CN113980729A - Water-based wire drawing lubricant for drawing iron-chromium-aluminum filaments, and preparation method and application thereof - Google Patents
Water-based wire drawing lubricant for drawing iron-chromium-aluminum filaments, and preparation method and application thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21C—MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES OR PROFILES, OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- B21C9/00—Cooling, heating or lubricating drawing material
- B21C9/02—Selection of compositions therefor
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
Abstract
The application relates to the technical field of reagents for drawing processes, in particular to a water-based wire drawing lubricant for drawing iron-chromium-aluminum filaments, a preparation method and application thereof, wherein the water-based wire drawing lubricant comprises the following components: the liquid A comprises a first surfactant, an organic solvent and a pH regulator, and the liquid B comprises an organic base and a second surfactant; the method comprises the following steps: respectively obtaining solution A and solution B containing the chemical components; mixing the solution A and the solution B with micro-electro-water to obtain a water-based wire drawing lubricant; the filament surface treatment method comprises the steps of fully dispersing all effective components to the surface of a filament by using a first surfactant, a pH regulator, organic base and a second surfactant and by using micro-electric water, removing oil stains on the surface of the filament by using the first surfactant, the second surfactant and the organic base, enabling the performance of all the effective components to be optimal by using the pH regulator, ensuring the surface quality of the filament, and lubricating and cleaning by using the micro-electric water to obtain a filament finished product with good lubricity and high surface quality.
Description
Technical Field
The application relates to the technical field of reagents for drawing processes, in particular to a water-based wire drawing lubricant for drawing iron-chromium-aluminum filaments, and a preparation method and application thereof.
Background
The existing drawing process of iron-chromium-aluminum filaments is to draw a semi-finished steel wire with the diameter of 1.0-1.5 mm after annealing in a protective atmosphere into a finished product of a filament with the diameter of 0.2-10.6 mm by using a water tank drawing machine through 10-19 dies, wherein the drawing lubricating medium used for drawing is drawing oil, and the conventional drawing oil consists of base oil and additives.
However, with the extension of the service life of the wire drawing oil, the kinematic viscosity, the granularity and the acid-base index of the wire drawing oil are increased, and the combined action of dust in the environment makes the wire drawing oil easy to deteriorate, the processing difficulty of the wire drawing oil deposition oil sludge after deterioration is large, the cost is high, and the efficiency is low.
Therefore, how to obtain the wire drawing lubricant with stable components on the basis of ensuring the quality of finished products is a technical problem to be solved urgently at present.
Disclosure of Invention
The application provides a water-based wire drawing lubricant for drawing iron-chromium-aluminum filaments, and a preparation method and application thereof, and aims to solve the technical problem that components of the wire drawing lubricant cannot be stable on the basis of ensuring the quality of finished products in the prior art.
In a first aspect, the present application provides a water-based wire drawing lubricant for drawing iron-chromium-aluminum filaments, comprising, in mass fraction: solution A: 6.5-7%, liquid B: 3 to 3.5 percent of solvent and the balance of solvent;
the solution A comprises a first surfactant, an organic solvent, a pH regulator and an auxiliary agent, and the solution B comprises an organic base and a second surfactant.
Optionally, the first surfactant comprises at least one of nonylphenol polyoxyethylene ether, lauryl alcohol polyoxyethylene ether and fatty alcohol polyoxyethylene ether carboxylic acid alcohol;
the organic solvent comprises at least one of diethylene glycol butyl ether and propylene glycol methyl ether acetate;
the pH regulator comprises at least one of sodium hydroxide, potassium hydroxide and ammonia water;
the auxiliary agent comprises at least one of water-soluble silicone oil and dimethyl silicone oil.
Optionally, the liquid a comprises the following raw materials in percentage by mass: polyoxyethylene nonyl phenyl ether: 16-17%, polyoxyethylene lauryl ether: 9% -10%, diethylene glycol monobutyl ether: 6.8-7.2%, fatty alcohol-polyoxyethylene ether carboxylic acid alcohol: 4.5% -5.5%, potassium hydroxide: 1.1-1.5%, water-soluble silicone oil: 2% -2.5%, water: 58 to 60 percent.
Optionally, the organic base comprises at least one of diethanolamine, triethanolamine, and oleic acid;
the second surfactant comprises at least one of dodecyl dimethyl benzyl ammonium chloride, dodecyl trimethyl benzyl ammonium chloride and lauryl dimethyl benzyl ammonium chloride.
Optionally, the liquid B comprises the following raw materials in parts by mass: diethanolamine: 7% -7.5%, triethanolamine: 14% -16%, oleic acid: 13% -14%, dodecyl dimethyl benzyl ammonium chloride: 0.3% -0.5%, water: 63 to 65 percent.
Optionally, the mass concentration of the dodecyl dimethyl benzyl ammonium chloride is 45-50%.
Optionally, the solvent comprises micro-electricity water, and the pH value of the micro-electricity water is 13-14.
Optionally, the pH of the water-based wire drawing lubricant is 8.5-9.
In a second aspect, the present application provides a method of preparing a water-based wire drawing lubricant for drawing iron chromium aluminum filaments, the method comprising:
respectively obtaining a solution A and a solution B containing the raw materials;
and mixing the solution A and the solution B with micro-electro-water to obtain the water-based wire drawing lubricant.
In a third aspect, the application provides the use of the water-based wire-drawing lubricant for drawing iron chromium aluminum filaments, wherein the water-based wire-drawing lubricant is used in the drawing process for preparing the iron chromium aluminum filaments.
Compared with the prior art, the technical scheme provided by the embodiment of the application has the following advantages:
the water-based wire drawing lubricant for drawing iron-chromium-aluminum filaments provided by the embodiment of the application adopts the first surfactant, the pH regulator, the organic solvent and the auxiliary agent in the solution A, the first surfactant and the pH regulator are fully mixed by the organic solvent and the auxiliary agent to form a solution, then the organic base and the second surfactant in the solution B are passed through, the solvent comprising the micro-electricity water is reused, the micro-electricity water is an aqueous solution of small molecular groups generated by electrolyzing water, so the water-based wire drawing lubricant has the characteristics of lubricity, rust resistance, cleaning property and permeability, the effective components of the first surfactant in the solution A, the second surfactant in the solution B and the organic base can be fully dispersed on the surfaces of the filaments, meanwhile, the first surfactant, the second surfactant and the organic base can remove organic impurities such as oil stains on the surfaces of the filaments, and the pH regulator can regulate the effective components of each reagent to the optimal pH, the performance of each effective component is optimized, so that the surface quality of the filament is ensured, and the finished filament with good lubricity and high surface quality can be obtained after micro-electric water lubrication and cleaning and drawing.
Drawings
The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments consistent with the invention and together with the description, serve to explain the principles of the invention.
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, and it is obvious for those skilled in the art that other drawings can be obtained according to the drawings without inventive exercise.
Fig. 1 is a schematic flow chart of a preparation method provided in an embodiment of the present application.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present application clearer, the technical solutions in the embodiments of the present application will be clearly and completely described below with reference to the drawings in the embodiments of the present application, and it is obvious that the described embodiments are some embodiments of the present application, but not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present application.
In one embodiment of the present application, as shown in fig. 1, there is provided a water-based wire drawing lubricant for drawing iron chromium aluminum filaments, the water-based wire drawing lubricant comprising, in mass fraction: solution A: 6.5-7%, liquid B: 3 to 3.5 percent of solvent and the balance of solvent;
the solution A comprises a first surfactant, an organic solvent, a pH regulator and an auxiliary agent, and the solution B comprises an organic base and a second surfactant.
In the application, the positive effect that the mass fraction of the solution A is 6.5-7% is that in the mass fraction range, the water-based wire drawing lubricant has good lubricity and smaller friction coefficient, and meanwhile, the heat dissipation and cooling performance of the water-based wire drawing lubricant is good; when the mass fraction is larger than the maximum value of the end point of the range, the adverse effect is that the content of the liquid A is too much, so that the heat dissipation effect of the iron-chromium-aluminum alloy material is poor, and when the mass fraction is smaller than the minimum value of the end point of the range, the adverse effect is that the content of the liquid A is too little, so that the cleaning effect of the lubrication of the wire drawing lubricant is poor.
The positive effect that the mass fraction of the liquid B is 3-3.5% is that the liquid B can adjust the pH value of the water-based wire-drawing lubricant within the mass fraction range, when the mass fraction is larger than the maximum value of the end point of the range, the adverse effect is caused that the content of the liquid B is too much, the cleaning effect of the ferrochromium-aluminum powder is poor, and when the mass fraction is smaller than the minimum value of the end point of the range, the adverse effect is caused that the content of the liquid B is too little, and the surface brightness effect of the drawn ferrochromium-aluminum filament finished product is poor.
As an alternative embodiment, the first surfactant includes at least one of nonylphenol polyoxyethylene ether, lauryl alcohol polyoxyethylene ether, and fatty alcohol polyoxyethylene ether carboxylic acid alcohol;
the organic solvent comprises at least one of diethylene glycol butyl ether and propylene glycol methyl ether acetate;
the pH regulator comprises at least one of sodium hydroxide, potassium hydroxide and ammonia water;
the auxiliary agent comprises at least one of water-soluble silicone oil and dimethyl silicone oil.
As an optional embodiment, the raw materials of the solution a comprise, by mass fraction: polyoxyethylene nonyl phenyl ether: 16-17%, polyoxyethylene lauryl ether: 9% -10%, diethylene glycol monobutyl ether: 6.8-7.2%, fatty alcohol-polyoxyethylene ether carboxylic acid alcohol: 4.5% -5.5%, potassium hydroxide: 1.1-1.5%, water-soluble silicone oil: 2% -2.5%, water: 58 to 60 percent.
In the component of the solution A, the positive effect that the mass fraction of the polyoxyethylene nonyl phenyl ether is 16-17% is that the polyoxyethylene nonyl phenyl ether can fully play the function of a surfactant within the mass fraction range; when the value of the mass fraction is larger than the maximum value of the end point of the range, the adverse effect is that the content of the polyoxyethylene nonyl phenyl ether is too much, the emulsifying property of the water-based wire-drawing lubricant is poor, and when the value of the mass fraction is smaller than the minimum value of the end point of the range, the adverse effect is that the cleaning and rust removing effect of the water-based wire-drawing lubricant is not obvious.
The lauryl alcohol polyoxyethylene ether with the mass fraction of 9-10% has the positive effect that the lauryl alcohol polyoxyethylene ether can fully play the role of a surfactant in the mass fraction range; when the mass fraction is larger than the maximum value of the end point of the range, the adverse effect is that the content of the polyoxyethylene lauryl ether is too much, a uniform oil film layer is formed on the surface of the finished product of the iron-chromium-aluminum wire after wire drawing, so that the brightness effect of the finished product of the iron-chromium-aluminum wire is poor, and when the mass fraction is smaller than the minimum value of the end point of the range, the adverse effect is that the content of the polyoxyethylene lauryl ether is too low, so that the lubricating effect of the water-based wire drawing lubricant is poor.
The positive effect that the mass fraction of the diethylene glycol butyl ether is 6.8-7.2% is that the diethylene glycol butyl ether can be used as an organic solvent in the mass fraction range; when the mass fraction is larger than the maximum value of the end point of the range, the adverse effect is that the content of the diethylene glycol butyl ether is too large, the lubricating performance of the diethylene glycol butyl ether is poor, and when the mass fraction is smaller than the minimum value of the end point of the range, the adverse effect is that the content of the diethylene glycol butyl ether is too low, and the cleaning effect of the iron-chromium-aluminum filament finished product is poor.
The fatty alcohol-polyoxyethylene ether carboxylic acid alcohol has the positive effect that the fatty alcohol-polyoxyethylene ether carboxylic acid alcohol can promote the components to be uniformly dispersed in the wire-drawing lubricant within the mass fraction range, so that the stability of the water-based wire-drawing lubricant can be effectively improved, and meanwhile, the fatty alcohol-polyoxyethylene ether carboxylic acid alcohol can also obviously prolong the service life and the storage life of the water-based wire-drawing lubricant; when the value of the mass fraction is larger than the maximum value of the end point of the range, the adverse effect is that the content of the fatty alcohol-polyoxyethylene ether carboxylic alcohol is too large, the water-based wire-drawing lubricant is too viscous, and when the value of the mass fraction is smaller than the minimum value of the end point of the range, the adverse effect is that the content of the fatty alcohol-polyoxyethylene ether carboxylic alcohol is too low, the components of the water-based wire-drawing lubricant are easy to agglomerate, and the lubricating performance of the water-based wire-drawing lubricant is affected.
The positive effect that the mass fraction of the potassium hydroxide is 1.1-1.5% is that the pH value of the water-based wire drawing lubricant can be fully adjusted within the mass fraction range; when the mass fraction is greater than the maximum of the end of the range, an adverse effect will result in an excessive potassium hydroxide content which will result in a high pH of the water-based wiredrawing lubricant, and when the mass fraction is less than the minimum of the end of the range, an adverse effect will result in an excessively low potassium hydroxide content which will result in a low pH of the wiredrawing lubricant.
The water-soluble silicone oil with the mass fraction of 2-2.5% has the positive effects that in the mass fraction range, the water-soluble silicone oil can effectively reduce the friction force and stress among molecules of the water-based wire drawing lubricant component, thereby playing the roles of leveling and defoaming; when the value of the mass fraction is larger than the maximum value of the end point of the range, the adverse effect is that the content of the water-soluble silicone oil is too much, the wiredrawing lubricant is too viscous, and when the value of the mass fraction is smaller than the minimum value of the end point of the range, the adverse effect is that the content of the water-soluble silicone oil is too low, and the leveling and defoaming effects are not ideal.
The water has the positive effects of improving the lubricating performance of the water-based wire drawing lubricant, and simultaneously being a lubricating medium for reducing the frictional resistance and slowing down the abrasion of the water-based wire drawing lubricant; when the mass fraction is greater than the maximum value at the end of the range, an adverse effect will result in dilution of the water-based wire drawing lubricant by an excessive amount of water, and when the mass fraction is less than the minimum value at the end of the range, an adverse effect will result in an excessively low amount of water, which will result in an insignificant improvement in the lubricating effect of the water-based wire drawing lubricant.
As an alternative embodiment, the organic base comprises at least one of diethanolamine, triethanolamine, and oleic acid;
the second surfactant includes at least one of dodecyl dimethyl benzyl ammonium chloride and lauryl dimethyl benzyl ammonium chloride.
As an optional embodiment, the liquid B comprises the following raw materials in parts by mass: diethanolamine: 7% -7.5%, triethanolamine: 14% -16%, oleic acid: 13% -14%, dodecyl dimethyl benzyl ammonium chloride: 0.3% -0.5%, water: 63 to 65 percent.
The positive effect that the mass fraction of the diethanolamine is 7-7.5 percent is that the diethanolamine can play a corrosion inhibition role in the wire drawing lubricant within the mass fraction range; when the mass fraction is larger than the maximum value of the end point of the range, the adverse effect is that the diethanolamine content is too high, the wiredrawing lubricant solution is too alkaline, and when the mass fraction is smaller than the minimum value of the end point of the range, the adverse effect is that the diethanolamine content is insufficient, and the wiredrawn iron-chromium-aluminum filaments are easy to corrode.
The positive effect that the mass fraction of the triethanolamine is 14-16% is that in the mass fraction range, the triethanolamine plays a role in neutralizing and lubricating the wire drawing lubricant, and the decontamination performance of the water-based wire drawing lubricant is improved; when the mass fraction is greater than the maximum of the end point of the range, the resulting adverse effect is that the triethanolamine content is too high, resulting in the wiredrawing lubricant being too alkaline, and when the mass fraction is less than the minimum of the end point of the range, the resulting adverse effect is that the triethanolamine content is less, resulting in poor stain removal performance of the water-based wiredrawing lubricant.
The active effect that the mass fraction of the oleic acid is 13-14% is that the oleic acid can play a good role in lubricating and removing rust within the value range of the mass fraction; when the mass fraction is greater than the maximum value of the end point of the range, the adverse effect is that the content of oleic acid is too large, so that the water-based wire-drawing lubricant is easy to deteriorate, and when the mass fraction is less than the minimum value of the end point of the range, the adverse effect is that the content of oleic acid is too small, so that the rust removal effect of the water-based wire-drawing lubricant is poor.
The mass fraction of the dodecyl dimethyl benzyl ammonium chloride is 0.3-0.5%, and the dodecyl dimethyl benzyl ammonium chloride can play the roles of emulsification and bacteriostasis within the value range of the mass fraction; when the mass fraction is larger than the maximum value of the end point of the range, the adverse effect is that the content of the dodecyl dimethyl benzyl ammonium chloride is too much, the water-based wire-drawing lubricating fluid is too dispersed, and when the mass fraction is smaller than the minimum value of the end point of the range, the adverse effect is that the content of the dodecyl dimethyl benzyl ammonium chloride is too low, so that the emulsification and bacteriostasis effects of the water-based wire-drawing lubricating fluid are poor.
The lubricating performance of the water-based wire drawing lubricant can be improved, and the lubricating medium is used for reducing the friction resistance and slowing down the abrasion of the water-based wire drawing lubricant; when the mass fraction is greater than the maximum value at the end of the range, an adverse effect will result in dilution of the water-based wire drawing lubricant by an excessive amount of water, and when the mass fraction is less than the minimum value at the end of the range, an adverse effect will result in an excessively low amount of water, which will result in an insignificant improvement in the lubricating effect of the water-based wire drawing lubricant.
As an optional embodiment, the mass concentration of the dodecyl dimethyl benzyl ammonium chloride is 45% to 50%.
In the application, the positive effect that the mass concentration of the dodecyl dimethyl benzyl ammonium chloride is 40-45% is that the dodecyl dimethyl benzyl ammonium chloride can effectively control the bacterial reproduction in the lubricant within the mass fraction range, so that the water-based wire drawing lubricant has a certain corrosion inhibition effect; when the value of the mass concentration is larger than the maximum value of the end point of the range, the adverse effect is that the content of the dodecyl dimethyl benzyl ammonium chloride is too much, the water-based wiredrawing lubricating fluid is too dispersed, and when the value of the mass concentration is smaller than the minimum value of the end point of the range, the adverse effect is that the content of the dodecyl dimethyl benzyl ammonium chloride is too low, the bacteriostatic effect is poor, and the corrosion inhibition effect of the water-based wiredrawing lubricating fluid is not obvious.
As an optional embodiment, the solvent comprises micro-electricity water, and the pH value of the micro-electricity water is 13-14.
In the application, the pH value of the micro-electricity water is 13-14, and the positive effects that in the range, the micro-electricity water can effectively adjust the pH value of the wire drawing lubricant, and meanwhile, the micro-electricity water has lubricating, cleaning, rust preventing and permeating effects due to small molecular groups in the micro-electricity water; when the value of the pH value is less than the minimum value of the end point of the range, the adverse effect is that the alkalinity of the micro-electricity water is insufficient, and the lubricating, cleaning, rust prevention and infiltration effects of the micro-electricity water are poor.
As an optional embodiment, the pH of the water-based wire drawing lubricant is 8.5-9.
In one embodiment of the present application, there is provided a method of preparing a water-based wire drawing lubricant for drawing iron chromium aluminum filaments, the method comprising:
s1, respectively obtaining a solution A and a solution B containing the raw materials;
and S2, mixing the solution A and the solution B with micro-electro-water to obtain the water-based wire drawing lubricant.
In one embodiment of the present application, there is provided the use of a water-based wire drawing lubricant for drawing iron chromium aluminum filaments, the water-based wire drawing lubricant being used in a drawing process for iron chromium aluminum filament preparation.
Example 1
A water-based wire drawing lubricant for drawing iron chromium aluminum filaments comprises the following components in percentage by mass: solution A: 6.75%, liquid B: 3.25 percent, and the balance of solvent;
the liquid A comprises a first surfactant, an organic solvent and a pH regulator, and the liquid B comprises an organic base and a second surfactant.
The liquid A comprises the following raw materials in parts by mass: polyoxyethylene nonyl phenyl ether: 16.5%, polyoxyethylene lauryl ether: 9.5%, diethylene glycol butyl ether: 7% of fatty alcohol-polyoxyethylene ether carboxylic acid alcohol: 5%, potassium hydroxide: 1.3%, water-soluble silicone oil: 2.25%, water: 58.45 percent.
The liquid B comprises the following raw materials in percentage by mass: diethanolamine: 7.25%, triethanolamine: 15%, oleic acid: 13.5%, dodecyl dimethyl benzyl ammonium chloride: 0.4%, water: 63.85 percent.
The mass concentration of the dodecyl dimethyl benzyl ammonium chloride is 45 percent.
The solvent is microelectric water, and the pH value of the microelectric water is 13.8.
In one embodiment of the present application, there is provided a method of preparing a water-based wire drawing lubricant for drawing iron chromium aluminum filaments, the method comprising:
s1, respectively obtaining a solution A and a solution B containing the chemical components;
and S2, mixing the solution A and the solution B with micro-electro-water to obtain the water-based wire drawing lubricant.
The pH of the water-based drawing lubricant was 8.7.
Example 2
Comparing example 2 with example 1, example 2 differs from example 1 in that:
a water-based wire drawing lubricant for drawing iron chromium aluminum filaments comprises the following components in percentage by mass: solution A: 6.5%, liquid B: 3 percent of solvent and the balance of solvent;
the liquid A comprises a first surfactant, an organic solvent and a pH regulator, and the liquid B comprises an organic base and a second surfactant.
The liquid A comprises the following raw materials in parts by mass: polyoxyethylene nonyl phenyl ether: 16%, polyoxyethylene lauryl ether: 9%, diethylene glycol butyl ether: 6.8%, fatty alcohol polyoxyethylene ether carboxylic acid alcohol: 4.5%, potassium hydroxide: 1.1%, water-soluble silicone oil: 2.0%, water: 60.6 percent.
The liquid B comprises the following raw materials in percentage by mass: diethanolamine: 7%, triethanolamine: 15%, oleic acid: 13%, dodecyl dimethyl benzyl ammonium chloride: 0.3%, water: and (4) 64.7%.
The mass concentration of the dodecyl dimethyl benzyl ammonium chloride is 45 percent.
The solvent is microelectric water, and the pH value of the microelectric water is 13.
The pH of the water-based drawing lubricant was 8.5.
Example 3
Comparing example 3 with example 1, example 3 differs from example 1 in that:
a water-based wire drawing lubricant for drawing iron chromium aluminum filaments, the water-based wire drawing lubricant comprising, in mass fraction: solution A: 7%, liquid B: 3.5 percent, and the balance of solvent;
the liquid A comprises a first surfactant, an organic solvent and a pH regulator, and the liquid B comprises an organic base and a second surfactant.
The liquid A comprises the following raw materials in parts by mass: polyoxyethylene nonyl phenyl ether: 17%, polyoxyethylene lauryl ether: 10%, diethylene glycol butyl ether: 7.2%, fatty alcohol-polyoxyethylene ether carboxylic acid alcohol: 5.5%, potassium hydroxide: 1.5%, water-soluble silicone oil: 2.5%, water: 56.3 percent.
The liquid B comprises the following raw materials in percentage by mass: diethanolamine: 7.5%, triethanolamine: 20%, oleic acid: 14%, dodecyl dimethyl benzyl ammonium chloride: 0.5%, water: 58 percent.
The mass concentration of the dodecyl dimethyl benzyl ammonium chloride is 50 percent.
The solvent is microelectric water, and the pH value of the microelectric water is 14.
The pH of the water-based drawing lubricant was 9.
Comparative example 1
Comparative example 1 and example 1 were compared, and comparative example 1 and example 1 were distinguished in that:
the oil extraction is carried out by adopting a conventional organic oil lubricant.
Comparative example 2
Comparative example 2 is compared with example 1, and comparative example 2 differs from example 1 in that:
the water-based wire drawing lubricant comprises the following components in percentage by mass: solution A: 10%, liquid B: 5 percent, and the balance of micro-electricity water.
Comparative example 3
Comparative example 3 is compared with example 1, and comparative example 3 differs from example 1 in that:
the water-based wire drawing lubricant comprises the following components in percentage by mass: solution A: 5%, liquid B: 2 percent of water, and the balance of micro-electricity water.
Comparative example 4
Comparative example 4 is compared with example 1, and comparative example 4 differs from example 1 in that:
the liquid A comprises the following raw materials in parts by mass: polyoxyethylene nonyl phenyl ether: 20%, polyoxyethylene lauryl ether: 15%, diethylene glycol butyl ether: 8% of fatty alcohol-polyoxyethylene ether carboxylic acid alcohol: 6%, potassium hydroxide: 2%, water-soluble silicone oil: 4%, water: 45 percent.
Comparative example 5
Comparative example 5 is compared with example 1, and comparative example 5 differs from example 1 in that:
the liquid A comprises the following raw materials in parts by mass: polyoxyethylene nonyl phenyl ether: 15%, polyoxyethylene lauryl ether: 8%, diethylene glycol monobutyl ether: 6 percent, fatty alcohol polyoxyethylene ether carboxylic acid alcohol: 4%, potassium hydroxide: 1%, water-soluble silicone oil: 1.5%, water: and (4) 64.5%.
Comparative example 6
Comparative example 6 is compared with example 1, and comparative example 6 differs from example 1 in that:
the liquid B comprises the following raw materials in percentage by mass: diethanolamine: 8%, triethanolamine: 20%, oleic acid: 15%, dodecyl dimethyl benzyl ammonium chloride: 1%, water: 56 percent.
Comparative example 7
Comparative example 7 was compared with example 1, and comparative example 7 was different from example 1 in that
The liquid B comprises the following raw materials in percentage by mass: diethanolamine: 6.5%, triethanolamine: 13%, oleic acid: 12%, dodecyl dimethyl benzyl ammonium chloride: 0.1%, water: 68.4 percent.
Comparative example 8
Comparative example 8 is compared with example 1, and comparative example 8 differs from example 1 in that:
the liquid A comprises the following raw materials in parts by mass: polyoxyethylene lauryl ether: 15%, diethylene glycol butyl ether: 7.5%, fatty alcohol polyoxyethylene ether carboxylic acid alcohol: 6.5%, potassium hydroxide: 2.5%, water-soluble silicone oil: 8.5%, water: 60 percent.
The liquid B comprises the following raw materials in percentage by mass: triethanolamine: 22%, oleic acid: 16%, dodecyl dimethyl benzyl ammonium chloride: 2.5%, water: and 59.5 percent.
The mass concentration of the dodecyl dimethyl benzyl ammonium chloride is 45 percent.
The solvent is microelectric water, and the pH value of the microelectric water is 13.8.
The pH of the water-based drawing lubricant was 9.
Comparative example 9
Comparative example 9 is compared with example 1, and comparative example 9 differs from example 1 in that:
the liquid A comprises the following raw materials in parts by mass: polyoxyethylene nonyl phenyl ether: 20%, diethylene glycol butyl ether: 11%, fatty alcohol polyoxyethylene ether carboxylic acid alcohol: 8%, potassium hydroxide: 2%, water-soluble silicone oil: 5%, water: 54 percent.
The liquid B comprises the following raw materials in percentage by mass: diethanolamine: 9%, oleic acid: 18%, dodecyl dimethyl benzyl ammonium chloride: 0.8%, water: 72.2 percent.
The mass concentration of the dodecyl dimethyl benzyl ammonium chloride is 45 percent.
The solvent is microelectric water, and the pH value of the microelectric water is 13.8.
The pH of the water-based drawing lubricant was 8.5.
Related experiments:
the drawing lubricants obtained in examples 1 to 3 and comparative examples 1 to 9 were collected, and the respective drawing lubricants were subjected to performance tests, and the results are shown in table 1.
Test methods of the related experiments:
difference in carbon content: the method is characterized in that a wire drawing lubricant is used in a wire drawing process, the carbon content of a filament before wire drawing and the carbon content of a filament after high-temperature annealing after wire drawing are detected, and the difference value of the carbon content and the carbon content is the carbon content difference rate, wherein the carbon content detection method is that the total carbon and sulfur content of steel is measured by an infrared absorption method after combustion in a high-frequency induction furnace according to GB/T20123-2006.
TABLE 1
| Categories | Carbon content before drawing (%) | Carbon content after drawing (%) | Difference in carbon content (%) |
| Example 1 | 0.035 | 0.036 | 2.86％ |
| Example 2 | 0.033 | 0.034 | 3.03％ |
| Example 3 | 0.030 | 0.031 | 3.33％ |
| Example 4 | 0.035 | 0.038 | 8.57％ |
| Example 5 | 0.034 | 0.036 | 5.88％ |
| Comparative example 1 | 0.032 | 0.034 | 6.25％ |
| Comparative example 2 | 0.035 | 0.037 | 5.71％ |
| Comparative example 3 | 0.034 | 0.036 | 5.88％ |
| Comparative example 4 | 0.033 | 0.035 | 6.06％ |
| Comparative example 5 | 0.029 | 0.031 | 6.89％ |
| Comparative example 6 | 0.030 | 0.032 | 6.67％ |
| Comparative example 7 | 0.031 | 0.033 | 6.45％ |
In the context of table 1, the following,
the carbon content difference refers to the carbon content difference before and after wire drawing, and the lower the carbon content difference is, the lower the carbon content in the wire drawing lubricant is, and the high quality of the finished product of the filament is also shown.
From the data of examples 1-5, it can be seen that:
when the proportion of each component of the wire drawing lubricant, the pH value of micro-electro-water and the like are in a given range, the difference of carbon content before and after drawing is small, and the wire drawing lubricant prepared according to the given range of the application has obvious effect on improving the carburization problem of finished products before and after drawing.
From the data of comparative examples 1 to 9, it can be seen that:
after the water-based wire drawing lubricant is adopted for drawing, the increase of the carbon content of the iron-chromium-aluminum thin wire is obviously less than that of an oil drawn iron-chromium-aluminum thin wire, and the water-based wire drawing lubricant can effectively clean residual wire drawing oil sludge on the surface of the drawn thin wire, metal powder attached to the surface of the steel wire and the like, and effectively solve the problem of recarburization of the steel wire in the drawing process. .
From comparative examples 2 and 3, it is understood that when the composition in A, B liquid in the drawing lubricant is kept constant, if the compounding ratio of A, B liquid is not within a given range, the difference in carbon content between before and after drawing increases to some extent; comparative examples 4 to 7 show that when the components in drawing lubricant A, B were outside the ranges given in the present application, the amount of carburization before and after drawing tended to increase; in comparison between examples 8 and 9, it is found that the amount of carburization before and after drawing tends to increase when the composition of drawing lubricant A, B is changed.
It can be seen from comparative example 7 that when the value of the triethanolamine mass fraction is less than the end-point minimum of the given range, the water-based wire-drawing lubricant has poor detergency, and the wire-drawing lubricant has poor cleaning effect, thereby increasing the degree of carburization.
(1) The surface quality and various performances of the finished product of the iron-chromium-aluminum wire produced by the water-based wire-drawing lubricant provided by the embodiment of the application can meet the standard requirements, and the quality of the finished product is consistent with that of the product produced by wire-drawing oil.
(2) The water-based wire drawing lubricant provided by the embodiment of the application has the advantages that the pH value is stable between 8.5 and 9, and meanwhile, due to the addition of multiple chemical components, the water-based wire drawing lubricant has a strong antibacterial effect, is not easy to deteriorate, and can stably improve the product quality.
(3) The water-based wire drawing lubricant provided by the embodiment of the application can obtain solid waste in an air drying or drying mode if excessive water-based wire drawing lubricant deposits exist on a machine tool or a filament, and the solid waste can be smelted again and recycled.
(4) The water-based wire drawing lubricant provided by the embodiment of the application is used for wire drawing, the residues on the surface of a steel wire after wire drawing are less, the surface carburization amplitude is small after heat treatment, and the water-based wire drawing lubricant is more suitable for producing products with strict requirements on the carbon content of finished products.
(5) The water-based wire drawing lubricant provided by the embodiment of the application has the characteristics of safer and more convenient storage management compared with a wire drawing lubricant of organic oil with higher flammability because a large amount of nonflammable substances are added.
It is noted that, in this document, relational terms such as "first" and "second," and the like, may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising an … …" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
The foregoing are merely exemplary embodiments of the present invention, which enable those skilled in the art to understand or practice the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.
Claims (10)
1. A water-based wire drawing lubricant for drawing iron chromium aluminum filaments, characterized in that the water-based wire drawing lubricant comprises, in mass fraction: solution A: 6.5-7%, liquid B: 3 to 3.5 percent of solvent and the balance of solvent;
the solution A comprises a first surfactant, an organic solvent, a pH regulator and an auxiliary agent, and the solution B comprises an organic base and a second surfactant.
2. The water-based wire drawing lubricant as claimed in claim 1, wherein the first surfactant comprises at least one of nonylphenol polyoxyethylene ether, polyoxyethylene lauryl ether, and fatty alcohol polyoxyethylene ether carboxylic acid alcohol;
the organic solvent comprises at least one of diethylene glycol butyl ether and propylene glycol methyl ether acetate;
the pH regulator comprises at least one of sodium hydroxide, potassium hydroxide and ammonia water;
the auxiliary agent comprises at least one of water-soluble silicone oil and dimethyl silicone oil.
3. The water-based drawing lubricant according to claim 2, wherein the raw materials of the liquid A comprise, in mass fraction: polyoxyethylene nonyl phenyl ether: 16-17%, polyoxyethylene lauryl ether: 9% -10%, diethylene glycol monobutyl ether: 6.8-7.2%, fatty alcohol-polyoxyethylene ether carboxylic acid alcohol: 4.5% -5.5%, potassium hydroxide: 1.1-1.5%, water-soluble silicone oil: 2 to 2.5 percent of the total weight of the paint, and the balance of water.
4. The water-based drawing lubricant according to claim 1, wherein the organic base comprises at least one of diethanolamine, triethanolamine, and oleic acid;
the second surfactant comprises at least one of dodecyl dimethyl benzyl ammonium chloride, dodecyl trimethyl benzyl ammonium chloride and lauryl dimethyl benzyl ammonium chloride.
5. The water-based drawing lubricant according to claim 4, wherein the raw materials of the liquid B comprise, in mass fraction: diethanolamine: 7% -7.5%, triethanolamine: 14% -16%, oleic acid: 13% -14%, dodecyl dimethyl benzyl ammonium chloride: 0.3 to 0.5 percent of the total weight of the paint, and the balance of water.
6. The water-based wire drawing lubricant according to claim 5, wherein the mass concentration of the dodecyl dimethyl benzyl ammonium chloride is 45-50%.
7. The water-based wire drawing lubricant according to claim 1, wherein the solvent comprises a microelectric water having a pH of 13 to 14.
8. The method of claim 1, wherein the water-based drawing lubricant has a pH of 8.5 to 9.
9. A method of preparing the water-based drawing lubricant of any one of claims 1-8, comprising:
respectively obtaining a solution A and a solution B containing the raw materials;
and mixing the solution A and the solution B with micro-electro-water to obtain the water-based wire drawing lubricant.
10. Use of a water-based wire drawing lubricant for drawing iron chromium aluminum filaments, characterized in that the water-based wire drawing lubricant according to any one of claims 1 to 8 is used in the drawing process for the preparation of iron chromium aluminum filaments.
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