CN108192356A - A kind of carrier model organosilicon adhesion promoter and preparation method thereof - Google Patents
A kind of carrier model organosilicon adhesion promoter and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/16—Halogen-containing compounds
- C08K2003/162—Calcium, strontium or barium halides, e.g. calcium, strontium or barium chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Abstract
The present invention provides a kind of carrier model organosilicon adhesion promoter and preparation method thereof, the carrier model organosilicon adhesion promoter is prepared by the component of following parts by weight:10 50 parts of ethyl orthosilicate, 1 10 parts of amine propyl trimethoxy silicane, 1 10 parts of glycidol ether methyl dimethoxysilane, 1 10 parts of amine ethylamine propyl trimethoxy silicane, 1 10 parts of amine ethylamine hydroxypropyl methyl dimethoxysilane, 0.1 2 parts of catalyst, 0.1 2 parts of neutralizer, 13 parts of dispersant, 1 50 parts of carrier, 15 parts of stabilizer, 1 10 parts of water.Carrier model organosilicon adhesion promoter prepared by the present invention greatly improves surface of plastic products adhesive force, the material can by way of physical blending extrusion modified plastics, improve frosting adhesive force, improve feel, the antiwear characteristic of product.
Description
Technical field
The present invention relates to polymeric material fields, more specifically to carrier model organosilicon adhesion promoter and its system
Preparation Method.
Technical background
Nearly more than ten years China's plastics industry rapidly develops, and the wide engineering plastics of domestic application have ABS, PG, PA, POM,
General-purpose plastics has PS, PC, PP, PVC etc..Plastic products are light, high specific surface area, easily batch production, it has also become national economy
With the indispensable material of people's lives.
Plastics are amorphous polymers, it has good comprehensive performance, and can carry out secondary operation to plastic products,
Therefore it is widely used on household electrical appliances, food, toy, medical or similar products.But since the plastics such as PP or PE are nonpolarity
Material has extremely low surface energy, it is difficult to be painted again on surface layer, coating processing, influences subsequent clients to appearance and surface
The requirement of performance.
Coating can adhere on PP plastics, be since there are two types of the presence of effect.One kind is that physical mechanical acts on, PP plastics
Product surface has uniform micro-rough structure, after coating sprays to this micro-roughened surface, in liquid condition with regard to energy
In " hole " that invades micro-rough, it is dry after coating crosslink, paint film just as nail " nail " on PP plastic products, this
It is exactly that mechanical anchor closes lock effect.Another kind is exactly chemical bond, contains certain polar group in PP molecules, due to being applied
The erosion of solvent in material, these polar groups are activated, and chemical bond are formed with some polar groups in coating, with coating
Curing, the two crosslink.Meanwhile the erosion of the solvent in coating also makes PP frostings generate pit, so as to also be machinery
Anchor closes lock effect and creates condition.
Invention content
(1) technical problems to be solved
To solve problem above, it can greatly improve surface of plastic products adhesive force the object of the present invention is to provide a kind of
Carrier model organosilicon adhesion promoter, the material can physical blending extrusion by way of modified plastics, improve plastic table
Face adhesive force improves feel, the antiwear characteristic of product.
(2) technical solution
First aspect present invention provides a kind of carrier model organosilicon adhesion promoter, and carrier model organosilicon adhesive force promotes
Agent is prepared by the component of following parts by weight:10-50 parts of ethyl orthosilicate, shrinks at 1-10 parts of amine propyl trimethoxy silicane
1-10 parts of glycerin ether methyl dimethoxysilane, 1-10 parts of amine ethylamine propyl trimethoxy silicane, amine ethylamine hydroxypropyl methyl
1-10 parts of dimethoxysilane, 0.1-2 parts of catalyst, 0.1-2 parts of neutralizer, 1-3 parts of dispersant, 1-50 parts of carrier, stabilizer
1-5 parts, 1-10 parts of water.
Further,
The catalyst is citric acid, formic acid.
The neutralizer is potassium hydroxide, sodium hydroxide.
The carrier for white carbon, calcium carbonate, polyethylene glycol, diatomite, carbon black it is one or more.
The stabilizer for sodium carboxymethylcellulose, anhydrous calcium chloride, Carbon Dioxide calcium it is one or more.
The dispersant is organosilicon modified polyether.
Second aspect of the present invention provides a kind of carrier model organosilicon adhesion promoter preparation method, and this method includes successively
Following steps:
1) catalyst and ethyl orthosilicate, amine propyl trimethoxy silicane, amine ethylamine propyl trimethoxy silicane are mixed
After closing uniformly, the mixture of water and glycidol ether methyl dimethoxysilane is slowly added dropwise, time for adding is 1 hour, is added dropwise
After, amine ethylamine propyldimethoxy-silane, 75 DEG C of heating back flow reaction 3 hours are then added, reaction product is light
Yellow transparent liquid, vacuum distillation add in neutralizer, neutralize, and filtering obtains organosilicon adhesion promoter;
2) carrier is added in kneader, is warming up to 100 DEG C, vacuumizes, stirred 1 hour, 70 DEG C are cooled to, by dispersant
It is added thereto, stirs 0.5 hour, organosilicon adhesion promoter is then added in into stirring in batches, form uniform powder, no group
After poly- phenomenon, stabilizer is added in, stirs evenly, obtains carrier model organosilicon adhesion promoter.
Third aspect present invention provides a kind of plastics containing above-mentioned carrier model organosilicon adhesion promoter, comprising
The carrier model organosilicon adhesion promoter of 0.1-5 parts by weight, the plastics of 95-99.9 parts by weight, the plastics are PC or PP.
Fourth aspect present invention provides a kind of preparation method of the plastics containing carrier model organosilicon adhesion promoter, will
Carrier model organosilicon adhesion promoter carries out blending granulation with plastic grain, and blending temperature is no more than 250 DEG C, finds time not
More than 1 minute.
Technical solution provided by the invention has the advantages that:
1st, the present invention forms main chain by the ratio control of specific functional groups and with two functional groups (amino reactivity)
Structure wherein the fulcrum that four pipes that ginseng has some structural rigidities strong can be rolled into a ball, plays mechanical structure intensity, then connects a part of three pipe energy
The reactive functional groups of other classes of group improve reactivity, the adhesive force between base material can be greatly improved, provide long-term
Adhesive force effect and part feel, antiwear characteristic.
2nd, carrier model organosilicon adhesion promoter of the invention is made every effort to promote organosilicon attachment by special kneading process
It is distributed in powder carrier into agent, is then modified in a manner of mixing extrusion with plastic grain, fundamentally solve plastics
The problem of adhesive force, and the feel of plastics, the characteristics such as wear-resisting can be improved.
3rd, the application method of carrier model organosilicon adhesion promoter of the invention is simple and effective, and product is nontoxic non-hazardous,
Validity is longer, and accommodation is wider.
Specific embodiment
Ethyl orthosilicate is purchased from Changzhou Wujin Heng Ye Chemical Co., Ltd.s.Amine propyl trimethoxy silicane, amine ethylamine
Propyl trimethoxy silicane, amine ethylamine hydroxypropyl methyl dimethoxysilane are purchased from Nanjing flag space chemistry Science and Technology Ltd..Contracting
Water glycerin ether methyl dimethoxysilane is purchased from Qufu morning twilight Chemical Co., Ltd..Citric acid, formic acid, potassium hydroxide, hydroxide
Sodium is purchased from Yantai reagent Co., Ltd in pairs.White carbon, calcium carbonate, polyethylene glycol, diatomite, carbon black, sodium carboxymethylcellulose,
Anhydrous calcium chloride, Carbon Dioxide calcium, organosilicon modified polyether are purchased from Jiangsu Hai'an petrochemical industry.Low density polyethylene (LDPE), Taiwan modeling
Expect Industries, Inc.Coating, Anyang market day show coating Co., Ltd.
Test row 1
1) synthesis of organosilicon adhesion promoter:By citric acid 0.1g and ethyl orthosilicate 10g, amine propyl trimethoxy
Silane 1g, amine ethylamine propyl trimethoxy silicane 1g, after mixing, are slowly added dropwise water 1g and glycidol ether methyl dimethoxy
The mixture of oxysilane 1g, time for adding are 1 hour, after being added dropwise, then add amine ethylamine dimethylamine oxygroup
Silane 1g, 75 DEG C of heating back flow reaction 3 hours, reaction product is light yellow transparent liquid, and vacuum distillation adds in potassium hydroxide
0.1g is neutralized, and filtering obtains organosilicon adhesion promoter;
2) synthesis of carrier model organosilicon adhesion promoter:White carbon 1-50g is added in kneader, is warming up to 100
DEG C, it vacuumizes, stirs 1 hour, cool to 70 DEG C, organosilicon modified polyether 1g is added thereto, stir 0.5 hour, then will
Organosilicon adhesion promoter 30g is added three times stirring, forms uniform powder, after soilless sticking phenomenon, adds in Carbon Dioxide calcium
1g is stirred evenly, and obtains carrier model organosilicon adhesion promoter.
Embodiment 2
1) synthesis of organosilicon adhesion promoter:By formic acid 2g and ethyl orthosilicate 50g, amine propyl trimethoxy silicane
10g, amine ethylamine propyl trimethoxy silicane 10g, after mixing, are slowly added dropwise water 10g and glycidol ether methyl dimethoxy
The mixture of oxysilane 10g, time for adding are 1 hour, after being added dropwise, then add amine ethylamine dimethylamine oxygroup
Silane 10g, 75 DEG C of heating back flow reaction 3 hours, reaction product is light yellow transparent liquid, and vacuum distillation adds in sodium hydroxide)
2g is neutralized, and filtering obtains organosilicon adhesion promoter;
2) synthesis of carrier model organosilicon adhesion promoter:White carbon 50g is added in kneader, is warming up to 100 DEG C,
It vacuumizes, stirs 1 hour, cool to 70 DEG C, organosilicon modified polyether 3g is added thereto, stir 0.5 hour, it then will be organic
30g points of 5 batches of silicon adhesion promoter, which add in, to be stirred, formation uniform powder, after soilless sticking phenomenon, adds in sodium carboxymethylcellulose
5g is stirred evenly, and obtains carrier model organosilicon adhesion promoter.
Embodiment 3
1) synthesis of organosilicon adhesion promoter:By formic acid 0.2g and ethyl orthosilicate 20g, amine propyl trimethoxy silicon
Alkane 4g, amine ethylamine propyl trimethoxy silicane 3g, after mixing, are slowly added dropwise water 6g and glycidol ether methyl dimethoxy oxygen
The mixture of base silane 3.5g, time for adding are 1 hour, after being added dropwise, then add amine ethylamine dimethylamine oxygroup
Silane 6.5g, 75 DEG C of heating back flow reaction 3 hours, reaction product is light yellow transparent liquid, and vacuum distillation adds in sodium hydroxide
1g is neutralized, and filtering obtains organosilicon adhesion promoter;
2) synthesis of carrier model organosilicon adhesion promoter:White carbon 20g, calcium carbonate 10g are added in kneader, risen
Temperature is vacuumized to 100 DEG C, is stirred 1 hour, is cooled to 70 DEG C, organosilicon modified polyether 1.3g is added thereto, and stirring 0.5 is small
When, then the 30g points of 3 batches additions of organosilicon adhesion promoter are stirred, formation uniform powder, after soilless sticking phenomenon, added in
Sodium carboxymethylcellulose 0.5g, anhydrous calcium chloride 1g, stir evenly, and obtain carrier model organosilicon adhesion promoter.
Embodiment 4
1) synthesis of organosilicon adhesion promoter:By citric acid 1.1g and ethyl orthosilicate 40g, amine propyl trimethoxy
Silane 8g, amine ethylamine propyl trimethoxy silicane 2.5g, after mixing, are slowly added dropwise water 7g and glycidol ether methyl two
The mixture of methoxy silane 2g, time for adding are 1 hour, after being added dropwise, then add amine ethylamine dimethylamine oxygen
Base silane 3g, 75 DEG C of heating back flow reaction 3 hours, reaction product is light yellow transparent liquid, and vacuum distillation adds in potassium hydroxide
0.8g is neutralized, and filtering obtains organosilicon adhesion promoter;
2) synthesis of carrier model organosilicon adhesion promoter:By white carbon 3g, calcium carbonate 5g, Macrogol 6000
20g, carbon black 5g are added in kneader, are warming up to 100 DEG C, are vacuumized, and are stirred 1 hour, are cooled to 70 DEG C, will be organic-silicon-modified poly-
Ether 3g is added thereto, and stirs 0.5 hour, 30g points of 3 batches of organosilicon adhesion promoter then are added in stirring, are formed uniform
Powder after soilless sticking phenomenon, adds in sodium carboxymethylcellulose 2g, stirs evenly, obtain carrier model organosilicon adhesion promoter.
Embodiment 5
1) synthesis of organosilicon adhesion promoter:By formic acid 1.5g and ethyl orthosilicate 20g, amine propyl trimethoxy silicon
Alkane 3g, amine ethylamine propyl trimethoxy silicane 4g, after mixing, are slowly added dropwise water 9g and glycidol ether methyl dimethoxy oxygen
The mixture of base silane 1g, time for adding are 1 hour, after being added dropwise, then add amine ethylamine dimethylamine oxygroup silicon
Alkane 3g, 75 DEG C of heating back flow reaction 3 hours, reaction product is light yellow transparent liquid, and vacuum distillation adds in sodium hydroxide 1g,
It neutralizes, filtering obtains organosilicon adhesion promoter;
2) synthesis of carrier model organosilicon adhesion promoter:4500 50g of polyethylene glycol is added in kneader, is heated up
It to 100 DEG C, vacuumizes, stirs 1 hour, cool to 70 DEG C, organosilicon modified polyether 3g is added thereto, stirring 0.5 hour, so
By organosilicon adhesion promoter 30g, 3 additions are stirred in batches afterwards, formation uniform powder, after soilless sticking phenomenon, add in stabilizer
Sodium carboxymethylcellulose 1g, stirs evenly, and obtains carrier model organosilicon adhesion promoter.
Test example
1st, the preparation of sheet material
Test example 1~5:Respectively by the carrier model organosilicon adhesion promoter of the Examples 1 to 5 of 3g, common silane with
97g low density polyethylene (LDPE)s (LDPE) particle carries out blending at no more than 250 DEG C and is granulated 1 hour, is extruded into sheet material, goes out the time not
More than 1 minute.
Comparative example:The common silane of 3g and 97g low density polyethylene (LDPE)s (LDPE) particle are blended at no more than 250 DEG C
It is granulated 1 hour, is extruded into sheet material, go out the time no more than 1 minute.
2nd, the preparation of coating
Specimen sample is prepared by the way of flow coat.By the above sheet of ready 98mm × 98mm × 3mm, surface is used
Anti-static dust-proof cloth wiped clean, spray paint, finishing coat is made to be uniformly coated on sheet surface, thickness 2mm.Room temperature surface drying 1h
Afterwards, cure 2h in 130 DEG C of drying oven, up to coating after cooling.
The formula of priming paint:It is 1 with mass ratio:1 one butyl acetate 95g of toluene dissolving 5gCPP, stand more than half a day, treat
CPP can be fully swollen by solvent, reheats mixture being dissolved into solution.
The reference formulation of finishing coat:Everbright fast yellow 12g, DFA1580 25g, BS1201 40g, DF133 10g, wetting dispersing agent
In right amount, appropriate levelling agent, appropriate antifoaming agent, diluent 10g.The fineness of all coating is all 2O~25 μm.
3rd, coating performance is tested
The test of coating performance carries out after forming a film 7 days.
Adhesion performance of coating:It is tested by GB/T9286-1998;
Coating pencil hardness performance:It is tested by GB/T6739-2006;
The resistance to alcohol performance of coating:Model is placed in absolute ethyl alcohol, is impregnated 1 hour at ambient temperature, is taken out, dries,
The variation of coating is observed, judges the resistance to alcohol performance of coating;
Coating water boiling resistance:Model is placed in 80 DEG C of deionized waters, is impregnated 1 hour, is taken out, dries, observing samples apply
The variation of layer;
Coating abrasion performance is tested:By the standards of QB2506-2001, uniformly wiped back and forth under 500g counterweights with 0000# steel wool
It wipes, the number wiped during cut occurs in calculating.
The wearability of coating:Sample is placed under the 0000# steel wool for being placed with 500g loads, sample surfaces are carried out back and forth
Friction 40 times, it is excellent to remember 0~5 cut, and 5~10 cuts are good, and 10 or more cuts are poor, judge to apply according to cut quantity
The wearability of layer.
Performance comparison is as follows:
Conclusion:1. the adhesive force for the coating being coated on common PP can only achieve 2~3 grades, expected mark is not achieved
Standard in the adhesive force of coating being coated on PP made of the accelerating agent for being added to the present invention at 0~1 grade, reaches industry production
The requirement of product, the levelability of coating is fine, is not in shrinkage cavity and serious lifting phenomenon, surface drying time is in 4min or so.2. it tries
If the resin single choice thermoplastic acrylic resin tested, the adhesive force of coating is poor, ethyl alcohol impregnate after coating peeling, come off
Seriously, this shows that the adhesion between the coating and thermoplastic acrylic resin that prepare is poor so that coating is resistance to alcohol repellency poor;But
After being addition adhesion promoter, though appearance of coat after curing, without significant change, performance change is notable.
Claims (9)
1. a kind of carrier model organosilicon adhesion promoter, it is characterised in that carrier model organosilicon adhesion promoter by weighing as follows
The component of amount part is prepared:10-50 parts of ethyl orthosilicate, 1-10 parts of amine propyl trimethoxy silicane, glycidol ether methyl
1-10 parts of dimethoxysilane, 1-10 parts of amine ethylamine propyl trimethoxy silicane, amine ethylamine hydroxypropyl methyl dimethoxy silicon
1-10 parts of alkane, 0.1-2 parts of catalyst, 0.1-2 parts of neutralizer, 1-3 parts of dispersant, 1-50 parts of carrier, 1-5 parts of stabilizer, water 1-
10 parts.
2. carrier model organosilicon adhesion promoter according to claim 1, which is characterized in that the catalyst is lemon
Acid, formic acid.
3. carrier model organosilicon adhesion promoter according to claim 1, which is characterized in that the neutralizer is hydrogen-oxygen
Change potassium, sodium hydroxide.
4. carrier model organosilicon adhesion promoter according to claim 1, which is characterized in that the carrier is hard charcoal
Black, calcium carbonate, polyethylene glycol, diatomite, carbon black it is one or more.
5. carrier model organosilicon adhesion promoter according to claim 1, which is characterized in that the stabilizer is carboxylic first
Base sodium cellulosate, anhydrous calcium chloride, Carbon Dioxide calcium it is one or more.
6. carrier model organosilicon adhesion promoter according to claim 1, which is characterized in that the dispersant is organic
Silicon-modified polyether.
7. a kind of preparation method of carrier model organosilicon adhesion promoter, which is characterized in that this method includes following step successively
Suddenly:
1) catalyst and ethyl orthosilicate, amine propyl trimethoxy silicane, amine ethylamine propyl trimethoxy silicane are mixed equal
After even, the mixture of water and glycidol ether methyl dimethoxysilane is slowly added dropwise, time for adding is 1 hour, is added dropwise
Afterwards, amine ethylamine propyldimethoxy-silane, 50-90 DEG C of heating back flow reaction 3 hours are then added, reaction product is yellowish
Color transparency liquid, vacuum distillation add in neutralizer, neutralize, and filtering obtains organosilicon adhesion promoter;
2) carrier is added in kneader, is warming up to 100 DEG C, vacuumizes, stirred 1 hour, cool to 70 DEG C, dispersant is added in
Wherein, it stirs 0.5 hour, organosilicon adhesion promoter is then added in into stirring in batches, form uniform powder, soilless sticking is existing
As rear, addition stabilizer stirs evenly, obtains carrier model organosilicon adhesion promoter.
8. a kind of plastics containing above-mentioned carrier model organosilicon adhesion promoter, which is characterized in that include 0.1-5 parts by weight
Carrier model organosilicon adhesion promoter, the plastics of 95-99.9 parts by weight, the plastics be PC or PP.
9. a kind of preparation method of the plastics containing carrier model organosilicon adhesion promoter, which is characterized in that this method includes
Following steps:Carrier model organosilicon adhesion promoter and plastic grain are subjected to blending granulation, blending temperature is no more than 250
DEG C, it finds time no more than 1 minute.
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CN110437657A (en) * | 2019-07-05 | 2019-11-12 | 惠州瑞德新材料科技股份有限公司 | A kind of adhesion promoter and preparation method |
CN115109480A (en) * | 2022-07-25 | 2022-09-27 | 江苏海晟涂料有限公司 | High-performance middle coating for metal surface |
CN115449295A (en) * | 2022-09-15 | 2022-12-09 | 朝阳市加华电子有限公司 | Underwater outboard cable penetrating seal enhancing liquid |
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