CN113926305A - Fumigating method for removing peculiar smell - Google Patents

Fumigating method for removing peculiar smell Download PDF

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Publication number
CN113926305A
CN113926305A CN202111328968.3A CN202111328968A CN113926305A CN 113926305 A CN113926305 A CN 113926305A CN 202111328968 A CN202111328968 A CN 202111328968A CN 113926305 A CN113926305 A CN 113926305A
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sodium
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peculiar smell
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谭迎春
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/76Gas phase processes, e.g. by using aerosols
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/18Vapour or smoke emitting compositions with delayed or sustained release
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/20Combustible or heat-generating compositions
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/08Alkali metal chlorides; Alkaline earth metal chlorides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/015Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • A61L9/02Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air by heating or combustion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60HARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
    • B60H3/00Other air-treating devices
    • B60H3/0007Adding substances other than water to the air, e.g. perfume, oxygen
    • B60H3/0035Adding substances other than water to the air, e.g. perfume, oxygen characterised by the control methods for adding the substance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/10Single element gases other than halogens
    • B01D2257/106Ozone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/406Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/704Solvents not covered by groups B01D2257/702 - B01D2257/7027
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/91Bacteria; Microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60HARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
    • B60H3/00Other air-treating devices
    • B60H3/0007Adding substances other than water to the air, e.g. perfume, oxygen
    • B60H2003/005Adding substances other than water to the air, e.g. perfume, oxygen with heating means for adding the substances
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60HARRANGEMENTS OF HEATING, COOLING, VENTILATING OR OTHER AIR-TREATING DEVICES SPECIALLY ADAPTED FOR PASSENGER OR GOODS SPACES OF VEHICLES
    • B60H3/00Other air-treating devices
    • B60H3/0007Adding substances other than water to the air, e.g. perfume, oxygen
    • B60H2003/0064Adding substances other than water to the air, e.g. perfume, oxygen adding more than one substance

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Toxicology (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Dispersion Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

The invention discloses a fumigating method for removing peculiar smell, which comprises the following steps: putting the gasified fumigant in a sealed space needing to remove the peculiar smell, and sequentially adding a peculiar smell decomposition agent and an exciting agent into the gasified fumigant; the peculiar smell decomposing agent comprises the following components in parts by weight: 50-60 parts of sodium chlorite, 25-35 parts of sodium chlorate and 10-15 parts of sodium chloride; the exciting agent comprises the following components in parts by weight: 50-70 parts of water, 10-15 parts of sodium bisulfate, 8-12 parts of sodium citrate, 5-10 parts of aluminum chloride hexahydrate, 1-5 parts of sodium dihydrogen phosphate and 1-5 parts of phytic acid; the gasification fumigant comprises the following components in parts by weight: 50-60 parts of calcium oxide, 18-30 parts of aluminum powder and 15-28 parts of sodium carbonate; the deodorant has good effect of eliminating peculiar smell in rooms, vehicles and other closed spaces, and particularly can reach about 97 percent in the rooms.

Description

Fumigating method for removing peculiar smell
Technical Field
The invention belongs to the technical field of air purification, and particularly relates to a fumigation method for removing peculiar smell.
Background
In recent years, the problem of indoor air quality caused by decoration pollution of a living room is a main source of indoor environmental pollution at present, and residual harmful substances after house decoration seriously affect human health.
People spend more than 80% of the time indoors on average every day, and the contribution of indoor pollution sources to the total exposure of human bodies is far higher than that of outdoor industrial pollution sources.
For vehicles which are just produced, the residual harmful substances in the vehicle chamber are still more, and the health of human beings is also seriously influenced.
The residual harmful substances in the living room and the car room comprise formaldehyde and TVOC which are mainly emitted from interior or car interior decoration materials. In addition, acetaldehyde, ammonia, ozone, pet odors, bacteria, etc. are also a major source of indoor and vehicular pollution.
At present, the removing mode aiming at the residual harmful substances mainly comprises physical, chemical and biological methods, wherein the physical method mainly comprises an adsorption method, and the chemical method mainly comprises a photocatalysis method; the adsorption method has no selectivity to gas, and the capacity is small, so that desorption is easy to generate, and secondary pollution is caused; the photocatalysis method can be carried out only under the irradiation of ultraviolet light, has larger limitation, and the general structure of the photocatalyst is unstable, and the photocatalysis efficiency is generally lower
Disclosure of Invention
The invention provides a fumigating method for removing peculiar smell.
The technical scheme disclosed by the invention is as follows: a fumigating method for removing peculiar smell comprises the following steps:
putting the gasified fumigant in a sealed space needing to remove the peculiar smell, and sequentially adding a peculiar smell decomposition agent and an exciting agent into the gasified fumigant;
the peculiar smell decomposing agent comprises the following components in parts by weight: 50-60 parts of sodium chlorite, 25-35 parts of sodium chlorate and 10-15 parts of sodium chloride;
the exciting agent comprises the following components in parts by weight: 50-70 parts of water, 10-15 parts of sodium bisulfate, 8-12 parts of sodium citrate, 5-10 parts of aluminum chloride hexahydrate, 1-5 parts of sodium dihydrogen phosphate and 1-5 parts of phytic acid;
the gasification fumigant comprises the following components in parts by weight: 50-60 parts of calcium oxide, 18-30 parts of aluminum powder and 15-28 parts of sodium carbonate.
Further limited, the odor decomposer comprises the following components in parts by weight: 55-60 parts of sodium chlorite, 25-30 parts of sodium chlorate and 10-12 parts of sodium chloride; the exciting agent comprises the following components in parts by weight: 60-70 parts of water, 10-12 parts of sodium bisulfate, 8-10 parts of sodium citrate, 5-8 parts of aluminum chloride hexahydrate, 3-5 parts of sodium dihydrogen phosphate and 1-3 parts of phytic acid; the gasification fumigant comprises the following components in parts by weight: 55-60 parts of calcium oxide, 20-25 parts of aluminum powder and 20-28 parts of sodium carbonate.
Further limited, the odor decomposer comprises the following components in parts by weight: 58 parts of sodium chlorite, 30 parts of sodium chlorate and 12 parts of sodium chloride; the exciting agent comprises the following components in parts by weight: 68 parts of water, 12 parts of sodium bisulfate, 8 parts of sodium citrate, 6 parts of aluminum chloride hexahydrate, 3 parts of sodium dihydrogen phosphate and 2 parts of phytic acid; the gasification fumigant comprises the following components in parts by weight: 55 parts of calcium oxide, 23 parts of aluminum powder and 22 parts of sodium carbonate.
Further defined, the odor decomposer is prepared by the following steps: mixing sodium chlorite, sodium chlorate and sodium chloride and stirring.
Further defined, the excitant is prepared by the following steps: mixing water, sodium bisulfate, sodium citrate, aluminum chloride hexahydrate, sodium dihydrogen phosphate and phytic acid, and stirring.
Further defined, the gasified fumigant is prepared by the following steps: and mixing and stirring the calcium oxide, the aluminum powder and the sodium carbonate uniformly.
The invention has the beneficial effects that: when the gasified fumigant contacts water in the excitant, the liquid generated by the peculiar smell decomposer is quickly heated, the generated heat vaporizes into gas, the gas is quickly evaporated and diffused to a treated space, the high diffusion concentration is kept, and peculiar smell substances in the space, particularly in a room and a vehicle, are removed in a specified time; the removal rate of indoor volatile peculiar smell substances can reach 97.7%. The peculiar smell decomposer, the gasification evaporant and the excitant have scientific design, simple and convenient use and strong practicability, have high-efficiency peculiar smell removing effect, can improve the living and working environment of people and care the health of human bodies.
Detailed Description
Example 1
A fumigation method for removing peculiar smell comprises the following steps:
s1: preparation of odor decomposer
Weighing the following raw materials in parts by mass, placing the raw materials in a stirrer, and stirring the raw materials for 50 minutes at a rotating speed of 500 rpm; 50kg of sodium chlorite, 25kg of sodium chlorate and 10kg of sodium chloride.
S2: preparation of the exciting agent
Weighing the following raw materials in parts by mass, placing the raw materials in a stirrer, and stirring the raw materials for 10 minutes at a rotating speed of 500 rpm; 50kg of water, 10kg of sodium bisulfate, 8kg of sodium citrate, 5kg of aluminum chloride hexahydrate, 1kg of sodium dihydrogen phosphate and 1kg of phytic acid.
S3: preparation of gasification fumigant
Weighing the following raw materials in parts by mass, placing the raw materials in a stirrer, and stirring the raw materials for 10 minutes at a rotating speed of 500 rpm; 50kg of calcium oxide, 18kg of aluminum powder and 15kg of sodium carbonate.
S4: putting the gasified fumigant packaged by non-woven fabric into a prepared heat-resistant polypropylene plastic container, then pouring the peculiar smell decomposition agent, and finally pouring the excitant.
Example 2
A fumigation method for removing peculiar smell comprises the following steps:
s1: preparation of odor decomposer
Weighing the following raw materials in parts by mass, placing the raw materials in a stirrer, and stirring the raw materials for 5 minutes at the rotating speed of 800 rpm; 58kg of sodium chlorite, 30kg of sodium chlorate and 12kg of sodium chloride.
S2: preparation of the exciting agent
Weighing the following raw materials in parts by mass, placing the raw materials in a stirrer, and stirring the raw materials for 3 minutes at a rotating speed of 600 rpm; 68kg of water, 12kg of sodium bisulfate, 8kg of sodium citrate, 6kg of aluminum chloride hexahydrate, 3kg of sodium dihydrogen phosphate and 2kg of phytic acid.
S3: preparation of gasification fumigant
Weighing the following raw materials in parts by mass, placing the raw materials in a stirrer, and stirring the raw materials for 8 minutes at a rotating speed of 700 rpm; 55kg of calcium oxide, 23kg of aluminum powder and 22kg of sodium carbonate.
S4: putting the gasified fumigant packaged by non-woven fabric into a prepared heat-resistant polypropylene plastic container, then pouring the peculiar smell decomposition agent, and finally pouring the excitant.
Example 3
A fumigation method for removing peculiar smell comprises the following steps:
s1: preparation of odor decomposer
Weighing the following raw materials in parts by mass, placing the raw materials in a stirrer, and stirring the raw materials for 8 minutes at the rotating speed of 800 rpm; 60kg of sodium chlorite, 35kg of sodium chlorate and 15kg of sodium chloride.
S2: preparation of the exciting agent
Weighing the following raw materials in parts by mass, placing the raw materials in a stirrer, and stirring the raw materials for 5 minutes at a rotating speed of 600 rpm; 70kg of water, 15kg of sodium bisulfate, 12kg of sodium citrate, 10kg of aluminum chloride hexahydrate, 5kg of sodium dihydrogen phosphate and 5kg of phytic acid.
S3: preparation of gasification fumigant
Weighing the following raw materials in parts by mass, placing the raw materials in a stirrer, and stirring for 8 minutes at the rotating speed of 900 rpm; 60kg of calcium oxide, 30kg of aluminum powder and 28kg of sodium carbonate.
S4: putting the gasified fumigant packaged by non-woven fabric into a prepared heat-resistant polypropylene plastic container, then pouring the peculiar smell decomposition agent, and finally pouring the excitant.
Comparative example 1
The spray type odor scavenger sold in the market is adopted in the comparative example and comprises the following components in parts by mass: 4.2g of tannic acid, 2.4g of cysteine hydrochloride, 0.8g of glycerol, 1.0g of water-soluble chitosan, 0.05g of cason, 0.06g of penetrant and 91.49g of purified water.
Experimental example 1
The procedure of example 2 was used in this experimental example.
At 1.5m3The method comprises the steps of applying odor pollutants in the experimental cabin, testing the concentration of the odor pollutants, placing a 200ml heat-resistant polypropylene plastic container, placing a non-woven fabric packaged gasification fumigant, pouring 10g of odor decomposer, then pouring 100ml of excitant, and then testing according to the QBT2761-2006 standard method for measuring the indoor air purification product purification effect in the light industry. The experimental results are as follows:
TABLE 1 detection report of the center for microbiological analysis and detection in Guangdong province
(Report No. 2020FM33963R01)
Figure BDA0003348183920000051
Figure BDA0003348183920000061
Experimental example 2
In this experimental example, the method disclosed in example 1 was compared with a commercially available spray-type odor scavenger (comparative example 1) in a room odor removing application.
1 application Effect test
At one room 36m3In the living room, the concentration of the odor pollutants in the room before treatment is firstly determined according to the light industry standard 'determination method for the purification effect of indoor air purification products' (QB T2761-. Then placing a 500ml heat-resistant polypropylene plastic container in the room, firstly placing 50g non-woven fabric packaged gasified fumigant, then pouring 30g odor decomposition agent, finally pouring 150ml excitant, closing door and window, and fumigating for 24 h. After treatment, detection is carried out according to the standard of light industry for measuring the purification effect of indoor air purification products (QB T2761-2006). The test results are as follows;
TABLE 2 test results of the method disclosed in example 1
Figure BDA0003348183920000062
Figure BDA0003348183920000071
2. Comparison of application effects of commercially available spray-type odor scavenger
At one room 36m3In the room, firstly according to the light industry standard of indoor airAnd (3) measuring the concentration of the odor pollutants in the room before treatment by a purification product purification effect measuring method (QB T2761-2006). Then the room was sprayed with a commercially available spray-type odor scavenger: the spray dose is 10ml per cubic meter of space according to the use instruction. Closing the door and window after spraying, and fumigating for 24 h. After treatment, detection is carried out according to the standard of light industry for measuring the purification effect of indoor air purification products (QB T2761-2006). The test results are as follows;
TABLE 3 comparison of test results for commercially available spray-type odor scavengers
Figure BDA0003348183920000072
The average removal rate of formaldehyde, ammonia, TVOC, benzene by the method of example 1 was 97.7% higher than the average removal rate of the commercial spray-type odor scavenger by 7.7%.
Finally, it should be noted that: the above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (6)

1. A fumigation method for removing peculiar smell is characterized by comprising the following steps:
putting the gasified fumigant in a sealed space needing to remove the peculiar smell, and sequentially adding a peculiar smell decomposition agent and an exciting agent into the gasified fumigant;
the peculiar smell decomposing agent comprises the following components in parts by weight: 50-60 parts of sodium chlorite, 25-35 parts of sodium chlorate and 10-15 parts of sodium chloride;
the exciting agent comprises the following components in parts by weight: 50-70 parts of water, 10-15 parts of sodium bisulfate, 8-12 parts of sodium citrate, 5-10 parts of aluminum chloride hexahydrate, 1-5 parts of sodium dihydrogen phosphate and 1-5 parts of phytic acid;
the gasification fumigant comprises the following components in parts by weight: 50-60 parts of calcium oxide, 18-30 parts of aluminum powder and 15-28 parts of sodium carbonate.
2. The fumigation method for removing odor according to claim 1, wherein the odor decomposition agent comprises the following components in parts by weight: 55-60 parts of sodium chlorite, 25-30 parts of sodium chlorate and 10-12 parts of sodium chloride; the exciting agent comprises the following components in parts by weight: 60-70 parts of water, 10-12 parts of sodium bisulfate, 8-10 parts of sodium citrate, 5-8 parts of aluminum chloride hexahydrate, 3-5 parts of sodium dihydrogen phosphate and 1-3 parts of phytic acid; the gasification fumigant comprises the following components in parts by weight: 55-60 parts of calcium oxide, 20-25 parts of aluminum powder and 20-28 parts of sodium carbonate.
3. The fumigation method for removing odor according to claim 2, wherein the odor decomposition agent comprises the following components in parts by weight: 58 parts of sodium chlorite, 30 parts of sodium chlorate and 12 parts of sodium chloride; the exciting agent comprises the following components in parts by weight: 68 parts of water, 12 parts of sodium bisulfate, 8 parts of sodium citrate, 6 parts of aluminum chloride hexahydrate, 3 parts of sodium dihydrogen phosphate and 2 parts of phytic acid; the gasification fumigant comprises the following components in parts by weight: 55 parts of calcium oxide, 23 parts of aluminum powder and 22 parts of sodium carbonate.
4. A fumigation method for removing an offensive odor according to any one of claims 1 to 3, wherein said offensive odor-decomposing agent is prepared by the steps of: mixing sodium chlorite, sodium chlorate and sodium chloride and stirring.
5. A fumigation method for removing odours as claimed in any one of claims 1 to 3, characterised in that said elicitor is prepared by: mixing water, sodium bisulfate, sodium citrate, aluminum chloride hexahydrate, sodium dihydrogen phosphate and phytic acid, and stirring.
6. A fumigation method for removing odours as claimed in any one of claims 1 to 3, characterised in that the vaporised fumigant is prepared by: and mixing and stirring the calcium oxide, the aluminum powder and the sodium carbonate uniformly.
CN202111328968.3A 2021-11-10 2021-11-10 Fumigating method for removing peculiar smell Pending CN113926305A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1035477A (en) * 1989-01-31 1989-09-13 中国人民解放军59174部队 The method of producing chlorine dioxide by acidifying chlorous sodium
CN101437754A (en) * 2006-02-28 2009-05-20 巴斯福催化剂公司 Chlorine dioxide based cleaner/sanitizer
JP2015227320A (en) * 2014-06-03 2015-12-17 有限会社クリーンケア Fumigation agent
CN106305771A (en) * 2015-06-19 2017-01-11 山西云大中天环境科技有限公司 Soil sterilizer and preparation method thereof
CN108849973A (en) * 2018-08-06 2018-11-23 山东华实药业有限公司 A kind of stability chlorine dioxide disinfectant powder and its manufacture craft
WO2021145732A1 (en) * 2020-01-17 2021-07-22 진남섭 Kit for chlorine dioxide fumigation

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1035477A (en) * 1989-01-31 1989-09-13 中国人民解放军59174部队 The method of producing chlorine dioxide by acidifying chlorous sodium
CN101437754A (en) * 2006-02-28 2009-05-20 巴斯福催化剂公司 Chlorine dioxide based cleaner/sanitizer
JP2015227320A (en) * 2014-06-03 2015-12-17 有限会社クリーンケア Fumigation agent
CN106305771A (en) * 2015-06-19 2017-01-11 山西云大中天环境科技有限公司 Soil sterilizer and preparation method thereof
CN108849973A (en) * 2018-08-06 2018-11-23 山东华实药业有限公司 A kind of stability chlorine dioxide disinfectant powder and its manufacture craft
WO2021145732A1 (en) * 2020-01-17 2021-07-22 진남섭 Kit for chlorine dioxide fumigation

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
贺启环等: "二氧化氯固体制剂的开发研究进展", 《化工标准.计量.质量》 *

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Application publication date: 20220114