CN114080156B - 消毒剂组合物 - Google Patents
消毒剂组合物 Download PDFInfo
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- CN114080156B CN114080156B CN202080049505.0A CN202080049505A CN114080156B CN 114080156 B CN114080156 B CN 114080156B CN 202080049505 A CN202080049505 A CN 202080049505A CN 114080156 B CN114080156 B CN 114080156B
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- 239000000203 mixture Substances 0.000 title claims abstract description 142
- 239000000645 desinfectant Substances 0.000 title claims abstract description 17
- 229920000642 polymer Polymers 0.000 claims abstract description 57
- 238000004140 cleaning Methods 0.000 claims abstract description 16
- 230000000845 anti-microbial effect Effects 0.000 claims abstract description 14
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 13
- 125000001453 quaternary ammonium group Chemical group 0.000 claims abstract description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 67
- 239000000178 monomer Substances 0.000 claims description 60
- 239000004094 surface-active agent Substances 0.000 claims description 39
- -1 alkyl glucosamines Chemical class 0.000 claims description 36
- 239000002736 nonionic surfactant Substances 0.000 claims description 22
- 150000001412 amines Chemical class 0.000 claims description 16
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- QNILTEGFHQSKFF-UHFFFAOYSA-N n-propan-2-ylprop-2-enamide Chemical compound CC(C)NC(=O)C=C QNILTEGFHQSKFF-UHFFFAOYSA-N 0.000 claims description 11
- 230000003115 biocidal effect Effects 0.000 claims description 9
- SMGTYJPMKXNQFY-UHFFFAOYSA-N octenidine dihydrochloride Chemical group Cl.Cl.C1=CC(=NCCCCCCCC)C=CN1CCCCCCCCCCN1C=CC(=NCCCCCCCC)C=C1 SMGTYJPMKXNQFY-UHFFFAOYSA-N 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims description 7
- 239000003002 pH adjusting agent Substances 0.000 claims description 4
- MMNOTXXCQAFCLV-UHFFFAOYSA-N n,n-dimethylmethanamine;2-methyl-n-propylprop-2-enamide;hydrochloride Chemical compound [Cl-].C[NH+](C)C.CCCNC(=O)C(C)=C MMNOTXXCQAFCLV-UHFFFAOYSA-N 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 27
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 24
- 229920002873 Polyethylenimine Polymers 0.000 description 16
- 229960003237 betaine Drugs 0.000 description 16
- 125000004432 carbon atom Chemical group C* 0.000 description 14
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 12
- ONLRKTIYOMZEJM-UHFFFAOYSA-N n-methylmethanamine oxide Chemical compound C[NH+](C)[O-] ONLRKTIYOMZEJM-UHFFFAOYSA-N 0.000 description 10
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 125000004429 atom Chemical group 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 9
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 8
- 150000001298 alcohols Chemical class 0.000 description 7
- 244000005700 microbiome Species 0.000 description 7
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 125000002947 alkylene group Chemical group 0.000 description 6
- 150000001408 amides Chemical class 0.000 description 6
- 239000002280 amphoteric surfactant Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 230000000813 microbial effect Effects 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 239000003760 tallow Substances 0.000 description 6
- 239000002888 zwitterionic surfactant Substances 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 150000001450 anions Chemical class 0.000 description 5
- 239000004599 antimicrobial Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 4
- 241000233866 Fungi Species 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- DTDMYWXTWWFLGJ-UHFFFAOYSA-N decan-4-ol Chemical compound CCCCCCC(O)CCC DTDMYWXTWWFLGJ-UHFFFAOYSA-N 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical group 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
- 239000012669 liquid formulation Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 3
- ZKWJQNCOTNUNMF-QXMHVHEDSA-N 2-[dimethyl-[3-[[(z)-octadec-9-enoyl]amino]propyl]azaniumyl]acetate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O ZKWJQNCOTNUNMF-QXMHVHEDSA-N 0.000 description 3
- GYSCXPVAKHVAAY-UHFFFAOYSA-N 3-Nonanol Chemical compound CCCCCCC(O)CC GYSCXPVAKHVAAY-UHFFFAOYSA-N 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 150000003863 ammonium salts Chemical class 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 3
- IXUOEGRSQCCEHB-UHFFFAOYSA-N nonan-4-ol Chemical compound CCCCCC(O)CCC IXUOEGRSQCCEHB-UHFFFAOYSA-N 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical group [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 3
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- XMVBHZBLHNOQON-UHFFFAOYSA-N 2-butyl-1-octanol Chemical compound CCCCCCC(CO)CCCC XMVBHZBLHNOQON-UHFFFAOYSA-N 0.000 description 2
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 2
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RKWGIWYCVPQPMF-UHFFFAOYSA-N Chloropropamide Chemical compound CCCNC(=O)NS(=O)(=O)C1=CC=C(Cl)C=C1 RKWGIWYCVPQPMF-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 241000588915 Klebsiella aerogenes Species 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- LCTONWCANYUPML-UHFFFAOYSA-N Pyruvic acid Chemical compound CC(=O)C(O)=O LCTONWCANYUPML-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 229920006187 aquazol Polymers 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- MLIREBYILWEBDM-UHFFFAOYSA-N cyanoacetic acid Chemical compound OC(=O)CC#N MLIREBYILWEBDM-UHFFFAOYSA-N 0.000 description 2
- ICEQLCZWZXUUIJ-UHFFFAOYSA-N decan-3-ol Chemical compound CCCCCCCC(O)CC ICEQLCZWZXUUIJ-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- ZGSIAHIBHSEKPB-UHFFFAOYSA-N dodecan-4-ol Chemical compound CCCCCCCCC(O)CCC ZGSIAHIBHSEKPB-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 229960001774 octenidine Drugs 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- JYVLIDXNZAXMDK-UHFFFAOYSA-N pentan-2-ol Chemical compound CCCC(C)O JYVLIDXNZAXMDK-UHFFFAOYSA-N 0.000 description 2
- LCPDWSOZIOUXRV-UHFFFAOYSA-N phenoxyacetic acid Chemical compound OC(=O)COC1=CC=CC=C1 LCPDWSOZIOUXRV-UHFFFAOYSA-N 0.000 description 2
- 229920001983 poloxamer Polymers 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 150000003333 secondary alcohols Chemical class 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- GRDYSMCYPTWIPT-UHFFFAOYSA-N tridecan-5-ol Chemical compound CCCCCCCCC(O)CCCC GRDYSMCYPTWIPT-UHFFFAOYSA-N 0.000 description 2
- HCARCYFXWDRVBZ-UHFFFAOYSA-N undecan-3-ol Chemical compound CCCCCCCCC(O)CC HCARCYFXWDRVBZ-UHFFFAOYSA-N 0.000 description 2
- FNORHVDKJWGANC-UHFFFAOYSA-N undecan-4-ol Chemical compound CCCCCCCC(O)CCC FNORHVDKJWGANC-UHFFFAOYSA-N 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- QBYIENPQHBMVBV-HFEGYEGKSA-N (2R)-2-hydroxy-2-phenylacetic acid Chemical compound O[C@@H](C(O)=O)c1ccccc1.O[C@@H](C(O)=O)c1ccccc1 QBYIENPQHBMVBV-HFEGYEGKSA-N 0.000 description 1
- XOMRRQXKHMYMOC-NRFANRHFSA-N (3s)-3-hexadecanoyloxy-4-(trimethylazaniumyl)butanoate Chemical compound CCCCCCCCCCCCCCCC(=O)O[C@@H](CC([O-])=O)C[N+](C)(C)C XOMRRQXKHMYMOC-NRFANRHFSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 description 1
- PHIQHXFUZVPYII-ZCFIWIBFSA-O (R)-carnitinium Chemical compound C[N+](C)(C)C[C@H](O)CC(O)=O PHIQHXFUZVPYII-ZCFIWIBFSA-O 0.000 description 1
- VXMQKONTARQGPP-UHFFFAOYSA-N (ethoxyamino)oxyethane Chemical compound CCONOCC VXMQKONTARQGPP-UHFFFAOYSA-N 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- WDRZVZVXHZNSFG-UHFFFAOYSA-N 1-ethenylpyridin-1-ium Chemical compound C=C[N+]1=CC=CC=C1 WDRZVZVXHZNSFG-UHFFFAOYSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- KZVIUXKOLXVBPC-UHFFFAOYSA-N 16-methylheptadecanamide Chemical compound CC(C)CCCCCCCCCCCCCCC(N)=O KZVIUXKOLXVBPC-UHFFFAOYSA-N 0.000 description 1
- PQSMEVPHTJECDZ-UHFFFAOYSA-N 2,3-dimethylheptan-2-ol Chemical compound CCCCC(C)C(C)(C)O PQSMEVPHTJECDZ-UHFFFAOYSA-N 0.000 description 1
- HGDVHRITTGWMJK-UHFFFAOYSA-N 2,6-dimethylheptan-2-ol Chemical compound CC(C)CCCC(C)(C)O HGDVHRITTGWMJK-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- QEJSCTLHIOVBLH-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)-octadecylazaniumyl]acetate Chemical compound CCCCCCCCCCCCCCCCCC[N+](CCO)(CCO)CC([O-])=O QEJSCTLHIOVBLH-UHFFFAOYSA-N 0.000 description 1
- NPKLJZUIYWRNMV-UHFFFAOYSA-N 2-[decyl(dimethyl)azaniumyl]acetate Chemical compound CCCCCCCCCC[N+](C)(C)CC([O-])=O NPKLJZUIYWRNMV-UHFFFAOYSA-N 0.000 description 1
- KKMIHKCGXQMFEU-UHFFFAOYSA-N 2-[dimethyl(tetradecyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O KKMIHKCGXQMFEU-UHFFFAOYSA-N 0.000 description 1
- AMRBZKOCOOPYNY-QXMHVHEDSA-N 2-[dimethyl-[(z)-octadec-9-enyl]azaniumyl]acetate Chemical compound CCCCCCCC\C=C/CCCCCCCC[N+](C)(C)CC([O-])=O AMRBZKOCOOPYNY-QXMHVHEDSA-N 0.000 description 1
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Abstract
本发明提供了一种消毒剂清洁组合物，其基本上不含季铵抗微生物活性物质，所述组合物包含：双吡啶鎓烷烃抗微生物活性物质和特定聚合物。
Description
技术领域
本发明属于消毒剂组合物领域，特别是消毒剂清洁组合物领域。组合物提供杀生物残余性，并且同时提供良好的清洁和光泽。
背景技术
如WO 2016/086012 A1中所述的组合物提供持久的消毒剂益处。然而，用此类组合物处理的表面可能留下较差的光泽概况、低干燥速率和发粘/粘性感觉，这对用户来说缺乏清洁。
WO2013/098547 A1公开了一种抗菌组合物，其包含季铵化合物以提供表面卫生处理或消毒，这些化合物倾向于沉积在表面上作为可见残余物，所述可见残余物给用户留下经处理的表面尚未清洁的印象。这是因为表面出现条纹，并且光泽较差。此外，经处理的表面可能感觉到轻微粘性，这进一步给用户留下清洁较差的印象。另外，季铵化合物通常与存在于组合物中的清洁表面活性剂相互作用。结果是，减少组合物的抗微生物功效，或者必须存在更高水平的抗微生物活性物质。由于环境原因，在清洁产品中使用高水平的季铵抗菌活性物质可能是不期望的。另一个缺点是它们的水平受到用于食品接触表面的产品的限制。
因此，仍然需要提供良好清洁、光泽和持久消毒的消毒剂组合物。优选地，组合物将适用于接触食物的表面。
发明内容
根据本发明的第一方面，提供一种消毒剂清洁组合物。所述组合物包含双吡啶鎓烷烃抗微生物剂和聚合物。组合物提供杀生物残余性。
根据本发明的第二方面，提供了本发明的组合物向表面特别是硬质表面提供杀生物残余性的用途。
根据本发明的第三方面，提供了一种用本发明的第一方面的组合物处理的制品。制品呈包含一个或多个非织造层的一次性或部分可重复使用的垫托物(substrate)的形式。制品为表面、特别是硬质表面提供卫生处理。制品在本文中有时被称为“本发明的制品”。
相对于本发明的第一方面描述的本发明的组合物的元素作必要修改之后适用于本发明的其他方面。
具体实施方式
除非另外指明，本文所用的所有百分比、比率和比例均按组合物的重量百分比计。除非另外明确指出，所有平均值均按组合物的重量计算。除非另外指明，所有比率均计算为重量/重量水平。
除非另外指明，所有的测量均在25℃下进行。
除非另外指明，否则所有组分或组合物水平均是就该组分或组合物的活性部分而言，且不包括可能存在于此类组分或组合物的可商购获得的来源中的杂质，例如残余溶剂或副产物。
如本文所用，术语“微生物(microbe)”或“微生物(microbial)”应解释为是指由微生物学家研究或在经处理的制品(treated article)的使用环境中发现的任何微观生物体。此类生物体包括但不限于细菌和真菌以及其他单细胞生物，诸如真菌(mould)、霉菌(mildew)和藻类。病毒颗粒和其他感染原(infectious agent)也包括在术语微生物中。
“抗微生物”进一步应理解为涵盖杀微生物和抑微生物(microbiostatic)性质两者。也就是说，术语包括微生物杀伤导致微生物数量减少，以及微生物生长的延迟效应，其中数量可保持或多或少恒定(但允许轻微增加/减少)。
为了便于讨论，本说明书使用术语抗微生物来表示广谱活性(例如针对细菌和真菌)。当谈到针对特定微生物或分类等级的功效时，将使用更专用的术语(例如，抗真菌剂，表示特别是针对真菌生长的功效)。使用以上示例，应当理解，针对真菌的功效并不以任何方式排除相同抗微生物组合物可展示针对另一类微生物的功效的可能性。
残余杀生物性质是指在环境保护局(EPA)批准的用于硬质、无孔表面上的干燥产品残余物的24小时残余自消毒(RSS)测试方法(EPA#01-1A)中实现至少99.9％的微生物减少。也就是说，显示残余杀生物性质的本发明组合物能够在12次磨蚀和5次再接种的24小时测试体系后提供至少99.9％的微生物减少。
消毒剂组合物
本发明涉及一种消毒剂组合物。所述组合物包含双吡啶鎓烷烃，优选地奥替尼啶二盐酸盐，和聚合物。
组合物还可包含载剂，优选地水、表面活性剂、pH调节剂和芳香剂以及其他组分。优选地，组合物呈液体形式，更优选地呈水性溶液的形式，优选地组合物包含按组合物的重量计超过80％、更优选地超过90％、并且尤其是95％至99％的水。所述组合物优选地为碱性的并且具有至14，优选地10至13的pH。
经由在EPA批准的24小时RSS测试方法(EPA#01-1A)中提供至少99.9％的微生物减少，该组合物被配制成具有表面消毒和残余杀生物性质至少24小时。可通过喷涂、滚涂、雾化、擦拭或其他手段将组合物施用到表面上。组合物充当表面消毒剂，杀死表面上存在的感染性微生物至少24小时。
一旦干燥，液体制剂就在表面上留下残余的保护膜。残余膜具有杀生物性质，使其能够在应用后的延长时间段内保持表面免受微生物污染的保护。
消毒剂组合物赋予膜在将膜沉积在经处理的表面上之后快速杀死细菌和其他病菌至少24小时的能力。快速杀死通常是指约30秒至约5分钟的时间段。膜将保留在表面上，并且能够耐受对表面的多次触摸和磨损。在将组合物施用到表面之后，表面呈现良好的光泽概况。
抗微生物剂
本发明的组合物包含双吡啶鎓烷烃，诸如GB1533952中描述的那些。术语双吡啶鎓烷烃包括通式(I)或(II)的双[4-(取代-氨基)-1-吡啶鎓]烷烃
其中
Y为具有4至18个碳原子的亚烷基或烷基基团；
R表示具有6至18个碳原子的烷基基团或具有5至7个碳原子的环烷基基团或具有或不具有卤素取代的苯基基团，并且A为一种阴离子或几种阴离子。
A可为一价、二价或多价阴离子，例如氯离子、溴离子、磷酸根或原硅酸根。A还可为具有式R4-COO～的有机酸，其中R4为氢、羟基或C1-C40烷基。
本发明的双吡啶鎓烷烃包括式(I)和(II)化合物的各种原型，诸如GB1533952和DE19647692A1中公开的那些。
其它合适的双吡啶鎓烷烃包括双吡啶胺的有机酸盐，其中有机酸含有约4至约30个碳原子，诸如WO2014100807中描述的那些。合适的有机酸包括但不限于羧酸，诸如(C1-C40)烷烃羧酸，例如，未被取代或被卤素取代的，饱和或不饱和二羧酸，诸如羟基羧酸，诸如氨基酸，诸如(C1-C40)烷基磺酸。可以衍生盐的另外有机酸包括例如乙酸、丙酸、磷酸、乙醇酸、丙酮酸、草酸、马来酸、丙二酸、琥珀酸、富马酸、酒石酸、柠檬酸、苯甲酸、肉桂酸、扁桃酸、甲烷磺酸、乙烷磺酸、对甲苯磺酸、甘草酸、水杨酸、硬脂酸、膦酸、三氟乙酸、氰乙酸、4-氰基苯甲酸、2-氯苯甲酸、2-硝基苯甲酸、苯氧基乙酸、苯磺酸。优选的是硬脂酸盐，诸如双吡啶鎓烷烃二硬脂酸盐。
优选的双吡啶鎓烷烃为奥替尼啶二盐酸盐(R＝正辛基，Y＝正癸基；A＝2×Cl，下文“奥替尼啶”CAS号70775-75-6)。
抗微生物剂仅需要以杀菌有效量存在，其可为按组合物的重量计少至0.001％至小于1％。在更优选的组合物中，清洁组合物包含按组合物的重量计约0.0025至约0.5％，更优选地0.005％至0.15％的水平的抗微生物剂。
使用EN13697(化学消毒剂杀菌活性试验)的方法，在5分钟内，杀菌有效量的抗微生物剂通常导致至少log 4的金黄色葡萄球菌减少。
聚合物
组合物优选地包含按组合物的重量计约0.0005％至约5％、优选约0.001％至约4％的聚合物。更优选地按组合物的重量计约0.05％至约3％的聚合物。聚合物为聚乙烯亚胺(PEI)或者包含下文所列单体中的至少一种。如果聚合物不为PEI，则聚合物包含至少一种选自以下的单体：
a)阳离子单体，所述阳离子单体选自二烯丙基二甲基氯化铵(DADMAC)；季铵化乙烯基咪唑(QVI)；季铵化乙烯基吡啶鎓(QVPy)；以及具有以下式：
H2C═CR1—CO—NH—R2—N+R3R4R5X-
或
H2C═CR1—CO—O—R2—N+R3R4R5X-
其中R1表示氢原子或具有1至4个C原子的烷基基团，R2表示具有1至12个C原子的直链或支链亚烷基基团，并且R3、R4和R5彼此独立地表示氢原子、具有1至18个C原子的烷基基团、或苯基基团，并且X表示来自卤素、硫酸根或烷基硫酸根、氢氧根、磷酸根、乙酸根、甲酸根或铵的阴离子。特别优选的是类型
a)的单体，其中R1表示甲基基团，R2表示CH2—CH2—CH2基团，并且R3、R4和R5各自表示甲基基团。X-表示合适的抗衡离子，诸如卤离子、氢氧根、硫酸根、硫酸氢根、磷酸根、甲酸根或乙酸根，优选氯离子。特别优选单体3-三甲基铵丙基甲基丙烯酰胺氯化物(MAPTAC)。
b)中性单体，所述中性单体选自2-(二甲基氨基)乙基甲基丙烯酸酯(DMAEMA)；N-异丙基丙烯酰胺(NIPAM)；2-二乙基氨基乙基甲基丙烯酸酯(DEAEMA)；3-二甲基氨基丙基甲基丙烯酰胺(DMAPMAm)；3-二甲基氨基-2,2-二甲基丙基丙烯酰胺(DMADMPAm)；C1-C4烷基丙烯酸酯；乙烯基咪唑；和乙烯基吡啶
c)两性离子单体，所述两性离子单体选自磺基丙基二甲基氨乙基甲基丙烯酸酯(SPE)、磺基丙基二甲基氨丙基甲基丙烯酰胺(SPP)、磺基羟丙基二甲基氨丙基甲基丙烯酰胺(SHPP)、磺基羟丙基二甲基氨乙基甲基丙烯酰胺(SHPE)
d)任选地，共聚单体，所述共聚单体选自丙烯酸(AA)；甲基丙烯酸(MA)；丙烯酰胺；甲基丙烯酰胺和2-丙烯酰胺-2-甲基丙烷磺酸(AMPS)；以及
e)它们的混合物。
优选的聚合物包含3-三甲基铵丙基甲基丙烯酰胺氯化物(MAPTAC)单体。
优选地，聚合物包含选自a)至d)的至少两种或三种单体。优选地，本发明的组合物的聚合物包含四种单体。
单体组分a)
该类型的单体遵循通式：
H2C═CR1—CO—NH—R2—N+R3R4R5X-
其中R1表示氢原子或具有1至4个C原子的烷基基团，R2表示具有1至12个C原子的直链或支链亚烷基基团，并且R3、R4和R5彼此独立地表示氢原子、具有1至18个C原子的烷基基团、或苯基基团，并且X表示来自卤素、硫酸根或烷基硫酸根、氢氧根、磷酸根、乙酸根、甲酸根或铵的阴离子。特别优选的是类型a)的单体，其中R1表示甲基基团，R2表示CH2—CH2—CH2基团，R3、R4和R5各自表示甲基基团。X-表示合适的抗衡离子，诸如卤离子、氢氧根、硫酸根、硫酸氢根、磷酸根、甲酸根或乙酸根，优选氯离子。特别优选单体3-三甲基铵丙基甲基丙烯酰胺氯化物(MAPTAC)。
单体组分b)
根据本发明的聚合物中含有的第二单体构造嵌段(building block)是具有以下通式的含氮、烯键式不饱和化合物：
H2C═CR6—CO—NR7R8
其中R6表示氢原子或具有1至4个C原子的烷基基团，并且R7和R8彼此独立地各自表示氢原子、具有1至4个C原子的烷基基团、或C3-C6环烷基基团，其中规定R7和R8不同时表示氢。单体b)包含一些丙烯酰胺。特别优选的是N-异丙基丙烯酰胺，也以缩写NIPAM已知。
单体组分c)
作为第三组分c)，烯键式不饱和酸和它们的盐诸如丙烯酸或甲基丙烯酸是合适的。丙烯酸(AA)是此处特别优选的单体。特别合适的盐是碱金属和铵盐。
单体组分d)
该类型的单体遵循通式：
H2C═CR—CO—NH—CR′R″R″′—SO3H
及其盐，尤其是碱金属和铵盐，其中R、R′、R″和R″′彼此独立地表示氢原子或具有1至4个C原子的烷基(亚烷基)基团。此处作为类型d)的单体构造嵌段特别优选的是具有通式或H2C═CR—CO—NH—CR′R″R″′—SO3H的分子，其中尤其是衍生物2-丙烯酰胺-2-甲基丙烷-磺酸(AMPS)是合适的。
除了上述a)至d)之外，另外的单体构造嵌段可存在于根据本发明的聚合物中，其中此处尤其优选含氮单体。示例是二甲基二烯丙基氯化铵(DADMAC)、2-二甲基氨基乙基(甲基)丙烯酸酯(DMAE(M)A)、2-二乙基氨基-乙基(甲基)丙烯酸酯、3-二甲基氨基丙基(甲基)丙烯酰胺(DMAP(M)A)、3-二甲基-氨基-2,2-二甲基丙基丙烯酰胺(DMADMPA)以及它们的衍生物，这些衍生物可通过质子化或季铵化获得，尤其是2-三甲基-铵甲基(甲基)丙烯酸酯氯化物和3-二乙基甲基铵丙基-丙烯酰胺氯化物。
根据本发明的聚合物是水溶性的，即，至少0.1g的聚合物在20℃下可溶于100ml水中。聚合物是两性的，即聚合物具有酸性和碱性亲水性基团两者，并且根据条件显示出酸性或碱性性能。根据本发明的聚合物优选地具有通过水性凝胶渗透色谱法(GPC)测量的平均分子量(重均分子量，Mw)，其中光散射检测(SEC-MALLS)在10,000Da至500,000Da的范围内。优选地，聚合物的分子量介于50,000Da和350,000Da之间，并且尤其介于100,000Da和250,000Da之间。特别优选的范围可落在110,000Da和140,000Da之间。
多种单体构造嵌段a)至d)优选地以某些选定的定量比率彼此发生。在每种情况下，优选的是含有相对于组分a)和c)过量的(均以摩尔为基础并且基于组分的重量)组分(b)的聚合物。此处优选这样的聚合物，其中单体a)、b)和c)之间的摩尔比在1:10:1至5:10:5的范围内，并且优选地在4:10:1至4.10:3的范围内，并且尤其在3:8:2至3:8:1的范围内。特别优选尤其是这样的聚合物，其中组分a)与b)之间的摩尔比为1:10至1:1，并且尤其是1:5至1:1。
基于相应单体的摩尔％，优选地存在20％至30％的单体a)、50％至70％的单体b)和10％至20％的单体c)。优选地，单体构造嵌段c)和d)以2:1至1:2的摩尔比同时存在，但特别优选地以1:1的比率存在。具有四种不同单体构造嵌段的特别优选的聚合物的摩尔比a):b):c):d)为2:4:1:1至1:10:1:1。特别优选的比率为3:8:1:1。
优选的聚合物特别是这样的聚合物，其中单体a)选自具有通式的化合物，其中R′表示甲基基团，R2表示具有3个C原子的亚烷基基团，R3、R4和R5分别表示甲基基团，并且X表示氯离子，单体b)选自具有通式的化合物，其中R6和R7表示氢原子，并且R8表示异丙基基团，并且单体c)表示H2C═CR—CO—NH—CR′R″R′″—SO3H及其盐，尤其是碱金属和铵盐，其中R、R′、R″和R″′彼此独立地表示氢原子或具有1至4个C原子的烷基(亚烷基)基团。
根据本发明的此类聚合物可通过各种聚合方法产生。例如，这些聚合物可通过溶液聚合或本体聚合(bulk polymerization)产生。优选地，这些聚合物通过溶液聚合产生，从而在溶剂和/或水中聚合单体，其中单体和由它们产生的聚合物都是可溶的。另外，聚合可通过最初或在单体流入下，间歇、半连续或连续地获取单体的总量来进行。优选地，聚合在具有或不具有单体流入的情况下作为间歇聚合进行。用于产生用于本发明组合物的聚合物的方法的细节存在于US 2007/0179265 A1中。
特别优选的并且因此本发明的另一方面是含有四种不同单体a)、b)、c)和d)的在20℃下可溶于水的聚合物，其中单体a)和b)以1:1至1:10的摩尔比存在，并且另外存在单体c)和d)，其中作为单体a)，优选3-三甲基铵丙基-甲基丙烯酰胺氯化物(MAPTAC)，作为单体b)，优选N-异丙基-丙烯酰胺(NIPAM)，作为单体c)，优选丙烯酸(AA)和/或甲基丙烯酸(MA)，并且作为单体d)，优选2-丙烯酰胺-2-甲基-1-丙磺酸(AMPS)，其中规定单体c)以基于水溶性聚合物总重量的最大25重量％的量存在于水溶性聚合物中。优选根据前述描述的聚合物，其中单体c)的重量分数总计为小于15重量％，并且尤其是等于或小于10重量％。单体c)的优选重量范围为5至25。
优选的聚合物在20℃下是水溶性的，并且含有单体MAPTAC、NIPAM、AA和AMPS，它们的重量比为25％至45％MAPTAC、40％至70％NIPAM、1％至15％AA和1％至15％AMPS，其中规定百分比的总和为100。
对于这些聚合物，上述优选的摩尔比也是适用的，并且聚合物内单体的优选重量比也是适用的，即，因此单体a)、b)和c)或d)之间的摩尔比位于1:10:1至5:10:5的范围内，并且优选地在4:10:1至4:10:3的范围内，并且尤其是在3:8:2至3:8:1的范围内。特别优选的聚合物含有摩尔比为3:8:1:1的单体a)、b)、c)和d)。
基于聚合物的重量比为20重量％至30重量％的单体a)、50重量％至70重量％的单体b)和10重量％至20重量％的单体c)和/或d)，其中规定百分比的总和为100。如果单体c)和d)同时存在于聚合物中，则它们优选以1:1的重量比存在。如上文详细描述的所选聚合物的平均分子量优选地在10,000至500,000的范围内。
另选地，聚合物可以是聚乙烯亚胺(PEI)，用于本文的优选PEI是分子量为10,000至50,000，更优选地15,000至40,000Da的支链未改性PEI。
适用于本发明的组合物的聚乙烯亚胺(PEI)可具有通式，尽管实际式不是完全已知的：
(-NHCH2CH2-)x[-N(CH2CH2NH2)CH2CH2-]y
其中x为1至120,000，优选地2至60,000，更优选地3至24,000的整数，并且y为1至60,000，优选地2至30,000，更优选地3至12,000的整数。聚乙烯亚胺的具体示例为PEI-700、PEI-800、PEI-1000、PEI-1500、PEI-1800、PEI-2000、PEI-2500、PEI-5000、PEI-10,000、PEI-25,000、PEI50,000、PEI-70,000、PEI-500,000等，
其中所述整数表示聚合物的平均分子量。如此指定的PEI可通过Aldrich获得。
PEI可以商品名Lupasol(R)从BASF公司商购获得(也以Polymin(R)出售)。这些化合物可以制备为各种分子量和产物活性。PEI也可以商品名Epomin(R)从PolymerEnterprises或Nippon Shokubai(日本)商购获得。
适用于本发明的PEI的其它频繁使用的商业商品名包括但不限于Polyazinidine(R)、Corcat(R)、Montek(R)、Polymin P(R)等。
表面活性剂
本发明的组合物可包含按组合物的重量计0.1％至5％的表面活性剂。表面活性剂有助于清洁组合物并将其铺展在待清洁的表面上。
醇烷氧基化非离子表面活性剂
合适的醇烷氧基化非离子表面活性剂根据式RO-(A)nH，其中：R是伯C4至C18，优选C6至C16，更优选C6至C14支链或直链烷基链，或C6至C28烷基苯链；A是乙氧基或丙氧基或丁氧基单元或其混合物，并且其中n为1至30，优选地1至15，更优选地3至12，甚至更优选地3至8。用于本文的优选R链是C6至C16直链或支链烷基链。
合适的支链烷氧基化醇可选自：C4-C10烷基支链烷氧基化醇以及它们的混合物。支链烷氧基化醇可来源于C4-C10烷基支链醇的烷氧基化作用，它们选自：具有一个或多个C1-C4支链基团的C4-C10一元伯醇(primary mono-alcohol)。
通过C4-C10一元伯醇，意指一元伯醇的主链总共具有4至10个碳原子。C4-C10一元伯醇可选自：甲基丁醇、乙基丁醇、甲基戊醇、乙基戊醇、甲基己醇、乙基己醇、丙基己醇、二甲基己醇、三甲基己醇、甲基庚醇、乙基庚醇、丙基庚醇、二甲基庚醇、三甲基庚醇、甲基辛醇、乙基辛醇、丙基辛醇、丁基辛醇、二甲基辛醇、三甲基辛醇、甲基壬醇、乙基壬醇、丙基壬醇、丁基壬醇、二甲基壬醇、三甲基壬醇以及它们的混合物。
C4-C10一元伯醇可选自：乙基己醇、丙基己醇、乙基庚醇、丙基庚醇、乙基辛醇、丙基辛醇、丁基辛醇、乙基壬醇、丙基壬醇、丁基壬醇以及它们的混合物。
优选地，C4-C10一元伯醇选自：乙基己醇、丙基己醇、乙基庚醇、丙基庚醇以及它们的混合物。
C4-C10一元伯醇最优选地是乙基己醇和丙基庚醇。
在支链烷氧基化醇中，该一个或多个C1-C4支链基团可在如从起始醇的羟基基团测量的C1至C3位置、优选C1至C2位置、更优选C2位置处被取代为C4-C10一元伯醇。
支链烷氧基化醇可包含1至14个、优选2至7个、更优选4至6个乙氧基化物单元，以及任选地1至9个、优选2至7个、更优选4至6个丙氧基化物单元。
支链烷氧基化醇优选地是乙氧基化至4至6的度并且丙氧基化至4至6的度的2-乙基己-1-醇，更优选地，醇首先丙氧基化并且然后乙氧基化。另一优选的支链烷氧基化醇是2-烷基-1-烷醇，诸如具有1至14个、优选2至7个、更优选3至6个乙氧基化物或乙氧基化物丙氧基化物单元的烷氧基化C10格尔伯特醇(guerbet alcohol)。
合适的支链烷氧基化醇的非限制性示例是例如可从陶氏公司(DOW)商购获得的
EH3、EH6和EH9，以及可从巴斯夫公司(BASF)购得的/>
XP烷氧基化格尔伯特醇和/>
XL乙氧基化格尔伯特醇。
本文优选的直链醇烷氧基化非离子表面活性剂是具有C8直链烷基链、C10直链烷基链、C12直链烷基链、C8至C10直链烷基链的混合物、C10至C12直链烷基链的混合物、C9至C11直链烷基链的混合物和8个或更少乙氧基化物单元、优选3至8个乙氧基化物单元的烷氧基化非离子表面活性剂。
用于本文的合适的直链烷氧基化非离子表面活性剂的非限制性示例是
91-2.5(R是C9和C11烷基链的混合物，n为2.5)、/>
91-5(R是C9至C11烷基链的混合物，n为5)；/>
91-10(R是C9至C11烷基链的混合物，n为10)；GreenbentineDE60(R是C10直链烷基链，n为6)；Marlipal 10-8(R是C10直链烷基链，n为8)；Neodol 91-8(R是C9至C11烷基链的混合物，n为8)；/>
KBE21(R是C12和C14烷基链的混合物，n为21)；Lutensol ON30(R是C10直链烷基链，n为3)；Lutensol ON50(R是C10直链烷基链，n为5)；Lutensol ON70(R是C10直链烷基链，n为7)；Novel 610-3.5(R是C6至C10直链烷基链的混合物，n为3.5)；Novel 810FD-5(R是C8至C10直链烷基链的混合物，n为5)；Novel 10-4(R是C10直链烷基链，n为4)；Novel 1412-3(R是C12至C14直链烷基链的混合物，n为3)；/>
11-5(R是C11直链烷基链，n为5)；/>
11-21(R是直链和支链C11烷基链的混合物，n为21)或它们的混合物。
烷氧基化非离子表面活性剂可以是仲醇乙氧基化物，诸如例如具有以下所示的通式并且可由陶氏公司商购获得的TergitolTM-15-S表面活性剂。
优选的仲醇乙氧基化物表面活性剂具有3-9个EO单元。
另一合适的烷氧基化非离子表面活性剂是烷基乙氧基烷氧基醇，优选地其中分子的烷氧基部分是丙氧基或丁氧基或丙氧基-丁氧基。更优选的烷基乙氧基烷氧基醇具有式(II)：
其中：
R为具有8至16个碳原子的支链或非支链烷基基团；
R1为具有1至5个碳原子的支链或非支链烷基基团；
n为1至10；并且m为6至35。
R优选地为12至15个，优选13个碳原子。R1优选地为具有1至2个碳原子的支链烷基基团。n优选地为1至5。m优选地为8至25。优选地，式(II)的乙氧基化烷氧基化非离子表面活性剂的重均分子量为500g/mol至2000g/mol，更优选地600g/mol至1700g/mol，最优选地800g/mol至1500g/mol。
乙氧基化烷氧基化非离子表面活性剂可以是聚氧化烯共聚物。聚氧化烯共聚物可以是混嵌(block-heteric)乙氧基化烷氧基化非离子表面活性剂，尽管嵌段-嵌段表面活性剂是优选的。合适的聚氧化烯嵌段共聚物包括式(III)的环氧乙烷/环氧丙烷嵌段聚合物：
(EO)x(PO)y(EO)x，或
(PO)x(EO)y(PO)x
其中EO表示环氧乙烷单元，PO表示环氧丙烷单元，并且x和y是详细说明每摩尔产物中环氧乙烷和环氧丙烷的平均摩尔数的数字。此类材料倾向于具有比大多数非离子表面活性剂更高的分子量，并且因此可以在1000g/mol和30000g/mol之间的范围内，但是该分子量应高于2200g/mol并且优选地低于13000g/mol以符合本发明。聚合非离子表面活性剂的分子量的优选范围为2400道尔顿至11500道尔顿。巴斯夫公司(Mount Olive,N.J.)制造一组合适的衍生物，并且在Pluronic商标下销售它们。这些衍生物的示例是分子量分别为6600g/mol、2450g/mol和11400g/mol的Pluronic(商标)F77、L62和F88。
其它合适的乙氧基化烷氧基化非离子表面活性剂描述于Surfactant Scienceand Technology，第三版，Wiley Press，ISBN 978-0-471-68024-6的第7章。
最优选地，烷氧基化非离子表面活性剂选自：2-丙基庚基EO8(Lutensol XL89-巴斯夫公司)；2-丙基庚基EO5(Lutensol XL50-巴斯夫公司)；C10醇EO5(Lutensol ON 50-巴斯夫公司)；C10-醇EO7(Lutensol ON 70-巴斯夫公司)；C8-C10 EO5(Novel 810FD5沙索公司(Sasol))；C10 EO4(Novel 10-4沙索公司)；Tergitol 15-S-3；Tergitol 15-S-5；Tergitol15-S-7；和乙基己醇PO5EO6(Ecosurf EH6-陶氏公司)。
烷基多葡糖苷
烷基多葡糖苷是本领域众所周知的可生物降解的非离子表面活性剂，并且可用于本发明的组合物中。合适的烷基多葡糖苷可具有通式CnH2n+1O(C6H10O5)xH，其中n优选地为8至16，更优选地8至14，并且x为至少1。合适的烷基多葡糖苷表面活性剂的示例是来自陶氏公司的TRITONTM烷基多葡糖苷；来自巴斯夫公司的Agnique PG、Disponil APG和Glucopon烷基多葡糖苷。优选的烷基多葡糖苷表面活性剂是其中n为8至12，更优选地8至10的那些，诸如例如Triton CG50(陶氏公司)。
氧化胺
合适的氧化胺表面活性剂包括：R1R2R3NO，其中R1、R2和R3各自独立地为具有1至30个碳原子的饱和或不饱和的、取代或未取代的直链或支链烃链。优选的氧化胺表面活性剂是具有下式的氧化胺：R1R2R3NO，其中R1为包含1至30个，优选地6至20个，更优选地8至16个碳原子的烃链，并且其中R2和R3独立地为包含1至4个碳原子、优选地1至3个碳原子，并且更优选地为甲基基团的饱和或不饱和的、取代或未取代的直链或支链烃链。R1可为饱和或不饱和的、取代或未取代的直链或支链烃链。
高度优选的氧化胺为C8二甲基氧化胺、C10二甲基氧化胺、C12二甲基氧化胺、C14二甲基氧化胺、以及它们的混合物。C8二甲基氧化胺可以商品名
OC从科莱恩公司(Clariant)商购获得；C10二甲基氧化胺可以商品名/>
K-10从科莱恩公司商购获得；C12二甲基氧化胺可以商品名/>
LA从科莱恩公司商购获得和以商品名Empigen OB从亨斯迈公司(Huntsman)商购获得；C14氧化胺可以商品名Empigen OH25从亨斯迈公司商购获得。其他合适的氧化胺表面活性剂是可以商品名Genaminox CHE从科莱恩公司获得的椰油酰基二乙氧基氧化胺，和可以商品名Empigen OS/A从亨斯迈公司商购获得的椰油酰胺丙基氧化胺(cocamydopropyl amine oxide)。特别优选的氧化胺表面活性剂是C10二甲基氧化胺，诸如Genaminox K-10。
烷基葡糖酰胺表面活性剂
本发明的组合物可包含烷基葡糖酰胺表面活性剂。葡糖酰胺表面活性剂为非离子表面活性剂，其中亲水部分(氨基-糖衍生物)和疏水部分(脂肪酸)经由酰胺键连接。这导致化学键联，该化学键联在碱性条件下高度稳定。特别优选的烷基葡糖酰胺表面活性剂为具有式(I)的N-烷基-N-酰基葡糖酰胺：
其中Ra为具有6至22个碳原子的直链或支链的、饱和或不饱和的烃基基团，并且Rb为C1-C4烷基。特别优选地，式(I)中的Rb为甲基基团。这些葡糖酰胺表面活性剂的非限制性示例为：N-辛酰基-N-甲基葡糖酰胺、N-壬酰基-N-甲基葡糖酰胺、N-癸酰基-N-甲基葡糖酰胺、N-十二烷酰基-N-甲基葡糖酰胺、N-椰油酰基-N-甲基葡糖酰胺，可以商品名GlucoPureFoam从科莱恩公司获得，N-月桂酰基/肉豆蔻酰基-N-甲基葡糖酰胺(可以商品名GlucoPureDeg从科莱恩公司获得)和N-辛酰基/癸酰基-N-甲基葡糖酰胺，可由科莱恩公司以商品名GlucoPure Wet获得。
烷基葡糖胺表面活性剂
本发明的组合物可包含烷基葡糖酰胺表面活性剂。
这些表面活性剂描述于EP16184415和US20190055496中。
两性离子表面活性剂和两性表面活性剂
硬质表面清洁组合物可包含两性表面活性剂、两性离子表面活性剂以及它们的混合物。合适的两性离子表面活性剂通常含有基本上等量比例的阳离子基团和阴离子基团两者，以便在使用的pH下呈电中性，并且在本领域中已知。两性离子表面活性剂的一些常见示例描述于美国专利2,082,275、2,702,279和2,255,082中。
合适的两性离子表面活性剂包括甜菜碱，诸如烷基甜菜碱、烷基酰胺甜菜碱、咪唑啉盐甜菜碱(amidazoliniumbetaine)、磺基甜菜碱(INCI磺基甜菜碱)以及磷酸甜菜碱。
合适的甜菜碱为式(Ia)的烷基甜菜碱、式(Ib)的烷基酰胺甜菜碱、式(Ic)的磺基甜菜碱和式(Id)的酰胺磺基甜菜碱；
R1-N+(CH3)2-CH2COO- (Ia)
R1-CO-NH(CH2)3-N+(CH3)2-CH2COO- (Ib)
R1-N+(CH3)2-CH2CH(OH)CH2SO3- (Ic)
R1-CO-NH-(CH2)3-N+(CH3)2-CH2CH(OH)CH2SO3- (Id)
其中R1为饱和或不饱和的C6-C22烷基残基，优选地C8-C18烷基残基。特别优选的是式Ia的甜菜碱，诸如例如N-烷基-N-二甲基甜菜碱，如由亨斯迈公司以商品名Empigen BB出售的甜菜碱。
合适的甜菜碱和磺基甜菜碱的示例如下根据[INCI]命名：杏仁油酰胺丙基甜菜碱、野杏油酰胺丙基甜菜碱、鳄梨油酰胺丙基甜菜碱、巴巴苏油酰胺丙基甜菜碱、山嵛酰胺丙基甜菜碱、山嵛基甜菜碱、甜菜碱、低芥酸菜子油酰胺丙基甜菜碱、辛酰/癸酰氨丙基甜菜碱、肉碱、鲸蜡基甜菜碱、椰油酰胺乙基甜菜碱、椰油酰胺丙基甜菜碱、椰油酰胺丙基羟基磺基甜菜碱、椰油甜菜碱、椰油羟基磺基甜菜碱、椰油/油酰胺丙基甜菜碱、椰油磺基甜菜碱、癸基甜菜碱、二羟基乙基油基甘氨酸盐、二羟基乙基大豆油甘氨酸盐、二羟基乙基硬脂基甘氨酸盐、二羟基乙基牛脂甘氨酸盐、聚二甲基硅氧烷丙基PG-甜菜碱、芥酸酰胺丙基羟基磺甜菜碱、氢化牛脂基甜菜碱、异硬脂酰胺丙基甜菜碱、月桂酰胺丙基甜菜碱、月桂基甜菜碱、月桂基羟基磺基甜菜碱、月桂基磺基甜菜碱、牛奶酰胺丙基甜菜碱、貂油酰胺丙基甜菜碱、肉豆蔻酰胺丙基甜菜碱、肉豆蔻基甜菜碱、油酰胺丙基甜菜碱、油酰胺丙基羟基磺基甜菜碱、油基甜菜碱、橄榄油酰胺丙基甜菜碱、棕榈油酰胺丙基甜菜碱、棕榈酰胺丙基甜菜碱(Palmitan idopropyl betaines)、棕榈酰肉碱、棕榈仁油酰胺丙基甜菜碱、聚四氟乙烯乙酰氧基丙基甜菜碱、蓖麻醇酸酰胺丙基甜菜碱、芝麻酰胺丙基甜菜碱、大豆油酰胺丙基甜菜碱、硬脂酰胺丙基甜菜碱、硬脂基甜菜碱、牛脂酰胺丙基甜菜碱、牛脂酰胺丙基羟基磺基甜菜碱、牛脂甜菜碱、牛脂二羟乙基甜菜碱、十一烯酸酯酰胺丙基甜菜碱和小麦胚芽油酰胺丙基甜菜碱。
如果组合物包含两性离子表面活性剂，则该表面活性剂优选地是式Ia的甜菜碱，诸如例如N-烷基-N-二甲基甜菜碱，如由亨斯迈公司以商品名Empigen BB出售的甜菜碱，烷基二甲基甜菜碱。
两性表面活性剂可为阳离子或阴离子的，具体取决于组合物的pH。合适的两性表面活性剂包括十二烷基β-丙氨酸、N-烷基牛磺酸，诸如通过十二烷基胺与羟乙基磺酸钠反应制备的那些，如美国专利2,658,072中所教导的；N-高级烷基天冬氨酸，诸如美国专利2,438,091中所教导的。其他合适的两性表面活性剂是由索尔维公司(Solvay)-Novecare以商品名Miranol出售的产品，诸如例如，月桂酰两性基乙酸钠(Miranol Ultra L-32E)、硬脂酰两性基乙酸钠(Miranol DM)、椰油酰两性基二乙酸二钠(Miranol C2m Conc NP)、月桂酰两性基二乙酸二钠(Miranol BM Conc)、辛酰两性基二丙酸二钠(Miranol JBS)、混合C8两性基羧酸钠(Miranol JEM Conc)和辛酰两性基羟丙基磺酸钠(Miranol JS)。合适的两性表面活性剂的其他非限制性示例是辛酰两性基二乙酸二钠(Mackam 2CY 75-索尔维公司Novecare)、辛基亚氨基二丙酸酯(Ampholak YJH40-阿克苏诺贝尔公司(Akzo Nobel))、月桂亚氨基二丙酸钠(Mirataine H2C-HA-索尔维公司Novecare)和月桂酰两性基羟丙基磺酸钠(Mackam LS-索尔维公司Novecare)。
其它合适的附加的表面活性剂可存在于McCutcheon’s Detergents andEmulsifiers,North American Ed.1980中。
阴离子表面活性剂
如果存在阴离子表面活性剂，则其优选以低水平存在，即按组合物的重量计低于0.05％。
用于本文的特别优选的表面活性剂包括非离子表面活性剂，特别是支链醇烷氧基化物，更特别地乙氧基化至4至6的度并且丙氧基化至4至6的度的2-乙基己-1-醇，更优选地，醇首先被丙氧基化并且然后乙氧基化，和2-烷基-1-烷醇诸如具有1至14个，优选2至8个，更优选3至6个乙氧基化物或乙氧基化物-丙氧基化物单元的烷氧基化C10格尔伯特醇。其他特别优选的非离子表面活性剂包括具有C8直链烷基链、C10直链烷基链、C12直链烷基链、C8至C10直链烷基链的混合物、C10至C12直链烷基链的混合物、C9至C11直链烷基链的混合物和8个或更少乙氧基化物单元、优选3至8个乙氧基化物单元的直链醇烷氧基化非离子表面活性剂。最优选地，烷氧基化非离子表面活性剂选自：2-丙基庚基EO8(Lutensol XL89-巴斯夫公司)；2-丙基庚基EO5(Lutensol XL50-巴斯夫公司)；C10醇EO5(Lutensol ON 50-巴斯夫公司)；C10醇EO7(Lutensol ON 70-巴斯夫公司)；C8-C10醇EO5(Novel 810FD5沙索公司)；C10醇EO4(Novel 10-4沙索公司)；和2-乙基-己醇PO5EO6(Ecosurf EH6-陶氏公司)。
用于本文的其他特别优选的表面活性剂包括直链氧化胺表面活性剂，特别是C8-C12二甲基氧化胺，更特别地C10二甲基氧化胺；烷基二甲基甜菜碱表面活性剂，更特别地N,N-二甲基-N-十二烷基甘氨酸甜菜碱(Empigen BB-亨斯迈公司)；烷基葡糖酰胺表面活性剂，诸如N-烷基-N-酰基葡糖酰胺，优选地N-癸酰基-N-甲基葡糖胺和由科莱恩公司以名称
和/>
出售的烷基葡糖酰胺表面活性剂；烷基多葡糖苷表面活性剂，更特别地C8至C12烷基多葡糖苷，更优选地C8至C10烷基多葡糖苷，诸如例如Triton CG50(陶氏公司)。
pH调节剂
根据目标用途，用于家庭护理用途的本发明液体制剂可能需要适当的pH条件。例如，如果液体产品用于厨房区域，则可能需要高pH产品，以便有效地去除该区域中常见的油脂污垢。如果产品用于浴室区域，则肥皂残渣和硬水沉积物可能是主要问题。在这种情况下，低pH产品可更适合于此目的。对于可添加到本发明的液体组合物中的pH调节剂的类型没有限制。可使用的pH调节剂的示例包括但不限于三乙醇胺、二乙醇胺、单乙醇胺、氢氧化钠、碳酸钠、氢氧化钾、碳酸钾、碳酸钙、柠檬酸、乙酸、盐酸、氨基磺酸、硫酸等。
除了上述组分以外，另外的功能组分可包含在本发明的组合物中。另外的组分包括但不限于螯合剂、增容剂、偶联剂、抗蚀剂、流变改性剂、芳香剂、着色剂、防腐剂、UV稳定剂、光学增白剂和活性成分指示剂。
本文中优选的组合物包括包含以下的组合物：
i)按所述组合物的重量计约0.05％至约2％的奥替尼啶二盐酸盐；
ii)按所述组合物的重量计0.1％至约4％的所述聚合物，优选地所述聚合物包含以下的单体：三甲基铵丙基甲基丙烯酰胺氯化物；N-异丙基丙烯酰胺；丙烯酸和/或甲基丙烯酸及其盐；和2-丙烯酰胺-2-甲基-1-丙烷-磺酸；或分子量为10,000至40,000Da的PEI；
iii)按组合物的重量计0.05％至2％的表面活性剂，该表面活性剂选自：氧化胺表面活性剂、非离子表面活性剂以及它们的混合物，优选C10二甲基氧化胺和乙基己醇PO5EO6的混合物；
iv)按组合物的重量计约0.2％至约3％的碱，优选地单乙醇胺；以及
v)约95％至99％的水。
本文中优选的组合物包括包含以下的组合物：
i)按所述组合物的重量计约0.05％至约2％的奥替尼啶二盐酸盐；
ii)按所述组合物的重量计0.1％至约4％的所述聚合物，优选地所述聚合物包含以下的单体：三甲基铵丙基甲基丙烯酰胺氯化物；N-异丙基丙烯酰胺；丙烯酸和/或甲基丙烯酸及其盐；和2-丙烯酰胺-2-甲基-1-丙烷-磺酸；或分子量为10,000至40,000Da的PEI；
iii)按组合物的重量计0.05％至2％的非离子表面活性剂；
iv)按组合物的重量计约0.2％至约3％的酸，优选地柠檬酸；以及
v)约95％至99％的水。
组合物的施用
组合物可通过多种手段施用。如果喷涂，则组合物有利地可以在具有喷涂器的常规瓶中供应。喷涂器可为触发式喷涂器。作为触发式喷涂器的一种选择，也可使用气溶胶将液体制剂递送到表面上。另外的施用手段包括但不限于通过各种施用装置雾化、滚涂、刷涂、拖涂和使用擦拭物。在本发明的范围内，还可制造擦拭产品，该擦拭产品包含本发明的一种或多种消毒剂制剂或预先用该一种或多种消毒剂制剂进行预处理，以例如用于现货销售或使用。
为了对污染的表面进行消毒，喷涂液体制剂直到区域被完全覆盖。随后可用干布或纸巾擦干湿的制剂。
本发明还涉及用根据本发明的方面的消毒剂制剂处理的制品。
实施例
实施例1：表1示出了根据本发明的组合物(组合物A至F)。组合物用作硬质表面消毒剂清洁剂。它们提供24小时残余自消毒(RSS)性能与优异的清洁和良好的表面光泽外观结合。成分表示为总组合物的重量百分比。
实施例2：在1.0％活性物质下采用不同聚合物的含奥替尼啶的组合物的性能(所 有其它组合物成分保持恒定)。
在不存在任何聚合物的情况下(无聚合物对照)，组合物未通过实现24小时RSS并且提供相对于参考制剂的更弱清洁性能。
含有基于本发明的聚合物的组合物均通过24小时RSS测试，而本发明范围之外的聚合物例如聚(2-乙基噁唑啉)(PEOX)没有通过。
所有三种性能属性(24小时RSS、光泽和清洁)的最佳执行组合物是含有聚(MAPTAC-AA-AMPS-NIPAM)的组合物。
*乙烯基吡咯烷酮
(1)基于EPA01-1A(24小时残余自消毒，12个磨蚀循环)的方案使用产气肠杆菌(Enterobacter aerogene)作为测试生物体并且玻璃作为测试表面。通过结果是指在12个磨损方案结束时至少99.9％细菌减少(log 3)。
(2)产品施用和擦拭后黑色、有光泽的瓷砖的光泽等级。专门小组成员根据以下标度在视觉上评估干燥砖的成条纹外观；0＝无条纹，1＝非常轻微的条纹，2＝轻微条纹，3＝轻微至中度条纹，4＝中度条纹，5＝中度至重度条纹，6＝重度条纹。
(3)清洁釉质表面上的烘焙/聚合油脂。将制剂施用于海绵，并且记录完全去除污垢的擦拭冲程数。然后相对于标准硬质表面清洁剂(指数100)将冲程数指数化，其中较高的指数暗示较好的清洁。
本文所公开的量纲和值不应理解为严格限于所引用的精确数值。相反，除非另外指明，否则每个此类量纲旨在表示所述值以及围绕该值功能上等同的范围。例如，公开为“40mm”的量纲旨在表示“约40mm”。
Claims (10)
1.一种消毒剂清洁组合物，其不含季铵抗微生物活性物质，所述组合物包含：
i)双吡啶鎓烷烃抗微生物活性物质；
ii)聚合物，其中所述聚合物包含以下的单体：三甲基铵丙基甲基丙烯酰胺氯化物；N-异丙基丙烯酰胺；丙烯酸和/或甲基丙烯酸及其盐；和2-丙烯酰胺基-2-甲基-1-丙烷-磺酸。
2.根据权利要求1所述的组合物，其中所述双吡啶鎓烷烃抗微生物活性物质为奥替尼啶二盐酸盐。
3.根据权利要求1所述的组合物，所述组合物包含按所述组合物的重量计0.1％至5％的所述聚合物。
4.根据权利要求1所述的组合物，所述组合物包含按所述组合物的重量计0.05％至5％的所述双吡啶鎓烷烃抗微生物活性物质。
5.根据权利要求1所述的组合物，所述组合物包含按所述组合物的重量计0.05％至5％的表面活性剂，其中所述表面活性剂选自：烷基多葡糖苷、脂肪醇烷氧基化物、甜菜碱、烷基葡糖胺、烷基葡糖酰胺、氧化胺以及它们的混合物。
6.根据权利要求1所述的组合物，所述组合物包含按所述组合物的重量计0.1％至10％的pH调节剂。
7.根据权利要求1所述的组合物，所述组合物包含：
i)按所述组合物的重量计0.05％至2％的奥替尼啶二盐酸盐；
ii)按所述组合物的重量计0.1％至4％的所述聚合物；
iii)按所述组合物的重量计0.05％至2％的表面活性剂，所述表面活性剂选自：氧化胺表面活性剂、非离子表面活性剂以及它们的混合物；
iv)按所述组合物的重量计0.2％至3％的pH调节剂；以及
v)90％至99％的水。
8.根据权利要求1所述的组合物，其中所述组合物向表面赋予杀生物残余性。
9.根据权利要求1所述的组合物的用途，其中所述组合物向表面提供杀生物残余性。
10.一种用根据权利要求1至8中任一项所述的组合物处理的制品，其中
所述制品呈擦拭物的形式或呈任何一次性垫托物的形式。
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| US20230111060A1 (en) * | 2021-10-07 | 2023-04-13 | The Clorox Company | Quat-Based Compostable and Biodegradable Premoistened Cleaning and Disinfecting Wipes System |
| WO2023166151A1 (en) * | 2022-03-03 | 2023-09-07 | Specialty Operations France | Compositions and methods for long lasting disinfection with mixed solvent systems |
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