CN114041521A - Portable bubble buccal tablet capable of being applied to multiple occasions for refreshing and production process thereof - Google Patents
Portable bubble buccal tablet capable of being applied to multiple occasions for refreshing and production process thereof Download PDFInfo
- Publication number
- CN114041521A CN114041521A CN202111445467.3A CN202111445467A CN114041521A CN 114041521 A CN114041521 A CN 114041521A CN 202111445467 A CN202111445467 A CN 202111445467A CN 114041521 A CN114041521 A CN 114041521A
- Authority
- CN
- China
- Prior art keywords
- vitamin
- bubble
- refreshing
- portable
- buccal tablet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 39
- 229940046011 buccal tablet Drugs 0.000 title claims abstract description 36
- 239000006189 buccal tablet Substances 0.000 title claims abstract description 36
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000000203 mixture Substances 0.000 claims abstract description 40
- RYYVLZVUVIJVGH-UHFFFAOYSA-N caffeine Chemical compound CN1C(=O)N(C)C(=O)C2=C1N=CN2C RYYVLZVUVIJVGH-UHFFFAOYSA-N 0.000 claims abstract description 38
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims abstract description 38
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 claims abstract description 30
- 239000011782 vitamin Substances 0.000 claims abstract description 30
- 235000013343 vitamin Nutrition 0.000 claims abstract description 30
- 229940088594 vitamin Drugs 0.000 claims abstract description 30
- 229930003231 vitamin Natural products 0.000 claims abstract description 30
- 239000004376 Sucralose Substances 0.000 claims abstract description 20
- 229960004543 anhydrous citric acid Drugs 0.000 claims abstract description 20
- 235000019408 sucralose Nutrition 0.000 claims abstract description 20
- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 claims abstract description 20
- 150000003722 vitamin derivatives Chemical class 0.000 claims abstract description 20
- LPHGQDQBBGAPDZ-UHFFFAOYSA-N Isocaffeine Natural products CN1C(=O)N(C)C(=O)C2=C1N(C)C=N2 LPHGQDQBBGAPDZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229960001948 caffeine Drugs 0.000 claims abstract description 19
- VJEONQKOZGKCAK-UHFFFAOYSA-N caffeine Natural products CN1C(=O)N(C)C(=O)C2=C1C=CN2C VJEONQKOZGKCAK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229960003080 taurine Drugs 0.000 claims abstract description 19
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims abstract description 16
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 claims abstract description 15
- 108010011485 Aspartame Proteins 0.000 claims abstract description 15
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims abstract description 15
- FEWJPZIEWOKRBE-XIXRPRMCSA-N Mesotartaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-XIXRPRMCSA-N 0.000 claims abstract description 15
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims abstract description 15
- 235000010358 acesulfame potassium Nutrition 0.000 claims abstract description 15
- 229960004998 acesulfame potassium Drugs 0.000 claims abstract description 15
- 239000000619 acesulfame-K Substances 0.000 claims abstract description 15
- 239000000605 aspartame Substances 0.000 claims abstract description 15
- 235000010357 aspartame Nutrition 0.000 claims abstract description 15
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 claims abstract description 15
- 229960003438 aspartame Drugs 0.000 claims abstract description 15
- 229940048879 dl tartaric acid Drugs 0.000 claims abstract description 15
- 235000019359 magnesium stearate Nutrition 0.000 claims abstract description 15
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims abstract description 15
- 239000008108 microcrystalline cellulose Substances 0.000 claims abstract description 15
- 229940016286 microcrystalline cellulose Drugs 0.000 claims abstract description 15
- 239000000600 sorbitol Substances 0.000 claims abstract description 15
- 235000010356 sorbitol Nutrition 0.000 claims abstract description 15
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims abstract description 10
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 13
- 238000010008 shearing Methods 0.000 claims description 13
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 12
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 12
- 239000000853 adhesive Substances 0.000 claims description 10
- 230000001070 adhesive effect Effects 0.000 claims description 10
- 239000011691 vitamin B1 Substances 0.000 claims description 10
- 239000011716 vitamin B2 Substances 0.000 claims description 10
- 239000011726 vitamin B6 Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 7
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 5
- AUNGANRZJHBGPY-SCRDCRAPSA-N Riboflavin Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-SCRDCRAPSA-N 0.000 claims description 5
- 238000011049 filling Methods 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- ZUFQODAHGAHPFQ-UHFFFAOYSA-N pyridoxine hydrochloride Chemical compound Cl.CC1=NC=C(CO)C(CO)=C1O ZUFQODAHGAHPFQ-UHFFFAOYSA-N 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- 229960002920 sorbitol Drugs 0.000 claims description 5
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 239000003826 tablet Substances 0.000 abstract description 19
- 239000000047 product Substances 0.000 abstract description 14
- 235000019640 taste Nutrition 0.000 abstract description 9
- 235000015872 dietary supplement Nutrition 0.000 abstract description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 5
- 235000010755 mineral Nutrition 0.000 abstract description 5
- 239000011707 mineral Substances 0.000 abstract description 5
- 235000017807 phytochemicals Nutrition 0.000 abstract description 5
- 229930000223 plant secondary metabolite Natural products 0.000 abstract description 5
- 235000009508 confectionery Nutrition 0.000 description 9
- 239000002585 base Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- 235000019606 astringent taste Nutrition 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 210000000214 mouth Anatomy 0.000 description 4
- 235000019614 sour taste Nutrition 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- XHFLOLLMZOTPSM-UHFFFAOYSA-M sodium;hydrogen carbonate;hydrate Chemical compound [OH-].[Na+].OC(O)=O XHFLOLLMZOTPSM-UHFFFAOYSA-M 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000013361 beverage Nutrition 0.000 description 2
- 235000014171 carbonated beverage Nutrition 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 235000011888 snacks Nutrition 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000015040 sparkling wine Nutrition 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 229960001367 tartaric acid Drugs 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
- A23G3/48—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing plants or parts thereof, e.g. fruits, seeds, extracts
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
- A23G3/362—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing inorganic compounds
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
- A23G3/364—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
- A23G3/364—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins
- A23G3/368—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing microorganisms or enzymes; containing paramedical or dietetical agents, e.g. vitamins containing vitamins, antibiotics
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
- A23G3/00—Sweetmeats; Confectionery; Marzipan; Coated or filled products
- A23G3/34—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof
- A23G3/36—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds
- A23G3/44—Sweetmeats, confectionery or marzipan; Processes for the preparation thereof characterised by the composition containing organic or inorganic compounds containing peptides or proteins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Abstract
The invention discloses a portable bubble buccal tablet capable of being applied to multiple occasions for refreshing and a production process thereof, wherein the portable bubble buccal tablet comprises the following components in percentage by weight: 10% of caffeine, 20% of taurine, 0.294% of a vitamin mixture, 9% of anhydrous citric acid, 2% of DL-tartaric acid, 14% of sodium bicarbonate, 29% of sorbitol, 12.956% of microcrystalline cellulose, 0.15% of sucralose, 0.12% of aspartame, 0.08% of acesulfame potassium, 1.6% of magnesium stearate and 0.8% of edible essence, so that novel taste experience of tablet products is realized; meanwhile, the tablet is combined with a nutritional supplement, and comprises common vitamins, minerals and novel phytochemicals, so that the functionality of the tablet is improved.
Description
Technical Field
The invention relates to the technical field of food research and development, in particular to a portable refreshing bubble buccal tablet capable of being applied to multiple occasions and a production process thereof.
Background
As a substitute for carbonated beverages, the sparkling water is healthier in ingredients, retains the stimulation, cool mouthfeel and richer flavor of carbonated beverages, and is therefore very popular among young consumers. Since bubbles are very easy to combine with various types of drinks, numerous subdivided beverage types such as sparkling wine, sparkling juice, sparkling coffee, etc. are thereby extended. This "bubble" cyclone has not been confined to beverages, but has begun to spread rapidly towards the snack field. As for the new style of bubble candy, a specific production formula and a corresponding production process are not available at present, so that a snack of the bubble candy is sought to have higher market economic value.
Disclosure of Invention
This section is for the purpose of summarizing some aspects of embodiments of the invention and to briefly introduce some preferred embodiments. In this section, as well as in the abstract and the title of the invention of this application, simplifications or omissions may be made to avoid obscuring the purpose of the section, the abstract and the title, and such simplifications or omissions are not intended to limit the scope of the invention.
The present invention has been made in view of the above-mentioned problems with the conventional confectionery products.
Therefore, the technical problem solved by the invention is as follows: solves the problem that the prior art has no specific production formula and corresponding production process for preparing the bubble tabletted candy.
In order to solve the technical problems, the invention provides the following technical scheme: a portable bubble buccal tablet capable of being applied to multiple occasions for refreshing comprises the following components in percentage by weight: 10% of caffeine, 20% of taurine, 0.294% of vitamin mixture, 9% of anhydrous citric acid, 2% of DL-tartaric acid, 14% of sodium bicarbonate, 29% of sorbitol, 12.956% of microcrystalline cellulose, 0.15% of sucralose, 0.12% of aspartame, 0.08% of acesulfame potassium, 1.6% of magnesium stearate and 0.8% of edible essence.
In order to solve the technical problems, the invention also provides the following technical scheme: a portable bubble buccal tablet capable of being applied to multiple occasions for refreshing comprises the following components in percentage by weight: 5% of caffeine, 20% of taurine, 0.294% of vitamin mixture, 9% of anhydrous citric acid, 2% of DL-tartaric acid, 14% of sodium bicarbonate, 34% of sorbitol, 12.956% of microcrystalline cellulose, 0.15% of sucralose, 0.12% of aspartame, 0.08% of acesulfame potassium, 1.6% of magnesium stearate and 0.8% of edible essence.
In order to solve the technical problems, the invention also provides the following technical scheme: a portable bubble buccal tablet capable of being applied to multiple occasions for refreshing comprises the following components in percentage by weight: 20% of caffeine, 20% of taurine, 0.294% of vitamin mixture, 9% of anhydrous citric acid, 2% of DL-tartaric acid, 14% of sodium bicarbonate, 20% of sorbitol, 11.956% of microcrystalline cellulose, 0.15% of sucralose, 0.12% of aspartame, 0.08% of acesulfame potassium, 1.6% of magnesium stearate and 0.8% of edible essence.
As a preferred scheme of the portable refreshing bubble buccal tablet capable of being applied to multiple occasions, the refreshing bubble buccal tablet comprises the following components in parts by weight: the vitamin mixture comprises vitamin B1Vitamin B2And vitamin B6And vitamin B1: vitamin B2: vitamin B6=80:30:37。
In order to solve the technical problems, the invention also provides the following technical scheme: a portable production process of a bubble buccal tablet capable of being applied to multiple occasions for refreshing is characterized by comprising the following steps:
(1) weighing a certain amount of raw materials according to the rated proportion;
(2) premixing: uniformly mixing a mixture of caffeine, taurine and vitamins, adding anhydrous citric acid, DL-tartaric acid, sorbitol, sucralose, aspartame, acesulfame potassium and edible essence at the temperature of 30 ℃, stirring for 1.5h, putting into a shearing machine, shearing at the rotating speed of 12000-16000 r/min at the temperature of 60 ℃ for 1h to be in a homogeneous state, adding microcrystalline cellulose and magnesium stearate, and continuously reacting for more than 2h for later use;
(3) and (3) polarity treatment: adding a sodium bicarbonate aqueous solution into the mixture, adjusting the pH value of the reaction solution, and controlling the pH value to be 5-7;
(4) and (3) pressurizing and subpackaging: pressurizing the mixture at the temperature of 80 ℃ under the condition of 60-80N to form an adhesive state, quickly filling the adhesive state into prepared plastic bags according to the subpackage dosage of 500 mg/granule, sealing the bags, and cooling the bags in cold water.
As a preferred scheme of the production process of the portable refreshing bubble buccal tablet capable of being applied to multiple occasions, the production process comprises the following steps: the concentration of the sodium bicarbonate aqueous solution is 3%.
As a preferred scheme of the production process of the portable refreshing bubble buccal tablet capable of being applied to multiple occasions, the production process comprises the following steps: the mixture was pressurized and the viscosity was determined to be 1000mpa.s and was acceptable.
As a preferred scheme of the production process of the portable refreshing bubble buccal tablet capable of being applied to multiple occasions, the production process comprises the following steps: in the cooling process, the temperature of the cold water is-10-0 ℃.
As a preferred scheme of the production process of the portable refreshing bubble buccal tablet capable of being applied to multiple occasions, the production process comprises the following steps: and the vitamin mixture is sieved by a sieve of 80 meshes, and the anhydrous citric acid, the sucralose and the edible essence are all sieved by a sieve of 60 meshes.
The invention has the beneficial effects that: the invention provides a portable bubble buccal tablet capable of refreshing in multiple occasions and a production process thereof, wherein proper acid-base material proportion such as caffeine and taurine is selected, the addition amount of sodium bicarbonate and production process parameters are continuously adjusted to increase the size of bubbles, proper bubble speed is realized under the condition of limited water source in the oral cavity, balance is found on taste generated by acid and base, the tablet has pleasant feeling of candy, unpleasant sour taste and astringent taste are not generated, and novel taste experience of tablet products is realized; meanwhile, the tablet is combined with a nutritional supplement, and comprises common vitamins, minerals and novel phytochemicals, so that the functionality of the tablet is improved.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings needed to be used in the description of the embodiments will be briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art to obtain other drawings based on these drawings without inventive exercise. Wherein:
fig. 1 is a schematic overall structure diagram of a portable production device of the bubble buccal tablet capable of being applied to multiple occasions for refreshing.
Fig. 2 is a schematic diagram of the internal structure of the portable refreshing bubble buccal tablet production device which can be applied in multiple occasions.
Detailed Description
In order to make the aforementioned objects, features and advantages of the present invention comprehensible, embodiments accompanied with figures are described in detail below.
In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention, but the present invention may be practiced in other ways than those specifically described and will be readily apparent to those of ordinary skill in the art without departing from the spirit of the present invention, and therefore the present invention is not limited to the specific embodiments disclosed below.
Furthermore, reference herein to "one embodiment" or "an embodiment" means that a particular feature, structure, or characteristic described in connection with the embodiment is included in at least one implementation of the invention. The appearances of the phrase "in one embodiment" in various places in the specification are not necessarily all referring to the same embodiment, nor are separate or alternative embodiments mutually exclusive of other embodiments.
Example 1
For the new style of bubble candy, the prior art has no specific production formula and corresponding production process.
Considering that the acid and the alkali are added simultaneously, even if a certain product is a solid raw material at the same time, corresponding neutralization reaction still occurs along with the lapse of time, and the mouthfeel is greatly changed after the neutralization reaction. In view of the above, the laboratory first carried out the embedding treatment of the acid during the process exploration, and then thoroughly mixed the alkaline raw materials such as sodium bicarbonate to avoid direct contact.
In the process of making the product, DL-malic acid or food raw materials such as sodium citrate and tartaric acid can be added in proportion to adjust the astringency. The corresponding sourness can be adjusted by adding a sweetening agent to achieve the sour-sweet flavor accepted by the public.
Therefore, the invention provides a portable bubble buccal tablet capable of being applied to multiple occasions for refreshing, which comprises the following components in percentage by weight: 10% of caffeine, 20% of taurine, 0.294% of vitamin mixture, 9% of anhydrous citric acid, 2% of DL-tartaric acid, 14% of sodium bicarbonate, 29% of sorbitol, 12.956% of microcrystalline cellulose, 0.15% of sucralose, 0.12% of aspartame, 0.08% of acesulfame potassium, 1.6% of magnesium stearate and 0.8% of edible essence.
Wherein the vitamin mixture comprises vitamin B1Vitamin B2And vitamin B6And vitamin B1: vitamin B2: vitamin B6=80:30:37。
Meanwhile, the embodiment of the invention also provides a portable production process of the bubble buccal tablet capable of refreshing in multiple occasions, which comprises the following steps:
(1) weighing a certain amount of raw materials according to the rated proportion;
(2) premixing: uniformly mixing a mixture of caffeine, taurine and vitamins, adding anhydrous citric acid, DL-tartaric acid, sorbitol, sucralose, aspartame, acesulfame potassium and edible essence at the temperature of 30 ℃, stirring for 1.5h, putting into a shearing machine, shearing at the rotating speed of 12000-16000 r/min at the temperature of 60 ℃ for 1h to be in a homogeneous state, adding microcrystalline cellulose and magnesium stearate, and continuously reacting for more than 2h for later use;
(3) and (3) polarity treatment: adding a sodium bicarbonate aqueous solution into the mixture, adjusting the pH value of the reaction solution, and controlling the pH value to be 5-7;
(4) and (3) pressurizing and subpackaging: pressurizing the mixture at the temperature of 80 ℃ under the condition of 60-80N to form an adhesive state, quickly filling the adhesive state into prepared plastic bags according to the subpackage dosage of 500 mg/granule, sealing the bags, and cooling the bags in cold water.
Wherein, the concentration of the sodium bicarbonate water solution is 3 percent.
Further, the mixture was pressurized, and the viscosity was measured to be 1000mPa.s, and passed.
Furthermore, in the cooling process, the temperature of the cold water is-10 to 0 ℃.
It should be additionally noted that the vitamin mixture is sieved through a 80 mesh sieve, and the anhydrous citric acid, the sucralose and the flavoring essence are all sieved through a 60 mesh sieve.
As shown in fig. 1 and 2, in the drawings, 1 is a reaction kettle, 2 is a charging port, 3 and 4 are stirring and shearing structures, 5 is a cooling inner wall ring layer, and 6 is a heating layer and a grinding and filtering platform, so that the reaction smoothness and the reaction controllability of the device are improved.
As shown in table 1 below, the physicochemical properties of the product prepared in this example are:
table 1: physical and chemical properties of the product
The invention provides a portable bubble buccal tablet capable of refreshing in multiple occasions and a production process thereof, wherein proper acid-base material proportion such as caffeine and taurine is selected, the addition amount of sodium bicarbonate and production process parameters are continuously adjusted to increase the size of bubbles, proper bubble speed is realized under the condition of limited water source in the oral cavity, balance is found on taste generated by acid and base, the tablet has pleasant feeling of candy, unpleasant sour taste and astringent taste are not generated, and novel taste experience of tablet products is realized; meanwhile, the tablet is combined with a nutritional supplement, and comprises common vitamins, minerals and novel phytochemicals, so that the functionality of the tablet is improved.
Example 2
The invention also provides a portable bubble buccal tablet capable of being applied to multi-occasion refreshing, which comprises the following components in percentage by weight: 5% of caffeine, 20% of taurine, 0.294% of vitamin mixture, 9% of anhydrous citric acid, 2% of DL-tartaric acid, 14% of sodium bicarbonate, 34% of sorbitol, 12.956% of microcrystalline cellulose, 0.15% of sucralose, 0.12% of aspartame, 0.08% of acesulfame potassium, 1.6% of magnesium stearate and 0.8% of edible essence.
Wherein the vitamin mixture comprises vitamin B1Vitamin B2And vitamin B6And vitamin B1: vitamin B2: vitamin B6=80:30:37。
Meanwhile, the embodiment of the invention also provides a portable production process of the bubble buccal tablet capable of refreshing in multiple occasions, which comprises the following steps:
(1) weighing a certain amount of raw materials according to the rated proportion;
(2) premixing: uniformly mixing a mixture of caffeine, taurine and vitamins, adding anhydrous citric acid, DL-tartaric acid, sorbitol, sucralose, aspartame, acesulfame potassium and edible essence at the temperature of 30 ℃, stirring for 1.5h, putting into a shearing machine, shearing at the rotating speed of 12000-16000 r/min at the temperature of 60 ℃ for 1h to be in a homogeneous state, adding microcrystalline cellulose and magnesium stearate, and continuously reacting for more than 2h for later use;
(3) and (3) polarity treatment: adding a sodium bicarbonate aqueous solution into the mixture, adjusting the pH value of the reaction solution, and controlling the pH value to be 5-7;
(4) and (3) pressurizing and subpackaging: pressurizing the mixture at the temperature of 80 ℃ under the condition of 60-80N to form an adhesive state, quickly filling the adhesive state into prepared plastic bags according to the subpackage dosage of 500 mg/granule, sealing the bags, and cooling the bags in cold water.
Wherein, the concentration of the sodium bicarbonate water solution is 3 percent.
Further, the mixture was pressurized, and the viscosity was measured to be 1000mPa.s, and passed.
Furthermore, in the cooling process, the temperature of the cold water is-10 to 0 ℃.
It should be additionally noted that the vitamin mixture is sieved through a 80 mesh sieve, and the anhydrous citric acid, the sucralose and the flavoring essence are all sieved through a 60 mesh sieve.
As shown in fig. 1 and 2, in the drawings, 1 is a reaction kettle, 2 is a charging port, 3 and 4 are stirring and shearing structures, 5 is a cooling inner wall ring layer, and 6 is a heating layer and a grinding and filtering platform, so that the reaction smoothness and the reaction controllability of the device are improved.
As shown in table 2 below, the physicochemical properties of the product prepared in this example are:
table 2: physical and chemical properties of the product
The invention provides a portable bubble buccal tablet capable of refreshing in multiple occasions and a production process thereof, wherein proper acid-base material proportion such as caffeine and taurine is selected, the addition amount of sodium bicarbonate and production process parameters are continuously adjusted to increase the size of bubbles, proper bubble speed is realized under the condition of limited water source in the oral cavity, balance is found on taste generated by acid and base, the tablet has pleasant feeling of candy, unpleasant sour taste and astringent taste are not generated, and novel taste experience of tablet products is realized; meanwhile, the tablet is combined with a nutritional supplement, and comprises common vitamins, minerals and novel phytochemicals, so that the functionality of the tablet is improved.
Example 3
The invention also provides a portable bubble buccal tablet capable of being applied to multi-occasion refreshing, which comprises the following components in percentage by weight: 20% of caffeine, 20% of taurine, 0.294% of vitamin mixture, 9% of anhydrous citric acid, 2% of DL-tartaric acid, 14% of sodium bicarbonate, 20% of sorbitol, 11.956% of microcrystalline cellulose, 0.15% of sucralose, 0.12% of aspartame, 0.08% of acesulfame potassium, 1.6% of magnesium stearate and 0.8% of edible essence.
Wherein the vitamin mixture comprises vitamin B1Vitamin B2And vitamin B6And vitamin B1: vitamin B2: vitamin B6=80:30:37。
Meanwhile, the embodiment of the invention also provides a portable production process of the bubble buccal tablet capable of refreshing in multiple occasions, which comprises the following steps:
(1) weighing a certain amount of raw materials according to the rated proportion;
(2) premixing: uniformly mixing a mixture of caffeine, taurine and vitamins, adding anhydrous citric acid, DL-tartaric acid, sorbitol, sucralose, aspartame, acesulfame potassium and edible essence at the temperature of 30 ℃, stirring for 1.5h, putting into a shearing machine, shearing at the rotating speed of 12000-16000 r/min at the temperature of 60 ℃ for 1h to be in a homogeneous state, adding microcrystalline cellulose and magnesium stearate, and continuously reacting for more than 2h for later use;
(3) and (3) polarity treatment: adding a sodium bicarbonate aqueous solution into the mixture, adjusting the pH value of the reaction solution, and controlling the pH value to be 5-7;
(4) and (3) pressurizing and subpackaging: pressurizing the mixture at the temperature of 80 ℃ under the condition of 60-80N to form an adhesive state, quickly filling the adhesive state into prepared plastic bags according to the subpackage dosage of 500 mg/granule, sealing the bags, and cooling the bags in cold water.
Wherein, the concentration of the sodium bicarbonate water solution is 3 percent.
Further, the mixture was pressurized, and the viscosity was measured to be 1000mPa.s, and passed.
Furthermore, in the cooling process, the temperature of the cold water is-10 to 0 ℃.
It should be additionally noted that the vitamin mixture is sieved through a 80 mesh sieve, and the anhydrous citric acid, the sucralose and the flavoring essence are all sieved through a 60 mesh sieve.
As shown in fig. 1 and 2, in the drawings, 1 is a reaction kettle, 2 is a charging port, 3 and 4 are stirring and shearing structures, 5 is a cooling inner wall ring layer, and 6 is a heating layer and a grinding and filtering platform, so that the reaction smoothness and the reaction controllability of the device are improved.
As shown in table 3 below, the physicochemical properties of the product prepared in this example are:
table 3: physical and chemical properties of the product
The invention provides a portable bubble buccal tablet capable of refreshing in multiple occasions and a production process thereof, wherein proper acid-base material proportion such as caffeine and taurine is selected, the addition amount of sodium bicarbonate and production process parameters are continuously adjusted to increase the size of bubbles, proper bubble speed is realized under the condition of limited water source in the oral cavity, balance is found on taste generated by acid and base, the tablet has pleasant feeling of candy, unpleasant sour taste and astringent taste are not generated, and novel taste experience of tablet products is realized; meanwhile, the tablet is combined with a nutritional supplement, and comprises common vitamins, minerals and novel phytochemicals, so that the functionality of the tablet is improved.
It is important to note that the construction and arrangement of the present application as shown in the various exemplary embodiments is illustrative only. Although only a few embodiments have been described in detail in this disclosure, those skilled in the art who review this disclosure will readily appreciate that many modifications are possible (e.g., variations in sizes, dimensions, structures, shapes and proportions of the various elements, values of parameters (e.g., temperatures, pressures, etc.), mounting arrangements, use of materials, colors, orientations, etc.) without materially departing from the novel teachings and advantages of the subject matter recited in this application. For example, elements shown as integrally formed may be constructed of multiple parts or elements, the position of elements may be reversed or otherwise varied, and the nature or number of discrete elements or positions may be altered or varied. Accordingly, all such modifications are intended to be included within the scope of this invention. The order or sequence of any process or method steps may be varied or re-sequenced according to alternative embodiments. In the claims, any means-plus-function clause is intended to cover the structures described herein as performing the recited function and not only structural equivalents but also equivalent structures. Other substitutions, modifications, changes and omissions may be made in the design, operating conditions and arrangement of the exemplary embodiments without departing from the scope of the present inventions. Therefore, the present invention is not limited to a particular embodiment, but extends to various modifications that nevertheless fall within the scope of the appended claims.
Moreover, in an effort to provide a concise description of the exemplary embodiments, all features of an actual implementation may not be described (i.e., those unrelated to the presently contemplated best mode of carrying out the invention, or those unrelated to enabling the invention).
It should be appreciated that in the development of any such actual implementation, as in any engineering or design project, numerous implementation-specific decisions may be made. Such a development effort might be complex and time consuming, but would nevertheless be a routine undertaking of design, fabrication, and manufacture for those of ordinary skill having the benefit of this disclosure, without undue experimentation.
It should be noted that the above-mentioned embodiments are only for illustrating the technical solutions of the present invention and not for limiting, and although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, which should be covered by the claims of the present invention.
Claims (9)
1. The portable bubble buccal tablet capable of being applied to multiple occasions for refreshing is characterized by comprising the following components in percentage by weight: 10% of caffeine, 20% of taurine, 0.294% of vitamin mixture, 9% of anhydrous citric acid, 2% of DL-tartaric acid, 14% of sodium bicarbonate, 29% of sorbitol, 12.956% of microcrystalline cellulose, 0.15% of sucralose, 0.12% of aspartame, 0.08% of acesulfame potassium, 1.6% of magnesium stearate and 0.8% of edible essence.
2. The portable bubble buccal tablet capable of being applied to multiple occasions for refreshing is characterized by comprising the following components in percentage by weight: 5% of caffeine, 20% of taurine, 0.294% of vitamin mixture, 9% of anhydrous citric acid, 2% of DL-tartaric acid, 14% of sodium bicarbonate, 34% of sorbitol, 12.956% of microcrystalline cellulose, 0.15% of sucralose, 0.12% of aspartame, 0.08% of acesulfame potassium, 1.6% of magnesium stearate and 0.8% of edible essence.
3. The portable bubble buccal tablet capable of being applied to multiple occasions for refreshing is characterized by comprising the following components in percentage by weight: 20% of caffeine, 20% of taurine, 0.294% of vitamin mixture, 9% of anhydrous citric acid, 2% of DL-tartaric acid, 14% of sodium bicarbonate, 20% of sorbitol, 11.956% of microcrystalline cellulose, 0.15% of sucralose, 0.12% of aspartame, 0.08% of acesulfame potassium, 1.6% of magnesium stearate and 0.8% of edible essence.
4. The portable refreshing bubble buccal tablet according to any one of claims 1 to 3, which is applied to multiple occasions, and is characterized in that: the vitamin mixture comprises vitamin B1Vitamin B2And vitamin B6And vitamin B1: vitamin B2: vitamin B6=80:30:37。
5. A portable production process of a bubble buccal tablet capable of being applied to multiple occasions for refreshing is characterized by comprising the following steps:
(1) weighing a certain amount of raw materials according to the rated proportion;
(2) premixing: uniformly mixing a mixture of caffeine, taurine and vitamins, adding anhydrous citric acid, DL-tartaric acid, sorbitol, sucralose, aspartame, acesulfame potassium and edible essence at the temperature of 30 ℃, stirring for 1.5h, putting into a shearing machine, shearing at the rotating speed of 12000-16000 r/min at the temperature of 60 ℃ for 1h to be in a homogeneous state, adding microcrystalline cellulose and magnesium stearate, and continuously reacting for more than 2h for later use;
(3) and (3) polarity treatment: adding a sodium bicarbonate aqueous solution into the mixture, adjusting the pH value of the reaction solution, and controlling the pH value to be 5-7;
(4) and (3) pressurizing and subpackaging: pressurizing the mixture at the temperature of 80 ℃ under the condition of 60-80N to form an adhesive state, quickly filling the adhesive state into prepared plastic bags according to the subpackage dosage of 500 mg/granule, sealing the bags, and cooling the bags in cold water.
6. The production process of the portable refreshing bubble buccal tablet capable of being applied to multiple occasions according to claim 5 is characterized in that: the concentration of the sodium bicarbonate aqueous solution is 3%.
7. The production process of the portable refreshing bubble buccal tablet capable of being applied to multiple occasions according to claim 6 is characterized in that: the mixture was pressurized and the viscosity was determined to be 1000mpa.s and was acceptable.
8. The production process of the portable refreshing bubble buccal tablet capable of being applied to multiple occasions according to claim 7 is characterized in that: in the cooling process, the temperature of the cold water is-10-0 ℃.
9. The production process of the portable refreshing bubble buccal tablet capable of being applied to multiple occasions according to any one of claims 5 to 8 is characterized by comprising the following steps of: and the vitamin mixture is sieved by a sieve of 80 meshes, and the anhydrous citric acid, the sucralose and the edible essence are all sieved by a sieve of 60 meshes.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111445467.3A CN114041521A (en) | 2021-11-30 | 2021-11-30 | Portable bubble buccal tablet capable of being applied to multiple occasions for refreshing and production process thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111445467.3A CN114041521A (en) | 2021-11-30 | 2021-11-30 | Portable bubble buccal tablet capable of being applied to multiple occasions for refreshing and production process thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN114041521A true CN114041521A (en) | 2022-02-15 |
Family
ID=80211947
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202111445467.3A Pending CN114041521A (en) | 2021-11-30 | 2021-11-30 | Portable bubble buccal tablet capable of being applied to multiple occasions for refreshing and production process thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN114041521A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114903172A (en) * | 2022-05-13 | 2022-08-16 | 柏维力生物技术(安徽)股份有限公司 | Formula and preparation method of sugar-free effervescent tablets for improving vigor |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108031351A (en) * | 2017-12-25 | 2018-05-15 | 郑州丽福爱生物技术有限公司 | Hand-held dry feed, which is mixed, prepares charging gear |
CN112754018A (en) * | 2020-12-28 | 2021-05-07 | 华润圣海健康科技有限公司 | Vitamin bubble buccal tablet and preparation method thereof |
CN112806578A (en) * | 2020-12-30 | 2021-05-18 | 江苏艾兰得营养品有限公司 | Composite vitamin B tablet based on oral microbubble fast disintegrating formula and preparation method thereof |
-
2021
- 2021-11-30 CN CN202111445467.3A patent/CN114041521A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108031351A (en) * | 2017-12-25 | 2018-05-15 | 郑州丽福爱生物技术有限公司 | Hand-held dry feed, which is mixed, prepares charging gear |
CN112754018A (en) * | 2020-12-28 | 2021-05-07 | 华润圣海健康科技有限公司 | Vitamin bubble buccal tablet and preparation method thereof |
CN112806578A (en) * | 2020-12-30 | 2021-05-18 | 江苏艾兰得营养品有限公司 | Composite vitamin B tablet based on oral microbubble fast disintegrating formula and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
营养创新探索进化: "《我换个赛道,你换种方式,一起开动马力帮你摆脱疲劳》", 6 April 2020, "HTTPS://MP.WEIXIN.QQ.COM/S?SRC=11&TIMESTAMP=1693812709&VER=4753&SIGNATURE=BU45FWT8VYHF2VGZMZRXQKYLLFHMB6DBYAAOERUCBHO9VQGN1IVDYIVWUX*UQHGPSMNELU57Y9AASIVEKYHEMIRKJS64YLC1SJVCSTBSOZ9YN6GUIGBWPKQY9BX9RQQG&NEW=1", pages: 1 - 7 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114903172A (en) * | 2022-05-13 | 2022-08-16 | 柏维力生物技术(安徽)股份有限公司 | Formula and preparation method of sugar-free effervescent tablets for improving vigor |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102067935B (en) | Red date and tremella jam for frozen beverage and preparation method thereof | |
CN102389005A (en) | Passiflora edulis drink and preparation method thereof | |
JP2009112236A (en) | Mixing of carbon dioxide-containing soft jelly-like drink packed in hermetic container, and production method of the drink | |
CN105166254A (en) | Fruity soft sweets and preparation method thereof | |
CA2863613A1 (en) | Low calorie drink tablet | |
CN101933565A (en) | Upper jam for semi-solidified or solidified yoghurt | |
CN103396927B (en) | Egg and rice wine contained beverage and production method thereof | |
CN114041521A (en) | Portable bubble buccal tablet capable of being applied to multiple occasions for refreshing and production process thereof | |
CN103053777A (en) | Preserved plum powder tabletting candy produced by directly tabletting complete powder, and preparation method | |
CN105265706A (en) | Making method of teeth-protection sweet orange soft sweets | |
CN106616097A (en) | Passion fruit beverage and making method thereof | |
CN102273693A (en) | Strawberry pulp juice beverage and preparation method thereof | |
CN102232595A (en) | Malt and soda sweet beverage | |
CN113875958A (en) | Suction type functional sleep jelly and production process thereof | |
KR20180020840A (en) | fruit vinegar Jelly | |
CN113040309A (en) | Bottled nutrient soda solid beverage and processing technology thereof | |
CN102232589A (en) | Strawberry pulp and juice and acetic acid drink and preparation method thereof | |
CN107951034B (en) | Effervescent vitamin preparation and its preparing process | |
CN102296019A (en) | Strawberry pulp unstrained wine and preparation method thereof | |
CN104687197A (en) | Coconut fruit particle drink and preparation method thereof | |
CN101919546A (en) | Jujube cheese and preparation process thereof | |
CN108853048A (en) | Organic selenium effervescent tablet and preparation method thereof | |
CN108113005A (en) | Sweet orange multivitamin effervescent tablet | |
TW201608989A (en) | Soft candy and production method thereof | |
CN109221829A (en) | A kind of passiflora edulis drink and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |