CN113944064A - Preparation method of plant fiber mulching paper - Google Patents
Preparation method of plant fiber mulching paper Download PDFInfo
- Publication number
- CN113944064A CN113944064A CN202010691518.XA CN202010691518A CN113944064A CN 113944064 A CN113944064 A CN 113944064A CN 202010691518 A CN202010691518 A CN 202010691518A CN 113944064 A CN113944064 A CN 113944064A
- Authority
- CN
- China
- Prior art keywords
- paper
- pulp
- mulching
- mulching film
- plant fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 8
- 238000002360 preparation method Methods 0.000 title claims description 5
- 241000196324 Embryophyta Species 0.000 claims abstract description 8
- 239000010902 straw Substances 0.000 claims description 11
- 239000002994 raw material Substances 0.000 claims description 8
- 229920000742 Cotton Polymers 0.000 claims description 4
- 235000014676 Phragmites communis Nutrition 0.000 claims description 4
- 241000209140 Triticum Species 0.000 claims description 4
- 235000021307 Triticum Nutrition 0.000 claims description 4
- 244000025254 Cannabis sativa Species 0.000 claims description 3
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 240000008042 Zea mays Species 0.000 claims description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 claims description 2
- 235000005822 corn Nutrition 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 239000004033 plastic Substances 0.000 abstract description 5
- 229920003023 plastic Polymers 0.000 abstract description 5
- 239000002689 soil Substances 0.000 abstract description 3
- 230000015556 catabolic process Effects 0.000 abstract description 2
- 238000006731 degradation reaction Methods 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 239000002985 plastic film Substances 0.000 abstract description 2
- 229920006255 plastic film Polymers 0.000 abstract description 2
- 230000009172 bursting Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 239000010408 film Substances 0.000 description 14
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 6
- 239000012752 auxiliary agent Substances 0.000 description 6
- -1 alkyl ketene dimer Chemical compound 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000003801 milling Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000012286 potassium permanganate Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- 238000012271 agricultural production Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 229920006238 degradable plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G13/00—Protecting plants
- A01G13/02—Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
- A01G13/0256—Ground coverings
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C3/00—Pulping cellulose-containing materials
- D21C3/04—Pulping cellulose-containing materials with acids, acid salts or acid anhydrides
- D21C3/06—Pulping cellulose-containing materials with acids, acid salts or acid anhydrides sulfur dioxide; sulfurous acid; bisulfites sulfites
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/17—Ketenes, e.g. ketene dimers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/18—Reinforcing agents
- D21H21/20—Wet strength agents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/28—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture specially adapted for farming
Abstract
The plant fiber mulching paper has excellent wet tensile strength, tearing strength, bursting strength and water resistance. The natural-color mulching paper is made of plant fibers, is degradable and does not pollute the environment. Through field tests, the paper mulching film has good effects of preserving moisture, preserving soil moisture and inhibiting weeds, and the coverage period can reach 3-4 months; the natural color mulching film paper can replace the plastic film on the current market, and can solve the problems of difficult degradation and environmental pollution of the plastic mulching film.
Description
Technical Field
The invention belongs to a crop straw utilization technology, and relates to a preparation method of plant fiber mulching film paper.
Background
With the continuous development of agricultural production, the scale of plastic mulching films used in rural areas is larger and larger, and the agricultural mulching films are generally formed by blow molding of plastics such as polyvinyl chloride and the like and are very thin films. The agricultural mulching film is difficult to recover after being used, most of the agricultural mulching film is abandoned in farmlands, and the agricultural mulching film cannot be degraded for a long time, so that the environment is polluted. In addition, when the degradable plastic mulching film produced at present is used, a large amount of plastic particles enter soil, so that the soil structure can be damaged, and the agricultural production can be influenced in the long term.
Disclosure of Invention
The invention aims to provide natural-color mulching film paper which can replace plastic films on the current market and solve the problems of difficult degradation and environmental pollution of the plastic mulching films.
The technical scheme of the invention is as follows:
a preparation method of plant fiber mulching paper comprises the following steps:
1) adding ammonium sulfite into the processed grass raw material for cooking, wherein the use amount of the ammonium sulfite is 10-25% of the absolute dry raw material, and the liquid ratio is 1: 2.5-10, introducing steam for heating, raising the temperature to 185 ℃, and preserving the heat for 220 minutes;
2) mixing the straw pulp prepared by steaming and boiling with the commodity wood pulp in proportion: 65-85% of straw pulp and 15-35% of wood pulp, feeding the mixed pulp into a disc mill for milling, and simultaneously adding 2-10% of wet strength agent auxiliary agent to enhance wet strength;
3) feeding the ground pulp into a fan pump, adding 2-10% of AKD (alkyl ketene dimer) auxiliary agent before feeding to enhance the water resistance, and obtaining papermaking pulp;
4) and (4) feeding the papermaking slurry to a paper machine for papermaking to produce the mulching paper.
Quantifying the prepared paper mulching film: 30.0-100.0 g/m2(ii) a Transverse tensile index of 10-30N.m/g, longitudinal tensile index of 20-40N.m/g, transverse wet tensile index of 4-10N.m/g, longitudinal wet tensile index of 6-15N.m/g, transverse tear index of 4-12mN.m2Per g, longitudinal tear index 4-10mN.m2(ii)/g, burst index 1.5-5kPa.m2Per g, surface absorption 10-30g/m2
The grass raw material is one or more of wheat straw, rice straw, cotton stalk, corn stalk and reed.
The digesters used in the present invention include a rotary spherical digester, a vertical digester and a continuous digester.
Detailed Description
Example 1:
feeding the prepared wheat straw into a rotary spherical digester, adding ammonium sulfite with the absolute dry raw material amount of 10%, wherein the liquid ratio is 1: and 4, idling for 20 minutes after the wheat straw is full, introducing steam to heat for the first time, raising the temperature to 100 ℃, preserving the heat for 20 minutes at the temperature, then raising the temperature for the second time, raising the temperature for 30 minutes to 165 ℃, preserving the heat for 60 minutes to obtain coarse pulp with the potassium permanganate value of 18, and extracting and washing the black liquor of the coarse pulp to obtain washed pulp with the concentration of 9%. And (3) feeding the cleaned pulp into a disc mill for milling, and adding 4% of wet strength agent to enhance the wet strength of the pulp.
And (3) feeding the ground pulp into a fan pump, adding 4% of AKD (alkyl ketene dimer) auxiliary agent before feeding to enhance the water resistance to obtain papermaking pulp, and papermaking to finish the production of the mulching film paper.
Example 2:
feeding the prepared straws into a rotary spherical digester, adding ammonium sulfite with the oven-dried raw material amount of 12%, wherein the liquid ratio is 1: and 3, idling for 20 minutes after the straws are filled, introducing steam to heat for the first time, raising the temperature to 110 ℃, preserving the heat for 20 minutes at the temperature, then raising the temperature for the second time, raising the temperature for 30 minutes to 175 ℃, preserving the heat for 60 minutes to obtain rough pulp with the potassium permanganate value of 16, and extracting and washing the black liquor of the rough pulp to obtain washed pulp with the concentration of 8 percent. And (3) feeding the cleaned pulp into a disc mill for milling, and simultaneously adding 5% of wet strength agent to enhance the wet strength of the pulp.
And (3) feeding the ground pulp into a fan pump, adding 5% of AKD (alkyl ketene dimer) auxiliary agent before feeding to enhance the water resistance to obtain papermaking pulp, and papermaking to finish the production of the mulching film paper.
Example 3:
feeding the prepared cotton stalks into a rotary spherical digester, adding ammonium sulfite with the absolute dry raw material amount of 15%, wherein the liquid ratio is 1: and 2.5, idling for 20 minutes after the cotton stalks are filled, introducing steam to heat for the first time, raising the temperature to 120 ℃, preserving the heat for 20 minutes at the temperature, then raising the temperature for the second time, raising the temperature for 30 minutes to 180 ℃, preserving the heat for 60 minutes to obtain coarse pulp with the potassium permanganate value of 16, and extracting and washing the black liquor of the coarse pulp to obtain the washed pulp with the concentration of 7%. And (3) feeding the cleaned pulp into a disc mill for milling, and adding 4% of wet strength agent to enhance the wet strength of the pulp.
And (3) feeding the ground pulp into a fan pump, adding 4% of AKD (alkyl ketene dimer) auxiliary agent before feeding to enhance the water resistance to obtain papermaking pulp, and papermaking to finish the production of the mulching film paper.
Example 4:
feeding the prepared reed into a rotary spherical digester, adding ammonium sulfite with the absolute dry raw material amount of 11%, wherein the liquid ratio is 1: and 4, idling for 20 minutes after the reed is fully filled, introducing steam to heat for the first time to 100 ℃, preserving the heat for 20 minutes at the temperature, then heating for the second time to 30-165 ℃ and preserving the heat for 60 minutes to obtain coarse pulp with the potassium permanganate value of 18, and extracting and washing the black liquor of the coarse pulp to obtain the washed pulp with the concentration of 8%. And (3) feeding the cleaned pulp into a disc mill for milling, and simultaneously adding 5% of wet strength agent to enhance the wet strength of the pulp.
And (3) feeding the ground pulp into a fan pump, adding 5% of AKD (alkyl ketene dimer) auxiliary agent before feeding to enhance the water resistance to obtain papermaking pulp, and papermaking to finish the production of the mulching film paper.
Claims (2)
1. A preparation method of plant fiber mulching film paper is characterized by comprising the following steps: and quantifying the mulching film paper: 30.0-100.0 g/m2(ii) a Transverse tensile index of 10-30N.m/g, longitudinal tensile index of 20-40N.m/g, transverse wet tensile index of 4-10N.m/g, longitudinal wet tensile index of 6-15N.m/g, transverse tear index of 4-12mN.m2Per g, longitudinal tear index 4-10mN.m2(ii)/g, burst index 1.5-5kPa.m2Per g, surface absorption 10-30g/m2。
2. The method for preparing plant fiber mulching paper according to claim 1, wherein the method comprises the following steps: the grass raw material is one or more of wheat straw, rice straw, cotton stalk, corn stalk and reed.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010691518.XA CN113944064A (en) | 2020-07-17 | 2020-07-17 | Preparation method of plant fiber mulching paper |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010691518.XA CN113944064A (en) | 2020-07-17 | 2020-07-17 | Preparation method of plant fiber mulching paper |
Publications (1)
Publication Number | Publication Date |
---|---|
CN113944064A true CN113944064A (en) | 2022-01-18 |
Family
ID=79327055
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010691518.XA Pending CN113944064A (en) | 2020-07-17 | 2020-07-17 | Preparation method of plant fiber mulching paper |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN113944064A (en) |
-
2020
- 2020-07-17 CN CN202010691518.XA patent/CN113944064A/en active Pending
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Legal Events
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PB01 | Publication | ||
PB01 | Publication | ||
WD01 | Invention patent application deemed withdrawn after publication | ||
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Application publication date: 20220118 |