CN113912181A - Preparation method of water treatment carbon source - Google Patents
Preparation method of water treatment carbon source Download PDFInfo
- Publication number
- CN113912181A CN113912181A CN202111336798.3A CN202111336798A CN113912181A CN 113912181 A CN113912181 A CN 113912181A CN 202111336798 A CN202111336798 A CN 202111336798A CN 113912181 A CN113912181 A CN 113912181A
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- China
- Prior art keywords
- carbon source
- water
- parts
- stirring
- water treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 60
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000003756 stirring Methods 0.000 claims abstract description 42
- 150000001720 carbohydrates Chemical class 0.000 claims abstract description 29
- 239000000654 additive Substances 0.000 claims abstract description 22
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 22
- 239000003899 bactericide agent Substances 0.000 claims abstract description 22
- 239000000243 solution Substances 0.000 claims abstract description 19
- 230000000996 additive effect Effects 0.000 claims abstract description 17
- 239000007864 aqueous solution Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 39
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 33
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 33
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 16
- 235000013312 flour Nutrition 0.000 claims description 11
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 11
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 10
- 239000008103 glucose Substances 0.000 claims description 10
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 7
- 229930091371 Fructose Natural products 0.000 claims description 7
- 239000005715 Fructose Substances 0.000 claims description 7
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 7
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 7
- 229930006000 Sucrose Natural products 0.000 claims description 7
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 7
- 229960004793 sucrose Drugs 0.000 claims description 7
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 claims description 5
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical group C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 claims description 5
- 239000006013 carbendazim Substances 0.000 claims description 5
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000005747 Chlorothalonil Substances 0.000 claims description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 2
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000005720 sucrose Substances 0.000 claims description 2
- 235000014633 carbohydrates Nutrition 0.000 claims 1
- 239000010865 sewage Substances 0.000 abstract description 11
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 abstract description 5
- 238000013329 compounding Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 230000036632 reaction speed Effects 0.000 abstract description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 4
- 239000001632 sodium acetate Substances 0.000 description 4
- 235000017281 sodium acetate Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 230000004075 alteration Effects 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/28—Anaerobic digestion processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/06—Nutrients for stimulating the growth of microorganisms
Abstract
The invention discloses a preparation method of a water treatment carbon source, which comprises the following steps: preparing raw materials: saccharides, bactericides, additives and water; mixing saccharide with water at room temperature, and stirring to obtain saccharide solution; adding a bactericide into the sugar water solution to obtain a sterile sugar water solution; and adding an additive into the sterile sugar aqueous solution, fully stirring, and obtaining the carbon source after the carbon source is completely dissolved. The invention provides a preparation method of a water treatment carbon source, which adopts a plurality of carbon sources for compounding and is used for sewage treatment, and the COD reaction speed and effect can be well increased; solves the problems of insufficient carbon source and high ammonia nitrogen of the inlet water of the urban sewage treatment plant for a long time.
Description
Technical Field
The invention relates to the technical field of wastewater treatment, in particular to a preparation method of a water treatment carbon source.
Background
With the continuous and rapid development of economy in China, the problem of environmental pollution is obvious, wherein sewage discharge is a big problem. The increasing living standard of people leads to the long-term water quality conditions of insufficient carbon source and high ammonia nitrogen in the inlet water of the urban sewage treatment plant, and the ammonia nitrogen in the outlet water of the sewage treatment plant exceeds the standard. Therefore, an additional carbon source, such as glucose, methanol, sodium acetate, etc., is required.
Glucose is used as a carbon source, the denitrification rate is slow, and the glucose is used to easily cause mass propagation of bacteria and increase the sludge production; the methanol is easy to be utilized by denitrifying bacteria, but has certain toxicity and higher price; sodium acetate is used as a carbon source, the response of the denitrification process is fast, the sodium acetate can be used as emergency treatment of a sewage treatment plant, but the price is high, and the sodium acetate cannot be used on a large scale.
In addition, according to research, the diversity of the florae in the environment of the single carbon source is gradually weakened, and the denitrification capability of the denitrifying florae is weakened by long-term feeding of the single carbon source. Because the carbon source input amount of the urban sewage plant is large, the development of a novel economic and effective carbon source is very necessary.
Disclosure of Invention
Technical problem to be solved
Aiming at the defects of the prior art, the invention provides a preparation method of a water treatment carbon source, which adopts a plurality of carbon sources for compounding and is used for sewage treatment, and the COD reaction speed and effect can be well increased; solves the problems of insufficient carbon source and high ammonia nitrogen of the inlet water of the urban sewage treatment plant for a long time.
(II) technical scheme
In order to achieve the purpose, the invention provides the following technical scheme:
a preparation method of a water treatment carbon source comprises the following steps:
(1) preparing raw materials: saccharides, bactericides, additives and water;
(2) mixing saccharide with water at room temperature, and stirring to obtain saccharide solution;
(3) adding a bactericide into the sugar water solution to obtain a sterile sugar water solution;
(4) and adding an additive into the sterile sugar aqueous solution, fully stirring, and obtaining the carbon source after the carbon source is completely dissolved.
Optionally, the saccharide substance is a mixture of glucose, sucrose, maltose and fructose.
Optionally, the bactericide is carbendazim or chlorothalonil.
Optionally, the carbon source comprises: saccharide, bactericide, additive and water.
Optionally, the additives include: methanol, glycol, acetic acid, glycerol and flour.
Optionally, the weight ratio of the methanol to the glycol to the acetic acid to the glycerol to the flour is 1: 1-2:1-2:0.5-1:2-3.
Optionally, the carbon source comprises, by weight: 25-35 parts of saccharides, 3-5 parts of bactericide, 5-10 parts of additive and 45-55 parts of water.
Optionally, the saccharide comprises: 8-10 parts of glucose, 5-7 parts of cane sugar, 5-8 parts of maltose and 7-10 parts of fructose.
Optionally, in the step (2), the stirring speed is as follows: 60-80 r/min; stirring time: 20-30 min; stirring at 20-35 deg.C;
in the step (4), the stirring speed is as follows: 100-120 r/min; stirring time: 25-35 min; stirring at 20-35 deg.C;
the invention also provides a water treatment carbon source which is obtained by adopting the preparation method.
(III) advantageous effects
Compared with the prior art, the invention provides a preparation method of a water treatment carbon source, which has the following beneficial effects:
1. the invention provides a preparation method of a water treatment carbon source, which adopts a plurality of carbon sources for compounding and is used for sewage treatment, and the COD reaction speed and effect can be well increased; solves the problems of insufficient carbon source and high ammonia nitrogen of the inlet water of the urban sewage treatment plant for a long time.
2. The invention adopts the compounding of various saccharides and carbon source additives, has mutual synergy and adopts the bactericide for sterilization, thereby avoiding the bacterial reproduction and reducing the sludge production.
3. The methanol, the glycol, the acetic acid, the glycerol and the flour have a synergistic effect mutually, and can supplement a carbon source more effectively.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The embodiment 1 of the invention provides a preparation method of a water treatment carbon source, which comprises the following steps:
(1) preparing raw materials: 25 parts of saccharides, 3 parts of bactericide, 5 parts of additive and 45 parts of water;
the saccharide substance includes: 8 parts of glucose, 5 parts of cane sugar, 5 parts of maltose and 7 parts of fructose;
the bactericide is carbendazim;
the additive comprises: methanol, glycol, acetic acid, glycerol and flour.
The weight ratio of the methanol to the glycol to the acetic acid to the glycerol to the flour is 1: 1:1:0.5:2.
(2) Mixing the saccharide with water at room temperature, and stirring uniformly at the following stirring speed: 60 r/min; stirring time: 20 min; stirring at the temperature of 20 ℃; dissolving the saccharide in water to obtain a sugar water solution;
(3) adding a bactericide into the sugar water solution to obtain a sterile sugar water solution;
(4) adding an additive into the sterile sugar aqueous solution, and fully stirring at the following stirring speed: 100 r/min; stirring time: 25 min; stirring at the temperature of 20 ℃;
and after all the carbon source is dissolved, obtaining the carbon source.
Example 2
The embodiment 2 of the invention provides a preparation method of a water treatment carbon source, which comprises the following steps:
(1) preparing raw materials: 35 parts of saccharides, 5 parts of bactericide, 10 parts of additive and 55 parts of water;
the saccharide substance includes: 10 parts of glucose, 7 parts of cane sugar, 8 parts of maltose and 10 parts of fructose;
the bactericide is carbendazim;
the additive comprises: methanol, glycol, acetic acid, glycerol and flour.
The weight ratio of the methanol to the glycol to the acetic acid to the glycerol to the flour is 1: 2:2:1:3.
(2) Mixing the saccharide with water at room temperature, and stirring uniformly at the following stirring speed: 80 r/min; stirring time: 30 min; stirring temperature: 35 ℃; dissolving the saccharide in water to obtain a sugar water solution;
(3) adding a bactericide into the sugar water solution to obtain a sterile sugar water solution;
(4) adding an additive into the sterile sugar aqueous solution, and fully stirring at the following stirring speed: 120 r/min; stirring time: 35 min; the stirring temperature is 35 ℃;
and after all the carbon source is dissolved, obtaining the carbon source.
Example 3
Embodiment 3 of the present invention provides a method for preparing a water treatment carbon source, comprising the following steps:
(1) preparing raw materials: 30 parts of saccharides, 4 parts of bactericide, 8 parts of additive and 50 parts of water;
the saccharide substance includes: 9 parts of glucose, 6 parts of cane sugar, 7 parts of maltose and 8 parts of fructose;
the bactericide is carbendazim;
the additive comprises: methanol, glycol, acetic acid, glycerol and flour.
The weight ratio of the methanol to the glycol to the acetic acid to the glycerol to the flour is 1: 1.5:1.5:0.8:2.5.
(2) Mixing the saccharide with water at room temperature, and stirring uniformly at the following stirring speed: 70 r/min; stirring time: 25 min; the stirring temperature is 30 ℃; dissolving the saccharide in water to obtain a sugar water solution;
(3) adding a bactericide into the sugar water solution to obtain a sterile sugar water solution;
(4) adding an additive into the sterile sugar aqueous solution, and fully stirring at the following stirring speed: 110 r/min; stirring time: 30 min; the stirring temperature is 30 ℃;
and after all the carbon source is dissolved, obtaining the carbon source.
It should be noted that, in this document, terms such as "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Without further limitation, an element defined by the phrase "comprising an … …" does not exclude the presence of other identical elements in a process, method, article, or apparatus that comprises the element.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (10)
1. A preparation method of a water treatment carbon source is characterized by comprising the following steps:
(1) preparing raw materials: saccharides, bactericides, additives and water;
(2) mixing saccharide with water at room temperature, and stirring to obtain saccharide solution;
(3) adding a bactericide into the sugar water solution to obtain a sterile sugar water solution;
(4) and adding an additive into the sterile sugar aqueous solution, fully stirring, and obtaining the carbon source after the carbon source is completely dissolved.
2. The method for preparing a carbon source for water treatment according to claim 1, wherein the sugar is a mixture of glucose, sucrose, maltose and fructose.
3. The method for preparing the carbon source for water treatment according to claim 1, wherein the bactericide is carbendazim or chlorothalonil.
4. The method of claim 1, wherein the carbon source comprises: saccharide, bactericide, additive and water.
5. The method of claim 1, wherein the additive comprises: methanol, glycol, acetic acid, glycerol and flour.
6. The method for preparing the water treatment carbon source according to claim 1, wherein the weight ratio of the methanol, the glycol, the acetic acid, the glycerol and the flour is 1: 1-2:1-2:0.5-1:2-3.
7. The method for preparing the carbon source for water treatment according to claim 1, wherein the carbon source comprises the following components in parts by weight: 25-35 parts of saccharides, 3-5 parts of bactericide, 5-10 parts of additive and 45-55 parts of water.
8. The method of claim 1, wherein the carbohydrate comprises: 8-10 parts of glucose, 5-7 parts of cane sugar, 5-8 parts of maltose and 7-10 parts of fructose.
9. The method for preparing a carbon source for water treatment according to claim 1,
in the step (2), the stirring speed is as follows: 60-80 r/min; stirring time: 20-30 min; stirring at 20-35 deg.C;
in the step (4), the stirring speed is as follows: 100-120 r/min; stirring time: 25-35 min; the stirring temperature is 20-35 ℃.
10. A water treatment carbon source obtained by the production method according to any one of claims 1 to 9.
Priority Applications (1)
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CN202111336798.3A CN113912181A (en) | 2021-11-12 | 2021-11-12 | Preparation method of water treatment carbon source |
Applications Claiming Priority (1)
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CN202111336798.3A CN113912181A (en) | 2021-11-12 | 2021-11-12 | Preparation method of water treatment carbon source |
Publications (1)
Publication Number | Publication Date |
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CN113912181A true CN113912181A (en) | 2022-01-11 |
Family
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CN202111336798.3A Pending CN113912181A (en) | 2021-11-12 | 2021-11-12 | Preparation method of water treatment carbon source |
Country Status (1)
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2021
- 2021-11-12 CN CN202111336798.3A patent/CN113912181A/en active Pending
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Legal Events
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PB01 | Publication | ||
PB01 | Publication | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20220111 |
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WD01 | Invention patent application deemed withdrawn after publication |