CN114122461A - Activation method for fuel cell - Google Patents

Activation method for fuel cell Download PDF

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Publication number
CN114122461A
CN114122461A CN202010897806.0A CN202010897806A CN114122461A CN 114122461 A CN114122461 A CN 114122461A CN 202010897806 A CN202010897806 A CN 202010897806A CN 114122461 A CN114122461 A CN 114122461A
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China
Prior art keywords
pressure
cathode
fuel cell
inlet
anode
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CN202010897806.0A
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CN114122461B (en
Inventor
侯晓玲
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Weishi Energy Technology Co Ltd
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Weishi Energy Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1004Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The invention discloses an activation method of a fuel cell, wherein an anode plate and a cathode plate of the fuel cell are separated by a membrane electrode assembly, an anode inlet and a cathode outlet are positioned at a first end of the membrane electrode assembly, and an anode outlet and a cathode inlet are positioned at a second end of the membrane electrode assembly, and the activation method comprises the following steps: acquiring a first end pressure difference; if the first end pressure differential exceeds a threshold, the cathode inlet pressure is raised to reduce the first end pressure differential. Therefore, the membrane electrode assembly can be prevented from being directly acted on by a large pressure difference, the mechanical property damage of the membrane electrode assembly is avoided, the aging speed of the membrane electrode assembly is slowed down, the service lives of the membrane electrode assembly and the fuel cell are prolonged, the hydraulic diameter of the cathode side is prevented from being extruded by the membrane electrode assembly, the change of the hydraulic diameter of the cathode side is avoided, the drainage characteristic of the cathode side is kept stable, the drainage effect of the cathode side is improved, the water flooding phenomenon of the cathode side is avoided, and the working stability of the fuel cell is improved.

Description

Activation method for fuel cell
Technical Field
The invention relates to the technical field of fuel cells, in particular to an activation method of a fuel cell.
Background
Before a fuel cell is put into practical use, it is necessary to perform an activation test on a Membrane Electrode Assembly (MEA), remove residual impurities introduced during the manufacturing process of the MEA and the fuel cell stack, activate reaction sites of catalyst metals that cannot participate in the reaction, ensure a transfer path of reactants to the catalyst, and ensure a transfer path of hydrogen ions by sufficiently hydrating an electrolyte contained in an electrolyte membrane and electrodes.
In the related art, during the activation process of the fuel cell, the inlet pressures of the cathode plate and the anode plate are kept at fixed values, and as the current density rises, the gas flow continuously rises, which causes a pressure drop between the inlet and the outlet of the gas. Especially, when the gas flow directions of the cathode plate and the anode plate of the fuel cell are opposite, a large pressure difference is formed between the two sides of the membrane electrode assembly at the anode inlet and the cathode outlet, and the mechanical performance of the membrane electrode assembly is damaged due to the generation of the pressure difference. When the differential pressure exceeds the bearing capacity of the membrane electrode assembly, the aging of the membrane electrode assembly is accelerated, even the rupture of the membrane electrode assembly can cause the damage of a cell stack, and the overlarge differential pressure on the two sides of the membrane electrode assembly can cause the hydraulic diameter of a cathode side distribution area of a fuel cell to be reduced, thereby generating a water flooding phenomenon.
Disclosure of Invention
The present invention is directed to solving at least one of the problems of the prior art. To this end, an object of the present invention is to provide an activation method of a fuel cell, which can reduce the pressure difference across a membrane electrode assembly, prevent the membrane electrode assembly from aging and even cracking, and improve the drainage performance of the cathode side of the fuel cell during activation.
According to an embodiment of the first aspect of the present application, a method of activating a fuel cell having an anode plate and a cathode plate spaced apart by a membrane electrode assembly, an anode inlet and a cathode outlet at a first end of the membrane electrode assembly, and an anode outlet and a cathode inlet at a second end of the membrane electrode assembly, comprises: acquiring a first end pressure difference; raising the cathode inlet pressure to lower the first end pressure differential if the first end pressure differential exceeds a threshold.
According to the activation method of the fuel cell, the first end pressure difference is obtained in real time, when the pressure difference exceeds the threshold value, the movement amplitude of the membrane electrode assembly towards the cathode side is reduced by raising the pressure of the cathode inlet, so that the phenomenon that a larger pressure difference is directly applied to the membrane electrode assembly is avoided, the mechanical property damage of the membrane electrode assembly is avoided, the aging speed of the membrane electrode assembly is reduced, the service lives of the membrane electrode assembly and the fuel cell are prolonged, the phenomenon that the hydraulic diameter of the cathode side is extruded by the membrane electrode assembly is avoided, the hydraulic diameter of the cathode side is prevented from changing, the drainage characteristic of the cathode side is kept stable, the drainage effect of the cathode side is improved, the phenomenon that the cathode side is flooded with water is avoided, and the working stability of the activated fuel cell is improved.
According to some embodiments of the present application, the cathode inlet pressure is raised while the anode inlet pressure is raised.
In some embodiments, the anode inlet pressure is greater than the cathode inlet pressure.
According to some embodiments of the application, further comprising: and acquiring the current density of the fuel cell, and setting an initial anode inlet pressure and an initial cathode inlet pressure according to the current density.
In some embodiments, if the fuel cell is in a high electrical density condition, setting the initial anode inlet pressure and the initial cathode inlet pressure to a high pressure; setting an initial anode inlet pressure and an initial cathode inlet pressure to a low pressure if the fuel cell is in a low electrical density condition.
Further, the acquiring a first end pressure difference includes: acquiring the initial anode inlet pressure and acquiring the anode outlet pressure; acquiring the initial cathode inlet pressure and acquiring the cathode outlet pressure; the initial anode inlet pressure-cathode outlet pressure is the first end pressure differential.
Optionally, the cathode outlet pressure is an initial cathode inlet pressure-cathode pressure drop and the anode outlet pressure is an initial anode inlet pressure-anode pressure drop.
According to some embodiments of the application, further comprising: continuing to acquire the first end pressure difference.
In some embodiments, the minimum activation voltage during activation of the fuel cell is 0.2 v.
Further, the cathode inlet pressure is less than the anode outlet pressure.
Additional aspects and advantages of the invention will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the invention.
Drawings
The above and/or additional aspects and advantages of the present invention will become apparent and readily appreciated from the following description of the embodiments, taken in conjunction with the accompanying drawings of which:
FIG. 1 is a schematic diagram of membrane electrode assembly displacement during fuel cell activation according to an embodiment of the present application;
fig. 2 is a schematic view of the displacement of a membrane electrode assembly during activation of a prior art fuel cell.
Reference numerals:
membrane electrode assembly 10, anode inlet 20, anode outlet 30, cathode inlet 40, cathode outlet 50.
Detailed Description
Reference will now be made in detail to embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein like or similar reference numerals refer to the same or similar elements or elements having the same or similar function throughout. The embodiments described below with reference to the accompanying drawings are illustrative only for the purpose of explaining the present invention, and are not to be construed as limiting the present invention.
First, as shown in fig. 2, in the prior art, during the activation of the fuel cell, the pressure of the cathode inlet 40 and the anode inlet 20 is kept constant, and as the current density increases, the gas flow rate continuously increases, which causes a pressure drop between the anode inlet 20 and the anode outlet 30, and a pressure drop between the cathode inlet 40 and the cathode outlet 50.
Resulting in a large pressure difference between the anode inlet 20 and the cathode outlet 50, which may cause the mea 10 to move toward the cathode side (see the dotted line portion of fig. 2), causing damage to the mechanical properties of the mea, and when the pressure difference exceeds the endurance capacity of the mea 10, aging of the mea 10 may be accelerated, or even rupture of the mea 10 may be caused, thereby causing damage to the stack.
Meanwhile, the pressure drop generation between the anode inlet 20 and the anode outlet 30 and the pressure drop generation between the cathode inlet 40 and the cathode outlet 50 are all related to the gas flow rate, the pressure and the hydraulic diameter (a path for discharging the working product of the fuel cell), and under the same pressure, the larger the flow rate is, the larger the pressure drop is, and under the same flow rate, the larger the pressure drop is, and the larger the hydraulic diameter is, the smaller the pressure drop is.
Therefore, in the activation process of the existing fuel cell (stack), when the current density is low, the flow rate is reduced due to the excessively high voltage, so that a flooding phenomenon (that is, the working product of the fuel cell cannot be discharged in time and is accumulated on the cathode side) occurs inside the fuel cell, and further, when the current density is high, the cathode pressure drop is increased, so that the pressure difference between the two sides of the end part of the membrane electrode assembly 10 is further increased, the hydraulic diameter is reduced, and the flooding phenomenon is further worsened.
An activation method of a fuel cell according to an embodiment of the invention is described below with reference to fig. 1 to 2.
As shown in fig. 1, according to the activation method of the fuel cell according to the embodiment of the first aspect of the present application, the anode plate and the cathode plate of the fuel cell are spaced apart by the membrane electrode assembly, the anode inlet 20 and the cathode outlet 50 are located at the first end of the membrane electrode assembly, and the anode outlet 30 and the cathode inlet 40 are located at the second end of the membrane electrode assembly.
Wherein the activation method comprises the following steps: acquiring a first end pressure difference; if the first end pressure differential exceeds the threshold, the cathode inlet 40 pressure is raised to reduce the first end pressure differential.
It is understood that the threshold represents a threshold for pressure differential, and that different fuel cell sizes and sizes may be set appropriately by those skilled in the art in practicing the method of the present application,
specifically, in the activation method of the fuel cell of the present application, first, a pressure difference of a first section where the anode inlet 20 and the cathode outlet 50 are located is obtained, and when the pressure difference exceeds a first threshold, it is determined that the membrane electrode assembly 10 will move toward the cathode side under the action of the pressure difference, and the pressure of the cathode inlet 40 is raised, as described above, as the pressure of the cathode inlet 40 is raised, the pressure drop between the cathode inlet 40 and the cathode outlet 50 is reduced, so that the pressure of the cathode outlet 50 is higher by raising the pressure of the cathode inlet 40, and it is ensured that the pressure difference between the anode inlet 20 and the cathode outlet 50 is within the threshold, so as to effectively reduce the displacement amount of the membrane electrode assembly 10 toward the cathode side.
According to the activation method of the fuel cell, the pressure difference of the first end is obtained in real time, when the pressure difference exceeds the threshold value, the pressure of the cathode inlet 40 is raised, so that the movement amplitude of the membrane electrode assembly 10 towards the cathode side is reduced, a large pressure difference can be prevented from being directly applied to the membrane electrode assembly 10, the membrane electrode assembly 10 is prevented from being damaged in mechanical performance, the aging speed of the membrane electrode assembly 10 is reduced, the service lives of the membrane electrode assembly 10 and the fuel cell are prolonged, the hydraulic diameter of the cathode side is prevented from being extruded by the membrane electrode assembly 10, the hydraulic diameter of the cathode side is prevented from being changed, the drainage characteristic of the cathode side is kept stable, the drainage effect of the cathode side is improved, the water logging phenomenon of the cathode side is avoided, and the working stability of the activated fuel cell is improved.
It should be noted that, if the fuel cell is flooded, the fuel cell may need to be shut down urgently, so that the membrane electrode assembly 10 has an open circuit point, and the life of the membrane electrode assembly 10 is reduced.
According to some embodiments of the present application, raising the cathode inlet 40 pressure while raising the anode inlet 20 pressure ensures that the anode inlet 20 pressure is greater than the cathode inlet 40 pressure.
It should be noted that when the cathode inlet 40 pressure is raised, it may cause the cathode inlet 40 pressure to be higher than the anode inlet 20 pressure, which may cause the gas on the cathode side to diffuse to the anode side, resulting in a hydrogen-air interface on the anode side, causing the opposite pole or membrane electrode assembly to degrade.
Further, the anode inlet 20 is raised while the pressure of the cathode inlet 40 is raised, and it is ensured that the pressure of the anode inlet 20 is greater than the pressure of the cathode inlet 40 to prevent the gas diffusion phenomenon from occurring at the anode side, thereby improving the operation stability of the fuel cell.
According to some embodiments of the application, the activation method further comprises: the current density of the fuel cell is obtained, and an initial anode inlet pressure and an initial cathode inlet pressure are set according to the current density.
Specifically, if the fuel cell is in a high electrical density condition, the initial anode inlet pressure and the initial cathode inlet pressure are set to high pressures; if the fuel cell is in a low electrical density condition, the initial anode inlet pressure and the initial cathode inlet pressure are set to low pressures. This makes the pressures at the anode inlet 20, the anode outlet 30, the cathode inlet 40, and the cathode outlet 50 more reasonable, and improves the activation efficiency and the activation level.
It is understood that acquiring the first end pressure differential includes: obtaining an initial anode inlet pressure, and obtaining an anode outlet 30 pressure; obtaining an initial cathode inlet pressure, and obtaining a cathode outlet 50 pressure; initial anode inlet pressure-cathode outlet 50 pressure-the first end pressure differential.
Where the cathode outlet 50 pressure is the initial cathode inlet pressure-cathode drop and the anode outlet 30 pressure is the initial anode inlet pressure-anode drop. Thus, the activation method of the application can obtain the pressure of the cathode outlet 50, the pressure of the anode inlet 20 and the pressure difference between the cathode outlet 50 and the anode inlet 20 more accurately in the activation process of the fuel cell, and can improve the accuracy of pressure regulation of the cathode inlet 40 and the anode inlet 20, thereby improving the activation stability.
According to some embodiments of the application, further comprising: the first end pressure differential continues to be acquired. That is, after adjusting the cathode inlet 40 and anode inlet 20 pressures, the first end pressure differential continues to be acquired, and when the first end pressure differential again exceeds the threshold, the cathode inlet 40 pressure and anode inlet 20 pressure are further adjusted.
In some embodiments, the minimum activation voltage during activation of the fuel cell is 0.2 v. Thereby, the activation efficiency can be accelerated to improve the activation efficiency of the fuel cell.
Further, the cathode inlet 40 pressure is less than the anode outlet 30 pressure.
Next, the activation method of the fuel cell of the present application will be explained with a specific example.
When the pressure at the anode inlet 20 is set to 210kPaa and the anode plate has the highest flow rate at the electric density of 2.0A/cm2, the pressure drop of the anode is 10kPa, and the pressure at the anode outlet 30 is 200 kPaa;
setting the pressure at the cathode inlet 40 to 200kPa, the pressure drop at the cathode plate to 100kPaa, and the pressure at the cathode outlet 50 to 100kPaa, where the pressure difference at the anode inlet 20 of the MEA is 210-100 kPa, which is much higher than the working pressure of the general MEA.
Further, the cathode inlet 40 pressure is raised, the pressure drop is reduced with the pressure rise, the cathode inlet 40 pressure is raised to 250kPaa, the cathode pressure drop is reduced from 100kPa to 50kPa, the cathode outlet 50 pressure is 200kPaa, the anode inlet 20 pressure is raised to 260kPa, and the anode outlet 30 pressure is not lower than 250 kPaa.
At this time, the pressure at the anode inlet 20 to the cathode outlet 50 is 60kPaa smaller than the initial 110kPaa, and the displacement width of the membrane electrode assembly 10 toward the cathode side can be reduced, thereby reducing the pressure difference between both sides of the membrane electrode assembly 10 and improving the drainage characteristics.
Based on the above, in the activation process of the fuel cell, the pressure setting is related to the current density, the low electricity density maintains the low voltage, the flooding caused by insufficient flow rate is improved, the high electricity density sets the high voltage, and the inlet pressures of the cathode plate and the anode plate are raised according to the pressure drop, so that the hydraulic diameter deformation is reduced, the deformation of the membrane electrode assembly 10 is reduced, the flooding problem caused by overlarge pressure drop is improved, and the activation process is smoothly carried out.
In the description of the present invention, it is to be understood that the terms "central," "longitudinal," "lateral," "length," "width," "thickness," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," "clockwise," "counterclockwise," "axial," "radial," "circumferential," and the like are used in the orientations and positional relationships indicated in the drawings for convenience in describing the invention and to simplify the description, and are not intended to indicate or imply that the referenced device or element must have a particular orientation, be constructed and operated in a particular orientation, and are not to be considered limiting of the invention.
In the description of the present invention, "the first feature" and "the second feature" may include one or more of the features.
In the description of the present invention, "a plurality" means two or more.
In the description of the present invention, the first feature being "on" or "under" the second feature may include the first and second features being in direct contact, and may also include the first and second features being in contact with each other not directly but through another feature therebetween.
In the description of the invention, "above", "over" and "above" a first feature in a second feature includes the first feature being directly above and obliquely above the second feature, or simply means that the first feature is higher in level than the second feature.
In the description herein, references to the description of the term "one embodiment," "some embodiments," "an illustrative embodiment," "an example," "a specific example," or "some examples" or the like mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
While embodiments of the invention have been shown and described, it will be understood by those of ordinary skill in the art that: various changes, modifications, substitutions and alterations can be made to the embodiments without departing from the principles and spirit of the invention, the scope of which is defined by the claims and their equivalents.

Claims (10)

1. A method of activating a fuel cell having anode and cathode plates spaced apart by a membrane electrode assembly, an anode inlet (20) and a cathode outlet (50) at a first end of the membrane electrode assembly, and an anode outlet (30) and a cathode inlet (40) at a second end of the membrane electrode assembly, the method comprising:
acquiring a first end pressure difference;
if the first end pressure differential exceeds a threshold, the cathode inlet (40) pressure is raised to reduce the first end pressure differential.
2. The activation method for a fuel cell according to claim 1, wherein the pressure at the cathode inlet (40) is raised while the pressure at the anode inlet (20) is raised.
3. The activation method for a fuel cell according to claim 2, wherein the anode inlet (20) pressure is greater than the cathode inlet (40) pressure.
4. The activation method for a fuel cell according to claim 1, further comprising: and acquiring the current density of the fuel cell, and setting an initial anode inlet pressure and an initial cathode inlet pressure according to the current density.
5. The activation method for a fuel cell according to claim 4, wherein if the fuel cell is under a high electrical density condition, an initial anode inlet pressure and an initial cathode inlet pressure are set to a high pressure; setting an initial anode inlet pressure and an initial cathode inlet pressure to a low pressure if the fuel cell is in a low electrical density condition.
6. The activation method for a fuel cell according to claim 5, wherein said acquiring the first end pressure difference includes:
obtaining the initial anode inlet pressure, obtaining an anode outlet (30) pressure;
obtaining the initial cathode inlet pressure, obtaining a cathode outlet (50) pressure;
the initial anode inlet pressure-cathode outlet (50) pressure-first end pressure differential.
7. The activation method for a fuel cell according to claim 6, wherein the cathode outlet (50) pressure is an initial cathode inlet pressure-cathode fall pressure, and the anode outlet (30) pressure is an initial anode inlet pressure-anode fall pressure.
8. The activation method for a fuel cell according to claim 1, further comprising: continuing to acquire the first end pressure difference.
9. The activation method for a fuel cell according to claim 1, wherein the minimum activation voltage during activation of the fuel cell is 0.2 v.
10. The activation method for a fuel cell according to any one of claims 1 to 9, wherein the cathode inlet (40) pressure is smaller than the anode outlet (30) pressure.
CN202010897806.0A 2020-08-31 2020-08-31 Method for activating fuel cell Active CN114122461B (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020022161A1 (en) * 2000-07-25 2002-02-21 Honda Giken Kogyo Kabushiki Kaisha Fuel cell system and process for controlling the same
JP2005150090A (en) * 2003-10-24 2005-06-09 Toyota Motor Corp Fuel cell system
JP2006147336A (en) * 2004-11-19 2006-06-08 Nissan Motor Co Ltd Fuel cell system
JP2009140672A (en) * 2007-12-05 2009-06-25 Honda Motor Co Ltd Fuel cell
JP2009181964A (en) * 2009-05-18 2009-08-13 Toyota Motor Corp Fuel cell system
US20100310957A1 (en) * 2009-06-05 2010-12-09 Honda Motor Co., Ltd. Fuel cell
KR20130083278A (en) * 2012-01-12 2013-07-22 지에스칼텍스 주식회사 Membrane electrode assembly for fuel cell
US20190131635A1 (en) * 2017-10-30 2019-05-02 Hyundai Motor Company Cell Frame for Fuel Cell and Fuel Cell Stack Using the Same

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020022161A1 (en) * 2000-07-25 2002-02-21 Honda Giken Kogyo Kabushiki Kaisha Fuel cell system and process for controlling the same
JP2005150090A (en) * 2003-10-24 2005-06-09 Toyota Motor Corp Fuel cell system
JP2006147336A (en) * 2004-11-19 2006-06-08 Nissan Motor Co Ltd Fuel cell system
JP2009140672A (en) * 2007-12-05 2009-06-25 Honda Motor Co Ltd Fuel cell
JP2009181964A (en) * 2009-05-18 2009-08-13 Toyota Motor Corp Fuel cell system
US20100310957A1 (en) * 2009-06-05 2010-12-09 Honda Motor Co., Ltd. Fuel cell
KR20130083278A (en) * 2012-01-12 2013-07-22 지에스칼텍스 주식회사 Membrane electrode assembly for fuel cell
US20190131635A1 (en) * 2017-10-30 2019-05-02 Hyundai Motor Company Cell Frame for Fuel Cell and Fuel Cell Stack Using the Same

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