CN1139130A - Polypropylene composition and uses thereof - Google Patents

Abstract

Disclosed is a polypropylene composition comprising (A) polypropylene and (B) a specific propylene-1-butene random copolymer in a specific amount ratio. Also disclosed is a polypropylene composite film comprising (I) a crystalline polypropylene layer and (II) a layer formed from the polypropylene composition, which is laminated on at least one surface of the crystalline polypropylene layer (I). The polypropylene composition is excellent in heat resistance and low-temperature heat-sealing properties as well as in flexibility and impact resistance. The polypropylene composite film is excellent in not only heat-sealing properties, particularly low-temperature heat-sealing properties, but also transparency, scratch resistance and blocking resistance.

Description

Polypropene composition and use thereof

The present invention relates to have the excellent thermotolerance and the polypropene composition of low-temperature heat-sealing performance and snappiness and shock-resistance, also relate to the use of polypropene composition.

So far polypropylene has been widely used as and has had high rigidity, the Themoplastic molding materials of thermotolerance and transparency.Yet polypropylene is being poor aspect snappiness and the shock-resistance, therefore in order to improve these performances, the soft rubber component is added in the polypropylene usually.

Yet, in polypropylene, add the soft rubber component and make the polypropene composition of acquisition improve snappiness and shock-resistance, caused that but polyacrylic thermotolerance suffers the destructive problem.The low-temperature heat-sealing performance of this polypropene composition also haves much room for improvement.

Therefore wish to occur having the excellent thermotolerance and the polypropene composition of low-temperature heat-sealing performance and snappiness and shock-resistance.

The crystalline polypropylene film is widely used in the food product pack field especially, and this is because its excellent mechanical property tensile strength for example, rigidity, surface hardness, shock-resistance and lower temperature resistance, optical property be glossiness and transparency and for example nontoxic and tasteless performance of food sanitation performance for example.When being heated to its heat-sealing temperature, the crystalline polypropylene film shrinks, and therefore is difficult to seal the film with simple layer structure.Therefore, the crystalline polypropylene film has hot sealing layer usually, and this hot sealing layer generally is by making such as the polymkeric substance of new LDPE (film grade) or propylene-ethylene random copolymers.

Need have for the polymkeric substance that forms hot sealing layer, for example, following performance:

(1) polymkeric substance can seal being lower than under the sizable a certain temperature of base material (crystalline polypropylene film);

(2) polymkeric substance has excellent heat seal strength and heat seal strength and does not change in time;

(3) polymkeric substance has excellent and bond strength base material;

(4) polymkeric substance has the transparency that almost is equal to or is higher than base material;

(5) polymkeric substance not adhesion voluntarily when storing;

(6) polymkeric substance can not stick on bag machine or the filling-packaging machine; With

(7) polymkeric substance has high scuff resistance.

Yet conventional heat-sealable material can not satisfy all these performances.For example, although new LDPE (film grade) can seal at low temperatures, its heat seal strength and with the bond properties of base material be difference and be easy to stick on the wrapping machine.

The propylene-ethylene random copolymers satisfies above-mentioned performance (2) to (7), but does not satisfy performance (1).For example, the polypropylene composite film that contains the hot sealing layer of propylene-ethylene random copolymers has narrow heat-sealing temperature scope.Therefore, when by automatic packing machine or automatic bag making machine heat-sealing composite membrane, the essential strict control of heat-sealing temperature.Once suggestion uses the blend of propylene-ethylene random copolymers and ethene-alpha-olefin copolymer as heat-sealable material.Yet, having more improved low-temperature heat-sealing performance although compare this blend with the propylene-ethylene random copolymers, its transparency is poor.

Inventor of the present invention find propylene content be 55-85% (weight) and crystal fusion heat (measuring) by dsc for the propylene of 20-80J/g-1-butylene random copolymers has the low-temperature heat-sealing performance that high transparency is become reconciled, so can be used as heat-sealable material.Find that based on these inventor of the present invention advises using the composition that comprises propylene-1-butylene random copolymers and the isotactic polyprophlene hot sealing layer (Japanese Patent L-O-P No.114887/1979) as polypropylene screen.The hot sealing layer of being made by this composition has excellent low-temperature heat-sealing performance and block resistance, but it on block resistance and scuff resistance a shade below the hot sealing layer of making by the propylene-ethylene random copolymers.

Inventor of the present invention also advises the composite membrane that will be made up of isotactic polyprophlene film and the hot sealing layer composite membrane as high heat sealability, and above-mentioned hot sealing layer is made (the open No.42626/1986 of Japanese Patent) by the composition that comprises 10-40% (weight) propylene-butene-1 copolymer and crystalline polypropylene-alpha-olefin random copolymers.

Wish that above-mentioned polypropylene screen also has such performance, film can be carried out high-speed packaging.Like this, wish that film not only has improved low-temperature heat-sealing performance and hot sticky attached performance, and have improved slip property and block resistance.

Under above-mentioned these backgrounds, inventor of the present invention has studied the polypropene composition that contains polypropylene and rubber components, and find to use polypropylene and specific propylene-1-butylene random copolymers to prepare to have the excellent thermotolerance and the polypropene composition of low-temperature heat-sealing performance and snappiness and shock resistance.Inventor of the present invention also finds to have the desirable performance of the high-speed packaging of being applied to by the polypropylene screen that contains hot sealing layer that above-mentioned polypropene composition is made, for example not only have excellent low-temperature heat-sealing performance and heat bonding performance, and have excellent slip property and block resistance.Yet inventor of the present invention finds to use specific Metallocenic compound catalyst component can prepare specific propylene-1-butylene random copolymers.Based on these discoveries, finished the present invention.

An object of the present invention is to provide and have the excellent thermotolerance and the polypropene composition of low-temperature heat-sealing performance and snappiness and shock resistance.

Another object of the present invention provides the polypropylene composite film that comprises the layer of being made by polypropene composition, and this composite membrane not only has excellent transparency, low-temperature heat-sealing performance and Thermoadhesive, and have excellent block resistance and mechanical property such as scuff resistance.

Comprise by polypropene composition provided by the present invention:

(A) polypropylene of 5-95 weight % and

(B) propylene of 95-5 weight %-1-butylene random copolymers;

Described propylene-1-butylene random copolymers (B) has following performance:

(1) multipolymer contains 50-95mol% from the formation unit of propylene and the 50-5mol% formation unit from 1-butylene;

(2) limiting viscosity that records in 135 ℃ naphthalane is 0.1-12dl/g;

(3) molecular weight distribution of being measured by gel permeation chromatography (GPC) (Mw/Mn) is not more than 3; With

(4) the B parameter value of the degree of randomness of demonstration comonomer sequence distribution is 1.0-1.5, is 1.0-1.3 preferably.

As polypropylene (A), be to use the multipolymer of propylene and the alkene except propylene preferably, contain and be not more than the unit of 10mol% from alkene.

Except performance (1)-(4), propylene-1-butylene random copolymers (B) also has following performance (5)-(6) preferably:

(5) the fusing point Tm that is recorded by dsc is 60-140 ℃, and fusing point Tm and 1-butylene constitute unitary content M (mol%) and satisfy following relation:

-2.6M+130≤Tm≤-2.3M+155; With

(6) degree of crystallinity C that is recorded by the X-ray diffraction method and 1-butylene constitute unitary content M (mol%) and satisfy following relation:

C≥-1.5M＋75

Be used for propylene of the present invention-1-butylene random copolymers (B) and can use the olefin polymerization catalysis preparation that comprises following component:

(a) transistion metal compound of representing by following structural formula (1): Wherein M is periodictable IVa, Va, or the transition metal of VIa family,

R ¹And R ²Be respectively hydrogen atom, halogen atom, the alkyl of 1-20 carbon atom, the halo alkyl of 1-20 carbon atom contains silica-basedly, contains the oxygen base, contains sulfenyl, nitrogenous base or phosphorous-containigroups groups,

R ³For can or containing the alkyl of 1-20 carbon atom of silica-based replacement by halogen atom,

R ⁴Be the alkyl of hydrogen atom or 1-20 carbon atom,

X ¹And X ²Be respectively hydrogen atom, halogen atom, the alkyl of 1-20 carbon atom, the halo alkyl of 1-20 carbon atom, contain the oxygen base or contain sulfenyl and

Y is the bivalent hydrocarbon radical of 1-20 carbon atom, the divalence halo alkyl of 1-20 carbon atom, and divalence contains silica-based, the germanic base of divalence, divalence contains tinbase ,-O-,-CO-,-S-,-SO-,-SO ₂-,-NR ⁵-,-P (R ⁵)-,-P (O) (R ⁵)-,-BR ⁵-or-AlR ⁵-(R ⁵Be hydrogen atom, halogen atom, the halo alkyl of the alkyl of a 1-20 carbon atom or 1-20 carbon atom);

(b) (b-1) Organoaluminoxy compound, and/or

(b-2) can with the right compound of transistion metal compound (a) reacting forming ion;

With optional,

(c) organo-aluminium compound.

In the present invention, be to use R in the said structure formula preferably ¹Transistion metal compound (a) for the alkyl of methyl and 2-6 carbon atom.

The present invention also provides the polypropylene composite film that comprises following component:

(I) the crystalline polypropylene layer and

(II) layer of being made by polypropene composition of the present invention, this is pressed on the surface of at least one crystalline polypropylene layer (I) layer by layer.

In the present invention, polypropene composition layer (II) is made by the polypropene composition that comprises following component preferably:

The polypropylene (A) of 5-50 weight % and

The propylene of 95-50 weight %-1-butylene random copolymers (B); Or

Be not less than 50 weight % and less than the polypropylene (A) of 90 weight % and

Be not less than 10 weight % and less than propylene-1-butylene random copolymers (B) of 50 weight %.

Polypropylene (A) is preferably for containing the unitary crystalline polypropylene from propylene that is not less than 90mol%.

The limiting viscosity (2) of propylene-1-butylene random copolymers (B) is 0.1-5dl/g preferably.

Crystalline polypropylene layer (I) can be unstretched or through biaxial stretch-formed.

Polypropene composition of the present invention will elaborate below.

Polypropene composition of the present invention comprises following polypropylene and following specific propylene-1-butylene random copolymers.

(A) polypropylene

In the present invention, the known polypropylene of any routine all can be used as polypropylene (A).Polypropylene can be homo-polypropylene or contain propylene units and a spot of (for example being not more than 10mol%) preferably less than 5mol% from the unitary random copolymer of propylene of the alkene except propylene.Wherein, random copolymer of propylene is preferably.

As described below, when attempting that polypropene composition of the present invention is used for composite membrane, polypropylene (A) is not less than the unitary crystalline polypropylene of 90mol% from propylene for containing preferably.

The example that is used for other alkene of random copolymer of propylene comprises the alpha-olefin of 2-20 carbon atom except propylene, ethene for example, 1-butylene, 1-amylene, the 1-hexene, 1-heptene, 1-octene, 1-decene, 1-dodecylene, cetene and 4-methyl-1-pentene.

In the present invention, be to use preferably by with the polypropylene of the conventional process of known solid titanium catalyst component preparation as polypropylene (A).Also spendable is the polypropylene for preparing with the Metallocenic compound catalyst component.

Be used for polyacrylic fusing point of the present invention (Tm) and be 100-165 ℃, be 120-165 ℃ preferably.In having the polypropylene of this fusing point, what wish use is the polypropylene that fusing point is higher than the fusing point of following propylene-1-butylene random copolymers.

Polyacrylic melt flow rate (MFR) MFR (ASTMD-1238, at 230 ℃, load is 2.16kg) is generally 0.1-400g/10min, is 1-100g/10min preferably, and molecular weight distribution (Mw/Mn) is greater than 3, is 4-15 preferably.

Polypropylene (A) has more rigidity than following propylene-1-butylene random copolymers (B) usually.

(B) propylene-1-butylene random copolymers

Polypropene composition of the present invention comprises following specific propylene-1-butylene random copolymers (B).This propylene-1-butylene random copolymers is the elastomerics state preferably.

(1) being used for propylene of the present invention-1-butylene random copolymers is the random copolymers of propylene and 1-butylene, and it comprises:

50-95mol% is 60-93mol% preferably, better be 70-90mol% from the formation unit of propylene and

50-5mol% is 40-7mol% preferably, better is the formation unit from 1-butylene of 30-10mol%.

This propylene-1-butylene random copolymers also can contain the formation unit from the alkene except propylene and 1-butylene, for example a spot of (for example, being not more than 10mol%) ethene.

(2) limiting viscosity (η)

Recording the limiting viscosity (η) that is used for propylene of the present invention-1-butylene random copolymers and be 0.1-12dl/g in 135 ℃ naphthalane, is 0.5-12dl/g preferably, better is 1-12dl/g.

(3) molecular weight distribution

By gel permeation chromatography (GPC) measure be used for propylene of the present invention-1-butylene random copolymers molecular weight distribution (Mw/Mn) for being not more than 3, be 1.8-3.0 preferably, better be 1.9-2.5.

(4) degree of randomness

The B parameter value that is used for propylene of the present invention-1-butylene random copolymers that indication comonomer sequence distributes is 1.0-1.5, is 1.0-1.3 preferably, better is 1.0-1.2.

At J.Polym.Sci., Al proposed in 3188 (1963) the B parameter value by B.D.Cole-man and T.G.Fox, and this parameter can be obtained by following formula:

B=P ₁₂/ (2P ₁P ₂) P wherein ₁Be the first monomer content component, P ₂Be the second monomer content component, P ₁₂It is the ratio of first monomer-second sequence monomer and total binary sequence.

When B=1, Bernoulli Jacob's statistics is used for multipolymer; In B＜1 o'clock, multipolymer is tending towards block; In B＞1 o'clock, multipolymer is tending towards alternately; During with B=2, multipolymer is an alternating copolymer.

Above-mentioned performance (1) also has following performance (5) to (4) and (6) are preferably except having to be used for propylene of the present invention-1-butylene random copolymers (B).

(5) fusing point Tm

The fusing point Tm that is used for propylene of the present invention-1-butylene random copolymers (B) that is measured by dsc is 60-140 ℃, is 80-130 ℃ preferably.

Desirable is in propylene-1-butylene random copolymers (B), and fusing point Tm and 1-butylene constitute unit content M (mol%) and satisfy following relation:

-2.6M＋130≤Tm≤-2.3M＋155

Wish also in propylene-1-butylene random copolymers (B) that (6) degree of crystallinity C that is measured by the X-ray diffraction method and 1-butylene constitute unit content M (mol%) and satisfy following relation:

C 〉=-1.5M+75 is used for propylene of the present invention-1-butylene random copolymers (B) and also has following performance (7).

(7) the stereospecific degree of propylene-1-butylene random copolymers (ternary tacticity, mm component)

The stereospecific degree that is used for propylene of the present invention-1-butylene random copolymers can be estimated by ternary tacticity (mm mark).

When connecting end to end, three propylene units sequences on polymer chain are represented with surperficial curved structure, and the mm mark is defined as the ratio of the propylene units sequence with identical methyl branch direction, and can be by following use ¹³C-NMR spectrographic method is measured.

For by ¹³The mm mark of C-NMR spectrometry propylene-1-butylene random copolymers is measured the mm mark of following mm mark as the propylene units that contains ternary sequence on the polymer chain: the propylene units ternary sequence that (i) is end-to-end and (ii) form propylene units and the butylene unit be end-to-end and contain propylene units as the second unitary propylene units-butylene unit ternary sequence.

The mm mark can be by ternary sequence (i) and (ii) the peak intensity of the pendant methyl of Unit second (propylene units) determine that details are as follows.

At flip angle (flip angle) is 45 ° and recurrent interval not to be shorter than 3.4T ₁(T ₁: under the measuring condition maximum duration in the methyl longitudinal relaxation time), be used in propylene-1-butylene random copolymers that 120 ℃ the proton method of uncoupling is fully measured the random copolymerization matter sample ¹³C-NMR spectrum, described sample fully are dissolved in and contain in the hexachlorobutadiene of a small amount of deuterate benzene as locking solvent (lock solvent).Because the T of methylene radical ₁T with methyne ₁Be shorter than the T of methyl ₁, the magnetization of all carbon atoms is replied and is not less than 99% in the sample under these conditions.As for chemical shift, the 3rd unitary methyl carbon peak is decided to be 21.593ppm (is benchmark with the tetramethylsilane) in the propylene units of will being end-to-end five metasequences (mmmm), and other carbon peak is that benchmark is determined with this peak then.

At propylene-1-butylene random copolymers of measuring like this ¹³In the C-NMR spectrum, the methyl carbon zone that will can be observed propylene units pendant methyl (about 19.5-21.9ppm) is divided into:

First peak zone (about 21.0-21.9ppm),

Zone, second peak (about 20.2-21.0ppm) and

Zone, the 3rd peak (about 19.5-20.2ppm).

In above-mentioned each zone, the observable ternary sequence that is end-to-end (i) and (ii) in the pendant methyl peak of Unit second (propylene units) as shown in following table 1.

Table 1

Shift value	Methyl carbon zone (19.5～21.9ppm)
				First area 21.0-21.9ppm	Second area 20.2-21.0ppm	The 3rd regional 19.5-20.2ppm
	Be end-to-end
Sequence (i) sequence (ii)				????PPP(mm) ????PPB(mm) ????BPB(mm)	????PPP(mr) ????PPB(mr) ????BPB(mr) ????PPB(rr) ????BPB(rr)	??????PPP(rr)

In above-mentioned table, P represents the formation unit from propylene, and B represents the formation unit from 1-butylene.

For the ternary sequence of only forming (i) by propylene units, i.e. PPP (mm), PPP (mr), and PPP (rr), at the ternary sequence that is end-to-end (i) of listing in table 1 with (ii), the direction of methyl is represented by following surperficial curved structure.These PPP sequences correspondingly are applied to and contain the unitary mm of butylene, mr and rr ternary sequence (PPB, BPB) in.PPP(mm)：

??PPP(mr)：

??PPP(rr)：

In the first area, mm ternary sequence PPP, the methyl of the Unit second (propylene units) among PPB and the BPB resonates.

In second area, mr ternary sequence PPP, the methyl of the methyl of the Unit second (propylene units) among PPB and the BPB and the Unit second (propylene units) among rr ternary sequence PPB and the BPB resonates.

In the 3rd zone, the methyl of the Unit second (propylene units) among the rr ternary sequence PPP resonates.

Therefore, work as use ¹³C-NMR spectrum (hexachlorobutadiene solution, the tetramethylsilane standard) measures propylene units ternary sequence neutralization that (i) be end-to-end when (ii) forming propylene units and the butylene unit that is end-to-end and containing propylene units as the pendant methyl of the second unit propylene units in the second unitary propylene units-butylene unit ternary sequence, the ternary tacticity (mm mark) of propylene-1-butylene random copolymers can be defined as by following formula, the area at the peak that occurs in 21.0-21.9ppm zone (first area) and the ratio (percentage ratio) of the total area that is decided to be 100% peak that (methyl carbon zone) occurs in the 19.5-21.9ppm zone

PPP(mr)＋PPB(mr)＋BPB(mr)＋

PPP(rr)＋PPB(rr)＋BPB(rr))

Be used for propylene of the present invention-1-butylene random copolymers, preferably for being not less than 90%, better be not less than 92% as above-mentioned definite mm mark, best is not less than 94%.

Except the above-mentioned ternary sequence that is end-to-end (i) with (ii), propylene-1-butylene random copolymers has and a spot ofly contains following structural formula (iii), (iv) and (the v) part-structure of Biao Shi regional irregular unit, and in above-mentioned methyl carbon zone (19.5-21.9ppm), observe self-contained this structure (iii), (iv) with the (peak of propylene units pendant methyl v).Structure (iii)

Structure (iv)

Structure (v)

(n 〉=2)

At said structure (iii), (iv) with (in the methyl v), in 17.3ppm and the resonance of 17.0ppm place, the result can not occur in first to the 3rd zone (19.5-21.9ppm) based on the peak of carbon A and carbon B respectively for methyl carbon A and methyl carbon B.And it doesn't matter with the propylene ternary sequence that is end-to-end for carbon A and carbon B, therefore do not need to consider them when calculating ternary tacticity (mm mark).

Based on the peak of methyl carbon C, occur in second area based on the peak of methyl carbon D with based on the peak of methyl carbon D ', occur in the 3rd zone based on the peak of methyl carbon E with based on the peak of methyl carbon E '.

Therefore, first to trimethylammonium carbon zone, appearance is based on the peak (pendant methyl on propylene-propylene-ethylene sequence) of PPE-methyl (20.7ppm or about), based on the peak (pendant methyl that ethylene-propylene-ethylene sequence lists) of EPE-methyl (19.8ppm or about) with based on methyl C, methyl D, methyl D ', the peak of methyl E and methyl E '.

As mentioned above, can be observed based on except ternary sequence (i) end to end with the peak of the methyl (ii), and when stating formula in the use and determining the mm mark, revise in the following manner.

Based on the peak area of PPE-methyl can by the PPE-methyne (30.6ppm or about locate resonance) peak area determine, based on the peak area of EPE-methyl can by the EPE-methyne (32.9ppm or about locate resonance) peak area determine.

Based on the peak area of methyl C can by adjacent methyne (31.3ppm or about locate resonance) peak area determine.

Based on the peak area of methyl D can by said structure (iv) in based on α β mesomethylene carbon (34.3ppm or about locate resonance and 34.5ppm or about locate resonance) 1/2 the determining of total peak area, based on the peak area of methyl D ' can by said structure (the adjacent methyne of methyl E ' v) (and 33.3ppm or about locate resonance) peak area determine.

Based on the peak area of methyl E can by adjacent methine carbon (33.7ppm or about locate resonance) peak area determine, the peak area of methyl E ' can by adjacent methine carbon (33.3ppm or about locate resonance) peak area determine.

Therefore, can determine by the peak area that from the total peak area at the second and the 3rd regional peak, deducts above-mentioned methyl based on the peak area of propylene units ternary sequence (i) that is end-to-end and methyl (ii).

Like this, can estimate that the result can calculate the mm mark by above-mentioned formula based on the propylene units ternary sequence (i) that is end-to-end and the peak area of methyl (ii).

Carbon peak in the spectrum can be referring to document " Polymer ", and 30,1350 (1989) are specified.

(8) heterodesmic unit

Be used for propylene of the present invention-1-butylene random copolymers (B) and have a spot of structure that contains heterodesmic unit (zone-irregular unit) sometimes, described heterodesmic unit is based on 2 of propylene in the propylene sequences, and 1-inserts or 1,3 insertion.

In polyreaction, propylene normally 1,2-inserts (the methylene cardinal extremity is bonded on the catalyzer) and forms aforementioned propylene sequences of being end-to-end, but propylene is 2 under few cases, and 1-inserts or 1, and 3-inserts.2,1-inserts propylene or 1, and 3-inserts propylene and forms by aforementioned structure (iii) in polymkeric substance, (iv) with (v) Biao Shi zone-irregular unit.Constitute in the unit 2 at polymkeric substance, 1-inserts and 1, and 3-inserts the ratio of propylene can be by following formula use ¹³C-NMR spectrum reference " Polymer ", 30,1350 (1989), determine with the method that is similar to aforementioned ternary tacticity.

Based on propylene 2, the ratio of the regional irregular unit that 1-inserts can be determined by following formula.

When being difficult to directly to determine the area of I α β etc., for example because peak overlapping can use the carbon peak with respective area to revise by spectrum.

Be used for propylene of the present invention-1-butylene random copolymers (B), can containing based on being present in propylene 2 in the propylene sequences, the unitary amount of heterodesmic that 1-inserts is a benchmark in all propylene units, for being not less than 0.01%, is good with 0.01-0.3% especially.

Contained based on propylene 1 in propylene-1-butylene random copolymers (B), the amount of the regional irregular unit that 3-inserts is for being not more than 0.05%, and should be based on propylene 1, the ratio of the regional irregular unit that 3-inserts can by β γ peak (27.4 or about locate resonance) measure.

This aforesaid propylene of the present invention-1-butylene random copolymers that is used for comprises the sticky ingredient than known conventional rubber less amount.

Be used for propylene of the present invention-1-butylene random copolymers (B) and can carry out the copolymerization preparation comprising in the presence of the olefin polymerization catalysis of following component by propylene and 1-butylene:

(a) transistion metal compound as described below;

(b) (b-1) Organoaluminoxy compound, and/or

(b-2) can react the compound that generates ion pair with transistion metal compound (a); With

Choose wantonly,

(c) organo-aluminium compound.

Below, describe the olefin polymerization catalysis that is used to prepare propylene of the present invention-1-butylene random copolymers (B) in detail.

Being used for the transistion metal compound (a) that the present invention forms olefin polymerization catalysis (below be sometimes referred to as " component (a) ") can be represented by following structural formula (1):

Wherein M is periodictable IVa, the transition metal of Va or VIa family.Its example comprises titanium, zirconium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten.Wherein be preferably titanium, zirconium and hafnium.Good especially is zirconium.Substituent R ¹And R ²

R ¹And R ²Be hydrogen atom independently respectively, halogen atom, the alkyl of 1-20 carbon atom, the halo alkyl of 1-20 carbon atom contains silica-basedly, contains the oxygen base, contains sulfenyl, nitrogenous base or phosphorous-containigroups groups.

The example of halides comprises the fluoro thing, chloro thing, bromo-derivative and iodo thing.

The example of the alkyl of 1-20 carbon atom comprises alkyl, methyl for example, ethyl, propyl group, butyl, hexyl, cyclohexyl, octyl group, nonyl, dodecyl, eicosyl, norcamphyl and adamantyl; Alkenyl, vinyl for example, propenyl and cyclohexenyl; Aralkyl, benzyl for example, styroyl and hydrocinnamyl; And aryl, phenyl for example, tolyl, xylyl, trimethylphenyl, ethylbenzene base, propyl phenyl, xenyl, naphthyl, first naphthyl, anthryl and phenanthryl.

The example of halo alkyl comprises that those replace above-mentioned alkyl with halogen atom and the base that obtains.

Contain the silyl that silica-based example comprises that single hydrocarbon replaces, for example methyl-silicane base and phenyl silyl; The silyl that two hydrocarbon replace, for example dimetylsilyl and diphenylmethyl silylation; The silyl that three hydrocarbon replace, trimethyl silyl for example, triethylsilyl, the tripropyl silyl, thricyclohexyl silyl, triphenyl silyl, the 3,5-dimethylphenyl silyl, methyldiphenyl base silyl, trimethylphenyl silyl and three naphthyl silyls; Hydrocarbon replaces the silyl ether of silyl, for example trimethyl silyl ether; The alkyl that silicon replaces, for example trimethyl silyl methyl; With the aryl of silicon replacement, for example trimethyl silyl phenyl.

The example that contains the oxygen base comprises hydroxyl; Alkoxyl group, methoxyl group for example, oxyethyl group, propoxy-and butoxy; Aryloxy, phenoxy group for example, methylphenoxy, dimethyl phenoxy and naphthyloxy; And aralkoxy, for example phenyl methoxyl group and phenyl ethoxy.

The example that contains sulfenyl be included in above-mentioned give an example contain the group that the oxygen in the oxygen base is replaced by sulphur.

The example of nitrogenous base comprises amino; Alkylamino, methylamino-for example, dimethylamino, diethylin, dipropyl amino, dibutylamino and dicyclohexylamine base; Amino and alkane virtue amino, for example phenylamino, diphenylamino, xylyl amino, dinaphthyl amino and aminomethyl phenyl amino with virtue.

The example of phosphorous-containigroups groups comprises phosphino-, for example dimethyl phosphino-and diphenylphosphino.

Wherein, R ¹Be hydrogen preferably, methyl, the alkyl of 2-6 carbon atom and aryl, good especially is the alkyl of methyl and 2-6 carbon atom.

R ²Being hydrogen and alkyl preferably, is special good with hydrogen.Substituent R ³

R ³For can or containing the alkyl of 1-20 carbon atom of silica-based replacement, be the second month in a season or the tertiary alkyl or the aryl of 3-20 carbon atom preferably by halogen atom.

The example of the second month in a season or tertiary alkyl comprises sec.-propyl, isobutyl-, sec-butyl, the tertiary butyl, 1,2-dimethyl propyl, 2,3-dimethyl propyl, isopentyl, tert-pentyl, neo-pentyl, cyclopentyl, cyclohexyl, 4-methylcyclohexyl, isohexyl, norcamphyl and adamantyl.

The example of aromatic base comprises aryl, phenyl for example, tolyl, 3,5-dimethylphenyl, trimethylphenyl, ethylbenzene base, propyl phenyl, xenyl, α-or betanaphthyl, first naphthyl, anthryl, phenanthryl, benzyl phenyl, pyrenyl, acenaphthenyl, phenalenyl, aceanthrylenyl, tetralyl, indenyl and xenyl; And aralkyl, for example benzyl, styroyl, hydrocinnamyl and methylbenzyl.These groups can contain two keys or triple bond.

And these groups can be by as R ¹Described in halogen atom and contain silica-based replacement.Substituent R ⁴

R ⁴Alkyl for hydrogen atom or 1-20 carbon atom.

The example of alkyl comprises chain and cyclic alkyl, for example methyl, ethyl, n-propyl, sec.-propyl, normal-butyl, isobutyl-, sec-butyl, the tertiary butyl, amyl group, hexyl, cyclohexyl, heptyl, octyl group, nonyl, dodecyl, eicosyl, norcamphyl and adamantyl.

These groups can be by as R ¹Described in halogen atom and contain silica-based replacement.X ¹And X ²

X ¹And X ²Be respectively hydrogen atom, halogen atom, the alkyl of 1-20 carbon atom, the halo alkyl of 1-20 carbon atom contains the oxygen base or contains sulfenyl.

Halogen atom contains the oxygen base, the example such as the R of the halo alkyl of the alkyl of a 1-20 carbon atom and 1-20 carbon atom ¹Described in.

The example that contains sulfenyl comprises that those are as R ¹Described in the person; And also have sulfonyloxy, and sulfonyloxy methyl oxygen base for example, trifluoro-methanesulfonyl oxy, the phenyl sulfonyloxy, the benzyl sulfonyloxy, tolysulfonyl oxygen base, the Three methyl Benzene sulfonyloxy, the triisobutyl phenylsulfonyloxy is to chlorobenzene sulfonyloxy and penta fluoro benzene sulfonyloxy; With sulfinyl oxygen base, methyl sulfinyl oxygen base for example, phenyl sulfinyl oxygen base, phenylsulfinyl oxygen base, to toluene sulfinyl oxygen base, Three methyl Benzene sulfinyl oxygen base and penta fluoro benzene sulfinyl oxygen base.Y

Y is the bivalent hydrocarbon radical of 1-20 carbon atom, the divalence halo alkyl of 1-20 carbon atom, and divalence contains silica-based, the germanic base of divalence, divalence contains tinbase ,-O-,-CO-,-S-,-SO-,-SO ₂-,-NR ⁵-,-P (R ⁵)-,-P (O) (R ⁵)-,-BR ⁵-or-AlR ⁵-(R ⁵Be hydrogen atom, halogen atom, the halo alkyl of the alkyl of a 1-20 carbon atom or 1-20 carbon atom).

Can be exemplified below more specifically:

The bivalent hydrocarbon radical of 1-20 carbon atom comprises alkylidene group, methylene radical for example, dimethylated methylene base, ethylene, dimethyl-1, the 2-ethylidene, 1, the 3-trimethylene, 1,4-tetramethylene, 1,2-cyclohexylene and 1,4-cyclohexylene, and arylmethylene alkyl, for example phenylbenzene methylene radical and phenylbenzene-ethylene.

The divalence halo alkyl of 1-20 carbon atom comprises the above-mentioned bivalent hydrocarbon radical of giving an example of halo, for example chlorine methylene radical;

Divalence contains the silica-based alkyl silicylene that comprises, alkaryl silicylene and aryl silicylene, methyl silicylene for example, the dimethylated methylene silylation, the diethyl silicylene, two (n-propyl) silicylene, two (sec.-propyl) silicylene, two (cyclohexyl) silicylene, the tolyl silicylene, the xenyl silicylene, two (p-methylphenyl) silicylene and two (rubigan) silicylene and alkyl two silicylene, alkaryl two silicylene and aryl two silicylene, tetramethyl--1 for example, 2-two silicylene and tetraphenyl-1,2-two silicylene.

The germanic base of divalence comprise those above-mentioned divalence of giving an example contain silica-based in silicon by the displaced group of germanium.

Divalence contain tinbase comprise those above-mentioned divalence of giving an example contain silica-based in silicon by the displaced group of tin.

R ⁵Example be as R ¹Described in halogen atom, the halo alkyl of the alkyl of a 1-20 carbon atom and 1-20 carbon atom.

Wherein, be preferably divalence and contain silica-basedly, germanic base of divalence and divalence contain tinbase, are more preferably divalence and contain silica-based.Wherein good especially is the alkyl silicylene, alkaryl silicylene and aryl silicylene.

What list below is the transistion metal compound of said structure formula (1) expression.

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-ethyl-indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-n-propyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-sec.-propyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-normal-butyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-sec-butyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-tertiary butyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-n-pentyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-n-hexyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-cyclohexyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-methylcyclohexyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-styroyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-phenyl dichloromethyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-chloromethyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-trimethyl silyl methyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-trimethylsiloxy methyl indenyl) } is closed zirconium (IV),

Racemize-dichloride diethyl silicylene-two { 1-(2,7-dimethyl-4-sec.-propyl indenyl) } is closed zirconium (IV),

Racemize-dichloride two (sec.-propyl) silicylene-two { 1-(2,7-dimethyl-4-sec.-propyl indenyl) } closes zirconium (IV),

Racemize-dichloride two (normal-butyl) silicylene-two { 1-(2,7-dimethyl-4-sec.-propyl indenyl) } closes zirconium (IV),

Racemize-dichloride two (cyclohexyl) silicylene-two { 1-(2,7-dimethyl-4-sec.-propyl indenyl) } closes zirconium (IV),

Racemize-dichloride tolyl silicylene-two { 1-(2,7-dimethyl-4-sec.-propyl indenyl) } is closed zirconium (IV),

Racemize-dichloride tolyl silicylene-two { 1-(2,7-dimethyl-4-tertiary butyl indenyl) } is closed zirconium (IV),

Racemize-dichloride phenylbenzene silicylene-two { 1-(2,7-dimethyl-4-tertiary butyl indenyl) } is closed zirconium (IV),

Racemize-dichloride phenylbenzene silicylene-two { 1-(2,7-dimethyl-4-sec.-propyl indenyl) } is closed zirconium (IV),

Racemize-dichloride phenylbenzene silicylene-two { 1-(2,7-dimethyl-4-ethyl-indenyl) } is closed zirconium (IV),

Racemize-dichloride two (p-methylphenyl) silicylene-two { 1-(2,7-dimethyl-4-sec.-propyl indenyl) } closes zirconium (IV),

Racemize-dichloride two (rubigan) silicylene-two { 1-(2,7-dimethyl-4-sec.-propyl indenyl) } closes zirconium (IV),

Racemize-dibrominated dimethylated methylene silylation-two { 1-(2-methyl-4-sec.-propyl-7-ethyl-indenyl) } is closed zirconium (IV),

Racemize-dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-sec.-propyl indenyl) } is closed zirconium dimethyl (IV),

Racemize-methyl chlorination dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-sec.-propyl indenyl) } is closed zirconium (IV),

Racemize-two (trifluoromethanesulfonic acid)-dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-sec.-propyl indenyl) } is closed zirconium (IV),

Racemize-two (to the phenyl-sulfinic acid)-dimethylated methylene silylation-two { 1-(2,7-dimethyl-4-sec.-propyl indenyl) } close zirconium (IV) and

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-phenyl-4-sec.-propyl-7-methyl indenyl) } is closed zirconium (IV).

In the transistion metal compound of said structure formula (1) expression, those compounds by following structural formula (1-a) expression are particularly preferred for the present invention.

M wherein, X ¹, X ², R ¹, R ³, identical with Y with the definition in the structural formula (1), and R ¹Be hydrogen, methyl or aromatic base preferably.

What list below is the example preferably of the transistion metal compound of said structure formula (1-a) expression.

Racemize-dichloride dimethylated methylene silylation-two { 1-(4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(betanaphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(1-anthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(2-anthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(9-anthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(9-phenanthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(to fluorophenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(pentafluorophenyl group) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(rubigan)-1-indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(chloro-phenyl-) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(Chloro-O-Phenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(neighbour, santochlor base) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(to bromophenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(p-methylphenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(tolyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(o-tolyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(neighbour, neighbour ' 3,5-dimethylphenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(to the ethylbenzene base) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(p-isopropyl phenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(to benzyl phenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(to xenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(xenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(to the trimethyl silyl phenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-methyl-4-(a trimethyl silyl phenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene silylation-two { 1-(2-phenyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride diethyl silicylene-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride two (sec.-propyl) silicylene-two { 1-(2-methyl-4-phenyl indenyl) } closes zirconium (IV),

Racemize-dichloride two (normal-butyl) silicylene-two { 1-(2-methyl-4-phenyl indenyl) } closes zirconium (IV),

Racemize-dichloride dicyclohexyl silicylene-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride aminomethyl phenyl silicylene-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride phenylbenzene silicylene-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride two (p-methylphenyl) silicylene-two { 1-(2-methyl-4-phenyl indenyl) } closes zirconium (IV),

Racemize-dichloride two (rubigan) silicylene-two { 1-(2-methyl-4-phenyl indenyl) } closes zirconium (IV),

Racemize-dichloride methylene radical-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride ethylidene-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene germane base-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride dimethylated methylene stannane base-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dibrominated dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium dimethyl (IV),

Racemize-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed methyl zirconium chloride (IV),

Racemize-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed SO ₂Me zirconium chloride (IV),

Racemize-OSO ₂Zirconium (IV) is closed in Me chlorination-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) },

Racemize-one (trifluoromethanesulfonic acid)-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-two (trifluoromethanesulfonic acid)-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-two (tosic acid)-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-two (methylsulfonic acid)-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-two (trifluoroacetic acid)-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-monochlor(in)ate one (n-butoxy)-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-two (n-butoxy)-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-monochlor(in)ate one (phenoxy group)-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } close titanium (IV) and

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-methyl-4-phenyl indenyl) } is closed hafnium (IV),

In above-claimed cpd, good especially is R wherein ¹Compound for the structural formula (1-a) of methyl.

Available is R wherein equally preferably ¹Be the alkyl of 2～6 carbon atoms and R ³It is the transistion metal compound of the structural formula (1-a) of the aryl of 6～16 carbon atoms.The example of these compounds is following listed:

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(β--naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(2-methyl isophthalic acid-naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(5-acenaphthenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(9-anthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(9-phenanthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(o-tolyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(tolyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(p-methylphenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(2, the 3-xylyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(2, the 4-xylyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(2, the 5-xylyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(mesityl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(Chloro-O-Phenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(chloro-phenyl-) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(rubigan) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(2, the 3-dichlorophenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(2, the 6-dichlorophenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(3, the 5-dichlorophenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(2-bromophenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(3-bromophenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(4-bromophenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(4-xenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-ethyl-4-(4-trimethyl silyl phenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-n-propyl-4-(phenyl indenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-n-propyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-n-propyl-4-(betanaphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-n-propyl-4-(2-methyl isophthalic acid-naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-n-propyl-4-(5-acenaphthenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-n-propyl-4-(9-anthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-n-propyl-4-(9-phenanthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-sec.-propyl-4-phenyl indenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-sec.-propyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-sec.-propyl-4-(betanaphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-sec.-propyl-4-(2-methyl isophthalic acid-naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-sec.-propyl-4-(5-acenaphthenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-sec.-propyl-4-(9-anthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-sec.-propyl-4-(9-phenanthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-sec-butyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-sec-butyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-sec-butyl-4-(betanaphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-sec-butyl-4-(8-methyl-9-naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two (1-(2-sec-butyl-4-(5-acenaphthenyl) indenyl) } close zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-sec-butyl-4-(9-anthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-sec-butyl-4-(9-phenanthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-n-pentyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-n-pentyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-normal-butyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-normal-butyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-normal-butyl-4-(betanaphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-normal-butyl-4-(2-methyl isophthalic acid-naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-normal-butyl-4-(5-acenaphthenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-normal-butyl-4-(9-anthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-normal-butyl-4-(9-phenanthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-isobutyl--4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-isobutyl--4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-isobutyl--4-(betanaphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-isobutyl--4-(2-methyl isophthalic acid-naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-isobutyl--4-(5-acenaphthenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-isobutyl--4-(9-anthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-isobutyl--4-(9-phenanthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-neo-pentyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-neo-pentyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-n-hexyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene silylation-two { 1-(2-n-hexyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-aminomethyl phenyl silicylene-two { 1-(2-ethyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-aminomethyl phenyl silicylene-two { 1-(2-ethyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-aminomethyl phenyl silicylene-two { 1-(2-ethyl-4-(9-anthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-aminomethyl phenyl silicylene-two { 1-(2-ethyl-4-(9-phenanthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-phenylbenzene silicylene-two { 1-(2-ethyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-phenylbenzene silicylene-two { 1-(2-ethyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-phenylbenzene silicylene-two { 1-(2-ethyl-4-(9-anthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-phenylbenzene silicylene-two { 1-(2-ethyl-4-(9-phenanthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-phenylbenzene silicylene-two { 1-(2-ethyl-4-(4-xenyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-methylene radical-two { 1-(2-ethyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-methylene radical-two { 1-(2-ethyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-ethylidene-two { 1-(2-ethyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-ethylidene-two { 1-(2-n-propyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene germane base-two { 1-(2-ethyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene germane base-two { 1-(2-ethyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene germane base-two { 1-(2-n-propyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene stannane base-two { 1-(2-ethyl-4-phenyl indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene stannane base-two { 1-(2-ethyl-4-(Alpha-Naphthyl) indenyl) } is closed zirconium (IV), indenyl) } close zirconium (IV),

Racemize-dichloride-dimethylated methylene germane base-two { 1-(2-ethyl-4-(9-phenanthryl) indenyl) } is closed zirconium (IV),

Racemize-dichloride-dimethylated methylene germane base-two { 1-(2-n-propyl-4-phenyl indenyl) } is closed zirconium (IV),

In the present invention, also can adopt the transistion metal compound that replaces with titanium, hafnium, vanadium, niobium, tantalum, chromium, molybdenum or tungsten corresponding to the metal zirconium in the above-mentioned compound of enumerating.

The compound of transistion metal compound (A) uses as olefin polymerization catalyst components with the form of racemic modification usually, but they also can the R type or the form of S type use.

The used transistion metal compound of the present invention can be according to " Journal ofOrganometallic Chem. ", and 288 (1985), pp63-67 and EP-A-0320762 are prepared.For example, formula (1-a) can be prepared by following reaction scheme.

Wherein Z is Cl, Br, I or O-tosyl group, and H ₂R ^aFor

The Organoaluminoxy compound (b-1) of used generation olefin polymerization catalysis among the present invention (hereinafter being called " component (b-1) " sometimes) can be the aikyiaiurnirsoxan beta known to usually or the Organoaluminoxy compound of benzene dissolubility, the latter exists, for example, among the open № 78687/1990 of Japanese Patent narration is arranged.

Usually the aikyiaiurnirsoxan beta known to can be passed through, for example, and the following procedure preparation.

(1) with organo-aluminium compound, for example, trialkylaluminium is added in the hydrocarbon medium dispersion of water that contains absorption or the compound of the salt that contains crystal water (for example hydrated magnesium chloride, hydrated copper sulfate, hydrazine aluminum sulfate, hydration nickel sulfate and hydration cerous compounds), so that the water of organo-aluminium compound and absorption or crystal water reaction.

(2) make water, ice or water vapour directly and organo-aluminium compound (for example, trialkylaluminium) in medium (for example benzene, toluene, ether or tetrahydrofuran (THF)), act on.

(3) organotin oxides such as tin methide oxide compound or dibutyl tin oxide and organo-aluminium compound (for example, trialkylaluminium) are reacted in medium (for example decane, benzene or toluene).

Aikyiaiurnirsoxan beta can contain a small amount of organo-metallic component.The aluminoxanes solution that obtains above can be with in the present invention, but also can boil off solvent or unreacted organo-aluminium compound from this solution, is dissolved in resistates in a kind of solvent more then or is dispersed in the poor solvent of aikyiaiurnirsoxan beta.

The example that is used to prepare the organo-aluminium compound of aikyiaiurnirsoxan beta comprises:

The trialkylaluminium class, for example, trimethyl aluminium, triethyl aluminum, triisopropylaluminiuand, three n-butylaluminum, triisobutyl aluminium, three sec-butyl aluminium, tri-tert aluminium, three amyl group aluminium, three hexyl aluminium, trioctylaluminum and three decyl aluminium;

Tricyclic alkyl aluminium class, for example, thricyclohexyl aluminium and three ring octyl group aluminium;

The dialkyl aluminum halide class, as chlorodimethylalumiu, diethylaluminum chloride, bromination diethyl aluminum and di-isobutyl aluminum chloride;

The dialkyl aluminum hydride class is as diethyl aluminium hydride and diisobutylaluminium hydride;

The aluminum dialkyl alkoxide is as dimethyl methoxy base aluminium and diethylaluminum ethoxide; And

Aluminum dialkyl virtue oxide compound is as diethyl phenoxy group aluminium.

Wherein, be preferably trialkylaluminium and tricyclic alkyl aluminium, good especially is triethyl aluminum.

The organo-aluminium compound that also can be used for preparing aikyiaiurnirsoxan beta has by the represented alkenyl aluminium of following formula:

(iC ₄H ₉) _xAl _y(C ₅H ₁₀) _zWherein x, y and z respectively are positive number, and z 〉=2x, for example prenyl aluminium.

Organo-aluminium compound above-mentioned can use separately or be used in combination.

Be used to prepare the solvent of aikyiaiurnirsoxan beta and the example of suspension comprises aromatic hydrocarbons, as benzene,toluene,xylene, cumene, Cymene; Aliphatic hydrocarbon is as pentane, hexane, heptane, octane, decane, dodecane, n-Hexadecane and octadecane; Alicyclic hydrocarbon is as pentamethylene, hexanaphthene, cyclooctane and methylcyclopentane; Petroleum fractions is as gasoline, kerosene and gas oil; And these aromatic hydrocarbons, aliphatic hydrocarbon and alicyclic halides, especially its muriate or bromide.Also can use ether, as ether and tetrahydrofuran (THF).In these solvents, preferably aromatic hydrocarbons and aliphatic hydrocarbon.

Be used to generate olefin polymerization catalysis of the present invention can be right with transistion metal compound (a) reacting forming ion compound (b-2) (hereinafter being called " component (b-2) " sometimes) comprise Lewis acid, ionic compound and carborane compound, these for example Japanese patent laid-open publication gazette No.501950/1989, No.502036/1989, No.179005/1991, No.179006/1991, No.207703/1991 and 207704/1991 and United States Patent (USP) 547,718 in be described.

Lewis acid example comprises triphenyl-boron, three (4-fluorophenyl) boron, three (p-methylphenyl) boron, three (o-tolyl) boron, three (3, the 5-xylyl) boron, three (pentafluorophenyl group) boron, Mg-Cl ₂, Al ₂O ₃And SiO ₂-Al ₂O ₃

The example of ionic compound comprises four (pentafluorophenyl group) boric acid triphenylcarbenium, four (pentafluorophenyl group) boric acid, three normal-butyl ammoniums, four (pentafluorophenyl group) boric acid N, N-dimethyl puratized agricultural spray and four (pentafluorophenyl group) boric acid ferrocene.

The carborane examples for compounds comprises ten diboron hexahydrides, 1-carbon generation 11 borines, 1-carbon generation ten hypoboric acid two (normal-butyl) ammoniums, 7,8-two carbon for 11-borate three (normal-butyl) ammonium and 13 hydrogen-7-carbon for 11-borate three (normal-butyl) ammonium.

Can use separately or be used in combination with the right compound (b-2) of transistion metal compound (a) reacting forming ion.

The Organoaluminoxy compound (c) of used generation olefin polymerization catalysis among the present invention (hereinafter being called " component (c) " sometimes) is passable, for example, represents with following formula (2):

R ⁹ _nAlX _3-n(2) R wherein ⁹For containing the alkyl of 1 to 12 carbon atom, X is halogen atom or hydrogen atom, and n is 1 to 3.

In above-mentioned formula (2), R ⁹For containing the alkyl of 1 to 12 carbon atom, for example alkyl, cycloalkyl or aryl.Its specific examples comprises methyl, ethyl, n-propyl, sec.-propyl, isobutyl-, amyl group, hexyl, octyl group, cyclopentyl, cyclohexyl, phenyl and tolyl.

The example of organo-aluminium compound (c) comprising:

The trialkylaluminium class, for example, trimethyl aluminium, triethyl aluminum, triisopropylaluminiuand, triisobutyl aluminium, trioctylaluminum, three (2-ethylhexyl) aluminium and three decyl aluminium;

Alkenyl aluminium, for example, pseudoallyl aluminium;

The dialkyl aluminum halide class, as chlorodimethylalumiu, diethylaluminum chloride, chlorination di-isopropyl aluminium, di-isobutyl aluminum chloride and bromination dimethyl aluminium;

Aluminum alkyls sesquihalide class is as sesquialter methyl chloride aluminium, sesquialter ethylaluminium chloride, sesquialter chlorination sec.-propyl aluminium, sesquialter chlorinated butyl aluminium and sesquialter bromination aluminium triethyl;

Alkyllithium dihalide is as methylaluminium dichloride, ethylaluminium dichloride, dichloride sec.-propyl aluminium and dibrominated aluminium triethyl; And

Dialkyl aluminum hydride is as ADEH and diisobutyl aluminium hydride.

Also can use the compound of representing by following formula (3) as organo-aluminium compound (c):

R ⁹ _nAlL _3-n(3) R wherein ⁹With identical in the following formula (2); L is-OR ¹⁰Base ,-OSiR ₃ ¹¹Base ,-OAlR ₂ ¹²Base ,-NR ₂ ¹³Base ,-SiR ₃ ¹⁴The base or-N (R ¹⁵) AlR ₂ ¹⁶Base; N is 1 to 2; R ¹⁰, R ¹¹, R ¹²And R ¹⁶Respectively be methyl, ethyl, sec.-propyl, isobutyl-, cyclohexyl, phenyl or the like, R ³Be hydrogen, methyl, ethyl, sec.-propyl, phenyl, trimethylammonium silylene or the like; R ¹⁴And R ¹⁵Respectively be methyl, ethyl or the like.

In these organo-aluminium compounds, be preferably R _n ⁹Al (OAlR ₂ ¹²) _3-n, for example, Et ₂AlOAlEt ₂(iso-Bu) ₂AlOAl (iso-Bu) ₂

In the organo-aluminium compound by formula (2) and (3) expression, be preferably formula R ₃ ⁹Those of Al, wherein that good especially is R ⁹Be iso-alkyl.

Used olefin polymerization catalysis can be by mixed composition (a) and component (b-1) (or component (b-2)) in unreactive hydrocarbons solvent or alkene solvent among the present invention, and component (c) and preparing randomly.

The example that is used to prepare the unreactive hydrocarbons solvent of olefin polymerization catalysis comprises aliphatic hydrocarbon, for example propane, butane, pentane, hexane, heptane, octane, decane, dodecane and kerosene; Alicyclic hydrocarbon, for example pentamethylene, hexanaphthene and methylcyclopentane; Aromatic hydrocarbon is benzene, toluene and dimethylbenzene for example; Halohydrocarbon, for example ethylene chloride, chlorobenzene and methylene dichloride; And the mixture of these solvents.

Above-mentioned component can mix with any order, but is preferably:

Component (b-1) (or component (b-2)) mixes with component (a);

Component (b-1) at first mixes with component (c), mixes with component (a) then;

Component (a) at first mixes with component (b-1) (or component (b-2)), mixes with component (c) then; Perhaps

Component (a) at first mixes with component (c), mixes with component (b-1) (or component (b-2)) then.

In the mixing of above-mentioned component, aluminium can be 10 to 10,000 usually to the atomic ratio (Al/ transition metal) of transition metal in the transistion metal compound (a) in the component (b-1), is preferably 20 to 5,000, and the concentration of component (a) can be 10 ^-8To 10 ^-1Mol/l is 10 preferably ^-7To 5 * 10 ^-2Mol/l.

When using component (b-2), component (a) can be 0.01 to 10 usually to the mol ratio (component (a)/component (b-2)) of component (b-2), is 0.1 to 5 preferably, and the concentration of component (a) can be 10 ^-8To 10 ^-1Mol/l is 10 preferably ^-7To 5 * 10 ^-2Mol/l.

When using component (c), aluminium atom (Al in the component (c) _c) to aluminium atom (Al in the component (b-1) _B-1) atomic ratio (Al _cAl _B-1) can be 0.02 to 20 usually, be preferably 0.2 to 10.

Above-mentioned catalyst component can mix in polymerization reactor, perhaps the ready-formed mixture can be added in the reactor.

If component is premixed, mixing temperature can be-50 ℃ to 150 ℃ usually, is-20 ℃ to 120 ℃ preferably; Can be 1 to 1,000 minute duration of contact, is 5 to 600 minutes preferably.Mixing temperature can change in mixing process.

Used olefin polymerization catalysis can be the solid olefin polymerization catalysis among the present invention, wherein above-mentioned component (a) and (b) and (c) at least a be carried on inorganic or organic, on the granular or fine particle solid carrier.

Inorganic carrier is preferably porous oxide, and the example comprises SiO ₂And Al ₂O ₃

Example granular or the fine particle solid organic compound comprises polymkeric substance and the multipolymer that is prepared as main component by alpha-olefin (for example ethene, propylene and 1-butylene) or vinylbenzene.

The used olefin polymerization catalysis of the present invention can be by fine-grained carrier, component (a), component (b) and the olefin polymer that is produced by prepolymerization, and optional component (c) generates.

In prepolymerization, can use alkene, for example propylene, ethene and 1-butylene.Also can use the mixture of these alkene and other alkene.

Except above-mentioned component, the used olefin polymerization catalysis of the present invention can also contain other component useful to olefinic polymerization, and for example water is as catalyst component.

Propylene-1-butylene random copolymers used among the present invention can by such method, promptly finally can obtain monomer composition as defined above by propylene and 1-butylene copolymerization in the presence of above-mentioned olefin polymerization catalysis.

Polymerization can be carried out with any liquid polymerization method (for example suspending or solution polymerization process) or gas phase polymerization process.

In liquid polymerization method, can use that unreactive hydrocarbons solvent is for example above-mentioned to be used to prepare those of catalyzer, also can use propylene itself as solvent.

In suspension polymerization, polymerization temperature can be-50 ℃ to 100 ℃ usually, is preferably 0 to 90 ℃; In solution polymerization process, be generally 0 to 250 ℃, be preferably 20 to 200 ℃; In gas phase polymerization process, be generally 0 to 120 ℃, be preferably 20 to 100 ℃.Polymerization pressure can be barometric point usually to 100kg/cm ², be preferably barometric point to 50kg/cm ²Polyreaction can be in batches, semicontinuous or carry out continuously.Polymerization also can be under different reaction conditionss in two steps or multistep carry out.

The molecular weight of the propylene that obtains-1-butylene random copolymers can be controlled by add hydrogen or change polymerization temperature or polymerization pressure in polymerization system.Polypropene composition

Polypropene composition of the present invention comprises:

5 to 95% (weight) are preferably 20 to 90% (weight), the polypropylene of 40 to 85% (weight) (A) more preferably, and

95 to 5% (weight) are preferably 80 to 10% (weight), more preferably the propylene of 60 to 15% (weight)-1-butylene random copolymers (B).

Polypropene composition can be with any usually known method preparation that is used to prepare resin combination, for example knead polypropylene (A) and propylene-1-butylene random copolymers (B) of fusion.

The melt flow rate MFR of polypropene composition can be preferably 1 to 100g/10min for 0.1 to 400g/10min.

The fusing point of polypropene composition can be 60 to 165 ℃, is preferably 80 to 160 ℃.

Except polypropylene and propylene-1-butylene random copolymers, propylene compositions of the present invention can also contain additive and other resin, only otherwise influencing purpose of the present invention gets final product.

The example of these additives comprises nucleator, anti-aging agent, hydrochloric acid absorbent, thermo-stabilizer, photostabilizer, ultraviolet absorbers, lubricant, static inhibitor, fire retardant, pigment, dyestuff, dispersion agent, copper(greening)inhibitor, neutralizing agent, whipping agent, softening agent, defoamer, linking agent, mobile dose for example superoxide and welding strength dose.

As anti-aging agent, can use phenolic type antioxidant, sulphur class anti-aging agent, Phosphorus anti-aging agent or the like.The example of phenolic type antioxidant comprises phenolic compound, for example 2,6 ditertbutylparacresols, (3,3-dimethyl-4-hydroxybenzyl) Thiovanic acid octadecane ester, β-(4-hydroxyl-3, the 5-di-tert-butyl-phenyl) propionic acid octadecane ester, 3,5-di-tert-butyl-4-hydroxyl benzyl di(2-ethylhexyl)phosphate (octadecane) ester, 2,4,6-three (3 ', 5 '-di-t-butyl-4 '-hydroxybenzyl sulphur)-1,3, the 5-triazine, (4-hydroxy-3-methyl-5-tertiary butyl benzyl) propanedioic acid two (octadecane) ester, 2,2 '-methylene-bis (4-methyl-6-tert butyl phenol), 4,4 '-methylene-bis (2, the 5-di-tert-butylphenol), 2,2 '-methylene-bis (6-(1-methylcyclohexyl) p-cresol), two (3,5-two (4-hydroxyl-3-tert-butyl-phenyl) butyric acid) glycol ester, 4,4 '-butylidene two (6-tertiary butyl meta-cresol), 1,1,3-three (2-methyl-4-hydroxyl-5-tert-butyl-phenyl) butane, terephthalic acid two (the 2-tertiary butyl-4-methyl-6-(the 2-hydroxyl-3-tertiary butyl-5-methyl-benzyl) phenyl) ester, isocyanuric acid-1,3,5-three (2,6-dimethyl-3-hydroxyl-4-tertiary butyl) benzyl ester, 1,3,5-three (3, the 5-di-tert-butyl-4-hydroxyl benzyl)-2,4, the 6-Three methyl Benzene, four (3-(3, the 5-di-tert-butyl-hydroxy phenyl) propionic acid methylene radical ester) methane, isocyanuric acid-1,3,5-three (3, the 5-di-tert-butyl-4-hydroxyl benzyl) ester, isocyanuric acid-1,3,5-three ((3, the 5-di-tert-butyl-hydroxy phenyl) ester propionyloxy ethyl), 2-octylsulfo-4,6-two (4-hydroxyl-3,5-di-t-butyl) phenoxy group-1,3,5-triazine and 4,4 '-sulfo-two (6-tertiary butyl meta-cresol); And the few ester of carbonic acid polyphenol, for example 4,4 '-the few ester of carbonic acid of butylidene two (the 2-tertiary butyl-5-sylvan) is (as the polymerization degree: 2 to 10).

The example of sulphur class anti-aging agent comprises the thio-2 acid dialkyl esters, for example Tyox B, thio-2 acid distearyl ester; And the ester class of polyvalent alcohol (for example glycerol, trimethylolethane, TriMethylolPropane(TMP), tetramethylolmethane and isocyanuric acid trihydroxyethyl ester) and alkylthio propionic acid (for example butyl propane thioic acid, octylsulfo propionic acid, lauryl propane thioic acid and stearyl propane thioic acid), for example four lauryl propane thioic acid pentaerythritol esters.

The example of Phosphorus anti-aging agent comprises the tricresyl phosphite monooctyl ester, trilauryl phosphite, tridecyl phosphite, phosphorous acid octyl group diphenyl, tricresyl phosphite (2, the 4-di-tert-butyl-phenyl) ester, triphenyl phosphite, tricresyl phosphite (butoxyethyl group) ester, tricresyl phosphite (nonyl phenyl) ester, diphosphorous acid distearyl acidic group pentaerythritol ester, four (tridecyl)-1,1, the diphosphites of 3-three (2-methyl-5-tert-butyl-hydroxy phenyl) butane, diphosphorous acid four (C12-C15 blended alkyl)-4,4 '-the isopropylidene diphenyl, diphosphorous acid four (tridecyl)-4,4 '-butylidene two (3-methyl-6-tert butyl phenol) ester, tricresyl phosphite (3, the 5-di-tert-butyl-hydroxy phenyl) ester, tricresyl phosphite (one-two blended nonyl phenyl) ester,-4 of hydrogenation, 4 '-polyphosphite of isopropylidene diphenol, two (octyl phenyl) two (4,4 '-butylidene two (3-methyl-6-tert butyl phenol)) 1, the diphosphites of 6-hexylene glycol, phenyl-4,4 '-diphosphites of isopropylidene diphenol tetramethylolmethane, two (2, the 4-di-tert-butyl-phenyl) diphosphites of tetramethylolmethane, two (2,6-di-t-butyl-4-aminomethyl phenyl) diphosphites of tetramethylolmethane, three (4,4 '-isopropylidene two (2-tert-butyl phenol)) phosphorous acid ester, the phosphorous acid ester of phenyl diiso decyl, the diphosphites of two (nonyl phenyl) tetramethylolmethane, tricresyl phosphite (1,3-distearyl acyl-oxygen sec.-propyl) ester, 4,4 '-two (nonyl phenyl) phosphorous acid ester of isopropylidene two (2-tert-butyl phenol), 9, the 10-dihydro-9-oxy is mixed-1-phospho hetero phenanthrene-10-oxide compound and diphosphorous acid four (2, the 4-di-tert-butyl-phenyl)-4,4 '-biphenyl ester.

The example of operable anti-aging agent also has 6-hydroxychroman derivative, for example α-, β-, γ-and Delta-Tocopherol and composition thereof, 2 of 2-(4-methyl-3-pentenyl)-6-hydroxychroman, the 5-dimethyl, 2,5,8-trimethylammonium and 2,5,7, the derivative that the 8-tetramethyl-replaces, 2,2, the 7-trimethylammonium-5-tertiary butyl-6-hydroxychroman, 2,2,5-trimethylammonium-7-the tertiary butyl-6-hydroxychroman, 2,2, the 5-trimethylammonium-6-tertiary butyl-6-hydroxychroman and 2, the 2-dimethyl-5-tertiary butyl-6-hydroxychroman.

As hydrochloric acid absorbent, can use by the represented mixing salt of following formula:

MxAly (OH) 2x+3y-2z (A) zaH ₂O wherein M is Mg, Ca or Zn; A is the negatively charged ion beyond the hydroxyl-removal; X, y and z respectively are positive number; A is 0 or positive number, for example Mg ₆Al ₂(OH) ₁₆CO ₃4H ₂O,

Mg ₆Al ₂(OH) ₂₀CO ₃·5H ₂O，

Mg ₅Al ₂(OH) ₁₄CO ₃·4H ₂O，

Mg ₁₀Al ₂(OH) ₂₂(CO ₃) ₂·4H ₂O，

Mg ₆Al ₂(OH) ₁₆HPO ₄·4H ₂O，

Ca ₆Al ₂(OH) ₁₆CO ₃·4H ₂O，

Zn ₆Al ₂(OH) ₁₆CO ₃·4H ₂O，

Zn ₆Al ₂(OH) ₁₆SO ₄·4H ₂O，

Mg ₆Al ₂(OH) ₁₆SO ₃4H ₂O and

Mg ₆Al ₂(OH) ₁₂CO ₃·3H ₂O。

The example of photostabilizer comprises the hydroxy benzophenone class, for example 2-hydroxyl-4-methoxyl group benzophenone, 2-hydroxyl-4-n-octyloxy benzophenone, 2,2 '-dihydroxyl-4-methoxyl group benzophenone and 2,4 dihydroxy benzophenone; Benzotriazole, for example 2-(2 '-hydroxyl-3 '-tertiary butyl-5 '-aminomethyl phenyl)-5-chlorobenzotriazole, 2-(2 '-hydroxyl-3 ', 5 '-di-tert-butyl-phenyl)-5-chlorobenzotriazole, 2-(2 '-hydroxyl-5 '-aminomethyl phenyl) benzotriazole and 2-(2 '-hydroxyl-3 ', 5 '-di-tert-pentyl-phenyl) benzotriazole; Benzoates, for example salol, p-t-butylphenyl salicylate, 3,5-di-tert-butyl-4-hydroxybenzoic acid-2,4-di-tert-butyl-phenyl ester and 3,5-di-tert-butyl-4-hydroxybenzoic acid n-Hexadecane ester; Nickel compound, for example 2,2 '-sulfo-two (uncle's 4-octyl phenol) Ni salt, (2,2 '-sulfo-two (uncle's 4-octyl group phenates))-n-butylamine Ni and (3, the 5-di-tert-butyl-4-hydroxyl benzyl) phosphonic acids-ethyl ester nickel salt; The vinyl cyanide that replaces, for example alpha-cyano-Beta-methyl-β-(right-p-methoxy-phenyl) methyl acrylate; Oxalyl diphenylamine, for example N '-2-ethylphenyl-N-phenetole oxalamide and N-2-ethylphenyl-N '-2-phenetole oxalamide; And the bulky amine compound, for example sebacic acid two (2,2,6,6-tetramethyl--4-piperidines) ester, it is poly-that ({ (6-(1,1,3, the 3-tetramethyl butyl) imino-)-1,3,5-triazine-2, { 4-(2 for 4-two bases, 2,6, the 6-tetramethyl-piperidyl) imino-} hexa-methylene) and 2-(4-hydroxyl-2,2,6,6-tetramethyl--piperidino) condenses of ethanol and succsinic acid dimethyl esters.

The example of lubricant comprises aliphatic hydrocarbon, for example paraffin and polyethylene wax and Poly Propylene Wax; Higher fatty acid, for example capric acid, lauric acid, tetradecanoic acid, palmitinic acid, margaric acid, stearic acid, eicosanoic acid and mountain Yu acid; The metallic salt that these are sour, for example lithium salts, calcium salt, sodium salt, magnesium salts and sylvite; Aliphatic alcohol class, for example palmityl alcohol, hexadecanol and stearyl alcohol; Aliphatic series acid amides, for example hexanamide, decoylamide, caprin acid amides, laurylamide, myristic amide, palmitic amide and stearylamide; The ester class of lipid acid and alcohol; And fluorochemicals, for example fluoroalkyl carboxylic acid or its metallic salt and fluoroalkyl metal organic sulfonate class.

The content of above-mentioned additive in polypropene composition can be 0.0001 to 10% (weight).

By these additives are added in the composition of the present invention, can be formed on by said composition, for example, the moulded product that is greatly improved of the balance of performance, wearing quality, paintability, impressionability, anti-damageability or each side such as wearability and mould process.

Polypropene composition of the present invention can contain nucleator as mentioned above.

Have no particular limits for nucleator as used herein, can use a variety of commonly known nucleator.In these nucleators, be preferably aromatic phosphate acid ester salt and Sorbitol dibenzal class.

As the aromatic phosphate acid ester salt, can use the compound that is expressed from the next:

R wherein ¹For oxygen, sulphur or contain the alkyl of 1 to 10 carbon atom; R ²And R ³Can be identical or different, respectively be hydrogen or the alkyl that contains 1 to 10 carbon atom; Two R ², two R ³, or R ²And R ³Can be joined together to form ring; M is that monovalence is to trivalent metal atom; N is 1 to 3 integer.

The example of the nucleator of being represented by following formula comprises 2,2 '-methylene radical-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester sodium, 2,2 '-ethylidene-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester sodium, 2,2 '-methylene radical-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester lithium, 2,2 '-ethylidene-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester lithium, 2,2 '-ethylidene-two (4-sec.-propyl-6-tert-butyl-phenyl) phosphoric acid ester sodium, 2,2 '-methylene radical-two (4-methyl-6-tert butyl phenyl) phosphoric acid ester lithium, 2,2 '-methylene radical-two (4-ethyl-6-tert-butyl-phenyl) phosphoric acid ester lithium, two (2,2 '-sulfo-two (4-methyl-6-tert butyl phenyl) phosphoric acid ester) calcium, two (2,2 '-sulfo-two (4-ethyl-6-tert-butyl-phenyl) phosphoric acid ester) calcium, two (2,2 '-sulfo-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester) calcium, two (2,2 '-sulfo-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester) magnesium, two (2,2 '-sulfo-two (uncle's 4-octyl phenyl) phosphoric acid ester) magnesium, 2,2 '-butylidene-two (4, the 6-3,5-dimethylphenyl) phosphoric acid ester sodium, 2,2 '-butylidene-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester sodium, 2,2 '-uncle's octyl group methylene radical-two (4, the 6-3,5-dimethylphenyl) phosphoric acid ester sodium, 2,2 '-uncle's octyl group methylene radical-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester sodium, two (2,2 '-methylene radical-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester) calcium, two (2,2 '-methylene radical-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester) magnesium, two (2,2 '-methylene radical-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester) barium, 2,2 '-methylene radical-two (4-methyl-6-tert butyl phenyl) phosphoric acid ester sodium, 2,2 '-methylene radical-two (4-ethyl-6-tert-butyl-phenyl) phosphoric acid ester sodium, (4,4 '-dimethyl-5,6 '-di-t-butyl-2,2 '-phenylbenzene) phosphoric acid ester sodium, two ((4,4 '-dimethyl-6,6 '-di-t-butyl-2,2 '-xenyl) phosphoric acid ester) calcium, 2,2 '-ethylidene-two (butyl between 4--6-tert-butyl-phenyl) phosphoric acid ester sodium, 2,2 '-methylene radical-two (4, the 6-3,5-dimethylphenyl) phosphoric acid ester sodium, 2,2 '-methylene radical-two (4,6-diethyl phenyl) phosphoric acid ester sodium, 2,2 '-ethylidene-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester potassium, two (2,2 '-ethylidene-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester) calcium, two (2,2 '-ethylidene-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester) magnesium, two (2,2 '-ethylidene-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester) barium, three (2,2 '-methylene radical-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester) aluminium, with three (2,2 '-ethylidene-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester) aluminium, and the mixture of these compounds.Wherein be preferably 2,2 '-methylene radical-two (4, the 6-di-tert-butyl-phenyl) phosphoric acid ester sodium.As nucleator, also can use following aromatic phosphate acid ester salt: R wherein ⁴For hydrogen or contain the alkyl of 1 to 10 carbon atom; M is that monovalence is to trivalent metal atom; N is 1 to 3 integer.These examples for compounds comprise two (4-tert-butyl-phenyl) phosphoric acid ester sodium, two (4-aminomethyl phenyl) phosphoric acid ester sodium, two (4-ethylphenyl) phosphoric acid ester sodium, two (4-isopropyl phenyl) phosphoric acid ester sodium, two (uncle's 4-octyl phenyl) phosphoric acid ester sodium, two (4-tert-butyl-phenyl) phosphoric acid ester potassium, two (4-tert-butyl-phenyl) phosphoric acid ester calcium, two (4-tert-butyl-phenyl) magnesium phosphorate, two (4-tert-butyl-phenyl) phosphoric acid ester lithium and two (4-tert-butyl-phenyl) aluminium phosphate, and the mixture of these compounds.Wherein, be preferably two (4-tert-butyl-phenyl) phosphoric acid ester sodium.

In addition, as nucleator, also can use the benzylidene sorbitol class that is expressed from the next:

R wherein ⁵For hydrogen or contain the hydro carbons of 1 to 10 carbon atom.

These examples for compounds comprise 1,3,2, the 4-Sorbitol dibenzal, 1,3-benzylidene-2,4-is to the methyl benzylidene sorbitol, 1,3-benzylidene-2,4-is to the ethyl benzylidene sorbitol, 1,3-is to methyl benzylidene-2, the 4-benzylidene sorbitol, 1,3-is to ethyl benzylidene-2, the 4-benzylidene sorbitol, 1,3-is to methyl benzylidene-2, and 4-is to the ethyl benzylidene sorbitol, 1,3-is to ethyl benzylidene-2,4-is to the methyl benzylidene sorbitol, 1,3,2,4-two (to the methyl benzylidene) sorbyl alcohol, 1,3,2,4-two (to the ethyl benzylidene) sorbyl alcohol, 1,3,2,4-two (to the n-propyl benzylidene) sorbyl alcohol, 1,3,2,4-two (p-isopropyl benzylidene) sorbyl alcohol, 1,3,2,4-two (to the normal-butyl benzylidene) sorbyl alcohol, 1,3,2,4-two (to the sec-butyl benzylidene) sorbyl alcohol, 1,3,2,4-two (to tertiary butyl benzylidene) sorbyl alcohol, 1,3,2,4-two (2 ', 4 '-dimethyl benzylidene) sorbyl alcohol, 1,3,2,4-two (to the methoxyl group benzylidene) sorbyl alcohol, 1,3,2,4-two (to the oxyethyl group benzylidene) sorbyl alcohol, 1,3-benzylidene-2,4-is to the chlorine benzylidene sorbitol, 1,3-is to chlorine benzylidene-2, the 4-benzylidene sorbitol, 1,3-is to chlorine benzylidene-2,4-is to the methyl benzylidene sorbitol, 1,3-is to chlorine benzylidene-2, and 4-is to the ethyl benzylidene sorbitol, 1,3-is to methyl benzylidene-2,4-is to the chlorine benzylidene sorbitol, 1,3-is to ethyl benzylidene-2, and 4-is to chlorine benzylidene sorbitol and 1,3,2,4-two (to the chlorine benzylidene) sorbyl alcohol, and the mixture of these compounds.Wherein, be preferably 1,3,2,4-Sorbitol dibenzal, 1,3,2,4-two (to the methyl benzylidene) sorbyl alcohol, 1,3,2,4-two (to the ethyl benzylidene) sorbyl alcohol, 1,3-to chlorine benzylidene-2.4-to methyl benzylidene sorbitol, 1,3,2,4-two (to the chlorine benzylidene) sorbyl alcohol and composition thereof.

In addition, operable nucleator also has the metallic salt of aromatic carboxylic acid and aliphatic carboxylic acid.The example comprises aluminum benzoate, p-tert-butyl benzoic acid aluminium, hexanodioic acid sodium, thiophene carboxylic acid's sodium and pyrroles's carboxylic acid sodium.

Also can use mineral compound such as talcum as nucleator.

The content of aforesaid nucleator in polypropene composition of the present invention can be 0.001 to 10% (weight), is preferably 0.01 to 5% (weight), more preferably 0.1 to 3% (weight).

By adding nucleator, the crystallization rate of polypropene composition can improve, and that the crystal grain in the crystallisation process can become is less, can realize that like this high speed is molded.

Other resin as adding in the composition of the present invention can use thermoplastic resin or thermosetting resin.The example of these resins comprises the alhpa olefin homopolymer, for example polyethylene and poly-1-butylene, alpha olefin copolymer, polypropylene, polymeric amide, polycarbonate, ABS resin, polystyrene, polyvinyl chloride, polyphenylene oxides, petroleum resin and resol that the multipolymer of alhpa olefin and vinyl monomer, modified olefine polymer are for example maleic anhydride-modified.

Polypropene composition of the present invention can also contain mineral filler.The example of mineral filler comprises:

Powder filler, for example natural silicic acid or silicate such as fine powder talcum, kaolin, calcined clay, pyrophyllite, silk Muscovitum and wollastonite, carbonate such as precipitated chalk, water-ground limestone and magnesiumcarbonate, oxyhydroxide such as aluminium hydroxide and magnesium hydroxide, oxide compound such as zinc oxide, zinc white and magnesium oxide, and synthetic silicic acid or silicate for example calcium silicate hydrate hydrated aluminium silicate, silicate hydrate and silicic anhydride;

Laminal filler, for example mica;

Bat wool, for example basic magnesium sulfate palpus crystalline substance, calcium titanate palpus crystalline substance, aluminum borate whiskers, sepiolite, PMF (finished mineral fibre), xonotlite, potassium titanate and ellestadite; And

Ball-type packing, for example granulated glass sphere and floating dust globe.

In these fillers, the fine powder talcum is preferred for the present invention.It is desirable to average particulate diameter especially is 0.2 to 3 μ m, especially the fine powder talcum of 0.2 to 2.5 μ m.

The ideal talcum is that the granule content that mean diameter is not less than 5 μ m is not more than 10% (weight), is preferably and is not more than 8% (weight).

The steatitic average particulate diameter can be measured by liquid-phase precipitation method.

In the present invention, talcum is that its mean aspect ratio ratio of thickness (the vertical or horizontal length with) is not less than 3 preferably, especially is not less than 4.

Mineral filler, especially talcum can pass through or be used for the present invention without surface treatment.Surface treatment can be carried out with chemistry and physical method, for example uses treatment agent such as silane coupling agent, higher fatty acid, fatty acid metal salt, unsaturated organic acid, organic titanate, resinous acid and polyoxyethylene glycol.

By using surface-treated mineral filler such as talcum, can obtain the also good polypropene composition of welding strength, paintability and mould process.

Above-mentioned mineral filler can be used in combination.

If desired, organic filler such as high-phenylethylene, xylogen and regenerated rubber can be used in combination with mineral filler.

Above-mentioned polypropene composition of the present invention has good thermotolerance and low temperature heat sealer and snappiness and shock-resistance.This polypropene composition can be used for heat sealable OPP preferably, and injection molded article has for example improved the container of impact strength, stretching-blow-molded article, container, film and the thin slice of the packed food that is used to sterilize.

In addition, polypropene composition of the present invention can be used for other various uses except that above-mentioned.For example, can be used for home appliances the parts for example shell and the bucket of washing machine, for example automotive interior decoration of automobile inner part, inner panel and cover for seat, automobile outer part be splash pan, collision bumper, side moles, splash pan and mirror cover for example, and foreign material commonly used.

Below, be described in detail the polypropylene composite film that contains above-mentioned polypropene composition layer of the present invention.The polypropylene composite film

Polypropylene composite film of the present invention comprises:

(I) crystalline polypropylene layer, and

(II) layer that is generated by polypropene composition of the present invention, it is laminated at least one surface of crystalline polypropylene layer (I).(I) crystalline polypropylene layer

Polypropylene composite film substrate of the present invention is generated by crystalline polypropylene (I).

In the present invention,, can use the polypropylene that is known as film forming material usually, use isotactic index I.I. (the insoluble component of boiling n-heptane) to be not less than 75%, be preferably 75 to 99% polypropylene but be preferably as crystalline polypropylene.

It is 0.89 to 0.92g/cm that crystalline polypropylene is preferably density ³, melt flow index (230 ℃) is 0.1 to 10g/10min person.

Though use homo-polypropylene usually as crystalline polypropylene, also can use and contain a small amount of (for example being not more than 5% (mole)) unitary propylene unregulated polymer from other alkene except that propylene, however influence purpose of the present invention.The example of other alkene comprises the alpha-olefin that contains 2 to 20 carbon atoms except that propylene, for example ethene, 1-butylene, 1-amylene, 1-hexene, 1-heptene, 1-octene, 1-decene, 1-dodecylene, cetene and 4-methyl-1-pentene.

Crystalline polypropylene used among the present invention can use known solid titanium catalyst component or Metallocenic compound catalyst component to be prepared with ordinary method.

Additive such as thermo-stabilizer, ultraviolet absorbers, release agent, surface slip agent and anti-aging agent can be added in the crystalline polypropylene.

In the present invention, the crystalline polypropylene layer can be not tensile or biaxial stretching.(II) polypropene composition layer

The thermal synthesis layer of polypropylene composite film is made by the polypropene composition of the invention described above.

Comprise following (A) polypropylene and (B) composition of propylene-1-butylene random copolymers be suitable especially one of the polypropene composition that forms the polypropylene composite film thermal synthesis layer that is used for.

Polypropylene (A) better is to contain the unitary crystalline polypropylene from propylene that is no less than 90% (mole).

Propylene-1-butylene random copolymers (B) should have following character:

(1) multipolymer contain propylene units quantity be 50-95% (mole), preferably for 55-93% (mole), best for 60-90% (mole), contained 1-butylene element number be 5-50% (mole), preferably be 7-45% (mole), be 10-40% (mole) best.

(2) limiting viscosity (η) 0.1-5 dl/g, preferably at 0.5-4 dl/g, best between 1-3 dl/g.

(3) molecular weight distribution (Mn/Mw) is not more than 3, is not more than 2.5 preferably.

(4) randomness B parameter value 1.0-1.5, preferably at 1.0-1.3, best between 1.0-1.2.

(5) fusing point of measuring with differential scanning calorimeter is between 60-140 ℃, preferably at 80-120 ℃, best between 90-110 ℃.

(6) degree of crystallinity of measuring with the X-ray diffraction method preferably at 15-65%, better between 20-60%.

In addition, propylene-butene-1 copolymer contained with 2 of propylene, 1-be inserted as the basis the unitary amount of regional irregularity be no less than 0.05%.

The polypropene composition that is used to form polypropylene composite film thermal synthesis layer of the present invention contains propylene-1-butylene random copolymers (B) that above-mentioned character is arranged, so it has shown fabulous heat seal character.For example, if greater than 5dl/g, the moldability of composition may reduce limiting viscosity (being all character of aforesaid propylene-butene-1 copolymer (2)), therefore may be difficult to form the thermal synthesis layer of desired thickness (as being not more than 50 microns).Less than 0.1dl/g, heat sealing strength can be lowered as limiting viscosity (η).

If fusing point (being above character (5)) surpasses 140 ℃, heat seal may need high temperature, as is not less than 130 ℃.If fusing point is lower than 60 ℃, low temperature heat seal performance can be enhanced, but resistance to marring can be lowered, and the adhesion of obtained film may take place in storage process, and the result is difficult to actual use.

Because can obtain the fabulous and high film of resistance to blocking of low temperature heat seal character, degree of crystallinity is that propylene-butene-1 copolymer of 15-65% is preferred.If degree of crystallinity is lower than 15%, the resistance to marring of gained film can be not enough, can stick together and bond.If degree of crystallinity greater than 65%, just can not fully improve low temperature heat seal character.

In the present invention, also available partly or entirely with unsaturated carboxylic acid or its anhydride modified propylene-1-butylene random copolymers.The outer packaging of the modified product of propylene-1-butylene random copolymers and with binding property as the other materials of metal and so on be fabulous.

In polypropylene composite film of the present invention, thermal synthesis layer (II) is made by the polypropene composition that contains polypropylene (A) and propylene-1-butylene random copolymers (B).Component (A) and the visual purposes of consumption (B) and suitably determine in addition.

For example, in the present invention, the polypropene composition of the available 5-50% of containing of the thermal synthesis layer of polypropylene composite film (II) (weight) polypropylene (A) and 95-50% (weight) propylene-1-butylene random copolymers is made.

It is fabulous to can be made into not only the transparency, low temperature heat sealer and heat-blocking by component that contains above-mentioned amount (A) and polypropene composition (B), and smooth property and the polypropylene composite film (1) also fabulous as the physical strength of resistance to blocking and resistance to marring and so on.

The thermal synthesis layer of polypropylene composite film of the present invention (II) also can be no less than 50% (weight) but is less than 90% (weight) polypropylene and is no less than 10% (weight) but the polypropene composition that is less than 50% (weight) propylene-1-butylene random copolymers is made by containing.

By component that contains above-mentioned amount (A) and polypropene composition (B) can be made into not only the transparency and the low temperature heat sealer fabulous, and the polypropylene composite film also fabulous (2) as the physical strength of resistance to blocking and scratch resistance and so on.

In polypropylene composite film of the present invention, if the amount of crystalline polypropylene (A) surpasses 90% (weight) in the polypropene composition, the softening temperature of film raises significantly, and the low temperature heat sealer is reduced significantly.If its amount is less than 5% (weight), the resistance to blocking of film and resistance to marring can be lowered.

Polypropylene composite film of the present invention comprises crystalline polypropylene (I) and polypropene composition thermal synthesis layer (II), and thermal synthesis layer (II) can be compounded in one or two surface as the crystalline polypropylene layer (I) of liner.

The crystalline polypropylene layer (I) that in polypropylene composite film of the present invention, is used as liner can be non-tensile, uniaxial drawing or biaxial stretching.One or two surface of liner (I) is gone up available ordinary method and is carried out Corona discharge Treatment.

Laminated film of the present invention for example can make with crystalline polypropylene (I) and polypropene composition (II) as follows.

(1) crystalline polypropylene (I) is become laminate with polypropene composition (II) co-extrusion.

This laminate can be at vertical or side direction single shaft to being stretched, or can be on vertical or side direction respectively or simultaneously twin shaft to being stretched.

(2) crystalline polypropylene (I) melt extrusion is become film (liner), then with polypropene composition (II) melt extrusion at its surperficial form layers laminated sheet.

This laminate can be at vertical or side direction single shaft to being stretched, or can distinguish on vertical or side direction or biaxial stretching simultaneously.

(3) become liner with crystalline polypropylene (I) melt extrusion, and in vertical or side direction uniaxial drawing.On the liner of uniaxial drawing, melt extrusion polypropene composition (II) or carry out lamination with preformed polypropene composition (II) film.The gained laminate stretches on the non-stretching direction of liner again.

(4), and vertically becoming liner respectively or simultaneously with the side direction biaxial stretching with crystalline polypropylene (I) melt extrusion.On the liner that biaxial stretching is crossed, melt extrusion polypropene composition (II) or carry out lamination with preformed polypropene composition (II) film.

(5) with tackiness agent crystalline polypropylene (I) film and polypropene composition (II) film laminating are in the same place.The gained laminate can uniaxial drawing on vertical or side direction, or can be at the same time or separately at biaxial stretching vertically and on the side direction.

In polypropylene composite film of the present invention, the thickness of crystalline polypropylene (I) layer is the 5-200 micron, is the 10-60 micron preferably, and the thickness of polypropene composition (II) layer is the 0.1-50 micron, is the 0.5-20 micron preferably.

In laminated film of the present invention, when the liner of making when crystalline polypropylene (I) is stretched, longitudinal stretching than for 3-7 doubly, be preferably 4-6 doubly, the side direction stretch ratio be 3-12 doubly, be 6-10 times preferably.The invention effect

The thermotolerance of polypropene composition of the present invention, low temperature heat sealer, snappiness and shock-resistance all are fabulous.Polypropene composition is suitable for injection-molded item, stretch blow goods, retort food container, film and the sheet material as higher container of heat sealable OPP, shock-resistance and so on.

In addition, polypropene composition of the present invention can be used for such use various uses in addition.For example, it can be used for as the shell of washing machine and pipe and so on household appliance components, as interior decoration, inner panel board and jociey stick and so on automotive interior parts.Automobile external part and sundry goods commonly used as protective shield, vibroshock, side moles, splash pan and Jing Gai and so on.

The heat sealer of the polypropylene composite film of the present invention of band polypropene composition thermal synthesis layer is fabulous.Particularly, film can be in wide temperature range, heat seal especially at low temperatures, and have high heat sealing strength.In addition, even polypropylene composite film is stored for some time, its heat-seal temperature can not become in time yet, therefore can guarantee stable heat seal operation.

In addition, because the fabulous transparency, resistance to marring and resistance to blocking are arranged, polypropylene composite film of the present invention can be used for high-speed packaging.

According to the present invention, can make the polypropylene composite film that except that above-mentioned excellent performance, also has good thermal viscosity.

Suitable food product pack, packing and the fiber packing of serving as of polypropylene composite film of the present invention.

Embodiment

The present invention is further described with reference to following embodiment, but should not think, the present invention is confined to these embodiment.

The measurement of propylene-1-butylene random copolymers (B) character

(1) propylene content and 1-butylene content: measure with 13C-NMR.

(2) limiting viscosity (η):

In 135 ℃ perhydronaphthalene, measure and represent with dl/g.

(3) molecular weight distribution (Mw/Mn):

The GPC-150C that produces with Millipore Co. measures as follows.

Using diameter is that 27 millimeters and length are 600 millimeters TSK-GNH-HT separator column.Column temperature is set in 140 ℃.Used moving phase for contain 0.025% (weight) BHT (available from Takeda Chemical Industries, the Ltd) neighbour-toluene dichloride of oxidation inhibitor (available from Wako Junyaku Kogyo K.K.), flow rate is 1.0ml/min.500 microlitre 0.1% (weight) sample solutions are introduced this post.Differential refractometer is as detecting meter.

Available from Toso Co., the polystyrene of Ltd. is as Mw＜1,000 and Mw＞4 * 10 ⁶Molecular weight standard, available from the polystyrene of Pressure Chemical Co. as 1,000＜Mw＜4 * 10 ⁶Molecular weight standard.

(4) B value (monomer distribution)

Measure the homogeneous phase sample solution of 200 milligrams of multipolymers in 1 milliliter of hexachlorobutadiene ¹³C NMR spectrum, the diameter of used sample tube are 10 millimeters, and used measuring condition is generally: temperature is 120 ℃, and frequency is 25.05MHz, spectrum width is 1,500Hz, and filter width is 1,500Hz, the pulse reproduction time is that 4.2 seconds, integral time are 2,000-5,000.From spectrum, can find out P _E, Po and Po _E, use P _E, Po and Po _ECalculate the B value.

(5) fusing point (Tm):

Fusing point is measured with the DSC-7 type survey meter that Perkin Elmer Co. produces as follows.About 5 milligrams of samples that are contained in the aluminium dish are heated to 200 ℃, kept 5 minutes, be cooled to-40 ℃ with 10 ℃/minute speed then, again with 10 ℃/minute speed heating, to obtain the exotherm of sample at 200 ℃.Can determine fusing point (Tm) by exotherm.

(6) degree of crystallinity:

The degree of crystallinity available thickness is that the X-diffraction spectra of 1.0 millimeters compressing tablet determines that compressing tablet stores at least 24 hours after compacting.

(7) three unit tacticitys

Measurement sample hexachlorobutadiene solution ¹³C-NMR spectrum (tetramethylsilane standard) calculates the ratio (%) of peak area that occurs and the peak area (100%) that occurs in the 19.5-21.9ppm scope in the 21.0-21.0ppm scope.

(8) by 2,1-inserts the heterodesmic ratio of calculating: with reference to " Polymer ", and 30,1350 (1989), use ¹³C-NMR spectrum is measured as stated above.

Polypropylene used in embodiment 1 to 6 and Comparative Examples 1 and 2 and propylene-1-butylene random copolymers is described below.

In embodiment and Comparative Examples, use following polypropylene with general solid titanium catalyst component preparation.

Polypropylene-1: alfon (limiting viscosity (η): 2.9dl/g, the DSC fusing point: 164 ℃, degree of crystallinity: 62%).

Polypropylene-2: the random homopolymer of propylene (composition: propylene=96.4% (mole), ethene=2.1% (mole), 1-butylene=1.5% (mole), limiting viscosity (η): 2.1dl/g, the DSC fusing point: 142 ℃, degree of crystallinity: 56%).

Next, the synthetic embodiment of synthetic catalyst component and use the preparation embodiment for preparing propylene-1-butylene random copolymers (B) by same procedure synthetic catalyst component among the synthetic embodiment is described.The character of the propylene-1-butylene random copolymers (PBR) that obtains in preparation embodiment is listed in table 2.

Synthetic embodiment 1 racemize-dichloro-dimethyl silicylene-two (1-(2-ethyls-4-phenyl indenyl)) close synthetic 3-(2-xenyl)-2-propionic acid ethyl synthetic of zirconium:

In 500 milliliter of four neck round-bottomed flask (agitator, Dimroth condenser, dropping funnel and thermometer are housed), add 13.46 gram (120 mmole) tert.-butoxy potassium, 100 milliliters of toluene and 20 milliliters of N-Methyl pyrrolidone, in nitrogen atmosphere, drip the solution of 20.7 gram (110 mmole) ethyl malonic acid diethylesters in 50 milliliters of toluene then, and be heated to 60 ℃.After dripping, mixture reacted 1 hour under uniform temp, dripped the solution of 20.27 gram (100 mmole) 2-phenylbenzyl bromines in 30 milliliters of toluene then under uniform temp, and after dripping, heated mixt also refluxed 2 hours.Reaction mixture is injected 200 ml waters, and add 2NHCl with pH regulator to 1 with mixture.Separate organic phase, water extracts three times with 100 milliliters of toluene.The organic phase that merges to being neutral, is used anhydrous sodium sulfate drying with the saturated brine solution washing then.Under reduced pressure remove and desolvate, obtain 36.7 gram yellowish-orange liquid concentrates.

In 1 liter of four neck round-bottomed flask (agitator, Dimroth condenser, dropping funnel and thermometer are housed), add 67.3 gram (1.02 moles) potassium hydroxide and the 160 ml methanol aqueous solution (methanol=4/1 (v/v)), in nitrogen atmosphere He under the room temperature, be added dropwise to the solution of the above-mentioned enriched material that obtains in the 50 ml methanol aqueous solution (methanol=4/1 (v/v)) then.After dripping, heated mixt also refluxed 4 hours, was cooled to room temperature then, the elimination precipitated solid.Solid is dissolved in the water, adds sulfuric acid in the solution until acid (pH=1).This solution is with 100 milliliters of dichloromethane extractions five times.The organic phase anhydrous sodium sulfate drying that merges, decompression removes down and desolvates then, obtains 24.2 gram white solid product.

Next, in 300 milliliter of four neck round-bottomed flask (agitator, Dimroth condenser and thermometer are housed), add above-mentioned white solid, 56 milliliter acetate, 37 ml waters and the 13.1 milliliters of vitriol oils of 24.2 grams, in nitrogen atmosphere, mixture was refluxed 6 hours.After the reaction, under reduced pressure boil off acetate, add 50 ml waters, this mixture is with 50 milliliters of dichloromethane extractions three times.The organic phase that merges is washed with 50 milliliters of saturated brine solutions, and uses anhydrous sodium sulfate drying.Under reduced pressure boil off solvent then, resistates is with the silica gel chromatography purifying, and hexane/ethyl acetate gradient elution (2/1-1/1 volume) obtains 13.7 gram white solid (productive rates: 54%).The character of the product that so obtains is expressed as follows:

FD-MS：254(M ⁺)

mp.：91.2-94.0℃

NMR(CDCl ₃，90Hz)：

δ＝0.71(t，J＝7.2Hz，3H，CH ₃)；

1.16-1.58(m，2H)；

2.32(bquin，J＝7.0Hz，1H，＞CH-)；

2.61-2.99(m，2H)；6.89-7.47(m，9H).

IR (KBr sheet): 1696cm ^-1(V _C=0) 3-(2-xenyl)-2-ethyl propionyl chloride synthetic

In 100 milliliter of three neck round-bottomed flask (agitator, Dimroth condenser, thermometer and sodium hydroxide trap are housed), add 13.3 gram (52.4 mmole) 3-(2-xenyl)-2-propionic acid ethyl and 25.9 milliliters of (355 mmole) thionyl chloride, and in nitrogen atmosphere reflux 2.5 hours.After reaction is finished, boil off unreacted thionyl chloride under the decompression, obtain the orange-yellow liquid crude product of 15.2 grams.This acyl chlorides need not further purification and just can be used for next step reaction.The character of this product is expressed as follows:

IR (pure): 1786cm ^-1(V _C-o).4-ethyl-2-phenyl-2,3-bihydrogen-1-indenone synthetic:

In 200 milliliter of three neck round-bottomed flask (agitator, Dimroth condenser, dropping funnel, thermometer and sodium hydroxide trap are housed), add 8.04 gram (60.3 mmole) Aluminum chloride anhydrous and 50 milliliters of dithiocarbonic anhydride, then at nitrogen atmosphere and ice-cooled 15.2 gram (52.4 mmole) above-mentioned 3-that obtains (2-the xenyl)-solution of 2-ethyl propionyl chloride in 21 milliliters of dithiocarbonic anhydride that are added dropwise to down.After dripping, temperature in the reaction flask is increased to room temperature, reacted one hour.Reaction soln is poured in 200 milliliters of frozen water then, decomposed unreacted aluminum chloride, with 100 milliliter ethers extraction secondary.The organic phase that merges is washed with 100 milliliters of saturated sodium bicarbonate aqueous solutions, with 100 milliliters of saturated brine solution washings, uses anhydrous sodium sulfate drying more then.Boil off solvent under the decompression, resistates with hexane/ethyl acetate (volume ratio is 10/1), obtains the required product of 10.8 grams with the silica gel chromatography purifying, is yellow solid (productive rate is 88%).The character of products therefrom is expressed as follows:

NMR(CDCl ₃，90Hz)：

δ＝0.98(t，J＝7.2Hz，3H，CH ₃)；

1.60-2.20(m，2H)；

2.42-2.82(m，1H，＞CH-)；

2.80(dd，J＝3.8Hz，16.5Hz，1H)；

3.36(dd，J＝7.6Hz，16.5Hz，1H)；

7.09-7.91(m，8H).

IR (KBr is pure): 1705cm ^-1(V _C=O) 2-ethyl-1-hydroxy-4-phenyl-2,3-indane synthetic

In 200 milliliter of three neck round-bottomed flask (agitator, Dimroth condenser, dropping funnel, thermometer and sodium hydroxide trap are housed), add 0.85 gram (22.6 mmole) sodium borohydride and 28 milliliters of ethanol, then under nitrogen atmosphere and room temperature, be added dropwise to 10.6 gram (45.1 mmole) 2-ethyl-4-phenyl-2, the solution of 3-bihydrogen-1-indenone in 20 milliliters of ethanol.After dripping, temperature is elevated to 50 ℃, reacted again 3.5 hours.After the reaction,, be added dropwise to acetone, to decompose unreacted sodium borohydride with the mixture cooling.Concentrating under reduced pressure reaction mixture then, and with 50 ml waters and 50 milliliters of ethers extractions.Separate organic phase, water extracts secondaries with 50 milliliters of ethers.The organic phase that merges is washed with 100 milliliters of saturated brine solutions, and uses anhydrous sodium sulfate drying.Under reduced pressure boil off solvent then and obtain 10.67 gram target products (two kinds of mixture of isomers), be viscosity weak yellow liquid (productive rate is 99%).The property description of products therefrom is as follows:

NMR(CDCl ₃，90Hz)：

δ＝1.02(t，J＝7.1Hz，3H，CH ₃)；

1.31-3.28(m，2H)；

4.86,5.03 (each d, each J=6.4Hz, J=5.1

Hz is total to 1H,＞CH-O-);

7.10-7.66(m，8H).

IR (KBr is pure): 3340cm ^-1(V _OH) 2-ethyl-4-phenylindan synthetic

In 300 milliliter of four neck round-bottomed flask (agitator, dropping funnel, thermometer are housed), add 9.78 gram (41.3 mmole) 2-ethyl-1-hydroxy-4-phenyls-2,3-indane, 17.2 milliliters of (123.8 mmole) triethylamines, 0.25 gram (2.1 mmole) 4-Dimethylamino pyridine and 98 milliliters of methylene dichloride, under nitrogen atmosphere and frozen water cooling, be added dropwise to the solution of 6.4 milliliters of (82.5 mmole) methylsulfonyl chlorides in 6.5 milliliters of methylene dichloride at leisure then.After dripping, under uniform temp, reacted again 3.5 hours.Reaction mixture is poured in the 250 milliliter frozen water, separated organic phase, water is with 50 milliliters of dichloromethane extraction secondaries.The organic phase that merges is washed with sodium bicarbonate aqueous solution, then with the saturated brine solution washing, and uses anhydrous sodium sulfate drying.Under reduced pressure boil off solvent then, resistates carries out purifying with hexane with silica gel chromatography, obtains 6.56 gram target products (mixture of isomers), is weak yellow liquid (productive rate is 73%).The property description of products therefrom is as follows:

NMR(CDCl ₃，90Hz)：

δ＝1.20(t，J＝7.6Hz，3H，CH ₃)；

2.49(q，J＝7.6Hz，2H)；

3.41(s，2H)；

6.61,6.72 (each bs, 1H altogether);

7.09-8.01 (m, 8H). synthesizing of dimethylated methylene silylation-two (2-ethyl-4-phenylindan)

In 200 milliliter of three neck round-bottomed flask (agitator, Dimroth condenser, dropping funnel and thermometer are housed), add 5.0 gram (22.8 mmole) 2-ethyl-4-phenylindan, 80 milligrams of (0.63 mmole) cupric thiocyanides and 50 milliliters of anhydrous ethers, then at nitrogen atmosphere and the ice-cooled solution (concentration be 1.6M) of 15.7 milliliters of (25.1 mmole) butyllithiums in hexane that is added dropwise at leisure down.After dripping,, be increased to room temperature, reacted again one hour reaction mixture.Drip the solution of 1.52 milliliters of (12.6 mmole) dimethyldichlorosilane(DMCS)s in 4.5 milliliters of anhydrous ethers then at leisure.After dripping, at room temperature reacted again 12 hours.Reaction mixture filters with diatomite (Celite), and filtrate is poured in 50 milliliters of saturated aqueous ammonium chlorides.Separate organic phase, water extracts with 50 milliliters of ethers.The organic phase that merges is washed with saturated brine solution, and uses anhydrous sodium sulfate drying.Under reduced pressure boil off solvent then, resistates separates with silica gel chromatography with hexane to hexanes/ch gradient elution (volume ratio is 20/1), obtains 4.5 gram target products (mixture of isomers), is faint yellow solid (productive rate is 80%).The property description of products therefrom is as follows:

NMR(CDCl ₃，90Hz)：

δ=-0.23 ,-0.17 (each s, common 6H, Si-CH ₃); 1.12,1.

19 (each t, each J=7.4Hz, common 6H, CH ₃);

2.44(bq，J＝7.4Hz，4H)；

3.81(s，2H，＞CH-Si-)；

6.75(bs，2H，3-H-Ind)；

6.88-7.74 (m, 16H). racemize-two chloro-dimethylated methylene silylation-two (1-(2-ethyl-4-phenyl indenyl)) closes the synthetic of zirconium:

In 50 milliliter of three neck round-bottomed flask (agitator, pearl condenser, dropping funnel and thermometer are housed), add 0.84 gram (1.69 mmole) dimethylated methylene silylation-two (1-(2-ethyl-4-phenylindan)) and 17 milliliters of anhydrous ethers, at room temperature be added dropwise to the solution (concentration: 1.58M) of 2.25 milliliters of (3.56 mmole) n-Butyl Lithiums in hexane then at leisure.After dripping, reacted 13.5 hours again, reaction soln is cooled to-70 ℃ in dry ice/acetone batch, add 0.395 gram (1.69 mmole) zirconium tetrachloride powder in batches, the mixture of gained stirs and spends the night.Under room temperature and decompression, boil off solvent then, add 30 milliliters of methylene dichloride, the elimination insolubles.Filtrate at room temperature concentrates, to be settled out solid, sedimentation and filtration come out, and with 3 milliliters of anhydrous ether washing secondaries, and drying under reduced pressure, obtain 0.17 gram target product, be yellowish-orange solid (productive rate: 15%).The property description of products therefrom is as follows:

NMR(CDCl ₃，90MHz)：

δ＝1.09(t，J＝7.3Hz，6H，CH ₃)；

1.34(s，6H，Si-CH ₃)；

2.46(quin，J＝7.3Hz，2H)；

2.73(quin，J＝7.3Hz，2H)；

6.96(s，2H，3-H-Ind)；

6.99-7.88 (m, 16H). the preparation of preparation embodiment 1PBR-1

In 2 liters of autoclaves that the thorough purge with nitrogen is crossed, add 900 milliliters of hexanes and 60 gram 1-butylene, add 1 mmole triisobutyl aluminium again.The temperature of system is increased to 70 ℃, feeds propylene, make total pressure reach 7kg/cm ²-G adds 0.30 mmole methylaluminoxane and 0.001 mmole (in zirconium atom) again and closes zirconium by racemize-two chloro-dimethylated methylene silylation-two (1-(the 2-methyl-4-phenyl indenyl)) that are similar to the method preparation among the above-mentioned synthetic embodiment.When continuous feeding propylene makes total pressure remain on 7kg/cm ²Under-the G, carry out 30 minutes polyreactions.After polyreaction is finished, autoclave is discharged, with a large amount of Methanol Recovery polymkeric substance.And under 110 ℃ of vacuum dry 12 hours.

The amount of resulting polymers (propylene-1-butylene random copolymers) is 39.7 grams, and polymerization activity is 79 kilograms of polymkeric substance/mmole zirconium hour.The 1-butylene content of this polymkeric substance is 26.4% (mole), and limiting viscosity (η) is 1.60dl/g, and fusing point is 88.4 ℃.With 2, the heterodesmic ratio that 1-is inserted as the basis is about 0.02%.Other character of polymkeric substance are listed in table 2.The preparation of preparation embodiment 2PBR-2

In 2 liters of autoclaves that the thorough purge with nitrogen is crossed, add 900 milliliters of hexanes and 60 gram 1-butylene, add 1 mmole triisobutyl aluminium again.The temperature of system is increased to 70 ℃, feeds propylene, make total pressure reach 7kg/cm ²-G adds 0.30 mmole methylaluminoxane and 0.001 mmole (in zirconium atom) again and closes zirconium by racemize-two chloro-dimethylated methylene silylation-two (1-(the 2-methyl-4-phenyl indenyl)) that are similar to the method preparation among the above-mentioned synthetic embodiment.When continuous feeding propylene makes total pressure remain on 7kg/cm ²Under-the G, carry out 30 minutes polyreactions.After polyreaction is finished, autoclave is discharged, with a large amount of Methanol Recovery polymkeric substance.And under 110 ℃ of vacuum dry 12 hours.

The amount of resulting polymers (propylene-1-butylene random copolymers) is 45.2 grams, and polymerization activity is 90 kilograms of polymkeric substance/mmole zirconium hour.The 1-butylene content of this polymkeric substance is 20.2% (mole), and limiting viscosity (η) is 1.90dl/g, and fusing point is 101.5 ℃.With 2, the heterodesmic ratio that 1-is inserted as the basis is about 0.02%.The preparation of preparation embodiment 3PBR-3

In 2 liters of autoclaves that the thorough purge with nitrogen is crossed, add 950 milliliters of hexanes and 30 gram 1-butylene, add 1 mmole triisobutyl aluminium again.The temperature of system is increased to 70 ℃, feeds propylene, make total pressure reach 7kg/cm ²-G adds 0.30 mmole methylaluminoxane and 0.001 mmole (in zirconium atom) again and closes zirconium by racemize-two chloro-dimethylated methylene silylation-two (1-(the 2-methyl-4-phenyl indenyl)) that are similar to the method preparation among the above-mentioned synthetic embodiment.When continuous feeding propylene makes total pressure remain on 7kg/cm ²Under-the G, carry out 30 minutes polyreactions.After polyreaction is finished, autoclave is discharged, with a large amount of Methanol Recovery polymkeric substance.And under 110 ℃ of vacuum dry 12 hours.

The amount of resulting polymers (propylene-1-butylene random copolymers) is 52.1 grams, and polymerization activity is 104 kilograms of polymkeric substance/mmole zirconium hour.The 1-butylene content of this polymkeric substance is 13.9% (mole), and limiting viscosity (η) is 2.51dl/g, and fusing point is 116.3 ℃.With 2, the heterodesmic ratio that 1-is inserted as the basis is about 0.02%.The preparation of preparation Comparative Examples 1PBR-4

In 2 liters of autoclaves that the thorough purge with nitrogen is crossed, add 830 milliliters of hexanes and 100 gram 1-butylene, add 1 mmole triisobutyl aluminium again.The temperature of system is increased to 70 ℃, feeds propylene, make total pressure reach 7kg/cm ²-G adds 1 mmole triethyl aluminum and 0.005 mmole (in titanium atom) again and loads on titanium catalyst on the magnesium chloride.When continuous feeding propylene makes total pressure remain on 7kg/cm ²Under-the G, carry out 30 minutes polyreactions.After polyreaction is finished, autoclave is discharged, with a large amount of Methanol Recovery polymkeric substance.And under 110 ℃ of vacuum dry 12 hours.

The amount of resulting polymers (propylene-1-butylene random copolymers) is 33.7 grams, and polymerization activity is 14 kilograms of polymkeric substance/mmole zirconium hour.The 1-butylene content of this polymkeric substance is 25.3% (mole), and limiting viscosity (η) is 1.89dl/g, and fusing point is 110.0 ℃.With 2, the heterodesmic ratio that 1-is inserted as the basis is lower than detection limit.

Table 2

		1-butylene content (mole %)	Limiting viscosity (η) (dl/g)	Fusing point (℃)	Degree of crystallinity (%)	Tacticity	??Mw/Mn	The B value
									Preparation embodiment 1	?PBR-1	?????13.9	????2.51	??116.3	???56	??100	????1.9	??1.0
Preparation embodiment 2	?PBR-2	?????20.2	????1.90	??101.5	???50	??100	????2.0	??1.0
									Preparation embodiment 3	?PBR-3	?????26.4	????1.60	??88.4	???40	??100	????2.0	??1.0
Preparation Comparative Examples 4	?PBR-4	?????25.3	????1.89	?110.0	???48	??100	????3.5	??0.94

PBR ... propylene-1-butylene random copolymers embodiment 1-6

Polypropylene-1 is melted in extruding machine, under 250 ℃ of resin temperatures, push through the T-die head then, and hardening by cooling is in blocks.With the roller of this sheet,, reach 5 times until stretch rate to carry out longitudinal stretching by heating.The result has formed the uniaxial drawing sheet of polypropylene-1 (crystalline polypropylene).

On a surface of the uniaxial drawing sheet liner of crystalline polypropylene, respectively polypropene composition listed in the table 3 is carried out lamination as follows.

Polypropene composition listed in the table 3 fusion in another extruding machine is kneaded, under 230 ℃ resin temperature, extrude the melt composition film, make it to be laminated on the substrate by another T-die head.The gained laminate continuously by the tenter machine (tenter) of heating, is carried out side direction and stretched, make stretch rate reach 10 times.The result obtains comprising the laminated film of the polypropene composition layer (thickness: 3 microns) of the crystalline polypropylene liner (thickness: 22 microns) of biaxial stretching and uniaxial drawing.

The laminated film of gained is assessed as follows, the results are shown in table 3.

(1) heat sealing strength

The laminated film of each embodiment gained is used as sample.

Two kinds of laminated films of being made by polypropene composition and tensile homo-polypropylene respectively are superimposed together in the relative mode in polypropene composition side, and be 5 millimeters heat combined roller, 1 second of hot pressing under the pressure of 2 kg/cm and differing temps with width with it, allow it place cooling then.It is 15 millimeters sample that the thermal synthesis layer press mold of every kind of gained is cut into width, with the heat seal part of the crossbeam speed peel test specimen of 20 mm/min, to measure stripping strength.The heat-seal temperature that produces/15 millimeters peel strength value of 300 grams is decided to be minimum effective heat sealable temperature.

(2) optical haze degree

In 50 ℃ of baking ovens, will wear out one day by the film that ASTMD1003 makes.Measure the optical haze degree of aging front and back.

(3) smooth property

In 50 ℃ of baking ovens, will wear out one day by the film that ASTMD1894 makes.Measure the statics and the kinetic coefficient of the friction of aging front and back.

(4) resistance to blocking

Assess by ASTMD1893.To be cut into width in order to the film sample of measuring heat sealing strength (1) and be 10 centimetres, length and be 15 centimetres sample.Two samples are superimposed in the relative mode in polypropene composition side, and put it between two sheet glass.Allow two samples of band sheet glass in 50 ℃ baking oven, place and apply 10 kilograms load.Take out sample after one day, measure stripping strength with universal tester.The stripping strength of each centimetre is decided to be resistance to blocking.Comparative Examples 1-2

Except that with the polypropene composition listed in the table 3, make laminated film by embodiment 1 identical method.The results are shown in table 3.

Table 3

	Composition (weight ratio)	Minimum effective heat-seal temperature (℃)	Optical haze degree (%)	Smooth property *	Resistance to blocking (g/cm)
						Embodiment 1	??PBR-1/PP-2 ???(75/25)	??????110	???0.8	????0.28/0.28	????0.1
Embodiment 2	??PBR-2/PP-2 ???(75/25)	??????100	???0.6	????0.32/0.31	????0.2
						Embodiment 3	??PBR-3/PP-2 ???(75/25)	??????88	????1.4	????0.99/0.51	????0.9
Comparative Examples 1	??PBR-4/PP-2 ???(75/25)	??????100	????1.7	????3.23/1.02	????2.6
						Embodiment 4	??PBR-1/PP-2 ???(50/50)	??????118	????0.6	????0.29/0.29	????0.1

Embodiment 5	??PBR-2/PP-2 ???(50/50)	??108	?0.5	??0.34/0.30	????0.2
						Embodiment 6	??PBR-3/PP-2 ???(50/50)	??95	?0.8	??0.27/0.27	????0.4
Comparative Examples 2	??PBR-4/PP-2 ???(50/50)	??105	?2.5	??0.37/0.32	????0.8

PBR ... propylene-1-butylene random copolymers PP ... polypropylene * ... static friction coefficient/kinetic friction coefficient

Measure the character of the propylene laminated film that in following embodiment, makes as follows.

(1) optical haze degree

Pressing ASTMD1003 measures.

(2) the optical haze degree over time

Laminated film kept 3 days down at 80 ℃, and allowed it place cooling.Then by test (1) identical method measuring light mist degree.

(3) glossiness

Pressing ASTM D523 measures.(4) tear strength (Elmendorf tear strength)

Pressing ASTM D1922 measures.

(5) smooth property

Pressing ASTM D1894 measures.

(6) smooth property over time

Laminated film keeps a week down at 40 ℃, and allows it place cooling.Measure smooth property by test (5) identical method then.

(7) resistance to blocking

Pressing ASTM D1893 measures.

(8) resistance to blocking over time

Laminated film keeps a week down at 50 ℃, and allows it place cooling.Measure the adhesion tendency by the identical method of test (7) then.

(9) heat sealing strength

Two kinds of laminated films are superimposed together with polypropene composition layer (II) relative mode, and are 5 millimeters heat combined roller, 1 second of hot pressing under the pressure of 2 kg/cm and the differing temps shown in the table 4 with width, allow it place cooling then it.

It is 15 millimeters sample that the sample of heat seal under each temperature is cut into width, with the heat seal part of the crossbeam speed peel test specimen of 300 mm/min, to measure stripping strength.

(10) thermal viscosity

Two kinds of laminated films are superimposed together in the relative mode of polypropene composition layer (II), and, under the loads of 45 grams, measure the peel distance of heat seal part then its 1 second of hot pressing under the pressure of 2 kg/cm and the differing temps shown in the table 4.The preparation of preparation embodiment 5PBR-5

In 2 liters of autoclaves that the thorough purge with nitrogen is crossed, add 900 milliliters of hexanes and 60 gram 1-butylene, add 1 mmole triisobutyl aluminium again.The temperature of system is increased to 70 ℃, feeds propylene, make total pressure reach 7kg/cm ²-G adds 0.30 mmole methylaluminoxane and 0.001 mmole (in zirconium atom) racemize-two chloro-dimethylated methylene silylation-two (1-(2-methyl-4-phenyl indenyl)) again and closes zirconium.When continuous feeding propylene makes total pressure remain on 7kg/cm ²Under-the G, carry out 30 minutes polyreactions.After polyreaction is finished, with autoclave emptying, with a large amount of Methanol Recovery polymkeric substance.And 110 ℃ of vacuum-dryings 12 hours.

The amount of resulting polymers (propylene-1-butylene random copolymers) is 39.7 grams, and polymerization activity is 79 kilograms of polymkeric substance/mmole zirconium hour.The 1-butylene content of this polymkeric substance (propylene-1-butylene random copolymers) is 24% (mole), and limiting viscosity (η) is 1.63dl/g, and fusing point is 92 ℃.The character of this polymkeric substance is listed in table 4.

Preparation embodiment 6-7

Listed propylene-1-butylene random copolymers is to make by preparing embodiment 5 identical methods except the consumption that changes hexane, 1-butylene and propylene in table 4 and the table 5.

Preparation Comparative Examples 8

In 2 liters of autoclaves that the thorough purge with nitrogen is crossed, add 830 milliliters of hexanes and 100 gram 1-butylene, add 1 mmole triisobutyl aluminium again.The temperature of system is increased to 70 ℃, feeds propylene, make total pressure reach 7kg/cm ²-G adds 1 mmole triethyl aluminum and 0.005 mmole (in titanium atom) again and loads on titanium catalyst on the magnesium chloride.When continuous feeding propylene makes total pressure remain on 7kg/cm ²Under-the G, carry out 30 minutes polyreactions.After polyreaction is finished, autoclave is discharged sky, with a large amount of Methanol Recovery polymkeric substance.And 110 ℃ of vacuum-dryings 12 hours.

The amount of resulting polymers is 33.7 grams, and polymerization activity is 14 kilograms of polymkeric substance/mmole titanium hour.

The 1-butylene content of this polymkeric substance is 23% (mole), and limiting viscosity (η) is 1.91dl/g, and fusing point is 110 ℃.The character of this polymkeric substance is listed in table 4 and table 5.Embodiment 7-9

With isotactic index (I.I) is 96%, and melt flow index is that 1.5 homo-polypropylene (I) is molded as sheet material at 240 ℃, and carries out longitudinal stretching at 140 ℃ of stretch rates by 5 times.

The sheet material of gained like this is used as liner.The following polypropene composition of laminating layer (II) on a surface of liner.

With 100 weight parts contain that 25% (weight) isotactic index is 96% for (I.I), melt flow index (230 ℃) be 6.5 and fusing point be that propylene-1-butylene random copolymers (B) mixture (PBR) that makes more than 140 ℃ the homo-polypropylene grain and 75% (weight) mixes with 0.1 weight part anti and 0.16 weight part surface slip agent.Mixture (being polypropene composition (II)) fusion in extruding machine with gained is squeezed on the liner under 200 ℃, then to form laminated sheet material.

This laminated sheet material carries out side direction at 170 ℃ of stretch rates with 10 times and stretches, and is allowed to condition at then to keep cooling under the stretched state basically.

The result obtains comprising that thickness is the biaxial stretching laminated film of 22 microns homo-polypropylene (I) layer (liner) and the thickness polypropene composition (II) layer (thermal synthesis layer) that is 3 microns.The results are shown in table 4.Comparative Examples 3

Except that the propylene-1-butylene-random copolymers (B) that when preparing polypropene composition, replaces obtaining among the preparation embodiment 5, make laminated film by method identical among the embodiment 7 with the propylene-1-butylene-random copolymers that obtains in the preparation Comparative Examples 8.The results are shown in table 4.Embodiment 10-12

With isotactic index (I.I) is 96%, and melt flow index is 6.5 homo-polypropylene (I) fusion, and sends into the die head that forms laminated film under 240 ℃ of resin temperatures.

In addition, in another extruding machine, 100 weight parts are contained 25% (weight) melt flow index (230 ℃) be 6.5 and fusing point be that propylene-1-butylene random copolymers (B) of making more than 140 ℃ the Atactic Polypropelene grain and 75% (weight) mixture and 0.1 weight part anti and 0.16 weight part surface slip agent (PBR) mixes and be incorporated in fusion in the extruding machine.Gained polypropene composition (II) is sent into the die head of above-mentioned formation laminated film under 200 ℃ of resin temperatures.

Homo-polypropylene (I) and polypropene composition (II) were extruded the die head that forms laminated film simultaneously, obtained comprising that thickness is the laminated film of 45 microns homo-polypropylene (I) layer (liner) and the thickness polypropene composition (II) layer (thermal synthesis layer) that is 5 microns.The results are shown in table 4.Comparative Examples 4

Except that the propylene-1-butylene-random copolymers (B) that replaces obtaining among the preparation embodiment 5 with the propylene-1-butylene-random copolymers that obtains in the preparation Comparative Examples 8, make laminated film by method identical among the embodiment 10.The results are shown in table 4.

Table 4-I

		Embodiment 7	Comparative Examples 3	Embodiment 8	Embodiment 9
						(B) PBR (1) propylene content % (mole) 1-butene content % (mole) (2) inherent viscosity (η) (dl/g) (3) Mw/Mn (4) B value (5) Tm (℃) (6) degree of crystallinity (%)		PBR-5 (Preparation Example 5) 76 24 1.63 2.05 1.00 92 40	PBR-8 (preparation Comparative Examples 8) 77 23 1.91 3.40 0.92 110 48	PBR-6 (Preparation Example 6) 81 19 1.65 2.10 1.02 103 49	PBR-7 (Preparation Example 7) 85 15 1.67 2.18 1.03 110 53
Composition	(A) polypropylene % (weight)	??????25	????25	?????25	?????25
						(B) PBR% (weight)	??????75	????75	?????75	?????75
	Thickness	(I) liner (μ m)	??????22	????22	?????22						?????22
(II) thermal synthesis layer (μ m)						??????3	????3	?????3	?????3
		(1) optical haze degree (%) (2) optical haze degree (%) over time		??????1.4 ??????1.1	????1.7 ????2.9					?????0.6 ?????1.0	?????0.8 ?????1.0
(3) glossiness (%)						??????115	????112	?????128	?????126
		(4) the smooth property of smooth property/stiction/kinetic friction (5) and time/stiction/kinetic friction		??????1.0 ??????0.5 ??????0.6 ??????0.4	????3.2 ????1.0 ????1.6 ????0.7					?????0.3 ?????0.3 ?????0.3 ?????0.3	?????0.3 ?????0.3 ?????0.3 ?????0.3

Table 4-I (continuing)

	Embodiment 7	Comparative Examples 3	Embodiment 8	Embodiment 9
					(B) 85 ℃ of 90 ℃ of 95 ℃ of 100 ℃ of 105 ℃ of 110 ℃ of 115 ℃ 120 ℃ (9) thermal viscosities (mm) of PBR (6) resistance to blocking (g/cm) (7) resistance to blocking temporal evolution (g/cm) (8) heat sealing strength (g/15mm) are 95 ℃ 100 ℃ 105 ℃ 110 ℃ 115 ℃ 120 ℃ 125 ℃	PBR-5 (Preparation Example 5) 1.9 3.0 40 480 630 550 730 520 520 300 32 15 8767	PBR-8 (preparation Comparative Examples 8) 2.6 7.0 20 50 130 480 570 570 520 300 230 120 63 27 13 18	PBR-6 (Preparation Example 6) 0.2 0.0 90 300 540 440 440 470 300 120 25 10 8	PBR-7 (Preparation Example 7) 0.1 0.0 20 320 540 500 300 120 42 12

????130℃ ????135℃ ????140℃

Embodiment 7877

Comparative Examples 3 16 15 18

Embodiment 8667

Embodiment 9565

Table 4-II

		Embodiment 10	Comparative Examples 4	Embodiment 11	Embodiment 12
						(B) BPR (1) propylene content % (mole) 1-butene content % (mole) (2) inherent viscosity (η) (dl/g) (3) Mw/Mn (4) B value (5) Tm (℃) (6) degree of crystallinity (%)		PBR-5 (Preparation Example 5) 76 24 1.63 2.05 1.00 92 40	PBR-8 (preparation Comparative Examples 8) 77 23 1.91 3.40 0.92 110 48	PBR-6 (Preparation Example 6) 81 19 1.65 2.10 1.02 103 49	PBR-7 (Preparation Example 7) 85 15 1.67 2.18 1.03 110 53
Composition	(A) polypropylene % (weight)	????25	????25	????25	????25
						(B) PBR% (weight)	????75	????75	????75	????75
	Thickness	(I) liner (μ m)	????45	????45	????45						????45
(II) thermal synthesis layer (μ m)						????5	????5	????5	????5
		(1) optical haze degree (%) (2) optical haze degree (%) over time		????1.8 ????2.0	????2.1 ????10.2					????4.2 ????4.0	????2.1 ????2.1
(3) glossiness (%)						????118	????114	????98	????114

????(B)BPR	PBR-5 (preparation embodiment 5)	PBR-8 (preparation Comparative Examples 8)	PBR-6 (preparation embodiment 6)	PBR-7 (preparation embodiment 7)
					(4) slipping/static friction/dynamic friction (5) slipping and time/static friction/dynamic friction (6) resistance to blocking (g/cm) (7) resistance to blocking temporal evolution (g/cm) (8) heat sealing strength (g/15mm) are 80 ℃ 90 ℃ 100 ℃ 110 ℃ 120 ℃ 130 ℃ 140 ℃ 150 ℃ 160 ℃ 170 ℃	????0.2 ????0.2 ????1.7 ????1.0 ????30 ????130 ????800 ????1650 ????1720 ????1730 ????2070	Not smooth 2.4 4.6 140 1,270 1,790 2,080 2,300 1,940 2,200 2100	????0.2 ????0.2 ????0.3 ????0.0 ????50 ????590 ????1570 ????440 ????440 ????470 ????440 ????440 ????470	????0.2 ????0.1 ????0.4 ????0.5 ????20 ????320 ????540 ????500 ????320 ????540 ????500

Table 4-II (continuing)

	Embodiment 10	Comparative Examples 4	Embodiment 11	Embodiment 12
					(9) thermal viscosity (mm) is 100 ℃ 110 ℃ 120 ℃ 130 ℃ 140 ℃ 150 ℃ 160 ℃ 170 ℃	????300 ????130 ????25 ????20 ????20 ????50 ????60	????300 ????220 ????120 ????50 ????40 ????55 ????50	????300 ????140 ????30 ????20 ????20 ????40 ????60	????300 ????220 ????30 ????20 ????20 ????40 ????50

Embodiment 13-14

Is 96% with isotactic index for (I.I), and melt flow index is that 1.5 homo-polypropylene (I) is molded as sheet material at 240 ℃, and carries out longitudinal stretching at 140 ℃ of stretch rates by 5 times.

The sheet material of gained is used as liner.The following polypropene composition of laminating layer (II) on a surface of liner.

With 100 weight parts contain that 75% (weight) isotactic index is 96% for (I.I), melt flow index (230 ℃) be 6.5 and fusing point be that propylene-1-butylene random copolymers (B) mixture (PBR) that makes more than 140 ℃ the Atactic Polypropelene grain and 25% (weight) mixes with 0.1 weight part anti and 0.16 weight part surface slip agent.Mixture (being polypropene composition (II)) fusion in extruding machine with gained is squeezed on the liner under 200 ℃, then to form laminated sheet material.

This laminated sheet material carries out side direction at 170 ℃ of stretch rates with 10 times then and stretches, and is allowed to condition at then to keep cooling under the stretched state basically.

The result obtains comprising that thickness is the biaxial stretching laminated film of 22 microns homo-polypropylene (I) layer (liner) and the thickness polypropene composition (II) layer (thermal synthesis layer) that is 3 microns.The results are shown in table 5.Comparative Examples 5

Except that the propylene-1-butylene-random copolymers (B) that when preparing polypropene composition, replaces obtaining among the preparation embodiment 5, make laminated film by method identical among the embodiment 13 with the propylene-1-butylene-random copolymers that obtains in the preparation Comparative Examples 8.The results are shown in table 5.Comparative Examples 15-17

With isotactic index (I.I) is 96%, and melt flow index is 6.5 homo-polypropylene (I) fusion, and sends into the die head that forms laminated film under 240 ℃ of resin temperatures.

In addition, in another extruding machine, 100 weight parts are contained 75% (weight) melt flow index (230 ℃) be 6.5 and fusing point be that propylene-1-butylene random copolymers (B) mixture (PBR) of making more than 140 ℃ the Atactic Polypropelene grain and 25% (weight) mixes with 0.1 weight part anti and 0.16 weight part surface slip agent and with its fusion.Gained polypropene composition (II) is sent into the die head of above-mentioned formation laminated film under 200 ℃ of resin temperatures.

Homo-polypropylene (I) and polypropene composition (II) were extruded the die head that forms laminated film simultaneously, obtained comprising that thickness is the laminated film of 45 microns homo-polypropylene (I) layer (liner) and the thickness polypropene composition (II) layer (thermal synthesis layer) that is 5 microns.The results are shown in table 5.

Comparative Examples 6

Except that the propylene-1-butylene-random copolymers (B) that when preparing polypropene composition, replaces obtaining among the preparation embodiment 5, make laminated film by method identical among the embodiment 15 with the propylene-1-butylene-random copolymers that obtains in the preparation Comparative Examples 8.The results are shown in table 5.

Table 5-I

		Embodiment 13	Comparative Examples 5	Embodiment 14
					(B) PBR (1) propylene content % (mole) 1-butene content % (mole) (2) inherent viscosity (η) (dl/g) (3) Mw/Mn (4) B value (5) Tm (℃) (6) degree of crystallinity (%)		PBR-5 (Preparation Example 5) 76 24 1.63 2.05 1.00 92 40	PBR-8 (preparation Comparative Examples 8) 77 23 1.91 3.40 0.92 110 48	PBR-6 (Preparation Example 6) 81 19 1.65 2.10 1.02 103 49
Composition	(A) polypropylene % (weight)	????75	????75	????75
					(B) PBR% (weight)	????25	????25	????25
	Thickness	(I) liner (μ m)	????22	????22					????22
(II) thermal synthesis layer (μ m)					????3	????3	????3
		(1) optical haze degree (%) (2) optical haze degree (%) over time		????1.7 ????1.4				????1.5 ????1.2	????1.9 ????1.6
(3) glossiness (%)					????122	????123	????122

	Embodiment 13	Comparative Examples 5	Embodiment 14
				(4) slipping/static friction/dynamic friction (5) adhesion tendency (g/cm) (6) adhesion tendency and 100 ℃ 105 ℃ 110 ℃ 115 ℃ 120 ℃ 125 ℃ 130 ℃ 135 ℃ 140 ℃ 150 ℃ of time (g/cm) (7) heat sealing strengths (g/15mm)	????0.3 ????0.3 ????0.1 ????0.3 ????40 ????100 ????400 ????510 ????540 ????500 ????460	????0.4 ????0.4 ????0.3 ????0.6 ????50 ????140 ????350 ????460 ????460 ????460 ????470 ????480	????0.3 ????0.3 ????0.1 ????0.3 ????30 ????180 ????510 ????480 ????480 ????480 ????470

Table 5-II

		Embodiment 15	Comparative Examples 6	Embodiment 16	Embodiment 17
						(B) resistance to blocking (1) propylene content % (mole) 1-butene content % (mole) (2) inherent viscosity (η) (dl/g) (3) Mw/Mn (4) B value (5) Tm (℃) (6) degree of crystallinity (%)		PBR-5 (Preparation Example 5) 76 24 1.63 2.05 1.00 92 40	PBR-8 (preparation Comparative Examples 8) 77 23 1.91 3.40 0.92 110 48	PBR-6 (Preparation Example 6) 81 19 1.65 2.10 1.02 103 49	PBR-7 (Preparation Example 7) 85 15 1.67 2.18 1.03 110 53
Composition	(A) polypropylene % (weight)	????75	????75	????75	?????75
						(B) PBR% (weight)	????25	????25	????25	?????25
	Thickness	(I) liner (μ m)	????45	????45	????45						?????45
(II) thermal synthesis layer (μ m)						????5	????5	????5	?????5
		(1) optical haze degree (%) (2) optical haze degree (%) over time		????2.4 ????2.0	????2.5 ????2.8					????2.0 ????2.0	?????2.1 ?????2.4
(3) glossiness (%)						????111	????115	????117	?????115
		(4) the smooth property of smooth property/stiction/kinetic friction (5) and time/stiction/kinetic friction		????0.2 ????0.2 ????0.2 ????1.0	????0.3 ????0.2 ????0.3 ????1.5					????0.3 ????0.2 ????0.2 ????0.3	?????0.2 ?????0.2 ?????0.3 ?????0.3

(6) resistance to blocking (g/cm) (7) resistance to blocking and time change (g/cm) (8) heat sealing strengths (g/15mm) 100 ℃ 110 ℃ 120 ℃ 130 ℃ 140 ℃ 150 ℃ 160 ℃

Embodiment 15 0.2 1.0 10 160 1,900 2,130 2,090 2400

Comparative Examples 6 0.3 1.5 10 80 1,360 2,380 2,370 2,520 2360

Embodiment 16 0.2 0.3 20 100 1,130 2,130 2,090 2400

Embodiment 17 0.3 0.3 20 80 900 2,100 1,900 1,890 1960

Claims (14)

1. polypropene composition, it comprises:

(A) polypropylene of 5～95 weight % and

(B) propylene of 95～5 weight %-1-butylene random copolymers;

Described propylene-1-butylene random copolymers (B) has following performance:

(1) multipolymer contains 50～95mol% from the formation unit of propylene and the 50～5mol% formation unit from 1-butylene;

(2) limiting viscosity that records in 135 ℃ naphthalane is 0.1～12dl/g;

(3) molecular weight distribution of being measured by gel permeation chromatography (GPC) (Mw/Mn) is not more than 3; With

(4) the B parameter value of the degree of randomness of demonstration comonomer sequence distribution is 1.0～1.5.

2. polypropene composition as claimed in claim 1, wherein polypropylene (A) is the random copolymers of propylene and the alkene except propylene, it contains and is not more than the unit of 10mol% from alkene.

3. polypropene composition as claimed in claim 1, wherein propylene-1-butylene random copolymers (B) also has following performance (5) and (6) except having performance (1)～(4):

(5) the fusing point Tm that is recorded by dsc is 60～140 ℃, and fusing point Tm and 1-butylene constitute unitary content M (mol%) and satisfy following relation:

-2.6M+130≤Tm≤-2.3M+155; With

(6) degree of crystallinity C that is recorded by the X-ray diffraction method and 1-butylene constitute unitary content M (mol%) and satisfy following relation:

C≥-1.5M＋75

4. polypropene composition as claimed in claim 3, wherein the B parameter value of propylene-1-butylene random copolymers (B) is 1.0～1.3.

5. polypropene composition as claimed in claim 1, wherein propylene-1-butylene random copolymers (B) is to use the olefin polymerization catalysis that comprises following component to make:

(a) transistion metal compound of representing by following structural formula (1):

Wherein M is periodictable IVa, Va, or the transition metal of VIa family,

R ¹And R ²Be respectively hydrogen atom, halogen atom, the alkyl of 1～20 carbon atom, the halo alkyl of 1～20 carbon atom contains silica-basedly, contains the oxygen base, contains sulfenyl, nitrogenous base or phosphorous-containigroups groups,

R ³For can or containing the alkyl of 1～20 carbon atom of silica-based replacement by halogen atom,

R ⁴Be the alkyl of hydrogen atom or 1～20 carbon atom,

X ¹And X ²Be respectively hydrogen atom, halogen atom, the alkyl of 1～20 carbon atom, the halo alkyl of 1～20 carbon atom, contain the oxygen base or contain sulfenyl and

Y is the bivalent hydrocarbon radical of 1～20 carbon atom, the divalence halo alkyl of 1～20 carbon atom, and divalence contains silica-based, the germanic base of divalence, divalence contains tinbase ,-O-,-CO-,-S-,-SO-,-SO ₂-,-NR ⁵-,-P (R ⁵)-,-P (O) (R ⁵)-,-BR ⁵-or-AlR ⁵-(R ⁵Be hydrogen atom, halogen atom, the halo alkyl of the alkyl of 1～20 carbon atom or 1～20 carbon atom);

(b) (b-1) Organoaluminoxy compound, and/or

(b-2) can with the right compound of transistion metal compound (a) reacting forming ion; With optional,

(c) organo-aluminium compound.

6. polypropene composition as claimed in claim 5, wherein in the structural formula of representing transistion metal compound (a) (I), R ¹Be methyl.

7. polypropene composition as claimed in claim 5, wherein in the structural formula of representing transistion metal compound (a) (I), R ¹It is the alkyl of 2～6 carbon atoms.

8. polypropylene composite film, it comprises:

(I) the crystalline polypropylene layer and

(II) layer of being made by the described polypropene composition of claim 1, this is pressed at least one surface of crystalline polypropylene layer (I) layer by layer.

9. polypropylene composite film as claimed in claim 8, wherein polypropene composition layer (I) comprises:

The polypropylene of 5～50 weight % (A) and

The propylene of 95～50 weight %-1-butylene random copolymers (B).

10. polypropylene composite film as claimed in claim 8, wherein polypropene composition layer (II) comprises:

Be not less than 50 weight % and less than the polypropylene (A) of 90 weight % and

Be not less than 10 weight % and less than propylene-1-butylene random copolymers (B) of 50 weight %.

11. as claim 9 or 10 described polypropylene composite films, wherein polypropylene (A) is for containing the unitary crystalline polypropylene from propylene that is not less than 90mol%.

12. as claim 9 or 10 described polypropylene composite films, wherein the limiting viscosity (2) of propylene-1-butylene random copolymers (B) is 0.1～5dl/g.

13. polypropylene composite film as claimed in claim 8, wherein crystalline polypropylene layer (I) is unstretched mistake.

14. polypropylene composite film as claimed in claim 8, wherein crystalline polypropylene layer (I) is to pass through biaxial stretch-formed mistake.