CN114041554B - Production method for reducing 5-hydroxymethylfurfural in french fries - Google Patents

Production method for reducing 5-hydroxymethylfurfural in french fries Download PDF

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CN114041554B
CN114041554B CN202111264023.XA CN202111264023A CN114041554B CN 114041554 B CN114041554 B CN 114041554B CN 202111264023 A CN202111264023 A CN 202111264023A CN 114041554 B CN114041554 B CN 114041554B
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hydroxymethylfurfural
potato strips
sodium alginate
fries
reducing
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CN114041554A (en
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谢明勇
黄优生
申明月
李昌
聂少平
李明宇
陆静楠
胡晖宇
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Nanchang University
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • A23L19/10Products from fruits or vegetables; Preparation or treatment thereof of tuberous or like starch containing root crops
    • A23L19/12Products from fruits or vegetables; Preparation or treatment thereof of tuberous or like starch containing root crops of potatoes
    • A23L19/18Roasted or fried products, e.g. snacks or chips
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/10General methods of cooking foods, e.g. by roasting or frying
    • A23L5/11General methods of cooking foods, e.g. by roasting or frying using oil
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/30Physical treatment, e.g. electrical or magnetic means, wave energy or irradiation
    • A23L5/32Physical treatment, e.g. electrical or magnetic means, wave energy or irradiation using phonon wave energy, e.g. sound or ultrasonic waves
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Preparation Of Fruits And Vegetables (AREA)

Abstract

The invention discloses a production method for reducing 5-hydroxymethylfurfural in french fries. The method comprises the following steps: ultrasonic soaking potato strips in sodium alginate solution, frying, cooling, and packaging. The invention has simple manufacturing process and safe raw materials. The potato chips are subjected to soaking pretreatment by adopting ultrasonic combination with sodium alginate, so that the fried potato chips with low 5-hydroxymethylfurfural content can be prepared, the risk of carcinogenesis, neurotoxicity and genotoxicity during ingestion by people can be effectively reduced, and meanwhile, the potato chips are pleasant in color, good in taste and low in greasy feel.

Description

Production method for reducing 5-hydroxymethylfurfural in french fries
Technical Field
The invention belongs to the field of food processing, and particularly relates to a production method for reducing 5-hydroxymethylfurfural in french fries.
Background
The fried food is widely consumed at home and abroad due to the crisp texture, golden color and special flavor. In the food frying process, complex reactions such as Maillard and caramelization can occur in substances such as sugar, amino acid and the like in raw materials, and the products of the reactions have the expected color and flavor substances, and simultaneously are accompanied with the generation of 5-hydroxymethylfurfural (5-HMF), acrylamide (AA) and other harmful substances, wherein the 5-HMF has no serious harm to human health, but metabolites of the 5-HMF, namely the hydroxymethylfurfural sulfonate and the 5-chloromethylfurfural have potential genotoxicity and carcinogenicity. Fries are a widely consumed fried food, and therefore, exploring a method for reducing the generation of 5-HMF in fries is of great importance to the health of humans.
Disclosure of Invention
The invention aims to provide a production method for reducing 5-hydroxymethylfurfural in french fries, so as to achieve the aim of remarkably reducing the content of 5-hydroxymethylfurfural in french fries, reduce the harm of the french fries to human bodies, and maintain good color and sensory quality of the french fries. The technical scheme is as follows:
a process for reducing the production of 5-hydroxymethylfurfural in french fries comprising the steps of:
immersing potato strips in water, performing ultrasonic treatment for 10-30min, taking out, immersing in sodium alginate solution for 10min, and draining surface solution;
and step two, frying the potato strips treated in the step one at 170 ℃ for 5min, cooling and packaging.
Sodium alginate is a nontoxic and safe natural hydrocolloid, has been widely used in the food industry and the medicine field, and ultrasonic treatment is a new green and energy-saving food processing technology. The ultrasonic and sodium alginate impregnation pretreatment process adopted by the invention is a green and safe method.
Preferably, the potato strips of step one are prepared by the process of: the potatoes were peeled after washing, cut into 7mm by 7cm potato strips, and rinsed in water for 1min.
Preferably, the sodium alginate solution has a mass concentration of 1%.
Preferably, the ultrasonic power is 180-220W.
The fries obtained by the above process have a 5-hydroxymethylfurfural content of 912.8-1003.4 μg/kg.
The beneficial effects of the invention are as follows: the invention has simple manufacturing process and safe raw materials. The potato chips are subjected to soaking pretreatment by adopting ultrasonic combination with sodium alginate, so that the fried potato chips with low 5-hydroxymethylfurfural content can be prepared, the risk of carcinogenesis, neurotoxicity and genotoxicity during ingestion by people can be effectively reduced, and meanwhile, the potato chips are pleasant in color, good in taste and low in greasy feel.
Detailed Description
The conception and technical effects of the present invention will be clearly and completely described in conjunction with examples below to fully understand the objects, aspects and effects of the present invention.
Example 1:
fresh potatoes were thoroughly rinsed with clean tap water, peeled and cut into 7mm by 7cm potato strips, which were immediately rinsed in distilled water for 1min. 70g of potato strips were immersed in a beaker containing 210mL of distilled water and placed in an ultrasonic apparatus for 30 minutes under ultrasound (200W). The potato strips were then removed and immersed in 210mL of 1% sodium alginate solution for 10min and the surface excess solution was drained. Finally, frying the pretreated potato strips in a frying pan at 170 ℃ for 5min, cooling and packaging.
Example 2:
fresh potatoes were thoroughly rinsed with clean tap water, peeled and cut into 7mm by 7cm potato strips, which were immediately rinsed in distilled water for 1min. 100g of potato strips were immersed in a beaker containing 300mL of distilled water and placed in an ultrasonic apparatus for 10 minutes under ultrasound (200W). The potato strips were then removed and immersed in 300mL of 1% sodium alginate solution for 10min and the surface excess solution was drained. Finally, frying the pretreated potato strips in a frying pan at 170 ℃ for 5min, cooling and packaging.
Example 3:
fresh potatoes were thoroughly rinsed with clean tap water, peeled and cut into 7mm by 7cm potato strips, which were immediately rinsed in distilled water for 1min. 200g of potato strips were immersed in a beaker containing 600mL of distilled water and placed in an ultrasonic apparatus for 20 minutes under ultrasound (200W). The potato strips were then removed and immersed in 600mL of 1% sodium alginate solution for 10min and the surface excess solution was drained. Finally, frying the pretreated potato strips in a frying pan at 170 ℃ for 5min, cooling and packaging.
Comparative example 1:
fresh potatoes were thoroughly rinsed with clean tap water, peeled and cut into 7mm by 7cm potato strips, which were immediately rinsed in distilled water for 1min. Soaking 100g of potato strips in a beaker filled with 300mL of distilled water for 40min, draining off superfluous surface solution, frying the potato strips in a frying pan at 170 ℃ for 5min, cooling and packaging.
Comparative example 2:
fresh potatoes were thoroughly rinsed with clean tap water, peeled and cut into 7mm by 7cm potato strips, which were immediately rinsed in distilled water for 1min. 100g of potato strips were immersed in a 300mL beaker of 90℃distilled water for 3min. The potato strips were then removed and immersed in 300mL of 1% sodium alginate solution for 10min and the surface excess solution was drained. Finally, frying the pretreated potato strips in a frying pan at 170 ℃ for 5min, cooling and packaging.
Effect test experiment:
(1) The fries obtained in examples 1-3 and comparative example 1 were subjected to hazard detection by liquid chromatography-triple quadrupole tandem mass spectrometry (LC-MS/MS), specifically:
HPLC analysis conditions: the chromatographic column is Phenomenex Synergi Hydro-RP chromatographic column (150 multiplied by 2mm,4 μm) with the column temperature of 30 ℃; the sample injection amount is 5.0 mu L; the chromatographic mobile phase was acetonitrile (A) and 0.1% (v/v) formic acid aqueous solution (B), the flow rate was 0.3mL/min, gradient elution procedure: 0-1min,95% -20% B;1-3min,20% B;3-3.1min,20% -95% B, 5min of balance.
MS/MS analysis conditions: adopting an electrospray ion source (ESI+), and a multi-reaction monitoring (MRM) mode; ion source temperature: 350 ℃; drying gas flow rate: 10L/min; atomizer pressure: 40psi; capillary voltage: 4000V; electron multiplier voltage: 300V; the MRM residence time is 40ms.5-HMF detection ion 127 > 53,127 > 81;5-HMF internal standard detection ion: 133 > 86.AA detection ion 72 > 55,72 > 44; AA internal standard detection ion: 75 > 58.
As a result, as shown in Table 1, it is evident from Table 1 that examples 1 to 3 showed fries having a lower 5-HMF content.
TABLE 1
Figure BDA0003325983290000031
Furthermore, the same detection means as described above was used to detect the AA content of the fries, and it was found that the minimum content of examples 1-3 was 756.7. Mu.g/kg, whereas comparative example 1 was 1699.5. Mu.g/kg.
Respectively using 1% acetic acid solution (v/v) and 1% NaHCO 3 The solution (m/v) is used for replacing distilled water in comparative example 1 to prepare the fries, and the fries prepared by using 1% acetic acid solution to replace distilled water are found to have an AA inhibition rate of 31.7%, but have a promotion effect on 5-HMF, and the content of 5-HMF is improved by 57.2%; with 1% NaHCO 3 The inhibition rate of the solution to 5-HMF reaches 54.2%, but the solution has promotion effect to AA, and the AA content is increased by 26.8%.
(2) The fries obtained in examples 1-3 and comparative example 2 were subjected to sensory evaluation, respectively, from the color (visual evaluation of the color of the fries), the flavor (aroma associated with the fries), the texture (whether the appearance of the fries is complete and full), the mouthfeel (taste after chewing of the fries), the greasy feel (perception of the oil content in the mouth during chewing), and the overall evaluation (non-attribute, overall evaluation by an evaluator based on all attributes). Sensory evaluation was expressed in terms of 10 scores, from 1 (very dislike) to 9 (very like). Samples were randomly numbered and the mouth was rinsed with warm water before and between tasting the first sample to reduce evaluation errors. The results are shown in Table 2.
TABLE 2
Figure BDA0003325983290000032
Figure BDA0003325983290000041
As can be seen from Table 2, comparative example 2, which had been treated with blanched sodium alginate solution, was significantly whiter in color, very less favored by the average consumer, and had a harder mouthfeel, and, overall, was far less organoleptic than the fries of examples 1-3, and had poor quality.
(3) The color of examples 1-3 and comparative example 2 before and after frying was examined using a color difference meter, the color difference ΔE of examples 1-3 was 2.83, 2.94 and 2.88, respectively, and the color difference ΔE of comparative example 2 was 6.45. Further, it is explained that the fries of comparative example 2 are significantly discolored, resulting in poor quality fries.
The present invention is not limited to the above embodiments, but is merely preferred embodiments of the present invention, and the present invention should be construed as being limited to the above embodiments as long as the technical effects of the present invention are achieved by the same means. Various modifications and variations are possible in the technical solution and/or in the embodiments within the scope of the invention.

Claims (2)

1. A process for reducing 5-hydroxymethylfurfural in french fries comprising the steps of:
immersing potato strips in water, performing ultrasonic treatment for 10-30min, taking out, immersing in sodium alginate solution for 10min, and draining surface solution;
frying the potato strips treated in the first step at 170 ℃ for 5min, cooling and packaging;
the mass concentration of the sodium alginate solution is 1%; the ultrasonic power is 180-220W.
2. The method of claim 1 wherein the potato strips of step one are prepared by the process of: the potatoes were peeled after washing, cut into potato strips of 7mm ×7mm ×7cm, and rinsed in water for 1min.
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