CN113967405A - 一种固体酸活化的二氧化氯缓释凝胶装置 - Google Patents
一种固体酸活化的二氧化氯缓释凝胶装置 Download PDFInfo
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Abstract
本发明公开了一种固体酸活化的二氧化氯缓释凝胶装置。该装置由容器A、容器B和外盖组成，容器A封装活性粉末，容器B封装亚氯酸钠溶液，活性粉末由凝胶干粉和固体酸活化剂组成，外盖带破膜器且盖顶有二氧化氯通气孔。向下旋转外盖，破膜器依次切割掉容器A和B的封装膜，容器A和B连通，活性粉末掉入亚氯酸钠溶液，吸水形成含固体酸活化剂的凝胶。固体酸不溶于水，亚氯酸钠只有扩散到固体酸的酸性位，才能发生反应。故本发明制备的固体酸活化的二氧化氯缓释凝胶装置，二氧化氯释放时间大幅延长。
Description
技术领域
本发明属于空气净化和消毒领域，具体为一种固体酸活化的二氧化氯缓释凝胶装置。
背景技术
二氧化氯具有氧化性和杀菌消毒作用，且低浓度的二氧化氯不影响人体健康，因此，二氧化氯可用于空气中甲醛及异味净化，还可消毒杀菌。用于空气净化和消毒的二氧化氯产品主要有固体二氧化氯缓释剂和二氧化氯缓释凝胶，如CN202010568096.7公开了一种固体二氧化氯缓释剂，CN201910781627.8公开了一种除甲醛二氧化氯缓释凝胶。目前的二氧化氯缓释凝胶装置大多数是二元结构，即亚氯酸钠溶液和含活化剂的凝胶粉末是单独分装，在使用的时候分别打开凝胶粉末和亚氯酸溶液，将粉末倒入溶液，形成凝胶再盖上释放盖，对用户来说操作麻烦。本发明公开了一种一体式的二氧化氯缓释凝胶装置，用户使用时，只需要撕掉装置的易拉胶圈，旋转释放盖即可，提升了用户体验效果。
亚氯酸钠释放二氧化氯需要酸性活化剂激活，为了延缓亚氯酸钠的分解，一般都采用弱酸作为活化剂，如专利CN201010548750.4采用醋酸作为活化剂，专利CN202110219633.1在实施例中分别以柠檬酸、草酸等作为活化剂。虽然将弱酸代替强酸作为活化剂，能在一定程度上使二氧化氯释放速率下降且延长其释放周期，但这些水溶性酸和亚氯酸钠是融为一体的，发生的是均相反应，释放速率仍然较快，导致产品的有效期短。
本发明采用固体酸作为亚氯酸钠的活化剂，固体酸不溶于水，活化亚氯酸钠的反应是液固非均相反应，亚氯酸钠只有扩散到固体酸的酸性位，才能发生反应。故本发明制备的固体酸活化的二氧化氯缓释凝胶装置，二氧化氯释放时间大幅延长。
发明内容
本发明提供了一种固体酸活化的二氧化氯缓释凝胶装置，所述装置为一体化设计，启用时只需要旋转瓶盖即可。活化剂为固体酸，大幅延长二氧化氯释放周期。
本发明所述技术方案如下：
1.一种固体酸活化的二氧化氯缓释凝胶装置由容器A、容器B、外盖组成；容器A内封装由凝胶干粉和固体酸活化剂组成的活性粉末，固体酸质量为凝胶干粉的1％-20％，凝胶干粉重量为容器B中亚氯酸溶液的2％-20％；容器B内封装浓度为1％-30％的亚氯酸钠溶液。
2.固体酸活化的二氧化氯缓释凝胶装置中，封装活性粉末的容器A通过螺纹与封装亚氯酸钠溶液的容器B连接，带破膜器的外盖套住容器A，并通过螺纹与容器B连接，外盖下部通过易拉胶圈固定住，不能自由旋动；破膜器为周边开孔的空心圆柱，末端为环形锯齿刃，装置启用前，破膜器位于容器A正上方；启用时，撕掉易拉胶圈，往下旋动外盖，破膜器依次切割掉容器A和B的封装膜，容器A和B连通，活性粉末掉入亚氯酸钠水溶液，吸水后形成二氧化氯缓释凝胶。
3.固体酸活化的二氧化氯缓释凝胶装置中，凝胶干粉为聚丙烯酰胺、聚丙烯酸钠、聚乙烯醇、壳聚糖、羧甲基纤维素钠、芦荟胶干粉、卡拉胶干粉、黄原胶干粉、海藻酸钠中的一种或多种；固体酸活化剂为氧化硅、氧化铌、氧化锰、氧化钨、氧化钼、沸石分子筛、杂多酸、高分子阳离子交换树脂、膨润土、高岭土、蒙脱土中的一种或多种。
附图说明
图1为本发明的结构示意图。
1-外盖；2-破膜器；3-外螺纹；4-内螺纹；5-易拉胶圈；6-容器B；7-通气孔；8-破膜器侧孔；9-封装膜；10-容器A；11-封装膜；12-封装膜；13-亚氯酸钠溶液；
具体实施方式
实施例1：称取2g羧甲基纤维素钠、4g聚丙烯酸钠、4g卡拉胶干粉、2g黄原胶，0.1g二氧化硅、0.1g五氧化二铌、0.1g 13X分子筛，封装于容器A内。称取10g亚氯酸钠溶于0.2L纯水中，得到亚氯酸钠溶液，将其封装于容器B内。二氧化氯缓释凝胶装置启用时(参见图1)，首先撕掉易拉胶圈5，向下旋转外盖1，破膜器2依次切割掉封装膜9、11、12，容器A 10与容器B 6连通，容器A 10中的粉末掉入容器B 6中与亚氯酸钠13混合，吸水形成凝胶，亚氯酸钠扩散到固体酸酸性位上被活化，释放二氧化氯气体，由下往上依次通过容器B 6、容器A10、外盖1、通气孔7，释放到空气中，净化和消毒空气。
实施例2：称取2g聚乙烯醇、4g聚丙烯酸钠、4g壳聚糖、2g芦荟胶干粉，0.1g膨润土、0.1gD152阳离子交换树脂、0.1g蒙脱土，封装于容器A内。称取20g亚氯酸钠溶于0.2L纯水中，得到亚氯酸钠溶液，将其封装于容器B内。本实施例中二氧化氯缓释凝胶装置启用方法参照实施例1。
实施例3：称取2g聚丙烯酸钠、2g壳聚糖、5g黄原胶干粉、5g海藻酸钠，0.2g膨润土、0.2g二氧化硅、0.1g蒙脱土，封装于容器A内。称取30g亚氯酸钠溶于0.2L纯水中，得到亚氯酸钠溶液，将其封装于容器B内。本实施例中二氧化氯缓释凝胶装置启用方法参照实施例1。
Claims (3)
1.一种固体酸活化的二氧化氯缓释凝胶装置，其特征在于，所述的固体酸活化的二氧化氯缓释凝胶装置由容器A、容器B、外盖组成；容器A内封装由凝胶干粉和固体酸活化剂组成的活性粉末，固体酸质量为凝胶干粉的1％-20％，凝胶干粉质量为容器B中亚氯酸溶液的2％-20％；容器B内封装质量浓度为1％-30％的亚氯酸钠溶液；外盖带破膜器，盖顶有二氧化氯通气孔。
2.权利要求1所述的固体酸活化的二氧化氯缓释凝胶装置，其特征在于，所述装置中封装活性粉末的容器A通过螺纹与封装亚氯酸钠溶液的容器B连接，带破膜器的外盖套住容器A，并通过螺纹与容器B连接，外盖下部通过易拉胶圈固定住，不能自由旋动；破膜器为周边开孔的空心圆柱，末端为环形锯齿刃，装置启用前，破膜器位于容器A正上方；启用时，撕掉易拉胶圈，往下旋动外盖，破膜器依次切割掉容器A和B的封装膜，容器A和B连通，活性粉末掉入亚氯酸钠水溶液，吸水后形成二氧化氯缓释凝胶。
3.权利要求1所述的固体酸活化的二氧化氯缓释凝胶装置，其特征在于，所述的凝胶干粉为聚丙烯酰胺、聚丙烯酸钠、聚乙烯醇、壳聚糖、羧甲基纤维素钠、芦荟胶干粉、卡拉胶干粉、黄原胶干粉、海藻酸钠中的一种或多种；所述的固体酸活化剂为氧化硅、氧化铌、氧化锰、氧化钨、氧化钼、沸石分子筛、杂多酸、高分子阳离子交换树脂、膨润土、高岭土、蒙脱土中的一种或多种。
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104707463A (zh) * | 2015-03-13 | 2015-06-17 | 华阳新兴科技（天津）集团有限公司 | 一种添加茶多酚的二氧化氯空气净化缓释制剂 |
| KR20190064672A (ko) * | 2017-09-29 | 2019-06-10 | 가부시키가이샤 아마테라 | 이산화염소 가스의 발생 방법, 이산화염소 가스 발생용 키트 및 겔상 조성물 |
| CN111296427A (zh) * | 2020-04-08 | 2020-06-19 | 青岛普泰克化工有限公司 | 一种固载二氧化氯缓释凝胶 |
| CN211119791U (zh) * | 2019-12-16 | 2020-07-28 | 泓毅医疗技术(东莞)有限公司 | 一种高效除甲醛、防渗漏的空气净化器 |
| CN113142239A (zh) * | 2021-03-31 | 2021-07-23 | 天津氯之家生物科技有限公司 | 一种二氧化氯反应型缓释消毒装置和消毒方法 |
-
2021
- 2021-11-12 CN CN202111341794.4A patent/CN113967405A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104707463A (zh) * | 2015-03-13 | 2015-06-17 | 华阳新兴科技（天津）集团有限公司 | 一种添加茶多酚的二氧化氯空气净化缓释制剂 |
| KR20190064672A (ko) * | 2017-09-29 | 2019-06-10 | 가부시키가이샤 아마테라 | 이산화염소 가스의 발생 방법, 이산화염소 가스 발생용 키트 및 겔상 조성물 |
| CN211119791U (zh) * | 2019-12-16 | 2020-07-28 | 泓毅医疗技术(东莞)有限公司 | 一种高效除甲醛、防渗漏的空气净化器 |
| CN111296427A (zh) * | 2020-04-08 | 2020-06-19 | 青岛普泰克化工有限公司 | 一种固载二氧化氯缓释凝胶 |
| CN113142239A (zh) * | 2021-03-31 | 2021-07-23 | 天津氯之家生物科技有限公司 | 一种二氧化氯反应型缓释消毒装置和消毒方法 |
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