CN114075397A - High-temperature-resistant water-based paint and furnace door liner applying same - Google Patents
High-temperature-resistant water-based paint and furnace door liner applying same Download PDFInfo
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- CN114075397A CN114075397A CN202010909063.4A CN202010909063A CN114075397A CN 114075397 A CN114075397 A CN 114075397A CN 202010909063 A CN202010909063 A CN 202010909063A CN 114075397 A CN114075397 A CN 114075397A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/14—Homopolymers or copolymers of vinyl fluoride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C15/00—Details
- F24C15/02—Doors specially adapted for stoves or ranges
- F24C15/028—Stoves doors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
The invention relates to a high-temperature resistant water-based paint and a furnace door liner applying the same, wherein a colorant adopted by the high-temperature resistant water-based paint is environment-friendly and nontoxic copper-chromium black, aldehyde-free adhesive polyvinyl fluoride dispersion liquid is adopted to adhere the copper-chromium black on the surface of a glass fiber tube, a styrene-based aminosilane coupling agent is adopted to improve the adhesion of epoxy resin and an inorganic substance (glass fiber cloth), and a dispersing agent is alkyl polyoxyethylene ether to improve the dispersibility of a system, so that the prepared paint can exist stably, the sedimentation of the paint is prevented, the color development performance of water-based color paste in the paint is improved, and the gloss of a coating film is improved.
Description
Technical Field
The invention relates to the technical field of coatings, in particular to a high-temperature-resistant water-based coating and a furnace door liner applying the same.
Background
The use of the oven in various countries in the world has been long, and the semi-airtight sealing piece between the oven and the oven door is a consumable accessory, and usually, the oven door liner is a strip-shaped glass fiber cloth tube taking a stainless steel wire as a framework and is placed at the joint of the oven body and the oven door through a positioning hook. The glass fiber cloth tube is generally white, and because the oven usually has large oil smoke when in use, the white glass fiber cloth tube is not suitable for being applied to an oven door, and the color of the glass fiber cloth tube is easy to change due to smoking or oil stain, so that the use and the attractiveness are affected. And the furnace door liner is in a high-temperature environment, so the furnace door liner needs to be colored, and the design of the high-temperature resistant water-based paint which has good wettability and uniform dyeing on the surface of the glass fiber cloth tube is a technical problem which needs to be solved urgently by the technology in the field.
Disclosure of Invention
The invention aims to provide a high-temperature-resistant water-based paint with good surface wettability and uniform dyeing and a furnace door liner applying the paint.
In order to solve the technical problems, the high-temperature resistant water-based paint provided by the invention is prepared by the following method:
A. preparing silane hydrolysate: adding 25 parts by mass of water into a container, adding 5 parts by mass of anhydrous acetic acid to obtain an acetic acid solution with the pH value of 3.5-4.0, adding 100 parts by mass of styryl amino trimethoxy silane, stirring for at least 5 minutes, and standing for not less than 2 hours at the temperature of 15-20 ℃ to obtain silane hydrolysate.
B. Preparing copper-chromium black powder: and grinding the copper-chromium black particles to obtain copper-chromium black powder with the particle size of about 3 um.
C. Adding 90 parts by mass of water into a stirring impregnation container for stirring, sequentially adding 6 parts by mass of copper-chromium black powder, 9 parts by mass of polyvinyl fluoride dispersion liquid and 10 parts by mass of silane hydrolysis liquid into the impregnation container, adding 5 parts by mass of alkyl polyoxyethylene ether as dispersion liquid, and stirring for 3-4 hours to obtain the high-temperature-resistant water-based paint.
Further, in the step B, the copper-chromium black particles are ground in a ball mill.
An oven door liner is obtained by dipping the high-temperature resistant water-based paint.
Further, the furnace door liner is put into high-temperature-resistant water-based paint for 30 to 45 seconds, taken out and put into a drying oven, wherein the drying temperature is 360 to 375 ℃, and the drying time is 15 to 20 minutes.
Further, the oven door liner was dried at 375 ℃ for 15 minutes.
The invention has the technical effects that: (1) compared with the prior art, the high-temperature-resistant water-based paint is mainly applied to a household oven, is used as a semi-sealing oven door liner to be coated on the surface of a glass fiber tube, and is used as a high-temperature protection coating layer, a novel black paint of a copper-chromium black system is stable in a normal-temperature environment, can resist temperature for 2 hours and 10 hours, still can not be decolorized, has small color difference, has excellent performance of slight color fading due to friction, and completely meets the temperature-resistant requirement of the oven door liner under the extreme condition; (2) the high-temperature-resistant water-based paint adopts the environment-friendly and non-toxic copper-chromium black as a coloring agent, adopts aldehyde-free adhesive polyvinyl fluoride dispersion liquid to adhere the copper-chromium black on the surface of a glass fiber tube, adopts a styryl aminosilane coupling agent to improve the adhesion of epoxy resin and inorganic matters (glass fiber cloth), and improves the dispersibility of a system by adopting alkyl polyoxyethylene ether, so that the prepared paint can stably exist, the sedimentation of the paint is prevented, the color development performance of water-based color paste in the paint is improved, and the gloss of a coating film is improved; (3) the high-temperature-resistant water-based paint has good wettability and uniform dyeing, can resist temperature for 2-10 hours at 430 ℃, does not change color or decolor, and can stably exist in air at normal temperature, wherein the particle size of the prepared system is in the range of 1-4 mu m, the requirement of the paint is met, and the high-temperature-resistant water-based paint is also an important factor for excellent stable coloring performance of the system.
Drawings
The invention is described in further detail below with reference to the drawings of the specification:
FIG. 1 is an SEM image of copper chromium black particles after grinding;
FIG. 2 is a comparison of temperature resistant replicates of BX-3 pigment dyed fiberglass tubing and American graphite milk dyed fiberglass tubing;
FIGS. 3a, 3b, and 3c are high temperature heat-resistant discoloration test reports from Ningbo materials of Chinese academy of sciences and engineering research institute.
Detailed Description
Example 1
As shown in fig. 1 to 3, the high temperature resistant water-based paint of the present embodiment is prepared by the following method:
A. preparing silane hydrolysate: adding 25 parts by mass of water into a container, adding 5 parts by mass of anhydrous acetic acid to obtain an acetic acid solution with the pH value of 3.5-4.0, adding 100 parts by mass of styryl amino trimethoxy silane, stirring for 5 minutes, and standing for 2 hours at 15 ℃ to obtain silane hydrolysate.
B. Preparing copper-chromium black powder: grinding the copper-chromium black particles in a ball mill to obtain copper-chromium black powder with the particle size of about 3 um; the particle size of the copper-chromium black powder can be observed about 3um by an electron microscope (SEM picture) (see attached figure 1 in the specification), and N is adopted2The absorption-desorption test (BET) is used to determine the information of the particle size distribution and the particle size of the catalyst, and the result shows that 95% of the copper-chromium black has a particle size of not more than 3.82 um.
The copper-chromium black is generally composed of CuO (copper oxide) and Cr2O3The copper-chromium black is produced by the chemical combination reaction of (chromium oxide) at a high temperature of 900 ℃, has a plurality of advantages, wherein the copper-chromium black has pure color and top pure blackness, is the blackest one of all black metal oxide pigments, and has only the blackness which is the carbon black, although the carbon black is the blackest one of all pigments and has good dip dyeing performance, the carbon black is a very good ultraviolet absorbent, so that the temperature of a coloring matter is increased, the aging of resin and the like is accelerated, and the endurable temperature is low, so the carbon black is not an ideal choice;
according to the literature data, the copper-chromium black is not only an environment-friendly and nontoxic pigment, but also has excellent light resistance, weather resistance, chemical stability and heat resistance, and can resist the high temperature of 800 ℃; meanwhile, the paint has the characteristics of solvent resistance, no migration, easy dispersion and the like; from the comprehensive consideration of performances such as price, blackness, high temperature resistance and the like, the copper-chromium black is a coating which is most suitable for mass production, and the application fields of the copper-chromium black are very wide, such as: non-stick pan coatings, industrial coatings, automotive coatings, interior and exterior wall coatings for buildings, engineering machinery coatings, aviation and marine coatings, military camouflage coatings, road marking coatings, rock mass mural coatings, painting coatings, oil coatings, water-based coatings, sun-resistant coatings, weather-resistant coatings, ultraviolet-resistant coatings, high-temperature-resistant coatings, and the like; in the pigment field, the copper chromium black can also be used in the fields of printing ink, glass, enamel, ceramics, sandstone and the like. Therefore, the inorganic metal oxide copper chromium black is undoubtedly the ideal choice in high temperature resistant water borne coating systems.
C. Adding 90 parts by mass of water into a stirring impregnation container for stirring, sequentially adding 6 parts by mass of copper-chromium black powder, 9 parts by mass of polyvinyl fluoride dispersion liquid and 10 parts by mass of silane hydrolysis liquid into the impregnation container, adding 5 parts by mass of alkyl polyoxyethylene ether as dispersion liquid, and stirring for 3-4 hours to obtain the high-temperature-resistant water-based paint.
Wherein, the anhydrous acetic acid (glacial acetic acid) adopts analytically pure anhydrous acetic acid produced by Zhongxing chemical reagent company of Zhejiang, styryl amino trimethoxy silane adopts a DOWSIL Z-6269 silane coupling agent produced by Dow's chemistry, and the copper chromium black granules adopt 2822A copper chromium black produced by Shanghai Hitai new material science and technology company; the polyvinyl fluoride dispersion liquid adopts F60 fluororesin produced by polymer GmbH of Changzhou; the ball mill adopts an F-P8L ball mill produced by Hunan Frekas laboratory instruments, Inc., the JA503 analytical balance produced by Hezhou lucky electronic equipment, Inc. is adopted for weighing, and the dipping container adopts an 85-2A magnetic stirring instrument produced by Jie Ruier electric appliance, Inc. of gold altar.
Example 2
An oven door gasket obtained by impregnating the high temperature resistant water-based paint of example 1.
Example 3
A furnace door liner is prepared by putting the furnace door liner in high-temperature-resistant water-based paint for 30 seconds, fishing out and putting into a drying oven, wherein the drying temperature is 360 ℃, and the drying time is 15 minutes.
The glass fiber tube cloth adopted by the furnace door liner is a dewaxed glass fiber tube produced by Shandong Taishan glass fiber GmbH, and the oven is a 101-1A temperature-controlled oven produced by Shanghai Shannan scientific instruments union plant.
In order to verify the temperature resistance stability and reproducibility of the furnace door liner, the high-temperature-resistant water-based paint is named as BX-3, the furnace door liner is sent to Ningbo materials of Chinese academy of sciences and engineering research institute for 3 times of high-temperature heat-resistant fading tests, the dried furnace door liner is heated at the high temperature of 420 ℃ in a Behck MF-1200C automatic constant-temperature muffle furnace, the temperature is respectively kept for 30 minutes, 1 hour and 2 hours, and meanwhile, the furnace door liner soaked by American Foss graphite milk (company name: Fuchs Lubricants Co., product model: LDP HYDROOGRAF PC) is heated and kept at the same temperature under the same conditions, and the specific test steps are as follows: respectively cutting 2 sections of 10cm BX-3 paint dyed glass fiber tubes and American graphite emulsion dyed glass fiber tubes, putting the tubes into a muffle furnace, setting the temperature at 430 ℃, baking the tubes for half an hour at the high temperature of 430 ℃, taking the tubes out, observing the decolorization conditions of the tubes and the tubes, cooling the tubes, rubbing the tubes on white paper back and forth for 5 times, comparing the decolorization conditions of the tubes and the tubes, and testing the temperature resistance for 2 hours and 10 hours in the same way.
The color difference of the glass fiber tube dyed by the BX-3 coating after being baked for 30 minutes is 1.0 percent, the color difference of the glass fiber tube after 2 hours is 2.5 percent, and the color difference of the glass fiber tube after 10 hours is 3.2 +/-0.3 percent, and the results of the test of resisting the temperature of 430 ℃ for 2 hours and 10 hours show that the color-rubbing-off performance of the glass fiber tube dyed by the BX-3 coating is better than that of the glass fiber tube dyed by the American graphite emulsion, and the test report with the number of 200-07-30-NE-001 in the specific reference from figure 3a to figure 3c is shown.
The applicant also performed 3 batches of high-temperature heat-resistant discoloration tests on the glass fiber tubes dyed by the BX-3 coating and the glass fiber tubes dyed by the American graphite emulsion, the SX-2 automatic constant-temperature control muffle furnace produced by Shanghai Jiacheng instrument equipment factory was adopted, the heating temperature was 420 ℃, after baking for 2 hours, the glass fiber tubes were taken out, the discoloration conditions of the two glass fiber tubes were observed, after cooling, the glass fiber tubes were rubbed back and forth on white paper for 5 times, and the rubbing discoloration conditions of the two glass fiber tubes were compared, the results are shown in figure 2, and the observation in figure 2 shows that the rubbing discoloration performance of the glass fiber tubes dyed by the BX-3 coating is superior to that of the American graphite emulsion glass fiber tube samples.
It should be understood that the above examples are only for clearly illustrating the present invention and are not intended to limit the embodiments of the present invention. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. And are neither required nor exhaustive of all embodiments. And such obvious variations or modifications which fall within the spirit of the invention are intended to be covered by the scope of the present invention.
Claims (5)
1. The high-temperature-resistant water-based paint is characterized by being prepared by the following method:
A. preparing silane hydrolysate: adding 25 parts by mass of water into a container, then adding 5 parts by mass of anhydrous acetic acid to obtain an acetic acid solution with the pH value of 3.5-4.0, then adding 100 parts by mass of styryl amino trimethoxy silane, stirring for at least 5 minutes, and standing for not less than 2 hours at the temperature of 15-20 ℃ to obtain silane hydrolysate;
B. preparing copper-chromium black powder: grinding the copper-chromium black particles to obtain copper-chromium black powder with the particle size of about 3 um;
C. adding 90 parts by mass of water into a stirring impregnation container for stirring, sequentially adding 6 parts by mass of copper-chromium black powder, 9 parts by mass of polyvinyl fluoride dispersion liquid and 10 parts by mass of silane hydrolysis liquid into the impregnation container, adding 5 parts by mass of alkyl polyoxyethylene ether as dispersion liquid, and stirring for 3-4 hours to obtain the high-temperature-resistant water-based paint.
2. The high-temperature resistant water-based paint according to claim 1, wherein in the step B, the copper chromium black particles are ground in a ball mill.
3. An oven door gasket obtained by impregnating the high temperature resistant aqueous coating of claim 1 or 2.
4. The furnace door liner as claimed in claim 3, wherein the furnace door liner is placed in the high temperature resistant water-based paint for 30 seconds to 45 seconds, and then taken out and placed in an oven, wherein the oven temperature is 360 ℃ to 375 ℃, and the oven time is 15 minutes to 20 minutes.
5. The oven door liner according to claim 4, wherein the oven door liner has a drying temperature of 375 ℃ and a drying time of 15 minutes.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
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| CN202010804609X | 2020-08-12 | ||
| CN202010804609 | 2020-08-12 |
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| CN114075397A true CN114075397A (en) | 2022-02-22 |
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