CN113909717B - Titanium/aluminum/titanium double-sided multilayer composite material fusion brazing method - Google Patents
Titanium/aluminum/titanium double-sided multilayer composite material fusion brazing method Download PDFInfo
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- CN113909717B CN113909717B CN202111285564.0A CN202111285564A CN113909717B CN 113909717 B CN113909717 B CN 113909717B CN 202111285564 A CN202111285564 A CN 202111285564A CN 113909717 B CN113909717 B CN 113909717B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K28/00—Welding or cutting not covered by any of the preceding groups, e.g. electrolytic welding
- B23K28/02—Combined welding or cutting procedures or apparatus
Abstract
A titanium/aluminum/titanium double-sided multilayer composite material melt brazing method belongs to the field of metal composite material welding, wherein a Y-shaped groove is processed on a part to be welded to promote the brazing filler metal to be wetted and spread, argon gas is adopted to protect gas shielded welding bottoming, argon tungsten arc welding is adopted for filling, a single-layer double-pass melt brazing cover surface is arranged on the side of an electric arc offset groove, and front welding is completed; and then back chipping is carried out, and the back welding of the workpiece is completed according to the front welding process. The Y-shaped groove and back gouging double-side welding process method provided by the invention balances the thermal stress of the front surface and the back surface of the workpiece, reduces the welding deformation and strengthens the strength of the root of the welding seam; the arc offset single-layer double-channel cover surface fusion brazing method realizes good spreading of the welding wire on the titanium clad plate, effectively controls the distribution and content of intermetallic compounds and improves the performance of a joint; simple operation, strong adaptability and good universality.
Description
Technical Field
The invention relates to the field of metal composite material welding, in particular to a titanium/aluminum/titanium double-sided multilayer composite material fusion brazing method.
Background
Titanium is a non-ferrous metal with good heat resistance, corrosion resistance, high specific strength, toughness and plasticity, and titanium alloy have wide application in the fields of aerospace, ocean, chemical industry and the like due to excellent performance. The total amount of titanium resources in China is the first of the world, and in recent years, the titanium industry develops rapidly, but because of difficult smelting process, higher cost and limited development. The aluminum alloy has the advantages of low cost, light weight and the like, is nonferrous metal with the largest application amount in the industry at present, and particularly the appearance of high-strength aluminum alloy, so that the aluminum alloy becomes the most ideal material of various components. However, aluminum alloys have strength and corrosion resistance properties inferior to those of titanium, and are limited in use in certain specific fields. The titanium and aluminum are compounded into the titanium-aluminum double-layer or multi-layer composite material, so that the advantages of the two metals can be integrated, and the composite material is suitable for various requirements of more fields on material performance. The titanium-aluminum-titanium composite material is a novel light high-strength material which is formed by coating a layer of titanium plate on the upper surface and the lower surface of an aluminum or aluminum alloy substrate and performing processes of vacuum brazing, rolling or explosive welding and the like, and has wide prospects in the national defense industry fields of transportation, marine equipment and the like. The realization of high-quality connection of the composite board is a key problem of expanding the application range of the composite material in a structural member and improving the comprehensive performance of the structural member. The welding has the advantages of good strength, strong applicability and the like in the aspect of metal connection, and is an important processing mode. However, dissimilar metal welding is obviously different from the same metal, and the realization difficulty is higher. The invention relates to titanium/aluminum/titanium composite board welding, which relates to the field of dissimilar metal connection and composite material connection and has more difficulties in the aspects of technical operation and mechanism research. The physical and chemical properties of titanium and aluminum are far from each other, the melting points are close to 1000 degrees, and when welding, if titanium is in a molten state, aluminum is seriously burnt, and a joint is difficult to meet the requirements. The difference between the heat conductivity of titanium and aluminum is about 15 times, so that the temperature gradient inside the welding seam is obvious, and the thermal stress is severe. The linear expansion coefficient of aluminum is much higher than that of titanium, so that welding deformation cannot be ignored, and the resilience of titanium is large, the elastic modulus is small, and deformation correction is difficult. In addition, titanium and aluminum are not metallurgically compatible, the solubility of titanium atoms in aluminum is extremely low, and the solid solubility is zero at room temperature. During welding, titanium and aluminum are increased along with temperature, intermetallic compounds are easily formed, and flaky Ti3Al, tiAl, tiAl3 and the like are gathered at an interface, so that the performance of the joint is greatly reduced.
Aiming at the welding of the composite plate, the currently adopted method comprises the steps of controlling the penetration through the design of a joint structure and avoiding the mutual dissolution of dissimilar materials, such as a strip pasting process of planing off a covering plate and then filling the covering plate. However, the method needs to select a welding heat source with high energy density, has a strict process and high operation requirements, and has the problems of complex process and low efficiency on a multi-layer and double-sided thin-coating composite material, and the industrial application is difficult. The other idea of composite board welding is to perform full penetration welding connection by adding a transition layer which is infinitely mutually soluble with the base plate and the covering plate, but the thickness and size requirements are limited, and the method is not easy to realize in thin plate welding. The welding of titanium and aluminum dissimilar metals adopts solid phase connection methods such as friction welding, diffusion welding, vacuum brazing and the like at present. Better joint performance can be obtained by friction welding, but the size and the shape of a weldment have certain limitations; diffusion welding and brazing joints generally have the condition of low tensile strength and are difficult to meet various requirements. The titanium/aluminum/titanium double-sided multilayer composite material has no formed welding process report yet.
Melt brazing has attracted increasing attention as a method of joining dissimilar metals by controlling the welding process to melt a low melting point metal to form a melt joint and a high melting point metal to remain solid to form a brazed joint. Depending on the heat source, there are laser brazing, electron beam brazing, arc brazing, and the like. Laser, electron beam etc. heat source energy density are high, can realize the meticulous control of linear energy to accurate control intermetallic compound thickness guarantees the joint performance, but laser welding, electron beam welding, and equipment cost is high, and electron beam vacuum chamber has more restricted the size of weldment, makes technical industry promote to receive the influence. The arc heat source has the advantages of low cost, convenient operation, strong adaptability and the like, particularly, the aluminum oxide film can be crushed by the cathode atomization effect generated when the alternating current TIG welding is used for welding aluminum and aluminum alloy, the effect of removing the oxide film is achieved, and the welding quality is further improved. Therefore, the invention designs a fusion brazing method using electric arc as a heat source, which has good joint performance and strong operability, fills the gap of the welding process of the titanium/aluminum/titanium multilayer double-sided composite plate, and promotes the application of the titanium-aluminum composite material in structural members.
Disclosure of Invention
The invention aims to provide a titanium/aluminum/titanium double-sided multilayer composite material fusion brazing method, which realizes the fusion brazing connection of a multilayer composite plate through effective structural design and process control. The heat input is controlled by adopting a single-layer double-pass welding seam with electric arc bias, the welding temperature field gradient of the titanium/aluminum joint is reduced, the micro-phase structure at a metal combination interface is optimized, the aluminum alloy soldering flux is promoted to be well spread on the titanium side, and the joint performance is improved; by adopting the process method of Y-shaped groove and back gouging double-sided welding, the heat stress of the front and back sides of the workpiece is balanced, the quality of the backing weld is enhanced, and the problems of welding deformation and weak strength of the root of the weld are solved. The method is a titanium/aluminum/titanium double-sided multilayer composite board welding method which is simple and convenient to operate and good in applicability.
A titanium/aluminum/titanium double-sided multilayer composite material fusion brazing method is characterized by comprising the following steps:
step 1, performing pre-welding treatment on the titanium/aluminum/titanium double-sided multilayer composite board, polishing to remove an oxidation film, and wiping with acetone; processing a Y-shaped groove to promote the solder to be wetted and spread; the upper surface and the lower surface of the workpiece are tightly pressed by a red copper pressing plate, and a semicircular groove with the radius of 5-10mm is formed in a lower copper base plate;
step 2, backing by MIG welding, filling aluminum alloy welding wires, enabling an electric arc to be vertical to a welding seam, enabling the height to be 5mm, enabling the welding current to be 140-150A, enabling the welding speed to be 1-1.5mm/s, protecting by 99.9% argon gas, enabling the gas flow to be 11L/min, and completing backing welding;
step 5, turning over and clamping the workpiece, and performing back gouging on the bottom-off welding line to strengthen the strength of the root of the welding line, wherein the back gouging depth is 2mm; cleaning the groove, cooling the weldment to be lower than 100 ℃, filling the weld joint by adopting alternating current flexible TIG welding, wherein the height of an electric arc is 5mm, the welding current is 100-120A, the welding speed is 0.8-1.2mm/s, the argon protection is 99.9 percent, the gas flow is 11L/min, the interlayer temperature is 60-100 ℃, and finishing 2-layer filling welding bead;
Compared with the prior art, the invention has the following advantages:
1. the invention connects the titanium/aluminum/titanium multilayer composite board by a melt brazing mode, adopts the welding bead design of double-welding-bead cover surface welding, the electric arc offset and the heat input control, realizes the good spreading of welding wires on the titanium clad plate, and has good joint performance.
2. According to the invention, the welding sequence and the welding bead arrangement of Y-shaped groove and back gouging double-sided welding are adopted, so that the problem of weak strength of the root of a welding seam is solved, and meanwhile, the welding deformation is reduced;
3. the titanium/aluminum/titanium multilayer composite board is connected in the melting brazing mode, the welding cost is low, the operation is simple and convenient, the technical adaptability is strong, the distribution and the content of intermetallic compounds are effectively controlled through structural design and process control, and good joint performance is realized.
Drawings
FIG. 1 is a schematic diagram of a composite plate structure and a joint groove structure.
Fig. 2 is a schematic view of the front bead arrangement and welding sequence.
Fig. 3 is a schematic view of the structure of the additional gas protection dragging cover.
FIG. 4 is a schematic view of the back weld bead arrangement and welding sequence of the work piece after back gouging.
Fig. 5 is a schematic view after weld forming.
Detailed Description
A titanium/aluminum/titanium double-sided multilayer composite material fusion brazing method comprises the following steps:
step 1, performing pre-welding treatment on a titanium/aluminum/titanium double-sided multilayer composite board, polishing to remove an oxidation film, and wiping with acetone; processing a Y-shaped groove to promote the solder to be wetted and spread; the upper surface and the lower surface of the workpiece are compressed by a red copper pressing plate, and a semicircular groove with the radius of 5-10mm is formed in the lower copper base plate;
step 2, backing by MIG welding, filling aluminum alloy welding wires, enabling electric arcs to be perpendicular to welding seams, enabling the height to be 5mm, enabling welding current to be 140-150A, enabling welding speed to be 1-1.5mm/s, protecting by 99.9% argon, enabling gas flow to be 11L/min, and completing backing welding;
step 5, turning over and clamping the workpiece, and performing back gouging on the bottoming weld joint to strengthen the root strength of the weld joint, wherein the back gouging depth is 2mm; cleaning a groove, cooling a weldment to be lower than 100 ℃, filling a weld joint by adopting alternating current flexible TIG welding, wherein the height of an electric arc is 5mm, the welding current is 100-120A, the welding speed is 0.8-1.2mm/s, the argon gas protection is 99.9%, the gas flow is 11L/min, the interlayer temperature is 60-100 ℃, and completing 2-layer filling welding bead;
The titanium/aluminum/titanium double-sided multilayer composite board material is a 5-layer composite board formed by TA2/1060/6061/1060/TA2 explosive welding, the board thickness is 13mm, and the thickness of the composite layer is sequentially 1.5mm, 1mm, 8mm, 1mm and 1.5mm from top to bottom.
The size of the Y-shaped groove is as follows: the Y-shaped groove with the angle of 45 degrees has the truncated edge size of 4mm, the assembly gap of 1mm and the joint assembly dislocation amount of not more than 0.1 delta.
The welding sequence and the welding seam layout of the workpiece are as follows: 1 MIG backing weld → 2 layer TIG filling weld → single layer double arc melting braze welding cover surface weld → turn back root cleaning → 2 layer TIG filling weld → double layer single arc melting braze welding cover surface weld.
The aluminum alloy welding wire is ER5356-AlMg5Cr.
In step 4 and step 6 of the invention, the arc is biased to one side of the groove for 2-3mm, and the arc inclination angle is 100 degrees; the height of the electric arc is 5mm, the welding current is 110A, the welding speed is 1.5-2mm/s, and the gas flow is 15L/min.
In step 4 and step 6 of the invention, the welding torch additional drag cover is made of red copper plates with the thickness of 1mm, the length is 145mm, the width is 50mm, the arch height is 50mm, and a soft skirt is additionally arranged below the welding torch additional drag cover.
In the steps 4 and 6 of the invention, the welding torch is additionally provided with a dragging cover for independent gas supply, the protective gas is 99.99 percent of primary argon, the gas flow is 15-20L/min, the protective gas is supplied 10S in advance, and the protective gas is closed 5-10S in delay.
In the step 4 and the step 6 of the invention, the single-layer double-channel cover surface welding lines are crossed at the central line of the groove to form a fusion welding line, and the brazing welding line is formed on the side of the parent metal of the composite plate.
Example 1
(1) The welding method is characterized in that a TA2/1060/6061/1060/TA2 titanium/aluminum/titanium 5-layer composite plate is adopted for welding, the plate thickness delta =13mm, the thickness of the composite plate is sequentially 1.5mm, 1mm, 8mm, 1mm and 1.5mm from top to bottom, and a novel ER5356-AlMg5Cr welding wire developed by Zhejiang light aluminum product Limited company is selected as a filling material.
(2) Cleaning the surface of the TA2/1060/6061/1060/TA2 titanium/aluminum/titanium composite plate before welding, and processing a groove at the welding part, wherein the joint structure is shown in figure 1; in fig. 1, 1 represents the thickness δ,2 of the covering plate, the thickness δ,3 of the aluminum material, the thickness δ, 4 of the aluminum alloy, 5 of the titanium covering plate, 1060, 6 of the aluminum material, 6061, 7 of the aluminum alloy, assembly clearance, 8 of the bevel angle, 9 of the bevel angle and the size of the truncated edge.
(3) Assembling a workpiece to be welded, wherein the assembling clearance is 1mm, the assembling dislocation quantity is not more than 0.1 delta, fixing the upper surface and the lower surface of the workpiece by using a red copper pressing plate, and forming a semicircular forming groove with the radius of 5-10mm on a lower copper base plate.
(4) The backing weld 11 in FIG. 2 is completed by MIG welding, the arc height is 5mm during welding, the welding current is 140-150A, the welding speed is 1-1.5mm/s, the argon gas protection is 99.9%, and the gas flow is 11L/min.
(5) Finishing a first filling welding line 12 and a second filling welding line 13 in the figure 2 by adopting alternating current flexible TIG welding, wherein the arc height is 5mm, the welding current is 100-120A, the welding speed is 0.8-1.2mm/s, the argon gas protection is 99.9 percent, the gas flow is 15L/min, and the interlayer temperature is 60-100 ℃; in fig. 2, 11, backing weld, 12, first filling weld, 13, second filling weld, 14, first capping weld, 15, second capping weld, 16, red copper pressure plate, 17, red copper backing plate, 18, forming groove, 19 and welding torch.
(6) Adopting a fusion brazing cover surface to connect titanium/aluminum dissimilar metal, adding a protective dragging cover (shown in figure 3) behind a welding torch during welding, independently supplying gas in the dragging cover, wherein the protective gas is 99.99% primary argon, the gas flow is 15-20L/min, feeding gas in advance by 10S, and closing the protective gas in delay of 5-10S; in figure 3, 21, a gas protection dragging cover, 22, a free connecting pipe, 23, a connecting pipe, 24, a soft skirt, 25, the height dimension of the dragging cover, 26 and the length dimension of the dragging cover.
(7) And (3) finishing the first cap welding seam 14 and the second cap welding seam 15 in the figure 2 by adopting melt brazing, wherein an electric arc is offset from the groove welding seam side by 2-3mm during welding, the electric arc inclination angle is 100 degrees, the electric arc height is about 5mm, the welding current is 110A, the welding speed is 1.5-2mm/s, the gas flow is 15L/min, a brazed joint is formed on the base metal side of the composite plate, and a fusion welded joint is formed between the two welding seams.
(8) And (3) clamping the workpiece by turning over, performing back chipping on the back-gouging welding line, wherein the back chipping depth is about 2mm, polishing after back chipping to form a groove shown as the back surface 1 of the back-gouged workpiece in figure 4, and cooling the welded part to be below 100 ℃.
(9) The first filling weld joint 36 and the second filling weld joint 37 in the figure 4 are filled by adopting alternating current flexible TIG welding, the height of an electric arc is 5mm during welding, the welding current is 100-120A, the welding speed is 0.8-1.2mm/s, the argon gas protection is 99.9 percent, the gas flow is 15L/min, and the interlayer temperature is 60-100 ℃.
(10) Finishing a first cap surface welding line 38 and a second cap surface welding line 39 in the step 4 by adopting fusion brazing, adding a protective dragging cover behind a welding torch during welding, independently supplying gas in the dragging cover, wherein the protective gas is 99.99% of primary argon, the gas flow is 15-20L/min, the gas is supplied in advance for 10S, and the protective gas is closed after 5-10S is delayed; welding an arc offset slope side 2-3mm, an arc inclination angle 100 degrees, an arc height about 5mm, welding current 110A, a welding speed 1.5-2mm/s and a gas flow 15L/min, forming a brazing joint on the composite plate base metal side, and forming a fusion welding joint between two welding joints. In fig. 4, 31 is the back shape of the workpiece after back gouging, 32 is the red copper press plate, 33 is the red copper press plate, 34 is the red copper press plate, 35 is the red copper press plate, 36 is the first filling bead, 37 is the second filling bead, 38 is the first cap weld, 39 is the second cap weld.
(11) Cleaning after welding: and cleaning the welded joint after welding, including polishing and acetone wiping.
(12) The tensile strength of the joint is 180MPa, and the appearance of the joint is shown in FIG. 5.
Example 2:
the present embodiment differs from the first embodiment in that: and 6, finishing the cover surface welding line in the step 10 by single-pass single-layer welding, wherein other steps and parameters are the same as those of the first specific embodiment.
Example 3:
the difference between the present embodiment and the first embodiment is: the aluminum alloy welding wire ER5356-AlMg5Cr used in welding is replaced by an aluminum-silicon welding wire 4043, and other steps and parameters are the same as those of the first embodiment.
Example 4:
the present embodiment differs from the first embodiment in that: in step 7, the arc has no offset and no inclination angle, and other steps and parameters are the same as those of the first embodiment.
Example 5:
the difference between the present embodiment and the first embodiment is: in step 7, the arc is not biased, and other steps and parameters are the same as those of the first embodiment.
The invention utilizes the electric arc as the melting brazing method of the heat source, the joint performance is good, the operability is strong, the vacancy of the welding process of the titanium/aluminum/titanium multilayer double-sided composite board is filled, and the application of the titanium-aluminum composite material in the structural member is promoted.
Claims (8)
1. The electric arc melting brazing method of the titanium/aluminum/titanium double-sided multilayer composite material is characterized by comprising the following steps of:
step 1, performing pre-welding treatment on a titanium/aluminum/titanium double-sided multilayer composite board, polishing to remove an oxidation film, and wiping with acetone; processing a Y-shaped groove to promote the solder to be wetted and spread; the upper surface and the lower surface of the workpiece are compressed by a red copper pressing plate, and a semicircular groove with the radius of 5-10mm is formed in the lower copper base plate;
step 2, backing by MIG welding, filling aluminum alloy welding wires, enabling an electric arc to be vertical to a welding seam, enabling the height to be 5mm, enabling the welding current to be 140-150A, enabling the welding speed to be 1-1.5mm/s, protecting by 99.9% argon gas, enabling the gas flow to be 11L/min, and completing backing welding;
step 3, filling by adopting alternating current flexible TIG welding, wherein the height of an electric arc is 5mm, the welding current is 100-120A, the welding speed is 0.8-1.2mm/s, the argon gas with the concentration of 99.9% is used for protection, the gas flow is 15L/min, the interlayer temperature is 60-100 ℃, and 2-layer filling welding passes are completed;
step 4, adopting a single-layer double-channel electric arc melting brazing cover surface, controlling heat input, adjusting temperature gradient, attaching a protective dragging cover behind a welding torch, independently supplying air in the dragging cover, filling with aluminum alloy welding wires, forming a brazing joint on the side of the composite plate base metal, and forming a fusion welding joint between two welding seams;
step 5, turning over and clamping the workpiece, and performing back gouging on the bottoming weld joint to strengthen the root strength of the weld joint, wherein the back gouging depth is 2mm; cleaning the groove, cooling the weldment to be lower than 100 ℃, filling the weld joint by adopting alternating current flexible TIG welding, wherein the height of an electric arc is 5mm, the welding current is 100-120A, the welding speed is 0.8-1.2mm/s, the argon protection is 99.9 percent, the gas flow is 11L/min, the interlayer temperature is 60-100 ℃, and finishing 2-layer filling welding bead;
step 6, adopting a single-layer double-channel electric arc melting brazing cover surface to control heat input; and a protective dragging cover is added behind the welding torch, the dragging cover is filled with aluminum alloy welding wires for independent gas supply, a brazing joint is formed on the side of the composite plate base metal, and a fusion welding joint is formed between two welding seams.
2. The method for arc welding and brazing the titanium/aluminum/titanium double-sided multilayer composite material according to claim 1, wherein the method comprises the following steps: the titanium/aluminum/titanium double-sided multilayer composite plate is a 5-layer composite plate formed by TA2/1060/6061/1060/TA2 explosive welding, the plate thickness is 13mm, and the thickness of the composite plate is sequentially 1.5mm, 1mm, 8mm, 1mm and 1.5mm from top to bottom.
3. The method for arc welding and brazing the titanium/aluminum/titanium double-sided multilayer composite material according to claim 1, wherein the method comprises the following steps: the welding sequence and the welding seam layout of the workpieces are as follows: 1 MIG backing weld → 2 layer TIG filling weld → single layer double arc melting braze welding cover surface weld → turn back root cleaning → 2 layer TIG filling weld → double layer single arc melting braze welding cover surface weld.
4. The method for arc welding and brazing the titanium/aluminum/titanium double-sided multilayer composite material according to claim 1, wherein the method comprises the following steps: the aluminum alloy welding wire is ER5356 AlMg5Cr.
5. The method for arc welding and brazing the titanium/aluminum/titanium double-sided multilayer composite material according to claim 1, wherein the method comprises the following steps: in the step 4 and the step 6, the arc is offset from one side of the groove by 2-3mm, and the arc inclination angle is 100 degrees; the height of the electric arc is 5mm, the welding current is 110A, the welding speed is 1.5-2mm/s, and the gas flow is 15L/min.
6. The method for arc welding and brazing the titanium/aluminum/titanium double-sided multilayer composite material according to claim 1, wherein the method comprises the following steps: in the step 4 and the step 6, the welding torch additional dragging cover is made of a red copper plate with the thickness of 1mm, the length is 145mm, the width is 50mm, the arch height is 50mm, and a soft skirt is attached to the lower part of the welding torch additional dragging cover.
7. The method for arc welding and brazing the titanium/aluminum/titanium double-sided multilayer composite material according to claim 1, wherein the method comprises the following steps: and 4, independently supplying gas in the welding torch additional drag cover, wherein the protective gas is 99.99 percent of primary argon, the gas flow is 15-20L/min, the protective gas is supplied 10S in advance, and the protective gas is closed 5-10S in delay.
8. The method for arc welding and brazing the titanium/aluminum/titanium double-sided multilayer composite material according to claim 1, wherein the method comprises the following steps: in the step 4 and the step 6, the single-layer double-channel cover surface welding seams are crossed at the central line of the groove to form a fusion welding seam, and the brazing welding seam is formed on the base metal side of the composite plate.
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