CN113956523A - Release film for free radical ultraviolet curing waterproof coiled material and preparation method thereof - Google Patents
Release film for free radical ultraviolet curing waterproof coiled material and preparation method thereof Download PDFInfo
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- CN113956523A CN113956523A CN202110192821.XA CN202110192821A CN113956523A CN 113956523 A CN113956523 A CN 113956523A CN 202110192821 A CN202110192821 A CN 202110192821A CN 113956523 A CN113956523 A CN 113956523A
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- 239000000463 material Substances 0.000 title claims abstract description 50
- 150000003254 radicals Chemical class 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- -1 polysiloxane Polymers 0.000 claims abstract description 63
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 51
- 239000000853 adhesive Substances 0.000 claims abstract description 27
- 239000002216 antistatic agent Substances 0.000 claims abstract description 23
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 22
- 239000000654 additive Substances 0.000 claims abstract description 22
- 230000000996 additive effect Effects 0.000 claims abstract description 22
- 230000001070 adhesive effect Effects 0.000 claims abstract description 21
- 238000000576 coating method Methods 0.000 claims abstract description 21
- 239000011248 coating agent Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 4
- LUCGNDPDLOAPJB-UHFFFAOYSA-N ethyl prop-2-enoate;phosphoric acid Chemical group OP(O)(O)=O.CCOC(=O)C=C LUCGNDPDLOAPJB-UHFFFAOYSA-N 0.000 claims description 11
- 238000003851 corona treatment Methods 0.000 claims description 10
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 8
- RJKPEKIHHFNMGS-UHFFFAOYSA-N 2,4-ditert-butyl-3-methylphenol Chemical compound CC1=C(C(C)(C)C)C=CC(O)=C1C(C)(C)C RJKPEKIHHFNMGS-UHFFFAOYSA-N 0.000 claims description 5
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims description 5
- 229920006262 high density polyethylene film Polymers 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000012298 atmosphere Substances 0.000 claims description 2
- 239000011261 inert gas Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 238000010438 heat treatment Methods 0.000 abstract description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052710 silicon Inorganic materials 0.000 abstract description 4
- 239000010703 silicon Substances 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 3
- 230000036632 reaction speed Effects 0.000 abstract description 3
- 239000004698 Polyethylene Substances 0.000 description 19
- 229920000573 polyethylene Polymers 0.000 description 18
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000012299 nitrogen atmosphere Substances 0.000 description 6
- 238000005096 rolling process Methods 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 230000000149 penetrating effect Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000010426 asphalt Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 3
- 239000012634 fragment Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- FIOCEWASVZHBTK-UHFFFAOYSA-N 2-[2-(2-oxo-2-phenylacetyl)oxyethoxy]ethyl 2-oxo-2-phenylacetate Chemical compound C=1C=CC=CC=1C(=O)C(=O)OCCOCCOC(=O)C(=O)C1=CC=CC=C1 FIOCEWASVZHBTK-UHFFFAOYSA-N 0.000 description 1
- UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 description 1
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 230000000181 anti-adherent effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 210000003813 thumb Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2483/04—Polysiloxanes
- C08J2483/06—Polysiloxanes containing silicon bound to oxygen-containing groups
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesive Tapes (AREA)
- Paints Or Removers (AREA)
Abstract
The invention belongs to the technical field of release films, and discloses a release film for a free radical ultraviolet curing waterproof coiled material and a preparation method thereof. The release film comprises the following raw materials: acrylate polysiloxane, hyperbranched polysiloxane, an adhesive force additive, an antistatic agent and a photoinitiator. The invention uses the organic silicon photoinitiator, does not need heating in the reaction process, has high reaction speed, utilizes ultraviolet light for curing, has small floor area of coating equipment and saves production space. The release film for the waterproof roll prepared by the invention can be stabilized in the release force range of 5-6cN/2.5cm at room temperature of 20min and aging at 70 ℃, the residual adhesive force is more than 90%, the production efficiency is high, the extensibility is good, the release film is easy to tear, the phenomena of sticking and tearing of the back surface of the self-adhesive waterproof roll can be avoided, and the use requirement of the release film for the waterproof roll can be met.
Description
Technical Field
The invention relates to the technical field of release films, in particular to a release film for a free radical ultraviolet curing waterproof coiled material and a preparation method thereof.
Background
With the rapid development of national economy in China, not only industrial buildings and civil buildings have requirements on various high-quality waterproof materials, but also the requirements on the waterproof materials in the fields of bridges, tunnels, national defense and military industry, agricultural water conservancy, transportation and the like are further improved, and the domestic waterproof market demand is large. In recent years, although some novel waterproof materials appear, the overall waterproof pattern mainly comprising a high polymer modified asphalt waterproof coiled material, a high polymer waterproof coiled material and a waterproof coating is not changed, and the waterproof coiled material is still in a leading position in the application of the building waterproof material in China and accounts for about 60 percent of the waterproof material.
The self-adhesive waterproof coiled material is a waterproof material which is prepared by taking self-adhesive rubber asphalt prepared from synthetic rubber such as SBS and the like, a tackifier, high-quality road petroleum asphalt and the like as a base material, taking a tough high-density polyethylene film or aluminum foil as an upper surface material and taking a strippable silicon-coated isolating film as a lower surface anti-adhesive isolating material. The isolating membrane used by the self-adhesive waterproof coiled material mainly comprises two types of PE and PET, and the thickness of the isolating membrane is generally 0.025-0.05 mm.
At present, most of waterproof coiled material isolating films on the market are prepared by using traditional thermosetting organic silicon release agents, but the release agents have the following defects: in the reaction process, micromolecular substances can be released, the film forming property and the stability of a release agent product are influenced to a certain degree, the crosslinking reaction speed of the release agent is low, and meanwhile, the release agent is mainly a solvent type and is diluted by toluene, gasoline and other solvents, so that the environment is polluted and danger is easy to occur. The release film produced by the release agent has unstable release force and residual adhesive force of only 70 percent, and a large amount of micromolecule substances are transferred into asphalt to influence the construction effect and quality.
Therefore, there is a need to develop a release film with low release force and high residual adhesion to meet the use requirements of the release film for waterproof roll.
Disclosure of Invention
The invention aims to provide a release film for a free radical ultraviolet curing waterproof coiled material and a preparation method thereof, and solves the problems that the release film prepared by the prior art is high in release capacity and low in residual adhesive force.
In order to achieve the above object, the present invention provides the following technical solutions:
the invention provides a release film for a free radical ultraviolet curing waterproof coiled material, which comprises the following raw materials in parts by weight:
60-160 parts of acrylate-based polysiloxane, 45-160 parts of hyperbranched polysiloxane, 6-10 parts of adhesive force additive, 1-10 parts of antistatic agent and 3-15 parts of photoinitiator.
Preferably, the release film for the free radical ultraviolet curing waterproof roll comprises the following raw materials in parts by weight:
160 parts of acrylate-based polysiloxane, 120 parts of hyperbranched polysiloxane, 8 parts of adhesive force additive, 6 parts of antistatic agent and 10 parts of photoinitiator.
Preferably, in the above-mentioned release film for a radical ultraviolet light curing waterproof roll, the acrylate-based polysiloxane is selected from TEGO @ RC 902, TEGO @ RC922, Silcolase UVPoly 110, Silcolase UVPoly 112, Silcolase UV Poly 118, Coatsil 7602, Japan company of Mitsubishi, X-62-7622 or X-62-7629. Further preferably, the acrylate-based polysiloxane is TEGO RC 902.
Preferably, in the release film for the free radical ultraviolet curing waterproof roll, the hyperbranched polysiloxane is selected from TEGO @ RC 715, TEGO @ RC711, TEGO @ RC 722, TEGO @ RC 706 of Germany winning specialty chemical company, Silcolease UVAdd 152 of French Angken organosilicon company, Silcolease UVAdd 153, Silcolease UVPC 900, X-62-7661, X-62-7989 or KF2005 of Japan shinning company. Further preferably, the hyperbranched polysiloxane is X-62-7989.
Preferably, in the release film for the free radical ultraviolet curing waterproof roll, the adhesive force additive is selected from one of SR9050-SR9052 of Arkema, France (Sartomer), SR9008-SR9012 or EM213 of Changxing chemical company (Eternal). Further preferably, the adhesion additive is SR 9051.
Preferably, in the release film for the radical ultraviolet curing waterproof roll, the antistatic agent is phosphate ethyl acrylate.
Further preferably, the phosphate ethyl acrylate antistatic agent is obtained by reacting hydroxyethyl acrylate, phosphorus oxychloride and 2, 6-di-tert-butyl hydroxy toluene. The preparation method comprises the following steps: controlling the temperature to be 1-10 ℃, dropwise adding phosphorus oxychloride into the dehydrated hydroxyethyl acrylate, and absorbing the generated gas by using a 10-30% sodium hydroxide aqueous solution by mass fraction; after the dropwise addition is finished, adding 2, 6-di-tert-butyl hydroxy toluene, heating to 60-70 ℃ at a heating rate of 2 ℃/min, and preserving heat for 2-3 h; heating to 80-90 ℃ at a heating rate of 2 ℃/min, keeping for 1-2h, reducing pressure, and vacuumizing to obtain the phosphate ethyl acrylate.
Further preferably, the mass ratio of the hydroxyethyl acrylate, the phosphorus oxychloride and the 2, 6-di-tert-butylhydroxytoluene is 700-: 1000-1300: 0.7-2.
Preferably, in the release film for the free radical ultraviolet curing waterproof roll, the photoinitiator is selected from one of Photonickator A18, IHT-PI185, IHT-PI907, Irgacure651, Irgacure184, Irgacure369, Irgacure754, Irgacure2022, Darocur1173 or Darocur MBF of the Germany winning specialty chemical company. Further preferably, the photoinitiator is Photonickatora 18.
The invention also provides a preparation method of the release film for the free radical ultraviolet curing waterproof roll, which comprises the following steps:
(1) uniformly mixing acrylate-based polysiloxane, hyperbranched polysiloxane, an adhesive force additive, an antistatic agent and a photoinitiator to obtain a mixed material for later use;
(2) and (3) after corona treatment of the base film, coating the mixed material in the step (1) in an inert gas atmosphere, and then carrying out ultraviolet curing to obtain the release film for the free radical ultraviolet curing waterproof roll.
Preferably, in the above method for preparing a release film for a radical ultraviolet light curing waterproof roll, the base film in step (2) is a polyolefin film, and the corona value of corona treatment is 38 to 60 dynes. More preferably, the polyolefin film is a high density polyethylene film.
Through the technical scheme, compared with the prior art, the invention has the following beneficial effects:
(1) the novel organic silicon photoinitiator is used, heating is not needed in the reaction process, the reaction speed is high, the organic solvent is not contained, the environment is friendly, potential safety hazards such as fire and explosion do not exist in the processes of storage, transportation, production and processing, and the production efficiency is greatly improved.
(2) The ultraviolet curing coating equipment has the advantages of small occupied area, production space saving, low energy consumption and low production cost.
(3) The release film for the waterproof roll produced by the invention can be stabilized in the release force range of 5-6cN/2.5cm at room temperature of 20min and at 70 ℃, the residual adhesive force is more than 90%, the production speed can reach 200 plus one year of 300m/min, the production efficiency is high, the extensibility is good, the release film is easy to tear, the phenomenon that the back of the self-adhesive waterproof roll is stuck and torn cannot occur, and the use requirement of the release film for the waterproof roll is met.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The polyethylene release film for the free radical ultraviolet curing waterproof coiled material comprises the following raw materials in parts by weight: 160 parts of TEGO RC 902 acrylate polysiloxane, 120 parts of X-62-7989 hyperbranched polysiloxane, 8 parts of SR9051 adhesion additive, 6 parts of phosphate ethyl acrylate antistatic agent and 10 parts of PhotonickelotorA 18 photoinitiator.
The preparation method of the polyethylene release film for the free radical ultraviolet curing waterproof coiled material comprises the following steps:
(1) uniformly mixing acrylate-based polysiloxane, hyperbranched polysiloxane, an adhesive force additive, an antistatic agent and a photoinitiator to obtain a mixed material for later use;
(2) and (3) penetrating a polyethylene film on a coating machine, coating the mixed material in the step (1) in a nitrogen atmosphere after corona treatment with a corona value of 60 dyne, then carrying out ultraviolet curing, and rolling to obtain a product 1.
Example 2
The polyethylene release film for the free radical ultraviolet curing waterproof coiled material comprises the following raw materials in parts by weight: 140 parts of TEGO RC 902 acrylate polysiloxane, 150 parts of X-62-7989 hyperbranched polysiloxane, 8 parts of SR9051 adhesion additive, 6 parts of phosphate ethyl acrylate antistatic agent and 10 parts of Photonickeloya A18 photoinitiator.
The preparation method of the polyethylene release film for the free radical ultraviolet curing waterproof coiled material comprises the following steps:
(1) uniformly mixing acrylate-based polysiloxane, hyperbranched polysiloxane, an adhesive force additive, an antistatic agent and a photoinitiator to obtain a mixed material for later use;
(2) and (3) penetrating a polyethylene film on a coating machine, coating the mixed material in the step (1) in a nitrogen atmosphere after corona treatment with a corona value of 55 dyne, then carrying out ultraviolet curing, and rolling to obtain a product 2.
Example 3
The polyethylene release film for the free radical ultraviolet curing waterproof coiled material comprises the following raw materials in parts by weight: 120 parts of TEGO RC 902 acrylate polysiloxane, 130 parts of X-62-7989 hyperbranched polysiloxane, 6 parts of SR9051 adhesion additive, 5 parts of phosphate ethyl acrylate antistatic agent and 8 parts of Photonickeloya A18 photoinitiator.
The preparation method of the polyethylene release film for the free radical ultraviolet curing waterproof coiled material comprises the following steps:
(1) uniformly mixing acrylate-based polysiloxane, hyperbranched polysiloxane, an adhesive force additive, an antistatic agent and a photoinitiator to obtain a mixed material for later use;
(2) and (3) putting a polyethylene film on a coating machine, coating the mixed material obtained in the step (1) in a nitrogen atmosphere after corona treatment with a corona value of 52 dyne, then carrying out ultraviolet curing, and rolling to obtain a product 3.
Example 4
The polyethylene release film for the free radical ultraviolet curing waterproof coiled material comprises the following raw materials in parts by weight: 100 parts of TEGO RC 902 acrylate polysiloxane, 160 parts of X-62-7989 hyperbranched polysiloxane, 8 parts of SR9051 adhesion additive, 8 parts of phosphate ethyl acrylate antistatic agent and 5 parts of PhotonickelotorA 18 photoinitiator.
The preparation method of the polyethylene release film for the free radical ultraviolet curing waterproof coiled material comprises the following steps:
(1) uniformly mixing acrylate-based polysiloxane, hyperbranched polysiloxane, an adhesive force additive, an antistatic agent and a photoinitiator to obtain a mixed material for later use;
(2) and (3) penetrating a polyethylene film on a coating machine, coating the mixed material in the step (1) in a nitrogen atmosphere after corona treatment with a corona value of 45 dynes, then carrying out ultraviolet curing, and rolling to obtain a product 4.
Example 5
The polyethylene release film for the free radical ultraviolet curing waterproof coiled material comprises the following raw materials in parts by weight: 80 parts of TEGO RC 902 acrylate polysiloxane, 80 parts of X-62-7989 hyperbranched polysiloxane, 6 parts of SR9051 adhesion additive, 3 parts of phosphate ethyl acrylate antistatic agent and 3 parts of PhotonickelotorA 18 photoinitiator.
The preparation method of the polyethylene release film for the free radical ultraviolet curing waterproof coiled material comprises the following steps:
(1) uniformly mixing acrylate-based polysiloxane, hyperbranched polysiloxane, an adhesive force additive, an antistatic agent and a photoinitiator to obtain a mixed material for later use;
(2) and (3) penetrating a polyethylene film on a coating machine, coating the mixed material in the step (1) in a nitrogen atmosphere after corona treatment with a corona value of 40 dyne, then carrying out ultraviolet curing, and rolling to obtain a product 5.
Example 6
The polyethylene release film for the free radical ultraviolet curing waterproof coiled material comprises the following raw materials in parts by weight: 60 parts of TEGO RC 902 acrylate polysiloxane, 55 parts of X-62-7989 hyperbranched polysiloxane, 6 parts of SR9051 adhesion additive, 5 parts of phosphate ethyl acrylate antistatic agent and 3 parts of PhotonickelotorA 18 photoinitiator.
The preparation method of the polyethylene release film for the free radical ultraviolet curing waterproof coiled material comprises the following steps:
(1) uniformly mixing acrylate-based polysiloxane, hyperbranched polysiloxane, an adhesive force additive, an antistatic agent and a photoinitiator to obtain a mixed material for later use;
(2) and (3) penetrating a polyethylene film on a coating machine, coating the mixed material in the step (1) in a nitrogen atmosphere after corona treatment with a corona value of 38 dyne, then carrying out ultraviolet curing, and rolling to obtain a product 6.
And (3) performance testing: the peel coating was tested for adhesion, peel value and subsequent adhesion.
Adhesion force: the adhesion of the cured coating to the carrier material was tested by vigorous rubbing with a thumb on the coating. In the case of insufficient tackiness, rubber-like shoulder fragments are formed. When the adhesiveness is good, no rubber-like shoulder fragments are generated even by vigorous rubbing. The test was performed by a trained panel. The evaluations were classified into a scale of 1 to 3.
Of these, grade 1 is very good scratch resistance and anchoring to the substrate. No shoulder fragments are detected for linear motion and subsequent circular motion at the same location.
Grade 2 is sufficiently good scratch resistance and adhesion to the substrate. The linear motion does not produce a shoulder breaker, but subsequent circular motion at the same location forms a shoulder breaker.
Grade 3 is insufficient scratch and tack resistance, even if linear motion produces shoulder chipping.
Peel value: the peel values were determined according to test protocol FTM 10 in FINAT manual version 8 (The Hague/NL, 2009) except that storage was carried out under pressure at 40 ℃. The adhesive tape isAndthe peel value depends on the adhesive tape, silicone and the cure of the silicone under test. Poorly crosslinked silicone release coatings produce significantly lower release values than similarly constructed well-crosslinked silicones.
And (3) subsequent adhesion: the subsequent adhesion was determined according to test protocol FTM 11 in The FINAT manual, 8 th edition (The Hague/NL, 2009) with The difference that The storage of The test adhesive strips in silicone contact was carried out for one minute and The standard surface was an untreated BOPP surface. The adhesive tape is7475. Subsequent adhesion is a measure of silicone cross-linking. If there is a silicone component that is not polymerized and therefore migratable, the subsequent adhesion values decrease with increasing proportions of such components, values above 80% being considered acceptable.
The results of the performance tests on products 1-6 prepared in the above examples of the invention are shown in table 1.
TABLE 1 Performance test results for products 1-6
As can be seen from the above Table 1, the products 1-6 prepared by the invention all have good release force, aging release force and residual adhesive force, the product 1 of the invention has the best performance, the release force can be as low as 5.0cN/2.5cm in 20min, the aging release force is only 6.0cN/2.5cm in 24h, and the residual adhesive force is as high as 99%. The release film prepared by the invention has good extensibility, is easy to tear, does not have the phenomenon that the back of the self-adhesive waterproof roll is stuck and torn, and meets the use requirement of the isolation film for the waterproof roll.
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (10)
1. The release film for the free radical ultraviolet curing waterproof coiled material is characterized by comprising the following raw materials in parts by weight:
60-160 parts of acrylate-based polysiloxane, 45-160 parts of hyperbranched polysiloxane, 6-10 parts of adhesive force additive, 1-10 parts of antistatic agent and 3-15 parts of photoinitiator.
2. The release film for the free radical ultraviolet curing waterproof roll according to claim 1, which is characterized by comprising the following raw materials in parts by weight:
160 parts of acrylate-based polysiloxane, 120 parts of hyperbranched polysiloxane, 8 parts of adhesive force additive, 6 parts of antistatic agent and 10 parts of photoinitiator.
3. The release film for the free radical ultraviolet curing waterproof roll according to claim 1, wherein the acrylate based polysiloxane is TEGO RC 902.
4. The release film for the free radical ultraviolet curing waterproof roll according to claim 1, wherein the hyperbranched polysiloxane is X-62-7989.
5. The release film for the free radical ultraviolet curing waterproof roll according to claim 1, wherein the adhesion additive is SR 9051.
6. The release film for the free radical ultraviolet curing waterproof roll according to claim 1, wherein the antistatic agent is phosphate ethyl acrylate.
7. The release film for the free radical ultraviolet curing waterproof roll as claimed in claim 6, wherein the phosphate ethyl acrylate antistatic agent is obtained by the reaction of hydroxyethyl acrylate, phosphorus oxychloride and 2, 6-di-tert-butylhydroxytoluene, and the mass ratio of the hydroxyethyl acrylate, the phosphorus oxychloride and the 2, 6-di-tert-butylhydroxytoluene is 700-: 1000-1300: 0.7-2.
8. The release film for a free radical ultraviolet curing waterproof roll according to claim 1, wherein the photoinitiator is Photonickatora 18.
9. The preparation method of the release film for the free radical ultraviolet curing waterproof roll according to any one of claims 1 to 8, characterized by comprising the following steps:
(1) uniformly mixing acrylate-based polysiloxane, hyperbranched polysiloxane, an adhesive force additive, an antistatic agent and a photoinitiator to obtain a mixed material for later use;
(2) and (3) after corona treatment of the base film, coating the mixed material in the step (1) in an inert gas atmosphere, and then carrying out ultraviolet curing to obtain the release film for the free radical ultraviolet curing waterproof roll.
10. The method for preparing the release film for the free radical ultraviolet curing waterproof roll according to claim 9, wherein the base film in the step (2) is a high density polyethylene film, and the corona value of the corona treatment is 38 to 60 dynes.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN116515121A (en) * | 2023-04-28 | 2023-08-01 | 广州腾富新材料科技有限公司 | High-solid low-viscosity acrylic resin and application thereof in automotive interior coating |
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EP1382651A1 (en) * | 2002-07-19 | 2004-01-21 | Goldschmidt AG | Use of antioxidants in radiation-curable coating compositions for the preparation of abhesive coatings |
WO2019009536A1 (en) * | 2017-07-07 | 2019-01-10 | 주재근 | Release film using acrylic silicone and manufacturing method therefor |
CN110885633A (en) * | 2019-11-25 | 2020-03-17 | 佛山华韩卫生材料有限公司 | Free radical photocuring release film and preparation method thereof |
CN111621156A (en) * | 2020-06-05 | 2020-09-04 | 苏州鸿科新材料科技有限公司 | Ultra-light release force free radical photocuring release film and preparation method thereof |
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2021
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EP1382651A1 (en) * | 2002-07-19 | 2004-01-21 | Goldschmidt AG | Use of antioxidants in radiation-curable coating compositions for the preparation of abhesive coatings |
WO2019009536A1 (en) * | 2017-07-07 | 2019-01-10 | 주재근 | Release film using acrylic silicone and manufacturing method therefor |
CN110885633A (en) * | 2019-11-25 | 2020-03-17 | 佛山华韩卫生材料有限公司 | Free radical photocuring release film and preparation method thereof |
CN111621156A (en) * | 2020-06-05 | 2020-09-04 | 苏州鸿科新材料科技有限公司 | Ultra-light release force free radical photocuring release film and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN116515121A (en) * | 2023-04-28 | 2023-08-01 | 广州腾富新材料科技有限公司 | High-solid low-viscosity acrylic resin and application thereof in automotive interior coating |
CN116515121B (en) * | 2023-04-28 | 2023-10-31 | 广州腾富新材料科技有限公司 | High-solid low-viscosity acrylic resin and application thereof in automotive interior coating |
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