CN114015123A - Daily-use clothes cutting-resistant material and preparation method thereof - Google Patents

Daily-use clothes cutting-resistant material and preparation method thereof Download PDF

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Publication number
CN114015123A
CN114015123A CN202111449688.8A CN202111449688A CN114015123A CN 114015123 A CN114015123 A CN 114015123A CN 202111449688 A CN202111449688 A CN 202111449688A CN 114015123 A CN114015123 A CN 114015123A
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China
Prior art keywords
mixing
mixed
stirring
bamboo
solution
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CN202111449688.8A
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Chinese (zh)
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肖惠玲
肖传淼
谢婷华
游淑朋
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Shenzhen Hantang Shijia Clothing Co ltd
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Shenzhen Hantang Shijia Clothing Co ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/02Cellulose; Modified cellulose
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • A41D31/24Resistant to mechanical stress, e.g. pierce-proof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/068Ultra high molecular weight polyethylene

Abstract

The invention provides a daily clothing anti-cutting material and a preparation method thereof, and relates to the technical field of new materials, wherein the daily clothing anti-cutting material comprises bamboo pulp, mother liquor, rubber powder, a mixing agent, a reinforcing agent and a deodorant, the mother liquor is an ultrahigh-strength polyethylene solution, the rubber powder is a rubber solution, the reinforcing agent is a shear thickening solution, the bamboo pulp, the mother liquor, the rubber powder, the mixing agent, the reinforcing agent and the deodorant are mixed and extruded, the clothing cost comfort is increased, the material service life is prolonged, an important effect on the material quality is achieved, the clothing made of the material can be prevented from wrinkling, the later-stage finishing is facilitated, the wrinkling of the clothing finished product is prevented, the hardness of the material is greatly improved, and the breakage rate of the material is reduced when the clothing is scratched by sharp foreign objects.

Description

Daily-use clothes cutting-resistant material and preparation method thereof
Technical Field
The invention relates to the technical field of new materials, in particular to a daily clothes cutting-resistant material and a preparation method thereof.
Background
The patent number is CN202011169665.7, a preparation method of a cutting-resistant material, in particular to a preparation method of a new cutting-resistant material, belonging to the field of high polymer materials. The ultrahigh molecular weight polyethylene fiber with high strength and high modulus is obtained, and has excellent functions of cutting resistance, creep resistance and the like; by utilizing the cheap and easily-obtained silicon dioxide nano powder without increasing complex process flow, a novel anti-cutting material with better excellent performance is obtained, and the anti-cutting creep resistance of the ultra-high molecular weight polyethylene fiber is improved, so that the application range of the ultra-high molecular weight polyethylene fiber is widened. The invention discloses a preparation method of a novel anti-cutting material, which comprises silicon dioxide nanometer powder, ultra-high molecular weight polyethylene and an antioxidant, wherein the rest components are solvents; wherein the concentration of the silicon dioxide nano powder is 0.5-2% (wt) of the ultrahigh molecular weight polyethylene, the concentration of the ultrahigh molecular weight polyethylene is 6-8% (wt), the concentration of the antioxidant is 6-8 thousandths (wt), and the solvent is decahydronaphthalene.
The patent number is CN201811565129.1, a PVC combined material, especially anti-cutting PVC combined material excels in, and it includes PVC glued membrane and wire net, the mode laminating that the PVC glued membrane adopted the hot pressing laminating is at the upper and lower surface of wire net, the PVC glued membrane includes the raw materials of following mass fraction: 45-55 parts of suspension method-polyvinyl chloride resin powder, 24-28 parts of diisononyl phthalate, 4.5-7 parts of dioctyl adipate, 1.0-2.5 parts of epoxidized soybean oil, 1.0-2.5 parts of barium-zinc liquid stabilizer, 10-15 parts of light active calcium carbonate, 0.15-0.25 part of mildew preventive and 1.5-2.2 parts of organic toner.
The anti-cutting material in the patent is poor in flexibility when being used as a raw material for garment processing, reduces wearing comfort, causes damage to the material when being scraped by a sharp foreign object, is low in hardness, and enables the garment formed by processing to be easy to damage.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides the daily clothing cut-preventing material and the preparation method thereof, which can ensure the flexibility of the material while improving the hardness of the material, increase the comfort of the clothing cost, prevent the clothing finished product from wrinkling, greatly improve the hardness of the material and reduce the breakage rate of the material when the material is scraped and bumped by sharp foreign objects.
(II) technical scheme
In order to achieve the purpose, the invention is realized by the following technical scheme: a cut resistant material for everyday clothing comprising: the bamboo pulp, the mother liquor, the rubber powder, the mixing agent, the reinforcing agent and the deodorant are mixed and extruded, the ratio of the bamboo pulp, the mother liquor, the rubber powder, the mixing agent, the reinforcing agent and the deodorant is respectively 3: 2: 2: 1: 1.5: 0.5.
a preparation method of a daily clothing cut-resistant material comprises the following steps:
sp 1: preparing the bamboo pulp: selecting Sasa Aromatica as a raw material, tangent-cutting the selected Sasa Aromatica into sheets, processing to form bamboo pulp, and storing for later use;
sp 2: extracting mother liquor: respectively mixing and stirring the ultra-high molecular weight polyethylene and the linear low density polyethylene with the spinning solution, and proportionally distributing the mixed solution;
sp3: preparation of rubber powder: adding potassium stearate soap into the rubber dry glue, stirring uniformly, adding magnesium sulfate, filtering, drying and molding into powder, and ventilating, drying and storing the obtained powder;
sp4: preparation of the reinforcing agent: putting polyethylene glycol with molecular weight of 200 into a container, uniformly stirring, adding silicon dioxide powder in the stirring process, and putting the stirred sample into a vacuum drying oven to obtain shear thickening fluid;
sp5: mixing raw materials: blending and mixing the bamboo pulp with the reinforcing agent, blending and mixing the mother solution with the rubber powder and the mixing agent, mixing the two blended solutions again, uniformly stirring at a high speed, and adding the deodorant in the stirring process to obtain a mixture;
sp6: extrusion and recovery: filtering, rolling and forming a film on the mixture, extruding and molding the mixture by a screw extruder, and storing and recovering the mixture.
Preferably, the Sagittaria sagittifolia is a bamboo raw material, the bamboo is cut, the cut surface of the bamboo is perpendicular to bamboo chips, the cut bamboo is hydrolyzed by sulfuric acid, the use amount of the sulfuric acid is 5%, and the liquid ratio is 1: and 5, adding 18.5 percent of sodium hydroxide and 2 percent of penetrating agent into the hydrolyzed bamboo for cooking, bleaching and purifying the cooked solution to form bamboo pulp for recycling and storing.
Preferably, the ultrahigh molecular weight polyethylene and the linear low density polyethylene are mixed and stirred with the spinning solution, 180g to 400g of antioxidant, 6g to 12g of emulsifier and 2g to 4g of titanium dioxide are sequentially added when the ultrahigh molecular weight polyethylene is mixed with the spinning solution, the mixture is heated and mixed, 80g to 100g of nucleating agent is added when the linear low density polyethylene is mixed with the spinning solution, and the two solutions are dissolved according to the ratio of 2:1, mixing, recovering and storing.
Preferably, 800g of rubber dry glue and 250g of potassium stearate soap are taken and stirred to be mixed, magnesium sulfate is added after the temperature is reduced, and rubber powder is obtained after filtration, washing and drying.
Preferably, the reinforcing agent is a shear thickening liquid, polyethylene glycol with the molecular weight of 200 is placed into a container, stirring and oscillation are carried out through a constant speed stirrer and an ultrasonic oscillator, the speed of the oscillator is 600r/min, silicon dioxide powder is added in the stirring and oscillation process, stirring and oscillation are continued for 1h, the sample is taken out and placed in a vacuum drying oven for 24h, and then air bubbles of the sample are removed to form the shear thickening liquid.
Preferably, the bamboo pulp and the shear thickening liquid are blended, mixed and placed on one side, the mother solution, the rubber powder and the mixing agent are blended, the two blended solutions are mixed again and stirred at a high speed, a deodorant is added in the stirring process to form a mixture, the mixing agent is a BPO solution, the deodorant is diatomite, pyroligneous liquor and octadecylamine, the mixture is filtered through a 200-mesh filter screen, the mixture is refined through a compression roller in a high-temperature roll refining furnace at 150 ℃, the mixture is subjected to calendering by a calendering machine to form a glue film, the temperature extruded by a screw extruder is adjusted to 220 ℃, and the glue film is extruded and recovered for storage.
(III) advantageous effects
The invention provides a daily clothes cutting-resistant material and a preparation method thereof, and the daily clothes cutting-resistant material has the following beneficial effects:
1. according to the invention, the Sagittaria sagittifolia is used as the raw material of the bamboo pulp, the comprehensive cellulose of the Sagittaria sagittifolia accounts for a larger proportion than that of other raw bamboos, the fiber length and width of the Sagittaria sagittifolia are larger, the bamboo pulp prepared from the Sagittaria sagittifolia and other raw materials are compounded and formed into a material, the dyeing property is good, the dye is easy to diffuse, the color fastness is strong, the finished product can be conveniently dyed in the later period, the ultraviolet-proof function is 20 times stronger than that of other cotton, the ultraviolet-proof function is realized, the bamboo pulp is increased, the smoothness and the hand feeling of the finished product are improved, and the clothes made from the finished product are cool and breathable.
2. According to the invention, by adding a certain amount of shear thickening liquid in the preparation of the material, the shear thickening liquid and the bamboo pulp are mixed to prepare and increase the anti-cutting performance of the material, so that the hardness of the material is increased, meanwhile, the anti-cutting performance of the shear thickening liquid can be enhanced along with the increase of the particle mass fraction of the raw material, the anti-cutting performance of the shear thickening liquid can be adjusted according to the situation, the operation of workers is facilitated, and the damage rate of finished products caused by the scratch of sharp foreign matters can be greatly reduced for clothes made of the material.
3. According to the invention, the ultra-high molecular weight polyethylene fiber and the rubber powder are combined to form the composite material, so that the stretchability of the material is improved, the elasticity and flexibility of the garment can be increased in the preparation of the garment, the wearing experience of the garment is improved, the ultra-high molecular weight polyethylene fiber is used as the whole material, the wear resistance is improved, the service life of the material is prolonged, the important effect on the quality of the material is achieved, the garment prepared from the material can be prevented from wrinkling, and the later-stage finishing is facilitated.
Drawings
FIG. 1 is a schematic view of the preparation method of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
as shown in fig. 1, a cut-resistant material for daily use clothing, comprising: the bamboo pulp, the mother liquor, the rubber powder, the mixing agent, the reinforcing agent and the deodorant are mixed and extruded, the ratio of the bamboo pulp, the mother liquor, the rubber powder, the mixing agent, the reinforcing agent and the deodorant is respectively 3: 2: 2: 1: 1.5: 0.5.
example two:
as shown in figure 1, the preparation method of the daily clothing cut-resistant material comprises the following steps:
sp 1: preparing the bamboo pulp: selecting Sasa Aromatica as a raw material, tangent-cutting the selected Sasa Aromatica into sheets, processing to form bamboo pulp, and storing for later use;
sp 2: extracting mother liquor: respectively mixing and stirring the ultra-high molecular weight polyethylene and the linear low density polyethylene with the spinning solution, and proportionally distributing the mixed solution;
sp3: preparation of rubber powder: adding potassium stearate soap into the rubber dry glue, stirring uniformly, adding magnesium sulfate, filtering, drying and molding into powder, and ventilating, drying and storing the obtained powder;
sp4: preparation of the reinforcing agent: putting polyethylene glycol with molecular weight of 200 into a container, uniformly stirring, adding silicon dioxide powder in the stirring process, and putting the stirred sample into a vacuum drying oven to obtain shear thickening fluid;
sp5: mixing raw materials: mixing and heating the bamboo pulp, the mother liquor, the rubber powder and the reinforcing agent, uniformly stirring at a high speed, and adding the mixing agent and the deodorant in the stirring process to obtain a mixture;
sp6: extrusion and recovery: blending and mixing the bamboo pulp with the reinforcing agent, blending and mixing the mother solution with the rubber powder and the mixing agent, mixing the two blended solutions again, uniformly stirring at a high speed, and adding the deodorant in the stirring process to obtain a mixture.
Example three:
as shown in fig. 1, the arrowhead bamboo is a bamboo raw material, the bamboo is cut, the cut surface of the bamboo is perpendicular to the bamboo sheet, the cut bamboo is hydrolyzed by sulfuric acid, the amount of the sulfuric acid is 5%, and the liquid ratio is 1:5, adding 18.5 percent of sodium hydroxide and 2 percent of penetrant into hydrolyzed bamboo for cooking, wherein the cooking times are two times, the first cooking heat preservation time is 60min, the temperature is 180 ℃, the second cooking heat preservation time is 120mon, the cooking temperature is 200 ℃, the cooked solution is bleached, the alkali content for oxygen bleaching is 3 percent, the enzyme chain additive is 5 percent, the temperature is 100 ℃, the bleaching time is 60min, then a 0.75mm pressure sieve is adopted for purification to form bamboo pulp for recycling and storing, the comprehensive cellulose of the Sasa albo-marginata is more than that of other raw bamboos, the fiber length and the width of the Sasa albo-marginata are larger, the bamboo pulp prepared by the Sasa albo-marginata and other raw materials are compounded and formed into a material, the material has good dyeing property, the dye is easy to diffuse, the color fastness is strong, the dyeing effect is good, the ultraviolet-proof function is 20 times stronger than that of other cotton, and has the ultraviolet-proof function, the bamboo pulp is added to improve the smoothness and hand feeling of the finished product, the clothing made by the finished product is cool and breathable, the reinforcing agent is shear thickening liquid, polyethylene glycol with the molecular weight of 200 is put into a container, stirring and oscillation are carried out through a constant speed stirrer and an ultrasonic oscillator, the speed of the oscillator is 600r/min, silica powder is added in the stirring oscillation process for continuous stirring oscillation for 1h, the silica powder is nano silica powder, a sample is taken out and placed in a vacuum drying box, the temperature of the vacuum drying box is 20 ℃, bubbles in the sample are removed after 24h waiting to form the shear thickening liquid, the shear thickening liquid and the bamboo pulp are mixed to prepare the anti-cutting performance of the material, the hardness of the material is increased, the anti-cutting performance of the shear thickening liquid can be enhanced along with the increase of the particle mass fraction of the raw material, the anti-cutting performance of the shear thickening liquid can be adjusted according to the situation, the clothing made of the material can greatly reduce the breakage rate of finished products caused by the scraping of sharp foreign objects.
Mixing and stirring the ultrahigh molecular weight polyethylene and the linear low density polyethylene with the spinning solution, sequentially adding 180g-400g of antioxidant, 6g-12g of emulsifier and 2g-4g of titanium dioxide when the ultrahigh molecular weight polyethylene is mixed with the spinning solution, heating and mixing, adding 80g-100g of nucleating agent when the linear low density polyethylene is mixed with the spinning solution, and dissolving the two materials according to the proportion of 2:1, mixing, recovering and storing 800g of rubber dry glue and 250g of potassium stearate soap, stirring and mixing, cooling, adding magnesium sulfate, filtering, washing and drying to obtain rubber powder, mixing the prepared ultra-high molecular weight polyethylene, adding the rubber powder, uniformly stirring, adding a mixing agent BPO in the stirring process, improving the stretchability of the material by mixing the ultra-high molecular weight polyethylene and the rubber powder, increasing the elasticity and flexibility of the garment in the preparation of the garment, improving the wearing experience of the garment, integrally improving the wear resistance of the ultra-high molecular weight polyethylene fiber, prolonging the service life of the material, playing an important role in the quality of the material, preventing the garment prepared from the material from wrinkling, facilitating later finishing, mixing and placing the bamboo pulp and the shear thickening fluid on one side, mixing and blending mother liquor with the rubber powder and the mixing agent, mixing the two blended solutions again, stirring at a high speed, adding a deodorant in the stirring process to form a mixture, wherein the mixture is a BPO solution, the deodorant is formed by mixing diatomite, pyroligneous liquor and octadecylamine, the peculiar smell of the material can be effectively removed, filtering the mixture through a 200-mesh filter screen, refining the mixture through a compression roller in a 150-DEG C high-temperature roller refining furnace, calendering the mixture into a glue film through a calendering machine, adjusting the temperature extruded by a screw extruder to 220 ℃, extruding the glue film, and recovering and storing the glue film.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising a reference structure" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (7)

1. A daily clothing cut-resistant material, comprising: the bamboo pulp, the mother liquor, the rubber powder, the mixing agent, the reinforcing agent and the deodorant are mixed and extruded, wherein the mother liquor is an ultrahigh-strength polyethylene solution, the rubber powder is a rubber solution, the reinforcing agent is a shear thickening solution, and the bamboo pulp, the mother liquor, the rubber powder, the mixing agent, the reinforcing agent and the deodorant are mixed and extruded.
2. The preparation method of the daily clothing cut-resistant material is characterized by comprising the following steps:
sp 1: preparing the bamboo pulp: selecting Sasa Aromatica as a raw material, tangent-cutting the selected Sasa Aromatica into sheets, processing to form bamboo pulp, and storing for later use;
sp 2: extracting mother liquor: respectively mixing and stirring the ultra-high molecular weight polyethylene and the linear low density polyethylene with the spinning solution, and proportionally distributing the mixed solution;
sp3 preparation of rubber powder: adding potassium stearate soap into the rubber dry glue, stirring uniformly, adding magnesium sulfate, filtering, drying and molding into powder, and ventilating, drying and storing the obtained powder;
sp4 preparation of fortifier: putting polyethylene glycol with molecular weight of 200 into a container, uniformly stirring, adding silicon dioxide powder in the stirring process, and putting the stirred sample into a vacuum drying oven to obtain shear thickening fluid;
sp5 raw material mixing: blending and mixing the bamboo pulp with the reinforcing agent, blending and mixing the mother solution with the rubber powder and the mixing agent, mixing the two blended solutions again, uniformly stirring at a high speed, and adding the deodorant in the stirring process to obtain a mixture;
sp6 extrusion recovery: filtering, rolling and forming a film on the mixture, extruding and molding the mixture by a screw extruder, and storing and recovering the mixture.
3. The method for preparing a cutting-resistant material for daily-use clothes according to claim 2, wherein the method comprises the following steps: the Sagittaria sagittifolia is a bamboo raw material, the bamboo is cut, the cut surface of the bamboo is perpendicular to bamboo chips, the cut bamboo is hydrolyzed by sulfuric acid, the amount of the sulfuric acid is 5%, the liquid ratio is 1:5, 18.5% of sodium hydroxide and 2% of penetrating agent are added into the hydrolyzed bamboo for cooking, and the cooked solution is bleached and purified to form bamboo pulp for recycling and storage.
4. The method for preparing a cutting-resistant material for daily-use clothes according to claim 2, wherein the method comprises the following steps: the ultra-high molecular weight polyethylene and the linear low density polyethylene are mixed and stirred with the spinning solution, 180g to 400g of antioxidant, 6g to 12g of emulsifier and 2g to 4g of titanium dioxide are sequentially added when the ultra-high molecular weight polyethylene is mixed with the spinning solution, the mixture is heated and mixed, 80g to 100g of nucleating agent is added when the linear low density polyethylene is mixed with the spinning solution, and the two solutions are mixed according to the proportion of 2:1, recovered and stored.
5. The method for preparing a cutting-resistant material for daily-use clothes according to claim 2, wherein the method comprises the following steps: and mixing 800g of rubber dry glue and 250g of potassium stearate soap, stirring, cooling, adding magnesium sulfate, filtering, washing and drying to obtain rubber powder.
6. The method for preparing a cutting-resistant material for daily-use clothes according to claim 2, wherein the method comprises the following steps: the reinforcing agent is shear thickening liquid, polyethylene glycol with the molecular weight of 200 is placed in a container, stirring and oscillation are carried out through a constant speed stirrer and an ultrasonic oscillator, the speed of the oscillator is 600r/min, silicon dioxide powder is added in the stirring and oscillation process to continue stirring and oscillation for 1h, a sample is taken out and placed in a vacuum drying oven to wait for 24h, and then air bubbles of the sample are removed to form the shear thickening liquid.
7. The method for preparing a cutting-resistant material for daily-use clothes according to claim 2, wherein the method comprises the following steps: the bamboo pulp and the shear thickening liquid are mixed and placed on one side, the mother solution, the rubber powder and the mixing agent are mixed and blended, the two blended solutions are mixed again and stirred at a high speed, a deodorant is added in the stirring process to form a mixture, the mixing agent is a BPO solution, the deodorant is formed by mixing diatomite, pyroligneous liquor and octadecylamine, the mixture is filtered through a 200-mesh filter screen, the mixture is refined through a compression roller in a 150-DEG C high-temperature roller refining furnace, the mixture is subjected to calendering by a calendering machine to form a glue film, the extruding temperature of a screw extruder is adjusted to 220 ℃ for extruding, and the glue film is recovered and stored.
CN202111449688.8A 2021-11-30 2021-11-30 Daily-use clothes cutting-resistant material and preparation method thereof Pending CN114015123A (en)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050266748A1 (en) * 2003-05-19 2005-12-01 Wagner Norman J Advanced body armor utilizing shear thickening fluids
CN1704439A (en) * 2004-06-02 2005-12-07 中国石油天然气股份有限公司 Method for making powdered rubber
CN1970850A (en) * 2006-10-25 2007-05-30 宜宾丝丽雅股份有限公司 Method for making bamboo pulp for use in preparation of artificial fiber
CN107815870A (en) * 2017-10-26 2018-03-20 天津工业大学 A kind of preparation method of soft permanent seal cooling stab-resistant material
CN108193533A (en) * 2017-12-10 2018-06-22 常州市雄图纺织有限公司 A kind of preparation method of bamboo pulp
CN110318116A (en) * 2019-05-29 2019-10-11 长青藤高性能纤维材料有限公司 A kind of preparation method of extra-high strong ultra high molecular weight polyethylene fiber
CN112391691A (en) * 2020-09-21 2021-02-23 江苏六甲科技有限公司 Bulletproof material prepared from ultrahigh molecular weight polyethylene fiber/shear thickening fluid composite fiber
CN112442753A (en) * 2020-10-28 2021-03-05 中石化南京化工研究院有限公司 Preparation method of novel anti-cutting material
CN112900105A (en) * 2021-01-18 2021-06-04 河北科技大学 Flexible protection composite material and manufacturing method thereof

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050266748A1 (en) * 2003-05-19 2005-12-01 Wagner Norman J Advanced body armor utilizing shear thickening fluids
CN1704439A (en) * 2004-06-02 2005-12-07 中国石油天然气股份有限公司 Method for making powdered rubber
CN1970850A (en) * 2006-10-25 2007-05-30 宜宾丝丽雅股份有限公司 Method for making bamboo pulp for use in preparation of artificial fiber
CN107815870A (en) * 2017-10-26 2018-03-20 天津工业大学 A kind of preparation method of soft permanent seal cooling stab-resistant material
CN108193533A (en) * 2017-12-10 2018-06-22 常州市雄图纺织有限公司 A kind of preparation method of bamboo pulp
CN110318116A (en) * 2019-05-29 2019-10-11 长青藤高性能纤维材料有限公司 A kind of preparation method of extra-high strong ultra high molecular weight polyethylene fiber
CN112391691A (en) * 2020-09-21 2021-02-23 江苏六甲科技有限公司 Bulletproof material prepared from ultrahigh molecular weight polyethylene fiber/shear thickening fluid composite fiber
CN112442753A (en) * 2020-10-28 2021-03-05 中石化南京化工研究院有限公司 Preparation method of novel anti-cutting material
CN112900105A (en) * 2021-01-18 2021-06-04 河北科技大学 Flexible protection composite material and manufacturing method thereof

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Application publication date: 20220208