CN114113526A - Intelligent water plant carbon-containing ion detection system and detection method thereof - Google Patents
Intelligent water plant carbon-containing ion detection system and detection method thereof Download PDFInfo
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- CN114113526A CN114113526A CN202111435143.1A CN202111435143A CN114113526A CN 114113526 A CN114113526 A CN 114113526A CN 202111435143 A CN202111435143 A CN 202111435143A CN 114113526 A CN114113526 A CN 114113526A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 135
- 238000001514 detection method Methods 0.000 title claims abstract description 71
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 44
- 238000005070 sampling Methods 0.000 claims abstract description 42
- 230000006698 induction Effects 0.000 claims description 37
- 230000009471 action Effects 0.000 claims description 30
- 239000008399 tap water Substances 0.000 claims description 30
- 235000020679 tap water Nutrition 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 29
- 239000002184 metal Substances 0.000 claims description 28
- 238000007789 sealing Methods 0.000 claims description 26
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- 241000196324 Embryophyta Species 0.000 claims description 22
- 150000002500 ions Chemical class 0.000 claims description 22
- 238000007667 floating Methods 0.000 claims description 21
- -1 carbon ion Chemical class 0.000 claims description 20
- 230000001939 inductive effect Effects 0.000 claims description 20
- 230000001681 protective effect Effects 0.000 claims description 20
- 229920000742 Cotton Polymers 0.000 claims description 15
- 239000012528 membrane Substances 0.000 claims description 15
- 230000005389 magnetism Effects 0.000 claims description 12
- 238000000746 purification Methods 0.000 claims description 10
- 244000208734 Pisonia aculeata Species 0.000 claims description 8
- 238000009434 installation Methods 0.000 claims description 8
- 230000002940 repellent Effects 0.000 claims description 7
- 239000005871 repellent Substances 0.000 claims description 7
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- 238000005259 measurement Methods 0.000 claims description 4
- 244000005700 microbiome Species 0.000 claims description 4
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- 235000013619 trace mineral Nutrition 0.000 claims description 4
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- 238000004891 communication Methods 0.000 claims description 3
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- 238000010586 diagram Methods 0.000 description 4
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- 238000005516 engineering process Methods 0.000 description 2
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- 238000012545 processing Methods 0.000 description 2
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- 206010063385 Intellectualisation Diseases 0.000 description 1
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/18—Water
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/10—Devices for withdrawing samples in the liquid or fluent state
- G01N1/14—Suction devices, e.g. pumps; Ejector devices
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/28—Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
- G01N1/34—Purifying; Cleaning
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/18—Water
- G01N33/182—Specific anions in water
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Abstract
The invention relates to the technical field of water quality detection of water plants and discloses a carbon-containing ion detection system of a smart water plant and a detection method thereof. Through the use of mutually supporting to kickboard, annular gasbag and end of sinking can guarantee that detecting system is in stable state all the time, make it float on the surface of water, and end of sinking can make wholly be in under the state of not rocking moreover, under the showy of annular gasbag and end of sinking, detecting system can carry out water sampling operation in arbitrary place on the surface of water, and so can be all-round, carries out carbon ion detection at many levels, and then has guaranteed the accuracy of detected data.
Description
Technical Field
The invention relates to the technical field of water quality detection of water plants, in particular to a carbon-containing ion detection system and a detection method for an intelligent water plant.
Background
The intelligent water plant fully explores data value and logic relation through the deep fusion of a new generation of information technology and a water affair technology, realizes the control intellectualization, the data reclamation, the management accuracy and the decision intelligence of a water affair service system, ensures the safe operation of water affair facilities, and ensures that the water affair service is more efficient in operation, more scientific in management and higher in service quality.
The quality of water is seriously influenced by the content of carbon ions in water, the carbanions in organic matters are generally unstable, the detection difficulty of the carbon ions in tap water is high, the ions are not uniformly distributed in the tap water, and in addition, the water in a tap water sedimentation tank ceaselessly overturns, so that the sampled water intelligently represents the condition of a specified point, in addition, the number of the sedimentation tanks of a tap water plant is high, the sampling difficulty is high during detection, and the sample detection time is long.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides an intelligent water plant carbon-containing ion detection system, which solves the problems in the background art.
(II) technical scheme
In order to achieve the purpose, the invention provides the following technical scheme: a carbon-containing ion detection system of a smart water plant comprises a control end, wherein an input end of the control end is provided with an internet data line, a plurality of branches of the internet data line are provided with a positioning device and an information feedback device, the tail ends of a plurality of branches of the internet data line are provided with a detection system and a buoy detection system, the buoy detection system comprises a floating system, a detection system, a sinking end and a sampling system, the top of the floating system is fixedly connected with the detection system, the bottom of the detection system is fixedly connected with the sinking end, the sampling system is fixedly connected with the bottom of the detection system, the sampling system penetrates through the sinking end, the detection system comprises a waterproof shell, the top of the inner wall of the waterproof shell is fixedly connected with a purification sleeve, the bottom of the purification sleeve penetrates through two connection hoses, and the top ends of the connection hoses are communicated with a water outlet pipe, the outlet pipe surface is provided with the apopore, the cover is equipped with the cotton layer of PP on the outlet pipe, the cover is equipped with the activated carbon layer on the cotton layer of PP, the annular hollow cover is established to the annular mounting inslot cover that the bottom of purifying the cover was seted up, the bottom of annular hollow cover is provided with the multilayer filter membrane and divides the filter sleeve, the left and right sides that the filter sleeve was divided to the multilayer filter membrane all communicates there is the acid-base detector, the top intercommunication of acid-base detector has the ionization head, the top intercommunication of ionization head has ionization device, the bottom of acid-base detector is provided with the feedback ware, both sides are all overlapped and are equipped with the filter screen about the annular hollow cover inner chamber.
As a further scheme of the invention: the floating system comprises a floating plate, the top of the floating plate is fixedly connected with an annular air bag, a bearing plate is sleeved in the floating plate, a circular groove is formed in the axis of the bearing plate, and the detection system is sleeved in the circular groove.
As a still further scheme of the invention: the sampling system comprises an underwater sealing pipe, the top end of the underwater sealing pipe is sleeved in a through hole formed in the bottom of the waterproof shell, the top of the underwater sealing pipe is fixedly connected with a protective cover, the top of the protective cover is provided with a booster pump, a gas pipe of the booster pump is arranged in the protective cover, three inductive switches are arranged on the left side and the right side of the inner wall of the underwater sealing pipe, a sliding plug is sleeved in the underwater sealing pipe, a ring plug is sleeved on the sliding plug, two vertical grooves are formed in the ring plug, a one-way plate is movably connected in the vertical grooves, two reserved grooves are formed in the sliding plug, two fixing rings are sleeved in the reserved grooves, the fixing rings are sleeved with fixing rings, the bottom end of the connecting hose is sleeved in the fixing rings, the two fixing rings are fixedly connected through flexible water pipes, and extension pipes are arranged at the bottoms of the fixing rings, the bottom of the two extension pipes is provided with a water intake, one side of the inner wall of the preformed groove is fixedly connected with two fixed hinged strips, one end of each of the two fixed hinged strips is fixedly connected with a second limiting head, the left side and the right side of the sliding plug are respectively provided with a movable groove, the upper side and the lower side of the inner wall of the movable groove are respectively fixedly connected with a sliding rail, the sliding rail is slidably connected with an installation seat, a plurality of pulleys are arranged in the installation seat and are lapped at one side of the sliding rail, a metal column is arranged between the two installation seats, an electromagnetic ring is sleeved on the metal column, one sides of the two installation seats are fixedly connected through a fixed strip, the other side of the installation seat is fixedly connected with a connecting strip, one side of the connecting strip is fixedly connected with a guide frame, a guide groove is arranged on the guide frame, a hinged rod is sleeved in the guide groove, one end of the hinged rod is fixedly connected with a transverse rod, the other end of the transverse rod is fixedly connected with an inclined strip through a second hinge post, a sliding frame is arranged in the inclined strip, the front end of the second hinge column is inserted into the first hinge column arranged in the sliding plug, the sliding frame is sleeved with the sliding column, one end of the sliding column is inserted into a transverse limiting groove arranged in the sliding plug, one side of the inner wall of the transverse limiting groove is provided with a vertical limiting groove, the other side of the inner wall of the transverse limiting groove is provided with an arc-shaped groove, a rotating column is fixedly connected in the arc-shaped groove, a first clamping strip is sleeved on the rotary column, a second clamping strip is fixedly connected with one side of the first clamping strip, the sliding column is lapped on the second clamping strip, the surface of the sliding column is fixedly connected with a movable hinge strip, one end of the movable hinged strip is hinged with a first limiting head through a hinged sleeve, and the surface of the first limiting head and the surface of the second limiting head are elastically connected with two telescopic strips.
As a still further scheme of the invention: the inductive switch comprises a first arc-shaped strip and a second arc-shaped strip, an arc plate is arranged on the inner ring of one side, opposite to the first arc-shaped strip, of the second arc-shaped strip, the metal rod is fixedly connected with one side, opposite to the second arc-shaped strip, of the first arc-shaped strip, and a magnetic rod coil is sleeved on the metal rod.
As a still further scheme of the invention: the ring plug is positioned above the three induction switches, and the induction switches, the booster pump and the electromagnetic coil are all connected with an external power supply.
As a still further scheme of the invention: and the control end is in communication connection with the inductive switch, the booster pump, the electromagnetic coil, the feedback device, the ionization device and the acid-base detector. .
A detection method of a detection system for detecting carbon-containing ions in an intelligent water plant comprises the following steps.
S1, the float detecting system is distributed in different water purifying pools of water plants, the control end controls a plurality of float detecting systems to sample tap water in the pool where the float detecting system is located, in the sampling process, the control end controls the booster pump, the booster pump increases air pressure to a space formed between the protective cover and the underwater sealing pipe, when the air pressure reaches a certain degree, the air pressure drives the sliding plug to move downwards, when shallow water is sampled, the sliding plug moves downwards to the uppermost inductive switch, when the uppermost inductive switch enters the vertical groove, the control end controls the inductive switch to be electrified, the magnetic rod coil on the inductive switch generates magnetic force on the metal rod, when the arc plate moves to the fixed strip, the electromagnetic ring at the fixed strip is electrified to generate magnetism repellent to the metal rod, at the moment, the internal fixed strip moves towards the movable groove under the repellent action along with the increase of the magnetism, at the moment, the pulley on the mounting seat moves on the surface of the slide rail, so that the moving sensitivity can be increased, in the process, the guide frame on the connecting strip moves inwards, the guide groove on the guide frame slides on the hinge rod, the hinge rod can drive the two transverse rods to pull the two pullback springs in the opposite directions under the action of the guide groove, so that the second hinge column slides in the first hinge column, the inclined strip at one end of the transverse rod moves, the slide frame on the inclined strip pulls the slide column out of the transverse limiting groove and enters the vertical limiting groove from the transverse limiting groove, at the moment, the movable hinge rod drives the first limiting head to be separated from the lap joint side state with the flexible water pipe, so that the flexible water pipe has a space for conveying sampling water, at the moment, the control end controls the water intake to suck shallow surface water and convey the shallow surface water into the purification sleeve, and through the improvement on the transverse limiting groove, horizontal spacing groove is provided with the quarter circular slot, and be provided with little arc wall in the quarter circular slot, and be provided with first card strip in the quarter circular slot, one side of first card strip is provided with the second card strip, the aim at that sets up like this, when the one end of traveller is located the quarter circular slot, under first card strip effect, traveller and first card strip contact, and the possibility that the traveller got into horizontal spacing groove is prevented to the second card strip, and when inductive switch removed to vertical groove department, the linkage that can be quick is opened, be favorable to quick fixed point sample like this, and linkage nature is strong, the operation is quick nimble, and be provided with the unilateral plate, the unilateral plate can prevent pressure downward leakage, and then guaranteed extension pipe downward movement's stability.
S2, when middle and deep sampling is carried out, the sliding plug moves downwards to the middle and lower induction switches, the uppermost induction switch enters the vertical groove, at the moment, the control end controls the induction switch to be electrified, the magnetic rod coil on the induction switch generates magnetic force on the metal rod, when the arc plate moves to the fixed strip, the electromagnetic coil on the fixed strip is electrified to generate magnetism repulsive to the metal rod, and then sampling operation can be carried out at different depths, the arrangement has the advantages that the control end can carry out carbon ion condition in the water by the aerial floating detection system at different depths in tap water, thereby obtaining accurate carbon ion content data, needing no manual sampling operation, and the arrangement aims at leading the sampling system to reach the appointed depth and accurately sample to screwing, and avoiding the situation that the sampler submerges, the problem that the sampled water has different depths possibly exists, so that the accuracy of measurement is ensured;
s3, when the sampled water enters the connecting hose, the connecting hose can discharge the sampled water from the water outlet pipe and discharge the sampled water from a water outlet hole arranged on the water outlet pipe, the sampled water is treated by the PP cotton layer and the activated carbon layer, microorganisms and impurities contained in tap water in the tap water tank can be filtered and adsorbed under the action of the PP cotton layer and the activated carbon layer, so that the interference of other trace elements in the detection process of carbon ions can be avoided, when the purified tap water enters the annular hollow sleeve, the purified tap water is treated again under the action of two filter screens in the annular hollow sleeve, after the treatment is finished, the water enters the multi-layer filter membrane separating sleeve, the sampled water enters the acid-base detector under the action of the multi-layer filter membrane separating sleeve, and after the water in the acid-base detector is detected by the ionization device and the ionization head, the generated data is transmitted to the feedback device, thus, the feedback device can feed data back to the control end through the positioning device and the information feedback device so as to obtain the condition of carbon ions in tap water;
s4, after sampling is completed, the control end controls the booster pump, the booster pump discharges pressure formed in a space formed between the protective cover and the underwater sealing pipe, when the pressure between the protective cover and the underwater sealing pipe is reduced, the sliding plug moves upwards under the action of negative pressure on the upper side, when the inductive switch is separated from the vertical groove, the two transverse rods move towards opposite directions under the elastic action of the pull-back spring, meanwhile, the mounting seat returns to the original state, in the process, the sliding frame on the inclined strip can drive the sliding column to enter the first clamping strip, then the first limiting head on the movable hinged strip abuts against the second limiting head, and further the flexible water pipe can be sealed.
(III) advantageous effects
The invention provides a carbon-containing ion detection system for an intelligent water plant. The method has the following beneficial effects:
(1) through to kickboard, annular gasbag and the end use of mutually supporting that sinks, annular gasbag and the end that sinks can guarantee that detecting system is in stable state all the time, make it float on the surface of water, and the end that sinks can make wholly be in under the state of not rocking moreover, under the showy of annular gasbag and the end that sinks, detecting system can carry out water sampling operation in arbitrary place on the surface of water, can be all-round like this, and multi-level carbon ion detection that carries on, and then guaranteed the accuracy of detected data.
(2) The control end controls the booster pump, the booster pump increases air pressure to a space formed between the protective cover and the underwater sealing pipe, when the air pressure reaches a certain degree, the air pressure drives the sliding plug to move downwards, when the sliding plug moves downwards to the uppermost induction switch when sampling shallow water, the uppermost induction switch enters the vertical groove, at the moment, the control end controls the induction switch to be electrified, at the moment, a magnetic rod coil on the induction switch generates magnetic force on the metal rod, when the arc-shaped plate moves to the fixed strip, an electromagnetic ring at the fixed strip is electrified to generate magnetism repellent to the metal rod, at the moment, along with the increase of the magnetism, the inner fixed strip moves towards the movable groove under the repellent effect, at the moment, a pulley on the mounting seat moves on the surface of the sliding rail, so that the moving sensitivity can be increased, in the process, the guide frame on the connecting strip moves towards the inner side, the process that the guide groove on the guide frame slides on the hinge rod, the hinge rod can drive the two transverse rods to pull the two pullback springs towards the opposite directions under the action of the guide groove, so that the second hinge column slides in the first hinge column, and the inclined strip at one end of the transverse rod moves, so that the slide frame on the inclined strip pulls the slide column out of the transverse limiting groove and enters the vertical limiting groove from the transverse limiting groove, at the moment, the movable hinge strip drives the first limiting head to be separated from the flexible water pipe from the lap joint side state, so that the flexible water pipe has a space for conveying sampled water, at the moment, the control end controls the water intake to suck shallow water and convey the shallow water to the interior of the purification sleeve, through the improvement of the transverse limiting groove, the transverse limiting groove is provided with a quarter circular groove, a small arc-shaped groove is arranged in the quarter circular groove, and a first clamping strip is arranged in the quarter circular groove, one side of first card strip is provided with the second card strip, the aim at that sets up like this, when the one end of traveller was located the quarter circular slot, under first card strip effect, traveller and first card strip contact, and the possibility that the traveller got into horizontal spacing groove is prevented to second card strip, and when inductive switch removed to vertical groove department, the linkage that can be quick was opened, be favorable to quick fixed point sample like this, and linkage nature is strong, the operation is quick nimble, and be provided with the one-way plate, the one-way plate can prevent pressure to leak downwards, and then guaranteed extension pipe downwardly moving's stability.
(3) When the sliding plug moves downwards to the middle and the lower induction switch, the uppermost induction switch enters the vertical groove, the control end controls the induction switch to be electrified, the upper magnetic rod coil of the induction switch generates magnetic force on the metal rod, when the arc-shaped plate moves to the fixing strip, the electromagnetic coil at the fixing strip is electrified to generate magnetism repulsive to the metal rod, and then sampling operation can be carried out at different depths, the arrangement has the advantages that the control end can carry out carbon ion building in water at different depths in the process of eating tap water through the aerial floating detection system, so that accurate carbon ion content data can be obtained, manual sampling operation is not needed, and the arrangement aims to enable the sampling system to reach the specified depth and accurately sample by screwing, the problem that the sampled water possibly has different depths in the process of submerging the sampler is avoided, thereby ensuring the accuracy of measurement.
(4) When the sampled water enters the connecting hose, the connecting hose can discharge the sampled water from the water outlet pipe and discharge the sampled water from a water outlet hole arranged on the water outlet pipe, and the sampled water is treated by the PP cotton layer and the activated carbon layer, so that microorganisms and impurities contained in tap water in the tap water tank can be filtered and adsorbed under the action of the PP cotton layer and the activated carbon layer, thereby ensuring that carbon ions can not be interfered by other trace elements in the detection process, when the purified tap water enters the annular hollow sleeve, the purified tap water is treated again under the action of two filter screens in the annular hollow sleeve, after the treatment is completed, the water enters the multilayer filter membrane separating sleeve, under the action of the multilayer filter membrane separating sleeve, the sampled water enters the acid-base detector, and after the water in the acid-base detector is detected by the ionization device and the ionization head, the generated data is transmitted to the feedback device, the feedback device can feed back data to the control end through the positioning device and the information feedback device, so that the condition of carbon ions in tap water is obtained, the detection speed is high, the information transmission is timely, and the carbon ions in the tap water can be detected in real time.
Drawings
FIG. 1 is a schematic diagram of a carbon-containing ion detection system of an intelligent water plant according to the present invention;
FIG. 2 is a schematic diagram of a float detection system in the detection system for carbon-containing ions in an intelligent water plant according to the present invention;
FIG. 3 is a cross-sectional view of a float detection system in the carbon-containing ion detection system of the intelligent water plant according to the present invention;
FIG. 4 is an enlarged view of the carbon-containing ion detection system of the intelligent water plant shown in FIG. 3A;
FIG. 5 is a schematic structural diagram of an inductive switch of a carbon-containing ion detection system of an intelligent water plant according to the present invention;
FIG. 6 is an enlarged view of the carbon-containing ion detection system of the intelligent water plant shown in B of FIG. 4;
FIG. 7 is a schematic structural diagram of a lateral limiting groove of a carbon-containing ion detection system of an intelligent water plant according to the present invention.
In the figure: the device comprises a control end 1, a network connection data line 2, a positioning device 3, an information feedback device 4, a float detection system 5, a floating plate 6, an annular air bag 7, a sinking end 8, a waterproof shell 9, an underwater sealing pipe 10, a bearing plate 11, a protective cover 12, a purification sleeve 13, a connecting hose 14, a water outlet pipe 15, a water outlet hole 16, a PP cotton layer 17, an activated carbon layer 18, a booster pump 19, a filter screen 20, an annular hollow sleeve 21, a multi-layer filter membrane separation sleeve 22, a movable groove 23, a mounting seat 24, a slide rail 25, a connecting strip 26, an electromagnetic ring 27, a guide frame 28, a guide groove 29, a pulley 30, a hinge rod 31, a fixing strip 32, a transverse rod 33, a pull-back spring 34, a first hinge column 35, a second hinge column 36, an inclined strip 37, a slide frame 38, a vertical limiting groove 39, a transverse limiting groove 40, a slide column 41, a movable hinge strip 42, a reserved groove 43, a fixing ring 44, a fixing ring 45, a fixing hinge strip 46, The device comprises a fixing rod 47, a flexible water pipe 48, a telescopic strip 49, a hinge sleeve 50, a first limiting head 51, a second limiting head 52, an arc-shaped groove 53, a rotary column 54, a first clamping strip 55, a second clamping strip 56, a first arc-shaped strip 57, a second arc-shaped strip 58, an arc-shaped plate 59, a metal rod 60, a magnetic rod coil 61, an ionization device 62, an ionization head 63, a feedback device 64, an extension pipe 65, an induction switch 66, a water intake 67, an acid-base detector 68, a ring plug 69, a one-way plate 70, a vertical groove 71 and a sliding plug 72.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
As shown in fig. 1 to 7, the present invention provides a technical solution: a carbon-containing ion detection system of a smart water plant comprises a control end 1, an input end of the control end 1 is provided with an internet data line 2, a plurality of branches of the internet data line 2 are provided with a positioning device 3 and an information feedback device 4, the tail ends of a plurality of branches of the internet data line 2 are provided with a detection system float detection system 5, the float detection system 5 comprises a floating system, a detection system, a sinking end 8 and a sampling system, the top of the floating system is fixedly connected with the detection system, the bottom of the detection system is fixedly connected with the sinking end 8, the sampling system is fixedly connected with the bottom of the detection system, the sampling system penetrates through the sinking end 8, the detection system comprises a waterproof shell 9, the top of the inner wall of the waterproof shell 9 is fixedly connected with a purification sleeve 13, the bottom of the purification sleeve 13 penetrates through two connection hoses 14, the top ends of the connection hoses 14 are communicated with a water outlet pipe 15, and the surface of the water outlet pipe 15 is provided with a water outlet 16, the cover is equipped with the cotton layer 17 of PP on the outlet pipe 15, the cover is equipped with activated carbon layer 18 on the cotton layer 17 of PP, the annular hollow cover 21 is established to the annular mounting inslot cover that the bottom of purifying sleeve 13 was seted up, the bottom of annular hollow cover 21 is provided with multilayer filter membrane and divides filter sleeve 22, the left and right sides that multilayer filter membrane divides filter sleeve 22 all communicates there is acid-base detector 68, the top intercommunication of acid-base detector 68 has ionization head 63, the top intercommunication of ionization head 63 has ionization device 62, the bottom of acid-base detector 68 is provided with feedback ware 64, both sides are all overlapped and are equipped with filter screen 20 about the annular hollow cover 21 inner chamber.
The floating system comprises a floating plate 6, an annular air bag 7 is fixedly connected to the top of the floating plate 6, a bearing plate 11 is sleeved in the floating plate 6, a circular groove is formed in the axis of the bearing plate 11, and the detection system is sleeved in the circular groove.
The sampling system comprises an underwater sealing pipe 10, the top end of the underwater sealing pipe 10 is sleeved in a through hole formed in the bottom of a waterproof shell 9, the top of the underwater sealing pipe 10 is fixedly connected with a protective cover 12, the top of the protective cover 12 is provided with a booster pump 19, an air pipe of the booster pump 19 is arranged inside the protective cover 12, three induction switches 66 are arranged on the left side and the right side of the inner wall of the underwater sealing pipe 10, a sliding plug 72 is sleeved in the underwater sealing pipe 10, a ring plug 69 is sleeved on the sliding plug 72, two vertical grooves 71 are formed in the ring plug 69, a one-way plate 70 is movably connected in each vertical groove 71, two reserved grooves 43 are formed in the sliding plug 72, two fixing rings 44 are sleeved in the reserved grooves 43, a fixing ring 45 is sleeved in each fixing ring 44, the bottom end of a connecting hose 14 is sleeved in each fixing ring 45, the two fixing rings 44 are fixedly connected through a flexible water pipe 48, an extension pipe 65 is arranged at the bottom of each fixing ring 44, the bottom of the two extension pipes 65 is provided with a water intake 67, one side of the inner wall of the reserved groove 43 is fixedly connected with two fixed hinged strips 46, one end of each of the two fixed hinged strips 46 is fixedly connected with a second limiting head 52, the left side and the right side of the sliding plug 72 are both provided with movable grooves 23, the upper side and the lower side of the inner wall of each movable groove 23 are both fixedly connected with sliding rails 25, the sliding rails 25 are slidably connected with mounting seats 24, a plurality of pulleys 30 are arranged in the mounting seats 24, the pulleys 30 are lapped on one side of the sliding rails 25, a metal column is arranged between the two mounting seats 24 and sleeved with an electromagnetic ring 27, one side of each of the two mounting seats 24 is fixedly connected with a fixing strip 32, the other side of each mounting seat 24 is fixedly connected with a connecting strip 26, one side of each connecting strip 26 is fixedly connected with a guide frame 28, a guide groove 29 is arranged on each guide frame 28, a hinged rod 31 is sleeved in each guide groove 29, and one end of each hinged rod 31 is fixedly connected with a transverse rod 33, the other end of the transverse rod 33 is fixedly connected with an inclined bar 37 through a second hinged column 36, a sliding frame 38 is arranged in the inclined bar 37, the front end of the second hinged column 36 is inserted in a first hinged column 35 arranged in a sliding plug 72, a sliding column 41 is sleeved in the sliding frame 38, one end of the sliding column 41 is inserted in a transverse limiting groove 40 arranged in the sliding plug 72, a vertical limiting groove 39 is formed in one side of the inner wall of the transverse limiting groove 40, an arc-shaped groove 53 is formed in the other side of the inner wall of the transverse limiting groove 40, a rotating column 54 is fixedly connected in the arc-shaped groove 53, a first clamping bar 55 is sleeved on the rotating column 54, a second clamping bar 56 is fixedly connected to one side of the first clamping bar 55, the sliding column 41 is overlapped on the second clamping bar 56, a movable hinged bar 42 is fixedly connected to the surface of the sliding column 41, a first limiting head 51 is hinged to one end of the movable hinged bar 42 through a hinged sleeve 50, and two telescopic bars 49 are elastically connected to the surfaces of the first limiting head 51 and the second limiting head 52.
The inductive switch 66 comprises a first arc-shaped strip 57 and a second arc-shaped strip 58, an arc-shaped plate 59 is arranged on the inner ring of one side, opposite to the first arc-shaped strip 57 and the second arc-shaped strip 58, of the first arc-shaped strip 57 is fixedly connected with the second arc-shaped strip 58 through a metal rod 60, and a magnetic rod coil 61 is sleeved on the metal rod 60.
The ring plug 69 is positioned above the three inductive switches 66, and the inductive switches 66, the booster pump 19 and the electromagnetic coil 27 are all connected with an external power supply.
The control end 1 is in communication connection with an inductive switch 66, a booster pump 19, an electromagnetic coil 27, a feedback device 64, an ionization device 62 and an acid-base detector 68.
A detection method of a detection system for detecting carbon-containing ions in an intelligent water plant comprises the following steps.
S1, the float detecting system 5 is distributed in different water purifying tanks of a water plant, the control end 1 controls a plurality of float detecting systems 5 to sample tap water in the water tank where the float detecting system 5 is located, in the sampling process, the control end 1 controls the booster pump 19, the booster pump 19 increases air pressure to a space formed between the protective cover 12 and the underwater sealing pipe 10, when the air pressure reaches a certain degree, the air pressure drives the sliding plug 72 to move downwards, when shallow water is sampled, the sliding plug 72 moves downwards to the uppermost induction switch 66, the uppermost induction switch 66 enters the vertical groove 71, at the moment, the control end 1 controls the induction switch 66 to be electrified, at the moment, the magnetic rod coil 61 on the induction switch 66 generates magnetic force on the metal rod 60, when the arc-shaped plate 59 moves to the fixing strip 32, the electromagnetic ring 27 on the fixing strip 32 is electrified to generate magnetism repellent to the metal rod 60, at this time, as the magnetism increases, the inner fixed strip 32 moves towards the movable groove 23 under the repulsive action, at this time, the pulley 30 on the mounting seat 24 moves on the surface of the slide rail 25, so that the moving sensitivity can be increased, in the process, the guide frame 28 on the connecting strip 26 moves towards the inner side, in the process that the guide groove 29 on the guide frame 28 slides on the hinge rod 31, the hinge rod 31 can drive the two transverse rods 33 to pull the two pull-back springs 34 towards the opposite directions under the action of the guide groove 29, so that the second hinge column 36 slides in the first hinge column 35, and the inclined strip 37 at one end of the transverse rod 33 moves, so that the slide frame 38 on the inclined strip 37 pulls the slide column 41 out of the transverse limiting groove 40 and enters the vertical limiting groove 39 from the transverse limiting groove 40, at this time, the movable hinge strip 42 drives the first limiting head 51 to be separated from the overlapping side of the flexible water pipe 48, therefore, the flexible water pipe 48 has a space for conveying sampling water, the control end 1 controls the water intake 67 to suck shallow water and convey the shallow water to the inside of the purification sleeve 13, through the improvement of the transverse limiting groove 40, the transverse limiting groove 40 is provided with a quarter circular groove, a small arc-shaped groove is arranged in the quarter circular groove, a first clamping strip 55 is arranged in the quarter circular groove, one side of the first clamping strip 55 is provided with a second clamping strip 56, the arrangement aims to prevent the possibility that the sliding column 41 enters the transverse limiting groove 40 under the action of the first clamping strip 55 when one end of the sliding column 41 is positioned in the quarter circular groove, the sliding column 41 is contacted with the first clamping strip 55, the second clamping strip 56 prevents the sliding column 41 from entering the transverse limiting groove 40, and when the induction switch 66 moves to the vertical groove 71, the quick linkage opening can be realized, so that the quick fixed-point sampling is facilitated, the linkage performance is strong, and the operation is quick and flexible, and a check plate 70 is provided, the check plate 70 being capable of preventing the pressure from leaking downward, thereby ensuring the stability of the downward movement of the extension pipe 65.
S2, when middle and deep sampling is carried out, the sliding plug 72 moves downwards to the middle and lower induction switches 66, when the uppermost induction switch 66 enters the vertical groove 71, at the moment, the control end 1 controls the induction switch 66 to be electrified, the magnetic rod coil 61 on the induction switch 66 generates magnetic force on the metal rod 60, when the arc-shaped plate 59 moves to the fixed strip 32, the electromagnetic coil 27 on the fixed strip 32 is electrified to generate magnetism repulsive to the metal rod 60, and then sampling operation can be carried out at different depths, so that the advantage is that the control end 1 can carry out carbon ion condition in the water by the air floating detection system 5 at different depths in the running water, thereby obtaining accurate carbon ion content data, needing no manual sampling operation, and the purpose is that the sampling system can reach the appointed depth and can accurately sample by screwing, the problem that the sampled water possibly has different depths in the submergence process of the sampler can be solved, and the measurement accuracy is further ensured;
s3, when the sampled water enters the connecting hose 14, the connecting hose 14 can discharge the sampled water from the water outlet pipe 15 and discharge the sampled water from the water outlet hole 16 arranged on the water outlet pipe 15, and after the processing of the PP cotton layer 17 and the activated carbon layer 18, microorganisms and impurities contained in the tap water pool can be filtered and adsorbed under the action of the PP cotton layer 17 and the activated carbon layer 18, so that the interference of other trace elements can be avoided in the detection process of carbon ions, when the purified tap water enters the annular hollow sleeve 21, the purified tap water is processed again under the action of the two filter screens 20 in the annular hollow sleeve 21, after the processing is completed, the water enters the multi-layer filter membrane separating sleeve 22, under the action of the multi-layer filter membrane separating sleeve 22, the sampled water enters the acid-base detector 68, and the water in the acid-base detector 68 is detected through the ionization device 62 and the ionization head 63, the generated data is transmitted to the feedback device 64, so that the feedback device 64 can feed the data back to the control end 1 through the positioning device 3 and the information feedback device 4 to obtain the condition of the carbon ions in the tap water;
s4, after sampling is completed, the control end 1 controls the booster pump 19, the booster pump 19 discharges pressure formed in a space formed between the protective cover 12 and the underwater sealing pipe 10, when the pressure between the protective cover 12 and the underwater sealing pipe 10 is reduced, the sliding plug 72 moves upwards under the action of negative pressure on the upper side, after the inductive switch 66 is separated from the vertical groove 71, the two transverse rods 33 move towards opposite directions under the elastic action of the pull-back spring 34, meanwhile, the mounting seat 24 is restored to the original state, and in the process, the sliding frame 38 on the inclined strip 37 can drive the sliding column 41 to enter the first clamping strip 55, so that the first limiting head 51 on the movable hinge strip 42 abuts against the second limiting head 52, and the flexible water pipe 48 can be sealed.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising a reference structure" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (7)
1. The utility model provides a carbon-containing ion detection system of wisdom water plant, its characterized in that includes control end (1), the input of control end (1) is provided with networking data line (2), be provided with positioner (3) and information feedback device (4) on a plurality of branches of networking data line (2), a plurality of branch ends of networking data line (2) are provided with detection system float detecting system (5), float detecting system (5) include showy system, detecting system and end (8) and the sampling system of sinking, the top fixedly connected with of showy system the detecting system, the bottom fixedly connected with of detecting system end (8) of sinking, the sampling system fixed connection in the bottom of detecting system, the sampling system runs through end (8) of sinking, the detecting system includes waterproof casing (9), the top fixedly connected with of waterproof casing (9) inner wall purifies cover (13), the bottom of purifying cover (13) is run through there are two coupling hose (14), the top intercommunication of coupling hose (14) has outlet pipe (15), outlet pipe (15) surface is provided with apopore (16), the cover is equipped with PP cotton layer (17) on outlet pipe (15), the cover is equipped with activated carbon layer (18) on PP cotton layer (17), the annular mounting groove endotheca that the bottom of purifying cover (13) was seted up has annular hollow cover (21), the bottom of annular hollow cover (21) is provided with multilayer filter membrane filter sleeve (22), the left and right sides of multilayer filter membrane filter sleeve (22) all communicates acid-base detector (68), the top intercommunication of acid-base detector (68) has ionization head (63), the top intercommunication of ionization head (63) has ionization device (62), the bottom of acid-base detector (68) is provided with feedback ware (64), both sides all are equipped with filter screen (20) about annular cavity (21) inner chamber.
2. The system of claim 1, wherein the carbon-containing ion detection system comprises: the floating system comprises a floating plate (6), an annular air bag (7) is fixedly connected to the top of the floating plate (6), a bearing plate (11) is sleeved in the floating plate (6), a circular groove is formed in the axis of the bearing plate (11), and the detection system is arranged in the circular groove in a sleeved mode.
3. The system of claim 2, wherein the carbon-containing ion detection system comprises: the sampling system comprises an underwater sealing pipe (10), wherein the top end of the underwater sealing pipe (10) is sleeved in the through hole formed in the bottom of the waterproof shell (9), the top of the underwater sealing pipe (10) is fixedly connected with a protective cover (12), the top of the protective cover (12) is provided with a booster pump (19), an air pipe of the booster pump (19) is arranged in the protective cover (12), the left side and the right side of the inner wall of the underwater sealing pipe (10) are respectively provided with three inductive switches (66), the inner sleeve of the underwater sealing pipe (10) is provided with a sliding plug (72), the sliding plug (72) is sleeved with a ring plug (69), the ring plug (69) is provided with two vertical grooves (71), the vertical grooves (71) are movably connected with one-way plates (70), the sliding plug (72) is provided with two reserved grooves (43), and the inner sleeve of the reserved grooves (43) is provided with two fixed rings (44), the inner sleeve of the fixing ring (44) is provided with a fixing ring (45), the bottom end of the connecting hose (14) is arranged in the fixing ring (45), two fixing rings (44) are fixedly connected through a flexible water pipe (48), the bottom of the fixing ring (44) is provided with an extension pipe (65), the bottoms of the two extension pipes (65) are provided with a water intake (67), one side of the inner wall of the preformed groove (43) is fixedly connected with two fixed hinged strips (46), one ends of the two fixed hinged strips (46) are fixedly connected with a second limiting head (52), the left side and the right side of the sliding plug (72) are provided with movable grooves (23), the upper side and the lower side of the inner wall of each movable groove (23) are fixedly connected with sliding rails (25), the sliding rails (25) are connected with mounting seats (24) in a sliding manner, and a plurality of pulleys (30) are arranged in the mounting seats (24), the pulley (30) is in lap joint with one side of the sliding rail (25), two metal columns are arranged between the installation seats (24), an electromagnetic ring (27) is sleeved on each metal column, one side of each installation seat (24) is fixedly connected with one fixing strip (32), the other side of each installation seat (24) is fixedly connected with one connecting strip (26), one side of each connecting strip (26) is fixedly connected with one guide frame (28), each guide frame (28) is provided with one guide groove (29), each guide groove (29) is internally sleeved with one hinge rod (31), one end of each hinge rod (31) is fixedly connected with one transverse rod (33), the other end of each transverse rod (33) is fixedly connected with one inclined strip (37) through one second hinge column (36), each inclined strip (37) is internally provided with one sliding frame (38), the front end of each second hinge column (36) is inserted into one first hinge column (35) arranged in the sliding plug (72), a sliding column (41) is sleeved in the sliding frame (38), one end of the sliding column (41) is inserted in a transverse limiting groove (40) arranged in the sliding plug (72), one side of the inner wall of the transverse limiting groove (40) is provided with a vertical limiting groove (39), an arc-shaped groove (53) is formed in the other side of the inner wall of the transverse limiting groove (40), a rotating column (54) is fixedly connected in the arc-shaped groove (53), a first clamping strip (55) is sleeved on the rotating column (54), a second clamping strip (56) is fixedly connected with one side of the first clamping strip (55), the sliding column (41) is lapped on the second clamping strip (56), the surface of the sliding column (41) is fixedly connected with a movable hinge strip (42), one end of the movable hinged strip (42) is hinged with a first limiting head (51) through a hinged sleeve (50), the surfaces of the first limiting head (51) and the second limiting head (52) are elastically connected with two expansion strips (49).
4. The system of claim 3, wherein the carbon-containing ion detection system comprises: inductive switch (66) include first arc strip (57) and second arc strip (58), the inner circle of one side is relative in first arc strip (57) and second arc strip (58) is provided with arc (59), metal pole (60) fixed connection is passed through to one side is relative in first arc strip (57) and second arc strip (58), the cover is equipped with magnetic pole coil (61) on metal pole (60).
5. The system of claim 4, wherein the carbon-containing ion detection system comprises: the ring plug (69) is positioned above the three induction switches (66), and the induction switches (66), the booster pump (19) and the electromagnetic coil (27) are all connected with an external power supply.
6. The system of claim 5, wherein the carbon-containing ion detection system comprises: the control end (1) is in communication connection with the inductive switch (66), the booster pump (19), the electromagnetic coil (27), the feedback device (64), the ionization device (62) and the acid-base detector (68).
7. The method as claimed in claims 1 to 6, comprising the steps of:
s1, the buoy detection systems (5) are distributed in different water purification tanks of a water plant, the control end (1) controls the buoy detection systems (5) to sample tap water in the water tank where the buoy detection systems (5) are located, in the sampling process, the control end (1) controls the booster pump (19), the booster pump (19) increases air pressure in a space formed between the protective cover (12) and the underwater sealing pipe (10), when the air pressure reaches a certain degree, the air pressure drives the sliding plug (72) to move downwards, when shallow water is sampled, the sliding plug (72) moves downwards to the uppermost induction switch (66), the uppermost induction switch (66) enters the vertical groove (71), at the moment, the control end (1) controls the induction switch (66) to be electrified, at the moment, the magnetic rod coil (61) on the induction switch (66) generates magnetic force on the metal rod (60), when the arc-shaped plate (59) moves to the fixed bar (32), the electromagnetic coil (27) at the fixed bar (32) is electrified to generate magnetism repellent to the metal rod (60), at the moment, the inner fixed bar (32) moves towards the movable groove (23) under the action of repulsion along with the increase of the magnetism, at the moment, the pulley (30) on the mounting seat (24) moves on the surface of the sliding rail (25), so that the moving sensitivity can be increased, in the process, the guide frame (28) on the connecting bar (26) moves inwards, in the process that the guide groove (29) on the guide frame (28) slides on the hinge rod (31), the hinge rod (31) can drive the two transverse rods (33) to pull the two pull-back springs (34) towards the opposite directions under the action of the guide groove (29), so that the second hinge rod (36) slides in the first hinge rod (35), and the inclined bar (37) at one end of the transverse rod (33) moves, so that the sliding frame (38) on the inclined bar (37) slides to slide The column (41) is pulled out from the horizontal limiting groove (40) and enters the vertical limiting groove (39) from the horizontal limiting groove (40), at the moment, the movable hinge strip (42) drives the first limiting head (51) and the flexible water pipe (48) to be separated from a lap joint side state, so that the flexible water pipe (48) has a space for conveying sampling water, at the moment, the control end (1) controls the water intake (67) to suck shallow water and convey the shallow water to the inside of the purification sleeve (13), through the improvement of the horizontal limiting groove (40), the horizontal limiting groove (40) is provided with a quarter circular groove, a small arc-shaped groove is arranged in the quarter circular groove, a first clamping strip (55) is arranged in the quarter circular groove, a second clamping strip (56) is arranged on one side of the first clamping strip (55), the arrangement aims to ensure that when one end of the sliding column (41) is positioned in the quarter circular groove, under the action of the first clamping strip (55), the sliding column (41) is in contact with the first clamping strip (55), the possibility that the sliding column (41) enters the transverse limiting groove (40) is prevented by the second clamping strip (56), and when the induction switch (66) moves to the vertical groove (71), the induction switch can be quickly opened in a linkage manner, so that quick fixed-point sampling is facilitated, the linkage is strong, the operation is quick and flexible, and the one-way plate (70) is arranged, pressure can be prevented from leaking downwards by the one-way plate (70), and the stability of downward movement of the extension pipe (65) is further ensured;
s2, when middle and deep sampling is carried out, the sliding plug (72) moves downwards to the middle and lower induction switches (66), the uppermost induction switch (66) enters the vertical groove (71), at the moment, the control end (1) controls the induction switch (66) to be electrified, the magnetic rod coil (61) on the induction switch (66) generates magnetic force on the metal rod (60), when the arc-shaped plate (59) moves to the fixed strip (32), the electromagnetic coil (27) on the fixed strip (32) is electrified to generate magnetism repellent with the metal rod (60), and then sampling operation can be carried out at different depths, so that the arrangement has the advantages that the control end (1) can carry out carbon ion building in tap water at different depths by the aerial floating detection system (5), thereby obtaining accurate carbon ion content data without manual sampling operation, the purpose of the arrangement is that the sampling system can reach the specified depth and accurately sample by screwing, the problem that the sampled water possibly has different depths in the submergence process of the sampler is solved, and the accuracy of measurement is further ensured;
s3, when sampled water enters the connecting hose (14), the connecting hose (14) can discharge the sampled water from the water outlet pipe (15) and discharge the sampled water from a water outlet hole (16) arranged on the water outlet pipe (15), and after the sampled water is treated by the PP cotton layer (17) and the activated carbon layer (18), microorganisms and impurities contained in tap water in the tap water tank can be filtered and adsorbed under the action of the PP cotton layer (17) and the activated carbon layer (18), so that the interference of other trace elements can be avoided in the detection process of carbon ions, when the purified tap water enters the annular hollow sleeve (21), the purified tap water is treated again under the action of two filter screens (20) in the annular hollow sleeve (21), after the treatment is finished, the water enters the multi-layer filter membrane filtering sleeve (22), the sampled water enters the acid-base detector (68) under the action of the multi-layer filter membrane filtering sleeve (22), after the ionization device (62) and the ionization head (63) are used for detecting water in the acid-base detector (68), generated data are transmitted to the feedback device (64), so that the feedback device (64) can feed the data back to the control end (1) through the positioning device (3) and the information feedback device (4) to obtain the condition of carbon ions in tap water;
s4: after sampling is finished, the control end (1) controls a booster pump (19), the booster pump (19) discharges pressure formed in a space formed between the protective cover (12) and the underwater sealing pipe (10), when the pressure between the protective cover (12) and the underwater sealing pipe (10) is reduced, the sliding plug (72) moves upwards under the action of the negative pressure on the upper side, and after the inductive switch (66) is separated from the vertical groove (71), under the elastic action of the pull-back spring (34), the two transverse rods (33) move towards opposite directions, and at the same time, the mounting seat (24) is restored to the original state, in the process, the sliding frame (38) on the inclined strip (37) can drive the sliding column (41) to enter the first clamping strip (55), and then the first limiting head (51) on the movable hinge strip (42) is abutted against the second limiting head (52), so that the flexible water pipe (48) can be sealed.
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| CN202111435143.1A CN114113526A (en) | 2021-11-29 | 2021-11-29 | Intelligent water plant carbon-containing ion detection system and detection method thereof |
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| CN202111435143.1A CN114113526A (en) | 2021-11-29 | 2021-11-29 | Intelligent water plant carbon-containing ion detection system and detection method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117129283A (en) * | 2023-10-26 | 2023-11-28 | 长岛国家海洋公园管理中心(庙岛群岛海豹省级自然保护区管理中心) | Underwater sampling device based on marine ecological restoration |
| CN117168896A (en) * | 2023-09-21 | 2023-12-05 | 中国科学院西北生态环境资源研究院 | Ecological environment water quality detection sampling device and working method thereof |
| CN117347113A (en) * | 2023-12-04 | 2024-01-05 | 苏州园科生态建设集团有限公司 | Ecological detection sampling device of little wetland water of manual work |
-
2021
- 2021-11-29 CN CN202111435143.1A patent/CN114113526A/en not_active Withdrawn
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117168896A (en) * | 2023-09-21 | 2023-12-05 | 中国科学院西北生态环境资源研究院 | Ecological environment water quality detection sampling device and working method thereof |
| CN117129283A (en) * | 2023-10-26 | 2023-11-28 | 长岛国家海洋公园管理中心(庙岛群岛海豹省级自然保护区管理中心) | Underwater sampling device based on marine ecological restoration |
| CN117129283B (en) * | 2023-10-26 | 2023-12-26 | 长岛国家海洋公园管理中心(庙岛群岛海豹省级自然保护区管理中心) | Underwater sampling device based on marine ecological restoration |
| CN117347113A (en) * | 2023-12-04 | 2024-01-05 | 苏州园科生态建设集团有限公司 | Ecological detection sampling device of little wetland water of manual work |
| CN117347113B (en) * | 2023-12-04 | 2024-02-09 | 苏州园科生态建设集团有限公司 | Ecological detection sampling device of little wetland water of manual work |
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