CN114134713B - Textile size with high adhesion performance and preparation method thereof - Google Patents
Textile size with high adhesion performance and preparation method thereof Download PDFInfo
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/72—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with metaphosphoric acids or their salts; with polyphosphoric acids or their salts; with perphosphoric acids or their salts
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
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- D—TEXTILES; PAPER
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2246—Esters of unsaturated carboxylic acids
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
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Abstract
The application belongs to the technical field of textile size, and particularly relates to textile size with high adhesion performance and a preparation method thereof, wherein the textile size comprises the following components in parts by weight: 20-30 parts of starch, 3-8 parts of acrylate monomer, 5-10 parts of acrylic monomer, 1-3 parts of sodium carbonate, 0.5-1.5 parts of sodium polyphosphate and 30-50 parts of water. This application adds a certain amount of acrylic acid thick liquids in starch thick liquids, can effectively improve the adhesion performance of thick liquids to the yarn, improves the film forming effect of sizing material simultaneously, obtains the better rete of compliance, improves the wearability that the yarn weaves the in-process, is difficult for fluffing, fracture etc. can effectively reduce the cost of weaving thick liquids simultaneously.
Description
Technical Field
The application belongs to the technical field of textile size, and particularly relates to textile size with high adhesion performance and a preparation method thereof.
Background
In the process of manufacturing the yarn into the fabric, the weaving machine can repeatedly perform mechanical actions such as stretching, bending and friction on the yarn, so that the yarn needs to be strong enough to bear the strength in the weaving process, and the problem that fluffing and even breaking occur in the manufacturing process to influence the quality of the grey fabric is avoided. The textile size is usually adopted to size the yarns to improve the strength and the toughness of the yarns, improve the wear resistance of the yarns, ensure the hairiness of the yarns to be more comfortable and improve the weavability of the yarns.
Textile size used in the domestic textile industry is currently mainly divided into three types, namely starch size, polyvinyl alcohol size and acrylic size. The starch size uses starch as the main component of the size, but the starch size has insufficient adhesion to yarn fibers due to a cyclic polyhydroxy structure in the starch, and the starch size has high hardness and brittleness, so that the starch needs to be modified to better meet the requirement of yarn sizing. The polyvinyl alcohol sizing agent can form a film layer with better performance on the surface of the yarn to improve the weaving performance of the yarn, but the main component polyvinyl alcohol of the polyvinyl alcohol sizing agent is difficult to explain in natural environment and is easy to cause environmental pollution. The acrylic sizing agent has good adhesion to the yarn, is easy to form a film, has good flexibility after film forming, is beneficial to yarn weaving, and is easy to biologically explain, more environment-friendly and higher in cost compared with polyvinyl alcohol.
In view of the above, there is a need to develop a textile size that is more environmentally friendly, has high adhesion to yarns, has good flexibility of film layers, and is low in cost.
Disclosure of Invention
In order to solve the problems, the application discloses a textile size with high adhesion performance and a preparation method thereof.
In a first aspect, the present application provides a textile size with high adhesion properties, using the following technical solution:
a textile size with high adhesion performance comprises the following components in parts by weight:
20-30 parts of starch
3-8 parts of acrylate monomer
5-10 parts of acrylic monomer
1-3 parts of sodium carbonate
Sodium polyphosphate 0.5-1.5 parts
30-50 parts of water.
A certain amount of acrylic acid sizing agent is added into the starch sizing agent, so that the adhesion performance of the sizing agent to the yarns can be effectively improved, the film forming effect of the sizing agent is improved, a film layer with better flexibility is obtained, the wear resistance of the yarns in the weaving process is improved, the yarns are not prone to fluffing, breaking and the like, and the cost of the textile sizing agent can be effectively reduced.
Preferably, the starch is a mixture of oxidized starch, hydroxyethyl starch and phosphate starch.
The starch is a mixture of oxidized starch, hydroxyethyl starch and phosphate starch according to a certain mass ratio, and is helpful for obtaining slurry with better viscosity and thermal stability.
Preferably, the mass ratio of the oxidized starch, the hydroxyethyl starch and the phosphate starch is 0.3-0.5.
Preferably, the acrylic ester monomer is one or more of methyl methacrylate, methyl acrylate, ethyl acrylate and butyl acrylate.
Preferably, the acrylic monomer is one or both of acrylic acid and methacrylic acid.
Preferably, the mass ratio of the sodium carbonate to the sodium polyphosphate is 1.5-2.
And simultaneously, sodium carbonate and sodium polyphosphate are added, so that the plant fiber yarn can be effectively swelled, the absorption effect of the yarn on slurry is improved, and the adhesion performance is improved. More sodium carbonate is beneficial to the better swelling effect of the yarn.
In a second aspect, the present application provides a method for preparing a textile size with high adhesion properties, using the following technical scheme:
a method for preparing textile size with high adhesive property comprises the following steps:
(1) Adding starch into partial water to obtain a starch solution, then respectively adding an acrylate monomer and an acrylic acid monomer, and uniformly stirring and mixing to obtain a solution A;
(2) Adding sodium carbonate and sodium polyphosphate into the rest water to obtain a solution B;
(3) And adding the solution B into the solution A, and uniformly mixing to obtain the textile size.
Preferably, the temperature of the solution during the preparation in the step (1) is controlled to be 35-45 ℃.
Preferably, the temperature in the step (3) is controlled to 50 to 60 ℃.
The application has the following beneficial effects:
(1) This application adds a certain amount of acrylic acid thick liquids in starch thick liquids, can effectively improve the adhesion properties of thick liquids to the yarn, improves the film forming effect of sizing material simultaneously, obtains the better rete of flexibility, improves the wearability that the yarn weaves the in-process, is difficult for fluffing, fracture etc. can effectively reduce the cost of weaving thick liquids simultaneously.
(2) The inventor of the application finds that sodium carbonate and sodium polyphosphate are added into the yarn sizing agent simultaneously, so that the plant fiber yarn can be effectively swelled, the absorption effect of the yarn on the sizing agent is improved, and the adhesion performance and the breaking strength of the sized yarn are improved.
(3) The starch used in the application is a mixture composed of oxidized starch, hydroxyethyl starch and phosphate starch according to a certain mass ratio, an acrylate monomer and an acrylic monomer are additionally added, the stability of the sizing agent can be effectively improved through the synergistic effect of the substances, and the sizing agent can be used for sizing yarns to help to obtain yarns with higher strength and better wear resistance.
Detailed Description
The present application will now be described in further detail with reference to examples.
Example 1
The components are as follows: 3.5 parts of oxidized starch, 5.5 parts of hydroxyethyl starch, 11 parts of phosphate starch, 2 parts of methyl methacrylate, 1 part of methyl acrylate, 2 parts of acrylic acid, 3 parts of methacrylic acid, 1 part of sodium carbonate, 0.5 part of sodium polyphosphate and 30 parts of water.
A method for preparing a textile size with high adhesion properties, comprising the steps of:
(1) Adding oxidized starch, hydroxyethyl starch and phosphate starch into four fifths of water at 35 ℃ to obtain a starch solution, then respectively adding methyl methacrylate, methyl acrylate, acrylic acid and methacrylic acid, and uniformly stirring and mixing to obtain a solution A;
(2) Adding sodium carbonate and sodium polyphosphate into the rest water to obtain a solution B;
(3) And adding the solution B into the solution A at 50 ℃, and uniformly mixing to obtain the textile size.
Example 2
The components are as follows: 6.5 parts of oxidized starch, 10.5 parts of hydroxyethyl starch, 13 parts of phosphate starch, 4 parts of ethyl acrylate, 4 parts of butyl acrylate, 5 parts of acrylic acid, 5 parts of methacrylic acid, 3 parts of sodium carbonate, 1.5 parts of sodium polyphosphate and 50 parts of water.
A method for preparing a textile size with high adhesion properties, comprising the steps of:
(1) Adding oxidized starch, hydroxyethyl starch and phosphate starch into four fifths of water at 45 ℃ to obtain a starch solution, then respectively adding ethyl acrylate, butyl acrylate, acrylic acid and methacrylic acid, and uniformly stirring and mixing to obtain a solution A;
(2) Adding sodium carbonate and sodium polyphosphate into the rest water to obtain a solution B;
(3) And adding the solution B into the solution A at 60 ℃, and uniformly mixing to obtain the textile size.
Example 3
The components are as follows: 5 parts of oxidized starch, 7.5 parts of hydroxyethyl starch, 12.5 parts of phosphate starch, 3 parts of methyl methacrylate, 3 parts of butyl acrylate, 3 parts of acrylic acid, 4 parts of methacrylic acid, 2 parts of sodium carbonate, 1 part of sodium polyphosphate and 40 parts of water.
A method for preparing a textile size with high adhesion properties, comprising the steps of:
(1) Adding oxidized starch, hydroxyethyl starch and phosphate starch into four fifths of water at 40 ℃ to obtain a starch solution, then respectively adding methyl methacrylate, butyl acrylate, acrylic acid and methacrylic acid, and uniformly stirring and mixing to obtain a solution A;
(2) Adding sodium carbonate and sodium polyphosphate into the rest water to obtain a solution B;
(3) And adding the solution B into the solution A at 55 ℃, and uniformly mixing to obtain the textile size.
Example 4
The components are as follows: 7.5 parts of oxidized starch, 7.5 parts of hydroxyethyl starch, 10 parts of phosphate starch, 3 parts of methyl methacrylate, 3 parts of butyl acrylate, 3 parts of acrylic acid, 4 parts of methacrylic acid, 2 parts of sodium carbonate, 1 part of sodium polyphosphate and 40 parts of water.
A method for preparing a textile size with high adhesion properties, comprising the steps of:
(1) Adding oxidized starch, hydroxyethyl starch and phosphate starch into four fifths of water at 40 ℃ to obtain a starch solution, then respectively adding methyl methacrylate, butyl acrylate, acrylic acid and methacrylic acid, and uniformly stirring and mixing to obtain a solution A;
(2) Adding sodium carbonate and sodium polyphosphate into the rest water to obtain a solution B;
(3) And adding the solution B into the solution A at 55 ℃, and uniformly mixing to obtain the textile size.
Example 5
The components are as follows: 7.5 parts of oxidized starch, 5 parts of hydroxyethyl starch, 12.5 parts of phosphate starch, 3 parts of methyl methacrylate, 3 parts of butyl acrylate, 3 parts of acrylic acid, 4 parts of methacrylic acid, 2 parts of sodium carbonate, 1 part of sodium polyphosphate and 40 parts of water.
A method for preparing a textile size with high adhesion properties, comprising the steps of:
(1) Adding oxidized starch, hydroxyethyl starch and phosphate starch into four fifths of water at 40 ℃ to obtain a starch solution, then respectively adding methyl methacrylate, butyl acrylate, acrylic acid and methacrylic acid, and uniformly stirring and mixing to obtain a solution A;
(2) Adding sodium carbonate and sodium polyphosphate into the rest water to obtain a solution B;
(3) And adding the solution B into the solution A at 55 ℃, and uniformly mixing to obtain the textile size.
Example 6
The components are as follows: 10 parts of hydroxyethyl starch, 15 parts of phosphate starch, 3 parts of methyl methacrylate, 3 parts of butyl acrylate, 3 parts of acrylic acid, 4 parts of methacrylic acid, 2 parts of sodium carbonate, 1 part of sodium polyphosphate and 40 parts of water.
A method for preparing a textile size with high adhesion properties, comprising the steps of:
(1) Adding hydroxyethyl starch and phosphate starch into four fifths of water at 40 ℃ to obtain a starch solution, then respectively adding methyl methacrylate, butyl acrylate, acrylic acid and methacrylic acid, and uniformly stirring and mixing to obtain a solution A;
(2) Adding sodium carbonate and sodium polyphosphate into the rest water to obtain a solution B;
(3) And adding the solution B into the solution A at 55 ℃, and uniformly mixing to obtain the textile size.
Example 7
The components are as follows: 10 parts of oxidized starch, 15 parts of phosphate starch, 3 parts of methyl methacrylate, 3 parts of butyl acrylate, 3 parts of acrylic acid, 4 parts of methacrylic acid, 2 parts of sodium carbonate, 1 part of sodium polyphosphate and 40 parts of water.
A method for preparing a textile size with high adhesion properties, comprising the steps of:
(1) Adding oxidized starch and phosphate starch into four fifths of water at 40 ℃ to obtain a starch solution, then respectively adding methyl methacrylate, butyl acrylate, acrylic acid and methacrylic acid, and uniformly stirring and mixing to obtain a solution A;
(2) Adding sodium carbonate and sodium polyphosphate into the rest water to obtain a solution B;
(3) And adding the solution B into the solution A at 55 ℃, and uniformly mixing to obtain the textile size.
Example 8
The components are as follows: 11 parts of oxidized starch, 14 parts of hydroxyethyl starch, 3 parts of methyl methacrylate, 3 parts of butyl acrylate, 3 parts of acrylic acid, 4 parts of methacrylic acid, 2 parts of sodium carbonate, 1 part of sodium polyphosphate and 40 parts of water.
A method for preparing a textile size with high adhesion properties, comprising the steps of:
(1) Adding oxidized starch and hydroxyethyl starch into four fifths of water at 40 ℃ to obtain a starch solution, then respectively adding methyl methacrylate, butyl acrylate, acrylic acid and methacrylic acid, and uniformly stirring and mixing to obtain a solution A;
(2) Adding sodium carbonate and sodium polyphosphate into the rest water to obtain a solution B;
(3) And adding the solution B into the solution A at 55 ℃, and uniformly mixing to obtain the textile size.
Comparative example 1
The components are as follows: 5 parts of oxidized starch, 7.5 parts of hydroxyethyl starch, 12.5 parts of phosphate starch, 3 parts of methyl methacrylate, 3 parts of butyl acrylate, 3 parts of acrylic acid, 4 parts of methacrylic acid, 3 parts of sodium polyphosphate and 40 parts of water.
A method for preparing a textile size with high adhesion properties, comprising the steps of:
(1) Adding oxidized starch, hydroxyethyl starch and phosphate starch into four fifths of water at 40 ℃ to obtain a starch solution, then respectively adding methyl methacrylate, butyl acrylate, acrylic acid and methacrylic acid, and uniformly stirring and mixing to obtain a solution A;
(2) Adding sodium polyphosphate into the rest water to obtain a solution B;
(3) And adding the solution B into the solution A at 55 ℃, and uniformly mixing to obtain the textile size.
Comparative example 2
The components are as follows: 5 parts of oxidized starch, 7.5 parts of hydroxyethyl starch, 12.5 parts of phosphate starch, 3 parts of methyl methacrylate, 3 parts of butyl acrylate, 3 parts of acrylic acid, 4 parts of methacrylic acid, 3 parts of sodium carbonate and 40 parts of water.
A method for preparing a textile size with high adhesion properties, comprising the steps of:
(1) Adding oxidized starch, hydroxyethyl starch and phosphate starch into four fifths of water at 40 ℃ to obtain a starch solution, then respectively adding methyl methacrylate, butyl acrylate, acrylic acid and methacrylic acid, and uniformly stirring and mixing to obtain a solution A;
(2) Adding sodium carbonate into the rest water to obtain solution B;
(3) And adding the solution B into the solution A at 55 ℃, and uniformly mixing to obtain the textile size.
Comparative example 3
The components are as follows: 6 parts of oxidized starch, 7.5 parts of hydroxyethyl starch, 12.5 parts of phosphate starch, 4 parts of methyl methacrylate, 3 parts of butyl acrylate, 4 parts of acrylic acid, 4 parts of methacrylic acid and 40 parts of water.
A method for preparing a textile size with high adhesion properties, comprising the steps of:
(1) Adding oxidized starch, hydroxyethyl starch and phosphate starch into water at 40 ℃ to obtain a starch solution, then respectively adding methyl methacrylate, butyl acrylate, acrylic acid and methacrylic acid, and uniformly stirring and mixing to obtain the textile size.
Comparative example 4
The components are as follows: 5 parts of oxidized starch, 7.5 parts of hydroxyethyl starch, 12.5 parts of phosphate starch, 3 parts of methyl methacrylate, 3 parts of butyl acrylate, 3 parts of acrylic acid, 4 parts of methacrylic acid, 1 part of sodium carbonate, 2 parts of sodium polyphosphate and 40 parts of water.
A method for preparing a textile size with high adhesion properties, comprising the steps of:
(1) Adding oxidized starch, hydroxyethyl starch and phosphate starch into four fifths of water at 40 ℃ to obtain a starch solution, then respectively adding methyl methacrylate, butyl acrylate, acrylic acid and methacrylic acid, and uniformly stirring and mixing to obtain a solution A;
(2) Adding sodium carbonate and sodium polyphosphate into the rest water to obtain a solution B;
(3) And adding the solution B into the solution A at 55 ℃, and uniformly mixing to obtain the textile size.
The textile pulps prepared in examples 1 to 8 and comparative examples 1 to 4 were subjected to performance tests, and the test results are shown in table 1.
TABLE 1
Test item | Viscosity thermal stability (%) | Adhesion to Cotton fibers (N) | Breaking Strength (N/mm) of slash 2 ) |
Example 1 | 96.3 | 50.2 | 63.7 |
Example 2 | 97.8 | 56.6 | 65.7 |
Example 3 | 97.3 | 54.4 | 65.1 |
Example 4 | 97.0 | 54.0 | 64.4 |
Example 5 | 96.8 | 54.3 | 64.8 |
Example 6 | 95.6 | 54.3 | 65.0 |
Example 7 | 95.8 | 54.4 | 64.7 |
Example 8 | 96.1 | 53.6 | 64.2 |
Comparative example 1 | 97.2 | 46.7 | 62.6 |
Comparative example 2 | 97.1 | 48.8 | 62.9 |
Comparative example 3 | 97.5 | 43.3 | 62.0 |
Comparative example 4 | 97.3 | 49.6 | 63.3 |
In table 1, viscosity thermal stability: stirring and heating the textile slurry to 95 ℃, firstly measuring the viscosity of the slurry when the temperature is kept for 1h, then measuring the viscosity of the slurry every 30min until 3h, measuring the viscosity of the slurry for five times in total, and calculating the thermal stability of the viscosity:
viscosity thermal stability (%) = 100-viscosity fluctuation ratio
Viscosity fluctuation ratio (%) = (max | η - η' |/η) × 100.
Wherein eta is the viscosity value of the slurry measured at the temperature of 95 ℃ for 1 h; max eta-eta' |/eta is the extreme difference of viscosity values measured five times at 95 ℃ for 1h and then every 30 min.
In table 1, breaking strength of slash: the slashing was first placed in a constant temperature and humidity cabinet 65% RH at 20 ℃ for 48h, and then the break strength of the slashing was tested on a single yarn strength meter.
As can be seen from Table 1, examples 1 to 8 of the present application were preparedThe viscosity thermal stability of the textile size is more than 95.6 percent, the adhesive force to cotton fiber is more than 50.2N, and the breaking strength of slashes prepared by the textile size of the embodiment 1-8 is 63.7N/mm 2 As described above, the textile size prepared in examples 1 to 8 of the present application has good thermal stability, good adhesion to cotton fiber, and high breaking strength of the prepared slashing.
As can be seen from comparative example 1, when sodium carbonate of example 3 was replaced with an equal weight part of sodium polyphosphate in comparative example 1, the adhesion of the prepared textile size to cotton fiber was significantly reduced, and the breaking strength of sized yarn was also reduced, which is probably because the swelling effect of sodium polyphosphate added alone to yarn was not as good as that of sodium carbonate and sodium polyphosphate added together, resulting in the failure of the size to better penetrate into yarn, affecting the absorption of the size by yarn, and thus affecting the adhesion and breaking strength.
As can be seen from comparative example 2, when sodium polyphosphate in example 3 was replaced with an equal weight part of sodium carbonate in comparative example 2, the adhesion of the prepared textile size to cotton fibers was significantly reduced and the breaking strength of slashed yarns was reduced, probably because the swelling effect of sodium carbonate alone to yarns was not as good as that of sodium carbonate and sodium polyphosphate simultaneously added, resulting in the failure of the size to penetrate into yarns well, affecting the absorption of the size by yarns, and thus affecting the adhesion and breaking strength.
It can be seen from comparative example 3 that, in comparative example 3, sodium carbonate and sodium polyphosphate are not added, but the sodium carbonate and the sodium polyphosphate are distributed into other substances in parts by weight, so that the adhesion of the prepared textile size to cotton fibers is remarkably reduced, the breaking strength of slashes is also remarkably reduced, and probably because the sodium carbonate and the sodium polyphosphate are not added, the textile size cannot be effectively swelled, the absorption of the size by yarns is reduced, the adhesion capability is reduced, and the size cannot be effectively infiltrated into the yarns, so that the breaking strength of the slashes is reduced.
It can be seen from comparative example 4 that when less sodium carbonate and more sodium polyphosphate were used in comparative example 4, the prepared textile size decreased in both the adhesion to cotton fibers and the breaking strength of slashing, indicating that relatively more sodium carbonate was advantageous in increasing the swelling effect of fibers and increasing the absorption of size, thereby improving the adhesion and breaking strength of slashing.
The present embodiment is merely illustrative, and not restrictive, and various changes and modifications may be made by persons skilled in the art without departing from the scope and spirit of the present invention. The technical scope of the present application is not limited to the content of the specification, and must be determined according to the scope of the claims.
Claims (6)
1. A textile size with high adhesion properties, characterized in that: the paint comprises the following components in parts by weight:
20-30 parts of starch
3-8 parts of acrylate monomer
5-10 parts of acrylic monomer
1-3 parts of sodium carbonate
0.5-1.5 parts of sodium polyphosphate
30-50 parts of water;
the starch is a mixture of oxidized starch, hydroxyethyl starch and phosphate starch; the mass ratio of the oxidized starch to the hydroxyethyl starch to the phosphate starch is 0.3-0.5;
the mass ratio of the sodium carbonate to the sodium polyphosphate is 1.5-2.
2. Textile size with high adhesion properties according to claim 1, characterized in that: the acrylate monomer is one or more of methyl methacrylate, methyl acrylate, ethyl acrylate and butyl acrylate.
3. Textile size with high adhesion properties according to claim 1, characterized in that: the acrylic monomer is one or two of acrylic acid and methacrylic acid.
4. A process for preparing a textile size with high adhesion properties according to claim 1, characterized in that: the method comprises the following steps:
(1) Adding starch into partial water to obtain a starch solution, then respectively adding an acrylate monomer and an acrylic acid monomer, and uniformly stirring and mixing to obtain a solution A;
(2) Adding sodium carbonate and sodium polyphosphate into the rest water to obtain a solution B;
(3) And adding the solution B into the solution A, and uniformly mixing to obtain the textile size.
5. A process for preparing a textile size with high adhesion properties according to claim 4, characterized in that: the temperature of the solution in the preparation process of the step (1) is controlled to be 35-45 ℃.
6. A process for preparing a textile size with high adhesion properties according to claim 4, characterized in that: the temperature in the step (3) is controlled to be 50-60 ℃.
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CN105113242A (en) * | 2015-09-11 | 2015-12-02 | 无锡市长安曙光手套厂 | Textile auxiliary used for textile sizing and preparing method thereof |
CN106480728A (en) * | 2016-11-17 | 2017-03-08 | 过冬 | A kind of spinning sizing agent and preparation method thereof |
CN106758224A (en) * | 2016-12-19 | 2017-05-31 | 长兴荣煜纺织科技有限公司 | A kind of composite spinning sizing agent and preparation method thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN105113242A (en) * | 2015-09-11 | 2015-12-02 | 无锡市长安曙光手套厂 | Textile auxiliary used for textile sizing and preparing method thereof |
CN106480728A (en) * | 2016-11-17 | 2017-03-08 | 过冬 | A kind of spinning sizing agent and preparation method thereof |
CN106758224A (en) * | 2016-12-19 | 2017-05-31 | 长兴荣煜纺织科技有限公司 | A kind of composite spinning sizing agent and preparation method thereof |
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