CN114149531A - Water-based acrylic resin capable of transferring and printing gloss oil and preparation method thereof - Google Patents
Water-based acrylic resin capable of transferring and printing gloss oil and preparation method thereof Download PDFInfo
- Publication number
- CN114149531A CN114149531A CN202111371617.0A CN202111371617A CN114149531A CN 114149531 A CN114149531 A CN 114149531A CN 202111371617 A CN202111371617 A CN 202111371617A CN 114149531 A CN114149531 A CN 114149531A
- Authority
- CN
- China
- Prior art keywords
- acrylic resin
- monomer
- ester monomer
- water
- gloss
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention discloses a water-based acrylic resin capable of being used as both transfer printing and gloss oil, which comprises the following raw materials in percentage by weight: 15-25% of butyl ester monomer, 20-28% of methyl ester monomer, 2-8% of styrene, 1-5% of functional acrylic monomer, 0.5-2% of emulsifier, 0.3-2% of neutralizer, 0.2-2% of chain transfer agent, 0.5-1% of initiator and 40-50% of pure water. The waterborne resin can radically improve the VOC emission limitation problem of the prior oleoresin and oleopaint and the problem of heavy pollution caused by odor during construction, has the characteristics of transfer printing and high-gloss oil, has good adhesive force after film forming, has low odor and greatly reduces the use cost.
Description
Technical Field
The invention relates to the technical field of transfer printing raw material preparation, in particular to a transfer printing and gloss oil dual-purpose water-based acrylic resin and a preparation method thereof.
Background
At present, because the popularity of water-based resins and water-based paints is low, most of transfer printing ink and gloss oil used in China still use oil-based products, most of the used resins are solid resins, and need to be dissolved by using solvents, and the solvents have unpleasant odor, have adverse effects on the environment of human bodies, and also do not meet the national environmental protection requirements, the development of the water-based resins is necessary.
In addition, the transfer printing ink and the gloss oil are generally used separately, the transfer printing ink is used for printing patterns, the gloss oil is used for increasing the color and luster of the patterns, the use is troublesome, and the adhesion of raw materials is poor.
Disclosure of Invention
The invention aims to provide the transfer printing and gloss oil dual-purpose water-based acrylic resin which is simple in preparation method, low in viscosity, good in glossiness and good in adhesive force, and is used for solving the technical problems in the background technology.
The invention discloses a transferable and gloss-oil dual-purpose water-based acrylic resin, which comprises the following raw materials in percentage by weight: 15-25% of butyl ester monomer, 20-28% of methyl ester monomer, 2-8% of styrene, 1-5% of functional acrylic monomer, 0.5-2% of emulsifier, 0.3-2% of neutralizer, 0.2-2% of chain transfer agent, 0.5-1% of initiator and 40-50% of pure water.
In a preferred embodiment, the material comprises the following raw materials in percentage by weight: 18% of butyl ester monomer, 21% of methyl ester monomer, 2% of styrene, 5% of functional acrylic monomer, 1% of emulsifier, 1.5% of neutralizer, 0.5% of chain transfer agent, 1% of initiator and 50% of pure water.
In a preferred embodiment, the butyl ester-based monomer is at least one of butyl methacrylate and butyl acrylate; the methyl ester monomer is at least one of methyl methacrylate and methyl acrylate.
In a preferred embodiment, the functional acrylic monomer is at least one of acrylic acid, methacrylic acid, hydroxyethyl methacrylate, glycidyl methacrylate, lauryl methacrylate and isobornyl methacrylate
In a preferred embodiment, the emulsifier is at least one of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, alkylphenol ethoxylates, fatty alcohol-polyoxyethylene ether, and CO-436.
In a preferred embodiment, the neutralizing agent is at least one of ammonia, monoethanolamine, diethanolamine, N-dimethylethanolamine.
In a preferred embodiment, the chain transfer agent is at least one of mercaptoethanol, thioglycolic acid, dodecyl mercaptan.
In a preferred embodiment, the initiator is at least one of potassium persulfate, sodium persulfate, ammonium persulfate, di-tert-butyl peroxide, tert-butyl peroxybenzoate and tert-amyl peroxybenzoate.
A preparation method of a transferable and gloss-oil dual-purpose water-based acrylic resin comprises the following steps:
s1, adding the emulsifier into the emulsifying kettle and the reaction kettle respectively according to the proportion of 7:3, adding pure water, and stirring to fully dissolve;
s2, sequentially adding a butyl ester monomer, a methyl ester monomer, a functional acrylic monomer, styrene and a chain transfer agent into the reaction kettle to emulsify for 30-40min under the stirring starting condition of the emulsification kettle to obtain a monomer emulsion;
s3, adding 1/3 monomer emulsion into a reaction kettle, adding 1/2 initiator, heating the reaction kettle to 75-80 ℃, and preserving heat for 1-1.5 hours;
s4, synchronously dripping the residual 2/3 monomer emulsion and the residual 1/2 initiator for 2-3h, and preserving the heat at 85-90 ℃ for 1-1.5 h;
and S5, cooling to below 40 ℃, adding a neutralizing agent into the reaction material, and adjusting the pH value to 7.0-7.5 to obtain the water-based acrylic resin.
The technical scheme of the invention has the beneficial effects that:
the waterborne resin can radically improve the VOC emission limitation problem of the prior oleoresin and oleopaint and the problem of heavy pollution caused by odor during construction, has the characteristics of transfer printing and high-gloss oil, has good adhesive force after film forming, has low odor and greatly reduces the use cost.
Detailed Description
The present invention will be described in further detail with reference to specific embodiments. The embodiments of the present invention have been presented for purposes of illustration and description, and are not intended to be exhaustive or limited to the invention in the form disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art. The embodiment was chosen and described in order to best explain the principles of the invention and the practical application, and to enable others of ordinary skill in the art to understand the invention for various embodiments with various modifications as are suited to the particular use contemplated.
The invention discloses a transferable and gloss-oil dual-purpose water-based acrylic resin, which comprises the following raw materials in percentage by weight: 15-25% of butyl ester monomer, 20-28% of methyl ester monomer, 2-8% of styrene, 1-5% of functional acrylic monomer, 0.5-2% of emulsifier, 0.3-2% of neutralizer, 0.2-2% of chain transfer agent, 0.5-1% of initiator and 40-50% of pure water.
The butyl ester monomer is at least one of butyl methacrylate and butyl acrylate; the methyl ester monomer is at least one of methyl methacrylate and methyl acrylate. The functional acrylic monomer is at least one of acrylic acid, methacrylic acid, hydroxyethyl methacrylate, glycidyl methacrylate, lauryl methacrylate and isobornyl methacrylate. The emulsifier is at least one of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, alkylphenol polyoxyethylene, fatty alcohol polyoxyethylene ether and CO-436. The neutralizer is at least one of ammonia water, monoethanolamine, diethanolamine and N, N-dimethylethanolamine. The chain transfer agent is at least one of mercaptoethanol, thioglycolic acid and dodecyl mercaptan. The initiator is at least one of potassium persulfate, sodium persulfate, ammonium persulfate, di-tert-butyl peroxide, tert-butyl peroxybenzoate and tert-amyl peroxybenzoate.
The preparation of the aqueous acrylic resin was carried out by four examples within the ranges specified for the above components and the ratio of the components, and the aqueous acrylic resin prepared in the four examples was subjected to the corresponding index detection.
Example 1
A water-based acrylic resin capable of being used as both transfer printing and gloss oil comprises the following raw materials in percentage by weight: 18% of butyl ester monomer, 21% of methyl ester monomer, 2% of styrene, 5% of functional acrylic monomer, 1% of emulsifier, 1.5% of neutralizer, 0.5% of chain transfer agent, 1% of initiator and 50% of pure water.
Selecting butyl acrylate as the butyl ester monomer; methyl methacrylate is selected as the methyl ester monomer; the functional acrylic monomer is acrylic acid; the emulsifier is sodium dodecyl sulfate; selecting ammonia water as a neutralizing agent; the chain transfer agent is mercaptoethanol; the initiator is potassium persulfate.
The preparation of the water-based acrylic resin according to the components and the component proportion comprises the following steps:
s1, adding the lauryl sodium sulfate into an emulsifying kettle and a reaction kettle respectively according to the proportion of 7:3, adding pure water, and stirring to fully dissolve; s2, sequentially adding butyl acrylate, methyl methacrylate, acrylic acid, styrene and mercaptoethanol into the reaction kettle to emulsify for 30min under the stirring starting condition of the emulsification kettle to obtain monomer emulsion; s3, adding 1/3 monomer emulsion into a reaction kettle, adding 1/2 potassium persulfate, heating the reaction kettle to 75 ℃, and keeping the temperature for 1 h; s4, synchronously dripping the residual 2/3 monomer emulsion and the residual 1/2 potassium persulfate for 1 hour, and preserving the temperature at 85 ℃ for 1 hour; and S5, cooling to 37 ℃, adding ammonia water into the reaction materials, and adjusting the pH value to 7.0 to obtain the aqueous acrylic resin.
Example 2
The invention discloses a transferable and gloss-oil dual-purpose water-based acrylic resin, which comprises the following raw materials in percentage by weight: 15% of butyl ester monomer, 28% of methyl ester monomer, 8% of styrene, 5% of functional acrylic monomer, 0.5% of emulsifier, 0.3% of neutralizer, 0.2% of chain transfer agent, 1% of initiator and 42% of pure water.
Butyl ester monomers are butyl methacrylate; methyl methacrylate is selected as the methyl ester monomer; the functional acrylic monomer is isobornyl methacrylate; the emulsifier is sodium dodecyl sulfate; the neutralizer is N, N-dimethylethanolamine; the chain transfer agent is dodecyl mercaptan; the initiator is tert-amyl peroxybenzoate.
The preparation of the water-based acrylic resin according to the components and the component proportion comprises the following steps:
s1, adding the lauryl sodium sulfate into an emulsifying kettle and a reaction kettle respectively according to the proportion of 7:3, adding pure water, and stirring to fully dissolve; s2, sequentially adding butyl methacrylate, methyl methacrylate, isobornyl methacrylate, styrene and dodecyl mercaptan into the reaction kettle to emulsify for 40min under the stirring starting condition of the emulsification kettle to obtain monomer emulsion; s3, adding 1/3 monomer emulsion into a reaction kettle, adding 1/2 tert-amyl peroxybenzoate, heating the reaction kettle to 80 ℃, and preserving heat for 1.5 hours; s4, synchronously dropwise adding the residual 2/3 monomer emulsion and the residual 1/2 tert-amyl peroxybenzoate for 3 hours, and preserving the temperature at 90 ℃ for 1.5 hours; and S5, cooling to 38 ℃, adding N, N-dimethylethanolamine into the reaction material, and adjusting the pH to 7.5 to obtain the water-based acrylic resin.
Example 3
The invention discloses a transferable and gloss-oil dual-purpose water-based acrylic resin, which comprises the following raw materials in percentage by weight: 25% of butyl ester monomer, 20% of methyl ester monomer, 2% of styrene, 1% of functional acrylic monomer, 0.5% of emulsifier, 2% of neutralizer, 2% of chain transfer agent, 0.5% of initiator and 47% of pure water.
Butyl ester monomers are butyl methacrylate; methyl acrylate is selected as the methyl ester monomer; the functional acrylic monomer is methacrylic acid; the emulsifier is selected from CO-436; selecting monoethanolamine as a neutralizing agent; selecting mercaptoacetic acid as a chain transfer agent; the initiator is sodium persulfate.
The preparation of the water-based acrylic resin according to the components and the component proportion comprises the following steps:
s1, mixing CO-436 with the weight ratio of 7:3, respectively adding the mixture into an emulsifying kettle and a reaction kettle, adding pure water, and stirring for full dissolution; s2, sequentially adding butyl methacrylate, methyl acrylate, methacrylic acid, styrene and thioglycollic acid into the reaction kettle to emulsify for 35min under the stirring starting condition of the emulsification kettle to obtain monomer emulsion; s3, adding 1/3 monomer emulsion into a reaction kettle, adding 1/2 sodium persulfate, heating the reaction kettle to 76 ℃, and preserving heat for 1 h; s4, synchronously dripping the residual 2/3 monomer emulsion and the residual 1/2 sodium persulfate for 2.5 hours, and preserving the temperature at 90 ℃ for 1.5 hours; and S5, cooling to 39 ℃, adding monoethanolamine into the reaction material, and adjusting the pH to 7.2 to obtain the water-based acrylic resin.
Example 4
The invention discloses a transferable and gloss-oil dual-purpose water-based acrylic resin, which comprises the following raw materials in percentage by weight: 22% of butyl ester monomer, 20% of methyl ester monomer, 2% of styrene, 1% of functional acrylic monomer, 0.5% of emulsifier, 2% of neutralizer, 2% of chain transfer agent, 0.5% of initiator and 50% of pure water.
Selecting butyl acrylate as the butyl ester monomer; methyl acrylate is selected as the methyl ester monomer; the functional acrylic monomer is lauryl methacrylate; the emulsifier is alkylphenol ethoxylates; selecting diethanolamine as a neutralizing agent; selecting mercaptoacetic acid as a chain transfer agent; the initiator is ammonium persulfate.
The preparation of the water-based acrylic resin according to the components and the component proportion comprises the following steps:
s1, adding alkylphenol polyoxyethylene into an emulsifying kettle and a reaction kettle respectively according to the proportion of 7:3, adding pure water, and stirring to fully dissolve; s2, sequentially adding butyl acrylate, methyl acrylate, lauryl methacrylate, styrene and thioglycolic acid into the reaction kettle to emulsify for 40min under the stirring starting condition of the emulsification kettle to obtain monomer emulsion; s3, adding 1/3 monomer emulsion into a reaction kettle, adding 1/2 ammonium persulfate, heating the reaction kettle to 80 ℃, and preserving heat for 1.5 hours; s4, synchronously dripping the residual 2/3 monomer emulsion and the residual 1/2 ammonium persulfate for 3 hours, and preserving the temperature for 1 hour at 90 ℃; s5, cooling to 36 ℃, adding diethanolamine into the reaction material, and adjusting the pH value to 7.0 to obtain the water-based acrylic resin.
The aqueous acrylic resins obtained in examples 1 to 4 were subjected to performance tests, and the results were as follows
Table 1 shows:
as can be seen from Table 1, the water-based acrylic resin prepared by the invention has good color and luster, high gloss, adhesive force reaching 0 grade and moderate viscosity; meanwhile, the performances of other aspects can reach the standard.
It is to be understood that the described embodiments are merely a few embodiments of the invention, and not all embodiments. All other embodiments, which can be derived by one of ordinary skill in the art and related arts based on the embodiments of the present invention without any creative effort, shall fall within the protection scope of the present invention. Structures, devices, and methods of operation not specifically described or illustrated herein are generally practiced in the art without specific recitation or limitation.
Claims (9)
1. The water-based acrylic resin for transfering and polishing oil is characterized by comprising the following raw materials in percentage by weight: 15-25% of butyl ester monomer, 20-28% of methyl ester monomer, 2-8% of styrene, 1-5% of functional acrylic monomer, 0.5-2% of emulsifier, 0.3-2% of neutralizer, 0.2-2% of chain transfer agent, 0.5-1% of initiator and 40-50% of pure water.
2. The water-based acrylic resin capable of being transferred and used as gloss oil according to claim 1, which is characterized by comprising the following raw materials in percentage by weight: 18% of butyl ester monomer, 21% of methyl ester monomer, 2% of styrene, 5% of functional acrylic monomer, 1% of emulsifier, 1.5% of neutralizer, 0.5% of chain transfer agent, 1% of initiator and 50% of pure water.
3. The transferable and gloss-and-oil waterborne acrylic resin according to claim 1 or 2, wherein the butyl ester monomer is at least one of butyl methacrylate and butyl acrylate; the methyl ester monomer is at least one of methyl methacrylate and methyl acrylate.
4. The transferable and gloss-and-oil waterborne acrylic resin according to claim 1 or 2, wherein the functional acrylic monomer is at least one of acrylic acid, methacrylic acid, hydroxyethyl methacrylate, glycidyl methacrylate, lauryl methacrylate and isobornyl methacrylate.
5. The transferable and gloss-oil waterborne acrylic resin according to claim 1 or 2, wherein the emulsifier is at least one of sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, alkylphenol ethoxylates, fatty alcohol-polyoxyethylene ether and CO-436.
6. The transferable and gloss-and-oil waterborne acrylic resin according to claim 1 or 2, wherein the neutralizer is at least one of ammonia, monoethanolamine, diethanolamine and N, N-dimethylethanolamine.
7. The transferable gloss-oil waterborne acrylic resin of claim 1 or 2, wherein the chain transfer agent is at least one of mercaptoethanol, thioglycolic acid and dodecyl mercaptan.
8. The transferable, dual-purpose water-based acrylic resin as claimed in claim 1 or 2, wherein the initiator is at least one of potassium persulfate, sodium persulfate, ammonium persulfate, di-tert-butyl peroxide, tert-butyl peroxybenzoate and tert-amyl peroxybenzoate.
9. The method for preparing the transferable and gloss-and-oil waterborne acrylic resin according to any one of claims 1 to 8, which is characterized by comprising the following steps:
s1, adding the emulsifier into the emulsifying kettle and the reaction kettle respectively according to the proportion of 7:3, adding pure water, and stirring to fully dissolve;
s2, sequentially adding a butyl ester monomer, a methyl ester monomer, a functional acrylic monomer, styrene and a chain transfer agent into the reaction kettle to emulsify for 30-40min under the stirring starting condition of the emulsification kettle to obtain a monomer emulsion;
s3, adding 1/3 monomer emulsion into a reaction kettle, adding 1/2 initiator, heating the reaction kettle to 75-80 ℃, and preserving heat for 1-1.5 hours;
s4, synchronously dripping the residual 2/3 monomer emulsion and the residual 1/2 initiator for 2-3h, and preserving the heat at 85-90 ℃ for 1-1.5 h;
and S5, cooling to below 40 ℃, adding a neutralizing agent into the reaction material, and adjusting the pH value to 7.0-7.5 to obtain the water-based acrylic resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111371617.0A CN114149531B (en) | 2021-11-18 | 2021-11-18 | Dual-purpose water-based acrylic resin capable of being transferred and polished and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111371617.0A CN114149531B (en) | 2021-11-18 | 2021-11-18 | Dual-purpose water-based acrylic resin capable of being transferred and polished and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114149531A true CN114149531A (en) | 2022-03-08 |
| CN114149531B CN114149531B (en) | 2023-07-11 |
Family
ID=80457000
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111371617.0A Active CN114149531B (en) | 2021-11-18 | 2021-11-18 | Dual-purpose water-based acrylic resin capable of being transferred and polished and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114149531B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575476A (en) * | 2009-05-27 | 2009-11-11 | 彭文表 | Aqueous wear-resistant gloss oil and preparation method thereof |
| CN102816272A (en) * | 2012-08-31 | 2012-12-12 | 佛山市三水灏诚合成树脂有限公司 | White-gasoline-resistant styrene-acrylic emulsion, white-gasoline-resistant emulsion gloss oil and preparation methods thereof |
| CN104311728A (en) * | 2014-11-06 | 2015-01-28 | 佛山市三水鲸鲨化工有限公司 | Thermoplastic acrylic resin for water transfer printing, preparation method of thermoplastic acrylic resin and water transfer printing ink composition |
| CN109651550A (en) * | 2018-12-06 | 2019-04-19 | 成都杰晟蜀邦新材料科技有限公司 | A kind of fatty acid modified acrylic emulsion and preparation method thereof |
| CN111303336A (en) * | 2020-03-13 | 2020-06-19 | 广东鲸鲨化工有限公司 | Water transfer printing tearable film resin, preparation method thereof and water transfer printing tearable film composition |
-
2021
- 2021-11-18 CN CN202111371617.0A patent/CN114149531B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575476A (en) * | 2009-05-27 | 2009-11-11 | 彭文表 | Aqueous wear-resistant gloss oil and preparation method thereof |
| CN102816272A (en) * | 2012-08-31 | 2012-12-12 | 佛山市三水灏诚合成树脂有限公司 | White-gasoline-resistant styrene-acrylic emulsion, white-gasoline-resistant emulsion gloss oil and preparation methods thereof |
| CN104311728A (en) * | 2014-11-06 | 2015-01-28 | 佛山市三水鲸鲨化工有限公司 | Thermoplastic acrylic resin for water transfer printing, preparation method of thermoplastic acrylic resin and water transfer printing ink composition |
| CN109651550A (en) * | 2018-12-06 | 2019-04-19 | 成都杰晟蜀邦新材料科技有限公司 | A kind of fatty acid modified acrylic emulsion and preparation method thereof |
| CN111303336A (en) * | 2020-03-13 | 2020-06-19 | 广东鲸鲨化工有限公司 | Water transfer printing tearable film resin, preparation method thereof and water transfer printing tearable film composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114149531B (en) | 2023-07-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101597355B (en) | Water-based room temperature crosslinking acrylic acid emulsion and preparation method thereof | |
| JPS5989313A (en) | Tackifying alkylacrylamide-containing emulsion copolymer | |
| AU635490B2 (en) | Polymers comprising alkali-insoluble core/alkali-soluble shell and compositions thereof | |
| AU2008202389B2 (en) | Pigment dispersants, their production process, and their use | |
| US4421902A (en) | Alkyl, poly(oxyethylene) poly(carbonyloxyethylene) acrylate emulsion copolymers for thickening purposes | |
| CN109608575B (en) | Hydroxyl-containing polyacrylate secondary aqueous dispersion and preparation method thereof | |
| CN103304719A (en) | Acrylic emulsion and preparation method and application in waterborne polyvinyl chloride (PVC) wallpaper ink thereof | |
| CN101698690A (en) | Method for preparing water-soluble varnish polyacrylic emulsion by glue method | |
| JPS6227410A (en) | Three-dimensional structure resin particle, its production and coating composition | |
| CN102101947A (en) | Gloss oil of aqueous ink fountain for offset printing press and preparation method thereof | |
| CN112266677B (en) | Hydroxyl acrylic acid dispersoid and acrylic acid anticorrosive paint | |
| CN111620983A (en) | Acrylate emulsion for moisture-resistant rubbing water-based ink and preparation method thereof | |
| CN108570131B (en) | Preparation method of hybrid emulsion of epoxy ester resin aqueous dispersion and acrylic resin | |
| CN109438605B (en) | Water-soluble and water-dispersible hydroxy acrylic resin and preparation method and application thereof | |
| CN111423764A (en) | Quick-drying water-based ink and preparation method thereof | |
| CN114149531B (en) | Dual-purpose water-based acrylic resin capable of being transferred and polished and preparation method thereof | |
| MXPA05000385A (en) | Carboxylic acid-modified vinylic polymeric compositions. | |
| CN106467603A (en) | A kind of anionic dispersing agents and its preparation method and application | |
| CN109456442B (en) | Low-solvent room-temperature quick-drying type hydroxyl acrylic acid dispersion and preparation method thereof | |
| CN111116831B (en) | Preparation method of hydroxyl acrylic emulsion | |
| CN110885406B (en) | Preparation method of acrylic emulsion, acrylic emulsion and application thereof | |
| CN115304957B (en) | Water-based ink dispersoid and preparation method thereof | |
| MXPA05002194A (en) | Rosin-fatty acid vinylic polymer compositions. | |
| JP4756444B2 (en) | Tackifying resin emulsion, adhesive composition, and adhesive composition for flooring | |
| CN109021689A (en) | A kind of graphene for water-based ink is acrylic resin modified and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 512400 Pearl Industrial Park, Nanxiong, Shaoguan, Guangdong Applicant after: Guang Dong Dongdun New Material Technology Co.,Ltd. Address before: 512400 Pearl Industrial Park, Nanxiong, Shaoguan, Guangdong Applicant before: NANXIONG SEATON CHEMICALS LTD. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |