota, then described polymer emulsion and described miscible fluid are injected reactor, and adopt at the uniform velocity high shear force whipping appts stirring therein, obtain the emulsion product after mixing.
With above-mentioned emulsion, pulvis, 425 #The cement of above label and GB medium sand compare with weight quota: 30-50: 515: 40-60: 100-150 mixes, and makes the aqueous-emulsion type co-mixed anti-corrosion anti-rust mortar, also can add microlith when needing, and is used for concrete construction.
Owing in aqueous-emulsion type co-mixed anti-corrosion anti-rust material of the present invention and mortar, added the polyvinylacetal binder constituents, made this material have good especially antiseepage effect; Adding thickening material in the material increases the stability of emulsion; And the adding powdery stabilizer can make pulvis wherein be difficult for moisture absorption caking in the material.
Owing to used the prescription and the method for the invention described above, this kind aqueous-emulsion type co-mixed anti-corrosion anti-rust material and mortar are compared with some at present commercially available like products, and have following advantage: (1) antiseptic and rustproof performance is comprehensive, and effect is remarkable; (2) the material comprehensive cost descends about 40% than like product; (3) easy construction, the good stability of storing and transporting; (4) manufacture method advanced person can be fit to suitability for industrialized production, and the constant product quality of producing is good; (5) early strength is big, can reduce curing time.
For feature of the present invention and advantage are understood in more detail, be described further below in conjunction with embodiment.
Embodiment 1:
Adopt aforesaid method, the component of following prescription be mixed and made into a kind of aqueous-emulsion type co-mixed anti-corrosion anti-rust material:
The composition weight share
Water 65
Ethene-vinyl acetate copolymer emulsion 80
CMC thickening material 6
Antiseptic and rustproof auxiliary agent 12
Silicone antifoam agent 3
Polyvinylacetal tackiness agent 70
The material that makes is an emulsion, and it can also can add this emulsion directly as the antiseptic and rustproof protective material that is applied to concrete surface in the novel concrete construction, as concrete anticorrosion impervious agent, and simultaneously reinforcing bar is also had the certain protection effect.
Embodiment 2:
The pulvis of the antiseptic and rustproof emulsion of the foregoing description 1 and following prescription is used:
The composition weight share
Light filler 85
Powdery oxygen absorbent 0.1
Urotropine 6
Water reducer 8
Phosphoric acid salt 10
Vitriol 11
Nitrite 20
Stablizer (anti-hard caking agent) 5
Above pulvis is equipped with 425 #Above cement and the medium sand of label carries out pre-mixing, adds the abundant mix of antiseptic and rustproof emulsion that makes in the foregoing description 1 again in this Preblend gradually, obtains the aqueous-emulsion type co-mixed anti-corrosion anti-rust mortar.This mortar is except that this has in the moderate corrosion medium the good barrier propterty to concrete structure, and the reinforcing bar to corrosion has outstanding protective benefits especially, can increase the weather resistance of buildings or structures.By long period on probation in Industrial buildings, prove to have solved the difficult problem that some organic coatings can't constructs and be lacked with self endurance cycles on wet base.The salient features that obtains through test is:
1, ultimate compression strength 〉=20MP
2, folding strength 〉=60MP
3, anti-permeability performance 〉=10MP
4, water-intake rate≤25%
5, adhesive property: good
6, to the weather resistance of medium corrosion strength chemical mediator: good
7, to the reinforced steel bar rust preventing performance: good
8, blending emulsion basic viscosity (being coated with 4 glasss): 7=30 second
The aqueous-emulsion type co-mixed anti-corrosion anti-rust material and the mortar that obtain according to the present invention can be applicable to following scope:
1, exterior decorations such as industrial premises, metope, roof boarding, floor, bearing column, beam are wiped one's face under the wet environment;
2, industrial buildings or structures reinforced concrete structure erosion repair that happiness is mended and consolidation process in anticorrosion maintenance;
3, buildingss such as civilian, the communal facility of industry, town road bridge lost efficacy, damaged recovery project;
4, the industrial civil building protection of exposed reinforcement in the engineering of temporarily suspending, postpone;
5, the protection of Steel Concrete under the gas phase of slight and moderate corrosion intensity, the liquid phase medium environment, alternative conditionally organic coating.

Claims (6)

1, a kind of aqueous-emulsion type co-mixed anti-corrosion anti-rust material, it is characterized in that, the emulsion that it is made up of following ingredients at least: the water of 40 to 80 weight quota, the polymer emulsion of 50 to 160 weight quota, the polyvinyl alcohol acetals tackiness agent of 20 to 100 weight quota, the thickening material of 5 to 16 weight quota, the antiseptic and rustproof auxiliary agent of 1 to 14 weight quota and the defoamer of 0.5 to 3 weight quota.
2, aqueous-emulsion type co-mixed anti-corrosion anti-rust material according to claim 1, it is characterized in that: it also can comprise the pulvis of following ingredients: the light filler of 70 to 100 weight quota, the nitrite of 10 to 30 weight quota, 0.5 to the phosphoric acid salt of 14 weight quota, the vitriol of 0.3 to 11 weight quota.0.1 to the urotropine of 6 weight quota, the stablizer of 1 to 5 weight quota, the powdery oxygen absorbent of the water reducer of 0.3 to 10 weight quota and 0.01 to 2 weight quota.
3, aqueous-emulsion type co-mixed anti-corrosion anti-rust material according to claim 1, it is characterized in that: described polymer emulsion is the ethene-vinyl acetate copolymer emulsion, benzene emulsion, ACRYLIC EMULSION, a kind of in the neoprene latex or two or more concurrent mixture wherein.
4, a kind of aqueous-emulsion type co-mixed anti-corrosion anti-rust mortar, it is characterized in that, it is made up of following ingredients: the water of 40 to 80 weight quota, the polymer emulsion of 50 to 160 weight quota, the polyvinylacetal tackiness agent of 20 to 100 weight quota, the thickening material of 5 to 16 weight quota, the emulsion that the defoamer of the antiseptic and rustproof auxiliary agent of 1 to 14 weight quota and 0.5 to 3 weight quota is formed; The light filler of 70 to 100 weight quota, the nitrite of 10 to 30 weight quota, 0.5 phosphoric acid salt to 14 weight quota, 0.3 vitriol to 11 weight quota, 0.1 urotropine to 6 weight quota, the stablizer of 1 to 5 weight quota, the pulvis that the powdery oxygen absorbent of the water reducer of 0.3 to 10 weight quota and 0.01 to 2 weight quota is formed; And the cement and the GB medium sand of the above label of 425# of suitable weight quota.
5, aqueous-emulsion type co-mixed anti-corrosion anti-rust mortar according to claim 4 is characterized in that: the weight quota ratio of described emulsion, pulvis, cement and sand is: 30-50: 5-15: 40: 60: 100-150.
6, a kind of manufacture method of aqueous-emulsion type co-mixed anti-corrosion anti-rust material, it is characterized in that: get the ethene-vinyl acetate copolymer emulsion in advance, benzene emulsion, ACRYLIC EMULSION, a kind of polymer emulsion in the neoprene latex or the weight quota of the blending emulsion 50 to 160 of two or more polymkeric substance wherein, and in advance with the water of 40 to 100 weight quota, the polyvinylacetal tackiness agent of 20 to 100 weight quota, the thickening material of 5 to 16 weight quota, the antiseptic and rustproof auxiliary agent of 1 to 14 weight quota and the miscible one-tenth miscible fluid of the defoamer of 0.5 to 3 weight quota, then described emulsion and described miscible fluid are injected reactor, in reactor, adopt at the uniform velocity high shear force whipping appts stirring, promptly make product after mixing.
CN 95107915 1995-08-03 1995-08-03 Aqueous-emulsion type co-mixed anti-corrosion anti-rust material, mortar and production method thereof Pending CN1141895A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 95107915 CN1141895A (en) 1995-08-03 1995-08-03 Aqueous-emulsion type co-mixed anti-corrosion anti-rust material, mortar and production method thereof

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Application Number Priority Date Filing Date Title
CN 95107915 CN1141895A (en) 1995-08-03 1995-08-03 Aqueous-emulsion type co-mixed anti-corrosion anti-rust material, mortar and production method thereof

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100567199C (en) * 2005-11-23 2009-12-09 同济大学 A kind of coating for concrete for maintenance and protection and preparation using method thereof
CN102399091A (en) * 2010-09-07 2012-04-04 上海法赫桥梁隧道养护工程技术有限公司 Water-resistant salt-resistant concrete protecting agent and preparation method thereof
CN101792279B (en) * 2010-02-08 2012-07-25 徐运海 Formula and preparation process of concrete sulfate resistance agent
CN102993840A (en) * 2011-09-19 2013-03-27 天津科技大学 Preparation technique of environment-friendly water-based rust inhibitor
CN105017823A (en) * 2015-06-30 2015-11-04 盐城工学院 Cement-based concrete reinforcing bar antirust paint, preparation method and application thereof
CN106609563A (en) * 2016-11-03 2017-05-03 柏利伟(上海)环保科技有限公司 Crack-resistant, anticorrosive and anti-seepage protection method for concrete structure surfaces

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100567199C (en) * 2005-11-23 2009-12-09 同济大学 A kind of coating for concrete for maintenance and protection and preparation using method thereof
CN101792279B (en) * 2010-02-08 2012-07-25 徐运海 Formula and preparation process of concrete sulfate resistance agent
CN102399091A (en) * 2010-09-07 2012-04-04 上海法赫桥梁隧道养护工程技术有限公司 Water-resistant salt-resistant concrete protecting agent and preparation method thereof
CN102399091B (en) * 2010-09-07 2013-06-05 上海法赫桥梁隧道养护工程技术有限公司 Water-resistant salt-resistant concrete protecting agent and preparation method thereof
CN102993840A (en) * 2011-09-19 2013-03-27 天津科技大学 Preparation technique of environment-friendly water-based rust inhibitor
CN105017823A (en) * 2015-06-30 2015-11-04 盐城工学院 Cement-based concrete reinforcing bar antirust paint, preparation method and application thereof
CN106609563A (en) * 2016-11-03 2017-05-03 柏利伟(上海)环保科技有限公司 Crack-resistant, anticorrosive and anti-seepage protection method for concrete structure surfaces

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