CN109609250A - A kind of water-soluble metal contour machining procedure lubricant and preparation method thereof - Google Patents
A kind of water-soluble metal contour machining procedure lubricant and preparation method thereof Download PDFInfo
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- CN109609250A CN109609250A CN201910005301.6A CN201910005301A CN109609250A CN 109609250 A CN109609250 A CN 109609250A CN 201910005301 A CN201910005301 A CN 201910005301A CN 109609250 A CN109609250 A CN 109609250A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of water-soluble metal contour machining procedure lubricants, including following component: basal liquid, lubricant, Water-soluble extreme pressure anti-wear agent, fatty acid ester antirust agent, PH regulator, water soluble polymer thickener, nonionic emulsifier, solid lubricant, the basal liquid is deionized water, glycerine, ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol 200, polyethylene glycol 400, polypropylene glycol 200, polypropylene glycol 400, one or more of polypropylene glycol 600 mixture, the lubricant is lauric acid sorbierite monoesters, oleic acid sorbierite monoesters, high molecular polyether, one or more of ten polyglycerol monoester of lauric acid mixture, the Water-soluble extreme pressure anti-wear agent is high molecular polymerization phosphoric acid ester complexes.The present invention can promote in the processing and formings industries such as punching, punching press deep drawn, drawing, extruding, bend pipe, flaring, necking, pipe expanding, very environmentally friendly, can bring considerable economic benefit and social benefit, while preparation process is simple.
Description
Technical field
The present invention relates to technical field of lubricant more particularly to a kind of water-soluble metal contour machining procedure lubricant and its
Preparation method.
Background technique
Current China has entered equipment manufacture big country ranks, and wherein metal forming is also China's equipment manufacture
Key point, and punching, punching press deep drawn, drawing, extruding, bend pipe, flaring, necking, expanding etc. in metal forming technique
Technique is one of the major way of equipment manufacturing technique, is widely used in aircraft, automobile, high-speed rail, electronics, household electrical appliances, machine-building
Etc..In the metal forming process of these industries, no matter equipment, mold or technique itself are all towards intelligent, high-end
The directions such as change, precise treatment are developed.A kind of but vital for the technological development and most critical stone --- lubricant
The development of technology is but without much progress.Current existing lubrication technology is still directly used with traditional animal and plant fat, or specially
Industry lubricant company (including external lubricant company, state) adds synthetic ester or chlorinated paraffin, sulfide additive based on mineral oil
The pure oily lubricant being deployed into Deng chemical reaction additive.In the demanding client of some cleanings, lubricant company is also only
Be above conventional mineral oil type lubricant formulations by way of some emulsifier is added, the cleaning of Lai Gaishan lubricant
Energy.
One: the prior art and disadvantage:
1, some common metal contour machining procedures, client directly use animal and plant fat (such as rapeseed oil, palm oil, flower
Oil generation, castor oil etc.) processing, it can satisfy technological lubrication requirement, but the easily oxidation polymerization in use of these greases substantially, lead
Viscous board, mold and product are caused, subsequent removing is very difficult.Site work environment is filthy.
2, for the punching stretch drawing process occasion of the requirements such as some high lubrications, cannot directly be expired using animal and plant fat
Sufficient lubricating requirement；Professional lubricant company is needed to prepare the oily lubricant of the EP agents such as chlorination-containing olefin, sulfide additive,
Some particularly harsh techniques, such as the drawing process of stainless steel tube, stick need to also add on the basis of oily lubricant
Solid powder lubricant is made into a kind of product paste and is just able to satisfy technique requirement.
Two: professional lubricant, which still has, to be had disadvantages that:
1, in processing technology, since formula chemically reacts additive containing chlorine, sulphur etc., corresponding chemical is generated under the high temperature that rubs
Solid film plays lubricating action, but these films are all that will lead to corrosive wear, shadow in lubrication using sacrificial metal basis material as cost
It rings die life and precision, influence workpiece roughness, dimensional accuracy and surface mechanical properties, especially chlorination-containing olefin addition
Agent, under hot day wet weather environment, occur quickly workpiece and mold all corrosion the case where, and active sulfide additive is then
Cause nickel in high nickel steel to generate intercrystalline corrosion and workpiece surface dimensional accuracy and roughness occur etc. to have an impact.
2, in terms of post-processing: since punching press deep drawn, drawing compound viscosity are all very high, some is directly semisolid cream
Shape is very difficult to removal completely with aqueous cleaning agent, and with various leaning solvents, there are fire safety evaluating, environmental protection, worker's occupations
Healthy hidden danger, it is at high cost the disadvantages of.Rise vacuum based solvent cleaning way again both at home and abroad now, solvent in vacuo is distilled to recover circulation benefit
With, but this technique is also not perfect in every way, due to generally containing the chemical extreme pressure agent such as chlorine, sulphur in present a lot of lubricants, in vacuum
While solvent distillation, some to be also cracked to form hydrogen chloride containing chlorine additive and evaporate with solvent, this is resulted in practice
Corrosion is generated to distillation equipment, damage equipment leaves security risk simultaneously, moreover generates chlorination containing chlorine additive and workpiece surface
Iron lubricating film, still not can be removed in a solvent, and return in air to workpiece is influenced to also result in by air moisture at leisure
Workpiece gets rusty.
3, clean waste liquid processing in terms of: no matter aqueous-base cleaning or solvent cleaning after liquid waste processing it is also very difficult,
Due to present most punching presses, lubricant all sulfur-bearing, chlorine additive are stretched, the mix lubricant waste liquid biological degradability is very
Difference, so cannot be handled by burial mode, and by burning disposal, sulfur-containing additive can generate hypertoxic sulfur dioxide, vulcanization
The gases such as hydrogen.And chlorinated paraffin can generate strong carcinogen dioxin, Given this EU countries limits chlorinated paraffin use
System, China in " limitation requirement and measuring method of metal working fluid harmful substance " newly put into effect also by short chain (carbon number 13 with
Under) chlorinated paraffin is classified as banned substance, middle long-chain (14 or more carbon number) is classified as regulated substance.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of water-soluble metal molding proposed
Processing technology lubricant.
A kind of water-soluble metal contour machining procedure lubricant, including following component: basal liquid, lubricant, water-soluble pole
Press antiwear additive, fatty acid ester antirust agent, PH regulator, nonionic emulsifier, water soluble polymer thickener, solid lubrication
Agent, the basal liquid are deionized water, glycerine, ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol 200, polyethylene glycol
400, one or more of polypropylene glycol 200, polypropylene glycol 400, polypropylene glycol 600 mixture, the lubricant are laurel
The mixing of one or more of sour sorbierite monoesters, oleic acid sorbierite monoesters, high molecular polyether, ten polyglycerol monoester of lauric acid
Object, the Water-soluble extreme pressure anti-wear agent are high molecular polymerization phosphoric acid ester complexes, and the nonionic emulsifier is lauryl amine polyoxy
One or both of vinethene, octadecylamine polyoxyethylene ether mixture；The PH regulator be monoethanolamine, diethanol amine,
One or more of the hydramine such as triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA), triisopropanolamine mixture, it is described water-soluble
Property macromolecule thickener be Sodium Polyacrylate, it is polyacrylamide, carboxymethyl cellulose, hydroxyethyl cellulose, polyethylene glycol oxide, poly-
One or more of mixtures in vinyl alcohol, the solid lubricant are molybdenum disulphide powder, boron nitride powder, talcum powder, mica powder, rouge
One or more of fat acid calcium soap powder, sodium soap soap powder mixture.
Preferably, a kind of water-soluble metal contour machining procedure lubricant, including following component: glycerine, two
Ethylene glycol, lauric acid sorbierite monoesters, high molecular polymerization phosphoric acid ester complexes, triethanolamine.
Preferably, a kind of water-soluble metal contour machining procedure lubricant, including following component: glycerine, three
Ethylene glycol, polyethylene glycol 200, oleic acid sorbierite monoesters, high molecular polymerization phosphoric acid ester complexes, triethanolamine.
Preferably, a kind of water-soluble metal contour machining procedure lubricant, including following component: glycerine gathers
Propylene glycol 200, high molecular polyether, high molecular polymerization phosphoric acid ester complexes, triethanolamine, talcum powder.
Preferably, a kind of water-soluble metal contour machining procedure lubricant, including following component: diethylene glycol,
Polypropylene glycol 600, ten polyglycerol monoester of lauric acid, high molecular polymerization phosphoric acid ester complexes, triethanolamine, triisopropanolamine, nitrogen
Change boron powder.
Preferably, a kind of water-soluble metal contour machining procedure lubricant, including following component: ethylene glycol, two
Ethylene glycol, phosphate, triethanolamine, triisopropanolamine.
Preferably, a kind of water-soluble metal contour machining procedure lubricant, including following component: deionized water,
Ethylene glycol, diethylene glycol, phosphate, triethanolamine.
Preferably, a kind of water-soluble metal contour machining procedure lubricant, including following component: deionized water,
Water-soluble polymeric phosphate, triethanolamine, water soluble polymer Sodium Polyacrylate.
Preferably, a kind of water-soluble metal contour machining procedure lubricant, including following component: deionized water,
Water-soluble polymeric phosphate, triethanolamine, water soluble polymer Sodium Polyacrylate, lauryl amine polyoxyethylene ether.
Preferably, a kind of water-soluble metal contour machining procedure lubricant, including following component: deionized water,
Water-soluble polymeric phosphate, triethanolamine, water soluble polymer Sodium Polyacrylate, sodium soap soap powder, talcum powder.
The invention also provides a kind of preparation methods of water-soluble metal contour machining procedure lubricant, including following step
It is rapid:
S1: basal liquid stirring is warming up to 40~50 DEG C, lubricant, Water-soluble extreme pressure anti-wear agent, fatty acid is then added
Esters antirust agent, PH regulator, nonionic emulsifier simultaneously stir evenly, and can add solid lubricant and stir evenly.
A kind of water-soluble metal contour machining procedure lubricant proposed by the present invention, has the following advantages that,
1, subsequent cleaning agent expense is saved, uses cleaning agent less, waste liquid amount is also synchronous to be reduced, and environmental protection treatment expense is also a little
More, it is corrosion-free to be mainly reflected in equipment, mold, reduces equipment, the mold repair frequency can greatly prolong service life, and there are also products
Finished product qualification rate is greatly improved due to reduction because corroding, while improving the precision of product, increases added value of product.
2, for society, sulfur-bearing chlorine etc. will not then not generate great to environmental disruption environmentally hazardous substance to product
Extremely toxic substance dioxin, hydrogen sulfide etc., without heavy metal, nontoxic after biochemical method is handled.
3, in the processing and formings industries such as punching, punching press deep drawn, drawing, extruding, bend pipe, flaring, necking, pipe expanding
It can be promoted, considerable economic benefit and social benefit can be brought, while preparation process is simple.
Specific embodiment
Combined with specific embodiments below the present invention is made further to explain.
Embodiment one
A kind of water-soluble metal contour machining procedure lubricant proposed by the present invention, including following component: deionized water, third
Triol, diethylene glycol, lauric acid sorbierite monoesters, high molecular polymerization phosphoric acid ester complexes, triethanolamine.
Preparation method, comprising the following steps:
S1: glycerine 40~80%, the stirring of diethylene glycol 10~20% are warming up to 40~50 DEG C, then sequentially add the moon
Cinnamic acid sorbierite monoesters 10~15%, high molecular polymerization phosphoric acid ester complexes 10~50%, triethanolamine 5~10%, stirring are equal
It is even.
Embodiment two
A kind of water-soluble metal contour machining procedure lubricant proposed by the present invention, including following component: glycerine, three second
Glycol, polyethylene glycol 200, oleic acid sorbierite monoesters, high molecular polymerization phosphoric acid ester complexes, triethanolamine.
Preparation method, comprising the following steps:
S1: glycerine 20~30%, triethylene glycol 5~10%, the stirring of polyethylene glycol 200 10~15% are warming up to 40
~50 DEG C, sequentially add oleic acid sorbierite monoesters 10~20%, high molecular polymerization phosphoric acid ester complexes 10~30%, triethanolamine
5~10%, it stirs evenly.
Embodiment three
A kind of water-soluble metal contour machining procedure lubricant proposed by the present invention, including following component: glycerine, poly- third
Glycol 200, high molecular polyether, high molecular polymerization phosphoric acid ester complexes, triethanolamine, talcum powder.
Preparation method, comprising the following steps:
S1: glycerine 20~30%, the stirring of polypropylene glycol 200 10~15% are warming up to 40~50 DEG C and then successively added
Enter high molecular polyether 10~15%, high molecular polymerization phosphoric acid ester complexes 10~40%, triethanolamine 10~15% to stir evenly
Afterwards, talcum powder 10~25% is slowly added to continue to be stirred until homogeneous fluid.
Example IV
A kind of water-soluble metal contour machining procedure lubricant proposed by the present invention, including following component: diethylene glycol gathers
Propylene glycol 600, ten polyglycerol monoester of lauric acid, high molecular polymerization phosphoric acid ester complexes, triethanolamine, triisopropanolamine, nitridation
Boron powder.
Preparation method, comprising the following steps:
S1: diethylene glycol 20~50%, 600 10-20% of polypropylene glycol stirring are warming up to 40~50 DEG C, primary that the moon is added
Ten polyglycerol monoester 5~10% of cinnamic acid, high molecular polymerization phosphoric acid ester complexes 10~30%, triethanolamine 1~5%, three isopropyls
Hydramine 5~8%, stirs evenly, and is finally slowly added to boron nitride solids powder 10~30% and stirs evenly.
Embodiment five
A kind of water-soluble metal contour machining procedure lubricant proposed by the present invention, including following component: ethylene glycol, diethyl
Glycol, phosphate, triethanolamine, triisopropanolamine.
Preparation method, comprising the following steps:
S1: ethylene glycol 20~35%, diethylene glycol 60~70% are mixed evenly, and then sequentially add phosphoesterase 30 .5
~2%, triethanolamine 1~4%, triisopropanolamine 1~2% stir evenly.
Embodiment six
A kind of water-soluble metal contour machining procedure lubricant proposed by the present invention, including following component: deionized water, second
Glycol, diethylene glycol, phosphate, triethanolamine.
Preparation method, comprising the following steps:
S1: deionized water 5~35%, 15~30% diethylene glycol 40~60% of ethylene glycol are mixed evenly, then according to
Secondary addition phosphoesterase 30 .5~2%, triethanolamine 2~5% stir evenly.
Embodiment seven
A kind of water-soluble metal contour machining procedure lubricant proposed by the present invention, including following component: deionized water, water
Soluble polymeric phosphate, triethanolamine, water soluble polymer Sodium Polyacrylate.
Preparation method, comprising the following steps:
S1: successively water-soluble polymeric phosphate 10~30%, triethanolamine 2~6% stir in deionized water 60~85%
It mixes uniformly, is eventually adding water soluble polymer Sodium Polyacrylate 0.1~0.5% and is uniformly dissolved.
Embodiment eight
A kind of water-soluble metal contour machining procedure lubricant proposed by the present invention, including following component: deionized water, water
Soluble polymeric phosphate, triethanolamine, water soluble polymer Sodium Polyacrylate, lauryl amine polyoxyethylene ether
Preparation method, comprising the following steps:
S1: sequentially added in deionized water 50~75% water-soluble polymeric phosphate 10~30%, triethanolamine 2~
6%, lauryl amine polyoxyethylene ether 5~10% stirs evenly, and is eventually adding water soluble polymer Sodium Polyacrylate 0.1~0.5%
It is uniformly dissolved.
Embodiment nine
A kind of water-soluble metal contour machining procedure lubricant proposed by the present invention, including following component: deionized water, water
Soluble polymeric phosphate, triethanolamine, water soluble polymer Sodium Polyacrylate, sodium soap soap powder, talcum powder.
Preparation method, comprising the following steps:
S1: in deionized water 50~70%, sequentially add water-soluble polymeric phosphate 10~30%, triethanolamine 2~
6% after mixing evenly, then water soluble polymer Sodium Polyacrylate 0.1~0.5% is uniformly dissolved, and is eventually adding sodium soap soap powder
5~15%, talcum powder 10~20% stirs evenly.
A kind of water-soluble metal contour machining procedure lubricant proposed by the present invention,
1, basal liquid deionized water, glycerine, ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, polypropylene glycol
Equal polyalcohols replace conventional mineral oil type basal liquid, and it is subsequent to realize that environment-friendly biodegradable and the purpose that can directly wash save
Cleaning agent expense uses cleaning agent less, and waste liquid amount is also synchronous to be reduced, and environmental protection treatment expense also reduces a lot, and is mainly reflected in equipment, mould
Have corrosion-free, service life can be greatly prolonged by reducing equipment, the mold repair frequency, and there are also greatly improves due to product is reduced because corroding
Finished product qualification rate, while the precision of product is improved, increase added value of product；
2, extreme-pressure anti-friction additive uses high molecular phosphoric acid ester compound, instead of tradition containing oiliness such as chlorine, sulphur and synthetic esters
Additive, product not sulfur-bearing chlorine etc. to environmentally hazardous substance, then will not generate to the great extremely toxic substance dioxin of environmental disruption,
Hydrogen sulfide etc., without heavy metal, nontoxic after biochemical method is handled；
3, for harsh processing technology, molybdenum disulfide, boron nitride, talcum powder, cloud are added on the basis of water base lubricant
The solid lubricants such as female powder, fatty acid calcium soap powder, sodium soap soap powder；
It 4, can be in the processing and formings industry such as punching, punching press deep drawn, drawing, extruding, bend pipe, flaring, necking, expanding
It is promoted, considerable economic benefit and social benefit can be brought, while preparation process is simple.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (10)
1. a kind of water-soluble metal contour machining procedure lubricant, which is characterized in that including following component: basal liquid, lubricant,
Water-soluble extreme pressure anti-wear agent, PH regulator, water soluble polymer thickener, nonionic emulsifier, is consolidated fatty acid ester antirust agent
Body lubricant, the basal liquid are deionized water, glycerine, ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol 200, gather
One or more of ethylene glycol 400, polypropylene glycol 200, polypropylene glycol 400, polypropylene glycol 600 mixture, the lubricant
For one or more of lauric acid sorbierite monoesters, oleic acid sorbierite monoesters, high molecular polyether, ten polyglycerol monoester of lauric acid
Mixture, the Water-soluble extreme pressure anti-wear agent are high molecular polymerization phosphoric acid ester complexes, and the water soluble polymer thickener is
It is Sodium Polyacrylate, polyacrylamide, carboxymethyl cellulose, hydroxyethyl cellulose, polyethylene glycol oxide, a kind of or several in polyvinyl alcohol
Kind of mixture, the PH regulator is monoethanolamine, diethanol amine, triethanolamine, monoisopropanolamine, diisopropanolamine (DIPA), three different
One or more of the hydramine such as Propanolamine mixture, the solid lubricant be molybdenum disulphide powder, boron nitride powder, talcum powder,
Mica powder, fatty acid calcium soap powder, sodium soap soap powder one or more of mixtures.
2. a kind of water-soluble metal contour machining procedure lubricant according to claim 1, which is characterized in that including following
Ingredient: glycerine, ethylene glycol, diethylene glycol, lauric acid sorbierite monoesters, high molecular polymerization phosphoric acid ester complexes, triethanolamine.
3. a kind of water-soluble metal contour machining procedure lubricant according to claim 1, which is characterized in that including following
Ingredient: glycerine, triethylene glycol, polyethylene glycol 200, oleic acid sorbierite monoesters, high molecular polymerization phosphoric acid ester complexes, three ethyl alcohol
Amine.
4. a kind of water-soluble metal contour machining procedure lubricant according to claim 1, which is characterized in that including following
Ingredient: glycerine, polypropylene glycol 200, high molecular polyether, high molecular polymerization phosphoric acid ester complexes, triethanolamine, talcum powder.
5. a kind of water-soluble metal contour machining procedure lubricant according to claim 1, which is characterized in that including following
Ingredient: ethylene glycol, diethylene glycol, phosphate, triethanolamine, triisopropanolamine.
6. a kind of water-soluble metal contour machining procedure lubricant according to claim 1, which is characterized in that including following
Ingredient: deionized water, ethylene glycol, diethylene glycol, phosphate, triethanolamine.
7. a kind of water-soluble metal contour machining procedure lubricant according to claim 1, which is characterized in that including following
Ingredient: deionized water, water-soluble polymeric phosphate, triethanolamine, water soluble polymer Sodium Polyacrylate.
8. a kind of water-soluble metal contour machining procedure lubricant according to claim 1, which is characterized in that including following
Ingredient: deionized water, water-soluble polymeric phosphate, triethanolamine, water soluble polymer Sodium Polyacrylate, lauryl amine polyoxyethylene
Ether.
9. a kind of water-soluble metal contour machining procedure lubricant according to claim 1, which is characterized in that including following
Ingredient: deionized water, water-soluble polymeric phosphate, triethanolamine, water soluble polymer Sodium Polyacrylate, sodium soap soap powder,
Talcum powder.
10. a kind of preparation method of water-soluble metal contour machining procedure lubricant, which comprises the following steps:
S1: basal liquid stirring is warming up to 40~50 DEG C, lubricant, Water-soluble extreme pressure anti-wear agent, fatty acid ester is then added
Antirust agent, PH regulator, nonionic emulsifier, water soluble polymer thickener simultaneously stir evenly, and can add solid as needed
Lubricant simultaneously stirs evenly.
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Cited By (3)
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| CN113980729A (en) * | 2021-11-15 | 2022-01-28 | 北京首钢吉泰安新材料有限公司 | Water-based wire drawing lubricant for drawing iron-chromium-aluminum filaments, and preparation method and application thereof |
| CN114425685A (en) * | 2022-01-20 | 2022-05-03 | 陕西工业职业技术学院 | Processing method of large-single-weight titanium and titanium alloy wire |
| CN116239941A (en) * | 2022-12-06 | 2023-06-09 | 蚌埠学院 | Environment-friendly self-lubricating liquid for automobile steel plate, preparation method thereof and process for forming self-lubricating coating |
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| CN113980729A (en) * | 2021-11-15 | 2022-01-28 | 北京首钢吉泰安新材料有限公司 | Water-based wire drawing lubricant for drawing iron-chromium-aluminum filaments, and preparation method and application thereof |
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| CN116239941A (en) * | 2022-12-06 | 2023-06-09 | 蚌埠学院 | Environment-friendly self-lubricating liquid for automobile steel plate, preparation method thereof and process for forming self-lubricating coating |
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Application publication date: 20190412 |