CN114058099A - Environment-friendly fly ash packaging material and manufacturing method thereof - Google Patents

Environment-friendly fly ash packaging material and manufacturing method thereof Download PDF

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Publication number
CN114058099A
CN114058099A CN202010777744.XA CN202010777744A CN114058099A CN 114058099 A CN114058099 A CN 114058099A CN 202010777744 A CN202010777744 A CN 202010777744A CN 114058099 A CN114058099 A CN 114058099A
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Prior art keywords
fly ash
environment
friendly
chimney
packaging material
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CN202010777744.XA
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Chinese (zh)
Inventor
陈宏宗
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Ningbo Environmental Protection Paper Co ltd
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Ningbo Environmental Protection Paper Co ltd
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Priority to CN202010777744.XA priority Critical patent/CN114058099A/en
Publication of CN114058099A publication Critical patent/CN114058099A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
    • C08L23/0815Copolymers of ethene with aliphatic 1-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2217Oxides; Hydroxides of metals of magnesium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/325Calcium, strontium or barium phosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/005Additives being defined by their particle size in general
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Wrappers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

An environment-friendly fly ash packing material comprises 25-40 wt% of fly ash, 25-40 wt% of inorganic mineral powder, 25-40 wt% of plastic and 1-2 wt% of auxiliary agent; the fly ash, the inorganic mineral powder, the plastic and the auxiliary agent are mixed and granulated to form a granular material, and the granular material is extruded through special design to form the fly ash environment-friendly packaging material. A method for manufacturing the environment-friendly fly ash packaging material is also provided. The environment-friendly fly ash packaging material provided by the invention is prepared from fly ash taken from a chimney of a coal-fired power plant, a chimney of a fuel-fired power plant, a chimney of an incinerator, a chimney of a coal-fired boiler or a chimney of a fuel-fired boiler, so that the fly ash can be reused, and the waste treatment amount of the fly ash is reduced. The fly ash belongs to a product electrically recycled by a fire furnace, has higher strength and fire resistance than calcium carbonate, is close to ceramic strength, but cannot be used as a solvent for iron making.

Description

Environment-friendly fly ash packaging material and manufacturing method thereof
Technical Field
The invention relates to an environment-friendly packaging material; in particular to an environment-friendly packaging material prepared from fly ash and a preparation method thereof.
Background
With the rising of environmental awareness and the establishment of the concept of resource recycling, modern people increasingly pay more attention to whether the environment is properly protected and whether byproducts generated by industrial and electric operation can be recycled.
Taking coal-fired power generation as an example, the annual output of coal ash in a coal-fired thermal power plant is up to millions of tons during operation. The fly ash is collected from the chimney of the coal-fired thermal power plant, and the bottom ash is collected from the furnace bottom of the boiler of the coal-fired thermal power plant. Specifically, the fly ash can be obtained from an electromagnetic dust collector in a boiler of a coal-fired thermal power plant.
Whether the bottom ash or the fly ash is mostly digested in a land filling manner, the bottom ash or the fly ash which is not in good condition is buried directly in the land filling manner, so that serious land pollution is caused, and the buried land cannot be used in the next decades.
As known from related researches, fly ash is most commonly used as an additive of cement or concrete and can also be used as a filler of flowable backfill soil or general backfill soil; in recent research, fly ash is used as a slow-release fertilizer after being sintered.
However, as is clear from the above, fly ash is not effectively used in a wide variety of fields because the fly ash is not digested to a low degree in other application fields than as an additive for cement/concrete and a filler for backfill.
Disclosure of Invention
In view of the above, the present invention provides an environment-friendly packaging material of fly ash, which is prepared by blending fly ash and plastic and extruding the mixture to form an environment-friendly packaging material of fly ash; it can be used as packing paper or decorative paper.
The invention achieves the aim, and the environment-friendly fly ash packaging material provided by the invention comprises 25-40 wt% of fly ash, 25-40 wt% of inorganic mineral powder, 25-40 wt% of plastic and 1-2 wt% of auxiliary agent; the fly ash, the inorganic mineral powder, the plastic and the auxiliary agent are mixed and granulated to form a granular material, and the granular material can be processed to form the fly ash environment-friendly packaging material.
Another objective of the present invention is to provide a method for manufacturing an environment-friendly fly ash packing material, which comprises at least the following steps:
mixing and granulating 25-40 wt% of fly ash, 25-40 wt% of inorganic mineral powder, 25-40 wt% of plastic and 1-2 wt% of auxiliary agent to form a granular material; and
and processing the granular material to form the environment-friendly fly ash packaging material.
The invention has the effects that the fly ash, the inorganic mineral powder and the plastic are mixed and processed to form the fly ash environment-friendly packaging material; the fly ash can be used as a light and thin packaging paper or a decorative paper which is increased in stiffness, so that the application field of the fly ash is increased, and the aim of increasing the consumption of the fly ash is fulfilled.
Detailed Description
In the embodiment of the invention, the environment-friendly fly ash packaging material comprises 100 wt% of fly ash, 25-40 wt% of inorganic mineral powder, 25-40 wt% of plastic and 1-2 wt% of auxiliary. In the embodiment of the invention, the fly ash environment-friendly packaging material is 100 wt%, the weight percentage of the fly ash is preferably 25 wt% to 30 wt%, the weight percentage of the inorganic mineral powder is preferably 30 wt% to 40 wt%, the weight percentage of the plastic is preferably 30 wt% to 40 wt%, and the weight percentage of the auxiliary agent is preferably 1.5 wt% to 2 wt%. In the embodiment of the invention, the fly ash environment-friendly packaging material is 100 wt%, the weight percentage of the fly ash is preferably 25 wt% to 28 wt%, the weight percentage of the inorganic mineral powder is preferably 35 wt% to 40 wt%, the weight percentage of the plastic is preferably 35 wt% to 40 wt%, and the weight percentage of the auxiliary agent is preferably 1.7 wt% to 2 wt%.
The fly ash, the inorganic mineral powder, the plastic and the auxiliary agent are kneaded to form granular materials, and the granular materials are processed to form the fly ash environment-friendly packaging material.
In the present embodiment, the particle size of the fly ash is between 5 microns and 20 microns, preferably between 7 microns and 17 microns, and more preferably between 10 microns and 15 microns.
In the embodiment of the invention, the fly ash is collected from a chimney or an electromagnetic dust collecting device of a spontaneous combustion coal power plant, a chimney or an electromagnetic dust collecting device of a fuel oil power plant, a chimney or an electromagnetic dust collecting device of an incinerator, a chimney or an electromagnetic dust collecting device of a coal-fired boiler, or a chimney or an electromagnetic dust collecting device of a fuel oil boiler.
In the embodiment of the present invention, the inorganic mineral powder is an inorganic powder with a particle size of 2-10 μm and obtained by grinding natural ore, and the main component of the inorganic powder is calcium carbonate (CaCO)3) Or a calcium phosphate. Because the dispersibility of the fly ash is not good, the fly ash cannot be uniformly dispersed when being mixed with plastics and additives, and the fly ash can be agglomerated, so that the fly ash paper with thinner thickness cannot be manufactured; for example, the fly ash paper material prepared by mixing the fly ash, the plastic and the additives not only has obvious fly ash lumps, but also has a minimum thickness of more than 1 mm. However, in the embodiment of the present invention, after the inorganic mineral powder with a specific weight percentage is added, the dispersibility of the fly ash can be greatly improved, so that the fly ash can be uniformly dispersed when being mixed with the inorganic mineral powder, the plastic and the auxiliary agent, and the agglomeration phenomenon can be avoided, and further the fly ash paper with a thinner thickness can be processed and manufactured. In the embodiment of the invention, the thickness of the fly ash environment-friendly packaging material is less than or equal to 0.2mm, preferably less than or equal to 0.15mm, and more preferably less than or equal toEqual to 0.12 mm. In the embodiment of the invention, the particle size of the inorganic mineral powder is preferably 4-9 micrometers, and more preferably 6-8 micrometers.
In embodiments of the invention, the plastic comprises Polyethylene (PE), polypropylene (PP), High Density Polyethylene (HDPE), Low Density Polyethylene (LDPE), Linear Low Density Polyethylene (LLDPE), metal aromatic linear low density polyethylene (MLLDPE), or a combination thereof. Wherein the Linear Low Density Polyethylene (LLDPE) has a number of carbon atoms comprising C4, C6, C8, or a combination thereof.
In embodiments of the invention, the auxiliary agent comprises an anti-blocking additive (anti-block additive), magnesium oxide, zinc oxide, aluminum oxide, polyolefin wax (polyofefin wax), or combinations thereof.
The manufacturing method of the fly ash environment-friendly packaging material comprises at least the following steps:
step 1, mixing 25-40 wt% of fly ash, 25-40 wt% of inorganic mineral powder, 25-40 wt% of plastic and 1-2 wt% of auxiliary agent to form a granular material; and
and 2, processing the granular material to form the fly ash environment-friendly packaging material.
In the embodiment of the invention, the fly ash environment-friendly packaging material is 100 wt%, the weight percentage of the fly ash is preferably 25 wt% to 30 wt%, the weight percentage of the inorganic mineral powder is preferably 30 wt% to 40 wt%, the weight percentage of the plastic is preferably 30 wt% to 40 wt%, and the weight percentage of the auxiliary agent is preferably 1.5 wt% to 2 wt%. In the embodiment of the invention, the weight percentage of the fly ash environment-friendly packaging material is 100 wt%, the weight percentage of the fly ash is more preferably 25 wt% to 28 wt%, the weight percentage of the inorganic mineral powder is more preferably 35 wt% to 40 wt%, the weight percentage of the plastic is more preferably 35 wt% to 40 wt%, and the weight percentage of the auxiliary agent is more preferably 1.7 wt% to 2 wt%.
In the present embodiment, the particle size of the fly ash is between 5 microns and 20 microns, preferably between 7 microns and 17 microns, and more preferably between 10 microns and 15 microns.
In the embodiment of the invention, the fly ash is collected from a chimney or a magnetic dust collecting device of a spontaneous combustion coal power plant, a chimney or an electromagnetic dust collecting device of a fuel oil power plant, a chimney or an electromagnetic dust collecting device of an incinerator, a chimney or an electromagnetic dust collecting device of a coal-fired boiler, or a chimney or an electromagnetic dust collecting device of a fuel oil boiler.
In the embodiment of the present invention, the inorganic mineral powder is an inorganic powder with a particle size of 2-10 μm and obtained by grinding natural ore, and the main component of the inorganic powder is calcium carbonate (CaCO)3) Or a calcium phosphate. Because the dispersibility of the fly ash is not good, the fly ash cannot be uniformly dispersed when being mixed with plastics and additives, and the fly ash can be agglomerated, so that the fly ash paper with thinner thickness cannot be manufactured; for example, the fly ash paper material prepared by mixing the fly ash, the plastic and the additives not only has obvious fly ash lumps, but also has a minimum thickness of more than 1 mm. However, in the embodiment of the present invention, after the inorganic mineral powder with a specific weight percentage is added, the dispersibility of the fly ash can be greatly improved, so that the fly ash can be uniformly dispersed when being mixed with the inorganic mineral powder, the plastic and the auxiliary agent, and the agglomeration phenomenon can be avoided, and further the fly ash paper with a thinner thickness can be processed and manufactured. In the embodiment of the invention, the thickness of the environment-friendly fly ash packaging material is less than or equal to 0.2mm, preferably less than or equal to 0.15mm, and more preferably less than or equal to 0.12 mm. In the embodiment of the invention, the particle size of the inorganic mineral powder is preferably 4-9 micrometers, and more preferably 6-8 micrometers.
In embodiments of the invention, the plastic comprises Polyethylene (PE), polypropylene (PP), High Density Polyethylene (HDPE), Low Density Polyethylene (LDPE), Linear Low Density Polyethylene (LLDPE), metal aromatic linear low density polyethylene (MLLDPE), or a combination thereof. Wherein the Linear Low Density Polyethylene (LLDPE) has a number of carbon atoms comprising C4, C6, C8, or a combination thereof.
In embodiments of the invention, the auxiliary agent comprises an anti-blocking additive (anti-block additive), magnesium oxide, zinc oxide, aluminum oxide, polyolefin wax (polyofefin wax), or combinations thereof.
Through the design of the invention, the fly ash and the plastic are mixed and processed to form the fly ash environment-friendly packaging material; the fly ash paper can be used as a light and thin packaging paper or a decorative paper which is increased in stiffness, so that the application field of the fly ash is increased, and the aim of increasing the consumption of the fly ash is fulfilled. In addition, in order to ensure that the modern living environment is properly protected, the fly ash environment-friendly packaging material provided by the invention reuses byproducts generated in industrial and electric operation so as to reduce the output of waste and endow the fly ash which seems useless originally with novel application.
The above description is only a preferred embodiment of the present invention, and all equivalent changes and modifications to the present invention as described and claimed should be included in the scope of the present invention.

Claims (15)

1. An environment-friendly fly ash packaging material, comprising:
25-40 wt% of fly ash;
25-40 wt% of inorganic mineral powder;
25 to 40 weight percent of plastic; and
1-2 wt% of assistant;
the fly ash, the inorganic mineral powder, the plastic and the auxiliary agent are kneaded to form a granular material, and the granular material is processed to form the fly ash environment-friendly packaging material.
2. The environment-friendly fly ash packaging material as claimed in claim 1, wherein the particle size of the fly ash is between 5 microns and 20 microns.
3. The environment-friendly fly ash packing material as claimed in claim 1, wherein the fly ash is collected from a chimney or an electromagnetic dust collecting apparatus of a self-ignition coal power plant, a chimney or an electromagnetic dust collecting apparatus of a fuel oil power plant, a chimney or an electromagnetic dust collecting apparatus of an incinerator, a chimney or an electromagnetic dust collecting apparatus of a coal-fired boiler, or a chimney or an electromagnetic dust collecting apparatus of a fuel oil boiler.
4. The environment-friendly fly ash packaging material of claim 1, wherein the plastic comprises polyethylene, polypropylene, high density polyethylene, low density polyethylene, linear low density polyethylene, metal aromatic linear low density polyethylene, or a combination thereof.
5. The environment-friendly fly ash packaging material of claim 4, wherein the linear low density polyethylene has a carbon number comprising C4, C6, C8, or a combination thereof.
6. The environment-friendly fly ash packaging material of claim 1, wherein the auxiliary agent comprises an anti-blocking additive, magnesium oxide, zinc oxide, aluminum oxide, polyolefin wax, or a combination thereof.
7. The environment-friendly fly ash packing material as claimed in claim 1, wherein the inorganic mineral powder is an inorganic powder having a particle size of 2 to 10 μm and obtained by grinding natural ore having no heavy metal content.
8. The environment-friendly fly ash packaging material as claimed in claim 1, wherein the thickness of the environment-friendly fly ash packaging material is less than or equal to 0.2 mm.
9. A manufacturing method of an environment-friendly fly ash packaging material comprises the following steps:
mixing 25-40 wt% of fly ash, 25-40 wt% of inorganic mineral powder, 25-40 wt% of plastic and 1-2 wt% of auxiliary agent to form a granular material; and
and processing the granular material to form the environment-friendly fly ash packaging material.
10. The method for manufacturing environment-friendly fly ash packing material as claimed in claim 9, wherein the particle size of the fly ash is between 5 microns and 20 microns.
11. The method for manufacturing environment-friendly fly ash packing material according to claim 9, wherein the fly ash is collected from a chimney or an electromagnetic dust collecting device of a self-combustion coal power plant, a chimney or an electromagnetic dust collecting device of a fuel power plant, a chimney or an electromagnetic dust collecting device of an incinerator, a chimney or an electromagnetic dust collecting device of a coal-fired boiler, or a chimney or an electromagnetic dust collecting device of a fuel boiler.
12. The method for manufacturing environment-friendly fly ash packing material as defined in claim 9, wherein the plastic comprises polyethylene, polypropylene, high density polyethylene, low density polyethylene, linear low density polyethylene, metal aromatic linear low density polyethylene or a combination thereof.
13. The method for manufacturing environment-friendly fly ash packing material as claimed in claim 12, wherein the number of carbon atoms of the linear low density polyethylene comprises C4, C6, C8 or a combination thereof.
14. The method for manufacturing the environment-friendly fly ash packaging material as defined in claim 9, wherein the auxiliary agent comprises an anti-blocking additive, magnesium oxide, zinc oxide, aluminum oxide, polyolefin wax or a combination thereof.
15. The method for manufacturing the environment-friendly fly ash packing material as defined in claim 9, wherein the inorganic mineral powder is an inorganic powder having a particle size of 2 to 10 μm and obtained by grinding natural ore, and the inorganic powder is calcium carbonate or calcium phosphate.
CN202010777744.XA 2020-08-05 2020-08-05 Environment-friendly fly ash packaging material and manufacturing method thereof Pending CN114058099A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1315300A (en) * 2000-03-23 2001-10-03 北京天成开元技术开发有限公司 One-pass formed composite flyash material and its preparing process
CN1483763A (en) * 2002-09-16 2004-03-24 鲍振林 Modified composition of waste plastics and flyash
US20070027234A1 (en) * 2005-07-28 2007-02-01 Sigworth William D Cellulosic-thermoplastic composite and method of making the same
CN101768907A (en) * 2010-01-26 2010-07-07 厦门大学 Fly ash-enhanced polymer composite material interlocking type ground tile and preparation method thereof
CN101817987A (en) * 2010-03-26 2010-09-01 王振宇 Silicon-plastic composite cylindrical particles prepared from power plant waste and method for preparing plastic plate thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1315300A (en) * 2000-03-23 2001-10-03 北京天成开元技术开发有限公司 One-pass formed composite flyash material and its preparing process
CN1483763A (en) * 2002-09-16 2004-03-24 鲍振林 Modified composition of waste plastics and flyash
US20070027234A1 (en) * 2005-07-28 2007-02-01 Sigworth William D Cellulosic-thermoplastic composite and method of making the same
CN101768907A (en) * 2010-01-26 2010-07-07 厦门大学 Fly ash-enhanced polymer composite material interlocking type ground tile and preparation method thereof
CN101817987A (en) * 2010-03-26 2010-09-01 王振宇 Silicon-plastic composite cylindrical particles prepared from power plant waste and method for preparing plastic plate thereof

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